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</header> </div> <div class="mw-page-container"> <div class="mw-page-container-inner"> <div class="vector-sitenotice-container"> <div id="siteNotice"></div> </div> <div class="vector-column-start"> <div class="vector-main-menu-container"> <div id="mw-navigation"> <nav id="mw-panel" class="vector-main-menu-landmark" aria-label="站点"> <div id="vector-main-menu-pinned-container" class="vector-pinned-container"> </div> </nav> </div> </div> <div class="vector-sticky-pinned-container"> <nav id="mw-panel-toc" aria-label="目录" data-event-name="ui.sidebar-toc" class="mw-table-of-contents-container vector-toc-landmark"> <div id="vector-toc-pinned-container" class="vector-pinned-container"> <div id="vector-toc" class="vector-toc vector-pinnable-element"> <div class="vector-pinnable-header vector-toc-pinnable-header vector-pinnable-header-pinned" data-feature-name="toc-pinned" data-pinnable-element-id="vector-toc" > <h2 class="vector-pinnable-header-label">目录</h2> <button 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<span class="vector-toc-numb">2</span> <span>反应</span> </div> </a> <button aria-controls="toc-反应-sublist" class="cdx-button cdx-button--weight-quiet cdx-button--icon-only vector-toc-toggle"> <span class="vector-icon mw-ui-icon-wikimedia-expand"></span> <span>开关反应子章节</span> </button> <ul id="toc-反应-sublist" class="vector-toc-list"> <li id="toc-三氯化钌和有机配体的反应" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#三氯化钌和有机配体的反应"> <div class="vector-toc-text"> <span class="vector-toc-numb">2.1</span> <span>三氯化钌和有机配体的反应</span> </div> </a> <ul id="toc-三氯化钌和有机配体的反应-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-三氯化钌和一氧化碳反应" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#三氯化钌和一氧化碳反应"> <div class="vector-toc-text"> <span class="vector-toc-numb">2.2</span> <span>三氯化钌和一氧化碳反应</span> </div> </a> <ul id="toc-三氯化钌和一氧化碳反应-sublist" class="vector-toc-list"> </ul> </li> </ul> </li> <li id="toc-参考资料" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#参考资料"> <div class="vector-toc-text"> <span class="vector-toc-numb">3</span> <span>参考资料</span> </div> </a> <ul id="toc-参考资料-sublist" class="vector-toc-list"> </ul> </li> </ul> </div> </div> </nav> </div> </div> <div class="mw-content-container"> <main id="content" class="mw-body"> <header class="mw-body-header vector-page-titlebar"> <nav aria-label="目录" class="vector-toc-landmark"> <div id="vector-page-titlebar-toc" class="vector-dropdown vector-page-titlebar-toc vector-button-flush-left" > <input type="checkbox" id="vector-page-titlebar-toc-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-page-titlebar-toc" class="vector-dropdown-checkbox " aria-label="开关目录" > <label id="vector-page-titlebar-toc-label" for="vector-page-titlebar-toc-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only " aria-hidden="true" ><span class="vector-icon mw-ui-icon-listBullet mw-ui-icon-wikimedia-listBullet"></span> <span class="vector-dropdown-label-text">开关目录</span> </label> <div class="vector-dropdown-content"> <div id="vector-page-titlebar-toc-unpinned-container" class="vector-unpinned-container"> </div> </div> </div> </nav> <h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">三氯化钌</span></h1> <div id="p-lang-btn" class="vector-dropdown mw-portlet mw-portlet-lang" > <input type="checkbox" id="p-lang-btn-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-p-lang-btn" class="vector-dropdown-checkbox mw-interlanguage-selector" aria-label="前往另一种语言写成的文章。18种语言可用" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-18" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">18种语言</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-af mw-list-item"><a href="https://af.wikipedia.org/wiki/Rutenium(III)chloried" title="Rutenium(III)chloried – 南非荷兰语" lang="af" hreflang="af" data-title="Rutenium(III)chloried" data-language-autonym="Afrikaans" data-language-local-name="南非荷兰语" class="interlanguage-link-target"><span>Afrikaans</span></a></li><li class="interlanguage-link interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D9%83%D9%84%D9%88%D8%B1%D9%8A%D8%AF_%D8%A7%D9%84%D8%B1%D9%88%D8%AB%D9%8A%D9%86%D9%8A%D9%88%D9%85_%D8%A7%D9%84%D8%AB%D9%84%D8%A7%D8%AB%D9%8A" title="كلوريد الروثينيوم الثلاثي – 阿拉伯语" lang="ar" hreflang="ar" data-title="كلوريد الروثينيوم الثلاثي" data-language-autonym="العربية" data-language-local-name="阿拉伯语" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-azb mw-list-item"><a href="https://azb.wikipedia.org/wiki/%DA%A9%D9%88%D9%84%D9%88%D8%B1%DB%8C%D8%AF_%D8%B1%D9%88%D8%AA%D9%86%DB%8C%D9%88%D9%85_(III)" title="کولورید روتنیوم (III) – South Azerbaijani" lang="azb" hreflang="azb" data-title="کولورید روتنیوم (III)" data-language-autonym="تۆرکجه" data-language-local-name="South Azerbaijani" class="interlanguage-link-target"><span>تۆرکجه</span></a></li><li class="interlanguage-link interwiki-ca mw-list-item"><a href="https://ca.wikipedia.org/wiki/Clorur_de_ruteni(III)" title="Clorur de ruteni(III) – 加泰罗尼亚语" lang="ca" hreflang="ca" data-title="Clorur de ruteni(III)" data-language-autonym="Català" data-language-local-name="加泰罗尼亚语" class="interlanguage-link-target"><span>Català</span></a></li><li class="interlanguage-link interwiki-cs mw-list-item"><a href="https://cs.wikipedia.org/wiki/Chlorid_ruthenit%C3%BD" title="Chlorid ruthenitý – 捷克语" lang="cs" hreflang="cs" data-title="Chlorid ruthenitý" data-language-autonym="Čeština" data-language-local-name="捷克语" class="interlanguage-link-target"><span>Čeština</span></a></li><li class="interlanguage-link interwiki-de mw-list-item"><a href="https://de.wikipedia.org/wiki/Ruthenium(III)-chlorid" title="Ruthenium(III)-chlorid – 德语" lang="de" hreflang="de" data-title="Ruthenium(III)-chlorid" data-language-autonym="Deutsch" data-language-local-name="德语" class="interlanguage-link-target"><span>Deutsch</span></a></li><li class="interlanguage-link interwiki-el mw-list-item"><a href="https://el.wikipedia.org/wiki/%CE%A4%CF%81%CE%B9%CF%87%CE%BB%CF%89%CF%81%CE%B9%CE%BF%CF%8D%CF%87%CE%BF_%CF%81%CE%BF%CF%85%CE%B8%CE%AE%CE%BD%CE%B9%CE%BF" title="Τριχλωριούχο ρουθήνιο – 希腊语" lang="el" hreflang="el" data-title="Τριχλωριούχο ρουθήνιο" data-language-autonym="Ελληνικά" data-language-local-name="希腊语" class="interlanguage-link-target"><span>Ελληνικά</span></a></li><li class="interlanguage-link interwiki-en mw-list-item"><a href="https://en.wikipedia.org/wiki/Ruthenium(III)_chloride" title="Ruthenium(III) chloride – 英语" lang="en" hreflang="en" data-title="Ruthenium(III) chloride" data-language-autonym="English" data-language-local-name="英语" class="interlanguage-link-target"><span>English</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%DA%A9%D9%84%D8%B1%DB%8C%D8%AF_%D8%B1%D9%88%D8%AA%D9%86%DB%8C%D9%85_(III)" title="کلرید روتنیم (III) – 波斯语" lang="fa" hreflang="fa" data-title="کلرید روتنیم (III)" data-language-autonym="فارسی" data-language-local-name="波斯语" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fi mw-list-item"><a href="https://fi.wikipedia.org/wiki/Ruteniumkloridi" title="Ruteniumkloridi – 芬兰语" lang="fi" hreflang="fi" data-title="Ruteniumkloridi" data-language-autonym="Suomi" data-language-local-name="芬兰语" class="interlanguage-link-target"><span>Suomi</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/Chlorure_de_ruth%C3%A9nium(III)" title="Chlorure de ruthénium(III) – 法语" lang="fr" hreflang="fr" data-title="Chlorure de ruthénium(III)" data-language-autonym="Français" data-language-local-name="法语" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-it mw-list-item"><a href="https://it.wikipedia.org/wiki/Cloruro_di_rutenio(III)" title="Cloruro di rutenio(III) – 意大利语" lang="it" hreflang="it" data-title="Cloruro di rutenio(III)" data-language-autonym="Italiano" data-language-local-name="意大利语" class="interlanguage-link-target"><span>Italiano</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E5%A1%A9%E5%8C%96%E3%83%AB%E3%83%86%E3%83%8B%E3%82%A6%E3%83%A0_(III)" title="塩化ルテニウム (III) – 日语" lang="ja" hreflang="ja" data-title="塩化ルテニウム (III)" data-language-autonym="日本語" data-language-local-name="日语" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-pl mw-list-item"><a href="https://pl.wikipedia.org/wiki/Chlorek_rutenu(III)" title="Chlorek rutenu(III) – 波兰语" lang="pl" hreflang="pl" data-title="Chlorek rutenu(III)" data-language-autonym="Polski" data-language-local-name="波兰语" class="interlanguage-link-target"><span>Polski</span></a></li><li class="interlanguage-link interwiki-pt mw-list-item"><a href="https://pt.wikipedia.org/wiki/Cloreto_de_rut%C3%AAnio(III)" title="Cloreto de rutênio(III) – 葡萄牙语" lang="pt" hreflang="pt" data-title="Cloreto de rutênio(III)" data-language-autonym="Português" data-language-local-name="葡萄牙语" class="interlanguage-link-target"><span>Português</span></a></li><li class="interlanguage-link interwiki-ru mw-list-item"><a href="https://ru.wikipedia.org/wiki/%D0%A5%D0%BB%D0%BE%D1%80%D0%B8%D0%B4_%D1%80%D1%83%D1%82%D0%B5%D0%BD%D0%B8%D1%8F(III)" title="Хлорид рутения(III) – 俄语" lang="ru" hreflang="ru" data-title="Хлорид рутения(III)" data-language-autonym="Русский" data-language-local-name="俄语" class="interlanguage-link-target"><span>Русский</span></a></li><li class="interlanguage-link interwiki-vi mw-list-item"><a href="https://vi.wikipedia.org/wiki/Rutheni(III)_chloride" title="Rutheni(III) chloride – 越南语" lang="vi" hreflang="vi" data-title="Rutheni(III) chloride" data-language-autonym="Tiếng Việt" data-language-local-name="越南语" class="interlanguage-link-target"><span>Tiếng Việt</span></a></li><li class="interlanguage-link interwiki-wuu mw-list-item"><a href="https://wuu.wikipedia.org/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%92%8C" title="三氯化钌 – 吴语" lang="wuu" hreflang="wuu" data-title="三氯化钌" data-language-autonym="吴语" data-language-local-name="吴语" class="interlanguage-link-target"><span>吴语</span></a></li> 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data-event-name="pinnable-header.vector-appearance.pin">移至侧栏</button> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-unpin-button" data-event-name="pinnable-header.vector-appearance.unpin">隐藏</button> </div> </div> </div> </nav> </div> </div> <div id="bodyContent" class="vector-body" aria-labelledby="firstHeading" data-mw-ve-target-container> <div class="vector-body-before-content"> <div class="mw-indicators"> </div> <div id="siteSub" class="noprint">维基百科，自由的百科全书</div> </div> <div id="contentSub"><div id="mw-content-subtitle"></div></div> <div id="mw-content-text" class="mw-body-content"><div class="mw-content-ltr mw-parser-output" lang="zh" dir="ltr"><style data-mw-deduplicate="TemplateStyles:r84001320">.mw-parser-output .ib-chembox{border-collapse:collapse;text-align:left}.mw-parser-output .ib-chembox td,.mw-parser-output .ib-chembox th{border:1px solid #a2a9b1;width:40%}.mw-parser-output .ib-chembox td+td{width:60%}</style> <table class="infobox ib-chembox nounderlines" cellspacing="0" cellpadding="3" rules="all" style="background-color:#f0f0f0; float:right; margin: 0 0 1em 1em; border-color: #aaaaaa; border-style:solid; border:1px; border-collapse:collapse; empty-cells:show; width:305px; font-size:90%;"> <tbody><tr> <th colspan="2" style="font-size:120%; text-align:center; background:#d6e0dc;">三氯化钌 </th></tr> <tr> <td colspan="2" style="background:#ffffff; text-align:center;"><span typeof="mw:File"><a href="/wiki/File:RuCl3structure.jpg" class="mw-file-description"><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/1/1a/RuCl3structure.jpg/200px-RuCl3structure.jpg" decoding="async" width="200" height="129" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/1/1a/RuCl3structure.jpg/300px-RuCl3structure.jpg 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/1/1a/RuCl3structure.jpg/400px-RuCl3structure.jpg 2x" data-file-width="600" data-file-height="387" /></a></span> </td></tr> <tr> <td colspan="2" style="background:#ffffff; text-align:center;"><span typeof="mw:File"><a href="/wiki/File:Ruthenium(III)_chloride_hydrate.jpg" class="mw-file-description"><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/2/21/Ruthenium%28III%29_chloride_hydrate.jpg/200px-Ruthenium%28III%29_chloride_hydrate.jpg" decoding="async" width="200" height="192" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/2/21/Ruthenium%28III%29_chloride_hydrate.jpg/300px-Ruthenium%28III%29_chloride_hydrate.jpg 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/2/21/Ruthenium%28III%29_chloride_hydrate.jpg/400px-Ruthenium%28III%29_chloride_hydrate.jpg 2x" data-file-width="2732" data-file-height="2628" /></a></span> </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">识别 </th></tr> <tr> <td><a href="/wiki/CAS%E5%8F%B7" title="CAS号">CAS号</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=10049-08-8">10049-08-8</a></span>（无水） <sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup><br /><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=13815-94-6">13815-94-6</a></span>（三水） <sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup><br /><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=14898-67-0">14898-67-0</a></span>（水合） <sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup> </td></tr> <tr> <td><a href="/wiki/PubChem" title="PubChem">PubChem</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="https://pubchem.ncbi.nlm.nih.gov/compound/82323">82323</a></span> </td></tr> <tr> <td><a href="/wiki/ChemSpider" title="ChemSpider">ChemSpider</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="http://www.chemspider.com/74294">74294</a></span> </td></tr> <tr> <td><a href="/wiki/SMILES" class="mw-redirect" title="SMILES">SMILES</a> </td> <td><div style="word-break:break-all;"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold;"><div> </div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0;"><li style="line-height: inherit; margin: 0"><span lang="en">[Cl-].[Cl-].[Cl-].[Ru+3]</span></li></ul> </div></div> </td></tr> <tr> <td><a href="/wiki/%E5%9B%BD%E9%99%85%E5%8C%96%E5%90%88%E7%89%A9%E6%A0%87%E8%AF%86" title="国际化合物标识">InChI</a> </td> <td><div style="word-break:break-all;"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold;"><div> </div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0;"><li style="line-height: inherit; margin: 0">1/3ClH.Ru/h3*1H;/q;;;+3/p-3</li></ul> </div></div> </td></tr> <tr> <td><a href="/wiki/%E5%9B%BD%E9%99%85%E5%8C%96%E5%90%88%E7%89%A9%E6%A0%87%E8%AF%86" title="国际化合物标识">InChIKey</a> </td> <td><small>YBCAZPLXEGKKFM-DFZHHIFOAX</small> </td></tr> <tr> <td><a href="/wiki/%E5%8C%96%E5%AD%A6%E7%89%A9%E8%B4%A8%E6%AF%92%E6%80%A7%E6%95%B0%E6%8D%AE%E5%BA%93" title="化学物质毒性数据库">RTECS</a> </td> <td>VM2650000 </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">性质 </th></tr> <tr> <td><a href="/wiki/%E5%8C%96%E5%AD%A6%E5%BC%8F" title="化学式">化学式</a> </td> <td><span lang="en">RuCl<sub>3</sub></span> </td></tr> <tr> <td><a href="/wiki/%E6%91%A9%E5%B0%94%E8%B4%A8%E9%87%8F" title="摩尔质量">摩尔质量</a> </td> <td>207.43 g/mol g·mol⁻¹ </td></tr> <tr> <td><a href="/wiki/%E7%86%94%E7%82%B9" title="熔点">熔点</a> </td> <td>>500 °C (分解) </td></tr> <tr> <td><a href="/wiki/%E6%BA%B6%E8%A7%A3%E6%80%A7" class="mw-redirect" title="溶解性">溶解性</a>（<a href="/wiki/%E6%B0%B4" title="水">水</a>） </td> <td>能溶 </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">结构 </th></tr> <tr> <td><a href="/wiki/%E6%99%B6%E4%BD%93%E7%BB%93%E6%9E%84" title="晶体结构">晶体结构</a> </td> <td><a href="/w/index.php?title=Trigonal&action=edit&redlink=1" class="new" title="Trigonal（页面不存在）">trigonal</a> (RuCl<sub>3</sub>), <a href="/wiki/%E7%9A%AE%E5%B0%94%E9%80%8A%E7%AC%A6%E5%8F%B7" title="皮尔逊符号">hP8</a> </td></tr> <tr> <td><a href="/wiki/%E7%A9%BA%E9%97%B4%E7%BE%A4" title="空间群">空间群</a> </td> <td>P3c1, No. 158 </td></tr> <tr> <td><a href="/wiki/%E9%85%8D%E5%90%88%E7%89%A9%E7%BB%93%E6%9E%84" title="配合物结构">配位几何</a> </td> <td>八面体 </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">危险性 </th></tr> <tr> <td>欧盟编号 </td> <td>未列出 </td></tr> <tr> <td><a href="/wiki/%E9%97%AA%E7%82%B9" title="闪点">闪点</a> </td> <td>不易燃 </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">相关物质 </th></tr> <tr> <td>其他<a href="/wiki/%E9%98%B4%E7%A6%BB%E5%AD%90" class="mw-redirect" title="阴离子">阴离子</a> </td> <td><a href="/wiki/%E4%B8%89%E6%BA%B4%E5%8C%96%E9%92%8C" title="三溴化钌">三溴化钌</a> </td></tr> <tr> <td>其他<a href="/wiki/%E9%98%B3%E7%A6%BB%E5%AD%90" class="mw-redirect" title="阳离子">阳离子</a> </td> <td><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%93%91" title="三氯化铑">三氯化铑</a><br /><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%93%81" class="mw-redirect" title="三氯化铁">三氯化铁</a><br /><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%94%87" title="三氯化锇">三氯化锇</a> </td></tr> <tr> <td>相关化学品 </td> <td><a href="/wiki/%E5%9B%9B%E6%B0%A7%E5%8C%96%E9%92%8C" title="四氧化钌">四氧化钌</a> </td></tr> <tr> <td style="background:#D6E0DC; text-align:center;" colspan="2">若非注明，所有数据均出自<a href="/wiki/%E6%A0%87%E5%87%86%E7%8A%B6%E6%80%81" title="标准状态">标准状态（25 ℃，100 kPa）</a>下。 </td></tr></tbody></table> <p><b>三氯化钌</b>，<a href="/wiki/%E5%88%86%E5%AD%90%E5%BC%8F" title="分子式">分子式</a>為RuCl<sub>3</sub>。一般所指的“三氯化钌”多指三氯化钌的水合物RuCl<sub>3</sub>·<i>x</i>H<sub>2</sub>O。无水三氯化钌和它的水合物均为棕黑色固体。三氯化钌的水合物通常是三水合物。这是一种钌化学常用的起始原料，可合成多个重要的、可作为均相催化剂或催化剂前体的钌配合物。 </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="制备方法及性质"><span id=".E5.88.B6.E5.A4.87.E6.96.B9.E6.B3.95.E5.8F.8A.E6.80.A7.E8.B4.A8"></span>制备方法及性质</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E4%B8%89%E6%B0%AF%E5%8C%96%E9%92%8C&action=edit&section=1" title="编辑章节：制备方法及性质"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>无水三氯化钌较少在反应中使用，通常可在氯气和一氧化碳组成的混合气（氯气和一氧化碳的比例为4;1）气氛中加热金属钌的粉末至700 °C来制得。产物以气流的形式逸出反应装置后冷却结晶<sup id="cite_ref-1" class="reference"><a href="#cite_note-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>。三氯化钌晶体有两种晶形，黑色的α-RuCl<sub>3</sub>具有与<a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%93%AC" class="mw-redirect" title="三氯化铬">三氯化铬</a>相同的晶体结构，两个相邻的钌原子间的距离较长，达到346 pm。棕黑色的<a href="/wiki/%E4%BA%9A%E7%A8%B3%E6%80%81" class="mw-redirect" title="亚稳态">亚稳态</a>β-RuCl<sub>3</sub>的以六角形的八面体结构为基本单元进行结晶，六角形结构的基本单元之间通过两两共面形成无限延长的链状结构，相邻的两个钌原子间的距离为283 pm。450–600 °C亚稳态的β-RuCl<sub>3</sub>不可逆地转变为α-RuCl<sub>3</sub>。 </p><p>气态的三氯化钌在高温下分解生成单质。 </p> <div class="mw-heading mw-heading2"><h2 id="反应"><span id=".E5.8F.8D.E5.BA.94"></span>反应</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E4%B8%89%E6%B0%AF%E5%8C%96%E9%92%8C&action=edit&section=2" title="编辑章节：反应"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>水合三氯化钌和次氯酸钠水溶液反应，可以得到<a href="/wiki/%E5%9B%9B%E6%B0%A7%E5%8C%96%E9%92%8C" title="四氧化钌">四氧化钌</a>： </p> <dl><dd>2RuCl<sub>3</sub>·<i>x</i>H<sub>2</sub>O + 8 NaClO → 2 RuO<sub>4</sub> + 8 HCl + 3 Cl<sub>2</sub> + 3 H<sub>2</sub>O</dd></dl> <p>三氯化钌在硫氰酸盐的浓溶液中可以形成红色的配合物<sup id="cite_ref-2" class="reference"><a href="#cite_note-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup>，它加热变为紫色。<sup id="cite_ref-3" class="reference"><a href="#cite_note-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="三氯化钌和有机配体的反应"><span id=".E4.B8.89.E6.B0.AF.E5.8C.96.E9.92.8C.E5.92.8C.E6.9C.89.E6.9C.BA.E9.85.8D.E4.BD.93.E7.9A.84.E5.8F.8D.E5.BA.94"></span>三氯化钌和有机配体的反应</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E4%B8%89%E6%B0%AF%E5%8C%96%E9%92%8C&action=edit&section=3" title="编辑章节：三氯化钌和有机配体的反应"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li>RuCl<sub>2</sub>(PPh<sub>3</sub>)<sub>3</sub>，一种可溶于苯的棕色固体，可用于催化苯乙烯的氢化。由三氯化钌的水合物和<a href="/wiki/%E4%B8%89%E8%8B%AF%E5%9F%BA%E8%86%A6" title="三苯基膦">三苯基膦</a>反应得到<sup id="cite_ref-4" class="reference"><a href="#cite_note-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup></li></ul> <dl><dd>2RuCl<sub>3</sub>·<i>x</i>H<sub>2</sub>O + 7 PPh<sub>3</sub> → 2 RuCl<sub>2</sub>(PPh<sub>3</sub>)<sub>3</sub> + OPPh<sub>3</sub> + 5 H<sub>2</sub>O + 2 HCl</dd></dl> <ul><li>[RuCl<sub>2</sub>(<a href="/wiki/%E8%8B%AF" title="苯">C<sub>6</sub>H<sub>6</sub></a>)]，一种棕色的在苯中溶解度较差的配合物，可由三氯化钌的水合物与1,3-环己二烯脱氢反应制备<sup id="cite_ref-5" class="reference"><a href="#cite_note-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup></li></ul> <dl><dd>2 RuCl<sub>3</sub>·<i>x</i>H<sub>2</sub>O + 2 C<sub>6</sub>H<sub>8</sub> → [RuCl<sub>2</sub>(C<sub>6</sub>H<sub>6</sub>)]<sub>2</sub> + 6 H<sub>2</sub>O + 2 HCl + H<sub>2</sub></dd></dl> <p>配体苯可与其他芳烃比如六甲基苯发生配体交换<sup id="cite_ref-6" class="reference"><a href="#cite_note-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup> </p> <ul><li><a href="/w/index.php?title=%E6%B0%AF%E5%8C%96%E4%B8%89(%E5%8F%8C%E5%90%A1%E5%95%B6)%E5%90%88%E9%92%8C(II)&action=edit&redlink=1" class="new" title="氯化三(双吡啶)合钌(II)（页面不存在）">Ru(bipy)<sub>3</sub>Cl<sub>2</sub></a>可由2,2'-联吡啶与三氯化钌的醇溶液反应得到</li></ul> <dl><dd>RuCl<sub>3</sub>·<i>x</i>H<sub>2</sub>O + 3 <a href="/wiki/2,2%27-%E8%81%94%E5%90%A1%E5%95%B6" title="2,2'-联吡啶">bipy</a> + 0.5 CH<sub>3</sub>CH<sub>2</sub>OH → [Ru(bipy)<sub>3</sub>]Cl<sub>2</sub> + 3 H<sub>2</sub>O + 0.5 CH<sub>3</sub>CHO + HCl</dd></dl> <ul><li><a href="/w/index.php?title=%E4%BA%8C%E6%B0%AF%E5%8C%96(%E5%AF%B9%E5%BC%82%E4%B8%99%E5%9F%BA%E7%94%B2%E8%8B%AF)%E9%92%8C%E4%BA%8C%E8%81%9A%E4%BD%93&action=edit&redlink=1" class="new" title="二氯化(对异丙基甲苯)钌二聚体（页面不存在）">[(Cymene)RuCl<sub>2</sub>]<sub>2</sub></a>(或称对伞花烃二氯化钌二聚体)可由水合三氯化钌与<a href="/wiki/%E5%AF%B9%E5%BC%82%E4%B8%99%E5%9F%BA%E7%94%B2%E8%8B%AF" title="对异丙基甲苯">对异丙基甲苯</a>在乙醇溶液中反应制得<sup id="cite_ref-7" class="reference"><a href="#cite_note-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup></li></ul> <dl><dd>2 RuCl<sub>3</sub>·<i>x</i>H<sub>2</sub>O + 2 C<sub>10</sub>H<sub>16</sub> + CH<sub>3</sub>CH<sub>2</sub>OH → [(Cymene)RuCl<sub>2</sub>]<sub>2</sub> + 6 H<sub>2</sub>O + CH<sub>3</sub>CHO + 2 HCl</dd></dl> <ul><li>RuCl(PPh<sub>3</sub>)<sub>2</sub>(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)可由水合三氯化钌和三苯基膦、环戊二烯在乙醇溶液中加热反应得到<sup id="cite_ref-8" class="reference"><a href="#cite_note-8"><span class="cite-bracket">[</span>8<span class="cite-bracket">]</span></a></sup></li></ul> <dl><dd>RuCl<sub>3</sub>·<i>x</i>H<sub>2</sub>O + 2 PPh<sub>3</sub> + C<sub>5</sub>H<sub>6</sub> + 0.5 C<sub>2</sub>H<sub>5</sub>OH → RuCl(PPh<sub>3</sub>)<sub>2</sub>(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>) + 3 H<sub>2</sub>O + 0.5 CH<sub>3</sub>CHO + HCl</dd></dl> <ul><li><a href="/w/index.php?title=%E4%B8%89(%E4%B9%99%E9%85%B0%E4%B8%99%E9%85%AE)%E9%92%8C(III)&action=edit&redlink=1" class="new" title="三(乙酰丙酮)钌(III)（页面不存在）">Ru(C<sub>5</sub>H<sub>7</sub>O<sub>2</sub>)<sub>3</sub></a>，红色、溶于苯的配合物，可有水合三氯化钌和<a href="/wiki/%E4%B9%99%E9%85%B0%E4%B8%99%E9%85%AE" title="乙酰丙酮">乙酰丙酮</a>在盐酸和甲苯的混合溶液加热回流反应得到<sup id="cite_ref-9" class="reference"><a href="#cite_note-9"><span class="cite-bracket">[</span>9<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-10" class="reference"><a href="#cite_note-10"><span class="cite-bracket">[</span>10<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-11" class="reference"><a href="#cite_note-11"><span class="cite-bracket">[</span>11<span class="cite-bracket">]</span></a></sup></li></ul> <dl><dd>RuCl<sub>3</sub>·<i>x</i>H<sub>2</sub>O + 3 C<sub>5</sub>H<sub>8</sub>O<sub>2</sub> → Ru(C<sub>5</sub>H<sub>7</sub>O<sub>2</sub>)<sub>3</sub> + 3 H<sub>2</sub>O + 3 HCl</dd></dl> <div class="mw-heading mw-heading3"><h3 id="三氯化钌和一氧化碳反应"><span id=".E4.B8.89.E6.B0.AF.E5.8C.96.E9.92.8C.E5.92.8C.E4.B8.80.E6.B0.A7.E5.8C.96.E7.A2.B3.E5.8F.8D.E5.BA.94"></span>三氯化钌和一氧化碳反应</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E4%B8%89%E6%B0%AF%E5%8C%96%E9%92%8C&action=edit&section=4" title="编辑章节：三氯化钌和一氧化碳反应"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>与同族的铁的氯化物几乎不与<a href="/wiki/%E4%B8%80%E6%B0%A7%E5%8C%96%E7%A2%B3" title="一氧化碳">一氧化碳</a>反应的性质形成对比，水合氯化钌能与一氧化碳在温和的条件下反应<sup id="cite_ref-12" class="reference"><a href="#cite_note-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup>。一氧化碳可将三价的氯化钌还原成黄色的二价钌物种。特别是在1atmCO气氛下的水合三氯化钌的乙醇溶液中取决于具体反应条件的不同，会反应产生[Ru<sub>2</sub>Cl<sub>4</sub>(CO)<sub>4</sub>]、 [Ru<sub>2</sub>Cl<sub>4</sub>(CO)<sub>4</sub>]<sup>2-</sup>或[RuCl<sub>3</sub>(CO)<sub>3</sub>]<sup>-</sup> </p> <dl><dd><dl><dd>3 RuCl<sub>3</sub>·<i>x</i>H<sub>2</sub>O + 4.5 Zn + 12 CO (高压) → <a href="/wiki/%E5%8D%81%E4%BA%8C%E7%BE%B0%E5%9F%BA%E4%B8%89%E9%92%8C" title="十二羰基三钌">Ru<sub>3</sub>(CO)<sub>12</sub></a> + 3 H<sub>2</sub>O + 4.5 ZnCl<sub>2</sub></dd></dl></dd></dl> <div class="mw-heading mw-heading2"><h2 id="参考资料"><span id=".E5.8F.82.E8.80.83.E8.B5.84.E6.96.99"></span>参考资料</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E4%B8%89%E6%B0%AF%E5%8C%96%E9%92%8C&action=edit&section=5" title="编辑章节：参考资料"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="reflist columns references-column-count references-column-count-2" 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style="padding:0em 0.25em"> <table style="width:100%;margin:0 auto;"> <tbody><tr style="background-color:mistyrose;vertical-align:top"> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E6%B0%A2" title="氯化氢">HCl</a> </td> <td style="background-color:white;border:none"> </td> <td style="background-color:white;border:none" colspan="10" rowspan="3"> </td> <td style="background-color:white;border:none" colspan="5"> </td> <td>He </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%94%82" title="氯化锂">LiCl</a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%93%8D" title="氯化铍">BeCl<sub>2</sub></a> </td> <td><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E7%A1%BC" title="三氯化硼">BCl<sub>3</sub></a> <br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E4%BA%8C%E7%A1%BC" title="四氯化二硼">B<sub>2</sub>Cl<sub>4</sub></a> </td> <td><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E7%A2%B3" title="四氯化碳">CCl<sub>4</sub></a><br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E4%B9%99%E7%83%AF" title="四氯乙烯">C<sub>2</sub>Cl<sub>4</sub></a><br /><a href="/wiki/%E5%85%AD%E6%B0%AF%E4%B9%99%E7%83%B7" title="六氯乙烷">C<sub>2</sub>Cl<sub>6</sub></a> </td> <td><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E6%B0%AE" title="三氯化氮">NCl<sub>3</sub></a><br /><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%93%B5" title="氯化铵">NH<sub>4</sub>Cl</a><br /><a href="/wiki/%E7%9B%90%E9%85%B8%E7%BE%9F%E8%83%BA" title="盐酸羟胺">NH<sub>4</sub>OCl</a> <br /><a href="/wiki/%E5%8F%A0%E6%B0%AE%E5%8C%96%E6%B0%AF" title="叠氮化氯">ClN<sub>3</sub></a> </td> <td><a href="/wiki/%E4%B8%80%E6%B0%A7%E5%8C%96%E4%BA%8C%E6%B0%AF" title="一氧化二氯">Cl<sub>2</sub>O</a><br /><a href="/wiki/%E4%BA%8C%E6%B0%A7%E5%8C%96%E6%B0%AF" title="二氧化氯">ClO<sub>2</sub></a><br /><a href="/wiki/%E4%B8%83%E6%B0%A7%E5%8C%96%E4%BA%8C%E6%B0%AF" title="七氧化二氯">Cl<sub>2</sub>O<sub>7</sub></a> </td> <td><a href="/wiki/%E4%B8%80%E6%B0%9F%E5%8C%96%E6%B0%AF" title="一氟化氯">ClF</a> <br /><a href="/wiki/%E4%B8%89%E6%B0%9F%E5%8C%96%E6%B0%AF" title="三氟化氯">ClF<sub>3</sub></a><br /><a href="/wiki/%E4%BA%94%E6%B0%9F%E5%8C%96%E6%B0%AF" title="五氟化氯">ClF<sub>5</sub></a> </td> <td>Ne </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%92%A0" title="氯化钠">NaCl</a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%95%81" title="氯化镁">MgCl<sub>2</sub></a> </td> <td><a href="/wiki/%E4%B8%80%E6%B0%AF%E5%8C%96%E9%93%9D" title="一氯化铝">AlCl</a><br /><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%93%9D" title="氯化铝">AlCl<sub>3</sub></a> </td> <td><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E7%A1%85" title="四氯化硅">SiCl<sub>4</sub></a> </td> <td><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E4%BA%8C%E7%A3%B7" title="四氯化二磷">P<sub>2</sub>Cl<sub>4</sub></a><br /><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E7%A3%B7" title="三氯化磷">PCl<sub>3</sub></a><br /><a href="/wiki/%E4%BA%94%E6%B0%AF%E5%8C%96%E7%A3%B7" title="五氯化磷">PCl<sub>5</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E4%BA%8C%E7%A1%AB" title="二氯化二硫">S<sub>2</sub>Cl<sub>2</sub></a><br /><a href="/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E7%A1%AB" title="二氯化硫">SCl<sub>2</sub></a><br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E7%A1%AB" title="四氯化硫">SCl<sub>4</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E7%89%A9" title="氯化物">Cl<sup>-</sup></a><br /><a href="/wiki/%E6%B0%AF%E6%B0%94" title="氯气">Cl<sub>2</sub></a> </td> <td>Ar </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%92%BE" title="氯化钾">KCl</a> </td> <td><a href="/wiki/%E4%B8%80%E6%B0%AF%E5%8C%96%E9%92%99" title="一氯化钙">CaCl</a><br /><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%88%A3" title="氯化鈣">CaCl<sub>2</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%92%AA" title="氯化钪">ScCl<sub>3</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E9%92%9B" title="二氯化钛">TiCl<sub>2</sub></a><br /><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%92%9B" title="三氯化钛">TiCl<sub>3</sub></a><br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%92%9B" title="四氯化钛">TiCl<sub>4</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E9%92%92" title="二氯化钒">VCl<sub>2</sub></a><br /><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%92%92" title="三氯化钒">VCl<sub>3</sub></a><br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%92%92" title="四氯化钒">VCl<sub>4</sub></a> <br /><a href="/wiki/%E4%BA%94%E6%B0%AF%E5%8C%96%E9%92%92" title="五氯化钒">VCl<sub>5</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E4%BA%9A%E9%93%AC" title="氯化亚铬">CrCl<sub>2</sub></a><br /><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%93%AC" title="氯化铬">CrCl<sub>3</sub></a><br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%93%AC" title="四氯化铬">CrCl<sub>4</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%94%B0" title="氯化锰">MnCl<sub>2</sub></a><br /><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%94%B0" title="三氯化锰">MnCl<sub>3</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E4%BA%9A%E9%93%81" title="氯化亚铁">FeCl<sub>2</sub></a><br /><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%93%81" title="氯化铁">FeCl<sub>3</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%88%B7" title="氯化鈷">CoCl<sub>2</sub></a> <br /> <span class="ilh-all" data-orig-title="三氯化钴" data-lang-code="en" data-lang-name="英语" data-foreign-title="Cobalt(III) chloride"><span class="ilh-page"><a href="/w/index.php?title=%E4%B8%89%E6%B0%AF%E5%8C%96%E9%92%B4&action=edit&redlink=1" class="new" title="三氯化钴（页面不存在）">CoCl<sub>3</sub></a></span><span class="noprint ilh-comment">（<span class="ilh-lang">英语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://en.wikipedia.org/wiki/Cobalt(III)_chloride" class="extiw" title="en:Cobalt(III) chloride"><span lang="en" dir="auto">Cobalt(III) chloride</span></a></span>）</span></span> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%95%8D" title="氯化镍">NiCl<sub>2</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E4%BA%9A%E9%93%9C" title="氯化亚铜">CuCl</a><br /><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%93%9C" title="氯化铜">CuCl<sub>2</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%94%8C" title="氯化锌">ZnCl<sub>2</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E9%95%93" title="二氯化镓">GaCl<sub>2</sub></a><br /><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%95%93" title="氯化镓">GaCl<sub>3</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E9%94%97" title="二氯化锗">GeCl<sub>2</sub></a><br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%8D%BA" title="四氯化鍺">GeCl<sub>4</sub></a> </td> <td><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E7%A0%B7" title="三氯化砷">AsCl<sub>3</sub></a><br /><a href="/wiki/%E4%BA%94%E6%B0%AF%E5%8C%96%E7%A0%B7" title="五氯化砷">AsCl<sub>5</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E4%BA%8C%E7%A1%92" title="二氯化二硒">Se<sub>2</sub>Cl<sub>2</sub></a><br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E7%A1%92" title="四氯化硒">SeCl<sub>4</sub></a> </td> <td><a href="/wiki/%E4%B8%80%E6%B0%AF%E5%8C%96%E6%BA%B4" title="一氯化溴">BrCl</a> </td> <td><a href="/w/index.php?title=%E4%B8%80%E6%B0%AF%E5%8C%96%E6%B0%AA&action=edit&redlink=1" class="new" title="一氯化氪（页面不存在）">KrCl</a> </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%93%B7" title="氯化铷">RbCl</a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%94%B6" title="氯化锶">SrCl<sub>2</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%92%87" title="氯化钇">YCl<sub>3</sub></a> </td> <td><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%94%86" title="三氯化锆">ZrCl<sub>3</sub></a><br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%94%86" title="四氯化锆">ZrCl<sub>4</sub></a> </td> <td><span class="ilh-all" data-orig-title="三氯化铌" data-lang-code="en" data-lang-name="英语" data-foreign-title="niobium trichloride"><span class="ilh-page"><a href="/w/index.php?title=%E4%B8%89%E6%B0%AF%E5%8C%96%E9%93%8C&action=edit&redlink=1" class="new" title="三氯化铌（页面不存在）">NbCl<sub>3</sub></a></span><span class="noprint ilh-comment">（<span class="ilh-lang">英语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://en.wikipedia.org/wiki/niobium_trichloride" class="extiw" title="en:niobium trichloride"><span lang="en" dir="auto">niobium trichloride</span></a></span>）</span></span><br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%93%8C" title="四氯化铌">NbCl<sub>4</sub></a><br /><a href="/wiki/%E4%BA%94%E6%B0%AF%E5%8C%96%E9%93%8C" title="五氯化铌">NbCl<sub>5</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E9%92%BC" title="二氯化钼">MoCl<sub>2</sub></a><br /><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%92%BC" title="三氯化钼">MoCl<sub>3</sub></a><br /> <a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%92%BC" title="四氯化钼">MoCl<sub>4</sub></a><br /><a href="/wiki/%E4%BA%94%E6%B0%AF%E5%8C%96%E9%92%BC" title="五氯化钼">Mo<sub>2</sub>Cl<sub>10</sub></a><br /><a href="/wiki/%E5%85%AD%E6%B0%AF%E5%8C%96%E9%92%BC" title="六氯化钼">MoCl<sub>6</sub></a> </td> <td><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%94%9D" title="三氯化锝">TcCl<sub>3</sub></a><br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%8E%9D" title="四氯化鎝">TcCl<sub>4</sub></a> </td> <td><a class="mw-selflink selflink">RuCl<sub>3</sub></a> </td> <td><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%93%91" title="三氯化铑">RhCl<sub>3</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%92%AF" title="氯化钯">PdCl<sub>2</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%93%B6" title="氯化银">AgCl</a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%8E%98" title="氯化鎘">CdCl<sub>2</sub></a> </td> <td><a href="/wiki/%E4%B8%80%E6%B0%AF%E5%8C%96%E9%93%9F" title="一氯化铟">InCl</a><br /><a href="/w/index.php?title=%E4%BA%8C%E6%B0%AF%E5%8C%96%E9%93%9F&action=edit&redlink=1" class="new" title="二氯化铟（页面不存在）">InCl<sub>2</sub></a><br /><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%93%9F" title="氯化铟">InCl<sub>3</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E4%BA%9E%E9%8C%AB" title="氯化亞錫">SnCl<sub>2</sub></a><br /><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%8C%AB" title="氯化錫">SnCl<sub>4</sub></a> </td> <td><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%8A%BB" title="三氯化銻">SbCl<sub>3</sub></a><br /><a href="/wiki/%E4%BA%94%E6%B0%AF%E5%8C%96%E9%94%91" title="五氯化锑">SbCl<sub>5</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E4%B8%89%E7%A2%B2" title="二氯化三碲">Te<sub>3</sub>Cl<sub>2</sub></a><br /><a href="/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E7%A2%B2" title="二氯化碲">TeCl<sub>2</sub></a><br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E7%A2%B2" title="四氯化碲">TeCl<sub>4</sub></a> </td> <td><a href="/wiki/%E4%B8%80%E6%B0%AF%E5%8C%96%E7%A2%98" title="一氯化碘">ICl</a><br /><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E7%A2%98" title="三氯化碘">ICl<sub>3</sub></a> </td> <td><span class="ilh-all" data-orig-title="一氯化氙" data-lang-code="en" data-lang-name="英语" data-foreign-title="Xenon monochloride"><span class="ilh-page"><a href="/w/index.php?title=%E4%B8%80%E6%B0%AF%E5%8C%96%E6%B0%99&action=edit&redlink=1" class="new" title="一氯化氙（页面不存在）">XeCl</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">英语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://en.wikipedia.org/wiki/Xenon_monochloride" class="extiw" title="en:Xenon monochloride"><span lang="en" dir="auto">Xenon monochloride</span></a></span>）</span></span><br /><a href="/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E6%B0%99" title="二氯化氙">XeCl<sub>2</sub></a><br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E6%B0%99" title="四氯化氙">XeCl<sub>4</sub></a> </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%93%AF" title="氯化铯">CsCl</a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%8B%87" title="氯化鋇">BaCl<sub>2</sub></a> </td> <td style="background-color:white;border:none"><span title="镧系元素" style="font-family: Courier, monospace;">镧系</span> </td> <td><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%93%AA" title="四氯化铪">HfCl<sub>4</sub></a> </td> <td><a href="/w/index.php?title=%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%92%BD&action=edit&redlink=1" class="new" title="四氯化钽（页面不存在）">TaCl<sub>4</sub></a><br /><a href="/wiki/%E4%BA%94%E6%B0%AF%E5%8C%96%E9%92%BD" title="五氯化钽">TaCl<sub>5</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E9%92%A8" title="二氯化钨">W<sub>6</sub>Cl<sub>12</sub></a><br /><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%92%A8" title="三氯化钨">W<sub>6</sub>Cl<sub>18</sub></a> <br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%92%A8" title="四氯化钨">WCl<sub>4</sub></a><br /> <a href="/wiki/%E4%BA%94%E6%B0%AF%E5%8C%96%E9%92%A8" title="五氯化钨">WCl<sub>5</sub></a> <br /><a href="/wiki/%E5%85%AD%E6%B0%AF%E5%8C%96%E9%92%A8" title="六氯化钨">WCl<sub>6</sub></a> </td> <td><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%93%BC" title="三氯化铼">ReCl<sub>3</sub></a><br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%93%BC" title="四氯化铼">ReCl<sub>4</sub></a><br /> <a href="/wiki/%E4%BA%94%E6%B0%AF%E5%8C%96%E9%93%BC" title="五氯化铼">ReCl<sub>5</sub></a> <br /> <a href="/wiki/%E5%85%AD%E6%B0%AF%E5%8C%96%E9%93%BC" title="六氯化铼">ReCl<sub>6</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E9%94%87" title="二氯化锇">OsCl<sub>2</sub></a><br /><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%94%87" title="三氯化锇">OsCl<sub>3</sub></a><br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%94%87" title="四氯化锇">OsCl<sub>4</sub></a><br /><a href="/wiki/%E4%BA%94%E6%B0%AF%E5%8C%96%E9%94%87" title="五氯化锇">OsCl<sub>5</sub></a> </td> <td><a href="/w/index.php?title=%E4%BA%8C%E6%B0%AF%E5%8C%96%E9%93%B1&action=edit&redlink=1" class="new" title="二氯化铱（页面不存在）">IrCl<sub>2</sub></a><br /><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%93%B1" title="三氯化铱">IrCl<sub>3</sub></a><br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%93%B1" title="四氯化铱">IrCl<sub>4</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E9%93%82" title="二氯化铂">PtCl<sub>2</sub></a><br /><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%93%82" title="三氯化铂">PtCl<sub>3</sub></a><br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%93%82" title="四氯化铂">PtCl<sub>4</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E4%BA%9A%E9%87%91" title="氯化亚金">AuCl</a><br /><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%87%91" title="氯化金">AuCl<sub>3</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E4%BA%9A%E6%B1%9E" title="氯化亚汞">Hg<sub>2</sub>Cl<sub>2</sub></a><br /><a href="/wiki/%E6%B0%AF%E5%8C%96%E6%B1%9E" title="氯化汞">HgCl<sub>2</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E4%BA%9A%E9%93%8A" title="氯化亚铊">TlCl</a><br /><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%93%8A" title="三氯化铊">TlCl<sub>3</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%89%9B" title="氯化鉛">PbCl<sub>2</sub></a><br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%93%85" title="四氯化铅">PbCl<sub>4</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%93%8B" title="氯化铋">BiCl<sub>3</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E9%92%8B" title="二氯化钋">PoCl<sub>2</sub></a><br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%92%8B" title="四氯化钋">PoCl<sub>4</sub></a> </td> <td><a href="/wiki/%E4%B8%80%E6%B0%AF%E5%8C%96%E7%A0%B9" class="mw-redirect" title="一氯化砹">AtCl</a> </td> <td><a href="/w/index.php?title=%E4%BA%8C%E6%B0%AF%E5%8C%96%E6%B0%A1&action=edit&redlink=1" class="new" title="二氯化氡（页面不存在）">RnCl<sub>2</sub></a> </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%92%AB" title="氯化钫">FrCl</a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%95%AD" title="氯化镭">RaCl<sub>2</sub></a> </td> <td style="background-color:white;border:none"><span title="锕系元素" style="font-family: Courier, monospace;">锕系</span> </td> <td><a href="/wiki/%F0%AC%AC%BB#实验化学" class="mw-redirect" title="𬬻">RfCl<sub>4</sub></a> </td> <td>Db </td> <td>Sg </td> <td>Bh </td> <td>Hs </td> <td>Mt </td> <td>Ds </td> <td>Rg </td> <td>Cn </td> <td>Nh </td> <td>Fl </td> <td>Mc </td> <td>Lv </td> <td>Ts </td> <td>Og </td></tr> <tr> <td style="background-color:white;border:none" rowspan="3"> </td> <td style="background-color:white;border:none" colspan="1"> </td> <td style="background-color:white;border:none">↓ </td> <td style="background-color:white;border:none" colspan="14"> </td> <td style="background-color:white;border:none" rowspan="3"> </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td style="background-color:white;border:none"><span title="镧系元素" style="font-family: Courier, monospace;">镧系</span> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%95%A7" title="氯化镧">LaCl<sub>3</sub></a> </td> <td><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%93%88" title="三氯化铈">CeCl<sub>3</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%95%A8" title="氯化镨">PrCl<sub>3</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E9%92%95" title="二氯化钕">NdCl<sub>2</sub></a><br /><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%92%95" title="三氯化钕">NdCl<sub>3</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%92%B7" title="氯化钷">PmCl<sub>3</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E4%BA%9A%E9%92%90" title="氯化亚钐">SmCl<sub>2</sub></a><br /><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%92%90" title="氯化钐">SmCl<sub>3</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E4%BA%9A%E9%93%95" title="氯化亚铕">EuCl<sub>2</sub></a><br /><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%93%95" title="三氯化铕">EuCl<sub>3</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%92%86" title="氯化钆">GdCl<sub>3</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%93%BD" title="氯化铽">TbCl<sub>3</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E9%95%9D" title="二氯化镝">DyCl<sub>2</sub></a><br /><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%95%9D" title="氯化镝">DyCl<sub>3</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%92%AC" title="氯化钬">HoCl<sub>3</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%93%92" title="氯化铒">ErCl<sub>3</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E4%BA%9A%E9%93%A5" title="氯化亚铥">TmCl<sub>2</sub></a><br /><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%93%A5" title="氯化铥">TmCl<sub>3</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E9%95%B1" title="二氯化镱">YbCl<sub>2</sub></a><br /><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%95%B1" title="三氯化镱">YbCl<sub>3</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%95%A5" title="氯化镥">LuCl<sub>3</sub></a> </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td style="background-color:white;border:none"><span title="锕系元素" style="font-family: Courier, monospace;">锕系</span> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%94%95" title="氯化锕">AcCl<sub>3</sub></a> </td> <td><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%92%8D" title="四氯化钍">ThCl<sub>4</sub></a> </td> <td><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%8F%B7" title="四氯化鏷">PaCl<sub>4</sub></a><br /><a href="/wiki/%E4%BA%94%E6%B0%AF%E5%8C%96%E9%8F%B7" title="五氯化鏷">PaCl<sub>5</sub></a> </td> <td><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%93%80" title="三氯化铀">UCl<sub>3</sub></a><br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%93%80" title="四氯化铀">UCl<sub>4</sub></a><br /><a href="/wiki/%E4%BA%94%E6%B0%AF%E5%8C%96%E9%93%80" title="五氯化铀">UCl<sub>5</sub></a><br /><a href="/wiki/%E5%85%AD%E6%B0%AF%E5%8C%96%E9%93%80" title="六氯化铀">UCl<sub>6</sub></a> </td> <td><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%95%8E" title="三氯化镎">NpCl<sub>3</sub></a><br /><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%95%8E" title="四氯化镎">NpCl<sub>4</sub></a> </td> <td><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%92%9A" title="三氯化钚">PuCl<sub>3</sub></a> </td> <td><a href="/w/index.php?title=%E4%BA%8C%E6%B0%AF%E5%8C%96%E9%95%85&action=edit&redlink=1" class="new" title="二氯化镅（页面不存在）">AmCl<sub>2</sub></a><br /><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%95%85" title="三氯化镅">AmCl<sub>3</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%94%94" title="氯化锔">CmCl<sub>3</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%94%AB" title="氯化锫">BkCl<sub>3</sub></a> </td> <td><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%94%8E" title="氯化锎">CfCl<sub>3</sub></a> </td> <td><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%94%BF" title="三氯化锿">EsCl<sub>3</sub></a> </td> <td>Fm </td> <td>Md </td> <td>No </td> <td><a href="/w/index.php?title=%E4%B8%89%E6%B0%AF%E5%8C%96%E9%93%B9&action=edit&redlink=1" class="new" title="三氯化铹（页面不存在）">LrCl<sub>3</sub></a> </td></tr></tbody></table> </div></td></tr></tbody></table></div>    </div><noscript><img src="https://login.wikimedia.org/wiki/Special:CentralAutoLogin/start?type=1x1" alt="" width="1" height="1" style="border: none; position: absolute;"></noscript> <div class="printfooter" data-nosnippet="">检索自“<a dir="ltr" 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