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E. Ebenso | University of South Africa - Academia.edu

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Ebenso" border="0" onerror="if (this.src != &#39;//a.academia-assets.com/images/s200_no_pic.png&#39;) this.src = &#39;//a.academia-assets.com/images/s200_no_pic.png&#39;;" width="200" height="200" src="https://0.academia-photos.com/43244766/11577472/33847120/s200_e..ebenso.jpg" /></div><div class="title-container"><h1 class="ds2-5-heading-sans-serif-sm">E. Ebenso</h1><div class="affiliations-container fake-truncate js-profile-affiliations"><div><a class="u-tcGrayDarker" href="https://unisouthafr.academia.edu/">University of South Africa</a>, <a class="u-tcGrayDarker" href="https://unisouthafr.academia.edu/Departments/Chemistry/Documents">Chemistry</a>, <span class="u-tcGrayDarker">Faculty Member</span></div><div><a class="u-tcGrayDarker" href="https://kingstu.academia.edu/">North West University Mafikeng Campus</a>, <a class="u-tcGrayDarker" href="https://kingstu.academia.edu/Departments/Chemistry/Documents">Chemistry</a>, <span class="u-tcGrayDarker">Faculty Member</span></div></div></div></div><div class="sidebar-cta-container"><button class="ds2-5-button hidden profile-cta-button grow js-profile-follow-button" data-broccoli-component="user-info.follow-button" data-click-track="profile-user-info-follow-button" data-follow-user-fname="E." data-follow-user-id="43244766" data-follow-user-source="profile_button" 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data-rails-context="{&quot;inMailer&quot;:false,&quot;i18nLocale&quot;:&quot;en&quot;,&quot;i18nDefaultLocale&quot;:&quot;en&quot;,&quot;href&quot;:&quot;https://unisouthafr.academia.edu/EEbenso&quot;,&quot;location&quot;:&quot;/EEbenso&quot;,&quot;scheme&quot;:&quot;https&quot;,&quot;host&quot;:&quot;unisouthafr.academia.edu&quot;,&quot;port&quot;:null,&quot;pathname&quot;:&quot;/EEbenso&quot;,&quot;search&quot;:null,&quot;httpAcceptLanguage&quot;:null,&quot;serverSide&quot;:false}"></div> <div class="js-react-on-rails-component" style="display:none" data-component-name="Pill" data-props="{&quot;color&quot;:&quot;gray&quot;,&quot;children&quot;:[&quot;Polymer Blends&quot;]}" data-trace="false" data-dom-id="Pill-react-component-72688f40-5505-4fac-935d-4d3867bcc902"></div> <div id="Pill-react-component-72688f40-5505-4fac-935d-4d3867bcc902"></div> </a><a data-click-track="profile-user-info-expand-research-interests" data-has-card-for-ri-list="43244766" href="https://www.academia.edu/Documents/in/Polymer_synthesis"><div class="js-react-on-rails-component" style="display:none" data-component-name="Pill" data-props="{&quot;color&quot;:&quot;gray&quot;,&quot;children&quot;:[&quot;Polymer synthesis&quot;]}" data-trace="false" data-dom-id="Pill-react-component-56971bc7-73fe-4d7b-b4a5-fd36344e1d2d"></div> <div id="Pill-react-component-56971bc7-73fe-4d7b-b4a5-fd36344e1d2d"></div> </a><a data-click-track="profile-user-info-expand-research-interests" data-has-card-for-ri-list="43244766" href="https://www.academia.edu/Documents/in/Organic_coatings"><div class="js-react-on-rails-component" style="display:none" data-component-name="Pill" data-props="{&quot;color&quot;:&quot;gray&quot;,&quot;children&quot;:[&quot;Organic coatings&quot;]}" data-trace="false" data-dom-id="Pill-react-component-5d6c3e71-1aa7-4368-8e1a-9c0e1f787be8"></div> <div id="Pill-react-component-5d6c3e71-1aa7-4368-8e1a-9c0e1f787be8"></div> </a><a 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id="Pill-react-component-d54ae075-49fd-4f43-88b0-8e75e1c3a318"></div> </a></div></div></div></div><div class="right-panel-container"><div class="user-content-wrapper"><div class="uploads-container" id="social-redesign-work-container"><div class="upload-header"><h2 class="ds2-5-heading-sans-serif-xs">Uploads</h2></div><div class="documents-container backbone-social-profile-documents" style="width: 100%;"><div class="u-taCenter"></div><div class="profile--tab_content_container js-tab-pane tab-pane active" id="all"><div class="profile--tab_heading_container js-section-heading" data-section="Papers" id="Papers"><h3 class="profile--tab_heading_container">Papers by E. Ebenso</h3></div><div class="js-work-strip profile--work_container" data-work-id="91359245"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/91359245/Green_Approaches_to_Corrosion_Mitigation"><img alt="Research paper thumbnail of Green Approaches to Corrosion Mitigation" class="work-thumbnail" src="https://attachments.academia-assets.com/94669208/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/91359245/Green_Approaches_to_Corrosion_Mitigation">Green Approaches to Corrosion Mitigation</a></div><div class="wp-workCard_item"><span>International Journal of Corrosion</span><span>, 2012</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="f1bcccd9e613f7d130d070d8bc0d128a" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{&quot;attachment_id&quot;:94669208,&quot;asset_id&quot;:91359245,&quot;asset_type&quot;:&quot;Work&quot;,&quot;button_location&quot;:&quot;profile&quot;}" href="https://www.academia.edu/attachments/94669208/download_file?st=MTczMzI2NTEzOSw4LjIyMi4yMDguMTQ2&s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="91359245"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="91359245"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 91359245; 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="89751026"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/89751026/Titanium_IV_oxide_as_corrosion_inhibitor_for_aluminium_and_mild_steel_in_acidic_medium"><img alt="Research paper thumbnail of Titanium (IV) oxide as corrosion inhibitor for aluminium and mild steel in acidic medium" class="work-thumbnail" src="https://attachments.academia-assets.com/93506284/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/89751026/Titanium_IV_oxide_as_corrosion_inhibitor_for_aluminium_and_mild_steel_in_acidic_medium">Titanium (IV) oxide as corrosion inhibitor for aluminium and mild steel in acidic medium</a></div><div class="wp-workCard_item"><span>International Journal of Electrochemical Science</span><span>, 2010</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="b77188dd2128d4ddd99b363a967e484b" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{&quot;attachment_id&quot;:93506284,&quot;asset_id&quot;:89751026,&quot;asset_type&quot;:&quot;Work&quot;,&quot;button_location&quot;:&quot;profile&quot;}" href="https://www.academia.edu/attachments/93506284/download_file?st=MTczMzI2NTEzOSw4LjIyMi4yMDguMTQ2&s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="89751026"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="89751026"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 89751026; 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The percentage inhibition efficiencies (%IE) increased with concentration of TO and decrease with increasing temperature in the order: 59.62 % MS \u003c 73.34 % Al. The activation energy, E a of aluminium (Al) and mild steel (MS) corrosion increased with increasing concentration. The experimental results fit the Langmuir adsorption isotherm. Physisorption mechanism has been proposed for the inhibitor based on the E a values (E a ≈ 9.82 kJmol-1 for Al and E a ≈7.18 kJmol-1 for MS). The negative values of heat of adsorption, Q ads obtained in this study implies that the adsorption of TO molecules on the Al and MS surfaces is spontaneous.","publication_date":{"day":null,"month":null,"year":2010,"errors":{}},"publication_name":"International Journal of Electrochemical Science","grobid_abstract_attachment_id":93506284},"translated_abstract":null,"internal_url":"https://www.academia.edu/89751026/Titanium_IV_oxide_as_corrosion_inhibitor_for_aluminium_and_mild_steel_in_acidic_medium","translated_internal_url":"","created_at":"2022-11-01T22:18:45.886-07:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":43244766,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[{"id":93506284,"title":"","file_type":"pdf","scribd_thumbnail_url":"https://attachments.academia-assets.com/93506284/thumbnails/1.jpg","file_name":"5111563.pdf","download_url":"https://www.academia.edu/attachments/93506284/download_file?st=MTczMzI2NTEzOSw4LjIyMi4yMDguMTQ2&","bulk_download_file_name":"Titanium_IV_oxide_as_corrosion_inhibitor.pdf","bulk_download_url":"https://d1wqtxts1xzle7.cloudfront.net/93506284/5111563-libre.pdf?1667366673=\u0026response-content-disposition=attachment%3B+filename%3DTitanium_IV_oxide_as_corrosion_inhibitor.pdf\u0026Expires=1733268739\u0026Signature=AqAJkd3zpdhMxF6LGy68Y0QxmekzFnFyxMRUV~ddjYT7j56D25s29vQpvA0Jfdg5lGEvhyzRLhZ5SckPePgJ7sTo0h8-qIRhDYizgBLMwt~LgjYIRyFWHQBYabDcAyh4cWOy995q8AAM0jZ5tiPuh5LdU3XClhHHuoN7QKxH58YiP1PGKvieGoSt6NKrn-mVg0SmHVz1sDhAm7HItsfcOfbIENI3pIbMpyzDKkvroEaJQBm~W7t1Hhi1sHgVIfoX4STdL-raZgdrb0Irf5ANcKXBGPkINfrkTPcief6c5~d3tT7hk9bb1zyikemsB3MPyzQ5Ucuvnc0kcevryQD0iQ__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA"}],"slug":"Titanium_IV_oxide_as_corrosion_inhibitor_for_aluminium_and_mild_steel_in_acidic_medium","translated_slug":"","page_count":11,"language":"en","content_type":"Work","owner":{"id":43244766,"first_name":"E.","middle_initials":null,"last_name":"Ebenso","page_name":"EEbenso","domain_name":"unisouthafr","created_at":"2016-02-15T02:34:01.575-08:00","display_name":"E. Ebenso","url":"https://unisouthafr.academia.edu/EEbenso"},"attachments":[{"id":93506284,"title":"","file_type":"pdf","scribd_thumbnail_url":"https://attachments.academia-assets.com/93506284/thumbnails/1.jpg","file_name":"5111563.pdf","download_url":"https://www.academia.edu/attachments/93506284/download_file?st=MTczMzI2NTEzOSw4LjIyMi4yMDguMTQ2&","bulk_download_file_name":"Titanium_IV_oxide_as_corrosion_inhibitor.pdf","bulk_download_url":"https://d1wqtxts1xzle7.cloudfront.net/93506284/5111563-libre.pdf?1667366673=\u0026response-content-disposition=attachment%3B+filename%3DTitanium_IV_oxide_as_corrosion_inhibitor.pdf\u0026Expires=1733268739\u0026Signature=AqAJkd3zpdhMxF6LGy68Y0QxmekzFnFyxMRUV~ddjYT7j56D25s29vQpvA0Jfdg5lGEvhyzRLhZ5SckPePgJ7sTo0h8-qIRhDYizgBLMwt~LgjYIRyFWHQBYabDcAyh4cWOy995q8AAM0jZ5tiPuh5LdU3XClhHHuoN7QKxH58YiP1PGKvieGoSt6NKrn-mVg0SmHVz1sDhAm7HItsfcOfbIENI3pIbMpyzDKkvroEaJQBm~W7t1Hhi1sHgVIfoX4STdL-raZgdrb0Irf5ANcKXBGPkINfrkTPcief6c5~d3tT7hk9bb1zyikemsB3MPyzQ5Ucuvnc0kcevryQD0iQ__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA"}],"research_interests":[{"id":369525,"name":"Aluminium","url":"https://www.academia.edu/Documents/in/Aluminium"},{"id":566295,"name":"Physisorption","url":"https://www.academia.edu/Documents/in/Physisorption"},{"id":803172,"name":"Mild Steel","url":"https://www.academia.edu/Documents/in/Mild_Steel"},{"id":1508346,"name":"Corrosion Inhibitor","url":"https://www.academia.edu/Documents/in/Corrosion_Inhibitor"},{"id":3661879,"name":"Titanium(IV) oxide","url":"https://www.academia.edu/Documents/in/Titanium_IV_oxide"}],"urls":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="88829716"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/88829716/QSAR_experimental_and_computational_chemistry_simulation_studies_on_the_inhibition_potentials_of_some_amino_acids_for_the_corrosion_of_mild_steel_in_0_1_M_HCl"><img alt="Research paper thumbnail of QSAR, experimental and computational chemistry simulation studies on the inhibition potentials of some amino acids for the corrosion of mild steel in 0.1 M HCl" class="work-thumbnail" src="https://attachments.academia-assets.com/92735660/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/88829716/QSAR_experimental_and_computational_chemistry_simulation_studies_on_the_inhibition_potentials_of_some_amino_acids_for_the_corrosion_of_mild_steel_in_0_1_M_HCl">QSAR, experimental and computational chemistry simulation studies on the inhibition potentials of some amino acids for the corrosion of mild steel in 0.1 M HCl</a></div><div class="wp-workCard_item"><span>International Journal of Electrochemical Science</span><span>, 2011</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="c70fbc0937efa68a8d0abb4736964ff3" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{&quot;attachment_id&quot;:92735660,&quot;asset_id&quot;:88829716,&quot;asset_type&quot;:&quot;Work&quot;,&quot;button_location&quot;:&quot;profile&quot;}" href="https://www.academia.edu/attachments/92735660/download_file?st=MTczMzI2NTEzOSw4LjIyMi4yMDguMTQ2&s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="88829716"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="88829716"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 88829716; 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dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "c70fbc0937efa68a8d0abb4736964ff3" } } $('.js-work-strip[data-work-id=88829716]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":88829716,"title":"QSAR, experimental and computational chemistry simulation studies on the inhibition potentials of some amino acids for the corrosion of mild steel in 0.1 M HCl","translated_title":"","metadata":{"grobid_abstract":"Inhibition and adsorption potentials of cysteine, glycine, leucine and alanine for the corrosion of mild steel in hydrochloric acid (HCl) solution were investigated using experimental and quantum chemical approaches. The experimental study was carried out using gravimetric, gasometric, thermometric and Fourier transformed infra red (FTIR) methods while the quantum chemical study was carried out using semi-empirical, ab-initio and quantitative structure activity relation (QSAR) methods. The results obtained indicated that various concentrations of the studied amino acids inhibited the corrosion of mild steel in HCl solution through physiosorption. The inhibition potentials of the inhibitors decreased in the order, cysteine \u003e leucine \u003e alanine \u003e glycine. The adsorption of the inhibitors on mild steel surface was found to be exothermic, spontaneous and supported the Langmuir adsorption model. Results obtained from quantum chemical studies showed excellent correlations between quantum chemical parameters and experimental inhibition efficiencies (for gas and aqueous phases using density functional theory (DFT) and Moller-Plesset (MP2) perturbations). Correlations between the experimental inhibition efficiencies and theoretical inhibition efficiencies (obtained from QSAR) were also excellent.","publication_date":{"day":null,"month":null,"year":2011,"errors":{}},"publication_name":"International Journal of Electrochemical Science","grobid_abstract_attachment_id":92735660},"translated_abstract":null,"internal_url":"https://www.academia.edu/88829716/QSAR_experimental_and_computational_chemistry_simulation_studies_on_the_inhibition_potentials_of_some_amino_acids_for_the_corrosion_of_mild_steel_in_0_1_M_HCl","translated_internal_url":"","created_at":"2022-10-19T22:48:59.566-07:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":43244766,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[{"id":92735660,"title":"","file_type":"pdf","scribd_thumbnail_url":"https://attachments.academia-assets.com/92735660/thumbnails/1.jpg","file_name":"6040931.pdf","download_url":"https://www.academia.edu/attachments/92735660/download_file?st=MTczMzI2NTEzOSw4LjIyMi4yMDguMTQ2&","bulk_download_file_name":"QSAR_experimental_and_computational_chem.pdf","bulk_download_url":"https://d1wqtxts1xzle7.cloudfront.net/92735660/6040931-libre.pdf?1666246216=\u0026response-content-disposition=attachment%3B+filename%3DQSAR_experimental_and_computational_chem.pdf\u0026Expires=1733268739\u0026Signature=UlxU1ivTRHSIYGXAfYrxoEVSbJbT5dT2IbDiLg7VOIrd9AA4XKmGFPLJ7RNYIGohmjSh~ktPxPRKUBp-DZRgq~1k7V7pbp8ffVS0Oret~G7TbDWQ0N5cEWR7m9O3VglNXfZXhFQZiXCmDibH5tA4rsC-mmpM3AGGwVmvROFBKUaGCov2yGDKNb7n6XdV8~PUBmXX5zc3fFxGu9yO7lr9h1Z5m8-lLvJHdmQ0DE4aHQKAmSmTKlpaYntKaMkis54Y4Xs3UU~tGhkW8mU~x0yQDuuAhZuIA4m5S4AUI2spmk~SO2EIZKEgRhWKvWapuebMeyV~AD86JSqdbjtEcGoBZQ__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA"}],"slug":"QSAR_experimental_and_computational_chemistry_simulation_studies_on_the_inhibition_potentials_of_some_amino_acids_for_the_corrosion_of_mild_steel_in_0_1_M_HCl","translated_slug":"","page_count":27,"language":"en","content_type":"Work","owner":{"id":43244766,"first_name":"E.","middle_initials":null,"last_name":"Ebenso","page_name":"EEbenso","domain_name":"unisouthafr","created_at":"2016-02-15T02:34:01.575-08:00","display_name":"E. 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="88378515"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/88378515/Adsorption_and_quantum_chemical_studies_on_cloxacillin_and_halides_for_the_corrosion_of_mild_steel_in_acidic_medium"><img alt="Research paper thumbnail of Adsorption and quantum chemical studies on cloxacillin and halides for the corrosion of mild steel in acidic medium" class="work-thumbnail" src="https://attachments.academia-assets.com/92362898/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/88378515/Adsorption_and_quantum_chemical_studies_on_cloxacillin_and_halides_for_the_corrosion_of_mild_steel_in_acidic_medium">Adsorption and quantum chemical studies on cloxacillin and halides for the corrosion of mild steel in acidic medium</a></div><div class="wp-workCard_item"><span>International Journal of Electrochemical Science</span><span>, 2010</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="9758499cb4269aa61cc82d7e1f432185" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{&quot;attachment_id&quot;:92362898,&quot;asset_id&quot;:88378515,&quot;asset_type&quot;:&quot;Work&quot;,&quot;button_location&quot;:&quot;profile&quot;}" href="https://www.academia.edu/attachments/92362898/download_file?st=MTczMzI2NTEzOSw4LjIyMi4yMDguMTQ2&s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="88378515"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="88378515"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 88378515; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=88378515]").text(description); $(".js-view-count[data-work-id=88378515]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 88378515; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='88378515']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 88378515, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "9758499cb4269aa61cc82d7e1f432185" } } $('.js-work-strip[data-work-id=88378515]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":88378515,"title":"Adsorption and quantum chemical studies on cloxacillin and halides for the corrosion of mild steel in acidic medium","translated_title":"","metadata":{"grobid_abstract":"The corrosion inhibition of mild steel in H 2 SO 4 by Cloxacillin (CLX) and its synergistic combination with halides (KI, KBr and KCl) was investigated using gravimetric, thermometric, gasometric and quantum chemical methods. The results indicated that CLX is a good adsorption inhibitor for the corrosion of mild steel in H 2 SO 4. Inhibition efficiency of CLX on mild steel increased with increase in concentration but decreased with rise in temperature ranging from 90.40 to 93.98%, 80.85 to 86.43%, 78.41 to 84.07% and 58.61 to 77.57% at 303, 313, 323 and 333 K respectively. The combination of CLX with the halides (KCl, KBr and KI) enhanced the inhibitive and adsorption capability of CLX to a greater extent indicating synergism. The adsorption was spontaneous and the experimental data were also found to fit into the Langmuir (mean R 2 = 0.9978) adsorption isotherm. Physical adsorption mechanism has been proposed from the thermodynamic data obtained in the study and the activation energies of the corrosion inhibition by CLX were higher than the value obtained for the blank which signifies physical adsorption. Some quantum chemical parameters and the Mulliken charge densities on the optimized structure of CLX were calculated using the B3LYP/6-31G (d,p) basis set method to provide further insight into the mechanism of the corrosion inhibition process. The local reactivity was analyzed through the Fukui function and condensed softness indices in order to know the possible sites of nucleophillic and electrophillic attacks.","publication_date":{"day":null,"month":null,"year":2010,"errors":{}},"publication_name":"International Journal of Electrochemical Science","grobid_abstract_attachment_id":92362898},"translated_abstract":null,"internal_url":"https://www.academia.edu/88378515/Adsorption_and_quantum_chemical_studies_on_cloxacillin_and_halides_for_the_corrosion_of_mild_steel_in_acidic_medium","translated_internal_url":"","created_at":"2022-10-12T20:53:54.780-07:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":43244766,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[{"id":92362898,"title":"","file_type":"pdf","scribd_thumbnail_url":"https://attachments.academia-assets.com/92362898/thumbnails/1.jpg","file_name":"5060731.pdf","download_url":"https://www.academia.edu/attachments/92362898/download_file?st=MTczMzI2NTEzOSw4LjIyMi4yMDguMTQ2&","bulk_download_file_name":"Adsorption_and_quantum_chemical_studies.pdf","bulk_download_url":"https://d1wqtxts1xzle7.cloudfront.net/92362898/5060731-libre.pdf?1665633358=\u0026response-content-disposition=attachment%3B+filename%3DAdsorption_and_quantum_chemical_studies.pdf\u0026Expires=1733268739\u0026Signature=BoOUYX8QHMpy4PNc7J8v6Lb1TtqTwlDi8JUaYCj3URLt~rD8BGwk0nUneklZ~eypS8WgQ0qTWjZKRryq2ma9v2jZGWq0i-QCozCZCpWGgNytiu24jdS5dxzzugQ6QTu7O2XTJZWZp7pkMtjKXip0ns9bcoC-rUdTmI7ntopuB3eurer4e2sfje~guqDPGrpA4eB8aQPLjIAJcY-WiaiF4aJN-hi-grm5jqzajhY-8lSxd1dUfku9iLNft~uwSmwu-ZoK2IW3~ktSD53hF4rqsL9Qg1Hv6byGtVYt0AvKys4bD4dvB1YjTha7DFmLpNk3xnMHpA3We09GdKc6u4iTHw__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA"}],"slug":"Adsorption_and_quantum_chemical_studies_on_cloxacillin_and_halides_for_the_corrosion_of_mild_steel_in_acidic_medium","translated_slug":"","page_count":20,"language":"en","content_type":"Work","owner":{"id":43244766,"first_name":"E.","middle_initials":null,"last_name":"Ebenso","page_name":"EEbenso","domain_name":"unisouthafr","created_at":"2016-02-15T02:34:01.575-08:00","display_name":"E. Ebenso","url":"https://unisouthafr.academia.edu/EEbenso"},"attachments":[{"id":92362898,"title":"","file_type":"pdf","scribd_thumbnail_url":"https://attachments.academia-assets.com/92362898/thumbnails/1.jpg","file_name":"5060731.pdf","download_url":"https://www.academia.edu/attachments/92362898/download_file?st=MTczMzI2NTEzOSw4LjIyMi4yMDguMTQ2&","bulk_download_file_name":"Adsorption_and_quantum_chemical_studies.pdf","bulk_download_url":"https://d1wqtxts1xzle7.cloudfront.net/92362898/5060731-libre.pdf?1665633358=\u0026response-content-disposition=attachment%3B+filename%3DAdsorption_and_quantum_chemical_studies.pdf\u0026Expires=1733268739\u0026Signature=BoOUYX8QHMpy4PNc7J8v6Lb1TtqTwlDi8JUaYCj3URLt~rD8BGwk0nUneklZ~eypS8WgQ0qTWjZKRryq2ma9v2jZGWq0i-QCozCZCpWGgNytiu24jdS5dxzzugQ6QTu7O2XTJZWZp7pkMtjKXip0ns9bcoC-rUdTmI7ntopuB3eurer4e2sfje~guqDPGrpA4eB8aQPLjIAJcY-WiaiF4aJN-hi-grm5jqzajhY-8lSxd1dUfku9iLNft~uwSmwu-ZoK2IW3~ktSD53hF4rqsL9Qg1Hv6byGtVYt0AvKys4bD4dvB1YjTha7DFmLpNk3xnMHpA3We09GdKc6u4iTHw__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA"}],"research_interests":[{"id":39752,"name":"Adsorption","url":"https://www.academia.edu/Documents/in/Adsorption"},{"id":561590,"name":"Corrosion Inhibition","url":"https://www.academia.edu/Documents/in/Corrosion_Inhibition"},{"id":957648,"name":"Synergism","url":"https://www.academia.edu/Documents/in/Synergism"},{"id":1187634,"name":"P","url":"https://www.academia.edu/Documents/in/P"},{"id":2631484,"name":"Adsorption isotherm","url":"https://www.academia.edu/Documents/in/Adsorption_isotherm"},{"id":3856363,"name":"Halides","url":"https://www.academia.edu/Documents/in/Halides"}],"urls":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="87588053"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/87588053/Adsorption_and_inhibitive_properties_of_ethanol_extract_of_Garcinia_kola_and_Cola_nitida_for_the_corrosion_of_mild_steel_in_H2SO4"><img alt="Research paper thumbnail of Adsorption and inhibitive properties of ethanol extract of Garcinia kola and Cola nitida for the corrosion of mild steel in H2SO4" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/87588053/Adsorption_and_inhibitive_properties_of_ethanol_extract_of_Garcinia_kola_and_Cola_nitida_for_the_corrosion_of_mild_steel_in_H2SO4">Adsorption and inhibitive properties of ethanol extract of Garcinia kola and Cola nitida for the corrosion of mild steel in H2SO4</a></div><div class="wp-workCard_item"><span>Pigment &amp;amp; Resin Technology</span><span>, 2010</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">PurposeThe purpose of this paper is to study the inhibitive and adsorption characteristics of eth...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">PurposeThe purpose of this paper is to study the inhibitive and adsorption characteristics of ethanol extract of Garcinia kola and Cola nitida for the corrosion of mild steel in H2SO4 solutions.Design/methodology/approachThe inhibition efficiencies were evaluated using weight loss and thermometric methods while the adsorption properties were studied using IR spectroscopy.FindingsThe inhibition efficiencies of ethanol extracts of Garcinia kola and Cola nitida were comparable and vary with concentration of the extract, period of immersion and with temperature. The extracts act as adsorption inhibitors because of its phytochemical composition. The extracts are adsorbed spontaneously on the surface of mild steel according to Langmuir adsorption isotherms. The mechanism of physical adsorption is proposed from the trend of the inhibition efficiency with temperature and the values of activation energy and some thermodynamic parameters obtained.Research limitations/implicationsThe study pro...</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="87588053"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="87588053"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 87588053; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=87588053]").text(description); $(".js-view-count[data-work-id=87588053]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 87588053; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='87588053']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 87588053, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=87588053]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":87588053,"title":"Adsorption and inhibitive properties of ethanol extract of Garcinia kola and Cola nitida for the corrosion of mild steel in H2SO4","translated_title":"","metadata":{"abstract":"PurposeThe purpose of this paper is to study the inhibitive and adsorption characteristics of ethanol extract of Garcinia kola and Cola nitida for the corrosion of mild steel in H2SO4 solutions.Design/methodology/approachThe inhibition efficiencies were evaluated using weight loss and thermometric methods while the adsorption properties were studied using IR spectroscopy.FindingsThe inhibition efficiencies of ethanol extracts of Garcinia kola and Cola nitida were comparable and vary with concentration of the extract, period of immersion and with temperature. The extracts act as adsorption inhibitors because of its phytochemical composition. The extracts are adsorbed spontaneously on the surface of mild steel according to Langmuir adsorption isotherms. The mechanism of physical adsorption is proposed from the trend of the inhibition efficiency with temperature and the values of activation energy and some thermodynamic parameters obtained.Research limitations/implicationsThe study pro...","publisher":"Emerald","publication_date":{"day":null,"month":null,"year":2010,"errors":{}},"publication_name":"Pigment \u0026amp; Resin Technology"},"translated_abstract":"PurposeThe purpose of this paper is to study the inhibitive and adsorption characteristics of ethanol extract of Garcinia kola and Cola nitida for the corrosion of mild steel in H2SO4 solutions.Design/methodology/approachThe inhibition efficiencies were evaluated using weight loss and thermometric methods while the adsorption properties were studied using IR spectroscopy.FindingsThe inhibition efficiencies of ethanol extracts of Garcinia kola and Cola nitida were comparable and vary with concentration of the extract, period of immersion and with temperature. The extracts act as adsorption inhibitors because of its phytochemical composition. The extracts are adsorbed spontaneously on the surface of mild steel according to Langmuir adsorption isotherms. The mechanism of physical adsorption is proposed from the trend of the inhibition efficiency with temperature and the values of activation energy and some thermodynamic parameters obtained.Research limitations/implicationsThe study pro...","internal_url":"https://www.academia.edu/87588053/Adsorption_and_inhibitive_properties_of_ethanol_extract_of_Garcinia_kola_and_Cola_nitida_for_the_corrosion_of_mild_steel_in_H2SO4","translated_internal_url":"","created_at":"2022-09-29T18:51:03.825-07:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":43244766,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[],"slug":"Adsorption_and_inhibitive_properties_of_ethanol_extract_of_Garcinia_kola_and_Cola_nitida_for_the_corrosion_of_mild_steel_in_H2SO4","translated_slug":"","page_count":null,"language":"en","content_type":"Work","owner":{"id":43244766,"first_name":"E.","middle_initials":null,"last_name":"Ebenso","page_name":"EEbenso","domain_name":"unisouthafr","created_at":"2016-02-15T02:34:01.575-08:00","display_name":"E. Ebenso","url":"https://unisouthafr.academia.edu/EEbenso"},"attachments":[],"research_interests":[{"id":523,"name":"Chemistry","url":"https://www.academia.edu/Documents/in/Chemistry"},{"id":26931,"name":"Nuclear Chemistry","url":"https://www.academia.edu/Documents/in/Nuclear_Chemistry"},{"id":27537,"name":"Corrosion","url":"https://www.academia.edu/Documents/in/Corrosion"},{"id":39752,"name":"Adsorption","url":"https://www.academia.edu/Documents/in/Adsorption"},{"id":89805,"name":"Weight Loss","url":"https://www.academia.edu/Documents/in/Weight_Loss"},{"id":121705,"name":"Ethanol","url":"https://www.academia.edu/Documents/in/Ethanol"},{"id":147640,"name":"Activation Energy","url":"https://www.academia.edu/Documents/in/Activation_Energy"},{"id":159687,"name":"Design Methodology","url":"https://www.academia.edu/Documents/in/Design_Methodology"},{"id":352757,"name":"Ascorbic Acid","url":"https://www.academia.edu/Documents/in/Ascorbic_Acid"},{"id":448421,"name":"IR Spectroscopy","url":"https://www.academia.edu/Documents/in/IR_Spectroscopy"},{"id":803172,"name":"Mild Steel","url":"https://www.academia.edu/Documents/in/Mild_Steel"},{"id":1127381,"name":"Sulphuric Acid","url":"https://www.academia.edu/Documents/in/Sulphuric_Acid"},{"id":1291063,"name":"Thermodynamic Parameter","url":"https://www.academia.edu/Documents/in/Thermodynamic_Parameter"},{"id":1508346,"name":"Corrosion Inhibitor","url":"https://www.academia.edu/Documents/in/Corrosion_Inhibitor"},{"id":2631484,"name":"Adsorption isotherm","url":"https://www.academia.edu/Documents/in/Adsorption_isotherm"}],"urls":[{"id":24317102,"url":"http://www.emeraldinsight.com/doi/full-xml/10.1108/03699421011085849"}]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="87152431"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/87152431/Theoretical_Study_and_Adsorption_Behavior_of_Urea_on_Mild_Steel_in_Automotive_Gas_Oil_AGO_Medium"><img alt="Research paper thumbnail of Theoretical Study and Adsorption Behavior of Urea on Mild Steel in Automotive Gas Oil (AGO) Medium" class="work-thumbnail" src="https://attachments.academia-assets.com/91444409/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/87152431/Theoretical_Study_and_Adsorption_Behavior_of_Urea_on_Mild_Steel_in_Automotive_Gas_Oil_AGO_Medium">Theoretical Study and Adsorption Behavior of Urea on Mild Steel in Automotive Gas Oil (AGO) Medium</a></div><div class="wp-workCard_item"><span>Lubricants</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">The continuous search for eco-friendly corrosion inhibitors due to differences in corrosive media...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">The continuous search for eco-friendly corrosion inhibitors due to differences in corrosive media remains an important point in corrosion control. The experimental studies on the corrosion inhibition of urea on mild steel in automotive gas oil (AGO) was conducted using gasometric techniques and scanning electron microscope (SEM). The theoretical approach on the density functional theory (DFT) on the urea molecule was carried out using Gaussian 09 software. The adsorption behavior of urea molecules on the surface of the mild steel was analyzed using Frumkin and Flory-Huggins adsorption isotherms models and Gibb’s free energy, respectively. The result of the experimental study shows a poor corrosion inhibitory effect of urea on mild steel in automobile gas oil (AGO) medium as the inhibition efficiency decreased from 69.30% in week 1 to 12% in week 11 at 200 ppm of inhibitor. The adsorption of urea on the mild steel surface obeys Frumkin’s adsorption isotherm model. Gibb’s free energy ...</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="5db3fff7bb226c0cfb9b20202b5f0593" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{&quot;attachment_id&quot;:91444409,&quot;asset_id&quot;:87152431,&quot;asset_type&quot;:&quot;Work&quot;,&quot;button_location&quot;:&quot;profile&quot;}" href="https://www.academia.edu/attachments/91444409/download_file?st=MTczMzI2NTEzOSw4LjIyMi4yMDguMTQ2&s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="87152431"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="87152431"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 87152431; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=87152431]").text(description); $(".js-view-count[data-work-id=87152431]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 87152431; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='87152431']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 87152431, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "5db3fff7bb226c0cfb9b20202b5f0593" } } $('.js-work-strip[data-work-id=87152431]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":87152431,"title":"Theoretical Study and Adsorption Behavior of Urea on Mild Steel in Automotive Gas Oil (AGO) Medium","translated_title":"","metadata":{"abstract":"The continuous search for eco-friendly corrosion inhibitors due to differences in corrosive media remains an important point in corrosion control. The experimental studies on the corrosion inhibition of urea on mild steel in automotive gas oil (AGO) was conducted using gasometric techniques and scanning electron microscope (SEM). The theoretical approach on the density functional theory (DFT) on the urea molecule was carried out using Gaussian 09 software. The adsorption behavior of urea molecules on the surface of the mild steel was analyzed using Frumkin and Flory-Huggins adsorption isotherms models and Gibb’s free energy, respectively. The result of the experimental study shows a poor corrosion inhibitory effect of urea on mild steel in automobile gas oil (AGO) medium as the inhibition efficiency decreased from 69.30% in week 1 to 12% in week 11 at 200 ppm of inhibitor. The adsorption of urea on the mild steel surface obeys Frumkin’s adsorption isotherm model. Gibb’s free energy ...","publisher":"MDPI AG","publication_name":"Lubricants"},"translated_abstract":"The continuous search for eco-friendly corrosion inhibitors due to differences in corrosive media remains an important point in corrosion control. The experimental studies on the corrosion inhibition of urea on mild steel in automotive gas oil (AGO) was conducted using gasometric techniques and scanning electron microscope (SEM). The theoretical approach on the density functional theory (DFT) on the urea molecule was carried out using Gaussian 09 software. The adsorption behavior of urea molecules on the surface of the mild steel was analyzed using Frumkin and Flory-Huggins adsorption isotherms models and Gibb’s free energy, respectively. The result of the experimental study shows a poor corrosion inhibitory effect of urea on mild steel in automobile gas oil (AGO) medium as the inhibition efficiency decreased from 69.30% in week 1 to 12% in week 11 at 200 ppm of inhibitor. The adsorption of urea on the mild steel surface obeys Frumkin’s adsorption isotherm model. Gibb’s free energy ...","internal_url":"https://www.academia.edu/87152431/Theoretical_Study_and_Adsorption_Behavior_of_Urea_on_Mild_Steel_in_Automotive_Gas_Oil_AGO_Medium","translated_internal_url":"","created_at":"2022-09-23T08:42:05.166-07:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":43244766,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[{"id":91444409,"title":"","file_type":"pdf","scribd_thumbnail_url":"https://attachments.academia-assets.com/91444409/thumbnails/1.jpg","file_name":"pdf.pdf","download_url":"https://www.academia.edu/attachments/91444409/download_file?st=MTczMzI2NTEzOSw4LjIyMi4yMDguMTQ2&","bulk_download_file_name":"Theoretical_Study_and_Adsorption_Behavio.pdf","bulk_download_url":"https://d1wqtxts1xzle7.cloudfront.net/91444409/pdf-libre.pdf?1663948608=\u0026response-content-disposition=attachment%3B+filename%3DTheoretical_Study_and_Adsorption_Behavio.pdf\u0026Expires=1733268739\u0026Signature=TbFjQBFcGrWZ3uanzusO7IbOYJQMDwKYoAQ5f-an2chQy3XXhPX5UKe3epSHhMkOERorIAMl8~pWXwY8YmuKgH8Xa7sP3ET-09ZgDYxzIo7SSEoksXSuV0Yg0aN9OsmnMSQDjUDcTN0slO19vhhYdKqz~J0lKehgAVoRC6jQXMHeOgr36sF9C4x-2PcbA0TywQvIbxvADSwwoGER0zdPYrdwYmjo3yT5~s1xGP5CMS5LRVh4TuVrSGbPq~aRn9mnn6SbKnBAzAldi7McdZCdGdP~n4gMP3Bk~Gt-nezJYF5aY-ung1Ug4ybdgZFn-eAt9z1GZROUGl6phPI2Sw7iKg__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA"}],"slug":"Theoretical_Study_and_Adsorption_Behavior_of_Urea_on_Mild_Steel_in_Automotive_Gas_Oil_AGO_Medium","translated_slug":"","page_count":13,"language":"en","content_type":"Work","owner":{"id":43244766,"first_name":"E.","middle_initials":null,"last_name":"Ebenso","page_name":"EEbenso","domain_name":"unisouthafr","created_at":"2016-02-15T02:34:01.575-08:00","display_name":"E. 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Several AAILs based on imidazolium, phosphonium, ammonium and cholinium ionic liquids have been widely employed in materials science, modern chemistry and bioscience. Some recent application of the AAILs includes heterogeneous catalysis, CO2 capture and solvents for chemical transformation, cellulose dissolution, extraction and separation processes. Several experimental and computational techniques are being employed to gain insight about the proper understanding of their physiochemical properties. The AAILs showed high thermal stability as compared to the pure ionic liquids which is attributed to the strong Van der Waals forces and hydrogen bonding (noncovalent bonds) which make them as solvents for high temperatur...</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="84163652"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="84163652"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 84163652; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=84163652]").text(description); $(".js-view-count[data-work-id=84163652]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 84163652; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='84163652']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 84163652, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=84163652]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":84163652,"title":"Recent Advancements in Synthesis and Applications of Amino Acid Ionic Liquids (AAILs): A Mini Review","translated_title":"","metadata":{"abstract":"Recently, amino acid ionic liquids (AAILs) have attracted increasing attention in the field of catalysis, solvents for separation science, cellulose dissolution and chemical transformations because of their non-toxic, biodegradable, biocompatible and low production cost. 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The AAILs showed high thermal stability as compared to the pure ionic liquids which is attributed to the strong Van der Waals forces and hydrogen bonding (noncovalent bonds) which make them as solvents for high temperatur...","publication_date":{"day":null,"month":null,"year":2018,"errors":{}}},"translated_abstract":"Recently, amino acid ionic liquids (AAILs) have attracted increasing attention in the field of catalysis, solvents for separation science, cellulose dissolution and chemical transformations because of their non-toxic, biodegradable, biocompatible and low production cost. Several AAILs based on imidazolium, phosphonium, ammonium and cholinium ionic liquids have been widely employed in materials science, modern chemistry and bioscience. Some recent application of the AAILs includes heterogeneous catalysis, CO2 capture and solvents for chemical transformation, cellulose dissolution, extraction and separation processes. Several experimental and computational techniques are being employed to gain insight about the proper understanding of their physiochemical properties. The AAILs showed high thermal stability as compared to the pure ionic liquids which is attributed to the strong Van der Waals forces and hydrogen bonding (noncovalent bonds) which make them as solvents for high temperatur...","internal_url":"https://www.academia.edu/84163652/Recent_Advancements_in_Synthesis_and_Applications_of_Amino_Acid_Ionic_Liquids_AAILs_A_Mini_Review","translated_internal_url":"","created_at":"2022-08-04T22:18:14.814-07:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":43244766,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[],"slug":"Recent_Advancements_in_Synthesis_and_Applications_of_Amino_Acid_Ionic_Liquids_AAILs_A_Mini_Review","translated_slug":"","page_count":null,"language":"en","content_type":"Work","owner":{"id":43244766,"first_name":"E.","middle_initials":null,"last_name":"Ebenso","page_name":"EEbenso","domain_name":"unisouthafr","created_at":"2016-02-15T02:34:01.575-08:00","display_name":"E. 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="84163648"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/84163648/Blends_of_polyvinyl_pyrrolidone_and_polyacrylamide_as_corrosion_inhibitors_for_aluminium_in_acidic_medium"><img alt="Research paper thumbnail of Blends of polyvinyl pyrrolidone and polyacrylamide as corrosion inhibitors for aluminium in acidic medium" class="work-thumbnail" src="https://attachments.academia-assets.com/89282108/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/84163648/Blends_of_polyvinyl_pyrrolidone_and_polyacrylamide_as_corrosion_inhibitors_for_aluminium_in_acidic_medium">Blends of polyvinyl pyrrolidone and polyacrylamide as corrosion inhibitors for aluminium in acidic medium</a></div><div class="wp-workCard_item"><span>Indian Journal of Chemical Technology</span><span>, 2008</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="ab1914892278d15471b11ec36cf47691" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{&quot;attachment_id&quot;:89282108,&quot;asset_id&quot;:84163648,&quot;asset_type&quot;:&quot;Work&quot;,&quot;button_location&quot;:&quot;profile&quot;}" href="https://www.academia.edu/attachments/89282108/download_file?st=MTczMzI2NTEzOSw4LjIyMi4yMDguMTQ2&s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="84163648"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="84163648"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 84163648; 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dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "ab1914892278d15471b11ec36cf47691" } } $('.js-work-strip[data-work-id=84163648]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":84163648,"title":"Blends of polyvinyl pyrrolidone and polyacrylamide as corrosion inhibitors for aluminium in acidic medium","translated_title":"","metadata":{"grobid_abstract":"The corrosion and inhibition behaviour of aluminium in hydrochloric acid (HCl) in the absence and presence of polyvinyl pyrrolidone (PVP), Polyacrylamide (PA) and their blends was studied in the temperature range of 30-60 o C using weight loss, hydrogen evolution and thermometric techniques. The inhibition efficiency (%I) increased with increase in inhibitors concentration. Increased in temperature led to increase in corrosion rate but decreased the inhibition efficiency PVP was found to have the higher inhibition efficiency than PA which may suggest that the differences in their molecular structures play a significant role in the adsorption and hence inhibition process. Inhibition efficiency was enhanced on blending the two polymers; the optimum inhibition efficiency was obtained at 3:1 blending ratio for PVP: PA. The inhibitors (PVP and PA) obey Freundlich, Temkin and Flory-Huggins adsorption isotherms at all the temperatures. Results obtained from the kinetic and thermodynamic parameters indicate spontaneous adsorption of the inhibitors unto aluminium surface following physical adsorption mechanism.","publication_date":{"day":null,"month":null,"year":2008,"errors":{}},"publication_name":"Indian Journal of Chemical Technology","grobid_abstract_attachment_id":89282108},"translated_abstract":null,"internal_url":"https://www.academia.edu/84163648/Blends_of_polyvinyl_pyrrolidone_and_polyacrylamide_as_corrosion_inhibitors_for_aluminium_in_acidic_medium","translated_internal_url":"","created_at":"2022-08-04T22:18:14.424-07:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":43244766,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[{"id":89282108,"title":"","file_type":"pdf","scribd_thumbnail_url":"https://attachments.academia-assets.com/89282108/thumbnails/1.jpg","file_name":"IJCT_20154_20355-363.pdf","download_url":"https://www.academia.edu/attachments/89282108/download_file?st=MTczMzI2NTEzOSw4LjIyMi4yMDguMTQ2&","bulk_download_file_name":"Blends_of_polyvinyl_pyrrolidone_and_poly.pdf","bulk_download_url":"https://d1wqtxts1xzle7.cloudfront.net/89282108/IJCT_20154_20355-363-libre.pdf?1659678381=\u0026response-content-disposition=attachment%3B+filename%3DBlends_of_polyvinyl_pyrrolidone_and_poly.pdf\u0026Expires=1733268739\u0026Signature=QC8Ip8T6lzngxt-YqVFE9LQ74q8BFotGPMN7xR3Tklwbq6jZZXCvXUlBmOnw~FkNYYDydyqNNrYdvTGTCxHEVWcVKxeokMpTWEYnPgrdOlyX8ZuwwEX6h0BfUs-RMRRdj6he3PBMUMSDm6XqXR21wDjdsJaDen5nHIBChbBEv4GXBBuETBSEtPItbICH~9w-MFi8nqqIgrI5-QLSiUnbQlrebKdeCJaDaoKnjOf7pAcmq5KHOMlacaCpjFddA0fyPhk11XBJKCgrGhQaOlZbuhzriBvQ4csa-h17FT5HB9Ksx0KKlPfrSmCCbvFv1hTw~szpRQLTApVw74EPwv8cHw__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA"}],"slug":"Blends_of_polyvinyl_pyrrolidone_and_polyacrylamide_as_corrosion_inhibitors_for_aluminium_in_acidic_medium","translated_slug":"","page_count":9,"language":"en","content_type":"Work","owner":{"id":43244766,"first_name":"E.","middle_initials":null,"last_name":"Ebenso","page_name":"EEbenso","domain_name":"unisouthafr","created_at":"2016-02-15T02:34:01.575-08:00","display_name":"E. 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="21989361"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/21989361/Electrochemical_Evaluation_of_Linseed_Oil_as_Environment_friendly_Inhibitor_for_Corrosion_of_Steel_in_HCl_Solution"><img alt="Research paper thumbnail of Electrochemical Evaluation of Linseed Oil as Environment-friendly Inhibitor for Corrosion of Steel in HCl Solution" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/21989361/Electrochemical_Evaluation_of_Linseed_Oil_as_Environment_friendly_Inhibitor_for_Corrosion_of_Steel_in_HCl_Solution">Electrochemical Evaluation of Linseed Oil as Environment-friendly Inhibitor for Corrosion of Steel in HCl Solution</a></div><div class="wp-workCard_item"><span>Portugaliae Electrochimica Acta</span><span>, 2015</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="21989361"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="21989361"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 21989361; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=21989361]").text(description); $(".js-view-count[data-work-id=21989361]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 21989361; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='21989361']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 21989361, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=21989361]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":21989361,"title":"Electrochemical Evaluation of Linseed Oil as Environment-friendly Inhibitor for Corrosion of Steel in HCl Solution","translated_title":"","metadata":{"publication_date":{"day":null,"month":null,"year":2015,"errors":{}},"publication_name":"Portugaliae Electrochimica Acta"},"translated_abstract":null,"internal_url":"https://www.academia.edu/21989361/Electrochemical_Evaluation_of_Linseed_Oil_as_Environment_friendly_Inhibitor_for_Corrosion_of_Steel_in_HCl_Solution","translated_internal_url":"","created_at":"2016-02-15T02:46:15.636-08:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":43244766,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[],"slug":"Electrochemical_Evaluation_of_Linseed_Oil_as_Environment_friendly_Inhibitor_for_Corrosion_of_Steel_in_HCl_Solution","translated_slug":"","page_count":null,"language":"en","content_type":"Work","owner":{"id":43244766,"first_name":"E.","middle_initials":null,"last_name":"Ebenso","page_name":"EEbenso","domain_name":"unisouthafr","created_at":"2016-02-15T02:34:01.575-08:00","display_name":"E. Ebenso","url":"https://unisouthafr.academia.edu/EEbenso"},"attachments":[],"research_interests":[],"urls":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="21989360"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/21989360/Density_and_speed_of_sound_of_1_ethyl_3_methylimidazolium_ethyl_sulphate_with_acetic_or_propionic_acid_at_different_temperatures"><img alt="Research paper thumbnail of Density and speed of sound of 1-ethyl-3-methylimidazolium ethyl sulphate with acetic or propionic acid at different temperatures" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/21989360/Density_and_speed_of_sound_of_1_ethyl_3_methylimidazolium_ethyl_sulphate_with_acetic_or_propionic_acid_at_different_temperatures">Density and speed of sound of 1-ethyl-3-methylimidazolium ethyl sulphate with acetic or propionic acid at different temperatures</a></div><div class="wp-workCard_item"><span>Journal of Molecular Liquids</span><span>, 2014</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">ABSTRACT In this work, new density, ρ, and speed of sound, u, were measured for IL, acetic acid, ...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">ABSTRACT In this work, new density, ρ, and speed of sound, u, were measured for IL, acetic acid, propionic acid, and their binary systems {IL (x1) + acetic or propionic acid (x2)} at 293.15, 298.15, 303.15, 308.15 and 313.15 K under atmospheric pressure. The IL used in this study was 1-ethyl-3-methylimidazolium ethyl sulphate ([EMIM]+[EtSO4]−). The derived properties such as excess molar volumes, VmE, isentropic compressibility, κs, and deviation in isentropic compressibility, Δκs, were calculated using experimental density and speed of sound data, respectively. Derived properties such as excess molar volumes, VmE, and deviation in isentropic compressibility, Δκs, data were fitted to the Redlich-Kister polynomial equation. The measured and calculated data were interpreted on the basis of intermolecular interactions and structural effects between like and unlike molecules upon mixing.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="21989360"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="21989360"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 21989360; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=21989360]").text(description); $(".js-view-count[data-work-id=21989360]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 21989360; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='21989360']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 21989360, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=21989360]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":21989360,"title":"Density and speed of sound of 1-ethyl-3-methylimidazolium ethyl sulphate with acetic or propionic acid at different temperatures","translated_title":"","metadata":{"abstract":"ABSTRACT In this work, new density, ρ, and speed of sound, u, were measured for IL, acetic acid, propionic acid, and their binary systems {IL (x1) + acetic or propionic acid (x2)} at 293.15, 298.15, 303.15, 308.15 and 313.15 K under atmospheric pressure. The IL used in this study was 1-ethyl-3-methylimidazolium ethyl sulphate ([EMIM]+[EtSO4]−). The derived properties such as excess molar volumes, VmE, isentropic compressibility, κs, and deviation in isentropic compressibility, Δκs, were calculated using experimental density and speed of sound data, respectively. Derived properties such as excess molar volumes, VmE, and deviation in isentropic compressibility, Δκs, data were fitted to the Redlich-Kister polynomial equation. The measured and calculated data were interpreted on the basis of intermolecular interactions and structural effects between like and unlike molecules upon mixing.","publication_date":{"day":null,"month":null,"year":2014,"errors":{}},"publication_name":"Journal of Molecular Liquids"},"translated_abstract":"ABSTRACT In this work, new density, ρ, and speed of sound, u, were measured for IL, acetic acid, propionic acid, and their binary systems {IL (x1) + acetic or propionic acid (x2)} at 293.15, 298.15, 303.15, 308.15 and 313.15 K under atmospheric pressure. The IL used in this study was 1-ethyl-3-methylimidazolium ethyl sulphate ([EMIM]+[EtSO4]−). The derived properties such as excess molar volumes, VmE, isentropic compressibility, κs, and deviation in isentropic compressibility, Δκs, were calculated using experimental density and speed of sound data, respectively. Derived properties such as excess molar volumes, VmE, and deviation in isentropic compressibility, Δκs, data were fitted to the Redlich-Kister polynomial equation. The measured and calculated data were interpreted on the basis of intermolecular interactions and structural effects between like and unlike molecules upon mixing.","internal_url":"https://www.academia.edu/21989360/Density_and_speed_of_sound_of_1_ethyl_3_methylimidazolium_ethyl_sulphate_with_acetic_or_propionic_acid_at_different_temperatures","translated_internal_url":"","created_at":"2016-02-15T02:46:15.457-08:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":43244766,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[],"slug":"Density_and_speed_of_sound_of_1_ethyl_3_methylimidazolium_ethyl_sulphate_with_acetic_or_propionic_acid_at_different_temperatures","translated_slug":"","page_count":null,"language":"en","content_type":"Work","owner":{"id":43244766,"first_name":"E.","middle_initials":null,"last_name":"Ebenso","page_name":"EEbenso","domain_name":"unisouthafr","created_at":"2016-02-15T02:34:01.575-08:00","display_name":"E. Ebenso","url":"https://unisouthafr.academia.edu/EEbenso"},"attachments":[],"research_interests":[{"id":2114155,"name":"Molecular liquids","url":"https://www.academia.edu/Documents/in/Molecular_liquids"}],"urls":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="21989359"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/21989359/Density_and_speed_of_sound_measurements_of_imidazolium_based_ionic_liquids_with_acetonitrile_at_various_temperatures"><img alt="Research paper thumbnail of Density and speed of sound measurements of imidazolium-based ionic liquids with acetonitrile at various temperatures" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/21989359/Density_and_speed_of_sound_measurements_of_imidazolium_based_ionic_liquids_with_acetonitrile_at_various_temperatures">Density and speed of sound measurements of imidazolium-based ionic liquids with acetonitrile at various temperatures</a></div><div class="wp-workCard_item"><span>Journal of Molecular Liquids</span><span>, 2014</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">ABSTRACT In the present study, the interactions between acetonitrile and imidazolium-based ionic ...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">ABSTRACT In the present study, the interactions between acetonitrile and imidazolium-based ionic liquids (ILs) were discussed in terms of density (ρ) and speed of sound (u) measurements. The ILs used in this study were 1-ethyl-3-methylimidazolium ethylsulfate ([EMIM]+[EtSO4]−) and 1-butyl-3-methylimidazolium thiocyanate ([BMIM]+[SCN]−). The ρ and u of acetonitrile, ILs, and their binary systems {[EMIM]+[EtSO4]− or [BMIM]+[SCN]− (x1) + acetonitrile (x2)} were measured at 293.15, 298.15, 303.15, 308.15 and 313.15 K and at p = 0.1 MPa. The derived properties such as excess molar volumes, VmE, isentropic compressibility, κs, and deviation in isentropic compressibility, Δκs, were calculated from experimental density and speed of sound data, respectively. The Redlich–Kister polynomial equation was used to fit the excess/deviation properties. These results are useful for describing the intermolecular interactions, developing structure–property correlation and molecular modeling that exist between the acetonitrile and imidazolium-based IL mixtures.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="21989359"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="21989359"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 21989359; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=21989359]").text(description); $(".js-view-count[data-work-id=21989359]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 21989359; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='21989359']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 21989359, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=21989359]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":21989359,"title":"Density and speed of sound measurements of imidazolium-based ionic liquids with acetonitrile at various temperatures","translated_title":"","metadata":{"abstract":"ABSTRACT In the present study, the interactions between acetonitrile and imidazolium-based ionic liquids (ILs) were discussed in terms of density (ρ) and speed of sound (u) measurements. 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The derived properties such as excess molar volumes, VmE, isentropic compressibility, κs, and deviation in isentropic compressibility, Δκs, were calculated from experimental density and speed of sound data, respectively. The Redlich–Kister polynomial equation was used to fit the excess/deviation properties. These results are useful for describing the intermolecular interactions, developing structure–property correlation and molecular modeling that exist between the acetonitrile and imidazolium-based IL mixtures.","internal_url":"https://www.academia.edu/21989359/Density_and_speed_of_sound_measurements_of_imidazolium_based_ionic_liquids_with_acetonitrile_at_various_temperatures","translated_internal_url":"","created_at":"2016-02-15T02:46:15.267-08:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":43244766,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[],"slug":"Density_and_speed_of_sound_measurements_of_imidazolium_based_ionic_liquids_with_acetonitrile_at_various_temperatures","translated_slug":"","page_count":null,"language":"en","content_type":"Work","owner":{"id":43244766,"first_name":"E.","middle_initials":null,"last_name":"Ebenso","page_name":"EEbenso","domain_name":"unisouthafr","created_at":"2016-02-15T02:34:01.575-08:00","display_name":"E. 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The results of the study reveals that the different concentrations of ethanol extract of Piper guinensis (EEPG) inhibit mild steel corrosion. Inhibition efficiency of the extract is found to vary with concentration, temperature and period of immersion. Values</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="15850ea4d3a3b1dac1620cdc34b61a50" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{&quot;attachment_id&quot;:42696686,&quot;asset_id&quot;:21989357,&quot;asset_type&quot;:&quot;Work&quot;,&quot;button_location&quot;:&quot;profile&quot;}" href="https://www.academia.edu/attachments/42696686/download_file?st=MTczMzI2NTE0MCw4LjIyMi4yMDguMTQ2&s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="21989357"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="21989357"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 21989357; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=21989357]").text(description); $(".js-view-count[data-work-id=21989357]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 21989357; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='21989357']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 21989357, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "15850ea4d3a3b1dac1620cdc34b61a50" } } $('.js-work-strip[data-work-id=21989357]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":21989357,"title":"Corrosion inhibitive properties and adsorption behaviour of ethanol extract of Piper guinensis as a green corrosion inhibitor for mild steel in H 2 SO 4","translated_title":"","metadata":{"abstract":"The corrosion inhibition of mild steel by ethanol extract of Piper guinensis (EEPG) has been studied using gravimetric, gasometric and thermometric methods. The results of the study reveals that the different concentrations of ethanol extract of Piper guinensis (EEPG) inhibit mild steel corrosion. Inhibition efficiency of the extract is found to vary with concentration, temperature and period of immersion. Values","publication_date":{"day":null,"month":null,"year":2008,"errors":{}}},"translated_abstract":"The corrosion inhibition of mild steel by ethanol extract of Piper guinensis (EEPG) has been studied using gravimetric, gasometric and thermometric methods. The results of the study reveals that the different concentrations of ethanol extract of Piper guinensis (EEPG) inhibit mild steel corrosion. Inhibition efficiency of the extract is found to vary with concentration, temperature and period of immersion. 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="21989356"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/21989356/Insulator_metal_transitions_induced_by_electric_and_magnetic_fields_in_thin_films_of_charge_ordered_Pr1_xCaxMnO3"><img alt="Research paper thumbnail of Insulator-metal transitions induced by electric and magnetic fields, in thin films of charge-ordered Pr1-xCaxMnO3" class="work-thumbnail" src="https://attachments.academia-assets.com/42696646/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/21989356/Insulator_metal_transitions_induced_by_electric_and_magnetic_fields_in_thin_films_of_charge_ordered_Pr1_xCaxMnO3">Insulator-metal transitions induced by electric and magnetic fields, in thin films of charge-ordered Pr1-xCaxMnO3</a></div><div class="wp-workCard_item"><span>Solid State Communications</span><span>, 2000</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="c9f6cdb21eaf1f83456fbe28c3c5557e" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{&quot;attachment_id&quot;:42696646,&quot;asset_id&quot;:21989356,&quot;asset_type&quot;:&quot;Work&quot;,&quot;button_location&quot;:&quot;profile&quot;}" href="https://www.academia.edu/attachments/42696646/download_file?st=MTczMzI2NTE0MCw4LjIyMi4yMDguMTQ2&s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="21989356"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="21989356"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 21989356; 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The films deposited on Si are generally polycrystalline, but they are highly oriented on the oxide substrates. The cobaltate films are generally not metallic, but exhibit low resistivity specially when x=0.3 and 0.5, the latter also exhibiting</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="21989355"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="21989355"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 21989355; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=21989355]").text(description); $(".js-view-count[data-work-id=21989355]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 21989355; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='21989355']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 21989355, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=21989355]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":21989355,"title":"Thin films of Ln1-xSrxCoO3 (Ln = La, Nd and Gd) and SrRuO3 by nebulized spray pyrolysis","translated_title":"","metadata":{"abstract":"Thin films of La1−xSrxCoO3, Nd0.5Sr0.5CoO3, Gd0.5Sr0.5CoO3 and SrRuO3 have been deposited on Si(100), LaAlO3(100) and SrTiO3(100) single crystal substrates by nebulized spray pyrolysis. The films deposited on Si are generally polycrystalline, but they are highly oriented on the oxide substrates. The cobaltate films are generally not metallic, but exhibit low resistivity specially when x=0.3 and 0.5, the latter also exhibiting","publication_date":{"day":null,"month":null,"year":2000,"errors":{}},"publication_name":"Solid State Sciences"},"translated_abstract":"Thin films of La1−xSrxCoO3, Nd0.5Sr0.5CoO3, Gd0.5Sr0.5CoO3 and SrRuO3 have been deposited on Si(100), LaAlO3(100) and SrTiO3(100) single crystal substrates by nebulized spray pyrolysis. The films deposited on Si are generally polycrystalline, but they are highly oriented on the oxide substrates. The cobaltate films are generally not metallic, but exhibit low resistivity specially when x=0.3 and 0.5, the latter also exhibiting","internal_url":"https://www.academia.edu/21989355/Thin_films_of_Ln1_xSrxCoO3_Ln_La_Nd_and_Gd_and_SrRuO3_by_nebulized_spray_pyrolysis","translated_internal_url":"","created_at":"2016-02-15T02:46:14.445-08:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":43244766,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[],"slug":"Thin_films_of_Ln1_xSrxCoO3_Ln_La_Nd_and_Gd_and_SrRuO3_by_nebulized_spray_pyrolysis","translated_slug":"","page_count":null,"language":"en","content_type":"Work","owner":{"id":43244766,"first_name":"E.","middle_initials":null,"last_name":"Ebenso","page_name":"EEbenso","domain_name":"unisouthafr","created_at":"2016-02-15T02:34:01.575-08:00","display_name":"E. 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="21989353"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/21989353/Corrosion_inhibition_and_adsorption_characteristics_of_tarivid_on_mild_steel_in_H2SO4"><img alt="Research paper thumbnail of Corrosion inhibition and adsorption characteristics of tarivid on mild steel in H2SO4" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/21989353/Corrosion_inhibition_and_adsorption_characteristics_of_tarivid_on_mild_steel_in_H2SO4">Corrosion inhibition and adsorption characteristics of tarivid on mild steel in H2SO4</a></div><div class="wp-workCard_item"><span>E-Journal of Chemistry</span><span>, 2010</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="21989353"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="21989353"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 21989353; 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Root extract on the corrosion and kinetics of corrosion process of copper in alkaline solutions" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/21989352/The_effects_of_cassia_siamea_lam_Root_extract_on_the_corrosion_and_kinetics_of_corrosion_process_of_copper_in_alkaline_solutions">The effects of cassia siamea lam. Root extract on the corrosion and kinetics of corrosion process of copper in alkaline solutions</a></div><div class="wp-workCard_item"><span>E-Journal of Chemistry</span><span>, 2011</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="21989352"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="21989352"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 21989352; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=21989352]").text(description); $(".js-view-count[data-work-id=21989352]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 21989352; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='21989352']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 21989352, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=21989352]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":21989352,"title":"The effects of cassia siamea lam. 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="89751026"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/89751026/Titanium_IV_oxide_as_corrosion_inhibitor_for_aluminium_and_mild_steel_in_acidic_medium"><img alt="Research paper thumbnail of Titanium (IV) oxide as corrosion inhibitor for aluminium and mild steel in acidic medium" class="work-thumbnail" src="https://attachments.academia-assets.com/93506284/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/89751026/Titanium_IV_oxide_as_corrosion_inhibitor_for_aluminium_and_mild_steel_in_acidic_medium">Titanium (IV) oxide as corrosion inhibitor for aluminium and mild steel in acidic medium</a></div><div class="wp-workCard_item"><span>International Journal of Electrochemical Science</span><span>, 2010</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="b77188dd2128d4ddd99b363a967e484b" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{&quot;attachment_id&quot;:93506284,&quot;asset_id&quot;:89751026,&quot;asset_type&quot;:&quot;Work&quot;,&quot;button_location&quot;:&quot;profile&quot;}" href="https://www.academia.edu/attachments/93506284/download_file?st=MTczMzI2NTE0MCw4LjIyMi4yMDguMTQ2&st=MTczMzI2NTEzOSw4LjIyMi4yMDguMTQ2&s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="89751026"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="89751026"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 89751026; 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The negative values of heat of adsorption, Q ads obtained in this study implies that the adsorption of TO molecules on the Al and MS surfaces is spontaneous.","publication_date":{"day":null,"month":null,"year":2010,"errors":{}},"publication_name":"International Journal of Electrochemical Science","grobid_abstract_attachment_id":93506284},"translated_abstract":null,"internal_url":"https://www.academia.edu/89751026/Titanium_IV_oxide_as_corrosion_inhibitor_for_aluminium_and_mild_steel_in_acidic_medium","translated_internal_url":"","created_at":"2022-11-01T22:18:45.886-07:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":43244766,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[{"id":93506284,"title":"","file_type":"pdf","scribd_thumbnail_url":"https://attachments.academia-assets.com/93506284/thumbnails/1.jpg","file_name":"5111563.pdf","download_url":"https://www.academia.edu/attachments/93506284/download_file?st=MTczMzI2NTE0MCw4LjIyMi4yMDguMTQ2&st=MTczMzI2NTEzOSw4LjIyMi4yMDguMTQ2&","bulk_download_file_name":"Titanium_IV_oxide_as_corrosion_inhibitor.pdf","bulk_download_url":"https://d1wqtxts1xzle7.cloudfront.net/93506284/5111563-libre.pdf?1667366673=\u0026response-content-disposition=attachment%3B+filename%3DTitanium_IV_oxide_as_corrosion_inhibitor.pdf\u0026Expires=1733268739\u0026Signature=AqAJkd3zpdhMxF6LGy68Y0QxmekzFnFyxMRUV~ddjYT7j56D25s29vQpvA0Jfdg5lGEvhyzRLhZ5SckPePgJ7sTo0h8-qIRhDYizgBLMwt~LgjYIRyFWHQBYabDcAyh4cWOy995q8AAM0jZ5tiPuh5LdU3XClhHHuoN7QKxH58YiP1PGKvieGoSt6NKrn-mVg0SmHVz1sDhAm7HItsfcOfbIENI3pIbMpyzDKkvroEaJQBm~W7t1Hhi1sHgVIfoX4STdL-raZgdrb0Irf5ANcKXBGPkINfrkTPcief6c5~d3tT7hk9bb1zyikemsB3MPyzQ5Ucuvnc0kcevryQD0iQ__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA"}],"slug":"Titanium_IV_oxide_as_corrosion_inhibitor_for_aluminium_and_mild_steel_in_acidic_medium","translated_slug":"","page_count":11,"language":"en","content_type":"Work","owner":{"id":43244766,"first_name":"E.","middle_initials":null,"last_name":"Ebenso","page_name":"EEbenso","domain_name":"unisouthafr","created_at":"2016-02-15T02:34:01.575-08:00","display_name":"E. 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="88829716"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/88829716/QSAR_experimental_and_computational_chemistry_simulation_studies_on_the_inhibition_potentials_of_some_amino_acids_for_the_corrosion_of_mild_steel_in_0_1_M_HCl"><img alt="Research paper thumbnail of QSAR, experimental and computational chemistry simulation studies on the inhibition potentials of some amino acids for the corrosion of mild steel in 0.1 M HCl" class="work-thumbnail" src="https://attachments.academia-assets.com/92735660/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/88829716/QSAR_experimental_and_computational_chemistry_simulation_studies_on_the_inhibition_potentials_of_some_amino_acids_for_the_corrosion_of_mild_steel_in_0_1_M_HCl">QSAR, experimental and computational chemistry simulation studies on the inhibition potentials of some amino acids for the corrosion of mild steel in 0.1 M HCl</a></div><div class="wp-workCard_item"><span>International Journal of Electrochemical Science</span><span>, 2011</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="c70fbc0937efa68a8d0abb4736964ff3" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{&quot;attachment_id&quot;:92735660,&quot;asset_id&quot;:88829716,&quot;asset_type&quot;:&quot;Work&quot;,&quot;button_location&quot;:&quot;profile&quot;}" href="https://www.academia.edu/attachments/92735660/download_file?st=MTczMzI2NTE0MCw4LjIyMi4yMDguMTQ2&st=MTczMzI2NTEzOSw4LjIyMi4yMDguMTQ2&s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="88829716"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="88829716"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 88829716; 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The experimental study was carried out using gravimetric, gasometric, thermometric and Fourier transformed infra red (FTIR) methods while the quantum chemical study was carried out using semi-empirical, ab-initio and quantitative structure activity relation (QSAR) methods. The results obtained indicated that various concentrations of the studied amino acids inhibited the corrosion of mild steel in HCl solution through physiosorption. The inhibition potentials of the inhibitors decreased in the order, cysteine \u003e leucine \u003e alanine \u003e glycine. The adsorption of the inhibitors on mild steel surface was found to be exothermic, spontaneous and supported the Langmuir adsorption model. Results obtained from quantum chemical studies showed excellent correlations between quantum chemical parameters and experimental inhibition efficiencies (for gas and aqueous phases using density functional theory (DFT) and Moller-Plesset (MP2) perturbations). Correlations between the experimental inhibition efficiencies and theoretical inhibition efficiencies (obtained from QSAR) were also excellent.","publication_date":{"day":null,"month":null,"year":2011,"errors":{}},"publication_name":"International Journal of Electrochemical Science","grobid_abstract_attachment_id":92735660},"translated_abstract":null,"internal_url":"https://www.academia.edu/88829716/QSAR_experimental_and_computational_chemistry_simulation_studies_on_the_inhibition_potentials_of_some_amino_acids_for_the_corrosion_of_mild_steel_in_0_1_M_HCl","translated_internal_url":"","created_at":"2022-10-19T22:48:59.566-07:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":43244766,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[{"id":92735660,"title":"","file_type":"pdf","scribd_thumbnail_url":"https://attachments.academia-assets.com/92735660/thumbnails/1.jpg","file_name":"6040931.pdf","download_url":"https://www.academia.edu/attachments/92735660/download_file?st=MTczMzI2NTE0MCw4LjIyMi4yMDguMTQ2&st=MTczMzI2NTEzOSw4LjIyMi4yMDguMTQ2&","bulk_download_file_name":"QSAR_experimental_and_computational_chem.pdf","bulk_download_url":"https://d1wqtxts1xzle7.cloudfront.net/92735660/6040931-libre.pdf?1666246216=\u0026response-content-disposition=attachment%3B+filename%3DQSAR_experimental_and_computational_chem.pdf\u0026Expires=1733268739\u0026Signature=UlxU1ivTRHSIYGXAfYrxoEVSbJbT5dT2IbDiLg7VOIrd9AA4XKmGFPLJ7RNYIGohmjSh~ktPxPRKUBp-DZRgq~1k7V7pbp8ffVS0Oret~G7TbDWQ0N5cEWR7m9O3VglNXfZXhFQZiXCmDibH5tA4rsC-mmpM3AGGwVmvROFBKUaGCov2yGDKNb7n6XdV8~PUBmXX5zc3fFxGu9yO7lr9h1Z5m8-lLvJHdmQ0DE4aHQKAmSmTKlpaYntKaMkis54Y4Xs3UU~tGhkW8mU~x0yQDuuAhZuIA4m5S4AUI2spmk~SO2EIZKEgRhWKvWapuebMeyV~AD86JSqdbjtEcGoBZQ__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA"}],"slug":"QSAR_experimental_and_computational_chemistry_simulation_studies_on_the_inhibition_potentials_of_some_amino_acids_for_the_corrosion_of_mild_steel_in_0_1_M_HCl","translated_slug":"","page_count":27,"language":"en","content_type":"Work","owner":{"id":43244766,"first_name":"E.","middle_initials":null,"last_name":"Ebenso","page_name":"EEbenso","domain_name":"unisouthafr","created_at":"2016-02-15T02:34:01.575-08:00","display_name":"E. 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="88378515"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/88378515/Adsorption_and_quantum_chemical_studies_on_cloxacillin_and_halides_for_the_corrosion_of_mild_steel_in_acidic_medium"><img alt="Research paper thumbnail of Adsorption and quantum chemical studies on cloxacillin and halides for the corrosion of mild steel in acidic medium" class="work-thumbnail" src="https://attachments.academia-assets.com/92362898/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/88378515/Adsorption_and_quantum_chemical_studies_on_cloxacillin_and_halides_for_the_corrosion_of_mild_steel_in_acidic_medium">Adsorption and quantum chemical studies on cloxacillin and halides for the corrosion of mild steel in acidic medium</a></div><div class="wp-workCard_item"><span>International Journal of Electrochemical Science</span><span>, 2010</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="9758499cb4269aa61cc82d7e1f432185" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{&quot;attachment_id&quot;:92362898,&quot;asset_id&quot;:88378515,&quot;asset_type&quot;:&quot;Work&quot;,&quot;button_location&quot;:&quot;profile&quot;}" href="https://www.academia.edu/attachments/92362898/download_file?st=MTczMzI2NTE0MCw4LjIyMi4yMDguMTQ2&st=MTczMzI2NTEzOSw4LjIyMi4yMDguMTQ2&s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="88378515"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="88378515"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 88378515; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=88378515]").text(description); $(".js-view-count[data-work-id=88378515]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 88378515; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='88378515']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 88378515, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "9758499cb4269aa61cc82d7e1f432185" } } $('.js-work-strip[data-work-id=88378515]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":88378515,"title":"Adsorption and quantum chemical studies on cloxacillin and halides for the corrosion of mild steel in acidic medium","translated_title":"","metadata":{"grobid_abstract":"The corrosion inhibition of mild steel in H 2 SO 4 by Cloxacillin (CLX) and its synergistic combination with halides (KI, KBr and KCl) was investigated using gravimetric, thermometric, gasometric and quantum chemical methods. The results indicated that CLX is a good adsorption inhibitor for the corrosion of mild steel in H 2 SO 4. Inhibition efficiency of CLX on mild steel increased with increase in concentration but decreased with rise in temperature ranging from 90.40 to 93.98%, 80.85 to 86.43%, 78.41 to 84.07% and 58.61 to 77.57% at 303, 313, 323 and 333 K respectively. The combination of CLX with the halides (KCl, KBr and KI) enhanced the inhibitive and adsorption capability of CLX to a greater extent indicating synergism. The adsorption was spontaneous and the experimental data were also found to fit into the Langmuir (mean R 2 = 0.9978) adsorption isotherm. Physical adsorption mechanism has been proposed from the thermodynamic data obtained in the study and the activation energies of the corrosion inhibition by CLX were higher than the value obtained for the blank which signifies physical adsorption. Some quantum chemical parameters and the Mulliken charge densities on the optimized structure of CLX were calculated using the B3LYP/6-31G (d,p) basis set method to provide further insight into the mechanism of the corrosion inhibition process. The local reactivity was analyzed through the Fukui function and condensed softness indices in order to know the possible sites of nucleophillic and electrophillic attacks.","publication_date":{"day":null,"month":null,"year":2010,"errors":{}},"publication_name":"International Journal of Electrochemical Science","grobid_abstract_attachment_id":92362898},"translated_abstract":null,"internal_url":"https://www.academia.edu/88378515/Adsorption_and_quantum_chemical_studies_on_cloxacillin_and_halides_for_the_corrosion_of_mild_steel_in_acidic_medium","translated_internal_url":"","created_at":"2022-10-12T20:53:54.780-07:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":43244766,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[{"id":92362898,"title":"","file_type":"pdf","scribd_thumbnail_url":"https://attachments.academia-assets.com/92362898/thumbnails/1.jpg","file_name":"5060731.pdf","download_url":"https://www.academia.edu/attachments/92362898/download_file?st=MTczMzI2NTE0MCw4LjIyMi4yMDguMTQ2&st=MTczMzI2NTEzOSw4LjIyMi4yMDguMTQ2&","bulk_download_file_name":"Adsorption_and_quantum_chemical_studies.pdf","bulk_download_url":"https://d1wqtxts1xzle7.cloudfront.net/92362898/5060731-libre.pdf?1665633358=\u0026response-content-disposition=attachment%3B+filename%3DAdsorption_and_quantum_chemical_studies.pdf\u0026Expires=1733268739\u0026Signature=BoOUYX8QHMpy4PNc7J8v6Lb1TtqTwlDi8JUaYCj3URLt~rD8BGwk0nUneklZ~eypS8WgQ0qTWjZKRryq2ma9v2jZGWq0i-QCozCZCpWGgNytiu24jdS5dxzzugQ6QTu7O2XTJZWZp7pkMtjKXip0ns9bcoC-rUdTmI7ntopuB3eurer4e2sfje~guqDPGrpA4eB8aQPLjIAJcY-WiaiF4aJN-hi-grm5jqzajhY-8lSxd1dUfku9iLNft~uwSmwu-ZoK2IW3~ktSD53hF4rqsL9Qg1Hv6byGtVYt0AvKys4bD4dvB1YjTha7DFmLpNk3xnMHpA3We09GdKc6u4iTHw__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA"}],"slug":"Adsorption_and_quantum_chemical_studies_on_cloxacillin_and_halides_for_the_corrosion_of_mild_steel_in_acidic_medium","translated_slug":"","page_count":20,"language":"en","content_type":"Work","owner":{"id":43244766,"first_name":"E.","middle_initials":null,"last_name":"Ebenso","page_name":"EEbenso","domain_name":"unisouthafr","created_at":"2016-02-15T02:34:01.575-08:00","display_name":"E. 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The extracts act as adsorption inhibitors because of its phytochemical composition. The extracts are adsorbed spontaneously on the surface of mild steel according to Langmuir adsorption isotherms. The mechanism of physical adsorption is proposed from the trend of the inhibition efficiency with temperature and the values of activation energy and some thermodynamic parameters obtained.Research limitations/implicationsThe study pro...</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="87588053"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="87588053"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 87588053; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=87588053]").text(description); $(".js-view-count[data-work-id=87588053]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 87588053; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='87588053']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 87588053, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=87588053]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":87588053,"title":"Adsorption and inhibitive properties of ethanol extract of Garcinia kola and Cola nitida for the corrosion of mild steel in H2SO4","translated_title":"","metadata":{"abstract":"PurposeThe purpose of this paper is to study the inhibitive and adsorption characteristics of ethanol extract of Garcinia kola and Cola nitida for the corrosion of mild steel in H2SO4 solutions.Design/methodology/approachThe inhibition efficiencies were evaluated using weight loss and thermometric methods while the adsorption properties were studied using IR spectroscopy.FindingsThe inhibition efficiencies of ethanol extracts of Garcinia kola and Cola nitida were comparable and vary with concentration of the extract, period of immersion and with temperature. The extracts act as adsorption inhibitors because of its phytochemical composition. The extracts are adsorbed spontaneously on the surface of mild steel according to Langmuir adsorption isotherms. The mechanism of physical adsorption is proposed from the trend of the inhibition efficiency with temperature and the values of activation energy and some thermodynamic parameters obtained.Research limitations/implicationsThe study pro...","publisher":"Emerald","publication_date":{"day":null,"month":null,"year":2010,"errors":{}},"publication_name":"Pigment \u0026amp; Resin Technology"},"translated_abstract":"PurposeThe purpose of this paper is to study the inhibitive and adsorption characteristics of ethanol extract of Garcinia kola and Cola nitida for the corrosion of mild steel in H2SO4 solutions.Design/methodology/approachThe inhibition efficiencies were evaluated using weight loss and thermometric methods while the adsorption properties were studied using IR spectroscopy.FindingsThe inhibition efficiencies of ethanol extracts of Garcinia kola and Cola nitida were comparable and vary with concentration of the extract, period of immersion and with temperature. The extracts act as adsorption inhibitors because of its phytochemical composition. The extracts are adsorbed spontaneously on the surface of mild steel according to Langmuir adsorption isotherms. The mechanism of physical adsorption is proposed from the trend of the inhibition efficiency with temperature and the values of activation energy and some thermodynamic parameters obtained.Research limitations/implicationsThe study pro...","internal_url":"https://www.academia.edu/87588053/Adsorption_and_inhibitive_properties_of_ethanol_extract_of_Garcinia_kola_and_Cola_nitida_for_the_corrosion_of_mild_steel_in_H2SO4","translated_internal_url":"","created_at":"2022-09-29T18:51:03.825-07:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":43244766,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[],"slug":"Adsorption_and_inhibitive_properties_of_ethanol_extract_of_Garcinia_kola_and_Cola_nitida_for_the_corrosion_of_mild_steel_in_H2SO4","translated_slug":"","page_count":null,"language":"en","content_type":"Work","owner":{"id":43244766,"first_name":"E.","middle_initials":null,"last_name":"Ebenso","page_name":"EEbenso","domain_name":"unisouthafr","created_at":"2016-02-15T02:34:01.575-08:00","display_name":"E. Ebenso","url":"https://unisouthafr.academia.edu/EEbenso"},"attachments":[],"research_interests":[{"id":523,"name":"Chemistry","url":"https://www.academia.edu/Documents/in/Chemistry"},{"id":26931,"name":"Nuclear Chemistry","url":"https://www.academia.edu/Documents/in/Nuclear_Chemistry"},{"id":27537,"name":"Corrosion","url":"https://www.academia.edu/Documents/in/Corrosion"},{"id":39752,"name":"Adsorption","url":"https://www.academia.edu/Documents/in/Adsorption"},{"id":89805,"name":"Weight Loss","url":"https://www.academia.edu/Documents/in/Weight_Loss"},{"id":121705,"name":"Ethanol","url":"https://www.academia.edu/Documents/in/Ethanol"},{"id":147640,"name":"Activation Energy","url":"https://www.academia.edu/Documents/in/Activation_Energy"},{"id":159687,"name":"Design Methodology","url":"https://www.academia.edu/Documents/in/Design_Methodology"},{"id":352757,"name":"Ascorbic Acid","url":"https://www.academia.edu/Documents/in/Ascorbic_Acid"},{"id":448421,"name":"IR Spectroscopy","url":"https://www.academia.edu/Documents/in/IR_Spectroscopy"},{"id":803172,"name":"Mild Steel","url":"https://www.academia.edu/Documents/in/Mild_Steel"},{"id":1127381,"name":"Sulphuric Acid","url":"https://www.academia.edu/Documents/in/Sulphuric_Acid"},{"id":1291063,"name":"Thermodynamic Parameter","url":"https://www.academia.edu/Documents/in/Thermodynamic_Parameter"},{"id":1508346,"name":"Corrosion Inhibitor","url":"https://www.academia.edu/Documents/in/Corrosion_Inhibitor"},{"id":2631484,"name":"Adsorption isotherm","url":"https://www.academia.edu/Documents/in/Adsorption_isotherm"}],"urls":[{"id":24317102,"url":"http://www.emeraldinsight.com/doi/full-xml/10.1108/03699421011085849"}]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="87152431"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/87152431/Theoretical_Study_and_Adsorption_Behavior_of_Urea_on_Mild_Steel_in_Automotive_Gas_Oil_AGO_Medium"><img alt="Research paper thumbnail of Theoretical Study and Adsorption Behavior of Urea on Mild Steel in Automotive Gas Oil (AGO) Medium" class="work-thumbnail" src="https://attachments.academia-assets.com/91444409/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/87152431/Theoretical_Study_and_Adsorption_Behavior_of_Urea_on_Mild_Steel_in_Automotive_Gas_Oil_AGO_Medium">Theoretical Study and Adsorption Behavior of Urea on Mild Steel in Automotive Gas Oil (AGO) Medium</a></div><div class="wp-workCard_item"><span>Lubricants</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">The continuous search for eco-friendly corrosion inhibitors due to differences in corrosive media...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">The continuous search for eco-friendly corrosion inhibitors due to differences in corrosive media remains an important point in corrosion control. The experimental studies on the corrosion inhibition of urea on mild steel in automotive gas oil (AGO) was conducted using gasometric techniques and scanning electron microscope (SEM). The theoretical approach on the density functional theory (DFT) on the urea molecule was carried out using Gaussian 09 software. The adsorption behavior of urea molecules on the surface of the mild steel was analyzed using Frumkin and Flory-Huggins adsorption isotherms models and Gibb’s free energy, respectively. The result of the experimental study shows a poor corrosion inhibitory effect of urea on mild steel in automobile gas oil (AGO) medium as the inhibition efficiency decreased from 69.30% in week 1 to 12% in week 11 at 200 ppm of inhibitor. The adsorption of urea on the mild steel surface obeys Frumkin’s adsorption isotherm model. Gibb’s free energy ...</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="5db3fff7bb226c0cfb9b20202b5f0593" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{&quot;attachment_id&quot;:91444409,&quot;asset_id&quot;:87152431,&quot;asset_type&quot;:&quot;Work&quot;,&quot;button_location&quot;:&quot;profile&quot;}" href="https://www.academia.edu/attachments/91444409/download_file?st=MTczMzI2NTE0MCw4LjIyMi4yMDguMTQ2&st=MTczMzI2NTEzOSw4LjIyMi4yMDguMTQ2&s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="87152431"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="87152431"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 87152431; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=87152431]").text(description); $(".js-view-count[data-work-id=87152431]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 87152431; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='87152431']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 87152431, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "5db3fff7bb226c0cfb9b20202b5f0593" } } $('.js-work-strip[data-work-id=87152431]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":87152431,"title":"Theoretical Study and Adsorption Behavior of Urea on Mild Steel in Automotive Gas Oil (AGO) Medium","translated_title":"","metadata":{"abstract":"The continuous search for eco-friendly corrosion inhibitors due to differences in corrosive media remains an important point in corrosion control. 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Gibb’s free energy ...","publisher":"MDPI AG","publication_name":"Lubricants"},"translated_abstract":"The continuous search for eco-friendly corrosion inhibitors due to differences in corrosive media remains an important point in corrosion control. The experimental studies on the corrosion inhibition of urea on mild steel in automotive gas oil (AGO) was conducted using gasometric techniques and scanning electron microscope (SEM). The theoretical approach on the density functional theory (DFT) on the urea molecule was carried out using Gaussian 09 software. The adsorption behavior of urea molecules on the surface of the mild steel was analyzed using Frumkin and Flory-Huggins adsorption isotherms models and Gibb’s free energy, respectively. The result of the experimental study shows a poor corrosion inhibitory effect of urea on mild steel in automobile gas oil (AGO) medium as the inhibition efficiency decreased from 69.30% in week 1 to 12% in week 11 at 200 ppm of inhibitor. The adsorption of urea on the mild steel surface obeys Frumkin’s adsorption isotherm model. 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Several AAILs based on imidazolium, phosphonium, ammonium and cholinium ionic liquids have been widely employed in materials science, modern chemistry and bioscience. Some recent application of the AAILs includes heterogeneous catalysis, CO2 capture and solvents for chemical transformation, cellulose dissolution, extraction and separation processes. Several experimental and computational techniques are being employed to gain insight about the proper understanding of their physiochemical properties. 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The inhibition efficiency (%I) increased with increase in inhibitors concentration. Increased in temperature led to increase in corrosion rate but decreased the inhibition efficiency PVP was found to have the higher inhibition efficiency than PA which may suggest that the differences in their molecular structures play a significant role in the adsorption and hence inhibition process. Inhibition efficiency was enhanced on blending the two polymers; the optimum inhibition efficiency was obtained at 3:1 blending ratio for PVP: PA. The inhibitors (PVP and PA) obey Freundlich, Temkin and Flory-Huggins adsorption isotherms at all the temperatures. 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="21989361"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/21989361/Electrochemical_Evaluation_of_Linseed_Oil_as_Environment_friendly_Inhibitor_for_Corrosion_of_Steel_in_HCl_Solution"><img alt="Research paper thumbnail of Electrochemical Evaluation of Linseed Oil as Environment-friendly Inhibitor for Corrosion of Steel in HCl Solution" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/21989361/Electrochemical_Evaluation_of_Linseed_Oil_as_Environment_friendly_Inhibitor_for_Corrosion_of_Steel_in_HCl_Solution">Electrochemical Evaluation of Linseed Oil as Environment-friendly Inhibitor for Corrosion of Steel in HCl Solution</a></div><div class="wp-workCard_item"><span>Portugaliae Electrochimica Acta</span><span>, 2015</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="21989361"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="21989361"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 21989361; 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Ebenso","url":"https://unisouthafr.academia.edu/EEbenso"},"attachments":[],"research_interests":[],"urls":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="21989360"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/21989360/Density_and_speed_of_sound_of_1_ethyl_3_methylimidazolium_ethyl_sulphate_with_acetic_or_propionic_acid_at_different_temperatures"><img alt="Research paper thumbnail of Density and speed of sound of 1-ethyl-3-methylimidazolium ethyl sulphate with acetic or propionic acid at different temperatures" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/21989360/Density_and_speed_of_sound_of_1_ethyl_3_methylimidazolium_ethyl_sulphate_with_acetic_or_propionic_acid_at_different_temperatures">Density and speed of sound of 1-ethyl-3-methylimidazolium ethyl sulphate with acetic or propionic acid at different temperatures</a></div><div class="wp-workCard_item"><span>Journal of Molecular Liquids</span><span>, 2014</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">ABSTRACT In this work, new density, ρ, and speed of sound, u, were measured for IL, acetic acid, ...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">ABSTRACT In this work, new density, ρ, and speed of sound, u, were measured for IL, acetic acid, propionic acid, and their binary systems {IL (x1) + acetic or propionic acid (x2)} at 293.15, 298.15, 303.15, 308.15 and 313.15 K under atmospheric pressure. The IL used in this study was 1-ethyl-3-methylimidazolium ethyl sulphate ([EMIM]+[EtSO4]−). The derived properties such as excess molar volumes, VmE, isentropic compressibility, κs, and deviation in isentropic compressibility, Δκs, were calculated using experimental density and speed of sound data, respectively. Derived properties such as excess molar volumes, VmE, and deviation in isentropic compressibility, Δκs, data were fitted to the Redlich-Kister polynomial equation. The measured and calculated data were interpreted on the basis of intermolecular interactions and structural effects between like and unlike molecules upon mixing.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="21989360"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="21989360"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 21989360; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=21989360]").text(description); $(".js-view-count[data-work-id=21989360]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 21989360; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='21989360']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 21989360, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=21989360]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":21989360,"title":"Density and speed of sound of 1-ethyl-3-methylimidazolium ethyl sulphate with acetic or propionic acid at different temperatures","translated_title":"","metadata":{"abstract":"ABSTRACT In this work, new density, ρ, and speed of sound, u, were measured for IL, acetic acid, propionic acid, and their binary systems {IL (x1) + acetic or propionic acid (x2)} at 293.15, 298.15, 303.15, 308.15 and 313.15 K under atmospheric pressure. The IL used in this study was 1-ethyl-3-methylimidazolium ethyl sulphate ([EMIM]+[EtSO4]−). The derived properties such as excess molar volumes, VmE, isentropic compressibility, κs, and deviation in isentropic compressibility, Δκs, were calculated using experimental density and speed of sound data, respectively. Derived properties such as excess molar volumes, VmE, and deviation in isentropic compressibility, Δκs, data were fitted to the Redlich-Kister polynomial equation. The measured and calculated data were interpreted on the basis of intermolecular interactions and structural effects between like and unlike molecules upon mixing.","publication_date":{"day":null,"month":null,"year":2014,"errors":{}},"publication_name":"Journal of Molecular Liquids"},"translated_abstract":"ABSTRACT In this work, new density, ρ, and speed of sound, u, were measured for IL, acetic acid, propionic acid, and their binary systems {IL (x1) + acetic or propionic acid (x2)} at 293.15, 298.15, 303.15, 308.15 and 313.15 K under atmospheric pressure. The IL used in this study was 1-ethyl-3-methylimidazolium ethyl sulphate ([EMIM]+[EtSO4]−). The derived properties such as excess molar volumes, VmE, isentropic compressibility, κs, and deviation in isentropic compressibility, Δκs, were calculated using experimental density and speed of sound data, respectively. Derived properties such as excess molar volumes, VmE, and deviation in isentropic compressibility, Δκs, data were fitted to the Redlich-Kister polynomial equation. The measured and calculated data were interpreted on the basis of intermolecular interactions and structural effects between like and unlike molecules upon mixing.","internal_url":"https://www.academia.edu/21989360/Density_and_speed_of_sound_of_1_ethyl_3_methylimidazolium_ethyl_sulphate_with_acetic_or_propionic_acid_at_different_temperatures","translated_internal_url":"","created_at":"2016-02-15T02:46:15.457-08:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":43244766,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[],"slug":"Density_and_speed_of_sound_of_1_ethyl_3_methylimidazolium_ethyl_sulphate_with_acetic_or_propionic_acid_at_different_temperatures","translated_slug":"","page_count":null,"language":"en","content_type":"Work","owner":{"id":43244766,"first_name":"E.","middle_initials":null,"last_name":"Ebenso","page_name":"EEbenso","domain_name":"unisouthafr","created_at":"2016-02-15T02:34:01.575-08:00","display_name":"E. Ebenso","url":"https://unisouthafr.academia.edu/EEbenso"},"attachments":[],"research_interests":[{"id":2114155,"name":"Molecular liquids","url":"https://www.academia.edu/Documents/in/Molecular_liquids"}],"urls":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="21989359"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/21989359/Density_and_speed_of_sound_measurements_of_imidazolium_based_ionic_liquids_with_acetonitrile_at_various_temperatures"><img alt="Research paper thumbnail of Density and speed of sound measurements of imidazolium-based ionic liquids with acetonitrile at various temperatures" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/21989359/Density_and_speed_of_sound_measurements_of_imidazolium_based_ionic_liquids_with_acetonitrile_at_various_temperatures">Density and speed of sound measurements of imidazolium-based ionic liquids with acetonitrile at various temperatures</a></div><div class="wp-workCard_item"><span>Journal of Molecular Liquids</span><span>, 2014</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">ABSTRACT In the present study, the interactions between acetonitrile and imidazolium-based ionic ...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">ABSTRACT In the present study, the interactions between acetonitrile and imidazolium-based ionic liquids (ILs) were discussed in terms of density (ρ) and speed of sound (u) measurements. The ILs used in this study were 1-ethyl-3-methylimidazolium ethylsulfate ([EMIM]+[EtSO4]−) and 1-butyl-3-methylimidazolium thiocyanate ([BMIM]+[SCN]−). The ρ and u of acetonitrile, ILs, and their binary systems {[EMIM]+[EtSO4]− or [BMIM]+[SCN]− (x1) + acetonitrile (x2)} were measured at 293.15, 298.15, 303.15, 308.15 and 313.15 K and at p = 0.1 MPa. The derived properties such as excess molar volumes, VmE, isentropic compressibility, κs, and deviation in isentropic compressibility, Δκs, were calculated from experimental density and speed of sound data, respectively. The Redlich–Kister polynomial equation was used to fit the excess/deviation properties. These results are useful for describing the intermolecular interactions, developing structure–property correlation and molecular modeling that exist between the acetonitrile and imidazolium-based IL mixtures.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="21989359"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="21989359"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 21989359; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=21989359]").text(description); $(".js-view-count[data-work-id=21989359]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 21989359; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='21989359']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 21989359, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=21989359]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":21989359,"title":"Density and speed of sound measurements of imidazolium-based ionic liquids with acetonitrile at various temperatures","translated_title":"","metadata":{"abstract":"ABSTRACT In the present study, the interactions between acetonitrile and imidazolium-based ionic liquids (ILs) were discussed in terms of density (ρ) and speed of sound (u) measurements. The ILs used in this study were 1-ethyl-3-methylimidazolium ethylsulfate ([EMIM]+[EtSO4]−) and 1-butyl-3-methylimidazolium thiocyanate ([BMIM]+[SCN]−). The ρ and u of acetonitrile, ILs, and their binary systems {[EMIM]+[EtSO4]− or [BMIM]+[SCN]− (x1) + acetonitrile (x2)} were measured at 293.15, 298.15, 303.15, 308.15 and 313.15 K and at p = 0.1 MPa. The derived properties such as excess molar volumes, VmE, isentropic compressibility, κs, and deviation in isentropic compressibility, Δκs, were calculated from experimental density and speed of sound data, respectively. The Redlich–Kister polynomial equation was used to fit the excess/deviation properties. These results are useful for describing the intermolecular interactions, developing structure–property correlation and molecular modeling that exist between the acetonitrile and imidazolium-based IL mixtures.","publication_date":{"day":null,"month":null,"year":2014,"errors":{}},"publication_name":"Journal of Molecular Liquids"},"translated_abstract":"ABSTRACT In the present study, the interactions between acetonitrile and imidazolium-based ionic liquids (ILs) were discussed in terms of density (ρ) and speed of sound (u) measurements. The ILs used in this study were 1-ethyl-3-methylimidazolium ethylsulfate ([EMIM]+[EtSO4]−) and 1-butyl-3-methylimidazolium thiocyanate ([BMIM]+[SCN]−). The ρ and u of acetonitrile, ILs, and their binary systems {[EMIM]+[EtSO4]− or [BMIM]+[SCN]− (x1) + acetonitrile (x2)} were measured at 293.15, 298.15, 303.15, 308.15 and 313.15 K and at p = 0.1 MPa. The derived properties such as excess molar volumes, VmE, isentropic compressibility, κs, and deviation in isentropic compressibility, Δκs, were calculated from experimental density and speed of sound data, respectively. The Redlich–Kister polynomial equation was used to fit the excess/deviation properties. These results are useful for describing the intermolecular interactions, developing structure–property correlation and molecular modeling that exist between the acetonitrile and imidazolium-based IL mixtures.","internal_url":"https://www.academia.edu/21989359/Density_and_speed_of_sound_measurements_of_imidazolium_based_ionic_liquids_with_acetonitrile_at_various_temperatures","translated_internal_url":"","created_at":"2016-02-15T02:46:15.267-08:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":43244766,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[],"slug":"Density_and_speed_of_sound_measurements_of_imidazolium_based_ionic_liquids_with_acetonitrile_at_various_temperatures","translated_slug":"","page_count":null,"language":"en","content_type":"Work","owner":{"id":43244766,"first_name":"E.","middle_initials":null,"last_name":"Ebenso","page_name":"EEbenso","domain_name":"unisouthafr","created_at":"2016-02-15T02:34:01.575-08:00","display_name":"E. Ebenso","url":"https://unisouthafr.academia.edu/EEbenso"},"attachments":[],"research_interests":[{"id":2114155,"name":"Molecular liquids","url":"https://www.academia.edu/Documents/in/Molecular_liquids"}],"urls":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="21989358"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/21989358/Steel_Corrosion_Inhibition_by_Acid_Garlic_Essential_Oil_as_a_Green_Corrosion_Inhibitor_and_Sorption_Behavior"><img alt="Research paper thumbnail of Steel Corrosion Inhibition by Acid Garlic Essential Oil as a Green Corrosion Inhibitor and Sorption Behavior" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/21989358/Steel_Corrosion_Inhibition_by_Acid_Garlic_Essential_Oil_as_a_Green_Corrosion_Inhibitor_and_Sorption_Behavior">Steel Corrosion Inhibition by Acid Garlic Essential Oil as a Green Corrosion Inhibitor and Sorption Behavior</a></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="21989358"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="21989358"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 21989358; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=21989358]").text(description); $(".js-view-count[data-work-id=21989358]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 21989358; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='21989358']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 21989358, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=21989358]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":21989358,"title":"Steel Corrosion Inhibition by Acid Garlic Essential Oil as a Green Corrosion Inhibitor and Sorption Behavior","translated_title":"","metadata":{},"translated_abstract":null,"internal_url":"https://www.academia.edu/21989358/Steel_Corrosion_Inhibition_by_Acid_Garlic_Essential_Oil_as_a_Green_Corrosion_Inhibitor_and_Sorption_Behavior","translated_internal_url":"","created_at":"2016-02-15T02:46:15.123-08:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":43244766,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[],"slug":"Steel_Corrosion_Inhibition_by_Acid_Garlic_Essential_Oil_as_a_Green_Corrosion_Inhibitor_and_Sorption_Behavior","translated_slug":"","page_count":null,"language":"en","content_type":"Work","owner":{"id":43244766,"first_name":"E.","middle_initials":null,"last_name":"Ebenso","page_name":"EEbenso","domain_name":"unisouthafr","created_at":"2016-02-15T02:34:01.575-08:00","display_name":"E. Ebenso","url":"https://unisouthafr.academia.edu/EEbenso"},"attachments":[],"research_interests":[],"urls":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="21989357"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/21989357/Corrosion_inhibitive_properties_and_adsorption_behaviour_of_ethanol_extract_of_Piper_guinensis_as_a_green_corrosion_inhibitor_for_mild_steel_in_H_2_SO_4"><img alt="Research paper thumbnail of Corrosion inhibitive properties and adsorption behaviour of ethanol extract of Piper guinensis as a green corrosion inhibitor for mild steel in H 2 SO 4" class="work-thumbnail" src="https://attachments.academia-assets.com/42696686/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/21989357/Corrosion_inhibitive_properties_and_adsorption_behaviour_of_ethanol_extract_of_Piper_guinensis_as_a_green_corrosion_inhibitor_for_mild_steel_in_H_2_SO_4">Corrosion inhibitive properties and adsorption behaviour of ethanol extract of Piper guinensis as a green corrosion inhibitor for mild steel in H 2 SO 4</a></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">The corrosion inhibition of mild steel by ethanol extract of Piper guinensis (EEPG) has been stud...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">The corrosion inhibition of mild steel by ethanol extract of Piper guinensis (EEPG) has been studied using gravimetric, gasometric and thermometric methods. The results of the study reveals that the different concentrations of ethanol extract of Piper guinensis (EEPG) inhibit mild steel corrosion. Inhibition efficiency of the extract is found to vary with concentration, temperature and period of immersion. Values</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="15850ea4d3a3b1dac1620cdc34b61a50" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{&quot;attachment_id&quot;:42696686,&quot;asset_id&quot;:21989357,&quot;asset_type&quot;:&quot;Work&quot;,&quot;button_location&quot;:&quot;profile&quot;}" href="https://www.academia.edu/attachments/42696686/download_file?st=MTczMzI2NTE0MCw4LjIyMi4yMDguMTQ2&st=MTczMzI2NTE0MCw4LjIyMi4yMDguMTQ2&s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="21989357"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="21989357"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 21989357; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=21989357]").text(description); $(".js-view-count[data-work-id=21989357]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 21989357; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='21989357']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 21989357, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "15850ea4d3a3b1dac1620cdc34b61a50" } } $('.js-work-strip[data-work-id=21989357]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":21989357,"title":"Corrosion inhibitive properties and adsorption behaviour of ethanol extract of Piper guinensis as a green corrosion inhibitor for mild steel in H 2 SO 4","translated_title":"","metadata":{"abstract":"The corrosion inhibition of mild steel by ethanol extract of Piper guinensis (EEPG) has been studied using gravimetric, gasometric and thermometric methods. The results of the study reveals that the different concentrations of ethanol extract of Piper guinensis (EEPG) inhibit mild steel corrosion. Inhibition efficiency of the extract is found to vary with concentration, temperature and period of immersion. Values","publication_date":{"day":null,"month":null,"year":2008,"errors":{}}},"translated_abstract":"The corrosion inhibition of mild steel by ethanol extract of Piper guinensis (EEPG) has been studied using gravimetric, gasometric and thermometric methods. The results of the study reveals that the different concentrations of ethanol extract of Piper guinensis (EEPG) inhibit mild steel corrosion. Inhibition efficiency of the extract is found to vary with concentration, temperature and period of immersion. Values","internal_url":"https://www.academia.edu/21989357/Corrosion_inhibitive_properties_and_adsorption_behaviour_of_ethanol_extract_of_Piper_guinensis_as_a_green_corrosion_inhibitor_for_mild_steel_in_H_2_SO_4","translated_internal_url":"","created_at":"2016-02-15T02:46:14.851-08:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":43244766,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[{"id":42696686,"title":"","file_type":"pdf","scribd_thumbnail_url":"https://attachments.academia-assets.com/42696686/thumbnails/1.jpg","file_name":"article1379425400_Ebenso_et_al.pdf","download_url":"https://www.academia.edu/attachments/42696686/download_file?st=MTczMzI2NTE0MCw4LjIyMi4yMDguMTQ2&st=MTczMzI2NTE0MCw4LjIyMi4yMDguMTQ2&","bulk_download_file_name":"Corrosion_inhibitive_properties_and_adso.pdf","bulk_download_url":"https://d1wqtxts1xzle7.cloudfront.net/42696686/article1379425400_Ebenso_et_al-libre.pdf?1455535343=\u0026response-content-disposition=attachment%3B+filename%3DCorrosion_inhibitive_properties_and_adso.pdf\u0026Expires=1733268740\u0026Signature=Nmh~yr5PtqeuKckvmoDQ~uoMY0l2HcxSftmk02QMa0FEoi4n3oqo9nY4aoL8ZTCIXAUNySSrQiBx-PrARLJjGcq9J~5YMNq~ExCsgFAZ14huZ2Xma36lbYjElLMbfYzl~b3q2u4vy6ZrX7pyxl-hPjsFRzEqv3SObA9rCwrj58bIG9iLxbu2WKf4YQDxWXDtLgOG09mSV1GU5o7GfwZWMCWLqz2Ar6ZgA~5ceD7WHG61K2mLX42vgDVO8YHDqZ2y1r3vCrQK04taV0IV8BKpxPBVu2gg1VTpVDcykR2yGXwbTndZgdRT-TfXAb5Gr~w7YNpn6Fv-pHiyQ9inly-2XQ__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA"}],"slug":"Corrosion_inhibitive_properties_and_adsorption_behaviour_of_ethanol_extract_of_Piper_guinensis_as_a_green_corrosion_inhibitor_for_mild_steel_in_H_2_SO_4","translated_slug":"","page_count":9,"language":"en","content_type":"Work","owner":{"id":43244766,"first_name":"E.","middle_initials":null,"last_name":"Ebenso","page_name":"EEbenso","domain_name":"unisouthafr","created_at":"2016-02-15T02:34:01.575-08:00","display_name":"E. 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="21989356"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/21989356/Insulator_metal_transitions_induced_by_electric_and_magnetic_fields_in_thin_films_of_charge_ordered_Pr1_xCaxMnO3"><img alt="Research paper thumbnail of Insulator-metal transitions induced by electric and magnetic fields, in thin films of charge-ordered Pr1-xCaxMnO3" class="work-thumbnail" src="https://attachments.academia-assets.com/42696646/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/21989356/Insulator_metal_transitions_induced_by_electric_and_magnetic_fields_in_thin_films_of_charge_ordered_Pr1_xCaxMnO3">Insulator-metal transitions induced by electric and magnetic fields, in thin films of charge-ordered Pr1-xCaxMnO3</a></div><div class="wp-workCard_item"><span>Solid State Communications</span><span>, 2000</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="c9f6cdb21eaf1f83456fbe28c3c5557e" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{&quot;attachment_id&quot;:42696646,&quot;asset_id&quot;:21989356,&quot;asset_type&quot;:&quot;Work&quot;,&quot;button_location&quot;:&quot;profile&quot;}" href="https://www.academia.edu/attachments/42696646/download_file?st=MTczMzI2NTE0MCw4LjIyMi4yMDguMTQ2&st=MTczMzI2NTE0MCw4LjIyMi4yMDguMTQ2&s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="21989356"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="21989356"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 21989356; 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The films deposited on Si are generally polycrystalline, but they are highly oriented on the oxide substrates. The cobaltate films are generally not metallic, but exhibit low resistivity specially when x=0.3 and 0.5, the latter also exhibiting</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="21989355"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="21989355"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 21989355; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=21989355]").text(description); $(".js-view-count[data-work-id=21989355]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 21989355; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='21989355']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 21989355, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=21989355]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":21989355,"title":"Thin films of Ln1-xSrxCoO3 (Ln = La, Nd and Gd) and SrRuO3 by nebulized spray pyrolysis","translated_title":"","metadata":{"abstract":"Thin films of La1−xSrxCoO3, Nd0.5Sr0.5CoO3, Gd0.5Sr0.5CoO3 and SrRuO3 have been deposited on Si(100), LaAlO3(100) and SrTiO3(100) single crystal substrates by nebulized spray pyrolysis. The films deposited on Si are generally polycrystalline, but they are highly oriented on the oxide substrates. The cobaltate films are generally not metallic, but exhibit low resistivity specially when x=0.3 and 0.5, the latter also exhibiting","publication_date":{"day":null,"month":null,"year":2000,"errors":{}},"publication_name":"Solid State Sciences"},"translated_abstract":"Thin films of La1−xSrxCoO3, Nd0.5Sr0.5CoO3, Gd0.5Sr0.5CoO3 and SrRuO3 have been deposited on Si(100), LaAlO3(100) and SrTiO3(100) single crystal substrates by nebulized spray pyrolysis. The films deposited on Si are generally polycrystalline, but they are highly oriented on the oxide substrates. The cobaltate films are generally not metallic, but exhibit low resistivity specially when x=0.3 and 0.5, the latter also exhibiting","internal_url":"https://www.academia.edu/21989355/Thin_films_of_Ln1_xSrxCoO3_Ln_La_Nd_and_Gd_and_SrRuO3_by_nebulized_spray_pyrolysis","translated_internal_url":"","created_at":"2016-02-15T02:46:14.445-08:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":43244766,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[],"slug":"Thin_films_of_Ln1_xSrxCoO3_Ln_La_Nd_and_Gd_and_SrRuO3_by_nebulized_spray_pyrolysis","translated_slug":"","page_count":null,"language":"en","content_type":"Work","owner":{"id":43244766,"first_name":"E.","middle_initials":null,"last_name":"Ebenso","page_name":"EEbenso","domain_name":"unisouthafr","created_at":"2016-02-15T02:34:01.575-08:00","display_name":"E. 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="21989353"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/21989353/Corrosion_inhibition_and_adsorption_characteristics_of_tarivid_on_mild_steel_in_H2SO4"><img alt="Research paper thumbnail of Corrosion inhibition and adsorption characteristics of tarivid on mild steel in H2SO4" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/21989353/Corrosion_inhibition_and_adsorption_characteristics_of_tarivid_on_mild_steel_in_H2SO4">Corrosion inhibition and adsorption characteristics of tarivid on mild steel in H2SO4</a></div><div class="wp-workCard_item"><span>E-Journal of Chemistry</span><span>, 2010</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="21989353"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="21989353"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 21989353; 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Root extract on the corrosion and kinetics of corrosion process of copper in alkaline solutions" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/21989352/The_effects_of_cassia_siamea_lam_Root_extract_on_the_corrosion_and_kinetics_of_corrosion_process_of_copper_in_alkaline_solutions">The effects of cassia siamea lam. Root extract on the corrosion and kinetics of corrosion process of copper in alkaline solutions</a></div><div class="wp-workCard_item"><span>E-Journal of Chemistry</span><span>, 2011</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="21989352"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="21989352"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 21989352; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=21989352]").text(description); $(".js-view-count[data-work-id=21989352]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 21989352; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='21989352']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 21989352, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=21989352]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":21989352,"title":"The effects of cassia siamea lam. 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