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We have used supramolecular chemistry... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_25860245" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">In this paper, we present a summary of our work on highly photostable supramolecular ruthenium complexes, which may be incorporated into more complex systems for artificial solar energy conversion. We have used supramolecular chemistry and photochemistry to synthesize highly photostable ruthenium bipyridine cnronates and a bipyridazine podate complex and to enhance photoelectron-transfer reactions in physical model systems for artificial photosynthesis.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/25860245" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="68310c06ecbf48c5938a0a845eaaf533" rel="nofollow" data-download="{"attachment_id":46227196,"asset_id":25860245,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/46227196/download_file?st=MTc0MDk5NDU4OSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="49647142" href="https://ksu.academia.edu/SBossmann">S. 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We have used supramolecular chemistry and photochemistry to synthesize highly photostable ruthenium bipyridine cnronates and a bipyridazine podate complex and to enhance photoelectron-transfer reactions in physical model systems for artificial photosynthesis.","downloadable_attachments":[{"id":46227196,"asset_id":25860245,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":49647142,"first_name":"S.","last_name":"Bossmann","domain_name":"ksu","page_name":"SBossmann","display_name":"S. 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Transfer","url":"https://www.academia.edu/Documents/in/Electron_Transfer?f_ri=4493"},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=4493"},{"id":875506,"name":"Physical Model","url":"https://www.academia.edu/Documents/in/Physical_Model?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_70559737" data-work_id="70559737" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/70559737/2_3H_Pyrrolone_A_Biologically_Active_Scaffold_A_Review_">2(3H)Pyrrolone – A Biologically Active Scaffold (A Review)</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest">Pyrrolones are the five-membered heterocyclic lactams which are either D 3 (1) or D 4 (2) derivatives described by several authors 1,2 .</div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/70559737" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="45fd955ebf881a16d35969256e5ff571" rel="nofollow" data-download="{"attachment_id":80261518,"asset_id":70559737,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" 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class="summarized">Hydrogenation of vegetable oils is a heterogeneous process where the process factors influence the conversion and selectivity. A Statistical study was performed on a sunflower oil (SFO) hydrogenation process using Pd-B/g-Al 2 O 3 catalyst... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_60167615" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Hydrogenation of vegetable oils is a heterogeneous process where the process factors influence the conversion and selectivity. A Statistical study was performed on a sunflower oil (SFO) hydrogenation process using Pd-B/g-Al 2 O 3 catalyst to study the effect of the process factors, including temperature, hydrogen pressure, agitation, catalyst dose and reaction time on the iodine value and trans fatty acid content of hydrogenated SFO. It was found that each factor has a noticeable effect on the iodine value and trans fatty acid content of hydrogenated SFO. The study was also aimed to find out the optimum values for the hydrogenation factors which are capable to decline the IV to 70 (g iodine per 100 g oil) as well as produce a minimum trans fatty acid content of the hydrogenated SFO. The optimum values were found to be 431 K, 1000 kPa, 1000 kPa, 0.29 % and 42.2 min for the temperature, hydrogen pressure, agitation, catalyst dose and reaction time respectively.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/60167615" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="912e20b29e98ff86ade47fcd49dd391f" rel="nofollow" data-download="{"attachment_id":73728412,"asset_id":60167615,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/73728412/download_file?st=MTc0MDk5NDU4OSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="47317409" href="https://independent.academia.edu/ZahiraYaakob">Zahira Yaakob</a><script data-card-contents-for-user="47317409" type="text/json">{"id":47317409,"first_name":"Zahira","last_name":"Yaakob","domain_name":"independent","page_name":"ZahiraYaakob","display_name":"Zahira Yaakob","profile_url":"https://independent.academia.edu/ZahiraYaakob?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_60167615 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="60167615"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 60167615, container: ".js-paper-rank-work_60167615", }); 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A Statistical study was performed on a sunflower oil (SFO) hydrogenation process using Pd-B/g-Al 2 O 3 catalyst to study the effect of the process factors, including temperature, hydrogen pressure, agitation, catalyst dose and reaction time on the iodine value and trans fatty acid content of hydrogenated SFO. It was found that each factor has a noticeable effect on the iodine value and trans fatty acid content of hydrogenated SFO. The study was also aimed to find out the optimum values for the hydrogenation factors which are capable to decline the IV to 70 (g iodine per 100 g oil) as well as produce a minimum trans fatty acid content of the hydrogenated SFO. The optimum values were found to be 431 K, 1000 kPa, 1000 kPa, 0.29 % and 42.2 min for the temperature, hydrogen pressure, agitation, catalyst dose and reaction time respectively.","downloadable_attachments":[{"id":73728412,"asset_id":60167615,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":47317409,"first_name":"Zahira","last_name":"Yaakob","domain_name":"independent","page_name":"ZahiraYaakob","display_name":"Zahira Yaakob","profile_url":"https://independent.academia.edu/ZahiraYaakob?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":530,"name":"Inorganic Chemistry","url":"https://www.academia.edu/Documents/in/Inorganic_Chemistry?f_ri=4493","nofollow":true},{"id":531,"name":"Organic Chemistry","url":"https://www.academia.edu/Documents/in/Organic_Chemistry?f_ri=4493","nofollow":true},{"id":532,"name":"Physical Chemistry","url":"https://www.academia.edu/Documents/in/Physical_Chemistry?f_ri=4493","nofollow":true},{"id":533,"name":"Theoretical Chemistry","url":"https://www.academia.edu/Documents/in/Theoretical_Chemistry?f_ri=4493","nofollow":true},{"id":2375,"name":"Medicinal Chemistry","url":"https://www.academia.edu/Documents/in/Medicinal_Chemistry?f_ri=4493"},{"id":2526,"name":"Polymer Chemistry","url":"https://www.academia.edu/Documents/in/Polymer_Chemistry?f_ri=4493"},{"id":3339,"name":"Radiation Chemistry","url":"https://www.academia.edu/Documents/in/Radiation_Chemistry?f_ri=4493"},{"id":3408,"name":"Green Chemistry","url":"https://www.academia.edu/Documents/in/Green_Chemistry?f_ri=4493"},{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493"},{"id":15368,"name":"Soil Chemistry","url":"https://www.academia.edu/Documents/in/Soil_Chemistry?f_ri=4493"},{"id":16137,"name":"Food Chemistry","url":"https://www.academia.edu/Documents/in/Food_Chemistry?f_ri=4493"},{"id":26931,"name":"Nuclear Chemistry","url":"https://www.academia.edu/Documents/in/Nuclear_Chemistry?f_ri=4493"},{"id":116394,"name":"Industrial chemistry","url":"https://www.academia.edu/Documents/in/Industrial_chemistry?f_ri=4493"},{"id":213373,"name":"Petrochemicals","url":"https://www.academia.edu/Documents/in/Petrochemicals?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_1499410" data-work_id="1499410" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/1499410/Gold_Nanoparticles_Assembly_Supramolecular_Chemistry_Quantum_Size_Related_Properties_and_Applications_toward_Biology_Catalysis_and_Nanotechnology">Gold Nanoparticles: Assembly, Supramolecular Chemistry, Quantum-Size-Related Properties, and Applications toward Biology, Catalysis, and Nanotechnology</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Figure 10. UV-vis spectra (A) and TEM images and size distributions (B) of (a) [AuCl 4 ]before reduction; dodecanethiol-AuNPs (b) as prepared and after heat treatment at (c) 150, (d) 190, and (e) 230°C; and (f) octadecanethiol-AuNPs... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_1499410" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Figure 10. UV-vis spectra (A) and TEM images and size distributions (B) of (a) [AuCl 4 ]before reduction; dodecanethiol-AuNPs (b) as prepared and after heat treatment at (c) 150, (d) 190, and (e) 230°C; and (f) octadecanethiol-AuNPs heat-treated at 250°C. Reprinted with permission from ref 188b (Miyake's group).</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/1499410" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="0d1a6a54c83e01bac3c2023623d6da4e" rel="nofollow" data-download="{"attachment_id":50948002,"asset_id":1499410,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/50948002/download_file?st=MTc0MDk5NDU4OSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="1245421" href="https://independent.academia.edu/KalpanaHari">Kalpana Hari</a><script data-card-contents-for-user="1245421" type="text/json">{"id":1245421,"first_name":"Kalpana","last_name":"Hari","domain_name":"independent","page_name":"KalpanaHari","display_name":"Kalpana Hari","profile_url":"https://independent.academia.edu/KalpanaHari?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_1499410 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="1499410"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 1499410, container: ".js-paper-rank-work_1499410", }); 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UV-vis spectra (A) and TEM images and size distributions (B) of (a) [AuCl 4 ]before reduction; dodecanethiol-AuNPs (b) as prepared and after heat treatment at (c) 150, (d) 190, and (e) 230°C; and (f) octadecanethiol-AuNPs heat-treated at 250°C. Reprinted with permission from ref 188b (Miyake's group).","downloadable_attachments":[{"id":50948002,"asset_id":1499410,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":1245421,"first_name":"Kalpana","last_name":"Hari","domain_name":"independent","page_name":"KalpanaHari","display_name":"Kalpana Hari","profile_url":"https://independent.academia.edu/KalpanaHari?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":4749,"name":"Catalysis","url":"https://www.academia.edu/Documents/in/Catalysis?f_ri=4493","nofollow":true},{"id":17733,"name":"Nanotechnology","url":"https://www.academia.edu/Documents/in/Nanotechnology?f_ri=4493","nofollow":true},{"id":65698,"name":"Gold nanoparticle","url":"https://www.academia.edu/Documents/in/Gold_nanoparticle?f_ri=4493","nofollow":true},{"id":76736,"name":"Gold","url":"https://www.academia.edu/Documents/in/Gold?f_ri=4493"},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=4493"},{"id":390245,"name":"Particle Size","url":"https://www.academia.edu/Documents/in/Particle_Size?f_ri=4493"},{"id":794074,"name":"Microspheres","url":"https://www.academia.edu/Documents/in/Microspheres?f_ri=4493"},{"id":809882,"name":"Base Sequence","url":"https://www.academia.edu/Documents/in/Base_Sequence?f_ri=4493"},{"id":1256747,"name":"Oxidation-Reduction","url":"https://www.academia.edu/Documents/in/Oxidation-Reduction?f_ri=4493"},{"id":1412233,"name":"Biosensing Techniques","url":"https://www.academia.edu/Documents/in/Biosensing_Techniques?f_ri=4493"},{"id":1575801,"name":"DNA probes","url":"https://www.academia.edu/Documents/in/DNA_probes?f_ri=4493"},{"id":2467566,"name":"Molecular Sequence Data","url":"https://www.academia.edu/Documents/in/Molecular_Sequence_Data?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_4324642" data-work_id="4324642" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/4324642/Stability_Constants_of_Some_Macrocyclic_Complexes_of_Ag_I_and_Cu_II_in_Mixed_Solvents_by_Potentiometry">Stability Constants of Some Macrocyclic Complexes of Ag(I) and Cu(II) in Mixed Solvents by Potentiometry</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Stability constants of complexes of Ag(I) and Cu(II) perchlorates and nitrates with some macrocyclic compounds in 90 and 75% (v/v) DMSO 1 water and 75% (v/v) DMF 1 water media have been determined by potentiometry. Silver and copper... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_4324642" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Stability constants of complexes of Ag(I) and Cu(II) perchlorates and nitrates with some macrocyclic compounds in 90 and 75% (v/v) DMSO 1 water and 75% (v/v) DMF 1 water media have been determined by potentiometry. Silver and copper wires, and Coated Wire Ion Selective Electrodes (CWISE) were used as indicator electrodes. It was observed that complexation is stronger when the salt is present as a perchlorate than when it is as a nitrate. For both cations the stability constant values in 75% (v/v) DMF 1 water were somewhat higher than in 75% (v/v) DMSO. The macrocyclic effect due to cyclization of linear amine tosylates has been observed. Competitive potentiometry has been utilized to compare some of the results.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/4324642" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="9b6a1753c9b2a0d2db79568c183b22be" rel="nofollow" data-download="{"attachment_id":49937289,"asset_id":4324642,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/49937289/download_file?st=MTc0MDk5NDU4OSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="5270515" href="https://independent.academia.edu/VijaykumarIjeri">Vijaykumar Ijeri</a><script data-card-contents-for-user="5270515" type="text/json">{"id":5270515,"first_name":"Vijaykumar","last_name":"Ijeri","domain_name":"independent","page_name":"VijaykumarIjeri","display_name":"Vijaykumar Ijeri","profile_url":"https://independent.academia.edu/VijaykumarIjeri?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_4324642 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="4324642"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 4324642, container: ".js-paper-rank-work_4324642", }); 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Silver and copper wires, and Coated Wire Ion Selective Electrodes (CWISE) were used as indicator electrodes. It was observed that complexation is stronger when the salt is present as a perchlorate than when it is as a nitrate. For both cations the stability constant values in 75% (v/v) DMF 1 water were somewhat higher than in 75% (v/v) DMSO. The macrocyclic effect due to cyclization of linear amine tosylates has been observed. Competitive potentiometry has been utilized to compare some of the results.","downloadable_attachments":[{"id":49937289,"asset_id":4324642,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":5270515,"first_name":"Vijaykumar","last_name":"Ijeri","domain_name":"independent","page_name":"VijaykumarIjeri","display_name":"Vijaykumar Ijeri","profile_url":"https://independent.academia.edu/VijaykumarIjeri?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":80692,"name":"Copper","url":"https://www.academia.edu/Documents/in/Copper?f_ri=4493","nofollow":true},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=4493","nofollow":true}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_15513411" data-work_id="15513411" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/15513411/Supramolecular_Chemistry_at_the_Single_Molecule_Level">Supramolecular Chemistry at the Single-Molecule Level</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">In supramolecular chemistry [1] synthetically designed organic constituents interact noncovalently, in a directed and specific way to form host-guest complexes of higher complexity. The ability to tailor the molecular interplay with... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_15513411" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">In supramolecular chemistry [1] synthetically designed organic constituents interact noncovalently, in a directed and specific way to form host-guest complexes of higher complexity. The ability to tailor the molecular interplay with respect of chemical design, specificity, and molecular switching opens up the development of new molecular materials for artificial molecular recognition, molecular organization, and selfassembly. We have used mechanical single-molecule force spectroscopy to investigate the binding of individual resorc-[4]arene-ligand host-guest complexes. By using diluted samples of the host and guest molecules that are modified with a long linker which is attached to an atomic force microscope (AFM) tip, we were able to prevent multiple binding and to observe single host-guest unbinding events in a supramolecular system for the first time. The molecular binding forces, their dependence on external loading rates, the rate of dissociation, and the molecular cavity length directly relate to the molecular properties of the supramolecular species and are consistent with an activated decay of a metastable bound state, a finding already established for biological receptor-ligand complexes. This result allows new insights into the mechanisms, kinetics, and thermodynamics of intermolecular association in chemistry and biology, and opens new possibilities in the investigation, design, and development of synthetic receptor systems.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/15513411" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="fb01912abb3b5791f822ba94d781e98a" rel="nofollow" data-download="{"attachment_id":43129750,"asset_id":15513411,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/43129750/download_file?st=MTc0MDk5NDU4OSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="34664541" href="https://independent.academia.edu/DarioAnselmetti">Dario Anselmetti</a><script data-card-contents-for-user="34664541" type="text/json">{"id":34664541,"first_name":"Dario","last_name":"Anselmetti","domain_name":"independent","page_name":"DarioAnselmetti","display_name":"Dario Anselmetti","profile_url":"https://independent.academia.edu/DarioAnselmetti?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_15513411 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="15513411"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 15513411, container: ".js-paper-rank-work_15513411", }); 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The ability to tailor the molecular interplay with respect of chemical design, specificity, and molecular switching opens up the development of new molecular materials for artificial molecular recognition, molecular organization, and selfassembly. We have used mechanical single-molecule force spectroscopy to investigate the binding of individual resorc-[4]arene-ligand host-guest complexes. By using diluted samples of the host and guest molecules that are modified with a long linker which is attached to an atomic force microscope (AFM) tip, we were able to prevent multiple binding and to observe single host-guest unbinding events in a supramolecular system for the first time. The molecular binding forces, their dependence on external loading rates, the rate of dissociation, and the molecular cavity length directly relate to the molecular properties of the supramolecular species and are consistent with an activated decay of a metastable bound state, a finding already established for biological receptor-ligand complexes. This result allows new insights into the mechanisms, kinetics, and thermodynamics of intermolecular association in chemistry and biology, and opens new possibilities in the investigation, design, and development of synthetic receptor systems.","downloadable_attachments":[{"id":43129750,"asset_id":15513411,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":34664541,"first_name":"Dario","last_name":"Anselmetti","domain_name":"independent","page_name":"DarioAnselmetti","display_name":"Dario Anselmetti","profile_url":"https://independent.academia.edu/DarioAnselmetti?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":24373,"name":"Atomic Force Microscopy","url":"https://www.academia.edu/Documents/in/Atomic_Force_Microscopy?f_ri=4493","nofollow":true},{"id":34975,"name":"Single molecule","url":"https://www.academia.edu/Documents/in/Single_molecule?f_ri=4493","nofollow":true},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=4493","nofollow":true},{"id":1862213,"name":"Calixarenes","url":"https://www.academia.edu/Documents/in/Calixarenes?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_55215455" data-work_id="55215455" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/55215455/Face_to_Face_Stacking_in_Sulfonamide_Based_Bis_ethylene_Bridged_Heteroaromatic_Dimers">Face-to-Face Stacking in Sulfonamide Based Bis-ethylene Bridged Heteroaromatic Dimers</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest">Four sulfonamide based bis-ethylene bridged heteroaromatic dimers were crystallized in offset face-to-face stacked geometry. Further, density functional theory revealed that crystallized structures were the most stable conformers.</div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/55215455" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="3a5abc3c95d7775ae97c748321b9c95c" rel="nofollow" data-download="{"attachment_id":71192118,"asset_id":55215455,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/71192118/download_file?st=MTc0MDk5NDU4OSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="14662054" href="https://independent.academia.edu/ArchanaGaurav">Archana Gaurav</a><script data-card-contents-for-user="14662054" type="text/json">{"id":14662054,"first_name":"Archana","last_name":"Gaurav","domain_name":"independent","page_name":"ArchanaGaurav","display_name":"Archana Gaurav","profile_url":"https://independent.academia.edu/ArchanaGaurav?f_ri=4493","photo":"https://0.academia-photos.com/14662054/15209808/15889781/s65_archana.gaurav.jpg"}</script></span></span></li><li class="js-paper-rank-work_55215455 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="55215455"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 55215455, container: ".js-paper-rank-work_55215455", }); 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Further, density functional theory revealed that crystallized structures were the most stable conformers.","downloadable_attachments":[{"id":71192118,"asset_id":55215455,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":14662054,"first_name":"Archana","last_name":"Gaurav","domain_name":"independent","page_name":"ArchanaGaurav","display_name":"Archana Gaurav","profile_url":"https://independent.academia.edu/ArchanaGaurav?f_ri=4493","photo":"https://0.academia-photos.com/14662054/15209808/15889781/s65_archana.gaurav.jpg"}],"research_interests":[{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":43662,"name":"Aromatic interactions","url":"https://www.academia.edu/Documents/in/Aromatic_interactions?f_ri=4493","nofollow":true},{"id":184005,"name":"Pi-Stacking","url":"https://www.academia.edu/Documents/in/Pi-Stacking?f_ri=4493","nofollow":true},{"id":410471,"name":"Folding","url":"https://www.academia.edu/Documents/in/Folding?f_ri=4493","nofollow":true}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_28984204" data-work_id="28984204" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/28984204/Modulation_of_Protein_Dimerization_by_a_Supramolecular_Host_Guest_System">Modulation of Protein Dimerization by a Supramolecular Host-Guest System</a></div></div><div class="u-pb4x u-mt3x"></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/28984204" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="b5ebc518f7c526fdff26a27664bcbb4d" rel="nofollow" data-download="{"attachment_id":49429224,"asset_id":28984204,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/49429224/download_file?st=MTc0MDk5NDU4OSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="54270071" href="https://independent.academia.edu/HoangNguyen575">Hoang Nguyen</a><script data-card-contents-for-user="54270071" type="text/json">{"id":54270071,"first_name":"Hoang","last_name":"Nguyen","domain_name":"independent","page_name":"HoangNguyen575","display_name":"Hoang Nguyen","profile_url":"https://independent.academia.edu/HoangNguyen575?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_28984204 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="28984204"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 28984204, container: ".js-paper-rank-work_28984204", }); 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$(".js-view-count[data-work-id=28984204]").text(description); $(".js-view-count-work_28984204").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_28984204").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="28984204"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">6</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="4493" rel="nofollow" href="https://www.academia.edu/Documents/in/Supramolecular_Chemistry">Supramolecular Chemistry</a>, <script data-card-contents-for-ri="4493" type="text/json">{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="11073" rel="nofollow" href="https://www.academia.edu/Documents/in/Self_Assembly">Self Assembly</a>, <script data-card-contents-for-ri="11073" type="text/json">{"id":11073,"name":"Self Assembly","url":"https://www.academia.edu/Documents/in/Self_Assembly?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="49833" rel="nofollow" href="https://www.academia.edu/Documents/in/Protein-protein_interactions">Protein-protein interactions</a>, <script data-card-contents-for-ri="49833" type="text/json">{"id":49833,"name":"Protein-protein interactions","url":"https://www.academia.edu/Documents/in/Protein-protein_interactions?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="50487" rel="nofollow" href="https://www.academia.edu/Documents/in/Protein-Protein_Interaction">Protein-Protein Interaction</a><script data-card-contents-for-ri="50487" type="text/json">{"id":50487,"name":"Protein-Protein Interaction","url":"https://www.academia.edu/Documents/in/Protein-Protein_Interaction?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=28984204]'), work: {"id":28984204,"title":"Modulation of Protein Dimerization by a Supramolecular Host-Guest System","created_at":"2016-10-07T08:22:10.618-07:00","url":"https://www.academia.edu/28984204/Modulation_of_Protein_Dimerization_by_a_Supramolecular_Host_Guest_System?f_ri=4493","dom_id":"work_28984204","summary":null,"downloadable_attachments":[{"id":49429224,"asset_id":28984204,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":54270071,"first_name":"Hoang","last_name":"Nguyen","domain_name":"independent","page_name":"HoangNguyen575","display_name":"Hoang Nguyen","profile_url":"https://independent.academia.edu/HoangNguyen575?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":11073,"name":"Self Assembly","url":"https://www.academia.edu/Documents/in/Self_Assembly?f_ri=4493","nofollow":true},{"id":49833,"name":"Protein-protein interactions","url":"https://www.academia.edu/Documents/in/Protein-protein_interactions?f_ri=4493","nofollow":true},{"id":50487,"name":"Protein-Protein Interaction","url":"https://www.academia.edu/Documents/in/Protein-Protein_Interaction?f_ri=4493","nofollow":true},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=4493"},{"id":717129,"name":"Energy Transfer","url":"https://www.academia.edu/Documents/in/Energy_Transfer?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_76884353" data-work_id="76884353" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/76884353/Synthesis_and_Structure_Characterization_of_a_Stable_Nonatwistacene">Synthesis and Structure Characterization of a Stable Nonatwistacene</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The Research about Synthesis and Characterization of SiO2 have been worked. We have synthesized Silica from "petung"bamboo leaf ash as SiO2 source. This step used sol gel methode. SiO2 were characterized by Fourier Transform Infra Red... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_76884353" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The Research about Synthesis and Characterization of SiO2 have been worked. We have synthesized Silica from "petung"bamboo leaf ash as SiO2 source. This step used sol gel methode. SiO2 were characterized by Fourier Transform Infra Red (FTIR) to investigated the stucture andX-Ray Diffaction to know about structure and crystallinity. FTIR spectra show peak at 617,22 cm-1 area that spesific for Si-H bond, peak at 786,96 cm-1 and 1095,57 cm-1 area specific for Si-O-Si bonds. Difractogram of SiO2 show that there are peak at 2θ 21,99; 31,67 and 38,88 were specific for SiO2 that calcinated at 800 o C, while for SiO2 that calcinated at 400 o C there were no peak at 2θ 31,67 dan 38,88. That peaks not shown may be because low crystallinity of SiO2 that calcinated at 400 o C. Calcination temperature greatly affects the crystallinity of SiO2.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/76884353" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="6ad1e6474e3969469b0ff5aa35fafc5b" rel="nofollow" data-download="{"attachment_id":84440428,"asset_id":76884353,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/84440428/download_file?st=MTc0MDk5NDU4OSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="112720106" href="https://independent.academia.edu/hieuDuong53">hieu Duong</a><script data-card-contents-for-user="112720106" type="text/json">{"id":112720106,"first_name":"hieu","last_name":"Duong","domain_name":"independent","page_name":"hieuDuong53","display_name":"hieu Duong","profile_url":"https://independent.academia.edu/hieuDuong53?f_ri=4493","photo":"https://0.academia-photos.com/112720106/33084651/29630678/s65_hieu.duong.jpg"}</script></span></span></li><li class="js-paper-rank-work_76884353 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="76884353"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 76884353, container: ".js-paper-rank-work_76884353", }); 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$(".js-view-count[data-work-id=76884353]").text(description); $(".js-view-count-work_76884353").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_76884353").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="76884353"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">19</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="523" rel="nofollow" href="https://www.academia.edu/Documents/in/Chemistry">Chemistry</a>, <script data-card-contents-for-ri="523" type="text/json">{"id":523,"name":"Chemistry","url":"https://www.academia.edu/Documents/in/Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="4493" rel="nofollow" href="https://www.academia.edu/Documents/in/Supramolecular_Chemistry">Supramolecular Chemistry</a>, <script data-card-contents-for-ri="4493" type="text/json">{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="5769" rel="nofollow" href="https://www.academia.edu/Documents/in/Mass_Spectrometry">Mass Spectrometry</a>, <script data-card-contents-for-ri="5769" type="text/json">{"id":5769,"name":"Mass Spectrometry","url":"https://www.academia.edu/Documents/in/Mass_Spectrometry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="12134" rel="nofollow" href="https://www.academia.edu/Documents/in/NMR_Spectroscopy">NMR Spectroscopy</a><script data-card-contents-for-ri="12134" type="text/json">{"id":12134,"name":"NMR Spectroscopy","url":"https://www.academia.edu/Documents/in/NMR_Spectroscopy?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=76884353]'), work: {"id":76884353,"title":"Synthesis and Structure Characterization of a Stable Nonatwistacene","created_at":"2022-04-18T18:20:37.342-07:00","url":"https://www.academia.edu/76884353/Synthesis_and_Structure_Characterization_of_a_Stable_Nonatwistacene?f_ri=4493","dom_id":"work_76884353","summary":"The Research about Synthesis and Characterization of SiO2 have been worked. We have synthesized Silica from \"petung\"bamboo leaf ash as SiO2 source. This step used sol gel methode. SiO2 were characterized by Fourier Transform Infra Red (FTIR) to investigated the stucture andX-Ray Diffaction to know about structure and crystallinity. FTIR spectra show peak at 617,22 cm-1 area that spesific for Si-H bond, peak at 786,96 cm-1 and 1095,57 cm-1 area specific for Si-O-Si bonds. Difractogram of SiO2 show that there are peak at 2θ 21,99; 31,67 and 38,88 were specific for SiO2 that calcinated at 800 o C, while for SiO2 that calcinated at 400 o C there were no peak at 2θ 31,67 dan 38,88. That peaks not shown may be because low crystallinity of SiO2 that calcinated at 400 o C. Calcination temperature greatly affects the crystallinity of SiO2.","downloadable_attachments":[{"id":84440428,"asset_id":76884353,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":112720106,"first_name":"hieu","last_name":"Duong","domain_name":"independent","page_name":"hieuDuong53","display_name":"hieu Duong","profile_url":"https://independent.academia.edu/hieuDuong53?f_ri=4493","photo":"https://0.academia-photos.com/112720106/33084651/29630678/s65_hieu.duong.jpg"}],"research_interests":[{"id":523,"name":"Chemistry","url":"https://www.academia.edu/Documents/in/Chemistry?f_ri=4493","nofollow":true},{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":5769,"name":"Mass Spectrometry","url":"https://www.academia.edu/Documents/in/Mass_Spectrometry?f_ri=4493","nofollow":true},{"id":12134,"name":"NMR Spectroscopy","url":"https://www.academia.edu/Documents/in/NMR_Spectroscopy?f_ri=4493","nofollow":true},{"id":21927,"name":"Advanced Materials","url":"https://www.academia.edu/Documents/in/Advanced_Materials?f_ri=4493"},{"id":26327,"name":"Medicine","url":"https://www.academia.edu/Documents/in/Medicine?f_ri=4493"},{"id":43465,"name":"Electrospray","url":"https://www.academia.edu/Documents/in/Electrospray?f_ri=4493"},{"id":50630,"name":"Crystal structure","url":"https://www.academia.edu/Documents/in/Crystal_structure?f_ri=4493"},{"id":95519,"name":"Selenium","url":"https://www.academia.edu/Documents/in/Selenium?f_ri=4493"},{"id":166448,"name":"Gas Chromatography","url":"https://www.academia.edu/Documents/in/Gas_Chromatography?f_ri=4493"},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=4493"},{"id":386527,"name":"X ray diffraction","url":"https://www.academia.edu/Documents/in/X_ray_diffraction?f_ri=4493"},{"id":394438,"name":"Single Crystal","url":"https://www.academia.edu/Documents/in/Single_Crystal?f_ri=4493"},{"id":634447,"name":"Analyst","url":"https://www.academia.edu/Documents/in/Analyst?f_ri=4493"},{"id":765007,"name":"Galactomannan","url":"https://www.academia.edu/Documents/in/Galactomannan?f_ri=4493"},{"id":995573,"name":"Biological Macromolecules","url":"https://www.academia.edu/Documents/in/Biological_Macromolecules?f_ri=4493"},{"id":1681026,"name":"Biochemistry and cell biology","url":"https://www.academia.edu/Documents/in/Biochemistry_and_cell_biology?f_ri=4493"},{"id":2512849,"name":"polysaccharide","url":"https://www.academia.edu/Documents/in/polysaccharide?f_ri=4493"},{"id":4069812,"name":"Sulfation","url":"https://www.academia.edu/Documents/in/Sulfation?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_41938423" data-work_id="41938423" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/41938423/Wet_spinning_and_radial_self_assembly_of_a_carbohydrate_low_molecular_weight_gelator_into_well_organized_hydrogel_filaments">Wet spinning and radial self-assembly of a carbohydrate low molecular weight gelator into well organized hydrogel filaments</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Wet spinning and radial self-assembly of a carbohydrate low molecular weight gelator into well organized hydrogel fi laments A single biocompatible small molecule, the N-heptyl-D-galactonamide can be spun into well-defi ned hydrogel fi... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_41938423" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Wet spinning and radial self-assembly of a carbohydrate low molecular weight gelator into well organized hydrogel fi laments A single biocompatible small molecule, the N-heptyl-D-galactonamide can be spun into well-defi ned hydrogel fi laments. A solution of this molecule in dimethylsulfoxide is injected in water, resulting in the formation of a continuous fi lament. The counter-diff usion of water and dimethylsulfoxide triggers the self-assembly of the molecule into supramolecular nanofi bers. A radial organization of the fi bers was observed in the gel fi laments. This method could be used for making well-defi ned cell culture scaff olds. 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described.","downloadable_attachments":[{"id":49328631,"asset_id":5357081,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":7438409,"first_name":"kankan","last_name":"bhaumik","domain_name":"independent","page_name":"bhaumikkankan","display_name":"kankan bhaumik","profile_url":"https://independent.academia.edu/bhaumikkankan?f_ri=4493","photo":"https://0.academia-photos.com/7438409/22257027/21479171/s65_kankan.bhaumik.jpg"}],"research_interests":[{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry?f_ri=4493","nofollow":true},{"id":528,"name":"Computational Chemistry","url":"https://www.academia.edu/Documents/in/Computational_Chemistry?f_ri=4493","nofollow":true},{"id":529,"name":"Quantum Chemistry","url":"https://www.academia.edu/Documents/in/Quantum_Chemistry?f_ri=4493","nofollow":true},{"id":530,"name":"Inorganic 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Chemistry","url":"https://www.academia.edu/Documents/in/Combinatorial_Chemistry?f_ri=4493"},{"id":135186,"name":"Colloids","url":"https://www.academia.edu/Documents/in/Colloids?f_ri=4493"},{"id":168760,"name":"Macromolecules","url":"https://www.academia.edu/Documents/in/Macromolecules?f_ri=4493"},{"id":176632,"name":"Interfaces","url":"https://www.academia.edu/Documents/in/Interfaces?f_ri=4493"},{"id":181569,"name":"Proteins","url":"https://www.academia.edu/Documents/in/Proteins?f_ri=4493"},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=4493"},{"id":391265,"name":"Crystal Structures","url":"https://www.academia.edu/Documents/in/Crystal_Structures?f_ri=4493"},{"id":627110,"name":"BioSensors","url":"https://www.academia.edu/Documents/in/BioSensors-1?f_ri=4493"},{"id":1199463,"name":"Combinatorial","url":"https://www.academia.edu/Documents/in/Combinatorial?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_18758219" data-work_id="18758219" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/18758219/Microwave_Assisted_Reactions_in_Heterocyclic_Compounds_with_Applications_in_Medicinal_and_Supramolecular_Chemistry">Microwave-Assisted Reactions in Heterocyclic Compounds with Applications in Medicinal and Supramolecular Chemistry</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Microwave irradiation has been successfully applied in organic chemistry. Spectacular accelerations, higher yields under milder reaction conditions and higher product purities have all been reported. Indeed, a number of authors have... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_18758219" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Microwave irradiation has been successfully applied in organic chemistry. Spectacular accelerations, higher yields under milder reaction conditions and higher product purities have all been reported. Indeed, a number of authors have described success in reactions that do not occur under conventional heating and modifications in selectivity (chemo-, regio-and stereoselectivity) have even been reported. Recent advances in microwave-assisted combinatorial chemistry include high-speed solid-phase and polymer-supported organic synthesis, rapid parallel synthesis of compound libraries, and library generation by automated sequential microwave irradiation. In addition, new instrumentation for high-throughput microwave-assisted synthesis continues to be developed at a steady pace. The impressive speed combined with the unmatched control over reaction parameters justifies the growing interest in this application of microwave heating. In this review we highlight our recent advances in this area, with a particular emphasis on cycloaddition reactions of heterocyclic compounds both with and without supports, applications in supramolecular chemistry and the reproducibility and scalability of organic reactions involving the use of microwave irradiation techniques.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/18758219" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="dcdefd91e29ff35cd17e0f604b45090c" rel="nofollow" data-download="{"attachment_id":42087092,"asset_id":18758219,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/42087092/download_file?st=MTc0MDk5NDU4OSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="38833189" href="https://independent.academia.edu/Jos%C3%A9Carrillo2">José Carrillo</a><script data-card-contents-for-user="38833189" type="text/json">{"id":38833189,"first_name":"José","last_name":"Carrillo","domain_name":"independent","page_name":"JoséCarrillo2","display_name":"José Carrillo","profile_url":"https://independent.academia.edu/Jos%C3%A9Carrillo2?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_18758219 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="18758219"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 18758219, container: ".js-paper-rank-work_18758219", }); });</script></li><li class="js-percentile-work_18758219 InlineList-item InlineList-item--bordered hidden u-tcGrayDark"><span class="percentile-widget hidden"><span class="u-mr2x percentile-widget" style="display: none">•</span><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 18758219; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-percentile-work_18758219"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></li><li class="js-view-count-work_18758219 InlineList-item InlineList-item--bordered hidden"><div><span><span class="js-view-count view-count u-mr2x" data-work-id="18758219"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 18758219; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=18758219]").text(description); $(".js-view-count-work_18758219").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_18758219").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="18758219"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">7</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="523" rel="nofollow" href="https://www.academia.edu/Documents/in/Chemistry">Chemistry</a>, <script data-card-contents-for-ri="523" type="text/json">{"id":523,"name":"Chemistry","url":"https://www.academia.edu/Documents/in/Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="4493" rel="nofollow" href="https://www.academia.edu/Documents/in/Supramolecular_Chemistry">Supramolecular Chemistry</a>, <script data-card-contents-for-ri="4493" type="text/json">{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="23390" rel="nofollow" href="https://www.academia.edu/Documents/in/Pharmaceutical_Chemistry">Pharmaceutical Chemistry</a>, <script data-card-contents-for-ri="23390" type="text/json">{"id":23390,"name":"Pharmaceutical Chemistry","url":"https://www.academia.edu/Documents/in/Pharmaceutical_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="439473" rel="nofollow" href="https://www.academia.edu/Documents/in/Microwaves">Microwaves</a><script data-card-contents-for-ri="439473" type="text/json">{"id":439473,"name":"Microwaves","url":"https://www.academia.edu/Documents/in/Microwaves?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=18758219]'), work: {"id":18758219,"title":"Microwave-Assisted Reactions in Heterocyclic Compounds with Applications in Medicinal and Supramolecular Chemistry","created_at":"2015-11-21T08:50:20.437-08:00","url":"https://www.academia.edu/18758219/Microwave_Assisted_Reactions_in_Heterocyclic_Compounds_with_Applications_in_Medicinal_and_Supramolecular_Chemistry?f_ri=4493","dom_id":"work_18758219","summary":"Microwave irradiation has been successfully applied in organic chemistry. Spectacular accelerations, higher yields under milder reaction conditions and higher product purities have all been reported. Indeed, a number of authors have described success in reactions that do not occur under conventional heating and modifications in selectivity (chemo-, regio-and stereoselectivity) have even been reported. Recent advances in microwave-assisted combinatorial chemistry include high-speed solid-phase and polymer-supported organic synthesis, rapid parallel synthesis of compound libraries, and library generation by automated sequential microwave irradiation. In addition, new instrumentation for high-throughput microwave-assisted synthesis continues to be developed at a steady pace. The impressive speed combined with the unmatched control over reaction parameters justifies the growing interest in this application of microwave heating. In this review we highlight our recent advances in this area, with a particular emphasis on cycloaddition reactions of heterocyclic compounds both with and without supports, applications in supramolecular chemistry and the reproducibility and scalability of organic reactions involving the use of microwave irradiation techniques.","downloadable_attachments":[{"id":42087092,"asset_id":18758219,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":38833189,"first_name":"José","last_name":"Carrillo","domain_name":"independent","page_name":"JoséCarrillo2","display_name":"José Carrillo","profile_url":"https://independent.academia.edu/Jos%C3%A9Carrillo2?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":523,"name":"Chemistry","url":"https://www.academia.edu/Documents/in/Chemistry?f_ri=4493","nofollow":true},{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":23390,"name":"Pharmaceutical Chemistry","url":"https://www.academia.edu/Documents/in/Pharmaceutical_Chemistry?f_ri=4493","nofollow":true},{"id":439473,"name":"Microwaves","url":"https://www.academia.edu/Documents/in/Microwaves?f_ri=4493","nofollow":true},{"id":582465,"name":"Cyclization","url":"https://www.academia.edu/Documents/in/Cyclization?f_ri=4493"},{"id":1279814,"name":"Heterocyclic compounds","url":"https://www.academia.edu/Documents/in/Heterocyclic_compounds?f_ri=4493"},{"id":1681026,"name":"Biochemistry and cell biology","url":"https://www.academia.edu/Documents/in/Biochemistry_and_cell_biology?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_20569846" data-work_id="20569846" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/20569846/18_Crown_6_templates_offset_linked_pyrogallol_4_arene_dimers">18-Crown-6 templates offset-linked pyrogallol[4]arene dimers</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Offset-linked dimers of C-ethylpyrogallol[4]arene (PgC 2 ) , 18-crown-6 have been synthesised and structurally elucidated. The 18-crown-6 acts as a template/guest for the assembly of the first observed tri-solvent-bridged, extended... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_20569846" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Offset-linked dimers of C-ethylpyrogallol[4]arene (PgC 2 ) , 18-crown-6 have been synthesised and structurally elucidated. The 18-crown-6 acts as a template/guest for the assembly of the first observed tri-solvent-bridged, extended pyrogallol[4] arene-based dimers. Oppositely, adjacently and diagonally positioned macrocycles are connected through a complex network of solvent-mediated H bonds.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/20569846" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="ca5fad3f75c66a2a1fa928da4cc4e9c1" rel="nofollow" data-download="{"attachment_id":41442630,"asset_id":20569846,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/41442630/download_file?st=MTc0MDk5NDU4OSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="41924546" href="https://independent.academia.edu/CarolDeakyne">Carol Deakyne</a><script data-card-contents-for-user="41924546" type="text/json">{"id":41924546,"first_name":"Carol","last_name":"Deakyne","domain_name":"independent","page_name":"CarolDeakyne","display_name":"Carol Deakyne","profile_url":"https://independent.academia.edu/CarolDeakyne?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_20569846 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="20569846"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 20569846, container: ".js-paper-rank-work_20569846", }); });</script></li><li class="js-percentile-work_20569846 InlineList-item InlineList-item--bordered hidden u-tcGrayDark"><span class="percentile-widget hidden"><span class="u-mr2x percentile-widget" style="display: none">•</span><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 20569846; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-percentile-work_20569846"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></li><li class="js-view-count-work_20569846 InlineList-item InlineList-item--bordered hidden"><div><span><span class="js-view-count view-count u-mr2x" data-work-id="20569846"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 20569846; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=20569846]").text(description); $(".js-view-count-work_20569846").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_20569846").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="20569846"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">2</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="4493" rel="nofollow" href="https://www.academia.edu/Documents/in/Supramolecular_Chemistry">Supramolecular Chemistry</a>, <script data-card-contents-for-ri="4493" type="text/json">{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="260118" rel="nofollow" href="https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES">CHEMICAL SCIENCES</a><script data-card-contents-for-ri="260118" type="text/json">{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=20569846]'), work: {"id":20569846,"title":"18-Crown-6 templates offset-linked pyrogallol[4]arene dimers","created_at":"2016-01-22T11:37:55.181-08:00","url":"https://www.academia.edu/20569846/18_Crown_6_templates_offset_linked_pyrogallol_4_arene_dimers?f_ri=4493","dom_id":"work_20569846","summary":"Offset-linked dimers of C-ethylpyrogallol[4]arene (PgC 2 ) , 18-crown-6 have been synthesised and structurally elucidated. The 18-crown-6 acts as a template/guest for the assembly of the first observed tri-solvent-bridged, extended pyrogallol[4] arene-based dimers. Oppositely, adjacently and diagonally positioned macrocycles are connected through a complex network of solvent-mediated H bonds.","downloadable_attachments":[{"id":41442630,"asset_id":20569846,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":41924546,"first_name":"Carol","last_name":"Deakyne","domain_name":"independent","page_name":"CarolDeakyne","display_name":"Carol Deakyne","profile_url":"https://independent.academia.edu/CarolDeakyne?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=4493","nofollow":true}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_56238699" data-work_id="56238699" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/56238699/A_sinapic_acid_calix_4_arene_hybrid_selectively_binds_Pb2_over_Hg2_and_Cd2_">A sinapic acid–calix[4]arene hybrid selectively binds Pb2+ over Hg2+ and Cd2+</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The binding affinity for Pb 2+ , Cd 2+ and Hg 2+ of the sinapic acid-calix[4]arene hybrid 2, having four sinapyl pendants at the upper rim, has been investigated via an UV-Vis study. Compound 2 has better complexing ability than the... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_56238699" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The binding affinity for Pb 2+ , Cd 2+ and Hg 2+ of the sinapic acid-calix[4]arene hybrid 2, having four sinapyl pendants at the upper rim, has been investigated via an UV-Vis study. Compound 2 has better complexing ability than the monomeric p-phenetidine derivative 1. This highlights that the clustering of sinapyl units in a basket-like structure, dictated by the calixarene scaffold, greatly enhances the complexing properties. Ligand 2 forms complexes even with Hg 2+ , which is not complexed by 1 at all; the complexes formed by 2 with Pb 2+ and Cd 2+ are much stronger than the analogous complexes formed by 1. The UV-Vis investigation shows that the hybrid 2 markedly favors Pb 2+ over Cd 2+ and Hg 2+. Information on the structural properties of the complex species was obtained by 1 H NMR spectroscopy. NMR data show that all three metal ions are placed into the cavity consisting of the calixarene scaffold and the sinapyl pendants, though their binding affects the coordinating regions to a different extent.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/56238699" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="b84c49a54c21fc48124ea6401e5afc55" rel="nofollow" data-download="{"attachment_id":71722737,"asset_id":56238699,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/71722737/download_file?st=MTc0MDk5NDU4OSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="372355" href="https://cnr-it.academia.edu/CorradaGeraci">Corrada Geraci</a><script data-card-contents-for-user="372355" type="text/json">{"id":372355,"first_name":"Corrada","last_name":"Geraci","domain_name":"cnr-it","page_name":"CorradaGeraci","display_name":"Corrada Geraci","profile_url":"https://cnr-it.academia.edu/CorradaGeraci?f_ri=4493","photo":"https://0.academia-photos.com/372355/114761/134540/s65_corrada.geraci.jpg"}</script></span></span></li><li class="js-paper-rank-work_56238699 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="56238699"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 56238699, container: ".js-paper-rank-work_56238699", }); 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$(".js-view-count[data-work-id=56238699]").text(description); $(".js-view-count-work_56238699").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_56238699").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="56238699"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">9</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="530" rel="nofollow" href="https://www.academia.edu/Documents/in/Inorganic_Chemistry">Inorganic Chemistry</a>, <script data-card-contents-for-ri="530" type="text/json">{"id":530,"name":"Inorganic Chemistry","url":"https://www.academia.edu/Documents/in/Inorganic_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="4493" rel="nofollow" href="https://www.academia.edu/Documents/in/Supramolecular_Chemistry">Supramolecular Chemistry</a>, <script data-card-contents-for-ri="4493" type="text/json">{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="12134" rel="nofollow" href="https://www.academia.edu/Documents/in/NMR_Spectroscopy">NMR Spectroscopy</a>, <script data-card-contents-for-ri="12134" type="text/json">{"id":12134,"name":"NMR Spectroscopy","url":"https://www.academia.edu/Documents/in/NMR_Spectroscopy?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="111050" rel="nofollow" href="https://www.academia.edu/Documents/in/Heavy_Metal">Heavy Metal</a><script data-card-contents-for-ri="111050" type="text/json">{"id":111050,"name":"Heavy Metal","url":"https://www.academia.edu/Documents/in/Heavy_Metal?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=56238699]'), work: {"id":56238699,"title":"A sinapic acid–calix[4]arene hybrid selectively binds Pb2+ over Hg2+ and Cd2+","created_at":"2021-10-07T03:00:43.235-07:00","url":"https://www.academia.edu/56238699/A_sinapic_acid_calix_4_arene_hybrid_selectively_binds_Pb2_over_Hg2_and_Cd2_?f_ri=4493","dom_id":"work_56238699","summary":"The binding affinity for Pb 2+ , Cd 2+ and Hg 2+ of the sinapic acid-calix[4]arene hybrid 2, having four sinapyl pendants at the upper rim, has been investigated via an UV-Vis study. Compound 2 has better complexing ability than the monomeric p-phenetidine derivative 1. This highlights that the clustering of sinapyl units in a basket-like structure, dictated by the calixarene scaffold, greatly enhances the complexing properties. Ligand 2 forms complexes even with Hg 2+ , which is not complexed by 1 at all; the complexes formed by 2 with Pb 2+ and Cd 2+ are much stronger than the analogous complexes formed by 1. The UV-Vis investigation shows that the hybrid 2 markedly favors Pb 2+ over Cd 2+ and Hg 2+. Information on the structural properties of the complex species was obtained by 1 H NMR spectroscopy. NMR data show that all three metal ions are placed into the cavity consisting of the calixarene scaffold and the sinapyl pendants, though their binding affects the coordinating regions to a different extent.","downloadable_attachments":[{"id":71722737,"asset_id":56238699,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":372355,"first_name":"Corrada","last_name":"Geraci","domain_name":"cnr-it","page_name":"CorradaGeraci","display_name":"Corrada Geraci","profile_url":"https://cnr-it.academia.edu/CorradaGeraci?f_ri=4493","photo":"https://0.academia-photos.com/372355/114761/134540/s65_corrada.geraci.jpg"}],"research_interests":[{"id":530,"name":"Inorganic Chemistry","url":"https://www.academia.edu/Documents/in/Inorganic_Chemistry?f_ri=4493","nofollow":true},{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":12134,"name":"NMR Spectroscopy","url":"https://www.academia.edu/Documents/in/NMR_Spectroscopy?f_ri=4493","nofollow":true},{"id":111050,"name":"Heavy Metal","url":"https://www.academia.edu/Documents/in/Heavy_Metal?f_ri=4493","nofollow":true},{"id":494642,"name":"Structural Properties","url":"https://www.academia.edu/Documents/in/Structural_Properties?f_ri=4493"},{"id":590943,"name":"Metal ion","url":"https://www.academia.edu/Documents/in/Metal_ion?f_ri=4493"},{"id":1862213,"name":"Calixarenes","url":"https://www.academia.edu/Documents/in/Calixarenes?f_ri=4493"},{"id":1868097,"name":"Selectivity","url":"https://www.academia.edu/Documents/in/Selectivity?f_ri=4493"},{"id":2225815,"name":"Binding affinity","url":"https://www.academia.edu/Documents/in/Binding_affinity?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_24104142" data-work_id="24104142" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/24104142/Spectrofluorometric_analytical_applications_of_cyclodextrins">Spectrofluorometric analytical applications of cyclodextrins</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Cyclodextrins (CDs) are a family of cyclic oligosaccharides composed of a-(1,4)-linked glucopyranose subunits. The most important feature of CDs is their ability to form inclusion complexes (host-guest complexes) with a very wide range of... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_24104142" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Cyclodextrins (CDs) are a family of cyclic oligosaccharides composed of a-(1,4)-linked glucopyranose subunits. The most important feature of CDs is their ability to form inclusion complexes (host-guest complexes) with a very wide range of solid, liquid and gaseous compounds by a molecular complexation. During the last decade, a considerable number of research papers has been focused on the use of CDs to enhance fluorescence intensity of different analytes and to develop CD-induced spectrofluorimetric method. In this review, the various spectrofluorimetric methods based on host-inclusion complex are presented.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/24104142" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="4b7fb52fc48fbd0da62e71675790bb76" rel="nofollow" data-download="{"attachment_id":44467557,"asset_id":24104142,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/44467557/download_file?st=MTc0MDk5NDU4OSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="33691111" href="https://nrc.academia.edu/HassanAboulenein">Hassan Aboul-enein</a><script data-card-contents-for-user="33691111" type="text/json">{"id":33691111,"first_name":"Hassan","last_name":"Aboul-enein","domain_name":"nrc","page_name":"HassanAboulenein","display_name":"Hassan Aboul-enein","profile_url":"https://nrc.academia.edu/HassanAboulenein?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_24104142 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="24104142"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 24104142, container: ".js-paper-rank-work_24104142", }); 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$(".js-view-count[data-work-id=24104142]").text(description); $(".js-view-count-work_24104142").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_24104142").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="24104142"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">4</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="4493" rel="nofollow" href="https://www.academia.edu/Documents/in/Supramolecular_Chemistry">Supramolecular Chemistry</a>, <script data-card-contents-for-ri="4493" type="text/json">{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="158914" rel="nofollow" href="https://www.academia.edu/Documents/in/Luminescence">Luminescence</a>, <script data-card-contents-for-ri="158914" type="text/json">{"id":158914,"name":"Luminescence","url":"https://www.academia.edu/Documents/in/Luminescence?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="594574" rel="nofollow" href="https://www.academia.edu/Documents/in/Cyclodextrins">Cyclodextrins</a>, <script data-card-contents-for-ri="594574" type="text/json">{"id":594574,"name":"Cyclodextrins","url":"https://www.academia.edu/Documents/in/Cyclodextrins?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="1681026" rel="nofollow" href="https://www.academia.edu/Documents/in/Biochemistry_and_cell_biology">Biochemistry and cell biology</a><script data-card-contents-for-ri="1681026" type="text/json">{"id":1681026,"name":"Biochemistry and cell biology","url":"https://www.academia.edu/Documents/in/Biochemistry_and_cell_biology?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=24104142]'), work: {"id":24104142,"title":"Spectrofluorometric analytical applications of cyclodextrins","created_at":"2016-04-06T01:38:22.126-07:00","url":"https://www.academia.edu/24104142/Spectrofluorometric_analytical_applications_of_cyclodextrins?f_ri=4493","dom_id":"work_24104142","summary":"Cyclodextrins (CDs) are a family of cyclic oligosaccharides composed of a-(1,4)-linked glucopyranose subunits. The most important feature of CDs is their ability to form inclusion complexes (host-guest complexes) with a very wide range of solid, liquid and gaseous compounds by a molecular complexation. During the last decade, a considerable number of research papers has been focused on the use of CDs to enhance fluorescence intensity of different analytes and to develop CD-induced spectrofluorimetric method. In this review, the various spectrofluorimetric methods based on host-inclusion complex are presented.","downloadable_attachments":[{"id":44467557,"asset_id":24104142,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":33691111,"first_name":"Hassan","last_name":"Aboul-enein","domain_name":"nrc","page_name":"HassanAboulenein","display_name":"Hassan Aboul-enein","profile_url":"https://nrc.academia.edu/HassanAboulenein?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":158914,"name":"Luminescence","url":"https://www.academia.edu/Documents/in/Luminescence?f_ri=4493","nofollow":true},{"id":594574,"name":"Cyclodextrins","url":"https://www.academia.edu/Documents/in/Cyclodextrins?f_ri=4493","nofollow":true},{"id":1681026,"name":"Biochemistry and cell biology","url":"https://www.academia.edu/Documents/in/Biochemistry_and_cell_biology?f_ri=4493","nofollow":true}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_959388" data-work_id="959388" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/959388/A_Survey_of_Tellurium_Centered_Secondary_Bonding_Supramolecular_Synthons">A Survey of Tellurium-Centered Secondary-Bonding Supramolecular Synthons</a></div></div><div class="u-pb4x u-mt3x"></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/959388" data-share-source="work_strip" 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itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="795773" href="https://mit.academia.edu/AnthonyCozzolino">Anthony Cozzolino</a><script data-card-contents-for-user="795773" type="text/json">{"id":795773,"first_name":"Anthony","last_name":"Cozzolino","domain_name":"mit","page_name":"AnthonyCozzolino","display_name":"Anthony Cozzolino","profile_url":"https://mit.academia.edu/AnthonyCozzolino?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_959388 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="959388"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 959388, container: ".js-paper-rank-work_959388", }); });</script></li><li class="js-percentile-work_959388 InlineList-item 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Group","url":"https://www.academia.edu/Documents/in/Functional_Group?f_ri=4493"},{"id":1189198,"name":"Intermolecular Interaction","url":"https://www.academia.edu/Documents/in/Intermolecular_Interaction?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_14362938 coauthored" data-work_id="14362938" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/14362938/A_spectroscopic_investigation_of_incompletely_condensed_polyhedral_oligomeric_silsesquioxanes_POSS_mono_ol_POSS_diol_and_POSS_triol_Hydrogen_bonded_interaction_and_host_guest_complex">A spectroscopic investigation of incompletely condensed polyhedral oligomeric silsesquioxanes (POSS-mono-ol, POSS-diol and POSS-triol): Hydrogen-bonded interaction and host–guest complex</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">1H NMR dilution experiment and FTIR were used to investigate the hydrogen bonded interaction in three different types of incompletely condensed silsesquioxanes (POSS-mono-ol, POSS-diol and POSS-triol). For POSS-triol, there existed a... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_14362938" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">1H NMR dilution experiment and FTIR were used to investigate the hydrogen bonded interaction in three different types of incompletely condensed silsesquioxanes (POSS-mono-ol, POSS-diol and POSS-triol). For POSS-triol, there existed a dynamic equilibrium between single molecule and hydrogen-bonded dimer, and the dimerization constants (Kdim) of POSS-triol in different solvents were determined by 1H NMR dilution experiment. In addition, based on</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/14362938" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="3d911199f78842c1e7b8d851b4357819" rel="nofollow" data-download="{"attachment_id":44281763,"asset_id":14362938,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/44281763/download_file?st=MTc0MDk5NDU4OSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="33450273" href="https://independent.academia.edu/ShinichiKondo">Shin-ichi Kondo</a><script data-card-contents-for-user="33450273" type="text/json">{"id":33450273,"first_name":"Shin-ichi","last_name":"Kondo","domain_name":"independent","page_name":"ShinichiKondo","display_name":"Shin-ichi Kondo","profile_url":"https://independent.academia.edu/ShinichiKondo?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span><span class="u-displayInlineBlock InlineList-item-text"> and <span class="u-textDecorationUnderline u-clickable InlineList-item-text js-work-more-authors-14362938">+1</span><div class="hidden js-additional-users-14362938"><div><span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a href="https://independent.academia.edu/HongzhiLiu">Hongzhi Liu</a></span></div></div></span><script>(function(){ var popoverSettings = { el: $('.js-work-more-authors-14362938'), placement: 'bottom', hide_delay: 200, html: true, content: function(){ return $('.js-additional-users-14362938').html(); 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For POSS-triol, there existed a dynamic equilibrium between single molecule and hydrogen-bonded dimer, and the dimerization constants (Kdim) of POSS-triol in different solvents were determined by 1H NMR dilution experiment. In addition, based on","downloadable_attachments":[{"id":44281763,"asset_id":14362938,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":33450273,"first_name":"Shin-ichi","last_name":"Kondo","domain_name":"independent","page_name":"ShinichiKondo","display_name":"Shin-ichi Kondo","profile_url":"https://independent.academia.edu/ShinichiKondo?f_ri=4493","photo":"/images/s65_no_pic.png"},{"id":33307355,"first_name":"Hongzhi","last_name":"Liu","domain_name":"independent","page_name":"HongzhiLiu","display_name":"Hongzhi Liu","profile_url":"https://independent.academia.edu/HongzhiLiu?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":530,"name":"Inorganic Chemistry","url":"https://www.academia.edu/Documents/in/Inorganic_Chemistry?f_ri=4493","nofollow":true},{"id":531,"name":"Organic Chemistry","url":"https://www.academia.edu/Documents/in/Organic_Chemistry?f_ri=4493","nofollow":true},{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":11648,"name":"Organometallic Chemistry","url":"https://www.academia.edu/Documents/in/Organometallic_Chemistry?f_ri=4493","nofollow":true},{"id":34975,"name":"Single molecule","url":"https://www.academia.edu/Documents/in/Single_molecule?f_ri=4493"},{"id":212520,"name":"Organometallic","url":"https://www.academia.edu/Documents/in/Organometallic?f_ri=4493"},{"id":240148,"name":"Hydrogen Bond","url":"https://www.academia.edu/Documents/in/Hydrogen_Bond?f_ri=4493"},{"id":1551329,"name":"Dynamic equilibrium","url":"https://www.academia.edu/Documents/in/Dynamic_equilibrium?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_20775510" data-work_id="20775510" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/20775510/Stereoselective_alkylation_of_thiacalix_4_arenes">Stereoselective alkylation of thiacalix[4]arenes</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">A direct tetraalkylation of thiacalix[4]arenes using procedures well established in ÔclassicalÕ calixarene chemistry usually gives the 1,3-alternate conformers as the main product (n-PrI/K 2 CO 3 /acetone) while the cone conformers are... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_20775510" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">A direct tetraalkylation of thiacalix[4]arenes using procedures well established in ÔclassicalÕ calixarene chemistry usually gives the 1,3-alternate conformers as the main product (n-PrI/K 2 CO 3 /acetone) while the cone conformers are obtained only in very poor yields (n-PrI/NaH/DMF). Surprisingly, the so far almost inaccessible cone conformers can be prepared in high yields using the two-step procedure: dialkylation-dialkylation, opening the way for their further utilisation in supramolecular chemistry.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/20775510" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="e035b2593ce9e8de5a43e21756ee0254" rel="nofollow" data-download="{"attachment_id":41924468,"asset_id":20775510,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/41924468/download_file?st=MTc0MDk5NDU5MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="42061743" href="https://independent.academia.edu/MichaelaPojarova">Michaela Pojarova</a><script data-card-contents-for-user="42061743" type="text/json">{"id":42061743,"first_name":"Michaela","last_name":"Pojarova","domain_name":"independent","page_name":"MichaelaPojarova","display_name":"Michaela Pojarova","profile_url":"https://independent.academia.edu/MichaelaPojarova?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_20775510 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="20775510"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 20775510, container: ".js-paper-rank-work_20775510", }); 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Surprisingly, the so far almost inaccessible cone conformers can be prepared in high yields using the two-step procedure: dialkylation-dialkylation, opening the way for their further utilisation in supramolecular chemistry.","downloadable_attachments":[{"id":41924468,"asset_id":20775510,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":42061743,"first_name":"Michaela","last_name":"Pojarova","domain_name":"independent","page_name":"MichaelaPojarova","display_name":"Michaela Pojarova","profile_url":"https://independent.academia.edu/MichaelaPojarova?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":531,"name":"Organic Chemistry","url":"https://www.academia.edu/Documents/in/Organic_Chemistry?f_ri=4493","nofollow":true},{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":16030,"name":"Calixarene","url":"https://www.academia.edu/Documents/in/Calixarene?f_ri=4493","nofollow":true},{"id":664186,"name":"Alkylation","url":"https://www.academia.edu/Documents/in/Alkylation?f_ri=4493","nofollow":true}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_73009574" data-work_id="73009574" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" rel="nofollow" href="https://www.academia.edu/73009574/Coordination_Architectures_of_Large_Heavy_Metal_Cations_Hg2_and_Pb2_with_Bis_tridentate_Ligands_Solution_and_Solid_State_Studies">Coordination Architectures of Large Heavy Metal Cations (Hg2+ and Pb2+) with Bis-tridentate Ligands: Solution and Solid-State Studies</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Abstract Solution and solid state studies of the complexation of Hg 2+ and Pb 2+ by the homologous bis-tridentate ligands 1 and 2H 2 obtained by condensation of bis (methylhydrazino) phenylpyrimidine and bis (hydrazino) phenylpyrimidine,... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_73009574" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Abstract Solution and solid state studies of the complexation of Hg 2+ and Pb 2+ by the homologous bis-tridentate ligands 1 and 2H 2 obtained by condensation of bis (methylhydrazino) phenylpyrimidine and bis (hydrazino) phenylpyrimidine, respectively, ...</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/73009574" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="23260074" href="https://independent.academia.edu/JuhaniHuuskonen">Juhani Huuskonen</a><script data-card-contents-for-user="23260074" type="text/json">{"id":23260074,"first_name":"Juhani","last_name":"Huuskonen","domain_name":"independent","page_name":"JuhaniHuuskonen","display_name":"Juhani Huuskonen","profile_url":"https://independent.academia.edu/JuhaniHuuskonen?f_ri=4493","photo":"https://0.academia-photos.com/23260074/6312732/7145352/s65_juhani.huuskonen.jpg"}</script></span></span></li><li class="js-paper-rank-work_73009574 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="73009574"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 73009574, container: ".js-paper-rank-work_73009574", }); });</script></li><li class="js-percentile-work_73009574 InlineList-item InlineList-item--bordered hidden u-tcGrayDark"><span class="percentile-widget hidden"><span class="u-mr2x percentile-widget" style="display: none">•</span><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 73009574; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-percentile-work_73009574"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></li><li class="js-view-count-work_73009574 InlineList-item InlineList-item--bordered hidden"><div><span><span class="js-view-count view-count u-mr2x" data-work-id="73009574"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 73009574; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=73009574]").text(description); $(".js-view-count-work_73009574").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_73009574").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="73009574"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">7</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="523" rel="nofollow" href="https://www.academia.edu/Documents/in/Chemistry">Chemistry</a>, <script data-card-contents-for-ri="523" type="text/json">{"id":523,"name":"Chemistry","url":"https://www.academia.edu/Documents/in/Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="530" rel="nofollow" href="https://www.academia.edu/Documents/in/Inorganic_Chemistry">Inorganic Chemistry</a>, <script data-card-contents-for-ri="530" type="text/json">{"id":530,"name":"Inorganic Chemistry","url":"https://www.academia.edu/Documents/in/Inorganic_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="4493" rel="nofollow" href="https://www.academia.edu/Documents/in/Supramolecular_Chemistry">Supramolecular Chemistry</a>, <script data-card-contents-for-ri="4493" type="text/json">{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="11073" rel="nofollow" href="https://www.academia.edu/Documents/in/Self_Assembly">Self Assembly</a><script data-card-contents-for-ri="11073" type="text/json">{"id":11073,"name":"Self Assembly","url":"https://www.academia.edu/Documents/in/Self_Assembly?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=73009574]'), work: {"id":73009574,"title":"Coordination Architectures of Large Heavy Metal Cations (Hg2+ and Pb2+) with Bis-tridentate Ligands: Solution and Solid-State Studies","created_at":"2022-03-04T01:58:41.257-08:00","url":"https://www.academia.edu/73009574/Coordination_Architectures_of_Large_Heavy_Metal_Cations_Hg2_and_Pb2_with_Bis_tridentate_Ligands_Solution_and_Solid_State_Studies?f_ri=4493","dom_id":"work_73009574","summary":"Abstract Solution and solid state studies of the complexation of Hg 2+ and Pb 2+ by the homologous bis-tridentate ligands 1 and 2H 2 obtained by condensation of bis (methylhydrazino) phenylpyrimidine and bis (hydrazino) phenylpyrimidine, respectively, ...","downloadable_attachments":[],"ordered_authors":[{"id":23260074,"first_name":"Juhani","last_name":"Huuskonen","domain_name":"independent","page_name":"JuhaniHuuskonen","display_name":"Juhani Huuskonen","profile_url":"https://independent.academia.edu/JuhaniHuuskonen?f_ri=4493","photo":"https://0.academia-photos.com/23260074/6312732/7145352/s65_juhani.huuskonen.jpg"}],"research_interests":[{"id":523,"name":"Chemistry","url":"https://www.academia.edu/Documents/in/Chemistry?f_ri=4493","nofollow":true},{"id":530,"name":"Inorganic Chemistry","url":"https://www.academia.edu/Documents/in/Inorganic_Chemistry?f_ri=4493","nofollow":true},{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":11073,"name":"Self Assembly","url":"https://www.academia.edu/Documents/in/Self_Assembly?f_ri=4493","nofollow":true},{"id":90017,"name":"Mercury","url":"https://www.academia.edu/Documents/in/Mercury?f_ri=4493"},{"id":111050,"name":"Heavy Metal","url":"https://www.academia.edu/Documents/in/Heavy_Metal?f_ri=4493"},{"id":116579,"name":"Lead","url":"https://www.academia.edu/Documents/in/Lead?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_52535903" data-work_id="52535903" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" rel="nofollow" href="https://www.academia.edu/52535903/Barbituric_acids_as_a_useful_tool_for_the_construction_of_coordination_and_supramolecular_compounds">Barbituric acids as a useful tool for the construction of coordination and supramolecular compounds</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">ABSTRACT In spite of its impressive record in medicinal chemistry, the role of barbituric acid H3BA (pyrimidine-2,4,6(1H,3H,5H)-trione) in coordination, organometallic and supramolecular chemistries has not yet been analyzed and reviewed.... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_52535903" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">ABSTRACT In spite of its impressive record in medicinal chemistry, the role of barbituric acid H3BA (pyrimidine-2,4,6(1H,3H,5H)-trione) in coordination, organometallic and supramolecular chemistries has not yet been analyzed and reviewed. However, H3BA can be readily functionalized and provides rich opportunities to create coordination bonds and non-covalent interactions. Thus, derivatives of H3BA (barbituric acids, BAs) are widely used for the preparation of a wide range of complexes with various metals of almost all groups of the periodic table. The review systematizes information on the synthesis, tautomerism, acid-base properties of BAs and their use for the construction of organometallic and coordination compounds, as well as coordination polymers and supramolecular assemblies. The role of different metal ions and the structure of BAs in directing the preparative pathways and tuning particular structural properties of the resulting compounds are discussed. Some valuable applications of BAs, in particular in the construction of molecular receptors, magnetic and nonlinear optic materials, bioactive compounds, drug cocrystal design, catalysis and photochemistry are also envisaged.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/52535903" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="201147097" href="https://bakustate.academia.edu/MalahatKurbanova">Malahat Kurbanova</a><script data-card-contents-for-user="201147097" type="text/json">{"id":201147097,"first_name":"Malahat","last_name":"Kurbanova","domain_name":"bakustate","page_name":"MalahatKurbanova","display_name":"Malahat Kurbanova","profile_url":"https://bakustate.academia.edu/MalahatKurbanova?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_52535903 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="52535903"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 52535903, container: ".js-paper-rank-work_52535903", }); 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$(".js-view-count[data-work-id=52535903]").text(description); $(".js-view-count-work_52535903").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_52535903").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="52535903"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">7</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="530" rel="nofollow" href="https://www.academia.edu/Documents/in/Inorganic_Chemistry">Inorganic Chemistry</a>, <script data-card-contents-for-ri="530" type="text/json">{"id":530,"name":"Inorganic Chemistry","url":"https://www.academia.edu/Documents/in/Inorganic_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="531" rel="nofollow" href="https://www.academia.edu/Documents/in/Organic_Chemistry">Organic Chemistry</a>, <script data-card-contents-for-ri="531" type="text/json">{"id":531,"name":"Organic Chemistry","url":"https://www.academia.edu/Documents/in/Organic_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="2414" rel="nofollow" href="https://www.academia.edu/Documents/in/Coordination_Chemistry">Coordination Chemistry</a>, <script data-card-contents-for-ri="2414" type="text/json">{"id":2414,"name":"Coordination Chemistry","url":"https://www.academia.edu/Documents/in/Coordination_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="4493" rel="nofollow" href="https://www.academia.edu/Documents/in/Supramolecular_Chemistry">Supramolecular Chemistry</a><script data-card-contents-for-ri="4493" type="text/json">{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=52535903]'), work: {"id":52535903,"title":"Barbituric acids as a useful tool for the construction of coordination and supramolecular compounds","created_at":"2021-09-16T12:26:07.757-07:00","url":"https://www.academia.edu/52535903/Barbituric_acids_as_a_useful_tool_for_the_construction_of_coordination_and_supramolecular_compounds?f_ri=4493","dom_id":"work_52535903","summary":"ABSTRACT In spite of its impressive record in medicinal chemistry, the role of barbituric acid H3BA (pyrimidine-2,4,6(1H,3H,5H)-trione) in coordination, organometallic and supramolecular chemistries has not yet been analyzed and reviewed. However, H3BA can be readily functionalized and provides rich opportunities to create coordination bonds and non-covalent interactions. Thus, derivatives of H3BA (barbituric acids, BAs) are widely used for the preparation of a wide range of complexes with various metals of almost all groups of the periodic table. The review systematizes information on the synthesis, tautomerism, acid-base properties of BAs and their use for the construction of organometallic and coordination compounds, as well as coordination polymers and supramolecular assemblies. The role of different metal ions and the structure of BAs in directing the preparative pathways and tuning particular structural properties of the resulting compounds are discussed. Some valuable applications of BAs, in particular in the construction of molecular receptors, magnetic and nonlinear optic materials, bioactive compounds, drug cocrystal design, catalysis and photochemistry are also envisaged.","downloadable_attachments":[],"ordered_authors":[{"id":201147097,"first_name":"Malahat","last_name":"Kurbanova","domain_name":"bakustate","page_name":"MalahatKurbanova","display_name":"Malahat Kurbanova","profile_url":"https://bakustate.academia.edu/MalahatKurbanova?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":530,"name":"Inorganic Chemistry","url":"https://www.academia.edu/Documents/in/Inorganic_Chemistry?f_ri=4493","nofollow":true},{"id":531,"name":"Organic Chemistry","url":"https://www.academia.edu/Documents/in/Organic_Chemistry?f_ri=4493","nofollow":true},{"id":2414,"name":"Coordination Chemistry","url":"https://www.academia.edu/Documents/in/Coordination_Chemistry?f_ri=4493","nofollow":true},{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":4749,"name":"Catalysis","url":"https://www.academia.edu/Documents/in/Catalysis?f_ri=4493"},{"id":55241,"name":"Synthetic Organic Chemistry","url":"https://www.academia.edu/Documents/in/Synthetic_Organic_Chemistry?f_ri=4493"},{"id":811222,"name":"Barbituric Acid","url":"https://www.academia.edu/Documents/in/Barbituric_Acid?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_29286586" data-work_id="29286586" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/29286586/Acanthocyclamine_A_From_the_Indonesian_Marine_Sponge_Acanthostrongylophora_ingens">Acanthocyclamine A From the Indonesian Marine Sponge Acanthostrongylophora ingens</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">A new 3-alkylpiperidine compound (À)-acanthocyclamine A (1) has been obtained from the methanolic extract of Acanthostrongylophora ingens (order Haplosclerida, family Petrosiidae) collected from Wakatobi Marine National Park in South East... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_29286586" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">A new 3-alkylpiperidine compound (À)-acanthocyclamine A (1) has been obtained from the methanolic extract of Acanthostrongylophora ingens (order Haplosclerida, family Petrosiidae) collected from Wakatobi Marine National Park in South East Sulawesi, Indonesia. The structure of 1 was investigated by extensive 1D-and 2D-NMR experiments. The absolute configuration of 1 was established by X-ray crystallography from anomalous dispersion effects using Cu radiation as C2 (R), C3 (R), C7 (R), and C9 (R). A plausible biosynthetic scheme leading to 1 is presented, and compared with the biosynthetic pathway proposed for the manzamine alkaloids.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/29286586" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="06de5a1979da7be53fa05357116924c2" rel="nofollow" data-download="{"attachment_id":49731440,"asset_id":29286586,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/49731440/download_file?st=MTc0MDk5NDU5MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="55314152" href="https://uq.academia.edu/AriyantiDewi">Ariyanti Dewi</a><script data-card-contents-for-user="55314152" type="text/json">{"id":55314152,"first_name":"Ariyanti","last_name":"Dewi","domain_name":"uq","page_name":"AriyantiDewi","display_name":"Ariyanti Dewi","profile_url":"https://uq.academia.edu/AriyantiDewi?f_ri=4493","photo":"https://0.academia-photos.com/55314152/19359745/19278767/s65_ariyanti.dewi.jpg"}</script></span></span></li><li class="js-paper-rank-work_29286586 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="29286586"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 29286586, container: ".js-paper-rank-work_29286586", }); 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$(".js-view-count[data-work-id=29286586]").text(description); $(".js-view-count-work_29286586").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_29286586").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="29286586"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">41</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="524" rel="nofollow" href="https://www.academia.edu/Documents/in/Analytical_Chemistry">Analytical Chemistry</a>, <script data-card-contents-for-ri="524" type="text/json">{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="528" rel="nofollow" href="https://www.academia.edu/Documents/in/Computational_Chemistry">Computational Chemistry</a>, <script data-card-contents-for-ri="528" type="text/json">{"id":528,"name":"Computational Chemistry","url":"https://www.academia.edu/Documents/in/Computational_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="529" rel="nofollow" href="https://www.academia.edu/Documents/in/Quantum_Chemistry">Quantum Chemistry</a>, <script data-card-contents-for-ri="529" type="text/json">{"id":529,"name":"Quantum Chemistry","url":"https://www.academia.edu/Documents/in/Quantum_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="530" rel="nofollow" href="https://www.academia.edu/Documents/in/Inorganic_Chemistry">Inorganic Chemistry</a><script data-card-contents-for-ri="530" type="text/json">{"id":530,"name":"Inorganic Chemistry","url":"https://www.academia.edu/Documents/in/Inorganic_Chemistry?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=29286586]'), work: {"id":29286586,"title":"Acanthocyclamine A From the Indonesian Marine Sponge Acanthostrongylophora ingens","created_at":"2016-10-19T23:22:42.939-07:00","url":"https://www.academia.edu/29286586/Acanthocyclamine_A_From_the_Indonesian_Marine_Sponge_Acanthostrongylophora_ingens?f_ri=4493","dom_id":"work_29286586","summary":"A new 3-alkylpiperidine compound (À)-acanthocyclamine A (1) has been obtained from the methanolic extract of Acanthostrongylophora ingens (order Haplosclerida, family Petrosiidae) collected from Wakatobi Marine National Park in South East Sulawesi, Indonesia. The structure of 1 was investigated by extensive 1D-and 2D-NMR experiments. The absolute configuration of 1 was established by X-ray crystallography from anomalous dispersion effects using Cu radiation as C2 (R), C3 (R), C7 (R), and C9 (R). A plausible biosynthetic scheme leading to 1 is presented, and compared with the biosynthetic pathway proposed for the manzamine alkaloids.","downloadable_attachments":[{"id":49731440,"asset_id":29286586,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":55314152,"first_name":"Ariyanti","last_name":"Dewi","domain_name":"uq","page_name":"AriyantiDewi","display_name":"Ariyanti Dewi","profile_url":"https://uq.academia.edu/AriyantiDewi?f_ri=4493","photo":"https://0.academia-photos.com/55314152/19359745/19278767/s65_ariyanti.dewi.jpg"}],"research_interests":[{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry?f_ri=4493","nofollow":true},{"id":528,"name":"Computational Chemistry","url":"https://www.academia.edu/Documents/in/Computational_Chemistry?f_ri=4493","nofollow":true},{"id":529,"name":"Quantum Chemistry","url":"https://www.academia.edu/Documents/in/Quantum_Chemistry?f_ri=4493","nofollow":true},{"id":530,"name":"Inorganic Chemistry","url":"https://www.academia.edu/Documents/in/Inorganic_Chemistry?f_ri=4493","nofollow":true},{"id":531,"name":"Organic Chemistry","url":"https://www.academia.edu/Documents/in/Organic_Chemistry?f_ri=4493"},{"id":532,"name":"Physical Chemistry","url":"https://www.academia.edu/Documents/in/Physical_Chemistry?f_ri=4493"},{"id":1177,"name":"Crystallography","url":"https://www.academia.edu/Documents/in/Crystallography?f_ri=4493"},{"id":2375,"name":"Medicinal Chemistry","url":"https://www.academia.edu/Documents/in/Medicinal_Chemistry?f_ri=4493"},{"id":2526,"name":"Polymer Chemistry","url":"https://www.academia.edu/Documents/in/Polymer_Chemistry?f_ri=4493"},{"id":3340,"name":"Reaction Mechanisms","url":"https://www.academia.edu/Documents/in/Reaction_Mechanisms?f_ri=4493"},{"id":3408,"name":"Green Chemistry","url":"https://www.academia.edu/Documents/in/Green_Chemistry?f_ri=4493"},{"id":3614,"name":"Structure","url":"https://www.academia.edu/Documents/in/Structure?f_ri=4493"},{"id":4331,"name":"Biosensors","url":"https://www.academia.edu/Documents/in/Biosensors?f_ri=4493"},{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493"},{"id":4748,"name":"Electrochemistry","url":"https://www.academia.edu/Documents/in/Electrochemistry?f_ri=4493"},{"id":4749,"name":"Catalysis","url":"https://www.academia.edu/Documents/in/Catalysis?f_ri=4493"},{"id":4987,"name":"Kinetics","url":"https://www.academia.edu/Documents/in/Kinetics?f_ri=4493"},{"id":5104,"name":"Photochemistry","url":"https://www.academia.edu/Documents/in/Photochemistry?f_ri=4493"},{"id":5427,"name":"Spectroscopy","url":"https://www.academia.edu/Documents/in/Spectroscopy?f_ri=4493"},{"id":5769,"name":"Mass 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calculations","url":"https://www.academia.edu/Documents/in/Ab_initio_calculations?f_ri=4493"},{"id":55405,"name":"Sensors","url":"https://www.academia.edu/Documents/in/Sensors?f_ri=4493"},{"id":80872,"name":"Scientific","url":"https://www.academia.edu/Documents/in/Scientific?f_ri=4493"},{"id":84578,"name":"Educational","url":"https://www.academia.edu/Documents/in/Educational?f_ri=4493"},{"id":93627,"name":"Density Functional Theory","url":"https://www.academia.edu/Documents/in/Density_Functional_Theory?f_ri=4493"},{"id":100696,"name":"Combinatorial 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class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_19433230" data-work_id="19433230" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/19433230/Complexation_of_2_6_Bis_acylamino_pyridines_with_Dipyridin_2_ylamine_and_4_4_Dimethylpiperidine_2_6_dione">Complexation of 2,6-Bis(acylamino)pyridines with Dipyridin-2-ylamine and 4,4-Dimethylpiperidine-2,6-dione</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Intermolecular hydrogen bonds between 2,6-bis(acylamino)pyridines and dipyridin-2-ylamine as well as 4,4- dimethylpiperidine-2,6-dione are responsible for relatively strong interactions between these species. Association has been found to... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_19433230" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Intermolecular hydrogen bonds between 2,6-bis(acylamino)pyridines and dipyridin-2-ylamine as well as 4,4- dimethylpiperidine-2,6-dione are responsible for relatively strong interactions between these species. Association has been found to be significantly affected by the size of acyl substituent (chemical shift of the NH proton was used as the main probe in determination of the association constants). Calculations at the DFT level of theory are in line with the experimentally observed results. Calculated energies of the interactions between the complex congeners also show the size of the substituent to affect the association. Conformational changes in the dipyridin-2-ylamine molecule are shown to adapt a geometry suitable for formation of efficient hydrogen bonding.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/19433230" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="e77553ec8b95ddf21530e4e87e060ba9" rel="nofollow" data-download="{"attachment_id":40617258,"asset_id":19433230,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/40617258/download_file?st=MTc0MDk5NDU5MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="3998615" href="https://torun-pl.academia.edu/BorysOsmialowski">Borys Osmialowski</a><script data-card-contents-for-user="3998615" type="text/json">{"id":3998615,"first_name":"Borys","last_name":"Osmialowski","domain_name":"torun-pl","page_name":"BorysOsmialowski","display_name":"Borys Osmialowski","profile_url":"https://torun-pl.academia.edu/BorysOsmialowski?f_ri=4493","photo":"https://0.academia-photos.com/3998615/15277743/15941026/s65_borys.osmialowski.jpg"}</script></span></span></li><li class="js-paper-rank-work_19433230 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="19433230"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 19433230, container: ".js-paper-rank-work_19433230", }); 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$(".js-view-count[data-work-id=19433230]").text(description); $(".js-view-count-work_19433230").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_19433230").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="19433230"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i></div><span class="InlineList-item-text u-textTruncate u-pl6x"><a class="InlineList-item-text" data-has-card-for-ri="4493" rel="nofollow" href="https://www.academia.edu/Documents/in/Supramolecular_Chemistry">Supramolecular Chemistry</a><script data-card-contents-for-ri="4493" type="text/json">{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (false) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=19433230]'), work: {"id":19433230,"title":"Complexation of 2,6-Bis(acylamino)pyridines with Dipyridin-2-ylamine and 4,4-Dimethylpiperidine-2,6-dione","created_at":"2015-12-03T13:22:52.548-08:00","url":"https://www.academia.edu/19433230/Complexation_of_2_6_Bis_acylamino_pyridines_with_Dipyridin_2_ylamine_and_4_4_Dimethylpiperidine_2_6_dione?f_ri=4493","dom_id":"work_19433230","summary":"Intermolecular hydrogen bonds between 2,6-bis(acylamino)pyridines and dipyridin-2-ylamine as well as 4,4- dimethylpiperidine-2,6-dione are responsible for relatively strong interactions between these species. Association has been found to be significantly affected by the size of acyl substituent (chemical shift of the NH proton was used as the main probe in determination of the association constants). Calculations at the DFT level of theory are in line with the experimentally observed results. Calculated energies of the interactions between the complex congeners also show the size of the substituent to affect the association. Conformational changes in the dipyridin-2-ylamine molecule are shown to adapt a geometry suitable for formation of efficient hydrogen bonding.","downloadable_attachments":[{"id":40617258,"asset_id":19433230,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":3998615,"first_name":"Borys","last_name":"Osmialowski","domain_name":"torun-pl","page_name":"BorysOsmialowski","display_name":"Borys Osmialowski","profile_url":"https://torun-pl.academia.edu/BorysOsmialowski?f_ri=4493","photo":"https://0.academia-photos.com/3998615/15277743/15941026/s65_borys.osmialowski.jpg"}],"research_interests":[{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_5039774" data-work_id="5039774" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/5039774/Flash_NanoPrecipitation_of_Organic_Actives_and_Block_Copolymers_using_a_Confined_Impinging_Jets_Mixer">Flash NanoPrecipitation of Organic Actives and Block Copolymers using a Confined Impinging Jets Mixer</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">A new technology to form nanoparticles of hydrophobic organic actives at high concentration and yield, as well as methods to characterize the process, are presented. In Flash NanoPrecipitation, an organic active and an amphiphilic diblock... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_5039774" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">A new technology to form nanoparticles of hydrophobic organic actives at high concentration and yield, as well as methods to characterize the process, are presented. In Flash NanoPrecipitation, an organic active and an amphiphilic diblock copolymer are molecularly dissolved in an organic phase and mixed rapidly with a miscible anti-solvent to afford precipitation of the active with a tunable, narrow submicron particle size distribution from 1 µm to 80 nm. The enabling components are a novel 'analytical' (quantified mixing time) confined impinging jets (CIJ) mixer for millisecond stream homogenization and amphiphilic diblock copolymers which alter the organic nucleation and growth, provide steric stabilization for the particles, and offer a functional surface for the particle. Applications in enhanced pharmaceutical delivery, dye preparation, and pesticide formulation are specifically targeted.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/5039774" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="a853c973dc137e4b34db48756824b791" rel="nofollow" data-download="{"attachment_id":49475234,"asset_id":5039774,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/49475234/download_file?st=MTc0MDk5NDU5MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="6711333" href="https://princeton.academia.edu/RobertPrudhomme">Robert Prud'homme</a><script data-card-contents-for-user="6711333" type="text/json">{"id":6711333,"first_name":"Robert","last_name":"Prud'homme","domain_name":"princeton","page_name":"RobertPrudhomme","display_name":"Robert Prud'homme","profile_url":"https://princeton.academia.edu/RobertPrudhomme?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_5039774 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="5039774"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 5039774, container: ".js-paper-rank-work_5039774", }); 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$(".js-view-count[data-work-id=5039774]").text(description); $(".js-view-count-work_5039774").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_5039774").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="5039774"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">47</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="524" rel="nofollow" href="https://www.academia.edu/Documents/in/Analytical_Chemistry">Analytical Chemistry</a>, <script data-card-contents-for-ri="524" type="text/json">{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="528" rel="nofollow" href="https://www.academia.edu/Documents/in/Computational_Chemistry">Computational Chemistry</a>, <script data-card-contents-for-ri="528" type="text/json">{"id":528,"name":"Computational Chemistry","url":"https://www.academia.edu/Documents/in/Computational_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="529" rel="nofollow" href="https://www.academia.edu/Documents/in/Quantum_Chemistry">Quantum Chemistry</a>, <script data-card-contents-for-ri="529" type="text/json">{"id":529,"name":"Quantum Chemistry","url":"https://www.academia.edu/Documents/in/Quantum_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="530" rel="nofollow" href="https://www.academia.edu/Documents/in/Inorganic_Chemistry">Inorganic Chemistry</a><script data-card-contents-for-ri="530" type="text/json">{"id":530,"name":"Inorganic Chemistry","url":"https://www.academia.edu/Documents/in/Inorganic_Chemistry?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=5039774]'), work: {"id":5039774,"title":"Flash NanoPrecipitation of Organic Actives and Block Copolymers using a Confined Impinging Jets Mixer","created_at":"2013-11-09T00:39:48.228-08:00","url":"https://www.academia.edu/5039774/Flash_NanoPrecipitation_of_Organic_Actives_and_Block_Copolymers_using_a_Confined_Impinging_Jets_Mixer?f_ri=4493","dom_id":"work_5039774","summary":"A new technology to form nanoparticles of hydrophobic organic actives at high concentration and yield, as well as methods to characterize the process, are presented. In Flash NanoPrecipitation, an organic active and an amphiphilic diblock copolymer are molecularly dissolved in an organic phase and mixed rapidly with a miscible anti-solvent to afford precipitation of the active with a tunable, narrow submicron particle size distribution from 1 µm to 80 nm. The enabling components are a novel 'analytical' (quantified mixing time) confined impinging jets (CIJ) mixer for millisecond stream homogenization and amphiphilic diblock copolymers which alter the organic nucleation and growth, provide steric stabilization for the particles, and offer a functional surface for the particle. Applications in enhanced pharmaceutical delivery, dye preparation, and pesticide formulation are specifically targeted.","downloadable_attachments":[{"id":49475234,"asset_id":5039774,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":6711333,"first_name":"Robert","last_name":"Prud'homme","domain_name":"princeton","page_name":"RobertPrudhomme","display_name":"Robert Prud'homme","profile_url":"https://princeton.academia.edu/RobertPrudhomme?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry?f_ri=4493","nofollow":true},{"id":528,"name":"Computational Chemistry","url":"https://www.academia.edu/Documents/in/Computational_Chemistry?f_ri=4493","nofollow":true},{"id":529,"name":"Quantum Chemistry","url":"https://www.academia.edu/Documents/in/Quantum_Chemistry?f_ri=4493","nofollow":true},{"id":530,"name":"Inorganic Chemistry","url":"https://www.academia.edu/Documents/in/Inorganic_Chemistry?f_ri=4493","nofollow":true},{"id":531,"name":"Organic Chemistry","url":"https://www.academia.edu/Documents/in/Organic_Chemistry?f_ri=4493"},{"id":532,"name":"Physical Chemistry","url":"https://www.academia.edu/Documents/in/Physical_Chemistry?f_ri=4493"},{"id":1177,"name":"Crystallography","url":"https://www.academia.edu/Documents/in/Crystallography?f_ri=4493"},{"id":2375,"name":"Medicinal Chemistry","url":"https://www.academia.edu/Documents/in/Medicinal_Chemistry?f_ri=4493"},{"id":2526,"name":"Polymer Chemistry","url":"https://www.academia.edu/Documents/in/Polymer_Chemistry?f_ri=4493"},{"id":3340,"name":"Reaction Mechanisms","url":"https://www.academia.edu/Documents/in/Reaction_Mechanisms?f_ri=4493"},{"id":3408,"name":"Green Chemistry","url":"https://www.academia.edu/Documents/in/Green_Chemistry?f_ri=4493"},{"id":3614,"name":"Structure","url":"https://www.academia.edu/Documents/in/Structure?f_ri=4493"},{"id":4331,"name":"Biosensors","url":"https://www.academia.edu/Documents/in/Biosensors?f_ri=4493"},{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493"},{"id":4748,"name":"Electrochemistry","url":"https://www.academia.edu/Documents/in/Electrochemistry?f_ri=4493"},{"id":4749,"name":"Catalysis","url":"https://www.academia.edu/Documents/in/Catalysis?f_ri=4493"},{"id":4987,"name":"Kinetics","url":"https://www.academia.edu/Documents/in/Kinetics?f_ri=4493"},{"id":5104,"name":"Photochemistry","url":"https://www.academia.edu/Documents/in/Photochemistry?f_ri=4493"},{"id":5427,"name":"Spectroscopy","url":"https://www.academia.edu/Documents/in/Spectroscopy?f_ri=4493"},{"id":5769,"name":"Mass 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calculations","url":"https://www.academia.edu/Documents/in/Ab_initio_calculations?f_ri=4493"},{"id":48319,"name":"Block Copolymer","url":"https://www.academia.edu/Documents/in/Block_Copolymer?f_ri=4493"},{"id":55405,"name":"Sensors","url":"https://www.academia.edu/Documents/in/Sensors?f_ri=4493"},{"id":59546,"name":"New Technology","url":"https://www.academia.edu/Documents/in/New_Technology?f_ri=4493"},{"id":80872,"name":"Scientific","url":"https://www.academia.edu/Documents/in/Scientific?f_ri=4493"},{"id":84578,"name":"Educational","url":"https://www.academia.edu/Documents/in/Educational?f_ri=4493"},{"id":93627,"name":"Density Functional Theory","url":"https://www.academia.edu/Documents/in/Density_Functional_Theory?f_ri=4493"},{"id":100696,"name":"Combinatorial Chemistry","url":"https://www.academia.edu/Documents/in/Combinatorial_Chemistry?f_ri=4493"},{"id":135186,"name":"Colloids","url":"https://www.academia.edu/Documents/in/Colloids?f_ri=4493"},{"id":159943,"name":"Nucleation and Growth","url":"https://www.academia.edu/Documents/in/Nucleation_and_Growth?f_ri=4493"},{"id":168760,"name":"Macromolecules","url":"https://www.academia.edu/Documents/in/Macromolecules?f_ri=4493"},{"id":176632,"name":"Interfaces","url":"https://www.academia.edu/Documents/in/Interfaces?f_ri=4493"},{"id":181569,"name":"Proteins","url":"https://www.academia.edu/Documents/in/Proteins?f_ri=4493"},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=4493"},{"id":391265,"name":"Crystal Structures","url":"https://www.academia.edu/Documents/in/Crystal_Structures?f_ri=4493"},{"id":627110,"name":"BioSensors","url":"https://www.academia.edu/Documents/in/BioSensors-1?f_ri=4493"},{"id":890638,"name":"Mixing Time","url":"https://www.academia.edu/Documents/in/Mixing_Time?f_ri=4493"},{"id":892198,"name":"Impinging Jet","url":"https://www.academia.edu/Documents/in/Impinging_Jet?f_ri=4493"},{"id":1136005,"name":"Particle Size Distribution","url":"https://www.academia.edu/Documents/in/Particle_Size_Distribution?f_ri=4493"},{"id":1199463,"name":"Combinatorial","url":"https://www.academia.edu/Documents/in/Combinatorial?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_42262178" data-work_id="42262178" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/42262178/3D_printing_of_a_biocompatible_low_molecular_weight_supramolecular_hydrogel_by_dimethylsulfoxide_water_solvent_exchange">3D printing of a biocompatible low molecular weight supramolecular hydrogel by dimethylsulfoxide water solvent exchange</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">A fragile and non-thixotropic biocompatible low molecular weight gel is printed in 3D structures by a solvent exchange process. The 3D printing process is based on the continuous extrusion of a solution of a small amphiphile molecule,... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_42262178" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">A fragile and non-thixotropic biocompatible low molecular weight gel is printed in 3D structures by a solvent exchange process. The 3D printing process is based on the continuous extrusion of a solution of a small amphiphile molecule, N-heptyl-D-galactonamide, in dimethylsulfoxide, that forms a gel in contact with water. The diffusion of water in the dimethylsulfoxide / N-heptyl-D-galactonamide solution triggers the self-assembly of the molecule into supramolecular fibers and the setting of the ink. The conditions for getting a well-defined pattern and the dimensions of the constructs have been determined. The resulting constructs can be easily dissolved, orienting its application as a sacrificial ink or a temporary support. This method opens the way to the injection and the 3D printing of other fragile and non-thixotropic supramolecular hydrogels.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/42262178" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="dc837553edc7845218c2effa3075623d" rel="nofollow" data-download="{"attachment_id":62414265,"asset_id":42262178,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/62414265/download_file?st=MTc0MDk5NDU5MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="37432690" href="https://cnrs.academia.edu/JulietteFitremann">Juliette Fitremann</a><script data-card-contents-for-user="37432690" type="text/json">{"id":37432690,"first_name":"Juliette","last_name":"Fitremann","domain_name":"cnrs","page_name":"JulietteFitremann","display_name":"Juliette Fitremann","profile_url":"https://cnrs.academia.edu/JulietteFitremann?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_42262178 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="42262178"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 42262178, container: ".js-paper-rank-work_42262178", }); 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$(".js-view-count[data-work-id=42262178]").text(description); $(".js-view-count-work_42262178").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_42262178").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="42262178"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">6</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="4493" rel="nofollow" href="https://www.academia.edu/Documents/in/Supramolecular_Chemistry">Supramolecular Chemistry</a>, <script data-card-contents-for-ri="4493" type="text/json">{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="12694" rel="nofollow" href="https://www.academia.edu/Documents/in/Supramolecular_self-assembly">Supramolecular self-assembly</a>, <script data-card-contents-for-ri="12694" type="text/json">{"id":12694,"name":"Supramolecular self-assembly","url":"https://www.academia.edu/Documents/in/Supramolecular_self-assembly?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="23091" rel="nofollow" href="https://www.academia.edu/Documents/in/3D_printing">3D printing</a>, <script data-card-contents-for-ri="23091" type="text/json">{"id":23091,"name":"3D printing","url":"https://www.academia.edu/Documents/in/3D_printing?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="102727" rel="nofollow" href="https://www.academia.edu/Documents/in/Hydrogel">Hydrogel</a><script data-card-contents-for-ri="102727" type="text/json">{"id":102727,"name":"Hydrogel","url":"https://www.academia.edu/Documents/in/Hydrogel?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=42262178]'), work: {"id":42262178,"title":"3D printing of a biocompatible low molecular weight supramolecular hydrogel by dimethylsulfoxide water solvent exchange","created_at":"2020-03-19T10:12:51.938-07:00","url":"https://www.academia.edu/42262178/3D_printing_of_a_biocompatible_low_molecular_weight_supramolecular_hydrogel_by_dimethylsulfoxide_water_solvent_exchange?f_ri=4493","dom_id":"work_42262178","summary":"A fragile and non-thixotropic biocompatible low molecular weight gel is printed in 3D structures by a solvent exchange process. The 3D printing process is based on the continuous extrusion of a solution of a small amphiphile molecule, N-heptyl-D-galactonamide, in dimethylsulfoxide, that forms a gel in contact with water. The diffusion of water in the dimethylsulfoxide / N-heptyl-D-galactonamide solution triggers the self-assembly of the molecule into supramolecular fibers and the setting of the ink. The conditions for getting a well-defined pattern and the dimensions of the constructs have been determined. The resulting constructs can be easily dissolved, orienting its application as a sacrificial ink or a temporary support. This method opens the way to the injection and the 3D printing of other fragile and non-thixotropic supramolecular hydrogels.","downloadable_attachments":[{"id":62414265,"asset_id":42262178,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":37432690,"first_name":"Juliette","last_name":"Fitremann","domain_name":"cnrs","page_name":"JulietteFitremann","display_name":"Juliette Fitremann","profile_url":"https://cnrs.academia.edu/JulietteFitremann?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":12694,"name":"Supramolecular self-assembly","url":"https://www.academia.edu/Documents/in/Supramolecular_self-assembly?f_ri=4493","nofollow":true},{"id":23091,"name":"3D 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class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_9276261" data-work_id="9276261" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/9276261/Second_sphere_coordination_complexes_via_hydrogen_bonding_Synthesis_spectroscopic_characterization_crystal_structures_and_packing_of_cis_diazidobis_ethylenediamine_cobalt_III_cations_with_complex_fluoroanions">Second-sphere coordination complexes via hydrogen bonding: Synthesis, spectroscopic characterization, crystal structures and packing of cis-diazidobis(ethylenediamine)cobalt(III) cations with complex fluoroanions</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">In an effort to explore [trans-Co(en) 2 Cl 2 ] C as anion receptor for tetrabromocadmate and tetraiodocadmate ion, green coloured single crystals of [trans-Co(en) 2 Cl 2 ]CdBr 4 I and [trans-Co(en) 2 Cl 2 ]CdI 4 II have been obtained by... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_9276261" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">In an effort to explore [trans-Co(en) 2 Cl 2 ] C as anion receptor for tetrabromocadmate and tetraiodocadmate ion, green coloured single crystals of [trans-Co(en) 2 Cl 2 ]CdBr 4 I and [trans-Co(en) 2 Cl 2 ]CdI 4 II have been obtained by slowly mixing the separately dissolved transdichlorobis(ethylenediamine)cobalt(III) chloride with potassium tetrabromocadmate and tetraiodocadmate in aqueous medium in 2:1 molar ratio. The newly synthesized complex salt was characterized on the basis of elemental analysis and spectroscopic techniques (IR, UV/visible, 1 H and 13 C NMR). Single crystal X-ray structure determination of [trans-Co(en) 2 Cl 2 ] 2 CdBr 4 revealed that it crystallizes in the orthorhombic space group Pbca with aZ18.6201(10), bZ12.0872(6), cZ24.0877(12) Å , VZ5421.3(5) Å 3 , ZZ8, RZ0.0727. Supramolecular hydrogen bonding networks between ionic groups: bromide ions of tetrabromocadmate group and NH groups of coordinated ethylenediamine molecules, i.e. N-H/Br K interactions by second sphere coordination besides electrostatic forces of attraction have been observed. This suggests that [trans-Co(en) 2 Cl 2 ] C is a promising anion receptor for the tetrabromocadmate. q</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/9276261" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="86c2bac32f372c788a620ecaa0dd3146" rel="nofollow" data-download="{"attachment_id":47834117,"asset_id":9276261,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/47834117/download_file?st=MTc0MDk5NDU5MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="21344686" href="https://independent.academia.edu/SHARMARAJPAL">RAJ PAL SHARMA</a><script data-card-contents-for-user="21344686" type="text/json">{"id":21344686,"first_name":"RAJ PAL","last_name":"SHARMA","domain_name":"independent","page_name":"SHARMARAJPAL","display_name":"RAJ PAL SHARMA","profile_url":"https://independent.academia.edu/SHARMARAJPAL?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_9276261 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="9276261"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 9276261, container: ".js-paper-rank-work_9276261", }); 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The newly synthesized complex salt was characterized on the basis of elemental analysis and spectroscopic techniques (IR, UV/visible, 1 H and 13 C NMR). Single crystal X-ray structure determination of [trans-Co(en) 2 Cl 2 ] 2 CdBr 4 revealed that it crystallizes in the orthorhombic space group Pbca with aZ18.6201(10), bZ12.0872(6), cZ24.0877(12) Å , VZ5421.3(5) Å 3 , ZZ8, RZ0.0727. Supramolecular hydrogen bonding networks between ionic groups: bromide ions of tetrabromocadmate group and NH groups of coordinated ethylenediamine molecules, i.e. N-H/Br K interactions by second sphere coordination besides electrostatic forces of attraction have been observed. This suggests that [trans-Co(en) 2 Cl 2 ] C is a promising anion receptor for the tetrabromocadmate. q","downloadable_attachments":[{"id":47834117,"asset_id":9276261,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":21344686,"first_name":"RAJ PAL","last_name":"SHARMA","domain_name":"independent","page_name":"SHARMARAJPAL","display_name":"RAJ PAL SHARMA","profile_url":"https://independent.academia.edu/SHARMARAJPAL?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":530,"name":"Inorganic Chemistry","url":"https://www.academia.edu/Documents/in/Inorganic_Chemistry?f_ri=4493","nofollow":true},{"id":2414,"name":"Coordination Chemistry","url":"https://www.academia.edu/Documents/in/Coordination_Chemistry?f_ri=4493","nofollow":true},{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":50157,"name":"Molecular","url":"https://www.academia.edu/Documents/in/Molecular?f_ri=4493","nofollow":true},{"id":50630,"name":"Crystal structure","url":"https://www.academia.edu/Documents/in/Crystal_structure?f_ri=4493"},{"id":160656,"name":"Potassium","url":"https://www.academia.edu/Documents/in/Potassium?f_ri=4493"},{"id":240148,"name":"Hydrogen Bond","url":"https://www.academia.edu/Documents/in/Hydrogen_Bond?f_ri=4493"},{"id":394438,"name":"Single Crystal","url":"https://www.academia.edu/Documents/in/Single_Crystal?f_ri=4493"},{"id":584724,"name":"Electrostatic force","url":"https://www.academia.edu/Documents/in/Electrostatic_force?f_ri=4493"},{"id":645605,"name":"THEORETICAL AND COMPUTATIONAL CHEMISTRY","url":"https://www.academia.edu/Documents/in/THEORETICAL_AND_COMPUTATIONAL_CHEMISTRY?f_ri=4493"},{"id":952991,"name":"Spectroscopic Techniques","url":"https://www.academia.edu/Documents/in/Spectroscopic_Techniques?f_ri=4493"},{"id":1146655,"name":"X Ray Crystallography","url":"https://www.academia.edu/Documents/in/X_Ray_Crystallography?f_ri=4493"},{"id":1724844,"name":"Molecular Structure","url":"https://www.academia.edu/Documents/in/Molecular_Structure?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_29762087" data-work_id="29762087" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/29762087/Gold_Nanoparticles_Assembly_Supramolecular_Chemistry_Quantum_Size_Related_Properties_and_Applications_toward_Biology_Catalysis_and_Nanotechnology">Gold Nanoparticles: Assembly, Supramolecular Chemistry, Quantum-Size-Related Properties, and Applications toward Biology, Catalysis, and Nanotechnology</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Figure 10. UV-vis spectra (A) and TEM images and size distributions (B) of (a) [AuCl 4 ]before reduction; dodecanethiol-AuNPs (b) as prepared and after heat treatment at (c) 150, (d) 190, and (e) 230°C; and (f) octadecanethiol-AuNPs... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_29762087" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Figure 10. UV-vis spectra (A) and TEM images and size distributions (B) of (a) [AuCl 4 ]before reduction; dodecanethiol-AuNPs (b) as prepared and after heat treatment at (c) 150, (d) 190, and (e) 230°C; and (f) octadecanethiol-AuNPs heat-treated at 250°C. Reprinted with permission from ref 188b (Miyake's group).</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/29762087" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="22679237b4f247e8040a3d6d030c4acb" rel="nofollow" data-download="{"attachment_id":50215038,"asset_id":29762087,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/50215038/download_file?st=MTc0MDk5NDU5MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="56319600" href="https://independent.academia.edu/DAstruc">Didier Astruc</a><script data-card-contents-for-user="56319600" type="text/json">{"id":56319600,"first_name":"Didier","last_name":"Astruc","domain_name":"independent","page_name":"DAstruc","display_name":"Didier Astruc","profile_url":"https://independent.academia.edu/DAstruc?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_29762087 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="29762087"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 29762087, container: ".js-paper-rank-work_29762087", }); 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$(".js-view-count[data-work-id=29762087]").text(description); $(".js-view-count-work_29762087").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_29762087").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="29762087"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">13</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="4493" rel="nofollow" href="https://www.academia.edu/Documents/in/Supramolecular_Chemistry">Supramolecular Chemistry</a>, <script data-card-contents-for-ri="4493" type="text/json">{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="4749" rel="nofollow" href="https://www.academia.edu/Documents/in/Catalysis">Catalysis</a>, <script data-card-contents-for-ri="4749" type="text/json">{"id":4749,"name":"Catalysis","url":"https://www.academia.edu/Documents/in/Catalysis?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="17733" rel="nofollow" href="https://www.academia.edu/Documents/in/Nanotechnology">Nanotechnology</a>, <script data-card-contents-for-ri="17733" type="text/json">{"id":17733,"name":"Nanotechnology","url":"https://www.academia.edu/Documents/in/Nanotechnology?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="65698" rel="nofollow" href="https://www.academia.edu/Documents/in/Gold_nanoparticle">Gold nanoparticle</a><script data-card-contents-for-ri="65698" type="text/json">{"id":65698,"name":"Gold nanoparticle","url":"https://www.academia.edu/Documents/in/Gold_nanoparticle?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=29762087]'), work: {"id":29762087,"title":"Gold Nanoparticles: Assembly, Supramolecular Chemistry, Quantum-Size-Related Properties, and Applications toward Biology, Catalysis, and Nanotechnology","created_at":"2016-11-09T10:48:57.189-08:00","url":"https://www.academia.edu/29762087/Gold_Nanoparticles_Assembly_Supramolecular_Chemistry_Quantum_Size_Related_Properties_and_Applications_toward_Biology_Catalysis_and_Nanotechnology?f_ri=4493","dom_id":"work_29762087","summary":"Figure 10. UV-vis spectra (A) and TEM images and size distributions (B) of (a) [AuCl 4 ]before reduction; dodecanethiol-AuNPs (b) as prepared and after heat treatment at (c) 150, (d) 190, and (e) 230°C; and (f) octadecanethiol-AuNPs heat-treated at 250°C. Reprinted with permission from ref 188b (Miyake's group).","downloadable_attachments":[{"id":50215038,"asset_id":29762087,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":56319600,"first_name":"Didier","last_name":"Astruc","domain_name":"independent","page_name":"DAstruc","display_name":"Didier Astruc","profile_url":"https://independent.academia.edu/DAstruc?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":4749,"name":"Catalysis","url":"https://www.academia.edu/Documents/in/Catalysis?f_ri=4493","nofollow":true},{"id":17733,"name":"Nanotechnology","url":"https://www.academia.edu/Documents/in/Nanotechnology?f_ri=4493","nofollow":true},{"id":65698,"name":"Gold nanoparticle","url":"https://www.academia.edu/Documents/in/Gold_nanoparticle?f_ri=4493","nofollow":true},{"id":76736,"name":"Gold","url":"https://www.academia.edu/Documents/in/Gold?f_ri=4493"},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=4493"},{"id":390245,"name":"Particle Size","url":"https://www.academia.edu/Documents/in/Particle_Size?f_ri=4493"},{"id":794074,"name":"Microspheres","url":"https://www.academia.edu/Documents/in/Microspheres?f_ri=4493"},{"id":809882,"name":"Base Sequence","url":"https://www.academia.edu/Documents/in/Base_Sequence?f_ri=4493"},{"id":1256747,"name":"Oxidation-Reduction","url":"https://www.academia.edu/Documents/in/Oxidation-Reduction?f_ri=4493"},{"id":1412233,"name":"Biosensing Techniques","url":"https://www.academia.edu/Documents/in/Biosensing_Techniques?f_ri=4493"},{"id":1575801,"name":"DNA probes","url":"https://www.academia.edu/Documents/in/DNA_probes?f_ri=4493"},{"id":2467566,"name":"Molecular Sequence Data","url":"https://www.academia.edu/Documents/in/Molecular_Sequence_Data?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_72989006" data-work_id="72989006" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" rel="nofollow" href="https://www.academia.edu/72989006/Supramolecular_Soft_Adhesive_Materials">Supramolecular Soft Adhesive Materials</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">ABSTRACT The rheological and adhesive properties of bis-urea functionalized low-molecular-weight polyisobutylenes (PIBUT) are investigated. The polymers, which can interact through supramolecular hydrogen bonds, can self-organize over... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_72989006" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">ABSTRACT The rheological and adhesive properties of bis-urea functionalized low-molecular-weight polyisobutylenes (PIBUT) are investigated. The polymers, which can interact through supramolecular hydrogen bonds, can self-organize over times of the order of days at room temperature. This organized structure has been identified by small angle X-ray scattering (SAXS) and its rheological properties indicate the behaviour of a soft viscoelastic gel. The ordered structure can be disrupted by temperature and shear so that at 80 °C, the material behaves as a highly viscoelastic fluid and no SAXS peak is observed. When cooled back at room temperature, the PIBUT retrieves its ordered structure and gel properties after 20 h of annealing. This very slow molecular dynamics gives PIBUT a highly dissipative nature upon deformation, which combined with strongly interacting moieties results in very interesting adhesive properties both on steel surfaces but more importantly on typical low adhesion surfaces such as silicone. A strategy based on the controlled incorporation of supramolecular bonds in a covalently crosslinked network appears promising for the development of a new generation of highly interacting and dissipative soft adhesives.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/72989006" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="40907845" href="https://independent.academia.edu/CorinneChaneac">Corinne Chaneac</a><script data-card-contents-for-user="40907845" type="text/json">{"id":40907845,"first_name":"Corinne","last_name":"Chaneac","domain_name":"independent","page_name":"CorinneChaneac","display_name":"Corinne Chaneac","profile_url":"https://independent.academia.edu/CorinneChaneac?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_72989006 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="72989006"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 72989006, container: ".js-paper-rank-work_72989006", }); 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$(".js-view-count[data-work-id=72989006]").text(description); $(".js-view-count-work_72989006").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_72989006").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="72989006"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">9</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="48" rel="nofollow" href="https://www.academia.edu/Documents/in/Engineering">Engineering</a>, <script data-card-contents-for-ri="48" type="text/json">{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="511" rel="nofollow" href="https://www.academia.edu/Documents/in/Materials_Science">Materials Science</a>, <script data-card-contents-for-ri="511" type="text/json">{"id":511,"name":"Materials Science","url":"https://www.academia.edu/Documents/in/Materials_Science?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="4493" rel="nofollow" href="https://www.academia.edu/Documents/in/Supramolecular_Chemistry">Supramolecular Chemistry</a>, <script data-card-contents-for-ri="4493" type="text/json">{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="7598" rel="nofollow" href="https://www.academia.edu/Documents/in/Rheology">Rheology</a><script data-card-contents-for-ri="7598" type="text/json">{"id":7598,"name":"Rheology","url":"https://www.academia.edu/Documents/in/Rheology?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=72989006]'), work: {"id":72989006,"title":"Supramolecular Soft Adhesive Materials","created_at":"2022-03-03T22:34:15.194-08:00","url":"https://www.academia.edu/72989006/Supramolecular_Soft_Adhesive_Materials?f_ri=4493","dom_id":"work_72989006","summary":"ABSTRACT The rheological and adhesive properties of bis-urea functionalized low-molecular-weight polyisobutylenes (PIBUT) are investigated. The polymers, which can interact through supramolecular hydrogen bonds, can self-organize over times of the order of days at room temperature. This organized structure has been identified by small angle X-ray scattering (SAXS) and its rheological properties indicate the behaviour of a soft viscoelastic gel. The ordered structure can be disrupted by temperature and shear so that at 80 °C, the material behaves as a highly viscoelastic fluid and no SAXS peak is observed. When cooled back at room temperature, the PIBUT retrieves its ordered structure and gel properties after 20 h of annealing. This very slow molecular dynamics gives PIBUT a highly dissipative nature upon deformation, which combined with strongly interacting moieties results in very interesting adhesive properties both on steel surfaces but more importantly on typical low adhesion surfaces such as silicone. A strategy based on the controlled incorporation of supramolecular bonds in a covalently crosslinked network appears promising for the development of a new generation of highly interacting and dissipative soft adhesives.","downloadable_attachments":[],"ordered_authors":[{"id":40907845,"first_name":"Corinne","last_name":"Chaneac","domain_name":"independent","page_name":"CorinneChaneac","display_name":"Corinne Chaneac","profile_url":"https://independent.academia.edu/CorinneChaneac?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=4493","nofollow":true},{"id":511,"name":"Materials Science","url":"https://www.academia.edu/Documents/in/Materials_Science?f_ri=4493","nofollow":true},{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":7598,"name":"Rheology","url":"https://www.academia.edu/Documents/in/Rheology?f_ri=4493","nofollow":true},{"id":42597,"name":"Adhesive","url":"https://www.academia.edu/Documents/in/Adhesive?f_ri=4493"},{"id":71615,"name":"Advanced Functional Materials","url":"https://www.academia.edu/Documents/in/Advanced_Functional_Materials?f_ri=4493"},{"id":118582,"name":"Physical sciences","url":"https://www.academia.edu/Documents/in/Physical_sciences?f_ri=4493"},{"id":209515,"name":"Interface","url":"https://www.academia.edu/Documents/in/Interface?f_ri=4493"},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_57364669" data-work_id="57364669" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/57364669/1_10_Phenanthroline_A_versatile_building_block_for_the_construction_of_ligands_for_various_purposes">1,10-Phenanthroline: A versatile building block for the construction of ligands for various purposes</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">This review will cover the developments in the chemistry of phenanthroline-based ligands in the last 10-15 years. 1,10-Phenanthroline (phen) is a classic ligand in coordination chemistry, which couples versatility in metal ion binding... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_57364669" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">This review will cover the developments in the chemistry of phenanthroline-based ligands in the last 10-15 years. 1,10-Phenanthroline (phen) is a classic ligand in coordination chemistry, which couples versatility in metal ion binding with peculiar properties of its complexes. For instance, metal complexes with phenanthroline can be featured by an intense luminescence or can interact with DNA in an intercalative fashion inducing, in some cases, DNA cleavage. For this reason a number of phenanthroline-containing ligands has been recently synthesized by inserting phenanthroline within open-chain or macrocyclic backbone, in order to develop new molecular chemosensors for metal cations and anions, ionophores as well as new intercalating agents for polynucleotides. Furthermore, phenanthroline is rigid and its insertion within cyclic or acyclic structures can impart to the resulting ligand a high degree of pre-organization, affording selective complexing agents. This review will discuss on the coordination, luminescence and intercalating and/or DNA cleaving properties as well as on analytical applications of metal complexes with phenanthroline-based ligands. Particular attention will be devoted to macrocyclic receptors or openchain ligands that, beside the phenanthroline nitrogen atoms, contain other donor atoms able to interact with the metal cations or anions.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/57364669" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="9bcd0c36ad0ee79a2763094be38aaa5d" rel="nofollow" data-download="{"attachment_id":72303275,"asset_id":57364669,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/72303275/download_file?st=MTc0MDk5NDU5MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="78119121" href="https://independent.academia.edu/BenciniAndrea">Andrea Bencini</a><script data-card-contents-for-user="78119121" type="text/json">{"id":78119121,"first_name":"Andrea","last_name":"Bencini","domain_name":"independent","page_name":"BenciniAndrea","display_name":"Andrea Bencini","profile_url":"https://independent.academia.edu/BenciniAndrea?f_ri=4493","photo":"https://0.academia-photos.com/78119121/74755630/63256789/s65_andrea.bencini.png"}</script></span></span></li><li class="js-paper-rank-work_57364669 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="57364669"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 57364669, container: ".js-paper-rank-work_57364669", }); 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$(".js-view-count[data-work-id=57364669]").text(description); $(".js-view-count-work_57364669").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_57364669").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="57364669"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">6</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="530" rel="nofollow" href="https://www.academia.edu/Documents/in/Inorganic_Chemistry">Inorganic Chemistry</a>, <script data-card-contents-for-ri="530" type="text/json">{"id":530,"name":"Inorganic Chemistry","url":"https://www.academia.edu/Documents/in/Inorganic_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="4493" rel="nofollow" href="https://www.academia.edu/Documents/in/Supramolecular_Chemistry">Supramolecular Chemistry</a>, <script data-card-contents-for-ri="4493" type="text/json">{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="29916" rel="nofollow" href="https://www.academia.edu/Documents/in/PET">PET</a>, <script data-card-contents-for-ri="29916" type="text/json">{"id":29916,"name":"PET","url":"https://www.academia.edu/Documents/in/PET?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="55405" rel="nofollow" href="https://www.academia.edu/Documents/in/Sensors">Sensors</a><script data-card-contents-for-ri="55405" type="text/json">{"id":55405,"name":"Sensors","url":"https://www.academia.edu/Documents/in/Sensors?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=57364669]'), work: {"id":57364669,"title":"1,10-Phenanthroline: A versatile building block for the construction of ligands for various purposes","created_at":"2021-10-12T11:54:55.492-07:00","url":"https://www.academia.edu/57364669/1_10_Phenanthroline_A_versatile_building_block_for_the_construction_of_ligands_for_various_purposes?f_ri=4493","dom_id":"work_57364669","summary":"This review will cover the developments in the chemistry of phenanthroline-based ligands in the last 10-15 years. 1,10-Phenanthroline (phen) is a classic ligand in coordination chemistry, which couples versatility in metal ion binding with peculiar properties of its complexes. For instance, metal complexes with phenanthroline can be featured by an intense luminescence or can interact with DNA in an intercalative fashion inducing, in some cases, DNA cleavage. For this reason a number of phenanthroline-containing ligands has been recently synthesized by inserting phenanthroline within open-chain or macrocyclic backbone, in order to develop new molecular chemosensors for metal cations and anions, ionophores as well as new intercalating agents for polynucleotides. Furthermore, phenanthroline is rigid and its insertion within cyclic or acyclic structures can impart to the resulting ligand a high degree of pre-organization, affording selective complexing agents. This review will discuss on the coordination, luminescence and intercalating and/or DNA cleaving properties as well as on analytical applications of metal complexes with phenanthroline-based ligands. Particular attention will be devoted to macrocyclic receptors or openchain ligands that, beside the phenanthroline nitrogen atoms, contain other donor atoms able to interact with the metal cations or anions.","downloadable_attachments":[{"id":72303275,"asset_id":57364669,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":78119121,"first_name":"Andrea","last_name":"Bencini","domain_name":"independent","page_name":"BenciniAndrea","display_name":"Andrea Bencini","profile_url":"https://independent.academia.edu/BenciniAndrea?f_ri=4493","photo":"https://0.academia-photos.com/78119121/74755630/63256789/s65_andrea.bencini.png"}],"research_interests":[{"id":530,"name":"Inorganic Chemistry","url":"https://www.academia.edu/Documents/in/Inorganic_Chemistry?f_ri=4493","nofollow":true},{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":29916,"name":"PET","url":"https://www.academia.edu/Documents/in/PET?f_ri=4493","nofollow":true},{"id":55405,"name":"Sensors","url":"https://www.academia.edu/Documents/in/Sensors?f_ri=4493","nofollow":true},{"id":141523,"name":"FRET","url":"https://www.academia.edu/Documents/in/FRET?f_ri=4493"},{"id":468416,"name":"Ecl","url":"https://www.academia.edu/Documents/in/Ecl?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_40455356" data-work_id="40455356" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/40455356/A_Review_about_Regulatory_Status_and_Recent_Patents_of_Pharmaceutical_Co_Crystals">A Review about Regulatory Status and Recent Patents of Pharmaceutical Co-Crystals</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Introduction Pharmaceutical co-crystals have established a new paradigm in the solid-state modification. The formation of API co-crystal offers a wide range of physical and chemical enhancements to the properties of drugs without altering... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_40455356" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Introduction Pharmaceutical co-crystals have established a new paradigm in the solid-state modification. The formation of API co-crystal offers a wide range of physical and chemical enhancements to the properties of drugs without altering their chemical nature, thereby maintaining its pharmaceutical importance as such. 1 This is evident from the fact that regulatory bodies like United States Food and Drug Administration (USFDA) and European Medicines Agency (EMA) have published regulatory guidelines to clarify the status of co-crystals in their respective regions. Pharmaceutical and Biotechnology companies rely upon intellectual protection for safeguarding their products. In order to maintain revenues generated through these products as a means to recover the resources and money spent on research and development, the presence of proper regulatory guidelines is expected to significantly affect the development and quality control as well as intellectual properties aspects of pharmaceutical cocrystals and their formulations. 2 However, the concern that remains unanswered is whether the standard development and manufacturing processes that were initially designed for salt-based formulations can also be used for co-crystal based formulations in order to achieve the desired product quality that is required to ensure the safety and efficacy. 3 Moreover, from regulatory perspective the addition of another component to the drug formulation could mandate additional bioequivalence, clinical and toxicity studies.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/40455356" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="9de1423f4c4b6dd5a8fd75902afccc5e" rel="nofollow" data-download="{"attachment_id":60719241,"asset_id":40455356,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/60719241/download_file?st=MTc0MDk5NDU5MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="515217" href="https://gfitm.academia.edu/ArunKumar">Arun Kumar</a><script data-card-contents-for-user="515217" type="text/json">{"id":515217,"first_name":"Arun","last_name":"Kumar","domain_name":"gfitm","page_name":"ArunKumar","display_name":"Arun Kumar","profile_url":"https://gfitm.academia.edu/ArunKumar?f_ri=4493","photo":"https://0.academia-photos.com/515217/19930848/19732795/s65_arun.kumar.jpg"}</script></span></span></li><li class="js-paper-rank-work_40455356 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="40455356"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 40455356, container: ".js-paper-rank-work_40455356", }); 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$(".js-view-count[data-work-id=40455356]").text(description); $(".js-view-count-work_40455356").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_40455356").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="40455356"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">5</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="4493" rel="nofollow" href="https://www.academia.edu/Documents/in/Supramolecular_Chemistry">Supramolecular Chemistry</a>, <script data-card-contents-for-ri="4493" type="text/json">{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="10704" rel="nofollow" href="https://www.academia.edu/Documents/in/Crystal_Engineering">Crystal Engineering</a>, <script data-card-contents-for-ri="10704" type="text/json">{"id":10704,"name":"Crystal Engineering","url":"https://www.academia.edu/Documents/in/Crystal_Engineering?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="70379" rel="nofollow" href="https://www.academia.edu/Documents/in/Pharmaceutical_Co-crystals">Pharmaceutical Co-crystals</a>, <script data-card-contents-for-ri="70379" type="text/json">{"id":70379,"name":"Pharmaceutical Co-crystals","url":"https://www.academia.edu/Documents/in/Pharmaceutical_Co-crystals?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="873824" rel="nofollow" href="https://www.academia.edu/Documents/in/Pharmaceutical_Cocrystals">Pharmaceutical Cocrystals</a><script data-card-contents-for-ri="873824" type="text/json">{"id":873824,"name":"Pharmaceutical Cocrystals","url":"https://www.academia.edu/Documents/in/Pharmaceutical_Cocrystals?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=40455356]'), work: {"id":40455356,"title":"A Review about Regulatory Status and Recent Patents of Pharmaceutical Co-Crystals","created_at":"2019-09-27T02:54:39.645-07:00","url":"https://www.academia.edu/40455356/A_Review_about_Regulatory_Status_and_Recent_Patents_of_Pharmaceutical_Co_Crystals?f_ri=4493","dom_id":"work_40455356","summary":"Introduction Pharmaceutical co-crystals have established a new paradigm in the solid-state modification. The formation of API co-crystal offers a wide range of physical and chemical enhancements to the properties of drugs without altering their chemical nature, thereby maintaining its pharmaceutical importance as such. 1 This is evident from the fact that regulatory bodies like United States Food and Drug Administration (USFDA) and European Medicines Agency (EMA) have published regulatory guidelines to clarify the status of co-crystals in their respective regions. Pharmaceutical and Biotechnology companies rely upon intellectual protection for safeguarding their products. In order to maintain revenues generated through these products as a means to recover the resources and money spent on research and development, the presence of proper regulatory guidelines is expected to significantly affect the development and quality control as well as intellectual properties aspects of pharmaceutical cocrystals and their formulations. 2 However, the concern that remains unanswered is whether the standard development and manufacturing processes that were initially designed for salt-based formulations can also be used for co-crystal based formulations in order to achieve the desired product quality that is required to ensure the safety and efficacy. 3 Moreover, from regulatory perspective the addition of another component to the drug formulation could mandate additional bioequivalence, clinical and toxicity studies.","downloadable_attachments":[{"id":60719241,"asset_id":40455356,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":515217,"first_name":"Arun","last_name":"Kumar","domain_name":"gfitm","page_name":"ArunKumar","display_name":"Arun Kumar","profile_url":"https://gfitm.academia.edu/ArunKumar?f_ri=4493","photo":"https://0.academia-photos.com/515217/19930848/19732795/s65_arun.kumar.jpg"}],"research_interests":[{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":10704,"name":"Crystal Engineering","url":"https://www.academia.edu/Documents/in/Crystal_Engineering?f_ri=4493","nofollow":true},{"id":70379,"name":"Pharmaceutical Co-crystals","url":"https://www.academia.edu/Documents/in/Pharmaceutical_Co-crystals?f_ri=4493","nofollow":true},{"id":873824,"name":"Pharmaceutical Cocrystals","url":"https://www.academia.edu/Documents/in/Pharmaceutical_Cocrystals?f_ri=4493","nofollow":true},{"id":893974,"name":"Cocrystals","url":"https://www.academia.edu/Documents/in/Cocrystals?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_72949792" data-work_id="72949792" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/72949792/Supramolecular_Chirality_of_Hydrogen_Bonded_Rosette_Assemblies">Supramolecular Chirality of Hydrogen-Bonded Rosette Assemblies</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The control of chirality in synthetic self-assembled systems remains challenging because of their lower stability and their higher susceptibility to racemization when compared to covalent systems. In this review the supramolecular... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_72949792" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The control of chirality in synthetic self-assembled systems remains challenging because of their lower stability and their higher susceptibility to racemization when compared to covalent systems. In this review the supramolecular chirality of noncovalent hydrogen-bonded assemblies formed by multiple cooperative hydrogenbonds between calix[4]arene dimelamines and cyanurates or barbiturates derivatives (rosette assemblies) are described. It is shown that the amplification of chirality (a high enantiomeric or diastereomeric excess induced by a small initial amount of chiral bias) of double and tetrarosette assemblies is influenced by bulky substitution on their components and electronic properties of the substituents as well as their proximity to the rosette core. In the absence of chiral centers in their components, the assemblies form as a racemic mixture of both enantiomers (P and M). The synthesis of enantiomerically pure rosette assemblies is conducted via induction of chirality ...</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/72949792" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="c7de7a015252788c64820a6cf6861543" rel="nofollow" data-download="{"attachment_id":81668002,"asset_id":72949792,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/81668002/download_file?st=MTc0MDk5NDU5MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="32788193" href="https://independent.academia.edu/DavidReinhoudt">David Reinhoudt</a><script data-card-contents-for-user="32788193" type="text/json">{"id":32788193,"first_name":"David","last_name":"Reinhoudt","domain_name":"independent","page_name":"DavidReinhoudt","display_name":"David Reinhoudt","profile_url":"https://independent.academia.edu/DavidReinhoudt?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_72949792 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="72949792"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 72949792, container: ".js-paper-rank-work_72949792", }); 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$(".js-view-count[data-work-id=72949792]").text(description); $(".js-view-count-work_72949792").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_72949792").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="72949792"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">6</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="523" rel="nofollow" href="https://www.academia.edu/Documents/in/Chemistry">Chemistry</a>, <script data-card-contents-for-ri="523" type="text/json">{"id":523,"name":"Chemistry","url":"https://www.academia.edu/Documents/in/Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="4493" rel="nofollow" href="https://www.academia.edu/Documents/in/Supramolecular_Chemistry">Supramolecular Chemistry</a>, <script data-card-contents-for-ri="4493" type="text/json">{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="189984" rel="nofollow" href="https://www.academia.edu/Documents/in/Electronic_properties">Electronic properties</a>, <script data-card-contents-for-ri="189984" type="text/json">{"id":189984,"name":"Electronic properties","url":"https://www.academia.edu/Documents/in/Electronic_properties?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="240148" rel="nofollow" href="https://www.academia.edu/Documents/in/Hydrogen_Bond">Hydrogen Bond</a><script data-card-contents-for-ri="240148" type="text/json">{"id":240148,"name":"Hydrogen Bond","url":"https://www.academia.edu/Documents/in/Hydrogen_Bond?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=72949792]'), work: {"id":72949792,"title":"Supramolecular Chirality of Hydrogen-Bonded Rosette Assemblies","created_at":"2022-03-03T12:11:39.759-08:00","url":"https://www.academia.edu/72949792/Supramolecular_Chirality_of_Hydrogen_Bonded_Rosette_Assemblies?f_ri=4493","dom_id":"work_72949792","summary":"The control of chirality in synthetic self-assembled systems remains challenging because of their lower stability and their higher susceptibility to racemization when compared to covalent systems. In this review the supramolecular chirality of noncovalent hydrogen-bonded assemblies formed by multiple cooperative hydrogenbonds between calix[4]arene dimelamines and cyanurates or barbiturates derivatives (rosette assemblies) are described. It is shown that the amplification of chirality (a high enantiomeric or diastereomeric excess induced by a small initial amount of chiral bias) of double and tetrarosette assemblies is influenced by bulky substitution on their components and electronic properties of the substituents as well as their proximity to the rosette core. In the absence of chiral centers in their components, the assemblies form as a racemic mixture of both enantiomers (P and M). The synthesis of enantiomerically pure rosette assemblies is conducted via induction of chirality ...","downloadable_attachments":[{"id":81668002,"asset_id":72949792,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":32788193,"first_name":"David","last_name":"Reinhoudt","domain_name":"independent","page_name":"DavidReinhoudt","display_name":"David Reinhoudt","profile_url":"https://independent.academia.edu/DavidReinhoudt?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":523,"name":"Chemistry","url":"https://www.academia.edu/Documents/in/Chemistry?f_ri=4493","nofollow":true},{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":189984,"name":"Electronic properties","url":"https://www.academia.edu/Documents/in/Electronic_properties?f_ri=4493","nofollow":true},{"id":240148,"name":"Hydrogen Bond","url":"https://www.academia.edu/Documents/in/Hydrogen_Bond?f_ri=4493","nofollow":true},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=4493"},{"id":2261988,"name":"Highly Oriented Pyrolytic Graphite","url":"https://www.academia.edu/Documents/in/Highly_Oriented_Pyrolytic_Graphite?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_4094755" data-work_id="4094755" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/4094755/Single_atom_catalysis_of_CO_oxidation_using_Pt1_FeOx">Single-atom catalysis of CO oxidation using Pt1/FeOx</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Platinum-based heterogeneous catalysts are critical to many important commercial chemical processes, but their efficiency is extremely low on a per metal atom basis, because only the surface active-site atoms are used. Catalysts with... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_4094755" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Platinum-based heterogeneous catalysts are critical to many important commercial chemical processes, but their efficiency is extremely low on a per metal atom basis, because only the surface active-site atoms are used. Catalysts with single-atom dispersions are thus highly desirable to maximize atom efficiency, but making them is challenging. Here we report the synthesis of a single-atom catalyst that consists of only isolated single Pt atoms anchored to the surfaces of iron oxide nanocrystallites. This single-atom catalyst has extremely high atom efficiency and shows excellent stability and high activity for both CO oxidation and preferential oxidation of CO in H2. Density functional theory calculations show that the high catalytic activity correlates with the partially vacant 5d orbitals of the positively charged, high-valent Pt atoms, which help to reduce both the CO adsorption energy and the activation barriers for CO oxidation.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/4094755" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="af4fe151991272bc5654eb898cfa0c9f" rel="nofollow" data-download="{"attachment_id":50036102,"asset_id":4094755,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/50036102/download_file?st=MTc0MDk5NDU5MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="4938913" href="https://spring8.academia.edu/YitaoCui">Yitao Cui</a><script data-card-contents-for-user="4938913" type="text/json">{"id":4938913,"first_name":"Yitao","last_name":"Cui","domain_name":"spring8","page_name":"YitaoCui","display_name":"Yitao Cui","profile_url":"https://spring8.academia.edu/YitaoCui?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_4094755 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="4094755"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 4094755, container: ".js-paper-rank-work_4094755", }); 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$(".js-view-count[data-work-id=4094755]").text(description); $(".js-view-count-work_4094755").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_4094755").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="4094755"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">56</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="145" rel="nofollow" href="https://www.academia.edu/Documents/in/Biochemistry">Biochemistry</a>, <script data-card-contents-for-ri="145" type="text/json">{"id":145,"name":"Biochemistry","url":"https://www.academia.edu/Documents/in/Biochemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="522" rel="nofollow" href="https://www.academia.edu/Documents/in/Thermodynamics">Thermodynamics</a>, <script data-card-contents-for-ri="522" type="text/json">{"id":522,"name":"Thermodynamics","url":"https://www.academia.edu/Documents/in/Thermodynamics?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="523" rel="nofollow" href="https://www.academia.edu/Documents/in/Chemistry">Chemistry</a>, <script data-card-contents-for-ri="523" type="text/json">{"id":523,"name":"Chemistry","url":"https://www.academia.edu/Documents/in/Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="528" rel="nofollow" href="https://www.academia.edu/Documents/in/Computational_Chemistry">Computational Chemistry</a><script data-card-contents-for-ri="528" type="text/json">{"id":528,"name":"Computational Chemistry","url":"https://www.academia.edu/Documents/in/Computational_Chemistry?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=4094755]'), work: {"id":4094755,"title":"Single-atom catalysis of CO oxidation using Pt1/FeOx","created_at":"2013-07-23T23:49:58.166-07:00","url":"https://www.academia.edu/4094755/Single_atom_catalysis_of_CO_oxidation_using_Pt1_FeOx?f_ri=4493","dom_id":"work_4094755","summary":"Platinum-based heterogeneous catalysts are critical to many important commercial chemical processes, but their efficiency is extremely low on a per metal atom basis, because only the surface active-site atoms are used. Catalysts with single-atom dispersions are thus highly desirable to maximize atom efficiency, but making them is challenging. Here we report the synthesis of a single-atom catalyst that consists of only isolated single Pt atoms anchored to the surfaces of iron oxide nanocrystallites. This single-atom catalyst has extremely high atom efficiency and shows excellent stability and high activity for both CO oxidation and preferential oxidation of CO in H2. Density functional theory calculations show that the high catalytic activity correlates with the partially vacant 5d orbitals of the positively charged, high-valent Pt atoms, which help to reduce both the CO adsorption energy and the activation barriers for CO oxidation.","downloadable_attachments":[{"id":50036102,"asset_id":4094755,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":4938913,"first_name":"Yitao","last_name":"Cui","domain_name":"spring8","page_name":"YitaoCui","display_name":"Yitao 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} })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_72841237" data-work_id="72841237" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" rel="nofollow" href="https://www.academia.edu/72841237/Cooperativity_and_the_Chelate_Macrocyclic_and_Cryptate_Effects">Cooperativity and the Chelate, Macrocyclic and Cryptate Effects</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The interrelationships between cooperativity and the chelate, macrocyclic, and cryptate effects are described in this chapter. The chapter begins by defining and providing a brief historical background of these four closely related... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_72841237" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The interrelationships between cooperativity and the chelate, macrocyclic, and cryptate effects are described in this chapter. The chapter begins by defining and providing a brief historical background of these four closely related effects as they pertain to both transition metal coordination chemistry and supramolecular chemistry. The second section provides an overview of bonding for supramolecular chemistry with a comparison illustrating similarities with and differences from transition metal coordination. Sections 3 and 4 describe the chemistry of the chelate, macrocyclic, and cryptate effects and the important role that cooperativity plays in each for transition metals coordination and supramolecular chemistry, respectively. Thermodynamic aspects and structural foundations for the increasing stability of complexes as they evolve from chelates through cryptates are also described. Section 4 on supramolecular chemistry is further divided into sections on the chemistry of cations, followed by anions. A short conclusion is provided at the end of the chapter. Throughout the chapter, examples are provided that illustrate the manner in which these important chemical effects are manifested. Keywords: cooperativity; chelate effect; macrocyclic effect; cryptate effect; supramolecular; thermodynamics; anion coordination; crown ethers</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/72841237" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="6214711" href="https://kansas.academia.edu/VictorDay">Victor Day</a><script data-card-contents-for-user="6214711" type="text/json">{"id":6214711,"first_name":"Victor","last_name":"Day","domain_name":"kansas","page_name":"VictorDay","display_name":"Victor Day","profile_url":"https://kansas.academia.edu/VictorDay?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_72841237 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="72841237"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 72841237, container: ".js-paper-rank-work_72841237", }); 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$(".js-view-count[data-work-id=72841237]").text(description); $(".js-view-count-work_72841237").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_72841237").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="72841237"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">4</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="522" rel="nofollow" href="https://www.academia.edu/Documents/in/Thermodynamics">Thermodynamics</a>, <script data-card-contents-for-ri="522" type="text/json">{"id":522,"name":"Thermodynamics","url":"https://www.academia.edu/Documents/in/Thermodynamics?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="523" rel="nofollow" href="https://www.academia.edu/Documents/in/Chemistry">Chemistry</a>, <script data-card-contents-for-ri="523" type="text/json">{"id":523,"name":"Chemistry","url":"https://www.academia.edu/Documents/in/Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="4493" rel="nofollow" href="https://www.academia.edu/Documents/in/Supramolecular_Chemistry">Supramolecular Chemistry</a>, <script data-card-contents-for-ri="4493" type="text/json">{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="477719" rel="nofollow" href="https://www.academia.edu/Documents/in/Cooperativity">Cooperativity</a><script data-card-contents-for-ri="477719" type="text/json">{"id":477719,"name":"Cooperativity","url":"https://www.academia.edu/Documents/in/Cooperativity?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=72841237]'), work: {"id":72841237,"title":"Cooperativity and the Chelate, Macrocyclic and Cryptate Effects","created_at":"2022-03-02T15:43:29.549-08:00","url":"https://www.academia.edu/72841237/Cooperativity_and_the_Chelate_Macrocyclic_and_Cryptate_Effects?f_ri=4493","dom_id":"work_72841237","summary":"The interrelationships between cooperativity and the chelate, macrocyclic, and cryptate effects are described in this chapter. The chapter begins by defining and providing a brief historical background of these four closely related effects as they pertain to both transition metal coordination chemistry and supramolecular chemistry. The second section provides an overview of bonding for supramolecular chemistry with a comparison illustrating similarities with and differences from transition metal coordination. Sections 3 and 4 describe the chemistry of the chelate, macrocyclic, and cryptate effects and the important role that cooperativity plays in each for transition metals coordination and supramolecular chemistry, respectively. Thermodynamic aspects and structural foundations for the increasing stability of complexes as they evolve from chelates through cryptates are also described. Section 4 on supramolecular chemistry is further divided into sections on the chemistry of cations, followed by anions. A short conclusion is provided at the end of the chapter. Throughout the chapter, examples are provided that illustrate the manner in which these important chemical effects are manifested. Keywords: cooperativity; chelate effect; macrocyclic effect; cryptate effect; supramolecular; thermodynamics; anion coordination; crown ethers","downloadable_attachments":[],"ordered_authors":[{"id":6214711,"first_name":"Victor","last_name":"Day","domain_name":"kansas","page_name":"VictorDay","display_name":"Victor Day","profile_url":"https://kansas.academia.edu/VictorDay?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":522,"name":"Thermodynamics","url":"https://www.academia.edu/Documents/in/Thermodynamics?f_ri=4493","nofollow":true},{"id":523,"name":"Chemistry","url":"https://www.academia.edu/Documents/in/Chemistry?f_ri=4493","nofollow":true},{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":477719,"name":"Cooperativity","url":"https://www.academia.edu/Documents/in/Cooperativity?f_ri=4493","nofollow":true}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_4274340" data-work_id="4274340" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/4274340/Designing_Biostable_Polyurethane_Elastomers_for_Biomedical_Implants">Designing Biostable Polyurethane Elastomers for Biomedical Implants</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The chemical structure, synthesis, morphology, and properties of polyurethane elastomers are briefly discussed. The current understanding of the effect of chemical structure and the associated morphology on the stability of polyurethanes... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_4274340" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The chemical structure, synthesis, morphology, and properties of polyurethane elastomers are briefly discussed. The current understanding of the effect of chemical structure and the associated morphology on the stability of polyurethanes in the biological environments is reviewed. The degradation of conventional polyurethanes appears as surface or deep cracking, stiffening, and deterioration of mechanical properties, such as flex-fatigue resistance. Polyester and poly(tetramethylene oxide) based polyurethanes degrade by hydrolytic and oxidative degradation of ester and ether functional groups, respectively. The recent approaches to develop polyurethanes with improved longterm biostability are based on developing novel polyether, hydrocarbon, polycarbonate, and siloxane macrodiols to replace degradation-prone polyester and polyether macrodiols in polyurethane formulations. The new approaches are discussed with respect to synthesis, properties and biostability based on reported in vivo studies. Among the newly developed materials, siloxane-based polyurethanes have exhibited excellent biostability and are expected to find many applications in biomedical implants.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/4274340" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="bcf4591b843af0e1ef636bd8ad97bb09" rel="nofollow" data-download="{"attachment_id":40916257,"asset_id":4274340,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/40916257/download_file?st=MTc0MDk5NDU5MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="5187035" href="https://independent.academia.edu/SimonMcCarthy1">Simon J McCarthy</a><script data-card-contents-for-user="5187035" type="text/json">{"id":5187035,"first_name":"Simon","last_name":"McCarthy","domain_name":"independent","page_name":"SimonMcCarthy1","display_name":"Simon J McCarthy","profile_url":"https://independent.academia.edu/SimonMcCarthy1?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_4274340 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="4274340"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 4274340, container: ".js-paper-rank-work_4274340", }); 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The current understanding of the effect of chemical structure and the associated morphology on the stability of polyurethanes in the biological environments is reviewed. The degradation of conventional polyurethanes appears as surface or deep cracking, stiffening, and deterioration of mechanical properties, such as flex-fatigue resistance. Polyester and poly(tetramethylene oxide) based polyurethanes degrade by hydrolytic and oxidative degradation of ester and ether functional groups, respectively. The recent approaches to develop polyurethanes with improved longterm biostability are based on developing novel polyether, hydrocarbon, polycarbonate, and siloxane macrodiols to replace degradation-prone polyester and polyether macrodiols in polyurethane formulations. The new approaches are discussed with respect to synthesis, properties and biostability based on reported in vivo studies. Among the newly developed materials, siloxane-based polyurethanes have exhibited excellent biostability and are expected to find many applications in biomedical implants.","downloadable_attachments":[{"id":40916257,"asset_id":4274340,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":5187035,"first_name":"Simon","last_name":"McCarthy","domain_name":"independent","page_name":"SimonMcCarthy1","display_name":"Simon J McCarthy","profile_url":"https://independent.academia.edu/SimonMcCarthy1?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry?f_ri=4493","nofollow":true},{"id":528,"name":"Computational Chemistry","url":"https://www.academia.edu/Documents/in/Computational_Chemistry?f_ri=4493","nofollow":true},{"id":529,"name":"Quantum 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Separation","url":"https://www.academia.edu/Documents/in/Phase_Separation?f_ri=4493"},{"id":610960,"name":"Australian","url":"https://www.academia.edu/Documents/in/Australian?f_ri=4493"},{"id":627110,"name":"BioSensors","url":"https://www.academia.edu/Documents/in/BioSensors-1?f_ri=4493"},{"id":1199463,"name":"Combinatorial","url":"https://www.academia.edu/Documents/in/Combinatorial?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_10682616" data-work_id="10682616" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/10682616/Oxyhalogen_Sulfur_Chemistry_Kinetics_and_Mechanism_of_Oxidation_of_N_Acetyl_Homocysteine_Thiolactone_by_Acidified_Bromate_and_Aqueous_Bromine">Oxyhalogen-Sulfur Chemistry: Kinetics and Mechanism of Oxidation of N -Acetyl Homocysteine Thiolactone by Acidified Bromate and Aqueous Bromine</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The kinetics and mechanism of the oxidation of the biologically important molecule, cysteamine, by acidic bromate and molecular bromine have been studied. In excess acidic bromate conditions, cysteamine is oxidized to Nbrominated... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_10682616" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The kinetics and mechanism of the oxidation of the biologically important molecule, cysteamine, by acidic bromate and molecular bromine have been studied. In excess acidic bromate conditions, cysteamine is oxidized to Nbrominated derivatives, and in excess cysteamine the oxidation product is taurine according to the following stoichiometry: BrO 3 -+ H 2 NCH 2 CH 2 SH ÷ H 2 NCH 2 CH 2 SO 3 H + Br -. There is quantitative formation of taurine before N-bromination commences. Excess aqueous bromine oxidizes cysteamine to give dibromotaurine: 5Br 2 + H 2 NCH 2 CH 2 SH + 3H 2 O ÷ Br 2 NCH 2 CH 2 SO 3 H + 8Br -+ 8H + , while excess cysteamine conditions gave monobromotaurine. The oxidation of cysteamine by aqueous bromine is effectively diffusion-controlled all the way to the formation of monobromotaurine. Further formation of dibromotaurine is dependent on acid concentrations, with highly acidic conditions inhibiting further reaction towards formation of dibromotaurine. The formation of the N-brominated derivatives of taurine is reversible, with taurine regenerated in the presence of a reducing agent such as iodide. This feature makes it possible for taurine to moderate hypobromous acid toxicity in the physiological environment.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/10682616" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="28b91119c9b78c04ec18702c26d19fe6" rel="nofollow" data-download="{"attachment_id":47207351,"asset_id":10682616,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/47207351/download_file?st=MTc0MDk5NDU5MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="26075780" href="https://independent.academia.edu/BiceMartincigh">Bice Martincigh</a><script data-card-contents-for-user="26075780" type="text/json">{"id":26075780,"first_name":"Bice","last_name":"Martincigh","domain_name":"independent","page_name":"BiceMartincigh","display_name":"Bice Martincigh","profile_url":"https://independent.academia.edu/BiceMartincigh?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_10682616 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="10682616"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 10682616, container: ".js-paper-rank-work_10682616", }); 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nanotechnology</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Figure 10. UV-vis spectra (A) and TEM images and size distributions (B) of (a) [AuCl 4 ]before reduction; dodecanethiol-AuNPs (b) as prepared and after heat treatment at (c) 150, (d) 190, and (e) 230°C; and (f) octadecanethiol-AuNPs... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_840642" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Figure 10. UV-vis spectra (A) and TEM images and size distributions (B) of (a) [AuCl 4 ]before reduction; dodecanethiol-AuNPs (b) as prepared and after heat treatment at (c) 150, (d) 190, and (e) 230°C; and (f) octadecanethiol-AuNPs heat-treated at 250°C. 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By definition, these constructs... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_4886956" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The core objective of nanoparticles is to control and manipulate biomacromolecular constructs and supramolecular assemblies that are critical to living cells in order to improve the quality of human health. By definition, these constructs and assemblies are nanoscale and include entities such as drugs, proteins, DNA/RNA, viruses, cellular lipid bilayers, cellular receptor sites and antibody variable regions critical for immunology and are involved in events of nanoscale proportions. The emergence of such nanotherapeutics/diagnostics will allow a deeper understanding of human longevity and human ills that include cancer, cardiovascular disease and genetic disorders. A technology platform that provides a wide range of synthetic nanostructures that may be controlled as a function of size, shape and surface chemistry and scale to these nanotechnical dimensions will be a critical first step in developing appropriate tools and a scientific basis for understanding nanoparticles.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/4886956" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="1d369bdbc4a1c150abf8409dd6a97326" rel="nofollow" data-download="{"attachment_id":32157582,"asset_id":4886956,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/32157582/download_file?st=MTc0MDk5NDU5MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="6368179" href="https://niper.academia.edu/SagarMudshinge">Sagar Mudshinge</a><script data-card-contents-for-user="6368179" type="text/json">{"id":6368179,"first_name":"Sagar","last_name":"Mudshinge","domain_name":"niper","page_name":"SagarMudshinge","display_name":"Sagar Mudshinge","profile_url":"https://niper.academia.edu/SagarMudshinge?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_4886956 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="4886956"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 4886956, container: ".js-paper-rank-work_4886956", }); 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$(".js-view-count[data-work-id=4886956]").text(description); $(".js-view-count-work_4886956").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_4886956").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="4886956"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">9</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="4493" rel="nofollow" href="https://www.academia.edu/Documents/in/Supramolecular_Chemistry">Supramolecular Chemistry</a>, <script data-card-contents-for-ri="4493" type="text/json">{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="11257" rel="nofollow" href="https://www.academia.edu/Documents/in/Drug_delivery">Drug delivery</a>, <script data-card-contents-for-ri="11257" type="text/json">{"id":11257,"name":"Drug delivery","url":"https://www.academia.edu/Documents/in/Drug_delivery?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="13621" rel="nofollow" href="https://www.academia.edu/Documents/in/Nanoparticles">Nanoparticles</a>, <script data-card-contents-for-ri="13621" type="text/json">{"id":13621,"name":"Nanoparticles","url":"https://www.academia.edu/Documents/in/Nanoparticles?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="24735" rel="nofollow" href="https://www.academia.edu/Documents/in/Cardiovascular_disease">Cardiovascular disease</a><script data-card-contents-for-ri="24735" type="text/json">{"id":24735,"name":"Cardiovascular disease","url":"https://www.academia.edu/Documents/in/Cardiovascular_disease?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=4886956]'), work: {"id":4886956,"title":"Nanoparticles: Emerging carriers for drug delivery","created_at":"2013-10-25T04:14:52.936-07:00","url":"https://www.academia.edu/4886956/Nanoparticles_Emerging_carriers_for_drug_delivery?f_ri=4493","dom_id":"work_4886956","summary":"The core objective of nanoparticles is to control and manipulate biomacromolecular constructs and supramolecular assemblies that are critical to living cells in order to improve the quality of human health. By definition, these constructs and assemblies are nanoscale and include entities such as drugs, proteins, DNA/RNA, viruses, cellular lipid bilayers, cellular receptor sites and antibody variable regions critical for immunology and are involved in events of nanoscale proportions. The emergence of such nanotherapeutics/diagnostics will allow a deeper understanding of human longevity and human ills that include cancer, cardiovascular disease and genetic disorders. A technology platform that provides a wide range of synthetic nanostructures that may be controlled as a function of size, shape and surface chemistry and scale to these nanotechnical dimensions will be a critical first step in developing appropriate tools and a scientific basis for understanding nanoparticles.","downloadable_attachments":[{"id":32157582,"asset_id":4886956,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":6368179,"first_name":"Sagar","last_name":"Mudshinge","domain_name":"niper","page_name":"SagarMudshinge","display_name":"Sagar Mudshinge","profile_url":"https://niper.academia.edu/SagarMudshinge?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":11257,"name":"Drug delivery","url":"https://www.academia.edu/Documents/in/Drug_delivery?f_ri=4493","nofollow":true},{"id":13621,"name":"Nanoparticles","url":"https://www.academia.edu/Documents/in/Nanoparticles?f_ri=4493","nofollow":true},{"id":24735,"name":"Cardiovascular disease","url":"https://www.academia.edu/Documents/in/Cardiovascular_disease?f_ri=4493","nofollow":true},{"id":29067,"name":"Surface Chemistry","url":"https://www.academia.edu/Documents/in/Surface_Chemistry?f_ri=4493"},{"id":128132,"name":"Nanostructures","url":"https://www.academia.edu/Documents/in/Nanostructures?f_ri=4493"},{"id":268788,"name":"Human health","url":"https://www.academia.edu/Documents/in/Human_health?f_ri=4493"},{"id":468375,"name":"Genetic Disorder","url":"https://www.academia.edu/Documents/in/Genetic_Disorder?f_ri=4493"},{"id":1145644,"name":"Lipid Bilayer","url":"https://www.academia.edu/Documents/in/Lipid_Bilayer?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_44964079" data-work_id="44964079" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/44964079/ROGER_BOSCOVICH_THE_FOUNDER_OF_MODERN_SCIENCE">ROGER BOSCOVICH - THE FOUNDER OF MODERN SCIENCE</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">In 1758 Roger Boscovich (1711-1787) published "A Theory of natural philosophy reduced to one unique law of forces that exist in nature". The Theory has had a major impact on Boscovich's contemporaries and resulted in many followers in the... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_44964079" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">In 1758 Roger Boscovich (1711-1787) published "A Theory of natural philosophy reduced to one unique law of forces that exist in nature". The Theory has had a major impact on Boscovich's contemporaries and resulted in many followers in the 19th and at the beginning of the 20th century. His life, scientific activity, and philosophical views, as well as his influence on contemporaries and followers, are dealt with in this monograph. The theory is actually the very first quantum theory. He was the first one to draw the orbitals by which some particle moves around particles located in a center and explain that by a transition from one orbital to another a particle either gains or loses a certain amount (quantum) of energy. His primary contribution was to the discovery of the structure of atoms of chemical elements. He anticipated the possibility of the existence of macromolecules (i.e. polymers), nano-tubes neutrino, quarks, gluons, and also the structure of diamond and graphite.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/44964079" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="b0dab679fb2ff31180cf306087cd3b8a" rel="nofollow" data-download="{"attachment_id":65497693,"asset_id":44964079,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/65497693/download_file?st=MTc0MDk5NDU5MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="32697313" href="https://ns.academia.edu/DragoslavStoiljkovic">Dragoslav Stoiljkovic</a><script data-card-contents-for-user="32697313" type="text/json">{"id":32697313,"first_name":"Dragoslav","last_name":"Stoiljkovic","domain_name":"ns","page_name":"DragoslavStoiljkovic","display_name":"Dragoslav Stoiljkovic","profile_url":"https://ns.academia.edu/DragoslavStoiljkovic?f_ri=4493","photo":"https://0.academia-photos.com/32697313/33709860/29925698/s65_dragoslav.stoiljkovic.jpg"}</script></span></span></li><li class="js-paper-rank-work_44964079 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="44964079"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 44964079, container: ".js-paper-rank-work_44964079", }); 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$(".js-view-count[data-work-id=44964079]").text(description); $(".js-view-count-work_44964079").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_44964079").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="44964079"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">20</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="132" rel="nofollow" href="https://www.academia.edu/Documents/in/History_of_Science_and_Technology">History of Science and Technology</a>, <script data-card-contents-for-ri="132" type="text/json">{"id":132,"name":"History of Science and Technology","url":"https://www.academia.edu/Documents/in/History_of_Science_and_Technology?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="518" rel="nofollow" href="https://www.academia.edu/Documents/in/Quantum_Physics">Quantum Physics</a>, <script data-card-contents-for-ri="518" type="text/json">{"id":518,"name":"Quantum Physics","url":"https://www.academia.edu/Documents/in/Quantum_Physics?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="803" rel="nofollow" href="https://www.academia.edu/Documents/in/Philosophy">Philosophy</a>, <script data-card-contents-for-ri="803" type="text/json">{"id":803,"name":"Philosophy","url":"https://www.academia.edu/Documents/in/Philosophy?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="821" rel="nofollow" href="https://www.academia.edu/Documents/in/Philosophy_of_Science">Philosophy of Science</a><script data-card-contents-for-ri="821" type="text/json">{"id":821,"name":"Philosophy of Science","url":"https://www.academia.edu/Documents/in/Philosophy_of_Science?f_ri=4493","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=44964079]'), work: {"id":44964079,"title":"ROGER BOSCOVICH - THE FOUNDER OF MODERN SCIENCE","created_at":"2021-01-24T00:15:05.630-08:00","url":"https://www.academia.edu/44964079/ROGER_BOSCOVICH_THE_FOUNDER_OF_MODERN_SCIENCE?f_ri=4493","dom_id":"work_44964079","summary":"In 1758 Roger Boscovich (1711-1787) published \"A Theory of natural philosophy reduced to one unique law of forces that exist in nature\". The Theory has had a major impact on Boscovich's contemporaries and resulted in many followers in the 19th and at the beginning of the 20th century. His life, scientific activity, and philosophical views, as well as his influence on contemporaries and followers, are dealt with in this monograph. The theory is actually the very first quantum theory. He was the first one to draw the orbitals by which some particle moves around particles located in a center and explain that by a transition from one orbital to another a particle either gains or loses a certain amount (quantum) of energy. His primary contribution was to the discovery of the structure of atoms of chemical elements. He anticipated the possibility of the existence of macromolecules (i.e. polymers), nano-tubes neutrino, quarks, gluons, and also the structure of diamond and graphite.","downloadable_attachments":[{"id":65497693,"asset_id":44964079,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":32697313,"first_name":"Dragoslav","last_name":"Stoiljkovic","domain_name":"ns","page_name":"DragoslavStoiljkovic","display_name":"Dragoslav Stoiljkovic","profile_url":"https://ns.academia.edu/DragoslavStoiljkovic?f_ri=4493","photo":"https://0.academia-photos.com/32697313/33709860/29925698/s65_dragoslav.stoiljkovic.jpg"}],"research_interests":[{"id":132,"name":"History of Science and Technology","url":"https://www.academia.edu/Documents/in/History_of_Science_and_Technology?f_ri=4493","nofollow":true},{"id":518,"name":"Quantum Physics","url":"https://www.academia.edu/Documents/in/Quantum_Physics?f_ri=4493","nofollow":true},{"id":803,"name":"Philosophy","url":"https://www.academia.edu/Documents/in/Philosophy?f_ri=4493","nofollow":true},{"id":821,"name":"Philosophy of Science","url":"https://www.academia.edu/Documents/in/Philosophy_of_Science?f_ri=4493","nofollow":true},{"id":2720,"name":"Polymer science","url":"https://www.academia.edu/Documents/in/Polymer_science?f_ri=4493"},{"id":3723,"name":"History of Science","url":"https://www.academia.edu/Documents/in/History_of_Science?f_ri=4493"},{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493"},{"id":5703,"name":"History of Philosophy of Science","url":"https://www.academia.edu/Documents/in/History_of_Philosophy_of_Science?f_ri=4493"},{"id":7942,"name":"Hegel","url":"https://www.academia.edu/Documents/in/Hegel?f_ri=4493"},{"id":11740,"name":"Atomic Physics","url":"https://www.academia.edu/Documents/in/Atomic_Physics?f_ri=4493"},{"id":12423,"name":"Natural philosophy","url":"https://www.academia.edu/Documents/in/Natural_philosophy?f_ri=4493"},{"id":13644,"name":"Atomic and Molecular Physics","url":"https://www.academia.edu/Documents/in/Atomic_and_Molecular_Physics?f_ri=4493"},{"id":18420,"name":"Philosophy of Quantum Mechanics","url":"https://www.academia.edu/Documents/in/Philosophy_of_Quantum_Mechanics?f_ri=4493"},{"id":28969,"name":"History and philosophy of science (History)","url":"https://www.academia.edu/Documents/in/History_and_philosophy_of_science_History_?f_ri=4493"},{"id":58852,"name":"Friedrich Engels","url":"https://www.academia.edu/Documents/in/Friedrich_Engels?f_ri=4493"},{"id":103213,"name":"Nanoscience","url":"https://www.academia.edu/Documents/in/Nanoscience?f_ri=4493"},{"id":168760,"name":"Macromolecules","url":"https://www.academia.edu/Documents/in/Macromolecules?f_ri=4493"},{"id":492079,"name":"Quarks","url":"https://www.academia.edu/Documents/in/Quarks?f_ri=4493"},{"id":860878,"name":"Roger Boscovich","url":"https://www.academia.edu/Documents/in/Roger_Boscovich?f_ri=4493"},{"id":2991076,"name":"Gluons","url":"https://www.academia.edu/Documents/in/Gluons?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_8252916" data-work_id="8252916" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/8252916/Dynamic_molecular_recognition_in_the_generation_of_a_new_crystal_engineering_motif_a_unique_case_study_of_a_dicarboxylic_acid_with_a_ditopic_receptor_favouring_a_polymeric_over_a_dimeric_hydrogen_bonded_supramolecular_complex">Dynamic molecular recognition in the generation of a new crystal-engineering motif: a unique case study of a dicarboxylic acid with a ditopic receptor favouring a polymeric over a dimeric hydrogen-bonded supramolecular complex</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">A new crystal-engineering motif has been developed where a ditopic receptor 1 shows a novel syn-syn hydrogen-bonded polymeric supramolecular complex ) (instead of a 1:1 dimeric syn-syn or polymeric syn-anti complex) giving rise to a... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_8252916" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">A new crystal-engineering motif has been developed where a ditopic receptor 1 shows a novel syn-syn hydrogen-bonded polymeric supramolecular complex ) (instead of a 1:1 dimeric syn-syn or polymeric syn-anti complex) giving rise to a hydrogen-bonded stair-like polymeric ribbon structure between the binding groups of the receptor pyridine amide and the carboxyl groups of the guest substrate.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/8252916" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a 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work: {"id":8252916,"title":"Dynamic molecular recognition in the generation of a new crystal-engineering motif: a unique case study of a dicarboxylic acid with a ditopic receptor favouring a polymeric over a dimeric hydrogen-bonded supramolecular complex","created_at":"2014-09-08T23:10:20.430-07:00","url":"https://www.academia.edu/8252916/Dynamic_molecular_recognition_in_the_generation_of_a_new_crystal_engineering_motif_a_unique_case_study_of_a_dicarboxylic_acid_with_a_ditopic_receptor_favouring_a_polymeric_over_a_dimeric_hydrogen_bonded_supramolecular_complex?f_ri=4493","dom_id":"work_8252916","summary":"A new crystal-engineering motif has been developed where a ditopic receptor 1 shows a novel syn-syn hydrogen-bonded polymeric supramolecular complex ) (instead of a 1:1 dimeric syn-syn or polymeric syn-anti complex) giving rise to a hydrogen-bonded stair-like polymeric ribbon structure between the binding groups of the receptor pyridine amide and the carboxyl groups of the guest substrate.","downloadable_attachments":[{"id":48166121,"asset_id":8252916,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":16317991,"first_name":"Shazia","last_name":"Anjum","domain_name":"iub-pk","page_name":"ShaziaAnjum","display_name":"Shazia Anjum","profile_url":"https://iub-pk.academia.edu/ShaziaAnjum?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":531,"name":"Organic Chemistry","url":"https://www.academia.edu/Documents/in/Organic_Chemistry?f_ri=4493","nofollow":true},{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":49834,"name":"Molecular Recognition","url":"https://www.academia.edu/Documents/in/Molecular_Recognition?f_ri=4493","nofollow":true},{"id":96047,"name":"Case Study","url":"https://www.academia.edu/Documents/in/Case_Study?f_ri=4493","nofollow":true},{"id":240148,"name":"Hydrogen Bond","url":"https://www.academia.edu/Documents/in/Hydrogen_Bond?f_ri=4493"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_10454355" data-work_id="10454355" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/10454355/Barbituric_acids_as_a_useful_tool_for_the_construction_of_coordination_and_supramolecular_compounds">Barbituric acids as a useful tool for the construction of coordination and supramolecular compounds</a></div></div><div class="u-pb4x u-mt3x"></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/10454355" 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href="https://www.academia.edu/Documents/in/Crystal_Engineering">Crystal Engineering</a>, <script data-card-contents-for-ri="10704" type="text/json">{"id":10704,"name":"Crystal Engineering","url":"https://www.academia.edu/Documents/in/Crystal_Engineering?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="260118" rel="nofollow" href="https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES">CHEMICAL SCIENCES</a>, <script data-card-contents-for-ri="260118" type="text/json">{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=4493","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="582825" rel="nofollow" href="https://www.academia.edu/Documents/in/Halogen_bonding">Halogen bonding</a><script data-card-contents-for-ri="582825" type="text/json">{"id":582825,"name":"Halogen 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href="https://www.academia.edu/17720542/Supramolecularly_Organized_Lanthanide_Complexes_for_Efficient_Metal_Excitation_and_Luminescence_as_Sensors_in_Organic_and_Biological_Applications">Supramolecularly Organized Lanthanide Complexes for Efficient Metal Excitation and Luminescence as Sensors in Organic and Biological Applications</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Using molecular shape for the functional control of multicomponent systems is one of the challenges in the field of supramolecular chemistry. The well-known emission in the visible region of certain lanthanide (III) salts has found a new... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_17720542" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Using molecular shape for the functional control of multicomponent systems is one of the challenges in the field of supramolecular chemistry. The well-known emission in the visible region of certain lanthanide (III) salts has found a new dimension by the controlled assembly of supramolecular architectures to enshroud and excite the metal. The emission properties of these systems find applications as luminescent probes in sensing schemes, interaction with biomolecules, or light conversion systems.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/17720542" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="cb32606876706df9ae9e3fd3b7c6dc2f" rel="nofollow" data-download="{"attachment_id":39673241,"asset_id":17720542,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/39673241/download_file?st=MTc0MDk5NDU5MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="37625388" href="https://uam.academia.edu/ErnestoBrunet">Ernesto Brunet</a><script data-card-contents-for-user="37625388" type="text/json">{"id":37625388,"first_name":"Ernesto","last_name":"Brunet","domain_name":"uam","page_name":"ErnestoBrunet","display_name":"Ernesto Brunet","profile_url":"https://uam.academia.edu/ErnestoBrunet?f_ri=4493","photo":"https://0.academia-photos.com/37625388/10605571/11837828/s65_ernesto.brunet.jpg"}</script></span></span><span class="u-displayInlineBlock InlineList-item-text"> and <span class="u-textDecorationUnderline u-clickable InlineList-item-text js-work-more-authors-17720542">+1</span><div class="hidden js-additional-users-17720542"><div><span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a href="https://independent.academia.edu/OlgaJuanes">Olga Juanes</a></span></div></div></span><script>(function(){ var popoverSettings = { el: $('.js-work-more-authors-17720542'), placement: 'bottom', hide_delay: 200, html: true, content: function(){ return $('.js-additional-users-17720542').html(); 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The well-known emission in the visible region of certain lanthanide (III) salts has found a new dimension by the controlled assembly of supramolecular architectures to enshroud and excite the metal. The emission properties of these systems find applications as luminescent probes in sensing schemes, interaction with biomolecules, or light conversion systems.","downloadable_attachments":[{"id":39673241,"asset_id":17720542,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":37625388,"first_name":"Ernesto","last_name":"Brunet","domain_name":"uam","page_name":"ErnestoBrunet","display_name":"Ernesto Brunet","profile_url":"https://uam.academia.edu/ErnestoBrunet?f_ri=4493","photo":"https://0.academia-photos.com/37625388/10605571/11837828/s65_ernesto.brunet.jpg"},{"id":37717925,"first_name":"Olga","last_name":"Juanes","domain_name":"independent","page_name":"OlgaJuanes","display_name":"Olga Juanes","profile_url":"https://independent.academia.edu/OlgaJuanes?f_ri=4493","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":4493,"name":"Supramolecular Chemistry","url":"https://www.academia.edu/Documents/in/Supramolecular_Chemistry?f_ri=4493","nofollow":true},{"id":151091,"name":"Nitrogen","url":"https://www.academia.edu/Documents/in/Nitrogen?f_ri=4493","nofollow":true},{"id":990774,"name":"Quantum Yield","url":"https://www.academia.edu/Documents/in/Quantum_Yield?f_ri=4493","nofollow":true}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_8946253" data-work_id="8946253" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/8946253/A_Practical_Guide_for_the_Determination_of_Binding_Constants">A Practical Guide for the Determination of Binding Constants</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">When working in the field of host–guest chemistry, the binding constants have to be determined on many occasions. Here is a detailed document of how to determine the binding constants which covers both the basic principle and the... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_8946253" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">When working in the field of host–guest chemistry, the binding constants have to be determined on many occasions. Here is<br />a detailed document of how to determine the binding constants which covers both the basic principle and the practical issue:<br />a practical experimental guideline, a representativemethod for the determination of stoichiometry and for the evaluation of a<br />complex concentration, precautions to be taken on setting up concentration conditions of the titration experiment, practical<br />data-treatment methods and estimation of statistical errors. This document is described in detail using the basic level of<br />mathematics, statistics, and programs of spreadsheet software. Especially, the titration experiments by means of UV-visible<br />and NMR spectroscopy are carried out and described.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/8946253" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="ee1f0e4f88cad5cc9d7c6f5f8b32b49c" rel="nofollow" data-download="{"attachment_id":35266327,"asset_id":8946253,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/35266327/download_file?st=MTc0MDk5NDU5MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="19839516" href="https://osaka-u.academia.edu/KeijiHirose">Keiji Hirose</a><script data-card-contents-for-user="19839516" type="text/json">{"id":19839516,"first_name":"Keiji","last_name":"Hirose","domain_name":"osaka-u","page_name":"KeijiHirose","display_name":"Keiji Hirose","profile_url":"https://osaka-u.academia.edu/KeijiHirose?f_ri=4493","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_8946253 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="8946253"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 8946253, container: ".js-paper-rank-work_8946253", }); 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Here is\na detailed document of how to determine the binding constants which covers both the basic principle and the practical issue:\na practical experimental guideline, a representativemethod for the determination of stoichiometry and for the evaluation of a\ncomplex concentration, precautions to be taken on setting up concentration conditions of the titration experiment, practical\ndata-treatment methods and estimation of statistical errors. This document is described in detail using the basic level of\nmathematics, statistics, and programs of spreadsheet software. 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