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class="u-taCenter"></div><div class="profile--tab_content_container js-tab-pane tab-pane active" id="all"><div class="profile--tab_heading_container js-section-heading" data-section="Papers" id="Papers"><h3 class="profile--tab_heading_container">Papers by Monisha Baby</h3></div><div class="js-work-strip profile--work_container" data-work-id="117291081"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/117291081/Catechol_Amine_Decorated_Epoxy_Resin_as_an_Underwater_Adhesive_A_Coacervate_Concept_Using_a_Liquid_Marble_Strategy"><img alt="Research paper thumbnail of Catechol-Amine-Decorated Epoxy Resin as an Underwater Adhesive: A Coacervate Concept Using a Liquid Marble Strategy" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/117291081/Catechol_Amine_Decorated_Epoxy_Resin_as_an_Underwater_Adhesive_A_Coacervate_Concept_Using_a_Liquid_Marble_Strategy">Catechol-Amine-Decorated Epoxy Resin as an Underwater Adhesive: A Coacervate Concept Using a Liquid Marble Strategy</a></div><div class="wp-workCard_item"><span>ACS omega</span><span>, Feb 16, 2023</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="117291081"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item 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href="https://www.academia.edu/117291080/_Makeover_by_DOPAMINE_An_Easy_Reliable_Effective_Supramolecular_Decoration_of_Boron_Nitride_and_Its_Hybrid_with_Epoxy_as_Thermally_Conductive_Composite"><img alt="Research paper thumbnail of ‘Makeover’ by DOPAMINE: An Easy, Reliable, Effective Supramolecular Decoration of Boron Nitride and Its Hybrid with Epoxy as Thermally Conductive Composite" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/117291080/_Makeover_by_DOPAMINE_An_Easy_Reliable_Effective_Supramolecular_Decoration_of_Boron_Nitride_and_Its_Hybrid_with_Epoxy_as_Thermally_Conductive_Composite">‘Makeover’ by DOPAMINE: An Easy, Reliable, Effective Supramolecular Decoration of Boron Nitride and Its Hybrid with Epoxy as Thermally Conductive Composite</a></div><div class="wp-workCard_item"><span>Transactions of the Indian National Academy of Engineering</span><span>, Mar 1, 2021</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">In this work, an easy, reliable, effective approach for preparation of modified Boron Nitride ( B...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">In this work, an easy, reliable, effective approach for preparation of modified Boron Nitride ( BN ) from h -BN ( Hexagonal boron nitride) was developed via liquid-phase exfoliation using a dopamine chemistry. Supramolecular interactions of the polydopamine (PDA) with h -BN has been used to achieve the facile surface modification of h -BN by forming a PDA shell on its surface. The successful and effective preparation of different h- BN -PDA hybrids has been confirmed by Scanning Electron Microscopy (SEM), Raman spectroscopy, XRD, IR and TGA investigations. The PDA coating increases the dispersibility of these hybrids as filler in polymers. Since polymer-based thermal interface materials (TIMs) with excellent thermal conductivity and electrical resistivity are in high demand, epoxy composites filled with h- BN , BBN (Ball milled Boron Nitride), MBN (Modified Boron Nitride) and MBBN (Modified Ball milled Boron Nitride) were processed. The thermal conductivity is as high as 4 W/mK for MBBN as compared with 0.2 W/mK of neat epoxy. This method of producing multifunctional exfoliated h- BN provides eco-friendly, easy handling, and suitable as a unique paradigm for developing the next generation of thermal conductive devices and solution-processed semiconductors.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="117291080"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="117291080"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 117291080; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); 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} }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="117291079"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/117291079/Novolac_epoxy_resin_from_4_4_dihydroxybenzophenone_Thermal_thermomechanical_interfacial_and_cure_kinetics_with_DGEBA_DICY_blend"><img alt="Research paper thumbnail of Novolac epoxy resin from 4,4′-dihydroxybenzophenone: Thermal, thermomechanical, interfacial, and cure kinetics with DGEBA/DICY blend" class="work-thumbnail" src="https://attachments.academia-assets.com/113186690/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/117291079/Novolac_epoxy_resin_from_4_4_dihydroxybenzophenone_Thermal_thermomechanical_interfacial_and_cure_kinetics_with_DGEBA_DICY_blend">Novolac epoxy resin from 4,4′-dihydroxybenzophenone: Thermal, thermomechanical, interfacial, and cure kinetics with DGEBA/DICY blend</a></div><div class="wp-workCard_item"><span>Journal of Applied Polymer Science</span><span>, Dec 21, 2017</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">A novolac epoxy resin based on 4,4 0-dihydroxybenzophenone (BZPNE) was synthesized via epoxidatio...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">A novolac epoxy resin based on 4,4 0-dihydroxybenzophenone (BZPNE) was synthesized via epoxidation of 4,4 0-dihydroxybenzophenone novolac resin (BZPN). BZPN was obtained by strong mineral acid catalyzed reaction of 4,4 0-dihydroxybenzophenone (BZP) and paraformaldehyde. The formation of BZPNE and BZPN was confirmed by Fourier transform infrared spectroscopy, proton and carbon nuclear magnetic resonance spectroscopy, gel permeation chromatography, and epoxy equivalent weight. Different blends of BZPNE with diglycidyl ether of bisphenol-A (DGEBA; EEW $180) were cured using dicyandiamide were characterized by thermogravimetric analysis, thermomechanical analysis, dynamic mechanical analysis, and interfacial property between aluminum adherends at ambient and elevated temperature. Thermal properties were found to improve on increasing quantity of BZPNE in DGEBA as it is evidenced from glass transition temperature (T g). Likewise, no deterioration in interfacial properties was observed with the highest quantity of BZPNE (30%) in DGEBA blend, when tested at 150 8C. Cure kinetics of compositions were studied by nonisothermal differential scanning calorimetry and Kissinger method was used to compute the kinetic parameters such as frequency factor (A), activation energy (E a) followed by the dependency of rate constant (k) on temperature of different blends. V</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="58454f6ad3deecf236fbec4385e42dba" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":113186690,"asset_id":117291079,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/113186690/download_file?s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="117291079"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="117291079"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 117291079; 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</script> <div class="js-work-strip profile--work_container" data-work-id="117291077"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/117291077/Bio_mimicking_hybrid_polymer_architectures_as_adhesion_promoters_for_low_and_high_surface_energy_substrates"><img alt="Research paper thumbnail of Bio-mimicking hybrid polymer architectures as adhesion promoters for low and high surface energy substrates" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/117291077/Bio_mimicking_hybrid_polymer_architectures_as_adhesion_promoters_for_low_and_high_surface_energy_substrates">Bio-mimicking hybrid polymer architectures as adhesion promoters for low and high surface energy substrates</a></div><div class="wp-workCard_item"><span>Journal of Industrial and Engineering Chemistry</span><span>, 2021</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">Abstract Thermoplastic materials like High Density Polyethylene (HDPE) and Polytetrafluoroethylen...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">Abstract Thermoplastic materials like High Density Polyethylene (HDPE) and Polytetrafluoroethylene (PTFE) are promising candidates for specialty industry/aerospace sectors considering their exceptional properties and lower densities. However, the low surface energy leading to poor wetting and reduced adhesion curtails the scope of their wide-spread usage. In this work, we report adhesion promoter primers based on epoxy–catechol with and without fluorinated polymer and investigated their adhesion promotion efficiency on low/high surface energy substrates. The rational design of catechol-fluorine-epoxy hybrid network, mimicking mussel chemistry enabled a non-destructive surface activating approach resulting in profound adhesion promotion. The fluorine containing primer could effectively enhance adhesion between homo and hetero interfaces of Aluminium/HDPE/PTFE owing to the good interface interaction and could outperform common etching methods. A series of molecular level characterizations together with computational and AFM studies provided evidences for the high degree of interaction of the primer between the substrates and epoxy-based adhesives. Bond integrity endurance test using a weight of 10 and 20 kg resulted in ‘no fail’ categorization for the primed substrates during the entire 40 days test duration. The catechol-functionalized primers reported here can be a good overreaching approach to keep non-polar substrates afloat in advanced sectors.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="117291077"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="117291077"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 117291077; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=117291077]").text(description); $(".js-view-count[data-work-id=117291077]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 117291077; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='117291077']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); 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</script> <div class="js-work-strip profile--work_container" data-work-id="117291076"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/117291076/Bioinspired_surface_activators_for_wet_dry_environments_through_greener_epoxy_catechol_amine_chemistry"><img alt="Research paper thumbnail of Bioinspired surface activators for wet/dry environments through greener epoxy-catechol amine chemistry" class="work-thumbnail" src="https://attachments.academia-assets.com/113186689/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/117291076/Bioinspired_surface_activators_for_wet_dry_environments_through_greener_epoxy_catechol_amine_chemistry">Bioinspired surface activators for wet/dry environments through greener epoxy-catechol amine chemistry</a></div><div class="wp-workCard_item"><span>Applied Surface Science</span><span>, 2019</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">This is a PDF file of an article that has undergone enhancements after acceptance, such as the ad...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">This is a PDF file of an article that has undergone enhancements after acceptance, such as the addition of a cover page and metadata, and formatting for readability, but it is not yet the definitive version of record. This version will undergo additional copyediting, typesetting and review before it is published in its final form, but we are providing this version to give early visibility of the article. Please note that, during the production process, errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="cbcbc3819835b67334543b6e9fd1a8ba" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":113186689,"asset_id":117291076,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/113186689/download_file?s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="117291076"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="117291076"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 117291076; 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="117291071"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/117291071/Non_isothermal_cure_and_decomposition_kinetics_of_epoxy_imidazole_systems"><img alt="Research paper thumbnail of Non-isothermal cure and decomposition kinetics of epoxy–imidazole systems" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/117291071/Non_isothermal_cure_and_decomposition_kinetics_of_epoxy_imidazole_systems">Non-isothermal cure and decomposition kinetics of epoxy–imidazole systems</a></div><div class="wp-workCard_item"><span>Journal of Thermal Analysis and Calorimetry</span><span>, 2017</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">Non-isothermal curing kinetics of a tetra functional epoxy resin with imidazole-based curing agen...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">Non-isothermal curing kinetics of a tetra functional epoxy resin with imidazole-based curing agents was investigated by differential scanning calorimetry (DSC), and decomposition of the cured compounds was studied by thermogravimetric analysis. N,N,N′,N′-tetraglycidyl-4, 4′diaminodiphenylmethane (TGDDM) was cured with three types of tertiary amine curing agents including 1-methyl imidazole (MI), 2-methyl imidazole (2MI) and 2-ethyl 4-methyl imidazole (EMI). These systems exhibited cure initiation at around 70–90 °C by DSC. 2-methyl imidazole and 2-ethyl 4-methyl imidazole showed two cure initiation profiles, while the 1-substituted counterpart, MI, showed a single cure initiation profile by DSC. The Kissinger equation was applied to calculate the apparent activation energy for epoxy–imidazole cure reactions. The rate constants and the pre-exponential factor were also determined. The activation energy varied from 59 to 65 kJ mol−1 for the systems. The Flynn–Wall–Ozawa iso-conversional approach was used to elucidate the activation energies at different extents of conversion during the cure reactions. The cured systems are found thermally stable up to 250 °C. Decomposition kinetics of cured networks was studied using Kissinger equation and Flynn–Wall–Ozawa iso-conversional approach. The cured resins were analyzed for the glass transition temperature and compared with that of a conventional amine-cured system.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="117291071"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="117291071"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 117291071; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=117291071]").text(description); 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</script> </div><div class="profile--tab_content_container js-tab-pane tab-pane" data-section-id="19063277" id="papers"><div class="js-work-strip profile--work_container" data-work-id="117291081"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/117291081/Catechol_Amine_Decorated_Epoxy_Resin_as_an_Underwater_Adhesive_A_Coacervate_Concept_Using_a_Liquid_Marble_Strategy"><img alt="Research paper thumbnail of Catechol-Amine-Decorated Epoxy Resin as an Underwater Adhesive: A Coacervate Concept Using a Liquid Marble Strategy" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/117291081/Catechol_Amine_Decorated_Epoxy_Resin_as_an_Underwater_Adhesive_A_Coacervate_Concept_Using_a_Liquid_Marble_Strategy">Catechol-Amine-Decorated Epoxy Resin as an Underwater Adhesive: A Coacervate Concept Using a Liquid Marble Strategy</a></div><div class="wp-workCard_item"><span>ACS omega</span><span>, Feb 16, 2023</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="117291081"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="117291081"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 117291081; 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</script> <div class="js-work-strip profile--work_container" data-work-id="117291080"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/117291080/_Makeover_by_DOPAMINE_An_Easy_Reliable_Effective_Supramolecular_Decoration_of_Boron_Nitride_and_Its_Hybrid_with_Epoxy_as_Thermally_Conductive_Composite"><img alt="Research paper thumbnail of ‘Makeover’ by DOPAMINE: An Easy, Reliable, Effective Supramolecular Decoration of Boron Nitride and Its Hybrid with Epoxy as Thermally Conductive Composite" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/117291080/_Makeover_by_DOPAMINE_An_Easy_Reliable_Effective_Supramolecular_Decoration_of_Boron_Nitride_and_Its_Hybrid_with_Epoxy_as_Thermally_Conductive_Composite">‘Makeover’ by DOPAMINE: An Easy, Reliable, Effective Supramolecular Decoration of Boron Nitride and Its Hybrid with Epoxy as Thermally Conductive Composite</a></div><div class="wp-workCard_item"><span>Transactions of the Indian National Academy of Engineering</span><span>, Mar 1, 2021</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">In this work, an easy, reliable, effective approach for preparation of modified Boron Nitride ( B...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">In this work, an easy, reliable, effective approach for preparation of modified Boron Nitride ( BN ) from h -BN ( Hexagonal boron nitride) was developed via liquid-phase exfoliation using a dopamine chemistry. Supramolecular interactions of the polydopamine (PDA) with h -BN has been used to achieve the facile surface modification of h -BN by forming a PDA shell on its surface. The successful and effective preparation of different h- BN -PDA hybrids has been confirmed by Scanning Electron Microscopy (SEM), Raman spectroscopy, XRD, IR and TGA investigations. The PDA coating increases the dispersibility of these hybrids as filler in polymers. Since polymer-based thermal interface materials (TIMs) with excellent thermal conductivity and electrical resistivity are in high demand, epoxy composites filled with h- BN , BBN (Ball milled Boron Nitride), MBN (Modified Boron Nitride) and MBBN (Modified Ball milled Boron Nitride) were processed. The thermal conductivity is as high as 4 W/mK for MBBN as compared with 0.2 W/mK of neat epoxy. This method of producing multifunctional exfoliated h- BN provides eco-friendly, easy handling, and suitable as a unique paradigm for developing the next generation of thermal conductive devices and solution-processed semiconductors.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="117291080"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="117291080"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 117291080; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=117291080]").text(description); $(".js-view-count[data-work-id=117291080]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 117291080; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='117291080']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); 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} }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="117291079"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/117291079/Novolac_epoxy_resin_from_4_4_dihydroxybenzophenone_Thermal_thermomechanical_interfacial_and_cure_kinetics_with_DGEBA_DICY_blend"><img alt="Research paper thumbnail of Novolac epoxy resin from 4,4′-dihydroxybenzophenone: Thermal, thermomechanical, interfacial, and cure kinetics with DGEBA/DICY blend" class="work-thumbnail" src="https://attachments.academia-assets.com/113186690/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/117291079/Novolac_epoxy_resin_from_4_4_dihydroxybenzophenone_Thermal_thermomechanical_interfacial_and_cure_kinetics_with_DGEBA_DICY_blend">Novolac epoxy resin from 4,4′-dihydroxybenzophenone: Thermal, thermomechanical, interfacial, and cure kinetics with DGEBA/DICY blend</a></div><div class="wp-workCard_item"><span>Journal of Applied Polymer Science</span><span>, Dec 21, 2017</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">A novolac epoxy resin based on 4,4 0-dihydroxybenzophenone (BZPNE) was synthesized via epoxidatio...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">A novolac epoxy resin based on 4,4 0-dihydroxybenzophenone (BZPNE) was synthesized via epoxidation of 4,4 0-dihydroxybenzophenone novolac resin (BZPN). BZPN was obtained by strong mineral acid catalyzed reaction of 4,4 0-dihydroxybenzophenone (BZP) and paraformaldehyde. The formation of BZPNE and BZPN was confirmed by Fourier transform infrared spectroscopy, proton and carbon nuclear magnetic resonance spectroscopy, gel permeation chromatography, and epoxy equivalent weight. Different blends of BZPNE with diglycidyl ether of bisphenol-A (DGEBA; EEW $180) were cured using dicyandiamide were characterized by thermogravimetric analysis, thermomechanical analysis, dynamic mechanical analysis, and interfacial property between aluminum adherends at ambient and elevated temperature. Thermal properties were found to improve on increasing quantity of BZPNE in DGEBA as it is evidenced from glass transition temperature (T g). Likewise, no deterioration in interfacial properties was observed with the highest quantity of BZPNE (30%) in DGEBA blend, when tested at 150 8C. Cure kinetics of compositions were studied by nonisothermal differential scanning calorimetry and Kissinger method was used to compute the kinetic parameters such as frequency factor (A), activation energy (E a) followed by the dependency of rate constant (k) on temperature of different blends. V</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="58454f6ad3deecf236fbec4385e42dba" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":113186690,"asset_id":117291079,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/113186690/download_file?s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="117291079"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="117291079"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 117291079; 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="117291078"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/117291078/Catechol_Amine_Decorated_Epoxy_Resin_as_an_Underwater_Adhesive_A_Coacervate_Concept_Using_a_Liquid_Marble_Strategy"><img alt="Research paper thumbnail of Catechol-Amine-Decorated Epoxy Resin as an Underwater Adhesive: A Coacervate Concept Using a Liquid Marble Strategy" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/117291078/Catechol_Amine_Decorated_Epoxy_Resin_as_an_Underwater_Adhesive_A_Coacervate_Concept_Using_a_Liquid_Marble_Strategy">Catechol-Amine-Decorated Epoxy Resin as an Underwater Adhesive: A Coacervate Concept Using a Liquid Marble Strategy</a></div><div class="wp-workCard_item"><span>ACS Omega</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="117291078"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="117291078"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 117291078; 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</script> <div class="js-work-strip profile--work_container" data-work-id="117291077"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/117291077/Bio_mimicking_hybrid_polymer_architectures_as_adhesion_promoters_for_low_and_high_surface_energy_substrates"><img alt="Research paper thumbnail of Bio-mimicking hybrid polymer architectures as adhesion promoters for low and high surface energy substrates" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/117291077/Bio_mimicking_hybrid_polymer_architectures_as_adhesion_promoters_for_low_and_high_surface_energy_substrates">Bio-mimicking hybrid polymer architectures as adhesion promoters for low and high surface energy substrates</a></div><div class="wp-workCard_item"><span>Journal of Industrial and Engineering Chemistry</span><span>, 2021</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">Abstract Thermoplastic materials like High Density Polyethylene (HDPE) and Polytetrafluoroethylen...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">Abstract Thermoplastic materials like High Density Polyethylene (HDPE) and Polytetrafluoroethylene (PTFE) are promising candidates for specialty industry/aerospace sectors considering their exceptional properties and lower densities. However, the low surface energy leading to poor wetting and reduced adhesion curtails the scope of their wide-spread usage. In this work, we report adhesion promoter primers based on epoxy–catechol with and without fluorinated polymer and investigated their adhesion promotion efficiency on low/high surface energy substrates. The rational design of catechol-fluorine-epoxy hybrid network, mimicking mussel chemistry enabled a non-destructive surface activating approach resulting in profound adhesion promotion. The fluorine containing primer could effectively enhance adhesion between homo and hetero interfaces of Aluminium/HDPE/PTFE owing to the good interface interaction and could outperform common etching methods. A series of molecular level characterizations together with computational and AFM studies provided evidences for the high degree of interaction of the primer between the substrates and epoxy-based adhesives. Bond integrity endurance test using a weight of 10 and 20 kg resulted in ‘no fail’ categorization for the primed substrates during the entire 40 days test duration. The catechol-functionalized primers reported here can be a good overreaching approach to keep non-polar substrates afloat in advanced sectors.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="117291077"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="117291077"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 117291077; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); 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</script> <div class="js-work-strip profile--work_container" data-work-id="117291076"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/117291076/Bioinspired_surface_activators_for_wet_dry_environments_through_greener_epoxy_catechol_amine_chemistry"><img alt="Research paper thumbnail of Bioinspired surface activators for wet/dry environments through greener epoxy-catechol amine chemistry" class="work-thumbnail" src="https://attachments.academia-assets.com/113186689/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/117291076/Bioinspired_surface_activators_for_wet_dry_environments_through_greener_epoxy_catechol_amine_chemistry">Bioinspired surface activators for wet/dry environments through greener epoxy-catechol amine chemistry</a></div><div class="wp-workCard_item"><span>Applied Surface Science</span><span>, 2019</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">This is a PDF file of an article that has undergone enhancements after acceptance, such as the ad...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">This is a PDF file of an article that has undergone enhancements after acceptance, such as the addition of a cover page and metadata, and formatting for readability, but it is not yet the definitive version of record. This version will undergo additional copyediting, typesetting and review before it is published in its final form, but we are providing this version to give early visibility of the article. Please note that, during the production process, errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="cbcbc3819835b67334543b6e9fd1a8ba" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":113186689,"asset_id":117291076,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/113186689/download_file?s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="117291076"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="117291076"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 117291076; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=117291076]").text(description); $(".js-view-count[data-work-id=117291076]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 117291076; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='117291076']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="117291071"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/117291071/Non_isothermal_cure_and_decomposition_kinetics_of_epoxy_imidazole_systems"><img alt="Research paper thumbnail of Non-isothermal cure and decomposition kinetics of epoxy–imidazole systems" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/117291071/Non_isothermal_cure_and_decomposition_kinetics_of_epoxy_imidazole_systems">Non-isothermal cure and decomposition kinetics of epoxy–imidazole systems</a></div><div class="wp-workCard_item"><span>Journal of Thermal Analysis and Calorimetry</span><span>, 2017</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">Non-isothermal curing kinetics of a tetra functional epoxy resin with imidazole-based curing agen...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">Non-isothermal curing kinetics of a tetra functional epoxy resin with imidazole-based curing agents was investigated by differential scanning calorimetry (DSC), and decomposition of the cured compounds was studied by thermogravimetric analysis. N,N,N′,N′-tetraglycidyl-4, 4′diaminodiphenylmethane (TGDDM) was cured with three types of tertiary amine curing agents including 1-methyl imidazole (MI), 2-methyl imidazole (2MI) and 2-ethyl 4-methyl imidazole (EMI). These systems exhibited cure initiation at around 70–90 °C by DSC. 2-methyl imidazole and 2-ethyl 4-methyl imidazole showed two cure initiation profiles, while the 1-substituted counterpart, MI, showed a single cure initiation profile by DSC. The Kissinger equation was applied to calculate the apparent activation energy for epoxy–imidazole cure reactions. The rate constants and the pre-exponential factor were also determined. The activation energy varied from 59 to 65 kJ mol−1 for the systems. The Flynn–Wall–Ozawa iso-conversional approach was used to elucidate the activation energies at different extents of conversion during the cure reactions. The cured systems are found thermally stable up to 250 °C. Decomposition kinetics of cured networks was studied using Kissinger equation and Flynn–Wall–Ozawa iso-conversional approach. The cured resins were analyzed for the glass transition temperature and compared with that of a conventional amine-cured system.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="117291071"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="117291071"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 117291071; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=117291071]").text(description); 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