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(PDF) Calorimetric study of nanocomposites of epoxy network DGEBA n = 0/m-XDA with gold nanoparticles | Francisco Fraga López and EUGENIO A. RODRÍGUEZ NÚÑEZ - Academia.edu

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The evolved heat (ΔHt), the glass transition temperature (Tg), and the associated activation energies of this relaxation process have been determined. Below a certain concentration of AuNPs (=8.5%, in mg AuNP/g epoxy matrix), Tg decreases linearly with the concentration of AuNPs, but above it, Tg is not affected. The degree of conversion α of this epoxy system was analyzed by the semiempirical Kamal’s model, evidencing that diffusion correction is required at high values of α. Activation energy values suggest that AuNPs can cause some impediments at the beginning of the crosslinking process (n-order mechanism). 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translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="6" data-entity-id="117291079" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/117291079/Novolac_epoxy_resin_from_4_4_dihydroxybenzophenone_Thermal_thermomechanical_interfacial_and_cure_kinetics_with_DGEBA_DICY_blend">Novolac epoxy resin from 4,4′-dihydroxybenzophenone: Thermal, thermomechanical, interfacial, and cure kinetics with DGEBA/DICY blend</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="283823307" href="https://independent.academia.edu/MonishaBaby1">Monisha Baby</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Journal of Applied Polymer Science, 2017</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Novolac epoxy resin from 4,4′-dihydroxybenzophenone: Thermal, thermomechanical, interfacial, and cure kinetics with DGEBA/DICY blend&quot;,&quot;attachmentId&quot;:113186690,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/117291079/Novolac_epoxy_resin_from_4_4_dihydroxybenzophenone_Thermal_thermomechanical_interfacial_and_cure_kinetics_with_DGEBA_DICY_blend&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/117291079/Novolac_epoxy_resin_from_4_4_dihydroxybenzophenone_Thermal_thermomechanical_interfacial_and_cure_kinetics_with_DGEBA_DICY_blend"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="7" data-entity-id="27419200" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/27419200/Investigation_of_the_curing_reactions_of_some_multifunctional_epoxy_resins_using_differential_scanning_calorimetry">Investigation of the curing reactions of some multifunctional epoxy resins using differential scanning calorimetry</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="51458251" href="https://independent.academia.edu/DanRosu3">Dan Rosu</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Thermochimica Acta, 2001</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Investigation of the curing reactions of some multifunctional epoxy resins using differential scanning calorimetry&quot;,&quot;attachmentId&quot;:47675853,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/27419200/Investigation_of_the_curing_reactions_of_some_multifunctional_epoxy_resins_using_differential_scanning_calorimetry&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/27419200/Investigation_of_the_curing_reactions_of_some_multifunctional_epoxy_resins_using_differential_scanning_calorimetry"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="8" data-entity-id="73017526" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/73017526/Curing_Kinetic_of_an_Epoxy_amine_System_by_Calorimetric_Method_and_FT_IR_Spectroscopy">Curing Kinetic of an Epoxy-amine System by Calorimetric Method and FT-IR Spectroscopy</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="36908407" href="https://independent.academia.edu/LuminitaWagner">Luminita Wagner</a></div><p class="ds-related-work--metadata ds2-5-body-xs">2009</p><p class="ds-related-work--abstract ds2-5-body-sm">The study presents experimental data regarding the curing reactions of some epoxy systems consisting of diglycidyl ethers of bisphenol A and different amine hardeners at room temperature and at microwaves. The curing reaction of the system composed of an epoxy resin (ROPOXID P 401) and 4,4’-diaminodiphenylmethane (HT 972) was studied by differential scanning calorimetry (DSC) and FT-IR spectroscopy. The degree of conversion obtained using FT-IR method is very close to that obtained using calorimetric method.</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Curing Kinetic of an Epoxy-amine System by Calorimetric Method and FT-IR Spectroscopy&quot;,&quot;attachmentId&quot;:81706879,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/73017526/Curing_Kinetic_of_an_Epoxy_amine_System_by_Calorimetric_Method_and_FT_IR_Spectroscopy&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/73017526/Curing_Kinetic_of_an_Epoxy_amine_System_by_Calorimetric_Method_and_FT_IR_Spectroscopy"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="9" data-entity-id="21505378" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/21505378/Studies_on_the_curing_and_thermal_behaviour_of_DGEBA_in_the_presence_of_bis_4_carboxyphenyl_dimethyl_silane">Studies on the curing and thermal behaviour of DGEBA in the presence of bis(4-carboxyphenyl) dimethyl silane</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="42596805" href="https://iitd.academia.edu/VeenaChoudhary">Veena Choudhary</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Polymer International, 2003</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Studies on the curing and thermal behaviour of DGEBA in the presence of bis(4-carboxyphenyl) dimethyl silane&quot;,&quot;attachmentId&quot;:41949098,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/21505378/Studies_on_the_curing_and_thermal_behaviour_of_DGEBA_in_the_presence_of_bis_4_carboxyphenyl_dimethyl_silane&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/21505378/Studies_on_the_curing_and_thermal_behaviour_of_DGEBA_in_the_presence_of_bis_4_carboxyphenyl_dimethyl_silane"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div></div></div><div class="ds-sticky-ctas--wrapper js-loswp-sticky-ctas hidden"><div class="ds-sticky-ctas--grid-container"><div class="ds-sticky-ctas--container"><button class="ds2-5-button js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;continue-reading-button--sticky-ctas&quot;,&quot;attachmentId&quot;:74706774,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;workUrl&quot;:null}">See full PDF</button><button class="ds2-5-button ds2-5-button--secondary js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;download-pdf-button--sticky-ctas&quot;,&quot;attachmentId&quot;:74706774,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;workUrl&quot;:null}"><span class="material-symbols-outlined" style="font-size: 20px" translate="no">download</span>Download PDF</button></div></div></div><div class="ds-below-fold--grid-container"><div class="ds-work--container js-loswp-embedded-document"><div class="attachment_preview" data-attachment="Attachment_74706774" style="display: none"><div class="js-scribd-document-container"><div class="scribd--document-loading js-scribd-document-loader" style="display: block;"><img alt="Loading..." src="//a.academia-assets.com/images/loaders/paper-load.gif" /><p>Loading Preview</p></div></div><div style="text-align: center;"><div class="scribd--no-preview-alert js-preview-unavailable"><p>Sorry, preview is currently unavailable. 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Mali</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Polymer-plastics Technology and Engineering, 2011</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Influence of Nano-Inorganic Particles on Properties of Epoxy Nanocomposites&quot;,&quot;attachmentId&quot;:47826560,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/9310299/Influence_of_Nano_Inorganic_Particles_on_Properties_of_Epoxy_Nanocomposites&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-related-work-grid-card-view-pdf" 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class="ds-related-work--metadata ds2-5-body-xs">Journal of Applied Polymer Science, 2004</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Cure kinetics of epoxy/anhydride nanocomposite systems with added reactive flame retardants&quot;,&quot;attachmentId&quot;:66820477,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/47959315/Cure_kinetics_of_epoxy_anhydride_nanocomposite_systems_with_added_reactive_flame_retardants&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-related-work-grid-card-view-pdf" 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class="ds-related-work--metadata"><a class="js-related-work-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="49708919" href="https://independent.academia.edu/MousaGhaemy">Mousa Ghaemy</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Chinese Journal of Polymer Science, 2011</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Effect of nanosilica on the kinetics of cure reaction and thermal degradation of epoxy resin&quot;,&quot;attachmentId&quot;:54363835,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/34498059/Effect_of_nanosilica_on_the_kinetics_of_cure_reaction_and_thermal_degradation_of_epoxy_resin&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" 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ether of bisphenol a (BADGE n = 0) with isophorone diamine</a><div class="ds-related-work--metadata"><a class="js-related-work-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="27676762" href="https://itgustavoamadero.academia.edu/IvanVazquez">Ivan Vazquez</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Journal of Applied Polymer Science, 2009</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Influence of the filler CaCO 3 on the cure kinetic of the epoxy network diglycidyl ether of bisphenol a (BADGE n = 0) with isophorone 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