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"https://www.academia.edu/login?post_login_redirect_url=https%3A%2F%2Fwww.academia.edu%2F11687847%2FApplicability_of_the_Bismuth_Bulk_Rotating_Disk_Electrode_for_heavy_metal_monitoring_in_undisturbed_environmental_and_biological_samples_Determination_of_Zn_II_in_rainwater_tap_water_and_urine%3Fshow_translation%3Dtrue"; window.loswp.previewableAttachments = [{"id":38987440,"identifier":"Attachment_38987440","shouldShowBulkDownload":false}]; window.loswp.shouldDetectTimezone = true; window.loswp.shouldShowBulkDownload = true; window.loswp.showSignupCaptcha = false window.loswp.willEdgeCache = false; window.loswp.work = {"work":{"id":11687847,"created_at":"2015-03-27T10:13:53.009-07:00","from_world_paper_id":null,"updated_at":"2024-11-17T07:38:39.070-08:00","_data":{"grobid_abstract":"The bismuth bulk rotating disk electrode (BiB-RDE) is investigated here as a new and advantageous alternative to determine heavy metal ions in undisturbed environmental and biological samples (pH 7.5) by anodic stripping voltammetry, with demonstrated applicability to the determination of Zn(II) in rainwater, tap water and urine. The proposed method benefits from the insensitiveness of the bismuth bulk electrode to the Bi(III) hydrolysis that affects the common \"in situ\" Bi film approach preventing its use at intermediate to alkaline pH. Instrumental parameters such as the rotation speed, deposition time, frequency, amplitude and step potential were optimized for Zn(II) and Cd(II) stripping signal enhancement. The stripping response is linear in the 20-160 mg L À1 concentration range (for 120 s deposition) with detection limits of 8.09 and 11.5 mg L À1 for Zn(II) and Cd(II), respectively. The accuracy of the results obtained was assessed successfully for Zn(II) determination by voltammetric measurements of surface water and wastewater certified reference materials. Applicability to Zn(II) determination in rainwater, tap water and urine was demonstrated by a good correlation with ICP-MS. Our results open a new application field for stripping voltammetry at bismuth electrodes, for heavy metal determination and speciation in environmental and biological samples.","grobid_abstract_attachment_id":"38987440"},"document_type":"paper","pre_hit_view_count_baseline":null,"quality":"high","language":"en","title":"Applicability of the Bismuth Bulk Rotating Disk Electrode for heavy metal monitoring in undisturbed environmental and biological samples: Determination of Zn(II) in rainwater, tap water and urine","broadcastable":true,"draft":null,"has_indexable_attachment":true,"indexable":true}}["work"]; window.loswp.workCoauthors = [5961249]; window.loswp.locale = "en"; window.loswp.countryCode = "SG"; window.loswp.cwvAbTestBucket = ""; window.loswp.designVariant = "ds_vanilla"; window.loswp.fullPageMobileSutdModalVariant = "full_page_mobile_sutd_modal"; window.loswp.useOptimizedScribd4genScript = false; window.loswp.appleClientId = 'edu.academia.applesignon';</script><script 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Pinilla-Gil" class="ds-work-card--author-avatar" src="https://0.academia-photos.com/5961249/35034448/30548096/s65_eduardo.pinilla-gil.jpg" />Eduardo Pinilla-Gil</a></div><div class="ds-work-card--detail"><div class="ds-work-card--work-metadata"><div class="ds-work-card--work-metadata__stat"><span class="material-symbols-outlined" style="font-size: 20px" translate="no">visibility</span><p class="ds2-5-body-sm" id="work-metadata-view-count">…</p></div><div class="ds-work-card--work-metadata__stat"><span class="material-symbols-outlined" style="font-size: 20px" translate="no">description</span><p class="ds2-5-body-sm">7 pages</p></div><div class="ds-work-card--work-metadata__stat"><span class="material-symbols-outlined" style="font-size: 20px" translate="no">link</span><p class="ds2-5-body-sm">1 file</p></div></div><script>(async () => { const workId = 11687847; const worksViewsPath = "/v0/works/views?subdomain_param=api&work_ids%5B%5D=11687847"; const getWorkViews = async (workId) => { 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class="ds-top-related-works--grid-container"><div class="ds-related-content--container ds-top-related-works--container"><h2 class="ds-related-content--heading">Related papers</h2><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="0" data-entity-id="1941189" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/1941189/_of_bismuth_film_electrodes_for_the_detection_of_trace_metals_by_anodic_stripping_voltammetry_and_their_application_to_the_determination_of_Pb_and_Zn_in_tapwater_and_">… of bismuth-film electrodes for the detection of trace metals by anodic stripping voltammetry and their application to the determination of Pb and Zn in tapwater and …</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="2513497" href="https://independent.academia.edu/CakeJaikaew">Cake Jaikaew</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Talanta, 2003</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"… of bismuth-film electrodes for the detection of trace metals by anodic stripping voltammetry and their application to the determination of Pb and Zn in tapwater and …","attachmentId":28028397,"attachmentType":"pdf","work_url":"https://www.academia.edu/1941189/_of_bismuth_film_electrodes_for_the_detection_of_trace_metals_by_anodic_stripping_voltammetry_and_their_application_to_the_determination_of_Pb_and_Zn_in_tapwater_and_","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/1941189/_of_bismuth_film_electrodes_for_the_detection_of_trace_metals_by_anodic_stripping_voltammetry_and_their_application_to_the_determination_of_Pb_and_Zn_in_tapwater_and_"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="1" data-entity-id="12316792" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/12316792/Performance_of_a_Bismuth_Bulk_Rotating_Disk_Electrode_for_Heavy_Metal_Analysis_Determination_of_Lead_in_Environmental_Samples">Performance of a Bismuth Bulk Rotating Disk Electrode for Heavy Metal Analysis: Determination of Lead in Environmental Samples</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="5961249" href="https://unex.academia.edu/EduardoPinillaGil">Eduardo Pinilla-Gil</a></div><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Performance of a Bismuth Bulk Rotating Disk Electrode for Heavy Metal Analysis: Determination of Lead in Environmental Samples","attachmentId":37593586,"attachmentType":"pdf","work_url":"https://www.academia.edu/12316792/Performance_of_a_Bismuth_Bulk_Rotating_Disk_Electrode_for_Heavy_Metal_Analysis_Determination_of_Lead_in_Environmental_Samples","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/12316792/Performance_of_a_Bismuth_Bulk_Rotating_Disk_Electrode_for_Heavy_Metal_Analysis_Determination_of_Lead_in_Environmental_Samples"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="2" data-entity-id="100166142" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/100166142/Simultaneous_Determination_of_Zn_II_Cd_II_Pb_II_and_Cu_II_Using_Differential_Pulse_Anodic_Stripping_Voltammetry_at_a_Bismuth_Film_Modified_Electrode">Simultaneous Determination of Zn(II), Cd(II), Pb(II), and Cu(II) Using Differential Pulse Anodic Stripping Voltammetry at a Bismuth Film-Modified Electrode</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="123738797" href="https://independent.academia.edu/VanHopN">Nguyen Van Hop</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Advances in Materials Science and Engineering, 2019</p><p class="ds-related-work--abstract ds2-5-body-sm">The simultaneous electrochemical determination of Zn(II), Cd(II), Pb(II), and Cu(II) in the aqueous solution has been developed on the basis of the bismuth film glassy carbon electrode (GCE) using differential pulse anodic stripping voltammetry (DP-ASV). The bismuth film electrode (BiFE) was prepared by adding 500 ppb bismuth(III) directly to the sample solution and simultaneously depositing bismuth and the metal analytes on GCE. The optimal operational parameters, namely, accumulation potential (–1.6 V), accumulation time (110 s), pulsed amplitude (0.07 V), and scan rate (0.021 V·s−1), were found using a Box–Behnken design. Under the optimum conditions, a linear relationship exists between the current and the concentration of Zn(II), Cd(II), Pb(II), and Cu(II) in the range between 5.0 ppb and 110.0 ppb with the detection limits of 1.07 for Zn(II), 0.93 ppb for Cd(II), 0.65 ppb for Pb(II), and 0.94 ppb for Cu(II) calculated on the basis of a signal-to-noise ratio equal to 3 (S/N = 3...</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Simultaneous Determination of Zn(II), Cd(II), Pb(II), and Cu(II) Using Differential Pulse Anodic Stripping Voltammetry at a Bismuth Film-Modified 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href="https://www.academia.edu/4687291/Modification_of_carbon_screen_printed_electrodes_by_adsorption_of_chemically_synthesized_Bi_nanoparticles_for_the_voltammetric_stripping_detection_of_Zn_II_Cd_II_and_Pb_II">Modification of carbon screen-printed electrodes by adsorption of chemically synthesized Bi nanoparticles for the voltammetric stripping detection of Zn(II), Cd(II) and Pb(II</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="5961249" href="https://unex.academia.edu/EduardoPinillaGil">Eduardo Pinilla-Gil</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Talanta, 2009</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Modification of carbon screen-printed electrodes by adsorption of chemically synthesized Bi nanoparticles for the voltammetric stripping detection of Zn(II), Cd(II) and Pb(II","attachmentId":37149113,"attachmentType":"pdf","work_url":"https://www.academia.edu/4687291/Modification_of_carbon_screen_printed_electrodes_by_adsorption_of_chemically_synthesized_Bi_nanoparticles_for_the_voltammetric_stripping_detection_of_Zn_II_Cd_II_and_Pb_II","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/4687291/Modification_of_carbon_screen_printed_electrodes_by_adsorption_of_chemically_synthesized_Bi_nanoparticles_for_the_voltammetric_stripping_detection_of_Zn_II_Cd_II_and_Pb_II"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="5" data-entity-id="28495253" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/28495253/Sequential_injection_anodic_stripping_voltammetry_with_monosegmented_flow_and_in_line_UV_digestion_for_determination_of_Zn_II_Cd_II_Pb_II_and_Cu_II_in_water_samples">Sequential injection anodic stripping voltammetry with monosegmented flow and in-line UV digestion for determination of Zn(II), Cd(II), Pb(II) and Cu(II) in water samples</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="53329870" href="https://independent.academia.edu/JaroonJakmunee">Jaroon Jakmunee</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Talanta, 2011</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Sequential injection anodic stripping voltammetry with monosegmented flow and in-line UV digestion for determination of Zn(II), Cd(II), Pb(II) and Cu(II) in water samples","attachmentId":48843195,"attachmentType":"pdf","work_url":"https://www.academia.edu/28495253/Sequential_injection_anodic_stripping_voltammetry_with_monosegmented_flow_and_in_line_UV_digestion_for_determination_of_Zn_II_Cd_II_Pb_II_and_Cu_II_in_water_samples","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/28495253/Sequential_injection_anodic_stripping_voltammetry_with_monosegmented_flow_and_in_line_UV_digestion_for_determination_of_Zn_II_Cd_II_Pb_II_and_Cu_II_in_water_samples"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="6" data-entity-id="104671924" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/104671924/Voltammetry_Determination_of_Pb_II_Cd_II_and_Zn_II_at_Bismuth_Film_Electrode_Combined_with_8_Hydroxyquinoline_as_a_Complexing_Agent">Voltammetry Determination of Pb(II), Cd(II), and Zn(II) at Bismuth Film Electrode Combined with 8-Hydroxyquinoline as a Complexing Agent</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="123738797" href="https://independent.academia.edu/VanHopN">Nguyen Van Hop</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Journal of Analytical Methods in Chemistry, 2019</p><p class="ds-related-work--abstract ds2-5-body-sm">A novel method was developed for the simultaneous determination of Pb(II), Cd(II), and Zn(II) based on the cathodic stripping response at a bismuth film electrode associated with oxine as a chelating agent. The developed method provided a high and sharp electrochemical response compared with the method without oxine. A linear response of peak currents was observed for Pb(II), Cd(II), and Zn(II) concentration in the range from 2 ppb to 110 ppb. The detection limits of Pb(II), Cd(II), and Zn(II) were 0.45, 0.17, and 0.78 ppb, respectively. This method was successfully applied to the determination of Pb(II), Cd(II), and Zn(II) in lake-water and river-water samples. The metals were detected at the ultratrace level, showing the feasibility of the proposed method for environmental applications.</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Voltammetry Determination of Pb(II), Cd(II), and Zn(II) at Bismuth Film Electrode Combined with 8-Hydroxyquinoline as a Complexing Agent","attachmentId":104338012,"attachmentType":"pdf","work_url":"https://www.academia.edu/104671924/Voltammetry_Determination_of_Pb_II_Cd_II_and_Zn_II_at_Bismuth_Film_Electrode_Combined_with_8_Hydroxyquinoline_as_a_Complexing_Agent","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/104671924/Voltammetry_Determination_of_Pb_II_Cd_II_and_Zn_II_at_Bismuth_Film_Electrode_Combined_with_8_Hydroxyquinoline_as_a_Complexing_Agent"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="7" data-entity-id="11708582" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/11708582/A_novel_cell_design_for_the_improved_stripping_voltammetric_detection_of_Zn_II_Cd_II_and_Pb_II_on_commercial_screen_printed_strips_by_bismuth_codeposition_in_stirred_solutions">A novel cell design for the improved stripping voltammetric detection of Zn(II), Cd(II) and Pb(II) on commercial screen printed strips by bismuth codeposition in stirred solutions</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="5961249" href="https://unex.academia.edu/EduardoPinillaGil">Eduardo Pinilla-Gil</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Electroanalysis, 2008</p><p class="ds-related-work--abstract ds2-5-body-sm">A novel electrochemical cell design is proposed to allow fast, reproducible and highly efficient convective transport of dissolved substances to screen-printed electrochemical three-electrode strips mounted on miniaturized plastic vessels, with the goal of improving detection limits in disposable electrochemical stripping field sensors. The experimental configuration has been tested for accumulation of the selected heavy metals ions Zn(II), Cd(II), and Pb(II), codeposited with bismuth ions on a carbon disk screen-printed working electrode before detection by square wave anodic stripping voltammetry. Chemical and instrumental variables of the proposed device and associate electrochemical method were optimized. Selected parameters gave detection limits in the low ng mL−1 range with moderate deposition time (120 s). Practical applicability was tested on certified water and real samples (tap water and waste water), with acceptable results, suggesting potential usefulness for field environmental monitoring of heavy metals.</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"A novel cell design for the improved stripping voltammetric detection of Zn(II), Cd(II) and Pb(II) on commercial screen printed strips by bismuth codeposition in stirred solutions","attachmentId":37148910,"attachmentType":"pdf","work_url":"https://www.academia.edu/11708582/A_novel_cell_design_for_the_improved_stripping_voltammetric_detection_of_Zn_II_Cd_II_and_Pb_II_on_commercial_screen_printed_strips_by_bismuth_codeposition_in_stirred_solutions","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/11708582/A_novel_cell_design_for_the_improved_stripping_voltammetric_detection_of_Zn_II_Cd_II_and_Pb_II_on_commercial_screen_printed_strips_by_bismuth_codeposition_in_stirred_solutions"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="8" data-entity-id="30210440" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/30210440/Determination_of_trace_heavy_Metals_by_Sequential_Injection_Anodic_Stripping_Voltammetry_Using_Bismuth_Film_Screen_printed_Printed_Carbon_Electrode">Determination of trace heavy Metals by Sequential Injection-Anodic Stripping Voltammetry Using Bismuth Film Screen-printed Printed Carbon Electrode</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="48222444" href="https://independent.academia.edu/ShojiMotomizu">Shoji Motomizu</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Analytical Sciences, 2008</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Determination of trace heavy Metals by Sequential Injection-Anodic Stripping Voltammetry Using Bismuth Film Screen-printed Printed Carbon Electrode","attachmentId":50669396,"attachmentType":"pdf","work_url":"https://www.academia.edu/30210440/Determination_of_trace_heavy_Metals_by_Sequential_Injection_Anodic_Stripping_Voltammetry_Using_Bismuth_Film_Screen_printed_Printed_Carbon_Electrode","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/30210440/Determination_of_trace_heavy_Metals_by_Sequential_Injection_Anodic_Stripping_Voltammetry_Using_Bismuth_Film_Screen_printed_Printed_Carbon_Electrode"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="9" data-entity-id="47707893" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/47707893/Determination_of_Dissolved_Zn_II_and_Cd_II_in_Estuarine_Water_by_Using_a_Bismuth_Film_Microelectrode">Determination of Dissolved Zn(II) and Cd(II) in Estuarine Water by Using a Bismuth Film Microelectrode</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="111555743" href="https://usp-br1.academia.edu/MauroBertotti">Mauro Bertotti</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Electroanalysis, 2011</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Determination of Dissolved Zn(II) and Cd(II) in Estuarine Water by Using a Bismuth Film Microelectrode","attachmentId":66661852,"attachmentType":"pdf","work_url":"https://www.academia.edu/47707893/Determination_of_Dissolved_Zn_II_and_Cd_II_in_Estuarine_Water_by_Using_a_Bismuth_Film_Microelectrode","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/47707893/Determination_of_Dissolved_Zn_II_and_Cd_II_in_Estuarine_Water_by_Using_a_Bismuth_Film_Microelectrode"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div></div></div><div class="ds-sticky-ctas--wrapper js-loswp-sticky-ctas hidden"><div class="ds-sticky-ctas--grid-container"><div class="ds-sticky-ctas--container"><button class="ds2-5-button 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class="ds-related-work--container js-related-work-sidebar-card" data-collection-position="2" data-entity-id="87792373" data-sort-order="default"><a class="ds-related-work--title js-related-work-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/87792373/A_Simple_Fast_and_Inexpensive_Simultaneous_Determination_of_Trace_Bismuth_III_and_Lead_II_in_Water_Samples_by_Adsorptive_Stripping_Voltammetry">A Simple, Fast, and Inexpensive Simultaneous Determination of Trace Bismuth(III) and Lead(II) in Water Samples by Adsorptive Stripping Voltammetry</a><div class="ds-related-work--metadata"><a class="js-related-work-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="36968971" href="https://independent.academia.edu/MGrabarczyk">Malgorzata Grabarczyk</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Journal of Analytical Methods in Chemistry, 2017</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline 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PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-related-work-sidebar-card" data-collection-position="3" data-entity-id="29732267" data-sort-order="default"><a class="ds-related-work--title js-related-work-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/29732267/Square_wave_anodic_stripping_voltammetry_determination_of_eco_toxic_metals_in_samples_of_biological_and_environmental_importance">Square wave anodic stripping voltammetry determination of eco-toxic metals in samples of biological and environmental importance</a><div class="ds-related-work--metadata"><a class="js-related-work-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="56321806" href="https://independent.academia.edu/StellaThGirousi">Stella Th. Girousi</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Central European Journal of Chemistry, 2010</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{"location":"wsj-grid-card-download-pdf-modal","work_title":"Square wave anodic stripping voltammetry determination of eco-toxic metals in samples of biological and environmental importance","attachmentId":50187942,"attachmentType":"pdf","work_url":"https://www.academia.edu/29732267/Square_wave_anodic_stripping_voltammetry_determination_of_eco_toxic_metals_in_samples_of_biological_and_environmental_importance","alternativeTracking":true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-related-work-grid-card-view-pdf" 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