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Black liquor - Wikipedia

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</ul> </li> <li id="toc-Extraction_of_lignin" class="vector-toc-list-item vector-toc-level-3"> <a class="vector-toc-link" href="#Extraction_of_lignin"> <div class="vector-toc-text"> <span class="vector-toc-numb">3.2.3</span> <span>Extraction of lignin</span> </div> </a> <ul id="toc-Extraction_of_lignin-sublist" class="vector-toc-list"> </ul> </li> </ul> </li> </ul> </li> <li id="toc-U.S._tax_credit_2007–2010" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#U.S._tax_credit_2007–2010"> <div class="vector-toc-text"> <span class="vector-toc-numb">4</span> <span>U.S. tax credit 2007–2010</span> </div> </a> <ul id="toc-U.S._tax_credit_2007–2010-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-References" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#References"> <div class="vector-toc-text"> <span class="vector-toc-numb">5</span> <span>References</span> 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href="/wiki/File:Black_Liquor_(cropped).jpg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/b/bc/Black_Liquor_%28cropped%29.jpg/220px-Black_Liquor_%28cropped%29.jpg" decoding="async" width="220" height="273" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/b/bc/Black_Liquor_%28cropped%29.jpg/330px-Black_Liquor_%28cropped%29.jpg 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/b/bc/Black_Liquor_%28cropped%29.jpg/440px-Black_Liquor_%28cropped%29.jpg 2x" data-file-width="1314" data-file-height="1632" /></a><figcaption>A black liquor sample</figcaption></figure> <p>In <a href="/wiki/Industrial_chemistry" class="mw-redirect" title="Industrial chemistry">industrial chemistry</a>, <b>black liquor</b> is the by-product from the <a href="/wiki/Kraft_process" title="Kraft process">kraft process</a> when digesting <a href="/wiki/Pulpwood" title="Pulpwood">pulpwood</a> into <a href="/wiki/Pulp_(paper)" title="Pulp (paper)">paper pulp</a> removing <a href="/wiki/Lignin" title="Lignin">lignin</a>, <a href="/wiki/Hemicellulose" title="Hemicellulose">hemicelluloses</a> and other extractives from the wood to free the <a href="/wiki/Cellulose" title="Cellulose">cellulose</a> fibers.<sup id="cite_ref-PSaT_1-0" class="reference"><a href="#cite_note-PSaT-1"><span class="cite-bracket">&#91;</span>1<span class="cite-bracket">&#93;</span></a></sup> </p><p>The equivalent material in the <a href="/wiki/Sulfite_process" title="Sulfite process">sulfite process</a> is usually called brown liquor, but the terms red liquor, thick liquor and sulfite liquor are also used.<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">&#91;<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (July 2024)">citation needed</span></a></i>&#93;</sup> </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="Composition">Composition</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Black_liquor&amp;action=edit&amp;section=1" title="Edit section: Composition"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Approximately seven tonnes of black liquor are produced in the manufacture of one tonne of pulp.<sup id="cite_ref-bier_2-0" class="reference"><a href="#cite_note-bier-2"><span class="cite-bracket">&#91;</span>2<span class="cite-bracket">&#93;</span></a></sup> </p><p>The black liquor is an aqueous solution of lignin residues, hemicellulose, and the <a href="/wiki/Inorganic_compound" title="Inorganic compound">inorganic chemicals</a> used in the process. The black liquor comprises 15% solids by weight of which two thirds are organic chemicals and the remainder are inorganic.<sup id="cite_ref-3" class="reference"><a href="#cite_note-3"><span class="cite-bracket">&#91;</span>3<span class="cite-bracket">&#93;</span></a></sup> Normally the organics in black liquor are 40-45% <a href="/wiki/Soap" title="Soap">soaps</a>,<sup id="cite_ref-4" class="reference"><a href="#cite_note-4"><span class="cite-bracket">&#91;</span>4<span class="cite-bracket">&#93;</span></a></sup> 35-45% lignin and 10-15% other organics. </p><p>The <a href="/wiki/Organic_compound" title="Organic compound">organic matter</a> in the black liquor is made up of water/alkali soluble degradation components from the wood.<sup id="cite_ref-PSaT_1-1" class="reference"><a href="#cite_note-PSaT-1"><span class="cite-bracket">&#91;</span>1<span class="cite-bracket">&#93;</span></a></sup> <a href="/wiki/Lignin" title="Lignin">Lignin</a> is degraded to shorter fragments with sulphur content at 1-2% and sodium content at about 6% of the dry solids. <a href="/wiki/Cellulose" title="Cellulose">Cellulose</a> and <a href="/wiki/Hemicellulose" title="Hemicellulose">hemicellulose</a> is degraded to aliphatic carboxylic acid soaps and hemicellulose fragments. The extractives gives <a href="/wiki/Tall_oil" title="Tall oil">tall oil</a> soap and crude <a href="/wiki/Turpentine" title="Turpentine">turpentine</a>. The soaps contain about 20% sodium.<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">&#91;<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (July 2024)">citation needed</span></a></i>&#93;</sup> </p><p>The residual lignin components currently serve for hydrolytic or pyrolytic conversion or just burning only. Hemicelluloses may undergo fermentation processes, alternatively.<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">&#91;<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (July 2024)">citation needed</span></a></i>&#93;</sup> </p><p>Black liquor creates <a href="/wiki/Chemical_oxygen_demand" title="Chemical oxygen demand">chemical oxygen demand</a> and <a href="/wiki/Biological_oxygen_demand" class="mw-redirect" title="Biological oxygen demand">biological oxygen demand</a>, and is highly alkaline, dark colored and may be warm.<sup id="cite_ref-alisreekrishnan2001_5-0" class="reference"><a href="#cite_note-alisreekrishnan2001-5"><span class="cite-bracket">&#91;</span>5<span class="cite-bracket">&#93;</span></a></sup> These properties contribute to the toxicity of plant effluent spills due in part to rapid depletion of dissolved oxygen and changes in water pH,<sup id="cite_ref-6" class="reference"><a href="#cite_note-6"><span class="cite-bracket">&#91;</span>6<span class="cite-bracket">&#93;</span></a></sup> with additional possible long-term effects on ecosystems from the presence of <a href="/wiki/Adsorbable_organic_halides" title="Adsorbable organic halides">adsorbable organic halides</a> generated by chlorine bleaching processes. The composition of black liquor is also influenced by the type of material used to create the paper, such as <a href="/wiki/Softwood" title="Softwood">softwood</a>.<sup id="cite_ref-alisreekrishnan2001_5-1" class="reference"><a href="#cite_note-alisreekrishnan2001-5"><span class="cite-bracket">&#91;</span>5<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="History">History</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Black_liquor&amp;action=edit&amp;section=2" title="Edit section: History"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Early kraft pulp mills discharged black liquor to watercourses. Black liquor is quite toxic to aquatic life, and causes a very dark caramel color in the water. The invention of the <a href="/wiki/Recovery_boiler" title="Recovery boiler">recovery boiler</a> by G.H. Tomlinson in the early 1930s was a milestone in the advancement of the kraft process.<sup id="cite_ref-eero_7-0" class="reference"><a href="#cite_note-eero-7"><span class="cite-bracket">&#91;</span>7<span class="cite-bracket">&#93;</span></a></sup> </p><p>By the 1990s, most kraft mills were consuming nearly all of their black liquor byproduct,<sup id="cite_ref-wpost_8-0" class="reference"><a href="#cite_note-wpost-8"><span class="cite-bracket">&#91;</span>8<span class="cite-bracket">&#93;</span></a></sup> and purifying the remainder in biological treatment plants, reducing the environmental effect of the waste waters below the level of scientific significance, except perhaps in very small streams.<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">&#91;<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (September 2021)">citation needed</span></a></i>&#93;</sup> Even in the 21st century, some small kraft mills remained (producing at most a few tons of pulp per day) that discharged all black liquor. However, these are rapidly disappearing. Some kraft mills, particularly in North America,<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">&#91;<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (June 2009)">citation needed</span></a></i>&#93;</sup> still recovered under 98% of the black liquor in 2007, which can cause some environmental contamination, even when biologically treated. The general trend is for such obsolete mills to modernize or shut down.<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">&#91;<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (August 2013)">citation needed</span></a></i>&#93;</sup> </p><p>In August 2011, a fish and mollusk kill occurred on the <a href="/wiki/Pearl_River_(Mississippi%E2%80%93Louisiana)" title="Pearl River (Mississippi–Louisiana)">Pearl River</a> when a neighboring Louisiana paper mill accidentally discharged black liquor due to a problem in its waste water treatment system.<sup id="cite_ref-9" class="reference"><a href="#cite_note-9"><span class="cite-bracket">&#91;</span>9<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-10" class="reference"><a href="#cite_note-10"><span class="cite-bracket">&#91;</span>10<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Usage">Usage</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Black_liquor&amp;action=edit&amp;section=3" title="Edit section: Usage"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>The black liquor contains more than half of the energy content of the wood fed into the <a href="/wiki/Kraft_process" title="Kraft process">digester</a> of a kraft pulp mill.<sup id="cite_ref-11" class="reference"><a href="#cite_note-11"><span class="cite-bracket">&#91;</span>11<span class="cite-bracket">&#93;</span></a></sup> It is normally concentrated to 65 - 80% by multi-effect <a href="/wiki/Evaporator" title="Evaporator">evaporators</a> and burned in a <a href="/wiki/Recovery_boiler" title="Recovery boiler">recovery boiler</a> to produce energy and recover the cooking chemicals. The <a href="/wiki/Viscosity" title="Viscosity">viscosity</a> increases as the concentration goes up. At about 50 - 55% solids the salt solubility limit is reached.<sup id="cite_ref-12" class="reference"><a href="#cite_note-12"><span class="cite-bracket">&#91;</span>12<span class="cite-bracket">&#93;</span></a></sup> <a href="/wiki/Tall_oil" title="Tall oil">Tall oil</a> is an important <a href="/wiki/Byproduct" class="mw-redirect" title="Byproduct">byproduct</a> separated from the black liquor with <a href="/wiki/Skimmer_(machine)" class="mw-redirect" title="Skimmer (machine)">skimming</a> before it goes to the evaporators or after the first evaporator stage. </p> <div class="mw-heading mw-heading3"><h3 id="Energy_source_for_the_pulp_mill">Energy source for the pulp mill</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Black_liquor&amp;action=edit&amp;section=4" title="Edit section: Energy source for the pulp mill"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p><a href="/wiki/Pulp_mill" title="Pulp mill">Pulp mills</a> have used black liquor as an energy source since at least the 1930s.<sup id="cite_ref-wpost_8-1" class="reference"><a href="#cite_note-wpost-8"><span class="cite-bracket">&#91;</span>8<span class="cite-bracket">&#93;</span></a></sup> Most kraft pulp mills use <a href="/wiki/Recovery_boiler" title="Recovery boiler">recovery boilers</a> to recover and burn much of the black liquor they produce, generating steam and recovering the cooking chemicals (<a href="/wiki/Sodium_hydroxide" title="Sodium hydroxide">sodium hydroxide</a> and <a href="/wiki/Sodium_sulfide" title="Sodium sulfide">sodium sulfide</a> used to separate lignin from the cellulose fibres needed for papermaking). This has helped paper mills reduce problems with water emissions, reduce their use of chemicals by recovery and reuse, and become nearly energy self-sufficient by producing, on average, 66 percent of their own electricity needs on-site.<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">&#91;<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (July 2024)">citation needed</span></a></i>&#93;</sup> </p><p>In the United States, paper companies have consumed nearly all of the black liquor they produce since the 1990s.<sup id="cite_ref-wpost_8-2" class="reference"><a href="#cite_note-wpost-8"><span class="cite-bracket">&#91;</span>8<span class="cite-bracket">&#93;</span></a></sup> As a result, the forest products industry has become one of the United States' leading generators of carbon-neutral renewable energy, producing approximately 28.5 terawatt hours of electricity annually.<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">&#91;<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (July 2024)">citation needed</span></a></i>&#93;</sup> </p> <div class="mw-heading mw-heading3"><h3 id="Use_as_biofuel_feedstock">Use as biofuel feedstock</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Black_liquor&amp;action=edit&amp;section=5" title="Edit section: Use as biofuel feedstock"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="mw-heading mw-heading4"><h4 id="Gasification">Gasification</h4><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Black_liquor&amp;action=edit&amp;section=6" title="Edit section: Gasification"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <figure class="mw-default-size" typeof="mw:File/Thumb"><a href="/wiki/File:Svartlut_76.jpg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/7/76/Svartlut_76.jpg/220px-Svartlut_76.jpg" decoding="async" width="220" height="184" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/7/76/Svartlut_76.jpg/330px-Svartlut_76.jpg 1.5x, //upload.wikimedia.org/wikipedia/commons/7/76/Svartlut_76.jpg 2x" data-file-width="392" data-file-height="328" /></a><figcaption>Black liquor as used for gasification</figcaption></figure> <p>New <a href="/wiki/Waste-to-energy" title="Waste-to-energy">waste-to-energy</a> methods to recover and utilize the energy in the black liquor have been developed.<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">&#91;<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (July 2024)">citation needed</span></a></i>&#93;</sup> The use of <a href="/wiki/Black_liquor_gasification" class="mw-redirect" title="Black liquor gasification">black liquor gasification</a> has the potential to achieve higher overall <a href="/wiki/Energy_conversion_efficiency" title="Energy conversion efficiency">energy efficiency</a> than the conventional recovery boiler, while generating an energy-rich <a href="/wiki/Syngas" title="Syngas">syngas</a> from the liquor.<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">&#91;<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (July 2024)">citation needed</span></a></i>&#93;</sup> The syngas can be burnt in a <a href="/wiki/Gas_turbine" title="Gas turbine">gas turbine</a> <a href="/wiki/Combined_cycle" class="mw-redirect" title="Combined cycle">combined cycle</a> to produce electricity (usually called <i>BLGCC</i> for Black Liquor Gasification Combined Cycle; similar to <a href="/wiki/Integrated_gasification_combined_cycle" title="Integrated gasification combined cycle">IGCC</a>) or converted through <a href="/wiki/Catalysis" title="Catalysis">catalytic processes</a> into chemicals or fuels such as <a href="/wiki/Methanol" title="Methanol">methanol</a>, <a href="/wiki/Dimethyl_ether" title="Dimethyl ether">dimethyl ether</a> (DME), or <a href="/wiki/Fischer%E2%80%93Tropsch_process" title="Fischer–Tropsch process">F-T</a> diesel (usually called <i>BLGMF</i> for Black Liquor Gasification for Motor Fuels). This gasification technology is currently<sup class="noprint Inline-Template" style="white-space:nowrap;">&#91;<i><a href="/wiki/Wikipedia:Manual_of_Style/Dates_and_numbers#Chronological_items" title="Wikipedia:Manual of Style/Dates and numbers"><span title="The time period mentioned near this tag is ambiguous. (July 2024)">when?</span></a></i>&#93;</sup> under operation in a 3 MW pilot plant at <a href="/wiki/Chemrec" title="Chemrec">Chemrec's</a><sup id="cite_ref-13" class="reference"><a href="#cite_note-13"><span class="cite-bracket">&#91;</span>13<span class="cite-bracket">&#93;</span></a></sup> test facility in <a href="/wiki/Pite%C3%A5" title="Piteå">Piteå</a>, <a href="/wiki/Sweden" title="Sweden">Sweden</a>. The DME synthesis step will be added in 2011<sup class="noprint Inline-Template" style="white-space:nowrap;">&#91;<i><a href="/wiki/Wikipedia:Manual_of_Style/Dates_and_numbers#Chronological_items" title="Wikipedia:Manual of Style/Dates and numbers"><span title="The date of the event predicted near this tag has passed. (July 2024)">needs update</span></a></i>&#93;</sup> in the "BioDME" project, supported by the <a href="/wiki/European_Commission" title="European Commission">European Commission</a>'s <a href="/wiki/Seventh_Framework_Programme" class="mw-redirect" title="Seventh Framework Programme">Seventh Framework Programme</a> (FP7) and the <a href="/wiki/Ministry_of_Enterprise,_Energy_and_Communications_(Sweden)" class="mw-redirect" title="Ministry of Enterprise, Energy and Communications (Sweden)">Swedish Energy Agency</a>.<sup id="cite_ref-14" class="reference"><a href="#cite_note-14"><span class="cite-bracket">&#91;</span>14<span class="cite-bracket">&#93;</span></a></sup> </p><p>Used for biofuels production, the black liquor gasification route has been shown to have very high <a href="/wiki/Energy_conversion_efficiency" title="Energy conversion efficiency">conversion efficiency</a> and <a href="/wiki/Greenhouse_gas" title="Greenhouse gas">greenhouse gas</a> reduction potential.<sup id="cite_ref-15" class="reference"><a href="#cite_note-15"><span class="cite-bracket">&#91;</span>15<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading4"><h4 id="Hydrothermal_liquefaction">Hydrothermal liquefaction</h4><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Black_liquor&amp;action=edit&amp;section=7" title="Edit section: Hydrothermal liquefaction"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p><a href="/wiki/Hydrothermal_liquefaction" title="Hydrothermal liquefaction">Hydrothermal liquefaction</a> is suitable for converting black liquor to advanced biofuels due to the process's ability to handle high moisture inputs.<sup id="cite_ref-16" class="reference"><a href="#cite_note-16"><span class="cite-bracket">&#91;</span>16<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading4"><h4 id="Extraction_of_lignin">Extraction of lignin</h4><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Black_liquor&amp;action=edit&amp;section=8" title="Edit section: Extraction of lignin"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Where <a href="/wiki/Recovery_boiler" title="Recovery boiler">recovery boiler</a> capacity is limited and a bottleneck in the <a href="/wiki/Pulp_mill" title="Pulp mill">pulp mill</a>, the <a href="/wiki/Lignin" title="Lignin">lignin</a> in the black liquor may be extracted, then exported or used as fuel in the mill's <a href="/wiki/Lime_kiln" title="Lime kiln">lime kiln</a>. This often replaces fossil-based fuel with biofuel.<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">&#91;<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (July 2024)">citation needed</span></a></i>&#93;</sup> </p> <div class="mw-heading mw-heading2"><h2 id="U.S._tax_credit_2007–2010"><span id="U.S._tax_credit_2007.E2.80.932010"></span>U.S. tax credit 2007–2010</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Black_liquor&amp;action=edit&amp;section=9" title="Edit section: U.S. tax credit 2007–2010"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>A tax credit created by the U.S. Congress in 2005 as part of the <a href="/wiki/Safe,_Accountable,_Flexible,_Efficient_Transportation_Equity_Act:_A_Legacy_for_Users" title="Safe, Accountable, Flexible, Efficient Transportation Equity Act: A Legacy for Users">2005 Highway Bill</a> to reward and support the use of liquid <a href="/wiki/Alternative_fuel" title="Alternative fuel">alternative fuel</a> derived from hydrocarbons in the transportation sector was expanded in 2007 to include non-mobile uses of liquid alternative fuel derived from biomass.<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">&#91;<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (July 2024)">citation needed</span></a></i>&#93;</sup> This change meant that, in addition to fish processors, animal renderers and meat packers, kraft pulp producers became eligible for the tax credit as a result of their generation and use of black liquor to make energy. For one large company (<a href="/wiki/International_Paper" title="International Paper">International Paper</a>) this could amount to as much as $3.7 billion in benefits.<sup id="cite_ref-wpost_8-3" class="reference"><a href="#cite_note-wpost-8"><span class="cite-bracket">&#91;</span>8<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-17" class="reference"><a href="#cite_note-17"><span class="cite-bracket">&#91;</span>17<span class="cite-bracket">&#93;</span></a></sup> <a href="/wiki/Weyerhaeuser" title="Weyerhaeuser">Weyerhaeuser</a> announced in May 2009 that it was also pursuing the tax credit.<sup id="cite_ref-18" class="reference"><a href="#cite_note-18"><span class="cite-bracket">&#91;</span>18<span class="cite-bracket">&#93;</span></a></sup> Some paper industry analysts<sup id="cite_ref-19" class="reference"><a href="#cite_note-19"><span class="cite-bracket">&#91;</span>19<span class="cite-bracket">&#93;</span></a></sup> criticized the paper industry's eligibility for the alternative fuel mix tax credit on the grounds that it increased fossil fuel use, but the industry countered that adding a fossil fuel was a requirement of the law and that, regardless, this did not result in a net increase in fossil fuel use since companies were merely replacing the existing fossil fuel they already mixed with black liquor—natural gas—with one of the three fuels specified by the law: gasoline, kerosene or diesel. The bio-fuel credit for black liquor ended on January 1, 2010.<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">&#91;<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (July 2024)">citation needed</span></a></i>&#93;</sup> </p> <div class="mw-heading mw-heading2"><h2 id="References">References</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Black_liquor&amp;action=edit&amp;section=10" title="Edit section: References"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <style data-mw-deduplicate="TemplateStyles:r1239543626">.mw-parser-output .reflist{margin-bottom:0.5em;list-style-type:decimal}@media screen{.mw-parser-output .reflist{font-size:90%}}.mw-parser-output .reflist .references{font-size:100%;margin-bottom:0;list-style-type:inherit}.mw-parser-output .reflist-columns-2{column-width:30em}.mw-parser-output .reflist-columns-3{column-width:25em}.mw-parser-output .reflist-columns{margin-top:0.3em}.mw-parser-output .reflist-columns ol{margin-top:0}.mw-parser-output .reflist-columns li{page-break-inside:avoid;break-inside:avoid-column}.mw-parser-output .reflist-upper-alpha{list-style-type:upper-alpha}.mw-parser-output .reflist-upper-roman{list-style-type:upper-roman}.mw-parser-output .reflist-lower-alpha{list-style-type:lower-alpha}.mw-parser-output .reflist-lower-greek{list-style-type:lower-greek}.mw-parser-output .reflist-lower-roman{list-style-type:lower-roman}</style><div class="reflist"> <div class="mw-references-wrap mw-references-columns"><ol class="references"> <li id="cite_note-PSaT-1"><span class="mw-cite-backlink">^ <a href="#cite_ref-PSaT_1-0"><sup><i><b>a</b></i></sup></a> <a href="#cite_ref-PSaT_1-1"><sup><i><b>b</b></i></sup></a></span> <span class="reference-text"><style data-mw-deduplicate="TemplateStyles:r1238218222">.mw-parser-output cite.citation{font-style:inherit;word-wrap:break-word}.mw-parser-output .citation q{quotes:"\"""\"""'""'"}.mw-parser-output .citation:target{background-color:rgba(0,127,255,0.133)}.mw-parser-output .id-lock-free.id-lock-free a{background:url("//upload.wikimedia.org/wikipedia/commons/6/65/Lock-green.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-limited.id-lock-limited a,.mw-parser-output .id-lock-registration.id-lock-registration a{background:url("//upload.wikimedia.org/wikipedia/commons/d/d6/Lock-gray-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-subscription.id-lock-subscription a{background:url("//upload.wikimedia.org/wikipedia/commons/a/aa/Lock-red-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .cs1-ws-icon a{background:url("//upload.wikimedia.org/wikipedia/commons/4/4c/Wikisource-logo.svg")right 0.1em center/12px no-repeat}body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-free a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-limited a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-registration a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-subscription a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .cs1-ws-icon a{background-size:contain;padding:0 1em 0 0}.mw-parser-output .cs1-code{color:inherit;background:inherit;border:none;padding:inherit}.mw-parser-output .cs1-hidden-error{display:none;color:var(--color-error,#d33)}.mw-parser-output .cs1-visible-error{color:var(--color-error,#d33)}.mw-parser-output .cs1-maint{display:none;color:#085;margin-left:0.3em}.mw-parser-output .cs1-kern-left{padding-left:0.2em}.mw-parser-output .cs1-kern-right{padding-right:0.2em}.mw-parser-output .citation .mw-selflink{font-weight:inherit}@media screen{.mw-parser-output .cs1-format{font-size:95%}html.skin-theme-clientpref-night .mw-parser-output .cs1-maint{color:#18911f}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .cs1-maint{color:#18911f}}</style><cite id="CITEREFStenius2000" class="citation book cs1">Stenius, Per, ed. (2000). "2". <i>Forest Products Chemistry</i>. Papermaking Science and Technology. Vol.&#160;3. Helsinki, Finland: Fapet OY. pp.&#160;62–78. <a href="/wiki/ISBN_(identifier)" class="mw-redirect" title="ISBN (identifier)">ISBN</a>&#160;<a href="/wiki/Special:BookSources/978-952-5216-03-5" title="Special:BookSources/978-952-5216-03-5"><bdi>978-952-5216-03-5</bdi></a>.</cite><span title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&amp;rft.genre=bookitem&amp;rft.atitle=2&amp;rft.btitle=Forest+Products+Chemistry&amp;rft.place=Helsinki%2C+Finland&amp;rft.series=Papermaking+Science+and+Technology&amp;rft.pages=62-78&amp;rft.pub=Fapet+OY&amp;rft.date=2000&amp;rft.isbn=978-952-5216-03-5&amp;rfr_id=info%3Asid%2Fen.wikipedia.org%3ABlack+liquor" class="Z3988"></span></span> </li> <li id="cite_note-bier-2"><span class="mw-cite-backlink"><b><a href="#cite_ref-bier_2-0">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFBiermann1993" class="citation book cs1">Biermann, Christopher J. (1993). <span class="id-lock-registration" title="Free registration required"><a rel="nofollow" class="external text" href="https://archive.org/details/essentialsofpulp0000bier"><i>Essentials of Pulping and Papermaking</i></a></span>. 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Retrieved <span class="nowrap">2009-06-03</span></span>.</cite><span title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&amp;rft.genre=unknown&amp;rft.btitle=Weyerhaeuser+says+applied+to+become+qualified+as+alternative+fuel+mixer&amp;rft.pub=CNBC&amp;rft.date=2009-05-05&amp;rft_id=https%3A%2F%2Fwww.cnbc.com%2Fid%2F30580378%2Fsite%2F14081545%2Ffor%2Fcnbc%2F&amp;rfr_id=info%3Asid%2Fen.wikipedia.org%3ABlack+liquor" class="Z3988"></span><sup class="noprint Inline-Template"><span style="white-space: nowrap;">&#91;<i><a href="/wiki/Wikipedia:Link_rot" title="Wikipedia:Link rot"><span title="&#160;Dead link tagged November 2024">dead link</span></a></i><span style="visibility:hidden; color:transparent; padding-left:2px">&#8205;</span>&#93;</span></sup> </span> </li> <li id="cite_note-19"><span class="mw-cite-backlink"><b><a href="#cite_ref-19">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFDizikes2009" class="citation news cs1">Dizikes, Cynthia (April 24, 2009). <a rel="nofollow" class="external text" href="https://www.minnpost.com/politics-policy/2009/04/paper-firms-reap-billions-tax-credit-should-they/">"Paper firms reap billions from tax credit — but should they?"</a>. <i><a href="/wiki/MinnPost" title="MinnPost">MinnPost</a></i><span class="reference-accessdate">. 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href="/wiki/Template:Wood_products" title="Template:Wood products"><abbr title="View this template">v</abbr></a></li><li class="nv-talk"><a href="/wiki/Template_talk:Wood_products" title="Template talk:Wood products"><abbr title="Discuss this template">t</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:EditPage/Template:Wood_products" title="Special:EditPage/Template:Wood products"><abbr title="Edit this template">e</abbr></a></li></ul></div><div id="Wood_products" style="font-size:114%;margin:0 4em"><a href="/wiki/Wood" title="Wood">Wood products</a></div></th></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Lumber" title="Lumber">Lumber</a>/<br />timber</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Batten" title="Batten">Batten</a></li> <li><a href="/wiki/Beam_(structure)" title="Beam (structure)">Beam</a></li> <li><a href="/wiki/Bressummer" title="Bressummer">Bressummer</a></li> <li><a href="/wiki/Canadian_Lumber_Standard" title="Canadian Lumber Standard">CLS</a></li> <li><a href="/wiki/Cruck" title="Cruck">Cruck</a></li> <li><a href="/wiki/Flitch_beam" title="Flitch beam">Flitch beam</a></li> <li><a href="/wiki/Wood_flooring" title="Wood flooring">Flooring</a></li> <li><a href="/wiki/Joist" title="Joist">Joist</a></li> <li><a href="/wiki/Lath" title="Lath">Lath</a></li> <li><a href="/wiki/Log_building" title="Log building">Log building</a></li> <li><a href="/wiki/Log_cabin" title="Log cabin">Log cabin</a></li> <li><a href="/wiki/Log_house" title="Log house">Log house</a></li> <li><a href="/wiki/Molding_(decorative)" title="Molding (decorative)">Molding</a></li> <li><a href="/wiki/Panelling" title="Panelling">Panelling</a></li> <li><a href="/wiki/Plank_(wood)" title="Plank (wood)">Plank</a></li> <li><a href="/wiki/Wall_plate" title="Wall plate">Plate</a></li> <li><a href="/wiki/Post_(structural)" title="Post (structural)">Post</a></li> <li><a href="/wiki/Purlin" title="Purlin">Purlin</a></li> <li><a href="/wiki/Rafter" title="Rafter">Rafter</a></li> <li><a href="/wiki/Railroad_tie#Wooden" title="Railroad tie">Railroad ties</a></li> <li><a href="/wiki/Reclaimed_lumber" title="Reclaimed lumber">Reclaimed</a></li> <li><a href="/wiki/Wood_shingle" title="Wood shingle">Shingle</a></li> <li><a href="/wiki/Siding_(construction)#Wood_siding" title="Siding (construction)">Siding</a></li> <li><a href="/wiki/Sill_plate" title="Sill plate">Sill</a></li> <li><a href="/wiki/Wall_stud" title="Wall stud">Stud</a></li> <li><a href="/wiki/Timber_roof_truss" title="Timber roof truss">Timber truss</a></li> <li><a href="/wiki/Treenail" title="Treenail">Treenail</a></li> <li><a href="/wiki/Truss" title="Truss">Truss</a></li> <li><a href="/wiki/Utility_pole" title="Utility pole">Utility pole</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Engineered_wood" title="Engineered wood">Engineered<br />wood</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Cross-laminated_timber" title="Cross-laminated timber">Cross-laminated timber</a></li> <li><a href="/wiki/Glued_laminated_timber" title="Glued laminated timber">Glued laminated timber</a> <ul><li><a href="/wiki/Wood_veneer" title="Wood veneer">veneer</a></li> <li><a href="/wiki/Laminated_veneer_lumber" title="Laminated veneer lumber">LVL</a></li> <li><a href="/wiki/Parallam" class="mw-redirect" title="Parallam">parallel strand</a></li></ul></li> <li><a href="/wiki/I-joist" title="I-joist">I-joist</a></li> <li><a href="/wiki/Fiberboard" title="Fiberboard">Fiberboard</a> <ul><li><a href="/wiki/Hardboard" title="Hardboard">hardboard</a></li> <li><a href="/wiki/Masonite" title="Masonite">Masonite</a></li> <li><a href="/wiki/Medium-density_fibreboard" title="Medium-density fibreboard">MDF</a></li></ul></li> <li><a href="/wiki/Oriented_strand_board" title="Oriented strand board">Oriented strand board</a></li> <li><a href="/wiki/Oriented_structural_straw_board" title="Oriented structural straw board">Oriented structural straw board</a></li> <li><a href="/wiki/Particle_board" title="Particle board">Particle board</a></li> <li><a href="/wiki/Plywood" title="Plywood">Plywood</a></li> <li><a href="/wiki/Structural_insulated_panel" title="Structural insulated panel">Structural insulated panel</a></li> <li><a href="/wiki/Wood%E2%80%93plastic_composite" title="Wood–plastic composite">Wood–plastic composite</a> <ul><li><a href="/wiki/Composite_lumber" title="Composite lumber">lumber</a></li></ul></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">Fuelwood</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Charcoal" title="Charcoal">Charcoal</a> <ul><li><a href="/wiki/Biochar" title="Biochar">biochar</a></li></ul></li> <li><a href="/wiki/Firelog" title="Firelog">Firelog</a></li> <li><a href="/wiki/Firewood" title="Firewood">Firewood</a></li> <li><a href="/wiki/Pellet_fuel" title="Pellet fuel">Pellet fuel</a></li> <li><a href="/wiki/Wood_fuel" title="Wood fuel">Wood fuel</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Wood_fibre" title="Wood fibre">Fibers</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Cardboard" title="Cardboard">Cardboard</a></li> <li><a href="/wiki/Corrugated_fiberboard" title="Corrugated fiberboard">Corrugated fiberboard</a></li> <li><a href="/wiki/Paper" title="Paper">Paper</a></li> <li><a href="/wiki/Paperboard" title="Paperboard">Paperboard</a></li> <li><a href="/wiki/Pulp_(paper)" title="Pulp (paper)">Pulp</a></li> <li><a href="/wiki/Pulpwood" title="Pulpwood">Pulpwood</a></li> <li><a href="/wiki/Rayon" title="Rayon">Rayon</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">Derivatives</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Birch-tar" class="mw-redirect" title="Birch-tar">Birch-tar</a></li> <li><a href="/wiki/Cellulose" title="Cellulose">Cellulose</a> <ul><li><a href="/wiki/Nanocellulose" title="Nanocellulose">nano</a></li></ul></li> <li><a href="/wiki/Hemicellulose" title="Hemicellulose">Hemicellulose</a></li> <li><a href="/wiki/Cellulosic_ethanol" title="Cellulosic ethanol">Cellulosic ethanol</a></li> <li><a href="/wiki/Dyewoods" title="Dyewoods">Dyes</a></li> <li><a href="/wiki/Lignin" title="Lignin">Lignin</a></li> <li><a href="/wiki/Liquid_smoke" title="Liquid smoke">Liquid smoke</a></li> <li><a href="/wiki/Lye" title="Lye">Lye</a></li> <li><a href="/wiki/Methanol" title="Methanol">Methanol</a></li> <li><a href="/wiki/Pyroligneous_acid" title="Pyroligneous acid">Pyroligneous acid</a></li> <li><a href="/wiki/Pine_tar" title="Pine tar">Pine tar</a></li> <li><a href="/wiki/Pitch_(resin)" title="Pitch (resin)">Pitch</a></li> <li><a href="/wiki/Sandalwood_oil" title="Sandalwood oil">Sandalwood oil</a></li> <li><a href="/wiki/Tannin" title="Tannin">Tannin</a></li> <li><a href="/wiki/Wood_gas" title="Wood gas">Wood gas</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/By-product" title="By-product">By-products</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Barkdust" title="Barkdust">Barkdust</a></li> <li><a class="mw-selflink selflink">Black liquor</a></li> <li><a href="/wiki/Ramial_chipped_wood" title="Ramial chipped wood">Ramial chipped wood</a></li> <li><a href="/wiki/Sawdust" title="Sawdust">Sawdust</a></li> <li><a href="/wiki/Tall_oil" title="Tall oil">Tall oil</a></li> <li><a href="/wiki/Wood_flour" class="mw-redirect" title="Wood flour">Wood flour</a></li> <li><a href="/wiki/Wood_wool" title="Wood wool">Wood wool</a></li> <li><a href="/wiki/Woodchips" title="Woodchips">Woodchips</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">Historical</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Axe_ties" class="mw-redirect" title="Axe ties">Axe ties</a></li> <li><a href="/wiki/Bavin_(wood)" title="Bavin (wood)">Bavin (wood)</a></li> <li><a href="/wiki/Billet_(wood)" title="Billet (wood)">Billet (wood)</a></li> <li><a href="/wiki/Clapboard_(architecture)" class="mw-redirect" title="Clapboard (architecture)">Clapboard</a></li> <li><a href="/wiki/Dugout_(boat)" class="mw-redirect" title="Dugout (boat)">Dugout canoe</a></li> <li><a href="/wiki/Potash" title="Potash">Potash</a></li> <li><a href="/wiki/Sawdust_brandy" title="Sawdust brandy">Sawdust brandy</a></li> <li><a href="/wiki/Split-rail_fence" title="Split-rail fence">Split-rail fence</a></li> <li><a href="/wiki/Tanbark" title="Tanbark">Tanbark</a></li> <li><a href="/wiki/Timber_framing" title="Timber framing">Timber framing</a></li> <li><a href="/wiki/Mast_(sailing)" title="Mast (sailing)">Wooden masts</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">See also</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Biomass" title="Biomass">Biomass</a></li> <li><a href="/wiki/Certified_wood" title="Certified wood">Certified wood</a></li> <li><a href="/wiki/Destructive_distillation" title="Destructive distillation">Destructive distillation</a></li> <li><a href="/wiki/Dry_distillation" title="Dry distillation">Dry distillation</a></li> <li><a href="/wiki/Engineered_bamboo" title="Engineered bamboo">Engineered bamboo</a></li> <li><a href="/wiki/Forestry" title="Forestry">Forestry</a></li> <li><a href="/wiki/Green_building_and_wood" title="Green building and wood">Green building and wood</a></li> <li><a href="/wiki/List_of_woods" title="List of woods">List of woods</a></li> <li><a href="/wiki/Mulch" title="Mulch">Mulch</a></li> <li><a href="/wiki/Non-timber_forest_product" title="Non-timber forest product">Non-timber forest products</a></li> <li><a href="/wiki/Natural_building" title="Natural building">Natural building</a></li> <li><a href="/wiki/Papermaking" title="Papermaking">Papermaking</a></li> <li><a href="/wiki/Reclaimed_lumber" title="Reclaimed lumber">Reclaimed lumber</a></li> <li><a href="/wiki/Timber_recycling" title="Timber recycling">Timber recycling</a></li> <li><a href="/wiki/Wood_drying" title="Wood drying">Wood drying</a></li> <li><a href="/wiki/Wood_preservation" title="Wood preservation">Wood preservation</a></li> <li><a href="/wiki/Wood_processing" title="Wood processing">Wood processing</a></li> <li><a href="/wiki/Woodworking" title="Woodworking">Woodworking</a></li> <li><i><a href="/wiki/Yakisugi" title="Yakisugi">Yakisugi</a></i></li></ul> </div></td></tr><tr><td class="navbox-abovebelow" colspan="2"><div> <ul><li><span class="noviewer" typeof="mw:File"><span title="Category"><img alt="" src="//upload.wikimedia.org/wikipedia/en/thumb/9/96/Symbol_category_class.svg/16px-Symbol_category_class.svg.png" decoding="async" width="16" height="16" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/9/96/Symbol_category_class.svg/23px-Symbol_category_class.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/9/96/Symbol_category_class.svg/31px-Symbol_category_class.svg.png 2x" data-file-width="180" data-file-height="185" /></span></span> <a href="/wiki/Category:Wood_products" title="Category:Wood products">Category</a></li> <li><span class="noviewer" typeof="mw:File"><span title="Commons page"><img alt="" src="//upload.wikimedia.org/wikipedia/en/thumb/4/4a/Commons-logo.svg/12px-Commons-logo.svg.png" decoding="async" width="12" height="16" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/4/4a/Commons-logo.svg/18px-Commons-logo.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/4/4a/Commons-logo.svg/24px-Commons-logo.svg.png 2x" data-file-width="1024" data-file-height="1376" /></span></span> <b><a href="https://commons.wikimedia.org/wiki/Category:Wood_products" class="extiw" title="commons:Category:Wood products">Commons</a></b></li> <li><span class="noviewer" typeof="mw:File"><span title="WikiProject"><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/3/37/People_icon.svg/16px-People_icon.svg.png" decoding="async" width="16" height="16" class="mw-file-element" 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