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(PDF) The Distribution and Timing of Molybdenite Mineralization at the El Teniente Cu-Mo Porphyry Deposit, Chile | Jose Seguel - Academia.edu

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[{"id":76440587,"identifier":"Attachment_76440587","shouldShowBulkDownload":false}]; window.loswp.shouldDetectTimezone = true; window.loswp.shouldShowBulkDownload = true; window.loswp.showSignupCaptcha = false window.loswp.willEdgeCache = false; window.loswp.work = {"work":{"id":64376450,"created_at":"2021-12-15T14:52:00.762-08:00","from_world_paper_id":187237238,"updated_at":"2024-11-23T08:26:46.719-08:00","_data":{"publisher":"Society of Economic Geologists","grobid_abstract":"The El Teniente Cu-Mo porphyry deposit, Chile, is one of the world's largest and most complex porphyry ore systems, containing an estimated premining resource of approximately 95 Mt Cu and 2.5 Mt Mo. Although Cu mineralization at the deposit is quite well studied, little work has focused specifically on the distribution and timing of Mo mineralization. Combined grade, vein, and breccia distribution analysis reveals that depositwide Mo grades of 0.01 to 0.06 wt % are strongly controlled by the abundance of main mineralization (type 6a) quartz ± molybdenite veins. These show a clear spatial relationship with several felsic-intermediate intrusions and appear to develop outward and upward into Cu-rich (type 6b-7b) quartz-chalcopyrite veins and (type 8) chalcopyrite-anhydrite ± bornite veins with sericitic alteration halos. High-precision Re-Os molybdenite dating reveals that these linked vein types did not develop in a single, deposit-wide evolution, but are diachronous, related to distinct episodes of hydrothermal activity associated with the emplacement of diorite finger porphyries and the composite Teniente Dacite Porphyry. These units acted as effective, short-lived (\u003c100,000 years) conduits for pulses of Mo-and Cu-bearing hydrothermal fluids between 6.3 and 4.6 Ma. The rapid thermal contraction of each system during mineralization led to extensive overprinting of Mo-rich veins by their lowertemperature, Cu-rich equivalents. Separate pulses in magmatic-hydrothermal activity are separated by distinct gaps of up to 300,000 years, during which Mo-mineralizing activity appears to have gone into quiescence. Mo grades exceeding 0.06 wt % correspond to the presence of molybdenite-bearing, late mineralizationstage, tourmaline-cemented (type 9), and anhydrite-carbonate ± gypsum (type 10) veins and breccias. These are abundant at shallow mine levels and show a close spatial relationship with a series of concentric faults associated with the Braden Breccia Pipe. Mineralization in this paragenetic stage is relatively short-lived and occurs in all parts of the deposit between 4.80 and 4.58 Ma. The generally Cu poor nature of the late mineralization stage is attributed to the prior preferential extraction of Cu from the underlying magma chamber in earlier mineralizing events. This led to the late exsolution of oxidized, Mo-rich fluids that may have undergone further enrichment by remobilizing Mo from main mineralization-type veins associated with the Teniente Dacite Porphyry. The formation of the Braden Breccia Pipe is likely to have occurred in a single cataclysmic event at approximately 4.58 Ma, which cut the Mo-rich tourmaline breccias and created a distinct Mo-rich grade halo at shallow mine levels. With the exception of minor mineralization associated with small dacitic dikes at approximately 4.42 Ma, the Braden event marked the termination of Mo deposition.","publication_date":"2015,1,23","publication_name":"Economic Geology","grobid_abstract_attachment_id":"76440587"},"document_type":"paper","pre_hit_view_count_baseline":null,"quality":"high","language":"en","title":"The Distribution and Timing of Molybdenite Mineralization at the El Teniente Cu-Mo Porphyry Deposit, Chile","broadcastable":true,"draft":null,"has_indexable_attachment":true,"indexable":true}}["work"]; window.loswp.workCoauthors = [4655155]; window.loswp.locale = "en"; window.loswp.countryCode = "SG"; window.loswp.cwvAbTestBucket = ""; window.loswp.designVariant = "ds_vanilla"; window.loswp.fullPageMobileSutdModalVariant = "full_page_mobile_sutd_modal"; window.loswp.useOptimizedScribd4genScript = false; window.loswp.appleClientId = 'edu.academia.applesignon';</script><script defer="" 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data-collection-position="5" data-entity-id="59974453" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/59974453/maydagan_2015_Porphyry_to_Epithermal_Transition_in_the_Altar_Cu_Au_Mo_Deposit_Argentina_Studied_by_Cathodoluminescence_LA_ICP_MS_and_Fluid_Inclusion_Analysis">maydagan 2015- Porphyry to Epithermal Transition in the Altar Cu-(Au-Mo) Deposit, Argentina, Studied by Cathodoluminescence, LA-ICP-MS, and Fluid Inclusion Analysis</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="113523103" href="https://uncoma.academia.edu/pablonavarro">pablo navarro</a></div><p class="ds-related-work--abstract ds2-5-body-sm">The middle to late Miocene Altar porphyry Cu-(Au-Mo) deposit, located in the Andean Main Cordillera of San Juan Province (Argentina), is characterized by the superposition of multiple vein generations consisting of both porphyry-type and high sulfidation epithermal-style alteration and mineralization. We constrain the physical and chemical evolution of the hydrothermal fluids that formed this deposit based on description and distribution of vein types, scanning electron microscopy, cathodoluminescence (CL) imaging, trace elements in quartz veins, and fluid inclusion microthermometry. Quartz CL textures and trace elements (chiefly Li, Al, Ti, and Ge) differentiate among quartz generations precipitated during different mineralization and alteration events. Early quartz ± chalcopyrite ± pyrite veins and quartz ± molybdenite veins (A and B veins) show considerable complexity and were commonly reopened, and some underwent quartz dissolution. Early quartz ± chalcopyrite ± pyrite veins (A veins) are dominated by equigranular bright CL quartz with homogeneous texture. Most of these veins contain higher Ti concentrations than any other vein type (average: 100 ppm) and have low to intermediate Al concentrations (65-448 ppm). Quartz ± molybdenite (B veins) and chlorite + rutile ± hematite (C veins) veins contain quartz of intermediate CL intensity that commonly shows growth zones with oscillatory CL intensity. Quartz from these veins has intermediate Ti concentrations (~20 ppm) and Al concentrations similar to those of A veins. Quartz from later quartz + pyrite veins with quartz + muscovite ± tourmaline halos (D veins) has significantly lower CL intensity, low Ti (&lt;15 ppm) and elevated Al concentrations (up to 1,000 ppm), and typically contains euhedral growth zones. Late veins rich in sulfides and sulfosalts show CL textures typical of epithermal deposits (dark CL quartz, crustiform banding, and euhedral growth zones). Quartz from these veins typically contains less than 5 ppm Ti, and Al, Li, and Ge concentrations are elevated relative to other vein types. Based on experimentally established relationships between Ti concentration in quartz and temperature, the decrease in Ti content in successively later quartz generations indicates that the temperature of the hydrothermal fluids decreased through time during the evolution of the system. Vein formation at Altar occurred at progressively lower pressure, shallower paleodepth, and lower temperature. Under lithostatic pressures, the magma supplied low-salinity aqueous fluids at depths of ~6 to 6.8 km (pressures of 1.6-1.8 kbar) and temperatures of 670° to 730°C (first quartz generation of early quartz ± chalcopyrite ± pyrite veins). This parental fluid episodically depressurized and cooled at temperatures and pressures below the brine-vapor solvus. Quartz ± molybdenite veins precipitated from fluids at temperatures of 510° to 540°C and pressures of 800 to 1,000 bars, corresponding to depths of 3 to 3.7 km under lithostatic pressures. Further cooling of hydrothermal fluids to temperatures between 425° and 370°C under hydrostatic pressures of 200 to 350 bars produced pyrite-quartz veins and pervasive quartz + muscovite ± tourmaline and illite alteration that overprinted the early hydrothermal assemblages. Late veins rich in sulfides and sulfosalts that overlapped the deep and intermediate high-temperature veins formed from fluids at temperatures of 250° to 280°C and pressures of 20 to 150 bars. The epithermal siliceous ledges formed from low-temperature fluids (&lt;230°C) at hydrostatic pressures of &lt;100 bars corresponding to depths of &lt;&lt;1 km.</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;maydagan 2015- Porphyry to Epithermal Transition in the Altar Cu-(Au-Mo) Deposit, Argentina, Studied by Cathodoluminescence, LA-ICP-MS, and Fluid Inclusion Analysis&quot;,&quot;attachmentId&quot;:73627239,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/59974453/maydagan_2015_Porphyry_to_Epithermal_Transition_in_the_Altar_Cu_Au_Mo_Deposit_Argentina_Studied_by_Cathodoluminescence_LA_ICP_MS_and_Fluid_Inclusion_Analysis&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/59974453/maydagan_2015_Porphyry_to_Epithermal_Transition_in_the_Altar_Cu_Au_Mo_Deposit_Argentina_Studied_by_Cathodoluminescence_LA_ICP_MS_and_Fluid_Inclusion_Analysis"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="6" data-entity-id="9593759" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/9593759/Evolution_of_the_Breccia_Hosted_Porphyry_Cu_Mo_Au_Deposit_at_Agua_Rica_Argentina_Progressive_Unroofing_of_a_Magmatic_Hydrothermal_System">Evolution of the Breccia-Hosted Porphyry Cu-Mo-Au Deposit at Agua Rica, Argentina: Progressive Unroofing of a Magmatic Hydrothermal System</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="3251128" href="https://independent.academia.edu/LucasV%C3%A1squez">Lucas Vásquez</a></div><p class="ds-related-work--abstract ds2-5-body-sm">Detailed geologic mapping has been used to show that Agua Rica is a porphyry-style Cu-Mo-Au deposit that was first overprinted by polystage brecciation associated with a high sulfidation epithermal event and then by a barren surface-venting phreatomagmatic diatreme, prior to a final stage of supergene enrichment. It was emplaced in the Miocene (~8–5 Ma) as an outlier of the Farallón Negro Volcanic Complex in northwestern Argentina. The Agua Rica deposit lies next to the contact between Precambrian or lower Paleozoic metasedimentary rocks and coarse-grained Ordovician granites. In a first pulse of Miocene magmatism, equigranular to porphyritic intrusions were emplaced, with minor potassic alteration and weak Cu-Mo mineralization. Subsequent intrusion of feldspar porphyries was associated with intense porphyry-style stockwork veining, potassic and propylitic alteration, and disseminated Cu-Mo-Au mineralization (molybdenite, chalcopyrite ± bornite ± pyrite). The present alteration and mineralization pattern is dominated by an almost pervasive overprint of high sulfidation epithermal assemblages (phyllic and advanced argillic alteration and Cu-Au-Ag-As-Pb-Zn mineralization) in breccia cements and as void fillings. Covellite is the dominant copper mineral in the ore and seems to have partly or completely replaced chalcopyrite and bornite of the earlier porphyry events. The high sulfidation epithermal assemblages are closely related to the emplacement of a largely clast-supported hydrothermal breccia. Three major bodies of this breccia have been mapped on the basis of clast lithology, clast shape and size, degree of alteration, and composition of breccia matrix. Igneous breccia with a fine-grained porphyritic matrix is intimately associated and interfingers with the base of the hydrothermal breccia columns. A final phase of magmatic hydrothermal activity formed a matrix-supported and commonly bedded crater infill breccia. It formed by a surface-venting phreatomagmatic eruption, as shown by a continuous downward transition from bedded breccias to clast-supported breccias with sandy or pumiceous matrix to a solid igneous breccia with a fine-grained porphyritic matrix in the lower core of the conical crater infill breccia body. Graded, matrix-rich epiclastic sediments subsequently filled the crater. Magmatic activity was terminated by a dike of unmineralized biotite porphyry, which intruded the crater infill breccia. Talus breccia was shed into the crater from the rim. Supergene leaching and enrichment, which replaced covellite, pyrite, chalcopyrite, and bornite by chalcocite and secondary covellite, formed an enrichment blanket that was dissected by the present-day, steeply incised topography. The distinctive feature of the Agua Rica hydrothermal system is the occurrence of early, weakly mineralized intrusions, later feldspar porphyries with stockwork-hosted chalcopyrite-bornite-molybdenite mineralization, hydrothermal breccias with an epithermal pyrite-covellite overprint, and barren surface-venting breccias—all exposed at one location within 1,000 m of vertical exposure. Reconstruction of the time sequence of these geologic elements indicates that Agua Rica is the result of a protracted history of magmatic hydrothermal activity with superposition of several intrusion events that probably extended over several million years during progressive regional uplift, erosion, and explosive unroofing.</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Evolution of the Breccia-Hosted Porphyry Cu-Mo-Au Deposit at Agua Rica, Argentina: Progressive Unroofing of a Magmatic Hydrothermal System&quot;,&quot;attachmentId&quot;:35803753,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/9593759/Evolution_of_the_Breccia_Hosted_Porphyry_Cu_Mo_Au_Deposit_at_Agua_Rica_Argentina_Progressive_Unroofing_of_a_Magmatic_Hydrothermal_System&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/9593759/Evolution_of_the_Breccia_Hosted_Porphyry_Cu_Mo_Au_Deposit_at_Agua_Rica_Argentina_Progressive_Unroofing_of_a_Magmatic_Hydrothermal_System"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="7" data-entity-id="86496659" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/86496659/Timing_of_porphyry_Cu_Mo_and_base_metal_Zn_Pb_Ag_Cu_mineralisation_in_a_magmatic_hydrothermal_system_Morococha_district_Peru">Timing of porphyry (Cu-Mo) and base metal (Zn-Pb-Ag-Cu) mineralisation in a magmatic-hydrothermal system—Morococha district, Peru</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="33754147" href="https://independent.academia.edu/KKouzmanov">K. Kouzmanov</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Mineralium Deposita, 2015</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Timing of porphyry (Cu-Mo) and base metal (Zn-Pb-Ag-Cu) mineralisation in a magmatic-hydrothermal system—Morococha district, Peru&quot;,&quot;attachmentId&quot;:90935899,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/86496659/Timing_of_porphyry_Cu_Mo_and_base_metal_Zn_Pb_Ag_Cu_mineralisation_in_a_magmatic_hydrothermal_system_Morococha_district_Peru&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline 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data-author-id="68752763" href="https://independent.academia.edu/JDilles">John Dilles</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Economic Geology, 2008</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Fluid Inclusion Evidence for Magmatic-Hydrothermal Fluid Evolution in the Porphyry Copper-Molybdenum Deposit at Butte, Montana&quot;,&quot;attachmentId&quot;:90743161,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/86246508/Fluid_Inclusion_Evidence_for_Magmatic_Hydrothermal_Fluid_Evolution_in_the_Porphyry_Copper_Molybdenum_Deposit_at_Butte_Montana&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free 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href="https://unibe-ch2.academia.edu/ThomasPettke">Thomas Pettke</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Mineralium Deposita, 2008</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Fluid and source magma evolution of the Questa porphyry Mo deposit, New Mexico, USA&quot;,&quot;attachmentId&quot;:51030856,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/30589609/Fluid_and_source_magma_evolution_of_the_Questa_porphyry_Mo_deposit_New_Mexico_USA&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" 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You can download the paper by clicking the button above.</p></div></div></div></div><div class="ds-sidebar--container js-work-sidebar"><div class="ds-related-content--container"><h2 class="ds-related-content--heading">Related papers</h2><div class="ds-related-work--container js-related-work-sidebar-card" data-collection-position="0" data-entity-id="99302075" data-sort-order="default"><a class="ds-related-work--title js-related-work-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/99302075/Geologic_exploration_of_a_molybdenum_rich_porphyry_copper_deposit_at_Mocoa_Colombia">Geologic exploration of a molybdenum-rich porphyry copper deposit at Mocoa, Colombia</a><div class="ds-related-work--metadata"><a class="js-related-work-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="263801522" href="https://independent.academia.edu/LuisJaramillo215">Luis Jaramillo</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Economic Geology, 1984</p><div 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href="https://www.academia.edu/28318427/Early_Halo_Type_Porphyry_and_Breccia_Cu_Mo_Mineralization_at_Copper_Creek_Pinal_County_Arizona"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-related-work-sidebar-card" data-collection-position="4" data-entity-id="3283042" data-sort-order="default"><a class="ds-related-work--title js-related-work-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/3283042/The_El_Teniente_porphyry_Cu_Mo_deposit_from_a_hydrothermal_rutile_perspective">The El Teniente porphyry Cu–Mo deposit from a hydrothermal rutile perspective</a><div class="ds-related-work--metadata"><a class="js-related-work-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="3782827" href="https://udec-cl.academia.edu/OsvaldoRabbia">Osvaldo Rabbia</a><span>, </span><a 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Constraints from Re–Os molybdenite dating</a><div class="ds-related-work--metadata"><a class="js-related-work-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="53855074" href="https://independent.academia.edu/EPerezDominguez">Eduardo Perez Dominguez</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Mineralium Deposita, 2008</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Late Carboniferous porphyry copper mineralization at La Voluntad, Neuquén, Argentina: Constraints from Re–Os molybdenite 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data-collection-position="9" data-entity-id="102674929" data-sort-order="default"><a class="ds-related-work--title js-related-work-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/102674929/Breccia_hosted_copper_molybdenum_mineralisation_at_Rio_Blanco_Chile">Breccia-hosted copper-molybdenum mineralisation at Rio Blanco, Chile</a><div class="ds-related-work--metadata"><a class="js-related-work-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="217501551" href="https://independent.academia.edu/PeterFrikken">Peter Frikken</a></div><p class="ds-related-work--metadata ds2-5-body-xs">2003</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Breccia-hosted copper-molybdenum mineralisation at Rio Blanco, 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