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class="vector-toc-numb">4.1</span> <span>Laboratory preparation</span> </div> </a> <ul id="toc-Laboratory_preparation-sublist" class="vector-toc-list"> </ul> </li> </ul> </li> <li id="toc-References" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#References"> <div class="vector-toc-text"> <span class="vector-toc-numb">5</span> <span>References</span> </div> </a> <ul id="toc-References-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-External_links" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#External_links"> <div class="vector-toc-text"> <span class="vector-toc-numb">6</span> <span>External links</span> </div> </a> <ul id="toc-External_links-sublist" class="vector-toc-list"> </ul> </li> </ul> </div> </div> </nav> </div> </div> <div class="mw-content-container"> <main id="content" class="mw-body"> <header class="mw-body-header 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</div> </div> </div> </nav> <h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">Zinc sulfide</span></h1> <div id="p-lang-btn" class="vector-dropdown mw-portlet mw-portlet-lang" > <input type="checkbox" id="p-lang-btn-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-p-lang-btn" class="vector-dropdown-checkbox mw-interlanguage-selector" aria-label="Go to an article in another language. Available in 34 languages" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-34" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">34 languages</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-af mw-list-item"><a href="https://af.wikipedia.org/wiki/Sinksulfied" title="Sinksulfied – Afrikaans" lang="af" hreflang="af" data-title="Sinksulfied" data-language-autonym="Afrikaans" data-language-local-name="Afrikaans" class="interlanguage-link-target"><span>Afrikaans</span></a></li><li class="interlanguage-link interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D9%83%D8%A8%D8%B1%D9%8A%D8%AA%D9%8A%D8%AF_%D8%A7%D9%84%D8%B2%D9%86%D9%83" title="كبريتيد الزنك – Arabic" lang="ar" hreflang="ar" data-title="كبريتيد الزنك" data-language-autonym="العربية" data-language-local-name="Arabic" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-azb mw-list-item"><a href="https://azb.wikipedia.org/wiki/%DA%86%DB%8C%D9%86%DA%A9%D9%88_%D8%B3%D9%88%D9%84%D9%81%DB%8C%D8%AF" title="چینکو سولفید – South Azerbaijani" lang="azb" hreflang="azb" data-title="چینکو سولفید" data-language-autonym="تۆرکجه" data-language-local-name="South Azerbaijani" class="interlanguage-link-target"><span>تۆرکجه</span></a></li><li class="interlanguage-link interwiki-bg mw-list-item"><a href="https://bg.wikipedia.org/wiki/%D0%A6%D0%B8%D0%BD%D0%BA%D0%BE%D0%B2_%D1%81%D1%83%D0%BB%D1%84%D0%B8%D0%B4" title="Цинков сулфид – Bulgarian" lang="bg" hreflang="bg" data-title="Цинков сулфид" data-language-autonym="Български" data-language-local-name="Bulgarian" class="interlanguage-link-target"><span>Български</span></a></li><li class="interlanguage-link interwiki-ca mw-list-item"><a href="https://ca.wikipedia.org/wiki/Sulfur_de_zinc" title="Sulfur de zinc – Catalan" lang="ca" hreflang="ca" data-title="Sulfur de zinc" data-language-autonym="Català" data-language-local-name="Catalan" class="interlanguage-link-target"><span>Català</span></a></li><li class="interlanguage-link interwiki-cs mw-list-item"><a href="https://cs.wikipedia.org/wiki/Sulfid_zine%C4%8Dnat%C3%BD" title="Sulfid zinečnatý – Czech" lang="cs" hreflang="cs" data-title="Sulfid zinečnatý" data-language-autonym="Čeština" data-language-local-name="Czech" class="interlanguage-link-target"><span>Čeština</span></a></li><li class="interlanguage-link interwiki-de mw-list-item"><a href="https://de.wikipedia.org/wiki/Zinksulfid" title="Zinksulfid – German" lang="de" hreflang="de" data-title="Zinksulfid" data-language-autonym="Deutsch" data-language-local-name="German" class="interlanguage-link-target"><span>Deutsch</span></a></li><li class="interlanguage-link interwiki-es mw-list-item"><a href="https://es.wikipedia.org/wiki/Sulfuro_de_zinc" title="Sulfuro de zinc – Spanish" lang="es" hreflang="es" data-title="Sulfuro de zinc" data-language-autonym="Español" data-language-local-name="Spanish" class="interlanguage-link-target"><span>Español</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%D8%B1%D9%88%DB%8C_%D8%B3%D9%88%D9%84%D9%81%DB%8C%D8%AF" title="روی سولفید – Persian" lang="fa" hreflang="fa" data-title="روی سولفید" data-language-autonym="فارسی" data-language-local-name="Persian" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/Sulfure_de_zinc" title="Sulfure de zinc – French" lang="fr" hreflang="fr" data-title="Sulfure de zinc" data-language-autonym="Français" data-language-local-name="French" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-ko mw-list-item"><a href="https://ko.wikipedia.org/wiki/%ED%99%A9%ED%99%94_%EC%95%84%EC%97%B0" title="황화 아연 – Korean" lang="ko" hreflang="ko" data-title="황화 아연" data-language-autonym="한국어" data-language-local-name="Korean" class="interlanguage-link-target"><span>한국어</span></a></li><li class="interlanguage-link interwiki-hy mw-list-item"><a href="https://hy.wikipedia.org/wiki/%D5%91%D5%AB%D5%B6%D5%AF%D5%AB_%D5%BD%D5%B8%D6%82%D5%AC%D6%86%D5%AB%D5%A4" title="Ցինկի սուլֆիդ – Armenian" lang="hy" hreflang="hy" data-title="Ցինկի սուլֆիդ" data-language-autonym="Հայերեն" data-language-local-name="Armenian" class="interlanguage-link-target"><span>Հայերեն</span></a></li><li class="interlanguage-link interwiki-hi mw-list-item"><a href="https://hi.wikipedia.org/wiki/%E0%A4%9C%E0%A4%BF%E0%A4%82%E0%A4%95_%E0%A4%B8%E0%A4%B2%E0%A5%8D%E0%A4%AB%E0%A4%BE%E0%A4%87%E0%A4%A1" title="जिंक सल्फाइड – Hindi" lang="hi" hreflang="hi" data-title="जिंक सल्फाइड" data-language-autonym="हिन्दी" data-language-local-name="Hindi" class="interlanguage-link-target"><span>हिन्दी</span></a></li><li class="interlanguage-link interwiki-hr mw-list-item"><a href="https://hr.wikipedia.org/wiki/Cinkov_sulfid" title="Cinkov sulfid – Croatian" lang="hr" hreflang="hr" data-title="Cinkov sulfid" data-language-autonym="Hrvatski" data-language-local-name="Croatian" class="interlanguage-link-target"><span>Hrvatski</span></a></li><li class="interlanguage-link interwiki-id mw-list-item"><a href="https://id.wikipedia.org/wiki/Seng_sulfida" title="Seng sulfida – Indonesian" lang="id" hreflang="id" data-title="Seng sulfida" data-language-autonym="Bahasa Indonesia" data-language-local-name="Indonesian" class="interlanguage-link-target"><span>Bahasa Indonesia</span></a></li><li class="interlanguage-link interwiki-it mw-list-item"><a href="https://it.wikipedia.org/wiki/Solfuro_di_zinco" title="Solfuro di zinco – Italian" lang="it" hreflang="it" data-title="Solfuro di zinco" data-language-autonym="Italiano" data-language-local-name="Italian" class="interlanguage-link-target"><span>Italiano</span></a></li><li class="interlanguage-link interwiki-hu mw-list-item"><a href="https://hu.wikipedia.org/wiki/Cink-szulfid" title="Cink-szulfid – Hungarian" lang="hu" hreflang="hu" data-title="Cink-szulfid" data-language-autonym="Magyar" data-language-local-name="Hungarian" class="interlanguage-link-target"><span>Magyar</span></a></li><li class="interlanguage-link interwiki-mk mw-list-item"><a href="https://mk.wikipedia.org/wiki/%D0%A6%D0%B8%D0%BD%D0%BA_%D1%81%D1%83%D0%BB%D1%84%D0%B8%D0%B4" title="Цинк сулфид – Macedonian" lang="mk" hreflang="mk" data-title="Цинк сулфид" data-language-autonym="Македонски" data-language-local-name="Macedonian" class="interlanguage-link-target"><span>Македонски</span></a></li><li class="interlanguage-link interwiki-nl mw-list-item"><a href="https://nl.wikipedia.org/wiki/Zinksulfide" title="Zinksulfide – Dutch" lang="nl" hreflang="nl" data-title="Zinksulfide" data-language-autonym="Nederlands" data-language-local-name="Dutch" class="interlanguage-link-target"><span>Nederlands</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E7%A1%AB%E5%8C%96%E4%BA%9C%E9%89%9B" title="硫化亜鉛 – Japanese" lang="ja" hreflang="ja" data-title="硫化亜鉛" data-language-autonym="日本語" data-language-local-name="Japanese" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-pl mw-list-item"><a href="https://pl.wikipedia.org/wiki/Siarczek_cynku" title="Siarczek cynku – Polish" lang="pl" hreflang="pl" data-title="Siarczek cynku" data-language-autonym="Polski" data-language-local-name="Polish" class="interlanguage-link-target"><span>Polski</span></a></li><li class="interlanguage-link interwiki-pt mw-list-item"><a href="https://pt.wikipedia.org/wiki/Sulfeto_de_zinco" title="Sulfeto de zinco – Portuguese" lang="pt" hreflang="pt" data-title="Sulfeto de zinco" data-language-autonym="Português" data-language-local-name="Portuguese" class="interlanguage-link-target"><span>Português</span></a></li><li class="interlanguage-link interwiki-ro mw-list-item"><a href="https://ro.wikipedia.org/wiki/Sulfur%C4%83_de_zinc" title="Sulfură de zinc – Romanian" lang="ro" hreflang="ro" data-title="Sulfură de zinc" data-language-autonym="Română" data-language-local-name="Romanian" class="interlanguage-link-target"><span>Română</span></a></li><li class="interlanguage-link interwiki-ru mw-list-item"><a href="https://ru.wikipedia.org/wiki/%D0%A1%D1%83%D0%BB%D1%8C%D1%84%D0%B8%D0%B4_%D1%86%D0%B8%D0%BD%D0%BA%D0%B0" title="Сульфид цинка – Russian" lang="ru" hreflang="ru" data-title="Сульфид цинка" data-language-autonym="Русский" data-language-local-name="Russian" class="interlanguage-link-target"><span>Русский</span></a></li><li class="interlanguage-link interwiki-simple mw-list-item"><a href="https://simple.wikipedia.org/wiki/Zinc_sulfide" title="Zinc sulfide – Simple English" lang="en-simple" hreflang="en-simple" data-title="Zinc sulfide" data-language-autonym="Simple English" data-language-local-name="Simple English" class="interlanguage-link-target"><span>Simple English</span></a></li><li class="interlanguage-link interwiki-sl mw-list-item"><a href="https://sl.wikipedia.org/wiki/Cinkov_sulfid" title="Cinkov sulfid – Slovenian" lang="sl" hreflang="sl" data-title="Cinkov sulfid" data-language-autonym="Slovenščina" data-language-local-name="Slovenian" class="interlanguage-link-target"><span>Slovenščina</span></a></li><li class="interlanguage-link interwiki-sr mw-list-item"><a href="https://sr.wikipedia.org/wiki/Cink_sulfid" title="Cink sulfid – Serbian" lang="sr" hreflang="sr" data-title="Cink sulfid" data-language-autonym="Српски / srpski" data-language-local-name="Serbian" class="interlanguage-link-target"><span>Српски / srpski</span></a></li><li class="interlanguage-link interwiki-sh mw-list-item"><a href="https://sh.wikipedia.org/wiki/Cink_sulfid" title="Cink sulfid – Serbo-Croatian" lang="sh" hreflang="sh" data-title="Cink sulfid" data-language-autonym="Srpskohrvatski / српскохрватски" data-language-local-name="Serbo-Croatian" class="interlanguage-link-target"><span>Srpskohrvatski / српскохрватски</span></a></li><li class="interlanguage-link interwiki-fi mw-list-item"><a href="https://fi.wikipedia.org/wiki/Sinkkisulfidi" title="Sinkkisulfidi – Finnish" lang="fi" hreflang="fi" data-title="Sinkkisulfidi" data-language-autonym="Suomi" data-language-local-name="Finnish" class="interlanguage-link-target"><span>Suomi</span></a></li><li class="interlanguage-link interwiki-sv mw-list-item"><a href="https://sv.wikipedia.org/wiki/Zinksulfid" title="Zinksulfid – Swedish" lang="sv" hreflang="sv" data-title="Zinksulfid" data-language-autonym="Svenska" data-language-local-name="Swedish" class="interlanguage-link-target"><span>Svenska</span></a></li><li class="interlanguage-link interwiki-ta mw-list-item"><a href="https://ta.wikipedia.org/wiki/%E0%AE%A8%E0%AE%BE%E0%AE%95_%E0%AE%9A%E0%AE%B2%E0%AF%8D%E0%AE%AA%E0%AF%88%E0%AE%9F%E0%AF%81" title="நாக சல்பைடு – Tamil" lang="ta" hreflang="ta" data-title="நாக சல்பைடு" data-language-autonym="தமிழ்" data-language-local-name="Tamil" class="interlanguage-link-target"><span>தமிழ்</span></a></li><li class="interlanguage-link interwiki-tr mw-list-item"><a href="https://tr.wikipedia.org/wiki/%C3%87inko_s%C3%BClf%C3%BCr" title="Çinko sülfür – Turkish" lang="tr" hreflang="tr" data-title="Çinko sülfür" data-language-autonym="Türkçe" data-language-local-name="Turkish" class="interlanguage-link-target"><span>Türkçe</span></a></li><li class="interlanguage-link interwiki-vi mw-list-item"><a href="https://vi.wikipedia.org/wiki/K%E1%BA%BDm_sulfide" title="Kẽm sulfide – Vietnamese" lang="vi" hreflang="vi" data-title="Kẽm sulfide" data-language-autonym="Tiếng Việt" data-language-local-name="Vietnamese" class="interlanguage-link-target"><span>Tiếng Việt</span></a></li><li class="interlanguage-link interwiki-zh mw-list-item"><a href="https://zh.wikipedia.org/wiki/%E7%A1%AB%E5%8C%96%E9%94%8C" title="硫化锌 – Chinese" lang="zh" hreflang="zh" data-title="硫化锌" data-language-autonym="中文" data-language-local-name="Chinese" class="interlanguage-link-target"><span>中文</span></a></li> </ul> <div class="after-portlet after-portlet-lang"><span class="wb-langlinks-edit wb-langlinks-link"><a href="https://www.wikidata.org/wiki/Special:EntityPage/Q204952#sitelinks-wikipedia" title="Edit interlanguage links" class="wbc-editpage">Edit links</a></span></div> </div> </div> </div> </header> <div class="vector-page-toolbar"> <div class="vector-page-toolbar-container"> <div id="left-navigation"> <nav 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td,.mw-parser-output .ib-chembox th{border:1px solid #a2a9b1;width:40%}.mw-parser-output .ib-chembox td+td{width:60%}@media screen{html.skin-theme-clientpref-night .mw-parser-output .ib-chembox figure:not(.skin-invert-image):not(.skin-invert):not(.bg-transparent){background:var(--background-color-inverted,#f8f9fa)}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .ib-chembox figure:not(.skin-invert-image):not(.skin-invert):not(.bg-transparent){background:var(--background-color-inverted,#f8f9fa)}}</style> <table class="infobox ib-chembox"> <caption>Zinc sulfide </caption> <tbody><tr> <td colspan="2" style="text-align:center; padding:2px;"><figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:Zinc_sulfide-edit.jpg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/e/e2/Zinc_sulfide-edit.jpg/250px-Zinc_sulfide-edit.jpg" decoding="async" width="250" height="202" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/e/e2/Zinc_sulfide-edit.jpg/375px-Zinc_sulfide-edit.jpg 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/e/e2/Zinc_sulfide-edit.jpg/500px-Zinc_sulfide-edit.jpg 2x" data-file-width="2153" data-file-height="1738" /></a><figcaption></figcaption></figure><div style="text-align:center;">ZnS powders containing different concentrations of sulfur vacancies<sup id="cite_ref-cat_1-0" class="reference"><a href="#cite_note-cat-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup></div> </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Names </th></tr> <tr> <td colspan="2" style="text-align:left;">Other names <div style="max-width:22em; word-wrap:break-word; padding-left:1.7em;"><a href="/wiki/Zincblende" class="mw-redirect" title="Zincblende">Zincblende</a><br /><a href="/wiki/Wurtzite" title="Wurtzite">Wurtzite</a></div> </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Identifiers </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/CAS_Registry_Number" title="CAS Registry Number">CAS Number</a></div> </td> <td><style data-mw-deduplicate="TemplateStyles:r1126788409">.mw-parser-output .plainlist ol,.mw-parser-output .plainlist ul{line-height:inherit;list-style:none;margin:0;padding:0}.mw-parser-output .plainlist ol li,.mw-parser-output .plainlist ul li{margin-bottom:0}</style><div class="plainlist"><ul><li><span title="commonchemistry.cas.org"><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=1314-98-3">1314-98-3</a></span><sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></li></ul></div> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">3D model (<a href="/wiki/JSmol" class="mw-redirect" title="JSmol">JSmol</a>)</div> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="chemapps.stolaf.edu (3D interactive model)"><a rel="nofollow" class="external text" href="https://chemapps.stolaf.edu/jmol/jmol.php?model=%5BZn%2B2%5D.%5BS-2%5D">Interactive image</a></span></li></ul></div> </td></tr> <tr> <td><a href="/wiki/ChemSpider" title="ChemSpider">ChemSpider</a> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="www.chemspider.com">[<a rel="nofollow" class="external free" href="https://www.chemspider.com/Chemical-Structure.8009652">https://www.chemspider.com/Chemical-Structure.8009652</a> <p>2.3.3 European Community (EC) Number 215-251-3.html 8009652 2.3.3 European Community (EC) Number </p> 215-251-3]</span></li></ul></div> </td></tr> <tr> <td><a href="/wiki/ECHA_InfoCard" class="mw-redirect" title="ECHA InfoCard"><span title="echa.europa.eu">ECHA InfoCard</span></a> </td> <td><a rel="nofollow" class="external text" href="https://echa.europa.eu/substance-information/-/substanceinfo/100.013.866">100.013.866</a> <span class="mw-valign-text-top noprint" typeof="mw:File/Frameless"><a href="https://www.wikidata.org/wiki/Q204952#P2566" title="Edit this at Wikidata"><img alt="Edit this at Wikidata" src="//upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/10px-OOjs_UI_icon_edit-ltr-progressive.svg.png" decoding="async" width="10" height="10" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/15px-OOjs_UI_icon_edit-ltr-progressive.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/20px-OOjs_UI_icon_edit-ltr-progressive.svg.png 2x" data-file-width="20" data-file-height="20" /></a></span> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/PubChem" title="PubChem">PubChem</a> <abbr title="Compound ID">CID</abbr></div> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="pubchem.ncbi.nlm.nih.gov"><a rel="nofollow" class="external text" href="https://pubchem.ncbi.nlm.nih.gov/compound/14821">14821</a></span></li></ul></div> </td></tr> <tr> <td><a href="/wiki/RTECS" class="mw-redirect" title="RTECS">RTECS number</a> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li>ZH5400000</li></ul></div> </td></tr> <tr> <td><a href="/wiki/Unique_Ingredient_Identifier" title="Unique Ingredient Identifier">UNII</a> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="precision.fda.gov"><a rel="nofollow" class="external text" href="https://precision.fda.gov/uniisearch/srs/unii/KPS085631O">KPS085631O</a></span><sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></li></ul></div> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/CompTox_Chemicals_Dashboard" title="CompTox Chemicals Dashboard">CompTox Dashboard</a> <span style="font-weight:normal">(<abbr title="U.S. Environmental Protection Agency">EPA</abbr>)</span></div> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="comptox.epa.gov"><a rel="nofollow" class="external text" href="https://comptox.epa.gov/dashboard/chemical/details/DTXSID7042518,">DTXSID101318257 DTXSID7042518, DTXSID101318257</a> <span class="mw-valign-text-top noprint" typeof="mw:File/Frameless"><a href="https://www.wikidata.org/wiki/Q204952#P3117" title="Edit this at Wikidata"><img alt="Edit this at Wikidata" src="//upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/10px-OOjs_UI_icon_edit-ltr-progressive.svg.png" decoding="async" width="10" height="10" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/15px-OOjs_UI_icon_edit-ltr-progressive.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/20px-OOjs_UI_icon_edit-ltr-progressive.svg.png 2x" data-file-width="20" data-file-height="20" /></a></span></span></li></ul></div> </td></tr> <tr> <td colspan="2"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold; text-align:left; font-weight:normal;"><div><a href="/wiki/International_Chemical_Identifier" title="International Chemical Identifier">InChI</a></div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0; word-break:break-all;"><li style="line-height: inherit; margin: 0"><div style="border-top:1px solid #ccc; padding:0.2em 0 0.2em 1.5em; text-align:left;"><div style="word-wrap:break-word; text-indent:-1.5em; font-size:97%; line-height:120%;">InChI=1S/S.Zn/q-2;+2</div><div style="word-wrap:break-word; text-indent:-1.5em; font-size:97%; line-height:120%;">Key: DRDVZXDWVBGGMH-UHFFFAOYSA-N</div></div></li></ul> </div> </td></tr> <tr> <td colspan="2"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold; text-align:left; font-weight:normal;"><div><a href="/wiki/Simplified_molecular-input_line-entry_system" class="mw-redirect" title="Simplified molecular-input line-entry system">SMILES</a></div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0; word-break:break-all;"><li style="line-height: inherit; margin: 0"><div style="border-top:1px solid #ccc; padding:0.2em 0 0.2em 1.6em; word-wrap:break-word; text-indent:-1.5em; text-align:left; font-size:97%; line-height:120%;">[Zn+2].[S-2]</div></li></ul> </div> </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Properties </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Chemical_formula" title="Chemical formula">Chemical formula</a></div> </td> <td>ZnS  </td></tr> <tr> <td><a href="/wiki/Molar_mass" title="Molar mass">Molar mass</a> </td> <td>97.474 g/mol    </td></tr> <tr> <td><a href="/wiki/Density" title="Density">Density</a> </td> <td>4.090 g/cm<sup>3</sup> </td></tr> <tr> <td><a href="/wiki/Melting_point" title="Melting point">Melting point</a> </td> <td>1,850 °C (3,360 °F; 2,120 K) (sublime) </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Aqueous_solution" title="Aqueous solution">Solubility in water</a></div> </td> <td>negligible </td></tr> <tr> <td><a href="/wiki/Band_gap" title="Band gap">Band gap</a> </td> <td>3.54 eV (cubic, 300 K)<br />3.91 eV (hexagonal, 300 K) </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Refractive_index" title="Refractive index">Refractive index</a> (<i>n</i><sub>D</sub>)</div> </td> <td>2.3677 </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Structure </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Crystal_structure" title="Crystal structure">Crystal structure</a></div> </td> <td><i>see text</i> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Coordination_geometry" title="Coordination geometry">Coordination geometry</a></div> </td> <td>Tetrahedral (Zn<sup>2+</sup>)<br />Tetrahedral (S<sup>2−</sup>) </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Thermochemistry </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Standard_enthalpy_change_of_formation" class="mw-redirect" title="Standard enthalpy change of formation">Std enthalpy of<br />formation</a> <span style="font-size:112%;">(Δ<sub>f</sub><i>H</i><sup>⦵</sup><sub>298</sub>)</span></div> </td> <td>−204.6 kJ/mol </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Hazards </th></tr> <tr> <td><a href="/wiki/NFPA_704" title="NFPA 704"><b>NFPA 704</b></a> (fire diamond) </td> <td><style data-mw-deduplicate="TemplateStyles:r1170367383">.mw-parser-output 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src="//upload.wikimedia.org/wikipedia/commons/thumb/6/6f/NFPA_704.svg/80px-NFPA_704.svg.png" decoding="async" width="80" height="80" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/6/6f/NFPA_704.svg/120px-NFPA_704.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/6/6f/NFPA_704.svg/160px-NFPA_704.svg.png 2x" data-file-width="512" data-file-height="512" usemap="#ImageMap_e43abf6a22fcb96c" /></span><map name="ImageMap_e43abf6a22fcb96c"><area href="/wiki/NFPA_704#Blue" shape="poly" coords="23,23,47,47,23,70,0,47" alt="Health 1: Exposure would cause irritation but only minor residual injury. E.g. turpentine" title="Health 1: Exposure would cause irritation but only minor residual injury. E.g. turpentine" /><area href="/wiki/NFPA_704#Red" shape="poly" coords="47,0,70,23,47,47,23,23" alt="Flammability 0: Will not burn. E.g. water" title="Flammability 0: Will not burn. E.g. water" /><area href="/wiki/NFPA_704#Yellow" shape="poly" coords="70,23,94,47,70,70,47,47" alt="Instability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogen" title="Instability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogen" /><area href="/wiki/NFPA_704#White" shape="poly" coords="47,47,70,70,47,94,23,70" alt="Special hazards (white): no code" title="Special hazards (white): no code" /></map><figcaption></figcaption></figure></div><div class="nfpa-704-diamond-code nfpa-704-diamond-blue"> <a href="/wiki/NFPA_704#Blue" title="NFPA 704"><span title="Health 1: Exposure would cause irritation but only minor residual injury. E.g. turpentine" class="notheme mw-no-invert">1</span></a></div><div class="nfpa-704-diamond-code nfpa-704-diamond-red"> <a href="/wiki/NFPA_704#Red" title="NFPA 704"><span title="Flammability 0: Will not burn. E.g. water" class="notheme mw-no-invert">0</span></a></div><div class="nfpa-704-diamond-code nfpa-704-diamond-yellow"> <a href="/wiki/NFPA_704#Yellow" title="NFPA 704"><span title="Instability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogen" class="notheme mw-no-invert">0</span></a></div></div></div></div> </td></tr> <tr> <td><a href="/wiki/Flash_point" title="Flash point">Flash point</a> </td> <td>Non-flammable </td></tr> <tr> <td><a href="/wiki/Safety_data_sheet" title="Safety data sheet">Safety data sheet</a> (SDS) </td> <td><a rel="nofollow" class="external text" href="http://www.inchem.org/documents/icsc/icsc/eics1627.htm">ICSC 1627</a> </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Related compounds </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">Other <a href="/wiki/Ion" title="Ion">anions</a></div> </td> <td><a href="/wiki/Zinc_oxide" title="Zinc oxide">Zinc oxide</a><br /><a href="/wiki/Zinc_selenide" title="Zinc selenide">Zinc selenide</a><br /><a href="/wiki/Zinc_telluride" title="Zinc telluride">Zinc telluride</a> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">Other <a href="/wiki/Ion" title="Ion">cations</a></div> </td> <td><a href="/wiki/Cadmium_sulfide" title="Cadmium sulfide">Cadmium sulfide</a><br /><a href="/wiki/Mercury_sulfide" title="Mercury sulfide">Mercury sulfide</a> </td></tr> <tr> <td colspan="2" style="text-align:left; background:#f8eaba; color:inherit; border:1px solid #a2a9b1;"><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">Except where otherwise noted, data are given for materials in their <a href="/wiki/Standard_state" title="Standard state">standard state</a> (at 25 °C [77 °F], 100 kPa).</div> <div style="margin-top: 0.3em;"><div style="text-align:center;"><span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/12px-Yes_check.svg.png" decoding="async" width="12" height="12" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/18px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/24px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span> <span class="reflink plainlinks nourlexpansion"><a class="external text" href="https://en.wikipedia.org/w/index.php?title=Special:ComparePages&rev1=454732423&page2=Zinc+sulfide">verify</a></span> (<a href="/wiki/Wikipedia:WikiProject_Chemicals/Chembox_validation" title="Wikipedia:WikiProject Chemicals/Chembox validation">what is</a> <sup><span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span><span typeof="mw:File"><span><img alt="☒" src="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/7px-X_mark.svg.png" decoding="async" width="7" height="8" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/11px-X_mark.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/14px-X_mark.svg.png 2x" data-file-width="525" data-file-height="600" /></span></span><span style="display:none">N</span></sup> ?) </div></div> <div style="margin-top: 0.3em; text-align: center;"><a href="/wiki/Wikipedia:Chemical_infobox#References" title="Wikipedia:Chemical infobox">Infobox references</a></div> </td></tr> </tbody></table><div class="shortdescription nomobile noexcerpt noprint searchaux" style="display:none">Chemical compound</div> <p><b>Zinc sulfide</b> (or <b>zinc sulphide</b>) is an <a href="/wiki/Inorganic_compound" title="Inorganic compound">inorganic compound</a> with the <a href="/wiki/Chemical_formula" title="Chemical formula">chemical formula</a> of ZnS. This is the main form of zinc found in nature, where it mainly occurs as the mineral <a href="/wiki/Sphalerite" title="Sphalerite">sphalerite</a>. Although this mineral is usually black because of various impurities, the pure material is white, and it is widely used as a pigment. In its dense synthetic form, zinc sulfide can be <a href="/wiki/Transparency_and_translucency" title="Transparency and translucency">transparent</a>, and it is used as a window for <a href="/wiki/Visible_light" class="mw-redirect" title="Visible light">visible optics</a> and <a href="/wiki/Infrared" title="Infrared">infrared</a> optics. </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="Structure">Structure</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc_sulfide&action=edit&section=1" title="Edit section: Structure"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <figure class="mw-default-size mw-halign-left" typeof="mw:File/Thumb"><a href="/wiki/File:Sphalerite-unit-cell-3D-balls.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/c/c0/Sphalerite-unit-cell-3D-balls.png/170px-Sphalerite-unit-cell-3D-balls.png" decoding="async" width="170" height="155" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/c/c0/Sphalerite-unit-cell-3D-balls.png/255px-Sphalerite-unit-cell-3D-balls.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/c/c0/Sphalerite-unit-cell-3D-balls.png/340px-Sphalerite-unit-cell-3D-balls.png 2x" data-file-width="1100" data-file-height="1000" /></a><figcaption>Sphalerite, the more common polymorph of zinc sulfide</figcaption></figure> <figure class="mw-default-size mw-halign-left" typeof="mw:File/Thumb"><a href="/wiki/File:Wurtzite-unit-cell-3D-balls.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/2/24/Wurtzite-unit-cell-3D-balls.png/170px-Wurtzite-unit-cell-3D-balls.png" decoding="async" width="170" height="189" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/2/24/Wurtzite-unit-cell-3D-balls.png/255px-Wurtzite-unit-cell-3D-balls.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/2/24/Wurtzite-unit-cell-3D-balls.png/340px-Wurtzite-unit-cell-3D-balls.png 2x" data-file-width="990" data-file-height="1100" /></a><figcaption>Wurtzite, the less common polymorph of zinc sulfide</figcaption></figure> <p>ZnS exists in two main <a href="/wiki/Crystalline_form" class="mw-redirect" title="Crystalline form">crystalline forms</a>. This dualism is an example of <a href="/wiki/Polymorphism_(materials_science)" class="mw-redirect" title="Polymorphism (materials science)">polymorphism</a>. In each form, the coordination geometry at Zn and S is tetrahedral. The more stable cubic form is known also as zinc blende or <a href="/wiki/Sphalerite" title="Sphalerite">sphalerite</a>. The hexagonal form is known as the mineral <a href="/wiki/Wurtzite" title="Wurtzite">wurtzite</a>, although it also can be produced synthetically.<sup id="cite_ref-Wells_2-0" class="reference"><a href="#cite_note-Wells-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> The transition from the sphalerite form to the wurtzite form occurs at around 1020 <a href="/wiki/%C2%B0C" class="mw-redirect" title="°C">°C</a>. </p> <div class="mw-heading mw-heading2"><h2 id="Applications">Applications</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc_sulfide&action=edit&section=2" title="Edit section: Applications"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="mw-heading mw-heading3"><h3 id="Luminescent_material">Luminescent material</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc_sulfide&action=edit&section=3" title="Edit section: Luminescent material"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <figure class="mw-halign-left" typeof="mw:File/Thumb"><a href="/wiki/File:ZnS_powders2.jpg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/4/46/ZnS_powders2.jpg/200px-ZnS_powders2.jpg" decoding="async" width="200" height="128" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/4/46/ZnS_powders2.jpg/300px-ZnS_powders2.jpg 1.5x, //upload.wikimedia.org/wikipedia/commons/4/46/ZnS_powders2.jpg 2x" data-file-width="343" data-file-height="219" /></a><figcaption>samples of zinc sulfide with varying <a href="/wiki/Crystal_defect" class="mw-redirect" title="Crystal defect">sulfur vacancies</a>.</figcaption></figure> <p>Zinc sulfide, with addition of a few <a href="/wiki/Parts_per_million" class="mw-redirect" title="Parts per million">ppm</a> of a suitable <a href="/wiki/Activator_(phosphor)" title="Activator (phosphor)">activator</a>, exhibits strong <a href="/wiki/Phosphorescence" title="Phosphorescence">phosphorescence</a>. The phenomenon was described by <a href="/wiki/Nikola_Tesla" title="Nikola Tesla">Nikola Tesla</a> in 1893,<sup id="cite_ref-3" class="reference"><a href="#cite_note-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> and is currently used in many applications, from <a href="/wiki/Cathode-ray_tube" title="Cathode-ray tube">cathode-ray tubes</a> through <a href="/wiki/X-ray" title="X-ray">X-ray</a> screens to <a href="/wiki/Phosphorescence" title="Phosphorescence">glow in the dark</a> products. When <a href="/wiki/Silver" title="Silver">silver</a> is used as activator, the resulting color is bright blue, with maximum at 450 <a href="/wiki/Nanometer" class="mw-redirect" title="Nanometer">nanometers</a>. Using <a href="/wiki/Manganese" title="Manganese">manganese</a> yields an orange-red color at around 590 nanometers. <a href="/wiki/Copper" title="Copper">Copper</a> gives a longer glow, and it has the familiar greenish glow-in-the-dark. Copper-doped zinc sulfide ("ZnS plus Cu") is used also in <a href="/wiki/Electroluminescence" title="Electroluminescence">electroluminescent</a> panels.<sup id="cite_ref-4" class="reference"><a href="#cite_note-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> It also exhibits <a href="/wiki/Phosphorescence" title="Phosphorescence">phosphorescence</a> due to impurities on illumination with blue or <a href="/wiki/Ultraviolet" title="Ultraviolet">ultraviolet</a> light. </p> <div class="mw-heading mw-heading3"><h3 id="Optical_material">Optical material</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc_sulfide&action=edit&section=4" title="Edit section: Optical material"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Zinc sulfide is also used as an <a href="/wiki/Infrared" title="Infrared">infrared</a> optical material, transmitting from visible <a href="/wiki/Wavelength" title="Wavelength">wavelengths</a> to just over 12 <a href="/wiki/Micrometre" title="Micrometre">micrometers</a>. It can be used planar as an <a href="/wiki/Optical_window" title="Optical window">optical window</a> or shaped into a <a href="/wiki/Lens_(optics)" class="mw-redirect" title="Lens (optics)">lens</a>. It is made as <a href="/wiki/Microcrystalline" title="Microcrystalline">microcrystalline</a> sheets by the synthesis from <a href="/wiki/Hydrogen_sulfide" title="Hydrogen sulfide">hydrogen sulfide</a> gas and zinc vapour, and this is sold as <a href="/wiki/FLIR" class="mw-redirect" title="FLIR">FLIR</a>-grade (Forward Looking Infrared), where the zinc sulfide is in a milky-yellow, opaque form. This material when <a href="/wiki/Hot_isostatic_pressing" title="Hot isostatic pressing">hot isostatically pressed</a> (HIPed) can be converted to a water-clear form known as <b>Cleartran</b> (trademark). Early commercial forms were marketed as <b>Irtran-2</b> but this designation is now obsolete. </p> <div class="mw-heading mw-heading3"><h3 id="Pigment">Pigment</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc_sulfide&action=edit&section=5" title="Edit section: Pigment"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Zinc sulfide is a common <a href="/wiki/Pigment" title="Pigment">pigment</a>, sometimes called sachtolith. When combined with barium sulfate, zinc sulfide forms <a href="/wiki/Lithopone" title="Lithopone">lithopone</a>.<sup id="cite_ref-Ullmann2_5-0" class="reference"><a href="#cite_note-Ullmann2-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="Catalyst">Catalyst</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc_sulfide&action=edit&section=6" title="Edit section: Catalyst"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Fine ZnS powder is an efficient <a href="/wiki/Photocatalyst" class="mw-redirect" title="Photocatalyst">photocatalyst</a>, which produces hydrogen gas from water upon illumination. Sulfur vacancies can be introduced in ZnS during its synthesis; this gradually turns the white-yellowish ZnS into a brown powder, and boosts the photocatalytic activity through enhanced light absorption.<sup id="cite_ref-cat_1-1" class="reference"><a href="#cite_note-cat-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="Semiconductor_properties">Semiconductor properties</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc_sulfide&action=edit&section=7" title="Edit section: Semiconductor properties"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Both sphalerite and wurtzite are intrinsic, wide-<a href="/wiki/Bandgap" class="mw-redirect" title="Bandgap">bandgap</a> <a href="/wiki/Semiconductor" title="Semiconductor">semiconductors</a>. These are prototypical <a href="/wiki/II-VI_semiconductor" class="mw-redirect" title="II-VI semiconductor">II-VI semiconductors</a>, and they adopt structures related to many of the other semiconductors, such as <a href="/wiki/Gallium_arsenide" title="Gallium arsenide">gallium arsenide</a>. The cubic form of ZnS has a <a href="/wiki/Band_gap" title="Band gap">band gap</a> of about 3.54 <a href="/wiki/Electron_volt" class="mw-redirect" title="Electron volt">electron volts</a> at 300 <a href="/wiki/Kelvin" title="Kelvin">kelvins</a>, but the hexagonal form has a band gap of about 3.91 electron volts. ZnS can be <a href="/wiki/Doping_(semiconductors)" class="mw-redirect" title="Doping (semiconductors)">doped</a> as either an <a href="/wiki/N-type_semiconductor" class="mw-redirect" title="N-type semiconductor">n-type semiconductor</a> or a <a href="/wiki/P-type_semiconductor" class="mw-redirect" title="P-type semiconductor">p-type semiconductor</a>. </p> <div class="mw-heading mw-heading2"><h2 id="History">History</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc_sulfide&action=edit&section=8" title="Edit section: History"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>The <a href="/wiki/Phosphorescence" title="Phosphorescence">phosphorescence</a> of ZnS was first reported by the French chemist <a href="/wiki/Th%C3%A9odore_Sidot" title="Théodore Sidot">Théodore Sidot</a> in 1866. His findings were presented by <a href="/wiki/A._E._Becquerel" class="mw-redirect" title="A. E. Becquerel">A. E. Becquerel</a>, who was renowned for the research on <a href="/wiki/Luminescence" title="Luminescence">luminescence</a>.<sup id="cite_ref-6" class="reference"><a href="#cite_note-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup> ZnS was used by <a href="/wiki/Ernest_Rutherford" title="Ernest Rutherford">Ernest Rutherford</a> and others in the early years of <a href="/wiki/Nuclear_physics" title="Nuclear physics">nuclear physics</a> as a <a href="/wiki/Scintillator" title="Scintillator">scintillation</a> detector, because it emits light upon excitation by <a href="/wiki/X-rays" class="mw-redirect" title="X-rays">x-rays</a> or <a href="/wiki/Electron_beam" class="mw-redirect" title="Electron beam">electron beam</a>, making it useful for X-ray screens and cathode-ray tubes.<sup id="cite_ref-G&E_7-0" class="reference"><a href="#cite_note-G&E-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup> This property made zinc sulfide useful in the <a href="/wiki/Radium_dials" class="mw-redirect" title="Radium dials">dials</a> of radium watches. </p> <div class="mw-heading mw-heading2"><h2 id="Production">Production</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc_sulfide&action=edit&section=9" title="Edit section: Production"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Zinc sulfide is usually produced from waste materials from other applications. Typical sources include smelter, slag, and pickle liquors.<sup id="cite_ref-Ullmann2_5-1" class="reference"><a href="#cite_note-Ullmann2-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> As an example, the synthesis of <a href="/wiki/Ammonia" title="Ammonia">ammonia</a> from <a href="/wiki/Methane" title="Methane">methane</a> requires <i>a priori</i> removal of <a href="/wiki/Hydrogen_sulfide" title="Hydrogen sulfide">hydrogen sulfide</a> impurities in the natural gas, for which <a href="/wiki/Zinc_oxide" title="Zinc oxide">zinc oxide</a> is used. This scavenging produces zinc sulfide: </p> <dl><dd>ZnO + H<sub>2</sub>S → ZnS + H<sub>2</sub>O</dd></dl> <div class="mw-heading mw-heading3"><h3 id="Laboratory_preparation">Laboratory preparation</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc_sulfide&action=edit&section=10" title="Edit section: Laboratory preparation"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Crude zinc sulfide can be produced by igniting a mixture of <a href="/wiki/Zinc" title="Zinc">zinc</a> and <a href="/wiki/Sulfur" title="Sulfur">sulfur</a>.<sup id="cite_ref-8" class="reference"><a href="#cite_note-8"><span class="cite-bracket">[</span>8<span class="cite-bracket">]</span></a></sup> More conventionally, ZnS is prepared by treating a mildly acidic solution of Zn<sup>2+</sup> salts with <a href="/wiki/Hydrogen_sulfide" title="Hydrogen sulfide">H<sub>2</sub>S</a>:<sup id="cite_ref-9" class="reference"><a href="#cite_note-9"><span class="cite-bracket">[</span>9<span class="cite-bracket">]</span></a></sup> </p> <dl><dd>Zn<sup>2+</sup> + S<sup>2−</sup> → ZnS</dd></dl> <p>This reaction is the basis of a <a href="/wiki/Gravimetric_analysis" title="Gravimetric analysis">gravimetric analysis</a> for zinc.<sup id="cite_ref-10" class="reference"><a href="#cite_note-10"><span class="cite-bracket">[</span>10<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="References">References</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc_sulfide&action=edit&section=11" title="Edit section: References"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <style data-mw-deduplicate="TemplateStyles:r1239543626">.mw-parser-output .reflist{margin-bottom:0.5em;list-style-type:decimal}@media screen{.mw-parser-output .reflist{font-size:90%}}.mw-parser-output .reflist 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no-repeat}body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-free a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-limited a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-registration a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-subscription a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .cs1-ws-icon a{background-size:contain;padding:0 1em 0 0}.mw-parser-output .cs1-code{color:inherit;background:inherit;border:none;padding:inherit}.mw-parser-output .cs1-hidden-error{display:none;color:var(--color-error,#d33)}.mw-parser-output .cs1-visible-error{color:var(--color-error,#d33)}.mw-parser-output .cs1-maint{display:none;color:#085;margin-left:0.3em}.mw-parser-output .cs1-kern-left{padding-left:0.2em}.mw-parser-output .cs1-kern-right{padding-right:0.2em}.mw-parser-output .citation .mw-selflink{font-weight:inherit}@media screen{.mw-parser-output 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(identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1038%2Fsrep08544">10.1038/srep08544</a>. <a href="/wiki/PMC_(identifier)" class="mw-redirect" title="PMC (identifier)">PMC</a> <span class="id-lock-free" title="Freely accessible"><a rel="nofollow" class="external text" href="https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4339798">4339798</a></span>. <a href="/wiki/PMID_(identifier)" class="mw-redirect" title="PMID (identifier)">PMID</a> <a rel="nofollow" class="external text" href="https://pubmed.ncbi.nlm.nih.gov/25712901">25712901</a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.jtitle=Scientific+Reports&rft.atitle=Synthesis+and+characterization+of+ZnS+with+controlled+amount+of+S+vacancies+for+photocatalytic+H%3Csub%3E2%3C%2Fsub%3E+production+under+visible+light&rft.volume=5&rft.pages=8544&rft.date=2015&rft_id=https%3A%2F%2Fwww.ncbi.nlm.nih.gov%2Fpmc%2Farticles%2FPMC4339798%23id-name%3DPMC&rft_id=info%3Apmid%2F25712901&rft_id=info%3Adoi%2F10.1038%2Fsrep08544&rft_id=info%3Abibcode%2F2015NatSR...5E8544W&rft.aulast=Wang&rft.aufirst=Gang&rft.au=Huang%2C+Baibiao&rft.au=Li%2C+Zhujie&rft.au=Lou%2C+Zaizhu&rft.au=Wang%2C+Zeyan&rft.au=Dai%2C+Ying&rft.au=Whangbo%2C+Myung-Hwan&rft_id=https%3A%2F%2Fwww.ncbi.nlm.nih.gov%2Fpmc%2Farticles%2FPMC4339798&rfr_id=info%3Asid%2Fen.wikipedia.org%3AZinc+sulfide" class="Z3988"></span></span> </li> <li id="cite_note-Wells-2"><span class="mw-cite-backlink"><b><a href="#cite_ref-Wells_2-0">^</a></b></span> <span class="reference-text"><link 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"Étude de la Phosphorescence du Sulfure de Zinc I. - La Méthode par Explosion". <i>Journal de Chimie Physique</i>. <b>28</b>: <span class="nowrap">277–</span>298. <a href="/wiki/Bibcode_(identifier)" class="mw-redirect" title="Bibcode (identifier)">Bibcode</a>:<a rel="nofollow" class="external text" href="https://ui.adsabs.harvard.edu/abs/1931JCP....28..277C">1931JCP....28..277C</a>. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1051%2Fjcp%2F1931280277">10.1051/jcp/1931280277</a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.jtitle=Journal+de+Chimie+Physique&rft.atitle=%C3%89tude+de+la+Phosphorescence+du+Sulfure+de+Zinc+I.+-+La+M%C3%A9thode+par+Explosion&rft.volume=28&rft.pages=%3Cspan+class%3D%22nowrap%22%3E277-%3C%2Fspan%3E298&rft.date=1931&rft_id=info%3Adoi%2F10.1051%2Fjcp%2F1931280277&rft_id=info%3Abibcode%2F1931JCP....28..277C&rft.aulast=Coustal&rft.aufirst=R.&rfr_id=info%3Asid%2Fen.wikipedia.org%3AZinc+sulfide" class="Z3988"></span></span> </li> <li id="cite_note-9"><span class="mw-cite-backlink"><b><a href="#cite_ref-9">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFF._WagenknechtR._Juza1963" class="citation book cs1 cs1-prop-long-vol">F. 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(2000), <i>Vogel's Quantitative Chemical Analysis</i> (6th ed.), New York: Prentice Hall, <a href="/wiki/ISBN_(identifier)" class="mw-redirect" title="ISBN (identifier)">ISBN</a> <a href="/wiki/Special:BookSources/0-582-22628-7" title="Special:BookSources/0-582-22628-7"><bdi>0-582-22628-7</bdi></a></cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=book&rft.btitle=Vogel%27s+Quantitative+Chemical+Analysis&rft.place=New+York&rft.edition=6th&rft.pub=Prentice+Hall&rft.date=2000&rft.isbn=0-582-22628-7&rft.au=Mendham%2C+J.&rft.au=Denney%2C+R.+C.&rft.au=Barnes%2C+J.+D.&rft.au=Thomas%2C+M.+J.+K.&rfr_id=info%3Asid%2Fen.wikipedia.org%3AZinc+sulfide" class="Z3988"></span></span> </li> </ol></div></div> <div class="mw-heading mw-heading2"><h2 id="External_links">External links</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc_sulfide&action=edit&section=12" title="Edit section: External 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href="http://www.reading.ac.uk/infrared/library/infraredmaterials/ir-infraredmaterials-zns.asp">University of Reading, Infrared Multilayer Laboratory</a> optical data</li> <li><a rel="nofollow" class="external autonumber" href="http://pubs.acs.org/doi/abs/10.1021/j150553a050">[1]</a> melting point</li></ul> <div class="navbox-styles"><style data-mw-deduplicate="TemplateStyles:r1129693374">.mw-parser-output .hlist dl,.mw-parser-output .hlist ol,.mw-parser-output .hlist ul{margin:0;padding:0}.mw-parser-output .hlist dd,.mw-parser-output .hlist dt,.mw-parser-output .hlist li{margin:0;display:inline}.mw-parser-output .hlist.inline,.mw-parser-output .hlist.inline dl,.mw-parser-output .hlist.inline ol,.mw-parser-output .hlist.inline ul,.mw-parser-output .hlist dl dl,.mw-parser-output .hlist dl ol,.mw-parser-output .hlist dl ul,.mw-parser-output .hlist ol dl,.mw-parser-output .hlist ol ol,.mw-parser-output .hlist ol ul,.mw-parser-output .hlist ul dl,.mw-parser-output .hlist ul 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aria-labelledby="Zinc_compounds33" style="padding:3px"><table class="nowraplinks mw-collapsible mw-collapsed navbox-inner" style="border-spacing:0;background:transparent;color:inherit"><tbody><tr><th scope="col" class="navbox-title" colspan="2"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1129693374"><style data-mw-deduplicate="TemplateStyles:r1239400231">.mw-parser-output .navbar{display:inline;font-size:88%;font-weight:normal}.mw-parser-output .navbar-collapse{float:left;text-align:left}.mw-parser-output .navbar-boxtext{word-spacing:0}.mw-parser-output .navbar ul{display:inline-block;white-space:nowrap;line-height:inherit}.mw-parser-output .navbar-brackets::before{margin-right:-0.125em;content:"[ "}.mw-parser-output .navbar-brackets::after{margin-left:-0.125em;content:" ]"}.mw-parser-output .navbar li{word-spacing:-0.125em}.mw-parser-output .navbar a>span,.mw-parser-output .navbar a>abbr{text-decoration:inherit}.mw-parser-output .navbar-mini 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title="Edit this template">e</abbr></a></li></ul></div><div id="Zinc_compounds33" style="font-size:114%;margin:0 4em"><a href="/wiki/Zinc_compounds" title="Zinc compounds">Zinc compounds</a></div></th></tr><tr><th scope="row" class="navbox-group" style="width:1%">Zinc(I)</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Organozinc(I)_compounds23" scope="row" class="navbox-group" style="width:1%">Organozinc(I) compounds</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Decamethyldizincocene" title="Decamethyldizincocene">Zn<sub>2</sub>(C<sub>5</sub>(CH<sub>3</sub>)<sub>5</sub>)<sub>2</sub></a></li></ul> </div></td></tr></tbody></table><div></div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">Zinc(II)</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Zinc_acetylacetonate" title="Zinc acetylacetonate">Zn(acac)<sub>2</sub></a></li> <li><a href="/wiki/Zinc_azide" title="Zinc azide">Zn(N<sub>3</sub>)<sub>2</sub></a></li> <li><a href="/wiki/Zinc_bromide" title="Zinc bromide">ZnBr<sub>2</sub></a></li> <li><a href="/wiki/Zinc_carbonate" title="Zinc carbonate">ZnCO<sub>3</sub></a></li> <li><a href="/wiki/Zinc_cyanide" title="Zinc cyanide">Zn(CN)<sub>2</sub></a></li> <li><a href="/wiki/Zinc_chloride" title="Zinc chloride">ZnCl<sub>2</sub></a></li> <li><a href="/wiki/Zinc_chlorate" title="Zinc chlorate">Zn(ClO<sub>3</sub>)<sub>2</sub></a></li> <li><a href="/wiki/Zinc_chromate" title="Zinc chromate">ZnCrO<sub>4</sub></a></li> <li><a href="/wiki/Zinc_fluoride" title="Zinc fluoride">ZnF<sub>2</sub></a></li> <li><a href="/wiki/Zinc_hydride" title="Zinc hydride">ZnH<sub>2</sub></a></li> <li><a href="/wiki/Zinc_iodide" title="Zinc iodide">ZnI<sub>2</sub></a></li> <li><a href="/wiki/Zinc_molybdate" title="Zinc molybdate">ZnMoO<sub>4</sub></a></li> <li><a href="/wiki/Zinc_nitrate" title="Zinc nitrate">Zn(NO<sub>3</sub>)<sub>2</sub></a></li> <li><a href="/wiki/Zinc_oxide" title="Zinc oxide">ZnO</a></li> <li><a href="/wiki/Zinc_peroxide" title="Zinc peroxide">ZnO<sub>2</sub></a></li> <li><a href="/wiki/Zinc_perchlorate" title="Zinc perchlorate"><span class="chemf nowrap">Zn(ClO<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">4</sub></span></span>)<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">2</sub></span></span></span></a></li> <li><a href="/wiki/Zinc_hydroxide" title="Zinc hydroxide">Zn(OH)<sub>2</sub></a></li> <li><a class="mw-selflink selflink">ZnS</a></li> <li><a href="/wiki/Zinc_sulfate" title="Zinc sulfate">ZnSO<sub>4</sub></a></li> <li><a href="/wiki/Zinc_selenide" title="Zinc selenide">ZnSe</a></li> <li><a href="/wiki/Zinc_telluride" title="Zinc telluride">ZnTe</a></li> <li><a href="/wiki/Zinc_pyrophosphate" title="Zinc pyrophosphate">Zn<sub>2</sub>P<sub>2</sub>O<sub>7</sub></a></li> <li><a href="/wiki/Zinc_antimonide" title="Zinc antimonide">Zn<sub>3</sub>Sb<sub>2</sub></a></li> <li><a href="/wiki/Zinc_arsenide" title="Zinc arsenide">Zn<sub>3</sub>As<sub>2</sub></a></li> <li><a href="/wiki/Zinc_nitride" title="Zinc nitride">Zn<sub>3</sub>N<sub>2</sub></a></li> <li><a href="/wiki/Zinc_phosphide" title="Zinc phosphide">Zn<sub>3</sub>P<sub>2</sub></a></li> <li><a href="/wiki/Zinc_diphosphide" title="Zinc diphosphide">ZnP<sub>2</sub></a></li> <li><a href="/wiki/Zinc_phosphate" title="Zinc phosphate">Zn<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub></a></li></ul></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Organozinc(II)_compounds24" scope="row" class="navbox-group" style="width:1%">Organozinc(II) compounds</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <li><a href="/wiki/Dimethylzinc" title="Dimethylzinc">Zn(CH<sub>3</sub>)<sub>2</sub></a></li> <li><a href="/wiki/Diethylzinc" title="Diethylzinc">Zn(C<sub>2</sub>H<sub>5</sub>)<sub>2</sub></a></li> <li><a href="/wiki/Zinc_acetate" title="Zinc acetate">Zn(CH<sub>3</sub>COO)<sub>2</sub></a></li> <li><a href="/wiki/Diisopropylzinc" title="Diisopropylzinc">Zn(CH(CH<sub>3</sub>)<sub>2</sub>)<sub>2</sub></a></li> <li><a href="/wiki/Di-tert-butylzinc" title="Di-tert-butylzinc">Zn(C(CH<sub>3</sub>)<sub>3</sub>)<sub>2</sub></a></li> <li><a href="/wiki/Diphenylzinc" title="Diphenylzinc">Zn(C<sub>6</sub>H<sub>5</sub>)<sub>2</sub></a></li> <li><a href="/wiki/Zinc_lactate" title="Zinc lactate">Zn(C<sub>3</sub>H<sub>5</sub>O<sub>3</sub>)<sub>2</sub></a></li> <li><a href="/wiki/Iodomethylzinc_iodide" title="Iodomethylzinc iodide">ZnICH<sub>2</sub>I</a></li> </div></td></tr></tbody></table><div> <ul><li><a href="/wiki/Zinc_laurate" title="Zinc laurate"><span class="chemf nowrap">C<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">24</sub></span></span>H<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">46</sub></span></span>ZnO<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">4</sub></span></span></span></a></li></ul> </div></td></tr></tbody></table></div> <div class="navbox-styles"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1129693374"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1236075235"><style data-mw-deduplicate="TemplateStyles:r886047488">.mw-parser-output .nobold{font-weight:normal}</style></div><div role="navigation" class="navbox" aria-labelledby="Sulfides_(S2−)173" style="display:table;;padding:3px"><table class="nowraplinks mw-collapsible autocollapse navbox-inner" style="border-spacing:0;background:transparent;color:inherit;table-layout:fixed;"><tbody><tr><th scope="col" class="navbox-title" colspan="2"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1129693374"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1239400231"><div class="navbar plainlinks hlist navbar-mini"><ul><li class="nv-view"><a href="/wiki/Template:Sulfides" title="Template:Sulfides"><abbr title="View this template">v</abbr></a></li><li class="nv-talk"><a href="/wiki/Template_talk:Sulfides" title="Template talk:Sulfides"><abbr title="Discuss this template">t</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:EditPage/Template:Sulfides" title="Special:EditPage/Template:Sulfides"><abbr title="Edit this template">e</abbr></a></li></ul></div><div id="Sulfides_(S2−)173" style="font-size:114%;margin:0 4em"><a href="/wiki/Sulfide" title="Sulfide">Sulfides</a> <span class="nobold">(S<sup>2−</sup>)</span></div></th></tr><tr><td colspan="2" class="navbox-list navbox-odd" style="width:100%;padding:0;border-width:0;"><div style="padding:0"><div class="mw-collapsible-content" style="overflow-x:auto"> <table class="center"> <tbody><tr style="background-color:mistyrose"> <td><a href="/wiki/Hydrogen_sulfide" title="Hydrogen sulfide">H<sub>2</sub>S</a> </td> <td style="background-color:white;color:inherit;border:none"> </td> <td style="background-color:white;color:inherit;border:none" colspan="11" rowspan="3"> </td> <td style="background-color:white;color:inherit;border:none" colspan="5"> </td> <td>He </td></tr> <tr style="background-color:mistyrose;color:black;"> <td><a href="/wiki/Lithium_sulfide" title="Lithium sulfide">Li<sub>2</sub>S</a> </td> <td><a href="/wiki/Beryllium_sulfide" title="Beryllium sulfide">BeS</a> </td> <td><a href="/wiki/Boron_sulfide" title="Boron sulfide">B<sub>2</sub>S<sub>3</sub></a><br /><a href="/wiki/Borate_sulfide" title="Borate sulfide">+BO<sub>3</sub></a> </td> <td><a href="/wiki/Carbon_disulfide" title="Carbon disulfide">CS<sub>2</sub></a><br /><a href="/wiki/Carbonyl_sulfide" title="Carbonyl sulfide">COS</a> </td> <td><a href="/wiki/Ammonium_hydrosulfide" title="Ammonium hydrosulfide">(NH<sub>4</sub>)SH</a> </td> <td>O </td> <td>F </td> <td>Ne </td></tr> <tr style="background-color:mistyrose;color:black;"> <td><a href="/wiki/Sodium_sulfide" title="Sodium sulfide">Na<sub>2</sub>S</a> </td> <td><a href="/wiki/Magnesium_sulfide" title="Magnesium sulfide">MgS</a> </td> <td><a href="/wiki/Aluminium_sulfide" title="Aluminium sulfide">Al<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Silicon_monosulfide" title="Silicon monosulfide">SiS</a><br /><a href="/wiki/Silicon_disulfide" title="Silicon disulfide">SiS<sub>2</sub></a><br /><a href="/wiki/Thiosilicate" title="Thiosilicate">-Si</a> </td> <td><a href="/wiki/Phosphorus_sulfide" class="mw-redirect" title="Phosphorus sulfide">P<sub><span class="texhtml mvar" style="font-style:italic;">x</span></sub>S<sub><span class="texhtml mvar" style="font-style:italic;">y</span></sub></a><br /><a href="/wiki/Thiophosphate" title="Thiophosphate">-P</a> </td> <td><a href="/wiki/Disulfides" class="mw-redirect" title="Disulfides">-S<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1.2em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline">2−</sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">2</sub></span></span></a> </td> <td>Cl </td> <td>Ar </td></tr> <tr style="background-color:mistyrose;color:black;"> <td><a href="/wiki/Potassium_sulfide" title="Potassium sulfide">K<sub>2</sub>S</a> </td> <td><a href="/wiki/Calcium_sulfide" title="Calcium sulfide">CaS</a> </td> <td style="background-color:white;color:inherit;border:none"> </td> <td><a href="/wiki/Scandium_monosulfide" title="Scandium monosulfide">ScS</a><br /><a href="/wiki/Scandium(III)_sulfide" title="Scandium(III) sulfide">Sc<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Titanium(II)_sulfide" title="Titanium(II) sulfide">TiS</a><br /><a href="/wiki/Titanium_disulfide" title="Titanium disulfide">TiS<sub>2</sub></a><br /><a href="/wiki/Titanium(III)_sulfide" title="Titanium(III) sulfide">Ti<sub>2</sub>S<sub>3</sub></a><br /><a href="/wiki/Titanium_trisulfide" title="Titanium trisulfide">TiS<sub>3</sub></a> </td> <td><a href="/w/index.php?title=Vanadium_monosulfide&action=edit&redlink=1" class="new" title="Vanadium monosulfide (page does not exist)">VS</a><br /><a href="/w/index.php?title=Vanadium_disulfide&action=edit&redlink=1" class="new" title="Vanadium disulfide (page does not exist)">VS<sub>2</sub></a><br /><a href="/w/index.php?title=Divanadium_trisulfide&action=edit&redlink=1" class="new" title="Divanadium trisulfide (page does not exist)">V<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Chromium(II)_sulfide" title="Chromium(II) sulfide">CrS</a><br /><a href="/wiki/Chromium(III)_sulfide" title="Chromium(III) sulfide">Cr<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Manganese(II)_sulfide" title="Manganese(II) sulfide">MnS</a><br /><a href="/wiki/Manganese_disulfide" title="Manganese disulfide">MnS<sub>2</sub></a> </td> <td><a href="/wiki/Iron(II)_sulfide" title="Iron(II) sulfide">FeS</a><br /><a href="/wiki/Iron(II,III)_sulfide" title="Iron(II,III) sulfide">Fe<sub>3</sub>S<sub>4</sub></a> </td> <td><a href="/wiki/Cobalt_sulfide" title="Cobalt sulfide">Co<sub><span class="texhtml mvar" style="font-style:italic;">x</span></sub>S<sub><span class="texhtml mvar" style="font-style:italic;">y</span></sub></a> </td> <td><a href="/wiki/Nickel_sulfide" title="Nickel sulfide">Ni<sub><span class="texhtml mvar" style="font-style:italic;">x</span></sub>S<sub><span class="texhtml mvar" style="font-style:italic;">y</span></sub></a> </td> <td><a href="/wiki/Copper(I)_sulfide" title="Copper(I) sulfide">Cu<sub>2</sub>S</a><br /><a href="/wiki/Copper_monosulfide" title="Copper monosulfide">CuS</a> </td> <td><a class="mw-selflink selflink">ZnS</a> </td> <td><a href="/wiki/Gallium(II)_sulfide" title="Gallium(II) sulfide">GaS</a><br /><a href="/wiki/Gallium(III)_sulfide" title="Gallium(III) sulfide">Ga<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Germanium(II)_sulfide" class="mw-redirect" title="Germanium(II) sulfide">GeS</a><br /><a href="/wiki/Germanium(IV)_sulfide" class="mw-redirect" title="Germanium(IV) sulfide">GeS<sub>2</sub></a><br /><a href="/wiki/Thiogermanate" title="Thiogermanate">-Ge</a> </td> <td><a href="/wiki/Arsenic_trisulfide" title="Arsenic trisulfide">As<sub>2</sub>S<sub>3</sub></a><br /><a href="/wiki/Tetraarsenic_trisulfide" class="mw-redirect" title="Tetraarsenic trisulfide">As<sub>4</sub>S<sub>3</sub></a><br /><a href="/wiki/Trithioarsenite" title="Trithioarsenite">-As</a> </td> <td><a href="/wiki/Selenium_disulfide" title="Selenium disulfide">SeS<sub>2</sub></a><br /><a href="/wiki/Sulfoselenide" class="mw-redirect" title="Sulfoselenide">+Se</a> </td> <td>Br </td> <td>Kr </td></tr> <tr style="background-color:mistyrose;color:black;"> <td><a href="/wiki/Rubidium_sulfide" title="Rubidium sulfide">Rb<sub>2</sub>S<sub></sub></a> </td> <td><a href="/wiki/Strontium_sulfide" title="Strontium sulfide">SrS</a> </td> <td style="background-color:white;color:inherit;border:none"> </td> <td><a href="/wiki/Yttrium_sulfide" class="mw-redirect" title="Yttrium sulfide">Y<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Zirconium_disulfide" title="Zirconium disulfide">ZrS<sub>2</sub></a> </td> <td><a href="/wiki/Niobium_disulfide" title="Niobium disulfide">NbS<sub>2</sub></a> </td> <td><a href="/wiki/Molybdenum_disulfide" title="Molybdenum disulfide">MoS<sub>2</sub></a><br /><a href="/wiki/Molybdenum_trisulfide" title="Molybdenum trisulfide">MoS<sub>3</sub></a> </td> <td><a href="/wiki/Technetium_disulphide" class="mw-redirect" title="Technetium disulphide"><style data-mw-deduplicate="TemplateStyles:r1123817410">'"`UNIQ--templatestyles-00000041-QINU`"'</style><span class="chemf nowrap">TcS<sub class="template-chem2-sub">2</sub></span></a><br /><a href="/wiki/Technetium(VII)_sulfide" title="Technetium(VII) sulfide"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">Tc<sub class="template-chem2-sub">2</sub>S<sub class="template-chem2-sub">7</sub></span></a> </td> <td>Ru </td> <td><a href="/wiki/Rhodium(III)_sulfide" title="Rhodium(III) sulfide">Rh<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Palladium(II)_sulfide" title="Palladium(II) sulfide">PdS</a> </td> <td><a href="/wiki/Silver_sulfide" title="Silver sulfide">Ag<sub>2</sub>S</a> </td> <td><a href="/wiki/Cadmium_sulfide" title="Cadmium sulfide">CdS</a> </td> <td><a href="/wiki/Indium_sulfide" class="mw-redirect" title="Indium sulfide">In<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Tin(II)_sulfide" title="Tin(II) sulfide">SnS</a><br /><a href="/wiki/Tin(IV)_sulfide" title="Tin(IV) sulfide">SnS<sub>2</sub></a><br /><a href="/wiki/Thiostannate" title="Thiostannate">-Sn</a> </td> <td><a href="/wiki/Antimony_trisulfide" title="Antimony trisulfide">Sb<sub>2</sub>S<sub>3</sub></a><br /><a href="/wiki/Antimony_pentasulfide" title="Antimony pentasulfide">Sb<sub>2</sub>S<sub>5</sub></a><br /><a href="/wiki/Thioantimonate" class="mw-redirect" title="Thioantimonate">-Sb</a> </td> <td><a href="/w/index.php?title=Tellurium_disulfide&action=edit&redlink=1" class="new" title="Tellurium disulfide (page does not exist)">TeS<sub>2</sub></a> </td> <td>I </td> <td>Xe </td></tr> <tr style="background-color:mistyrose;color:black;"> <td><a href="/wiki/Cesium_sulfide" class="mw-redirect" title="Cesium sulfide">Cs<sub>2</sub>S</a> </td> <td><a href="/wiki/Barium_sulfide" title="Barium sulfide">BaS</a> </td> <td style="background-color:white;color:inherit;border:none">* </td> <td><a href="/w/index.php?title=Lutetium_monosulfide&action=edit&redlink=1" class="new" title="Lutetium monosulfide (page does not exist)">LuS</a><br /><a href="/w/index.php?title=Lutetium(III)_sulfide&action=edit&redlink=1" class="new" title="Lutetium(III) sulfide (page does not exist)">Lu<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Hafnium_disulfide" title="Hafnium disulfide">HfS<sub>2</sub></a> </td> <td><a href="/wiki/Tantalum(IV)_sulfide" title="Tantalum(IV) sulfide">TaS<sub>2</sub></a> </td> <td><a href="/wiki/Tungsten_disulfide" title="Tungsten disulfide">WS<sub>2</sub></a><br /><a href="/wiki/Tungsten_trisulfide" title="Tungsten trisulfide">WS<sub>3</sub></a> </td> <td><a href="/wiki/Rhenium_disulfide" title="Rhenium disulfide">ReS<sub>2</sub></a><br /><a href="/wiki/Rhenium(VII)_sulfide" title="Rhenium(VII) sulfide">Re<sub>2</sub>S<sub>7</sub></a> </td> <td><a href="/wiki/Osmium_tetrasulfide" title="Osmium tetrasulfide"><span class="chemf nowrap">OsS<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">4</sub></span></span></span></a> </td> <td><a href="/wiki/Iridium(III)_sulfide" title="Iridium(III) sulfide">Ir<sub>2</sub>S<sub>3</sub></a><br /><a href="/wiki/Iridium_disulfide" title="Iridium disulfide">IrS<sub>2</sub></a> </td> <td><a href="/wiki/Platinum(II)_sulfide" title="Platinum(II) sulfide">PtS</a><br /><a href="/wiki/Platinum_disulfide" title="Platinum disulfide">PtS<sub>2</sub></a> </td> <td><a href="/wiki/Gold(I)_sulfide" title="Gold(I) sulfide">Au<sub>2</sub>S</a><br /><a href="/wiki/Gold(III)_sulfide" title="Gold(III) sulfide">Au<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Mercury_sulfide" title="Mercury sulfide">HgS</a> </td> <td><a href="/wiki/Thallium_sulfide" class="mw-redirect" title="Thallium sulfide">Tl<sub>2</sub>S</a> </td> <td><a href="/wiki/Lead(II)_sulfide" title="Lead(II) sulfide">PbS</a><br /><a href="/wiki/Lead(IV)_sulfide" title="Lead(IV) sulfide">PbS<sub>2</sub></a> </td> <td><a href="/wiki/Bismuth_sulfide" class="mw-redirect" title="Bismuth sulfide">Bi<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Polonium_sulfide" title="Polonium sulfide">PoS</a> </td> <td>At </td> <td>Rn </td></tr> <tr style="background-color:mistyrose;color:black;"> <td>Fr </td> <td>Ra </td> <td style="background-color:white;color:inherit;border:none">** </td> <td>Lr </td> <td>Rf </td> <td>Db </td> <td>Sg </td> <td>Bh </td> <td>Hs </td> <td>Mt </td> <td>Ds </td> <td>Rg </td> <td>Cn </td> <td>Nh </td> <td>Fl </td> <td>Mc </td> <td>Lv </td> <td>Ts </td> <td>Og </td></tr> <tr> <td style="background-color:white;color:inherit;border:none" colspan="2" rowspan="3"> </td> <td style="background-color:white;color:inherit;border:none" colspan="20">  </td></tr> <tr style="background-color:mistyrose;color:black;"> <td style="background-color:white;color:inherit;border:none">* </td> <td><a href="/wiki/Lanthanum_monosulfide" title="Lanthanum monosulfide">LaS</a><br /><a href="/wiki/Lanthanum(III)_sulfide" title="Lanthanum(III) sulfide">La<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Cerium_monosulfide" title="Cerium monosulfide">CeS</a><br /><a href="/wiki/Cerium(III)_sulfide" title="Cerium(III) sulfide">Ce<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Praseodymium_monosulfide" title="Praseodymium monosulfide">PrS</a><br /><a href="/wiki/Praseodymium(III)_sulfide" title="Praseodymium(III) sulfide">Pr<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Neodymium_monosulfide" title="Neodymium monosulfide">NdS</a><br /><a href="/wiki/Neodymium(III)_sulfide" title="Neodymium(III) sulfide">Nd<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Promethium_monosulfide" title="Promethium monosulfide">PmS</a><br /><a href="/wiki/Promethium(III)_sulfide" title="Promethium(III) sulfide">Pm<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Samarium_monosulfide" title="Samarium monosulfide">SmS</a><br /><a href="/wiki/Samarium(III)_sulfide" title="Samarium(III) sulfide">Sm<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Europium(II)_sulfide" title="Europium(II) sulfide">EuS</a><br /><a href="/w/index.php?title=Europium(III)_sulfide&action=edit&redlink=1" class="new" title="Europium(III) sulfide (page does not exist)">Eu<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Gadolinium_monosulfide" title="Gadolinium monosulfide">GdS</a><br /><a href="/w/index.php?title=Gadolinium(III)_sulfide&action=edit&redlink=1" class="new" title="Gadolinium(III) sulfide (page does not exist)">Gd<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Terbium_monosulfide" title="Terbium monosulfide">TbS</a><br /><a href="/w/index.php?title=Terbium(III)_sulfide&action=edit&redlink=1" class="new" title="Terbium(III) sulfide (page does not exist)">Tb<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Dysprosium_monosulfide" title="Dysprosium monosulfide">DyS</a><br /><a href="/wiki/Dysprosium(III)_sulfide" title="Dysprosium(III) sulfide">Dy<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Holmium_monosulfide" title="Holmium monosulfide">HoS</a><br /><a href="/wiki/Holmium(III)_sulfide" title="Holmium(III) sulfide">Ho<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/w/index.php?title=Erbium_monosulfide&action=edit&redlink=1" class="new" title="Erbium monosulfide (page does not exist)">ErS</a><br /><a href="/w/index.php?title=Erbium(III)_sulfide&action=edit&redlink=1" class="new" title="Erbium(III) sulfide (page does not exist)">Er<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/w/index.php?title=Thulium_monosulfide&action=edit&redlink=1" class="new" title="Thulium monosulfide (page does not exist)">TmS</a><br /><a href="/w/index.php?title=Thulium(III)_sulfide&action=edit&redlink=1" class="new" title="Thulium(III) sulfide (page does not exist)">Tm<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Ytterbium(II)_sulfide" title="Ytterbium(II) sulfide">YbS</a><br /><a href="/wiki/Ytterbium(III)_sulfide" title="Ytterbium(III) sulfide">Yb<sub>2</sub>S<sub>3</sub></a> </td></tr> <tr style="background-color:mistyrose;color:black;"> <td style="background-color:white;color:inherit;border:none">** </td> <td><a href="/wiki/Actinium(III)_sulfide" title="Actinium(III) sulfide">Ac<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/Thorium(IV)_sulfide" title="Thorium(IV) sulfide">ThS<sub>2</sub></a> </td> <td>Pa </td> <td><a href="/wiki/Uranium_monosulfide" title="Uranium monosulfide">US</a><br /><a href="/wiki/Uranium_disulfide" title="Uranium disulfide">US<sub>2</sub></a> </td> <td>Np </td> <td>Pu </td> <td>Am </td> <td>Cm </td> <td>Bk </td> <td>Cf </td> <td>Es </td> <td>Fm </td> <td>Md </td> <td>No </td></tr></tbody></table></div> </div></td></tr></tbody></table></div> <div class="navbox-styles"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1129693374"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1236075235"><style data-mw-deduplicate="TemplateStyles:r1038841319">.mw-parser-output .tooltip-dotted{border-bottom:1px dotted;cursor:help}</style><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1038841319"><link rel="mw-deduplicated-inline-style" 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