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Few months later rainy season started and effected in total rainfall of over 3,300 mm. This paper presents results of survey repeated 1 year after the tsunami. To assess the effects of rainy season on mobilization of previously determined potential contaminants, the same locations were sampled again and analysed with the same methods. The tsunami deposit layer was well preserved but in many locations the sediments were coarser than just after tsunami due to washing out of finer fractions. The water-soluble salts contents were strongly reduced after the rainy season. However, the concentrations of acid leachable heavy metals and metalloids were still elevated in comparison to reference sample from an area not impacted by tsunami. It is possible that the metals and metalloids are successively moved to more bioavailable fraction from forms which were more resistant to mobilization.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/3647253" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="cac539b76a2e4041f0fe5c306cae9a71" rel="nofollow" data-download="{"attachment_id":50195956,"asset_id":3647253,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/50195956/download_file?st=MTc0MDE2MTYzMiw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="36962588" href="https://amu.academia.edu/MarcinFrankowski">Marcin Frankowski</a><script data-card-contents-for-user="36962588" type="text/json">{"id":36962588,"first_name":"Marcin","last_name":"Frankowski","domain_name":"amu","page_name":"MarcinFrankowski","display_name":"Marcin Frankowski","profile_url":"https://amu.academia.edu/MarcinFrankowski","photo":"https://0.academia-photos.com/36962588/10534304/11756240/s65_marcin.frankowski.jpg"}</script></span></span><span class="u-displayInlineBlock InlineList-item-text"> and <span class="u-textDecorationUnderline u-clickable InlineList-item-text js-work-more-authors-3647253">+2</span><div class="hidden js-additional-users-3647253"><div><span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a href="https://amu.academia.edu/WitoldSzczuci%C5%84ski">Witold Szczuciński</a></span></div><div><span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a href="https://independent.academia.edu/AnettaZio%C5%82a">Anetta Zioła</a></span></div></div></span><script>(function(){ var popoverSettings = { el: $('.js-work-more-authors-3647253'), placement: 'bottom', hide_delay: 200, html: true, content: function(){ return $('.js-additional-users-3647253').html(); 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Few months later rainy season started and effected in total rainfall of over 3,300 mm. This paper presents results of survey repeated 1 year after the tsunami. To assess the effects of rainy season on mobilization of previously determined potential contaminants, the same locations were sampled again and analysed with the same methods. The tsunami deposit layer was well preserved but in many locations the sediments were coarser than just after tsunami due to washing out of finer fractions. The water-soluble salts contents were strongly reduced after the rainy season. However, the concentrations of acid leachable heavy metals and metalloids were still elevated in comparison to reference sample from an area not impacted by tsunami. 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Zioła","profile_url":"https://independent.academia.edu/AnettaZio%C5%82a","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":6227,"name":"Arsenic","url":"https://www.academia.edu/Documents/in/Arsenic","nofollow":true},{"id":10096,"name":"Thailand","url":"https://www.academia.edu/Documents/in/Thailand","nofollow":true},{"id":15780,"name":"Taphonomy","url":"https://www.academia.edu/Documents/in/Taphonomy","nofollow":true},{"id":27085,"name":"Tsunami","url":"https://www.academia.edu/Documents/in/Tsunami","nofollow":true},{"id":57697,"name":"Heavy metals","url":"https://www.academia.edu/Documents/in/Heavy_metals"},{"id":65427,"name":"Tsunamigenic deposit","url":"https://www.academia.edu/Documents/in/Tsunamigenic_deposit"},{"id":67433,"name":"Soil contamination","url":"https://www.academia.edu/Documents/in/Soil_contamination"},{"id":82107,"name":"Salinity","url":"https://www.academia.edu/Documents/in/Salinity"},{"id":847302,"name":"Postdepositional Changes","url":"https://www.academia.edu/Documents/in/Postdepositional_Changes"}],"publication_year":2007,"publication_year_with_fallback":2007,"paper_rank":null,"all_time_views":38,"active_discussion":{}}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_3706797 coauthored" data-work_id="3706797" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/3706797/Analysis_of_Labile_Aluminium_Form_in_Grain_Size_Fractions_of_Tsunami_Deposits_in_Thailand">Analysis of Labile Aluminium Form in Grain Size Fractions of Tsunami Deposits in Thailand</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Our study presents the results of determining labile aluminium form in samples from the 2004 tsunami-affected coastal zone of Thailand. The samples were collected from tsunami deposits, beach sediments, sediments underlying the tsunami... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_3706797" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Our study presents the results of determining labile aluminium form in samples from the 2004 tsunami-affected coastal zone of Thailand. The samples were collected from tsunami deposits, beach sediments, sediments underlying the tsunami deposits (pre 2004 tsunami soil), as well as from soils from areas, that were not flooded. The extraction of the lable form of aluminium was performed using 3 mol L(-1) HCl in twelve grain size fractions. In the surface layer samples the highest concentrations were determined in the tsunami deposits in fractions < 0.063 mm (5850 mg kg(-1)). The highest determined concentration in the whole set of investigated samples occurred in soil sample in fractions 0.09-0.125 mm (19770 mg kg(-1)). An increase in concentration of labile aluminium form, along with decreasing grain diameter, was observed in samples from all the studied settings. In general, concentrations were higher in soil samples not affected by the tsunami. This is probably due to steady weathering of minerals during soil fori-ning processes and removal of sediment grain surface coatings potentially enriched in labile Al during high energy transport by tsunami.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/3706797" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="acdb5bfab7e2b6d99aa36f9555f7bdd2" rel="nofollow" data-download="{"attachment_id":31389974,"asset_id":3706797,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/31389974/download_file?st=MTc0MDE2MTYzMiw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="36962588" href="https://amu.academia.edu/MarcinFrankowski">Marcin Frankowski</a><script data-card-contents-for-user="36962588" type="text/json">{"id":36962588,"first_name":"Marcin","last_name":"Frankowski","domain_name":"amu","page_name":"MarcinFrankowski","display_name":"Marcin Frankowski","profile_url":"https://amu.academia.edu/MarcinFrankowski","photo":"https://0.academia-photos.com/36962588/10534304/11756240/s65_marcin.frankowski.jpg"}</script></span></span><span class="u-displayInlineBlock InlineList-item-text"> and <span class="u-textDecorationUnderline u-clickable InlineList-item-text js-work-more-authors-3706797">+2</span><div class="hidden js-additional-users-3706797"><div><span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a href="https://amu.academia.edu/WitoldSzczuci%C5%84ski">Witold Szczuciński</a></span></div><div><span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a href="https://independent.academia.edu/AnettaZio%C5%82a">Anetta Zioła</a></span></div></div></span><script>(function(){ var popoverSettings = { el: $('.js-work-more-authors-3706797'), placement: 'bottom', hide_delay: 200, html: true, content: function(){ return $('.js-additional-users-3706797').html(); 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The samples were collected from tsunami deposits, beach sediments, sediments underlying the tsunami deposits (pre 2004 tsunami soil), as well as from soils from areas, that were not flooded. The extraction of the lable form of aluminium was performed using 3 mol L(-1) HCl in twelve grain size fractions. In the surface layer samples the highest concentrations were determined in the tsunami deposits in fractions \u003c 0.063 mm (5850 mg kg(-1)). The highest determined concentration in the whole set of investigated samples occurred in soil sample in fractions 0.09-0.125 mm (19770 mg kg(-1)). An increase in concentration of labile aluminium form, along with decreasing grain diameter, was observed in samples from all the studied settings. In general, concentrations were higher in soil samples not affected by the tsunami. This is probably due to steady weathering of minerals during soil fori-ning processes and removal of sediment grain surface coatings potentially enriched in labile Al during high energy transport by tsunami.","publication":"Polish Journal of Environmental Studies 18:77-85. ","publication_with_fallback":"Polish Journal of Environmental Studies 18:77-85. 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Frankowski","profile_url":"https://amu.academia.edu/MarcinFrankowski","photo":"https://0.academia-photos.com/36962588/10534304/11756240/s65_marcin.frankowski.jpg"},{"id":4421380,"first_name":"Witold","last_name":"Szczuciński","domain_name":"amu","page_name":"WitoldSzczuciński","display_name":"Witold Szczuciński","profile_url":"https://amu.academia.edu/WitoldSzczuci%C5%84ski","photo":"https://0.academia-photos.com/4421380/1799696/2145977/s65_witold.szczuci_ski.jpg"},{"id":37534225,"first_name":"Anetta","last_name":"Zioła","domain_name":"independent","page_name":"AnettaZioła","display_name":"Anetta Zioła","profile_url":"https://independent.academia.edu/AnettaZio%C5%82a","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":10096,"name":"Thailand","url":"https://www.academia.edu/Documents/in/Thailand","nofollow":true},{"id":369525,"name":"Aluminium","url":"https://www.academia.edu/Documents/in/Aluminium","nofollow":true},{"id":850360,"name":"Tsunami Deposits","url":"https://www.academia.edu/Documents/in/Tsunami_Deposits","nofollow":true},{"id":859840,"name":"Labile Fraction","url":"https://www.academia.edu/Documents/in/Labile_Fraction","nofollow":true}],"publication_year":2009,"publication_year_with_fallback":2009,"paper_rank":null,"all_time_views":132,"active_discussion":{}}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_17291899 coauthored" data-work_id="17291899" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/17291899/The_application_of_multivariate_statistical_techniques_improves_single_wavelength_anomalous_diffraction_phasing">The application of multivariate statistical techniques improves single-wavelength anomalous diffraction phasing</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Multivariate statistical techniques such as factor analysis (FA), cluster analysis (CA) and discriminant analysis (DA), were applied for the evaluation of spatial variations and the interpretation of a large complex water quality data set... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_17291899" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Multivariate statistical techniques such as factor analysis (FA), cluster analysis (CA) and discriminant analysis (DA), were applied for the evaluation of spatial variations and the interpretation of a large complex water quality data set of three cities (Lahore, Gujranwala and Sialkot) in Punjab, Pakistan. 16 parameters of water samples collected from nine different sampling stations of each city were determined. Factor analysis indicates five factors, which explained 74% of the total variance in water quality data set. Five factors are salinization, alkalinity, temperature, domestic waste and chloride, which explained 31.1%, 14.3%, 10.6%, 10.0% and 8.0% of the total variance respectively. Hierarchical cluster analysis grouped nine sampling stations of each city into three clusters, i.e., relatively less polluted (LP), and moderately polluted (MP) and highly polluted (HP) sites, based on the similarity of water quality characteristics. Discriminant analysis (DA) identified ten significant parameters (Calcium (Ca), Ammonia, Sulphate, Sodium (Na), electrical conductivity (EC), chloride, temperature (Temp), total hardness(TH), Turbidity), which discriminate the groundwater quality of three cities, with close to 100.0% correct assignment for spatial variations. This study illustrates the benefit of multivariate statistical techniques for interpreting complex data sets in the analysis of spatial variations in water quality, and to plan for future studies.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/17291899" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="bba441a1b66b4507655f9bc950cc5faf" rel="nofollow" data-download="{"attachment_id":39432186,"asset_id":17291899,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/39432186/download_file?st=MTc0MDE2MTYzMiw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="36962588" href="https://amu.academia.edu/MarcinFrankowski">Marcin Frankowski</a><script data-card-contents-for-user="36962588" type="text/json">{"id":36962588,"first_name":"Marcin","last_name":"Frankowski","domain_name":"amu","page_name":"MarcinFrankowski","display_name":"Marcin Frankowski","profile_url":"https://amu.academia.edu/MarcinFrankowski","photo":"https://0.academia-photos.com/36962588/10534304/11756240/s65_marcin.frankowski.jpg"}</script></span></span><span class="u-displayInlineBlock InlineList-item-text"> and <span class="u-textDecorationUnderline u-clickable InlineList-item-text js-work-more-authors-17291899">+1</span><div class="hidden js-additional-users-17291899"><div><span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a href="https://independent.academia.edu/Azhareasa">Azhar easa</a></span></div></div></span><script>(function(){ var popoverSettings = { el: $('.js-work-more-authors-17291899'), placement: 'bottom', hide_delay: 200, html: true, content: function(){ return $('.js-additional-users-17291899').html(); 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Factor analysis indicates five factors, which explained 74% of the total variance in water quality data set. Five factors are salinization, alkalinity, temperature, domestic waste and chloride, which explained 31.1%, 14.3%, 10.6%, 10.0% and 8.0% of the total variance respectively. Hierarchical cluster analysis grouped nine sampling stations of each city into three clusters, i.e., relatively less polluted (LP), and moderately polluted (MP) and highly polluted (HP) sites, based on the similarity of water quality characteristics. Discriminant analysis (DA) identified ten significant parameters (Calcium (Ca), Ammonia, Sulphate, Sodium (Na), electrical conductivity (EC), chloride, temperature (Temp), total hardness(TH), Turbidity), which discriminate the groundwater quality of three cities, with close to 100.0% correct assignment for spatial variations. This study illustrates the benefit of multivariate statistical techniques for interpreting complex data sets in the analysis of spatial variations in water quality, and to plan for future studies.","publication":"Acta Crystallographica Section D Biological Crystallography","publication_with_fallback":"Acta Crystallographica Section D Biological 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class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The paper presents the results of aluminium determinations in ground water samples of the Miocene aquifer from the area of the city of Poznań (Poland). The determined aluminium content amounted from &amp;amp;amp;amp;amp;amp;amp;lt;0.0001... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_17291903" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The paper presents the results of aluminium determinations in ground water samples of the Miocene aquifer from the area of the city of Poznań (Poland). The determined aluminium content amounted from &amp;amp;amp;amp;amp;amp;amp;lt;0.0001 to 752.7 μg L(-1). The aluminium determinations were performed using three analytical techniques: graphite furnace atomic absorption spectrometry (GF-AAS), inductively coupled plasma atomic emission spectrometry (ICP-AES) and inductively coupled plasma mass spectrometry (ICP-MS). The results of aluminium determinations in groundwater samples for particular analytical techniques were compared. The results were used to identify the ascent of ground water from the Mesozoic aquifer to the Miocene aquifer in the area of the fault graben. Using the Mineql+ program, the modelling of the occurrence of aluminium and the following aluminium complexes: hydroxy, with fluorides and sulphates was performed. The paper presents the results of aluminium determinations in ground water using different analytical techniques as well as the chemical modelling in the Mineql+ program, which was performed for the first time and which enabled the identification of aluminium complexes in the investigated samples. The study confirms the occurrence of aluminium hydroxy complexes and aluminium fluoride complexes in the analysed groundwater samples. Despite the dominance of sulphates and organic matter in the sample, major participation of the complexes with these ligands was not stated based on the modelling.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/17291903" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="cadc59df7d0b1ab1ab87430a973ea65b" rel="nofollow" data-download="{"attachment_id":42271917,"asset_id":17291903,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/42271917/download_file?st=MTc0MDE2MTYzMiw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="36962588" href="https://amu.academia.edu/MarcinFrankowski">Marcin Frankowski</a><script data-card-contents-for-user="36962588" type="text/json">{"id":36962588,"first_name":"Marcin","last_name":"Frankowski","domain_name":"amu","page_name":"MarcinFrankowski","display_name":"Marcin Frankowski","profile_url":"https://amu.academia.edu/MarcinFrankowski","photo":"https://0.academia-photos.com/36962588/10534304/11756240/s65_marcin.frankowski.jpg"}</script></span></span></li><li class="js-paper-rank-work_17291903 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="17291903"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 17291903, container: ".js-paper-rank-work_17291903", }); 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The determined aluminium content amounted from \u0026amp;amp;amp;amp;amp;amp;amp;lt;0.0001 to 752.7 μg L(-1). The aluminium determinations were performed using three analytical techniques: graphite furnace atomic absorption spectrometry (GF-AAS), inductively coupled plasma atomic emission spectrometry (ICP-AES) and inductively coupled plasma mass spectrometry (ICP-MS). The results of aluminium determinations in groundwater samples for particular analytical techniques were compared. The results were used to identify the ascent of ground water from the Mesozoic aquifer to the Miocene aquifer in the area of the fault graben. Using the Mineql+ program, the modelling of the occurrence of aluminium and the following aluminium complexes: hydroxy, with fluorides and sulphates was performed. The paper presents the results of aluminium determinations in ground water using different analytical techniques as well as the chemical modelling in the Mineql+ program, which was performed for the first time and which enabled the identification of aluminium complexes in the investigated samples. The study confirms the occurrence of aluminium hydroxy complexes and aluminium fluoride complexes in the analysed groundwater samples. 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external electric fields</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Charge carriers and neutral reactive intermediates were generated by ionizing radiation in model insulatorsFAr solids doped with O 2 , N 2 and CO. Combining methods of activation spectroscopyFthermally and photon-stimulated exoelectron... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_17291906" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Charge carriers and neutral reactive intermediates were generated by ionizing radiation in model insulatorsFAr solids doped with O 2 , N 2 and CO. Combining methods of activation spectroscopyFthermally and photon-stimulated exoelectron emission (TSEE and PSEE) with thermally stimulated luminescence we studied electronic and atomic processes of relaxation in these metastable solids. This experimental approach enables us (i) to identify the charge of mobile charge carriers, (ii) to separate reactions of neutral and charged species and (iii) to find the interconnection between thermally driven chemical reactions and charge carrier dynamics in insulators. r</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/17291906" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="6a2f54d8fcd4eb9db0f256c1e56bd3ac" rel="nofollow" data-download="{"attachment_id":39432159,"asset_id":17291906,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/39432159/download_file?st=MTc0MDE2MTYzMiw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="36962588" href="https://amu.academia.edu/MarcinFrankowski">Marcin Frankowski</a><script data-card-contents-for-user="36962588" type="text/json">{"id":36962588,"first_name":"Marcin","last_name":"Frankowski","domain_name":"amu","page_name":"MarcinFrankowski","display_name":"Marcin Frankowski","profile_url":"https://amu.academia.edu/MarcinFrankowski","photo":"https://0.academia-photos.com/36962588/10534304/11756240/s65_marcin.frankowski.jpg"}</script></span></span></li><li class="js-paper-rank-work_17291906 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="17291906"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 17291906, container: ".js-paper-rank-work_17291906", }); 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The IR spectra calculated using the density-fuctional theoretical method are... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_17291910" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Azidoacetonitrile (N 3 CH 2 CN) and azidoacetone (N 3 CH 2 COCH 3 ) are studied by matrix-isolation FTIR spectroscopy in solid neon, argon, and nitrogen. The IR spectra calculated using the density-fuctional theoretical method are discussed in comparison with the experimental data. Significant broadening of the recorded azide bands indicate an awkward fit of these compounds into the solid environment. The strongest absorption is observed for both compounds in the regions of asymmetric and symmetric stretches of the N 3 azide group. Strong band splittings in the N 3 asymmetric stretch region can be most likely explained by very strong Fermi resonances with the CN stretch and combinations and overtones of the numerous lowerfrequency vibrational modes.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/17291910" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="f2b430a08a9b5191990797b5b3a9c83e" rel="nofollow" data-download="{"attachment_id":39432179,"asset_id":17291910,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/39432179/download_file?st=MTc0MDE2MTYzMiw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="36962588" href="https://amu.academia.edu/MarcinFrankowski">Marcin Frankowski</a><script data-card-contents-for-user="36962588" type="text/json">{"id":36962588,"first_name":"Marcin","last_name":"Frankowski","domain_name":"amu","page_name":"MarcinFrankowski","display_name":"Marcin Frankowski","profile_url":"https://amu.academia.edu/MarcinFrankowski","photo":"https://0.academia-photos.com/36962588/10534304/11756240/s65_marcin.frankowski.jpg"}</script></span></span></li><li class="js-paper-rank-work_17291910 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="17291910"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 17291910, container: ".js-paper-rank-work_17291910", }); 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href="https://www.academia.edu/17291912/Speciation_of_aluminium_fluoride_complexes_and_Al3_in_soils_from_the_vicinity_of_an_aluminium_smelter_plant_by_hyphenated_High_Performance_Ion_Chromatography_Flame_Atomic_Absorption_Spectrometry_technique">Speciation of aluminium fluoride complexes and Al3+ in soils from the vicinity of an aluminium smelter plant by hyphenated High Performance Ion Chromatography Flame Atomic Absorption Spectrometry technique</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The paper presents a new tool for the determination of inorganic speciation forms of aluminium: AlF n (3 − n)+ , and Al 3+ by means of the HPIC-FAAS. The proposed method has been successfully used for speciation analysis (qualitative and... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_17291912" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The paper presents a new tool for the determination of inorganic speciation forms of aluminium: AlF n (3 − n)+ , and Al 3+ by means of the HPIC-FAAS. The proposed method has been successfully used for speciation analysis (qualitative and quantitative) of inorganic aluminium forms AlF n (3 − n)+ in soil samples. In order to isolate the most environmentally available fraction, 5 g of the sample was collected and extracted in deionised water (water soluble fraction) for 1 h using a magnetic stirrer. The determinations in a hyphenated technique system were performed for a number of prepared water extracts. Concentration determinations of particular aluminium forms were performed based on model studies and real samples. The separation of Al species with nominal charge of + 1, + 2, and + 3 required a run time of less than 4 min during a single analysis. Based on the analysis of water extracts of soil, it was obtained that aluminium forms elute in the following order: 1PA (first signal) -AlF 2 + and/or AlF 4 − ; 2PA (second signal) -AlF 2+ and/or AlF 3 0 ; 3PA (third signal) -Al 3+ . In order to confirm the occurrence of these forms a simulation using the Mineql program was conducted. The details of speciation analysis of aluminium fluoride forms by means of an HPIC-FAAS instrument equipped are presented. Interpretation of the speciation analysis of the water soluble fraction of soil samples is proposed, based on the separation during chromatographic run and calculated data by Mineql.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/17291912" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="361f0f33133f1c50a9464123ad7fe6f0" rel="nofollow" data-download="{"attachment_id":39432163,"asset_id":17291912,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/39432163/download_file?st=MTc0MDE2MTYzMiw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="36962588" href="https://amu.academia.edu/MarcinFrankowski">Marcin Frankowski</a><script data-card-contents-for-user="36962588" type="text/json">{"id":36962588,"first_name":"Marcin","last_name":"Frankowski","domain_name":"amu","page_name":"MarcinFrankowski","display_name":"Marcin Frankowski","profile_url":"https://amu.academia.edu/MarcinFrankowski","photo":"https://0.academia-photos.com/36962588/10534304/11756240/s65_marcin.frankowski.jpg"}</script></span></span></li><li class="js-paper-rank-work_17291912 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="17291912"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 17291912, container: ".js-paper-rank-work_17291912", }); 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The proposed method has been successfully used for speciation analysis (qualitative and quantitative) of inorganic aluminium forms AlF n (3 − n)+ in soil samples. In order to isolate the most environmentally available fraction, 5 g of the sample was collected and extracted in deionised water (water soluble fraction) for 1 h using a magnetic stirrer. The determinations in a hyphenated technique system were performed for a number of prepared water extracts. Concentration determinations of particular aluminium forms were performed based on model studies and real samples. The separation of Al species with nominal charge of + 1, + 2, and + 3 required a run time of less than 4 min during a single analysis. Based on the analysis of water extracts of soil, it was obtained that aluminium forms elute in the following order: 1PA (first signal) -AlF 2 + and/or AlF 4 − ; 2PA (second signal) -AlF 2+ and/or AlF 3 0 ; 3PA (third signal) -Al 3+ . In order to confirm the occurrence of these forms a simulation using the Mineql program was conducted. The details of speciation analysis of aluminium fluoride forms by means of an HPIC-FAAS instrument equipped are presented. Interpretation of the speciation analysis of the water soluble fraction of soil samples is proposed, based on the separation during chromatographic run and calculated data by Mineql.","publication":"Microchemical Journal","publication_with_fallback":"Microchemical 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Studies","downloadable_attachments":[{"id":39432183,"asset_id":17291913,"asset_type":"Work","always_allow_download":false,"scribd_thumbnail_url":"https://attachments.academia-assets.com/39432183/thumbnails/1.jpg","download_url":"https://d1wqtxts1xzle7.cloudfront.net/39432183/Distribution_of_heavy_metals_in_the_Maa_20151026-6021-chu5mi-libre.pdf?1445893781=\u0026response-content-disposition=attachment%3B+filename%3DDistribution_of_heavy_metals_in_the_Mala.pdf\u0026Expires=1732944730\u0026Signature=ICig0RAloLruimFRo-Iovedr2OuYf5vPsCWwkTA33fX0fQzOwUy9b-j34qjfxpMyibRwBxbeKJNqyscuVn~gg3A6AHrV1MW2EKo1GuwsMgDqjMFjz-syf0OMTqlL05jWQQhZ4QM-BExLjkWiCpsW7L6XpLaj4I5Sp-70A6RRLKgmj7DkCxyWmm90Bch1fZfwTeArTJjLqlz8A~V9oso2aQoAQqkRm1OCqGNrrQxqLXOkbl-DnEYxUBu6tdcfdIIFV8fIbJFgrLSE0cWAnZtqosC~gspDSCzr78R~yTxx2u3iokvqc4w-xsCMysqtA0k4etHyGa0Ct4-I0wNWkwahTA__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA","download_file_url":"https://www.academia.edu/attachments/39432183/download_file?st=MTc0MDE2MTYzMiw4LjIyMi4yMDguMTQ2&","full_thumbnail_url":"https://0.academia-photos.com/attachment_thumbnails/39432183/mini_magick20190222-9675-izkyrm.png?1550900973"}],"downloadable_attachments_with_full_thumbnails":[{"id":39432183,"asset_id":17291913,"asset_type":"Work","always_allow_download":false,"scribd_thumbnail_url":"https://attachments.academia-assets.com/39432183/thumbnails/1.jpg","download_url":"https://d1wqtxts1xzle7.cloudfront.net/39432183/Distribution_of_heavy_metals_in_the_Maa_20151026-6021-chu5mi-libre.pdf?1445893781=\u0026response-content-disposition=attachment%3B+filename%3DDistribution_of_heavy_metals_in_the_Mala.pdf\u0026Expires=1732944730\u0026Signature=ICig0RAloLruimFRo-Iovedr2OuYf5vPsCWwkTA33fX0fQzOwUy9b-j34qjfxpMyibRwBxbeKJNqyscuVn~gg3A6AHrV1MW2EKo1GuwsMgDqjMFjz-syf0OMTqlL05jWQQhZ4QM-BExLjkWiCpsW7L6XpLaj4I5Sp-70A6RRLKgmj7DkCxyWmm90Bch1fZfwTeArTJjLqlz8A~V9oso2aQoAQqkRm1OCqGNrrQxqLXOkbl-DnEYxUBu6tdcfdIIFV8fIbJFgrLSE0cWAnZtqosC~gspDSCzr78R~yTxx2u3iokvqc4w-xsCMysqtA0k4etHyGa0Ct4-I0wNWkwahTA__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA","download_file_url":"https://www.academia.edu/attachments/39432183/download_file?st=MTc0MDE2MTYzMiw4LjIyMi4yMDguMTQ2&","full_thumbnail_url":"https://0.academia-photos.com/attachment_thumbnails/39432183/mini_magick20190222-9675-izkyrm.png?1550900973"}],"has_pdf":true,"has_fulltext":true,"page_count":11,"ordered_authors":[{"id":36962588,"first_name":"Marcin","last_name":"Frankowski","domain_name":"amu","page_name":"MarcinFrankowski","display_name":"Marcin Frankowski","profile_url":"https://amu.academia.edu/MarcinFrankowski","photo":"https://0.academia-photos.com/36962588/10534304/11756240/s65_marcin.frankowski.jpg"}],"research_interests":[{"id":9846,"name":"Ecology","url":"https://www.academia.edu/Documents/in/Ecology","nofollow":true}],"publication_year":2000,"publication_year_with_fallback":2000,"paper_rank":null,"all_time_views":30,"active_discussion":{}}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_17291914" data-work_id="17291914" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/17291914/Microflow_Cytometers_with_Integrated_Hydrodynamic_Focusing">Microflow Cytometers with Integrated Hydrodynamic Focusing</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">This study demonstrates the suitability of microfluidic structures for high throughput blood cell analysis. The microfluidic chips exploit fully integrated hydrodynamic focusing based on two different concepts: Two-stage cascade focusing... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_17291914" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">This study demonstrates the suitability of microfluidic structures for high throughput blood cell analysis. The microfluidic chips exploit fully integrated hydrodynamic focusing based on two different concepts: Two-stage cascade focusing and spin focusing (vortex) principle. The sample-A suspension of micro particles or blood cells-is injected into a sheath fluid streaming at a substantially higher flow rate, which assures positioning of the particles in the center of the flow channel. Particle velocities of a few m/s are achieved as required for high throughput blood cell analysis. The stability of hydrodynamic particle positioning was evaluated by measuring the pulse heights distributions of fluorescence signals from calibration beads. Quantitative assessment based on coefficient of variation for the fluorescence intensity distributions resulted in a value of about 3% determined for the micro-device exploiting cascade hydrodynamic focusing. For the spin focusing approach similar values were achieved for sample flow rates being 1.5 times lower. Our results indicate that the performances of both variants of hydrodynamic focusing suit for blood cell differentiation and counting. The potential of the micro flow cytometer is demonstrated by detecting immunologically labeled CD3 positive and CD4 positive T-lymphocytes in blood.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/17291914" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="4df06b7d80b7e419958dba071967e562" rel="nofollow" data-download="{"attachment_id":39432170,"asset_id":17291914,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/39432170/download_file?st=MTc0MDE2MTYzMiw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="36962588" href="https://amu.academia.edu/MarcinFrankowski">Marcin Frankowski</a><script data-card-contents-for-user="36962588" type="text/json">{"id":36962588,"first_name":"Marcin","last_name":"Frankowski","domain_name":"amu","page_name":"MarcinFrankowski","display_name":"Marcin Frankowski","profile_url":"https://amu.academia.edu/MarcinFrankowski","photo":"https://0.academia-photos.com/36962588/10534304/11756240/s65_marcin.frankowski.jpg"}</script></span></span></li><li class="js-paper-rank-work_17291914 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="17291914"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 17291914, container: ".js-paper-rank-work_17291914", }); });</script></li><li class="js-percentile-work_17291914 InlineList-item InlineList-item--bordered hidden u-tcGrayDark"><span class="percentile-widget hidden"><span class="u-mr2x percentile-widget" style="display: none">•</span><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 17291914; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-percentile-work_17291914"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></li><li class="js-view-count-work_17291914 InlineList-item InlineList-item--bordered hidden"><div><span><span class="js-view-count view-count u-mr2x" data-work-id="17291914"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 17291914; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=17291914]").text(description); $(".js-view-count-work_17291914").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_17291914").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="17291914"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">12</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="524" rel="nofollow" href="https://www.academia.edu/Documents/in/Analytical_Chemistry">Analytical Chemistry</a>, <script data-card-contents-for-ri="524" type="text/json">{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="2721" rel="nofollow" href="https://www.academia.edu/Documents/in/Microfluidics">Microfluidics</a>, <script data-card-contents-for-ri="2721" type="text/json">{"id":2721,"name":"Microfluidics","url":"https://www.academia.edu/Documents/in/Microfluidics","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="6599" rel="nofollow" href="https://www.academia.edu/Documents/in/Flow_Cytometry">Flow Cytometry</a>, <script data-card-contents-for-ri="6599" type="text/json">{"id":6599,"name":"Flow Cytometry","url":"https://www.academia.edu/Documents/in/Flow_Cytometry","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="7598" rel="nofollow" href="https://www.academia.edu/Documents/in/Rheology">Rheology</a><script data-card-contents-for-ri="7598" type="text/json">{"id":7598,"name":"Rheology","url":"https://www.academia.edu/Documents/in/Rheology","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=17291914]'), work: {"id":17291914,"title":"Microflow Cytometers with Integrated Hydrodynamic Focusing","created_at":"2015-10-25T23:23:23.908-07:00","owner_id":36962588,"url":"https://www.academia.edu/17291914/Microflow_Cytometers_with_Integrated_Hydrodynamic_Focusing","slug":"Microflow_Cytometers_with_Integrated_Hydrodynamic_Focusing","dom_id":"work_17291914","summary":"This study demonstrates the suitability of microfluidic structures for high throughput blood cell analysis. The microfluidic chips exploit fully integrated hydrodynamic focusing based on two different concepts: Two-stage cascade focusing and spin focusing (vortex) principle. The sample-A suspension of micro particles or blood cells-is injected into a sheath fluid streaming at a substantially higher flow rate, which assures positioning of the particles in the center of the flow channel. Particle velocities of a few m/s are achieved as required for high throughput blood cell analysis. The stability of hydrodynamic particle positioning was evaluated by measuring the pulse heights distributions of fluorescence signals from calibration beads. Quantitative assessment based on coefficient of variation for the fluorescence intensity distributions resulted in a value of about 3% determined for the micro-device exploiting cascade hydrodynamic focusing. For the spin focusing approach similar values were achieved for sample flow rates being 1.5 times lower. Our results indicate that the performances of both variants of hydrodynamic focusing suit for blood cell differentiation and counting. The potential of the micro flow cytometer is demonstrated by detecting immunologically labeled CD3 positive and CD4 positive T-lymphocytes in blood.","publication":"Sensors","publication_with_fallback":"Sensors","downloadable_attachments":[{"id":39432170,"asset_id":17291914,"asset_type":"Work","always_allow_download":false,"scribd_thumbnail_url":"https://attachments.academia-assets.com/39432170/thumbnails/1.jpg","download_url":"https://d1wqtxts1xzle7.cloudfront.net/39432170/Microflow_Cytometers_with_Integrated_Hyd20151026-6029-cf9tc6-libre.pdf?1445893784=\u0026response-content-disposition=attachment%3B+filename%3DMicroflow_Cytometers_with_Integrated_Hyd.pdf\u0026Expires=1740115693\u0026Signature=dx1qC9knRCg8e6WLuCGLpVSMf0CExNkpdeS7dcDdmf~z4yU8Biyh8yftY6hHemS4q90YbPwqKe0bOoOZalrScYeaHXa5Jl~F2oR5LiId~Ey06-1Fy-kQE6WLpwGyuEj0E8yyVHWMwBdeljzw8icv6Q7FhV9BrHqiGXi1vNBrdv7IdO7G0hAijBLfgCeaGiSIQVaaJ8X2VSfO0BJ6KH77xYoXdqyaQMz5xb2j-RrIyTengWEtWR2KYy8cyXJ41Xsg9s~VOF~rlQtoOFypEmK4jP7JGPPshouh9Rf~HWGu6QuY4DPcA91GaYs5cKIxL8v9ZnSRC0038yXPjfMxn0MfOQ__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA","download_file_url":"https://www.academia.edu/attachments/39432170/download_file?st=MTc0MDE2MTYzMiw4LjIyMi4yMDguMTQ2&","full_thumbnail_url":"https://0.academia-photos.com/attachment_thumbnails/39432170/mini_magick20190222-22904-10fxhh6.png?1550900936"}],"downloadable_attachments_with_full_thumbnails":[{"id":39432170,"asset_id":17291914,"asset_type":"Work","always_allow_download":false,"scribd_thumbnail_url":"https://attachments.academia-assets.com/39432170/thumbnails/1.jpg","download_url":"https://d1wqtxts1xzle7.cloudfront.net/39432170/Microflow_Cytometers_with_Integrated_Hyd20151026-6029-cf9tc6-libre.pdf?1445893784=\u0026response-content-disposition=attachment%3B+filename%3DMicroflow_Cytometers_with_Integrated_Hyd.pdf\u0026Expires=1740115693\u0026Signature=dx1qC9knRCg8e6WLuCGLpVSMf0CExNkpdeS7dcDdmf~z4yU8Biyh8yftY6hHemS4q90YbPwqKe0bOoOZalrScYeaHXa5Jl~F2oR5LiId~Ey06-1Fy-kQE6WLpwGyuEj0E8yyVHWMwBdeljzw8icv6Q7FhV9BrHqiGXi1vNBrdv7IdO7G0hAijBLfgCeaGiSIQVaaJ8X2VSfO0BJ6KH77xYoXdqyaQMz5xb2j-RrIyTengWEtWR2KYy8cyXJ41Xsg9s~VOF~rlQtoOFypEmK4jP7JGPPshouh9Rf~HWGu6QuY4DPcA91GaYs5cKIxL8v9ZnSRC0038yXPjfMxn0MfOQ__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA","download_file_url":"https://www.academia.edu/attachments/39432170/download_file?st=MTc0MDE2MTYzMiw4LjIyMi4yMDguMTQ2&","full_thumbnail_url":"https://0.academia-photos.com/attachment_thumbnails/39432170/mini_magick20190222-22904-10fxhh6.png?1550900936"}],"has_pdf":true,"has_fulltext":true,"page_count":20,"ordered_authors":[{"id":36962588,"first_name":"Marcin","last_name":"Frankowski","domain_name":"amu","page_name":"MarcinFrankowski","display_name":"Marcin Frankowski","profile_url":"https://amu.academia.edu/MarcinFrankowski","photo":"https://0.academia-photos.com/36962588/10534304/11756240/s65_marcin.frankowski.jpg"}],"research_interests":[{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry","nofollow":true},{"id":2721,"name":"Microfluidics","url":"https://www.academia.edu/Documents/in/Microfluidics","nofollow":true},{"id":6599,"name":"Flow Cytometry","url":"https://www.academia.edu/Documents/in/Flow_Cytometry","nofollow":true},{"id":7598,"name":"Rheology","url":"https://www.academia.edu/Documents/in/Rheology","nofollow":true},{"id":7698,"name":"Fluorescence","url":"https://www.academia.edu/Documents/in/Fluorescence"},{"id":18529,"name":"Fluorescent Dyes and Reagents","url":"https://www.academia.edu/Documents/in/Fluorescent_Dyes_and_Reagents"},{"id":55405,"name":"Sensors","url":"https://www.academia.edu/Documents/in/Sensors"},{"id":96893,"name":"Calibration","url":"https://www.academia.edu/Documents/in/Calibration"},{"id":179332,"name":"Hydrodynamics","url":"https://www.academia.edu/Documents/in/Hydrodynamics"},{"id":1237788,"name":"Electrical And Electronic Engineering","url":"https://www.academia.edu/Documents/in/Electrical_And_Electronic_Engineering"},{"id":1311469,"name":"Blood cells","url":"https://www.academia.edu/Documents/in/Blood_cells"},{"id":1366954,"name":"Phycoerythrin","url":"https://www.academia.edu/Documents/in/Phycoerythrin"}],"publication_year":2013,"publication_year_with_fallback":2013,"paper_rank":null,"all_time_views":37,"active_discussion":{}}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_17291916" data-work_id="17291916" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/17291916/Relaxation_processes_induced_by_radiative_electronic_transitions_in_preirradiated_rare_gas_solids">Relaxation processes induced by radiative electronic transitions in preirradiated rare gas solids</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Energy relaxation processes in films grown from pure Ar gas and O 2 -Ar mixtures preliminary irradiated by an electron beam were studied with a focus on the role of radiative electronic transitions in the relaxation cascades. A... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_17291916" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Energy relaxation processes in films grown from pure Ar gas and O 2 -Ar mixtures preliminary irradiated by an electron beam were studied with a focus on the role of radiative electronic transitions in the relaxation cascades. A combination of luminescent spectroscopy methods (thermally stimulated luminescence (TSL) including spectrally resolved TSL and cathodoluminescence) with thermally stimulated exoelectron emission technique was used. New additional data were obtained in a favor of the radiative mechanism of electronic relaxation processes--electron detrapping and transport followed by exoelectron emission and charge recombination. Correlation in the electron and in the low temperature desorption yields is clearly demonstrated. Suppression of the desorption from oxygen-containing films was found in contrast to the effect observed under excitation.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/17291916" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="baedec51252cfc9b77a0fe56cf123ecf" rel="nofollow" data-download="{"attachment_id":39432164,"asset_id":17291916,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/39432164/download_file?st=MTc0MDE2MTYzMiw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="36962588" href="https://amu.academia.edu/MarcinFrankowski">Marcin Frankowski</a><script data-card-contents-for-user="36962588" type="text/json">{"id":36962588,"first_name":"Marcin","last_name":"Frankowski","domain_name":"amu","page_name":"MarcinFrankowski","display_name":"Marcin Frankowski","profile_url":"https://amu.academia.edu/MarcinFrankowski","photo":"https://0.academia-photos.com/36962588/10534304/11756240/s65_marcin.frankowski.jpg"}</script></span></span></li><li class="js-paper-rank-work_17291916 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="17291916"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 17291916, container: ".js-paper-rank-work_17291916", }); 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$(".js-view-count[data-work-id=17291916]").text(description); $(".js-view-count-work_17291916").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_17291916").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="17291916"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">6</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="505" rel="nofollow" href="https://www.academia.edu/Documents/in/Condensed_Matter_Physics">Condensed Matter Physics</a>, <script data-card-contents-for-ri="505" type="text/json">{"id":505,"name":"Condensed Matter Physics","url":"https://www.academia.edu/Documents/in/Condensed_Matter_Physics","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="518" rel="nofollow" href="https://www.academia.edu/Documents/in/Quantum_Physics">Quantum Physics</a>, <script data-card-contents-for-ri="518" type="text/json">{"id":518,"name":"Quantum Physics","url":"https://www.academia.edu/Documents/in/Quantum_Physics","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="2465" rel="nofollow" href="https://www.academia.edu/Documents/in/Surface_Science">Surface Science</a>, <script data-card-contents-for-ri="2465" type="text/json">{"id":2465,"name":"Surface Science","url":"https://www.academia.edu/Documents/in/Surface_Science","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="93366" rel="nofollow" href="https://www.academia.edu/Documents/in/Noble_Gases">Noble Gases</a><script data-card-contents-for-ri="93366" type="text/json">{"id":93366,"name":"Noble Gases","url":"https://www.academia.edu/Documents/in/Noble_Gases","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=17291916]'), work: {"id":17291916,"title":"Relaxation processes induced by radiative electronic transitions in preirradiated rare gas solids","created_at":"2015-10-25T23:23:24.066-07:00","owner_id":36962588,"url":"https://www.academia.edu/17291916/Relaxation_processes_induced_by_radiative_electronic_transitions_in_preirradiated_rare_gas_solids","slug":"Relaxation_processes_induced_by_radiative_electronic_transitions_in_preirradiated_rare_gas_solids","dom_id":"work_17291916","summary":"Energy relaxation processes in films grown from pure Ar gas and O 2 -Ar mixtures preliminary irradiated by an electron beam were studied with a focus on the role of radiative electronic transitions in the relaxation cascades. A combination of luminescent spectroscopy methods (thermally stimulated luminescence (TSL) including spectrally resolved TSL and cathodoluminescence) with thermally stimulated exoelectron emission technique was used. New additional data were obtained in a favor of the radiative mechanism of electronic relaxation processes--electron detrapping and transport followed by exoelectron emission and charge recombination. Correlation in the electron and in the low temperature desorption yields is clearly demonstrated. Suppression of the desorption from oxygen-containing films was found in contrast to the effect observed under excitation.","publication":"Surface Science","publication_with_fallback":"Surface Science","downloadable_attachments":[{"id":39432164,"asset_id":17291916,"asset_type":"Work","always_allow_download":false,"scribd_thumbnail_url":"https://attachments.academia-assets.com/39432164/thumbnails/1.jpg","download_url":"https://d1wqtxts1xzle7.cloudfront.net/39432164/s0039-6028_2802_2902643-2-libre.pdf20151026-6021-1t1ovpr?1445893783=\u0026response-content-disposition=attachment%3B+filename%3DRelaxation_processes_induced_by_radiativ.pdf\u0026Expires=1740115693\u0026Signature=EupCmA4rYjPrFakG4zkm1~BbMiOZ5d8UZlxqcESMHKQaT1JxkFBnk8QYIgFfnjBLGv-m8PAhYCpXzc0S5o8pgUQ1hAY5wopYstj4iLNPfroe5yefi~AcW1FaxXCkHGZAYUufEaHuROWaA49UdMHhvU0S2wgT2En0Vn7UfGpy~4xzscHeZhZrqX-McRkXzlCoiemdSz8gGpOvnr1ZKN0r2PvVqueX2RpMwJjsGQpyVSsHZsLio5ZFhynxSPRY65TLwlsodq-UdG9jlXNRDHlP9jdOb7FMnxVzPRBx-mDnKHDDNhopv8fvFnRu3vARrTbRNAAMyxCbjK80rAfN0dyAkw__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA","download_file_url":"https://www.academia.edu/attachments/39432164/download_file?st=MTc0MDE2MTYzMiw4LjIyMi4yMDguMTQ2&","full_thumbnail_url":"https://0.academia-photos.com/attachment_thumbnails/39432164/mini_magick20190222-10432-sb7p9g.png?1550900934"}],"downloadable_attachments_with_full_thumbnails":[{"id":39432164,"asset_id":17291916,"asset_type":"Work","always_allow_download":false,"scribd_thumbnail_url":"https://attachments.academia-assets.com/39432164/thumbnails/1.jpg","download_url":"https://d1wqtxts1xzle7.cloudfront.net/39432164/s0039-6028_2802_2902643-2-libre.pdf20151026-6021-1t1ovpr?1445893783=\u0026response-content-disposition=attachment%3B+filename%3DRelaxation_processes_induced_by_radiativ.pdf\u0026Expires=1740115693\u0026Signature=EupCmA4rYjPrFakG4zkm1~BbMiOZ5d8UZlxqcESMHKQaT1JxkFBnk8QYIgFfnjBLGv-m8PAhYCpXzc0S5o8pgUQ1hAY5wopYstj4iLNPfroe5yefi~AcW1FaxXCkHGZAYUufEaHuROWaA49UdMHhvU0S2wgT2En0Vn7UfGpy~4xzscHeZhZrqX-McRkXzlCoiemdSz8gGpOvnr1ZKN0r2PvVqueX2RpMwJjsGQpyVSsHZsLio5ZFhynxSPRY65TLwlsodq-UdG9jlXNRDHlP9jdOb7FMnxVzPRBx-mDnKHDDNhopv8fvFnRu3vARrTbRNAAMyxCbjK80rAfN0dyAkw__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA","download_file_url":"https://www.academia.edu/attachments/39432164/download_file?st=MTc0MDE2MTYzMiw4LjIyMi4yMDguMTQ2&","full_thumbnail_url":"https://0.academia-photos.com/attachment_thumbnails/39432164/mini_magick20190222-10432-sb7p9g.png?1550900934"}],"has_pdf":true,"has_fulltext":true,"page_count":7,"ordered_authors":[{"id":36962588,"first_name":"Marcin","last_name":"Frankowski","domain_name":"amu","page_name":"MarcinFrankowski","display_name":"Marcin Frankowski","profile_url":"https://amu.academia.edu/MarcinFrankowski","photo":"https://0.academia-photos.com/36962588/10534304/11756240/s65_marcin.frankowski.jpg"}],"research_interests":[{"id":505,"name":"Condensed Matter Physics","url":"https://www.academia.edu/Documents/in/Condensed_Matter_Physics","nofollow":true},{"id":518,"name":"Quantum Physics","url":"https://www.academia.edu/Documents/in/Quantum_Physics","nofollow":true},{"id":2465,"name":"Surface Science","url":"https://www.academia.edu/Documents/in/Surface_Science","nofollow":true},{"id":93366,"name":"Noble Gases","url":"https://www.academia.edu/Documents/in/Noble_Gases","nofollow":true},{"id":616972,"name":"Low Temperature","url":"https://www.academia.edu/Documents/in/Low_Temperature"},{"id":920313,"name":"Electron Beam","url":"https://www.academia.edu/Documents/in/Electron_Beam"}],"publication_year":2003,"publication_year_with_fallback":2003,"paper_rank":null,"all_time_views":12,"active_discussion":{}}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_17291918" data-work_id="17291918" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/17291918/Development_of_a_new_analytical_method_for_online_simultaneous_qualitative_determination_of_aluminium_free_aluminium_ion_aluminium_fluoride_complexes_by_HPLC_FAAS">Development of a new analytical method for online simultaneous qualitative determination of aluminium (free aluminium ion, aluminium-fluoride complexes) by HPLC-FAAS</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The paper presents a novel method for simultaneous online examination of inorganic forms of aluminium: AlF(2)(+), AlF(2+,) and Al(3+) by means of the high performance liquid chromatography hyphenated with a detection by the atomic... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_17291918" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The paper presents a novel method for simultaneous online examination of inorganic forms of aluminium: AlF(2)(+), AlF(2+,) and Al(3+) by means of the high performance liquid chromatography hyphenated with a detection by the atomic absorption spectrometry with flame atomization (HPLC-FAAS) without post-column reaction. The application of optimization procedure conditions of chromatographic separation of inorganic forms of aluminium was achieved by the analytical column IonPac CS5A (Dionex) with guard column IonPac CG5A (Dionex) and an aqueous ammonium chloride mobile phase, at pH about 3 with gradient elution. The separation of Al forms with nominal charge of 1+, 2+, 3+ required a run time of less than 8 min during a single analysis. The proposed method has been successfully used for the examination of aluminium forms formation AlF(n)((3-n)+) in environmental samples.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/17291918" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="a290331d9d708ebd9a99c07193c40b34" rel="nofollow" data-download="{"attachment_id":42271926,"asset_id":17291918,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/42271926/download_file?st=MTc0MDE2MTYzMyw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="36962588" href="https://amu.academia.edu/MarcinFrankowski">Marcin Frankowski</a><script data-card-contents-for-user="36962588" type="text/json">{"id":36962588,"first_name":"Marcin","last_name":"Frankowski","domain_name":"amu","page_name":"MarcinFrankowski","display_name":"Marcin Frankowski","profile_url":"https://amu.academia.edu/MarcinFrankowski","photo":"https://0.academia-photos.com/36962588/10534304/11756240/s65_marcin.frankowski.jpg"}</script></span></span></li><li class="js-paper-rank-work_17291918 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="17291918"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 17291918, container: ".js-paper-rank-work_17291918", }); 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$(".js-view-count[data-work-id=17291918]").text(description); $(".js-view-count-work_17291918").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_17291918").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="17291918"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">5</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="524" rel="nofollow" href="https://www.academia.edu/Documents/in/Analytical_Chemistry">Analytical Chemistry</a>, <script data-card-contents-for-ri="524" type="text/json">{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="55258" rel="nofollow" href="https://www.academia.edu/Documents/in/Aluminum">Aluminum</a>, <script data-card-contents-for-ri="55258" type="text/json">{"id":55258,"name":"Aluminum","url":"https://www.academia.edu/Documents/in/Aluminum","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="146936" rel="nofollow" href="https://www.academia.edu/Documents/in/Fluorides">Fluorides</a>, <script data-card-contents-for-ri="146936" type="text/json">{"id":146936,"name":"Fluorides","url":"https://www.academia.edu/Documents/in/Fluorides","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="246560" rel="nofollow" href="https://www.academia.edu/Documents/in/High_Pressure_Liquid_Chromatography">High Pressure Liquid Chromatography</a><script data-card-contents-for-ri="246560" type="text/json">{"id":246560,"name":"High Pressure Liquid Chromatography","url":"https://www.academia.edu/Documents/in/High_Pressure_Liquid_Chromatography","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=17291918]'), work: {"id":17291918,"title":"Development of a new analytical method for online simultaneous qualitative determination of aluminium (free aluminium ion, aluminium-fluoride complexes) by HPLC-FAAS","created_at":"2015-10-25T23:23:24.225-07:00","owner_id":36962588,"url":"https://www.academia.edu/17291918/Development_of_a_new_analytical_method_for_online_simultaneous_qualitative_determination_of_aluminium_free_aluminium_ion_aluminium_fluoride_complexes_by_HPLC_FAAS","slug":"Development_of_a_new_analytical_method_for_online_simultaneous_qualitative_determination_of_aluminium_free_aluminium_ion_aluminium_fluoride_complexes_by_HPLC_FAAS","dom_id":"work_17291918","summary":"The paper presents a novel method for simultaneous online examination of inorganic forms of aluminium: AlF(2)(+), AlF(2+,) and Al(3+) by means of the high performance liquid chromatography hyphenated with a detection by the atomic absorption spectrometry with flame atomization (HPLC-FAAS) without post-column reaction. The application of optimization procedure conditions of chromatographic separation of inorganic forms of aluminium was achieved by the analytical column IonPac CS5A (Dionex) with guard column IonPac CG5A (Dionex) and an aqueous ammonium chloride mobile phase, at pH about 3 with gradient elution. The separation of Al forms with nominal charge of 1+, 2+, 3+ required a run time of less than 8 min during a single analysis. The proposed method has been successfully used for the examination of aluminium forms formation AlF(n)((3-n)+) in environmental samples.","publication":"Talanta","publication_with_fallback":"Talanta","downloadable_attachments":[{"id":42271926,"asset_id":17291918,"asset_type":"Work","always_allow_download":false,"scribd_thumbnail_url":"https://attachments.academia-assets.com/42271926/thumbnails/1.jpg","download_url":"https://d1wqtxts1xzle7.cloudfront.net/42271926/j.talanta.2008.12.028-libre.pdf20160207-19345-a8ag6m?1454834431=\u0026response-content-disposition=attachment%3B+filename%3DDevelopment_of_a_new_analytical_method_f.pdf\u0026Expires=1739926737\u0026Signature=LX32LNhgC0T7g2uupXbHrqGwq23hIT6QPRMGUZ7Gi6OgS1~0ggaLePyFajqV3HnR0MjJIb3pAE17THRLETDq3kToVsvIlnYXyjqCBorwtcAk4VK0EknX93S2kArUR3qSb-mKBYbDkkAjWkZRFjPtNZNWbb8jU6XkyrYKpNorkeNTMR916F-nI9c9bIlf68MGSpV50a8GJVlc7MlrhPB5XTSWs6pv88Wxmw3daHrH73Hf7vNL5M5VAtj5etcx3M9L3ZPtxa2yJViFlAFf8yte4GTMNHLiwuQHNmEqwBQNs1ljd1SX3NlmExe9UOhH7ur~86fLw-Z8lz2YVIC~FuLIWw__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA","download_file_url":"https://www.academia.edu/attachments/42271926/download_file?st=MTc0MDE2MTYzMyw4LjIyMi4yMDguMTQ2&","full_thumbnail_url":"https://0.academia-photos.com/attachment_thumbnails/42271926/mini_magick20190217-5560-s02prn.png?1550471801"}],"downloadable_attachments_with_full_thumbnails":[{"id":42271926,"asset_id":17291918,"asset_type":"Work","always_allow_download":false,"scribd_thumbnail_url":"https://attachments.academia-assets.com/42271926/thumbnails/1.jpg","download_url":"https://d1wqtxts1xzle7.cloudfront.net/42271926/j.talanta.2008.12.028-libre.pdf20160207-19345-a8ag6m?1454834431=\u0026response-content-disposition=attachment%3B+filename%3DDevelopment_of_a_new_analytical_method_f.pdf\u0026Expires=1739926737\u0026Signature=LX32LNhgC0T7g2uupXbHrqGwq23hIT6QPRMGUZ7Gi6OgS1~0ggaLePyFajqV3HnR0MjJIb3pAE17THRLETDq3kToVsvIlnYXyjqCBorwtcAk4VK0EknX93S2kArUR3qSb-mKBYbDkkAjWkZRFjPtNZNWbb8jU6XkyrYKpNorkeNTMR916F-nI9c9bIlf68MGSpV50a8GJVlc7MlrhPB5XTSWs6pv88Wxmw3daHrH73Hf7vNL5M5VAtj5etcx3M9L3ZPtxa2yJViFlAFf8yte4GTMNHLiwuQHNmEqwBQNs1ljd1SX3NlmExe9UOhH7ur~86fLw-Z8lz2YVIC~FuLIWw__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA","download_file_url":"https://www.academia.edu/attachments/42271926/download_file?st=MTc0MDE2MTYzMyw4LjIyMi4yMDguMTQ2&","full_thumbnail_url":"https://0.academia-photos.com/attachment_thumbnails/42271926/mini_magick20190217-5560-s02prn.png?1550471801"}],"has_pdf":true,"has_fulltext":true,"page_count":8,"ordered_authors":[{"id":36962588,"first_name":"Marcin","last_name":"Frankowski","domain_name":"amu","page_name":"MarcinFrankowski","display_name":"Marcin Frankowski","profile_url":"https://amu.academia.edu/MarcinFrankowski","photo":"https://0.academia-photos.com/36962588/10534304/11756240/s65_marcin.frankowski.jpg"}],"research_interests":[{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry","nofollow":true},{"id":55258,"name":"Aluminum","url":"https://www.academia.edu/Documents/in/Aluminum","nofollow":true},{"id":146936,"name":"Fluorides","url":"https://www.academia.edu/Documents/in/Fluorides","nofollow":true},{"id":246560,"name":"High Pressure Liquid Chromatography","url":"https://www.academia.edu/Documents/in/High_Pressure_Liquid_Chromatography","nofollow":true},{"id":736321,"name":"Environmental Pollutants","url":"https://www.academia.edu/Documents/in/Environmental_Pollutants"}],"publication_year":2009,"publication_year_with_fallback":2009,"paper_rank":null,"all_time_views":47,"active_discussion":{}}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_17291924" data-work_id="17291924" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/17291924/Atomic_absorption_spectrometry_analysis_of_trace_elements_in_degenerated_intervertebral_disc_tissue">Atomic absorption spectrometry analysis of trace elements in degenerated intervertebral disc tissue</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Few studies have investigated trace elements (TE) in human intervertebral disc (IVD) tissue. Trace element presence can have diverse meanings: essential TE show the metabolic modalities of the tissue, while environmentally-related TE... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_17291924" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Few studies have investigated trace elements (TE) in human intervertebral disc (IVD) tissue. Trace element presence can have diverse meanings: essential TE show the metabolic modalities of the tissue, while environmentally-related TE indicate pollution and tissue-specific absorption and accumulation. IVD is a highly specific compartment with impaired communication with adjacent bone. Analysis of TE in IVD provides new insights regarding tissue metabolism and IVD communication with other tissues. Thirty intervertebral discs were acquired from 22 patients during surgical treatment for degenerative disease. Atomic absorption spectrometry was used to evaluate the concentrations of Al, Cd, Pb, Cu, Ni, Mo, Mg, and Zn. Al, Pb, Cu, Mg, and Zn were detected in all samples. Pb was significantly positively correlated with age, and Ni concentration was weakly correlated with population count in the patient&#39;s place of residence. Only Cu was observed in higher concentrations in IVD compared t...</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/17291924" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="4ad48b923f55eb879c6d342bd7f7e7eb" rel="nofollow" data-download="{"attachment_id":39432200,"asset_id":17291924,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/39432200/download_file?st=MTc0MDE2MTYzMyw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="36962588" href="https://amu.academia.edu/MarcinFrankowski">Marcin Frankowski</a><script data-card-contents-for-user="36962588" type="text/json">{"id":36962588,"first_name":"Marcin","last_name":"Frankowski","domain_name":"amu","page_name":"MarcinFrankowski","display_name":"Marcin Frankowski","profile_url":"https://amu.academia.edu/MarcinFrankowski","photo":"https://0.academia-photos.com/36962588/10534304/11756240/s65_marcin.frankowski.jpg"}</script></span></span></li><li class="js-paper-rank-work_17291924 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="17291924"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 17291924, container: ".js-paper-rank-work_17291924", }); 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$(".js-view-count[data-work-id=17291924]").text(description); $(".js-view-count-work_17291924").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_17291924").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="17291924"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">4</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="3243" rel="nofollow" href="https://www.academia.edu/Documents/in/Nonparametric_Statistics">Nonparametric Statistics</a>, <script data-card-contents-for-ri="3243" type="text/json">{"id":3243,"name":"Nonparametric Statistics","url":"https://www.academia.edu/Documents/in/Nonparametric_Statistics","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="193017" rel="nofollow" href="https://www.academia.edu/Documents/in/Intervertebral_disc_degeneration">Intervertebral disc degeneration</a>, <script data-card-contents-for-ri="193017" type="text/json">{"id":193017,"name":"Intervertebral disc degeneration","url":"https://www.academia.edu/Documents/in/Intervertebral_disc_degeneration","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="224577" rel="nofollow" href="https://www.academia.edu/Documents/in/Trace_Elements">Trace Elements</a>, <script data-card-contents-for-ri="224577" type="text/json">{"id":224577,"name":"Trace Elements","url":"https://www.academia.edu/Documents/in/Trace_Elements","nofollow":true}</script><a class="InlineList-item-text" data-has-card-for-ri="546419" rel="nofollow" href="https://www.academia.edu/Documents/in/Age_Factors">Age Factors</a><script data-card-contents-for-ri="546419" type="text/json">{"id":546419,"name":"Age Factors","url":"https://www.academia.edu/Documents/in/Age_Factors","nofollow":true}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=17291924]'), work: {"id":17291924,"title":"Atomic absorption spectrometry analysis of trace elements in degenerated intervertebral disc tissue","created_at":"2015-10-25T23:23:24.714-07:00","owner_id":36962588,"url":"https://www.academia.edu/17291924/Atomic_absorption_spectrometry_analysis_of_trace_elements_in_degenerated_intervertebral_disc_tissue","slug":"Atomic_absorption_spectrometry_analysis_of_trace_elements_in_degenerated_intervertebral_disc_tissue","dom_id":"work_17291924","summary":"Few studies have investigated trace elements (TE) in human intervertebral disc (IVD) tissue. Trace element presence can have diverse meanings: essential TE show the metabolic modalities of the tissue, while environmentally-related TE indicate pollution and tissue-specific absorption and accumulation. IVD is a highly specific compartment with impaired communication with adjacent bone. Analysis of TE in IVD provides new insights regarding tissue metabolism and IVD communication with other tissues. Thirty intervertebral discs were acquired from 22 patients during surgical treatment for degenerative disease. Atomic absorption spectrometry was used to evaluate the concentrations of Al, Cd, Pb, Cu, Ni, Mo, Mg, and Zn. Al, Pb, Cu, Mg, and Zn were detected in all samples. Pb was significantly positively correlated with age, and Ni concentration was weakly correlated with population count in the patient\u0026#39;s place of residence. Only Cu was observed in higher concentrations in IVD compared t...","publication":"Medical science monitor : international medical journal of experimental and clinical research","publication_with_fallback":"Medical science monitor : international medical journal of experimental and clinical research","downloadable_attachments":[{"id":39432200,"asset_id":17291924,"asset_type":"Work","always_allow_download":false,"scribd_thumbnail_url":"https://attachments.academia-assets.com/39432200/thumbnails/1.jpg","download_url":"https://d1wqtxts1xzle7.cloudfront.net/39432200/Atomic_Absorption_Spectrometry_Analysis_20151026-20747-fe66f2-libre.pdf?1445893773=\u0026response-content-disposition=attachment%3B+filename%3DAtomic_absorption_spectrometry_analysis.pdf\u0026Expires=1740165233\u0026Signature=Q7lj~NKfGGf7FVCwvfTsCXu1nhopbIwUsHDPozjch6MqZVA7CYcyFO5ShYO5nwz5k6sZzrilmN6HubWtjOin220QBih7IXGT74JboCYSOIxaUrIKTys8pnwfuwru1CfTEG7O0sxeN5nsZtOZQ1bGJCpbZLgZNia-sp1f1u7WZ2yZGUXNwjwZ~zYSNmFRC5Lpt9SoX1LMDtL3Qz4FA8WAB5g9uuMGb5gOP-6THLX~UqBwDBy2DwelSea~KjOxJ-KzpMdfT26xfMTu3gQ42tEkRzWhbWuj6zuj537UB1Rws3Gk-~E5BBpZ9ghCaJbMKYJR9bG0dnxtWvzLoJyWw5n0xA__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA","download_file_url":"https://www.academia.edu/attachments/39432200/download_file?st=MTc0MDE2MTYzMyw4LjIyMi4yMDguMTQ2&","full_thumbnail_url":"https://0.academia-photos.com/attachment_thumbnails/39432200/mini_magick20190222-28774-1h323n9.png?1550900944"}],"downloadable_attachments_with_full_thumbnails":[{"id":39432200,"asset_id":17291924,"asset_type":"Work","always_allow_download":false,"scribd_thumbnail_url":"https://attachments.academia-assets.com/39432200/thumbnails/1.jpg","download_url":"https://d1wqtxts1xzle7.cloudfront.net/39432200/Atomic_Absorption_Spectrometry_Analysis_20151026-20747-fe66f2-libre.pdf?1445893773=\u0026response-content-disposition=attachment%3B+filename%3DAtomic_absorption_spectrometry_analysis.pdf\u0026Expires=1740165233\u0026Signature=Q7lj~NKfGGf7FVCwvfTsCXu1nhopbIwUsHDPozjch6MqZVA7CYcyFO5ShYO5nwz5k6sZzrilmN6HubWtjOin220QBih7IXGT74JboCYSOIxaUrIKTys8pnwfuwru1CfTEG7O0sxeN5nsZtOZQ1bGJCpbZLgZNia-sp1f1u7WZ2yZGUXNwjwZ~zYSNmFRC5Lpt9SoX1LMDtL3Qz4FA8WAB5g9uuMGb5gOP-6THLX~UqBwDBy2DwelSea~KjOxJ-KzpMdfT26xfMTu3gQ42tEkRzWhbWuj6zuj537UB1Rws3Gk-~E5BBpZ9ghCaJbMKYJR9bG0dnxtWvzLoJyWw5n0xA__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA","download_file_url":"https://www.academia.edu/attachments/39432200/download_file?st=MTc0MDE2MTYzMyw4LjIyMi4yMDguMTQ2&","full_thumbnail_url":"https://0.academia-photos.com/attachment_thumbnails/39432200/mini_magick20190222-28774-1h323n9.png?1550900944"}],"has_pdf":true,"has_fulltext":true,"page_count":8,"ordered_authors":[{"id":36962588,"first_name":"Marcin","last_name":"Frankowski","domain_name":"amu","page_name":"MarcinFrankowski","display_name":"Marcin Frankowski","profile_url":"https://amu.academia.edu/MarcinFrankowski","photo":"https://0.academia-photos.com/36962588/10534304/11756240/s65_marcin.frankowski.jpg"}],"research_interests":[{"id":3243,"name":"Nonparametric Statistics","url":"https://www.academia.edu/Documents/in/Nonparametric_Statistics","nofollow":true},{"id":193017,"name":"Intervertebral disc degeneration","url":"https://www.academia.edu/Documents/in/Intervertebral_disc_degeneration","nofollow":true},{"id":224577,"name":"Trace Elements","url":"https://www.academia.edu/Documents/in/Trace_Elements","nofollow":true},{"id":546419,"name":"Age Factors","url":"https://www.academia.edu/Documents/in/Age_Factors","nofollow":true}],"publication_year":2014,"publication_year_with_fallback":2014,"paper_rank":null,"all_time_views":17,"active_discussion":{}}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_17291925" data-work_id="17291925" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/17291925/Analysis_of_trace_element_in_intervertebral_disc_by_Atomic_Absorption_Spectrometry_techniques_in_degenerative_disc_disease_in_the_Polish_population">Analysis of trace element in intervertebral disc by Atomic Absorption Spectrometry techniques in degenerative disc disease in the Polish population</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Objective. Although trace elements are regarded crucial and their content has been determined in number of tissue there are only few papers addressing this problem in intervertebral disc in humans. Most of the trace elements are important... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_17291925" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Objective. Although trace elements are regarded crucial and their content has been determined in number of tissue there are only few papers addressing this problem in intervertebral disc in humans. Most of the trace elements are important substrates of enzymes influencing metabolism and senescence process. Others are markers of environmental pollution. Therefore the aim of the research was to analyzed of the trace element content in the intervertebral disc, which may be a vital argument recognizing the background of degenerative changes to be the effect of the environment or metabolic factors. Materials and methods. Material consist of 18 intervertebral disc from 15 patients, acquired in surgical procedure of due to the degenerative disease with Atomic Absorption Spectrometry content of Al, Cd, Co, Pb, Cu, Ni, Mo, Mg, Zn was evaluated. Results. Only 4 of the trace elements were detected in all samples. The correlation analysis showed significant positive age correlation with Al and negative in case of Co. Among elements significant positive correlation was observed between Al/Pb, Co/Mo, Al/Mg, Al/Zn Pb/Zn and Mg/Zn. Negative correlation was observed in Al/Co, Cd/Mg, Co/Mg, Mo/Mg, Co/Zn and Mo/Zn. Conclusions. This study is the first to our knowledge that profiles the elements in intervertebral disc in patients with degenerative changes. We have confirmed significant differences between the trace element contents in intervertebral disc and other tissue. It can be ground for further investigation.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/17291925" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="8992d791abbee044418cedd6d86d56d3" rel="nofollow" data-download="{"attachment_id":39438970,"asset_id":17291925,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/39438970/download_file?st=MTc0MDE2MTYzMyw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="36962588" href="https://amu.academia.edu/MarcinFrankowski">Marcin Frankowski</a><script data-card-contents-for-user="36962588" type="text/json">{"id":36962588,"first_name":"Marcin","last_name":"Frankowski","domain_name":"amu","page_name":"MarcinFrankowski","display_name":"Marcin Frankowski","profile_url":"https://amu.academia.edu/MarcinFrankowski","photo":"https://0.academia-photos.com/36962588/10534304/11756240/s65_marcin.frankowski.jpg"}</script></span></span></li><li class="js-paper-rank-work_17291925 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="17291925"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 17291925, container: ".js-paper-rank-work_17291925", }); 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Although trace elements are regarded crucial and their content has been determined in number of tissue there are only few papers addressing this problem in intervertebral disc in humans. Most of the trace elements are important substrates of enzymes influencing metabolism and senescence process. Others are markers of environmental pollution. Therefore the aim of the research was to analyzed of the trace element content in the intervertebral disc, which may be a vital argument recognizing the background of degenerative changes to be the effect of the environment or metabolic factors. Materials and methods. Material consist of 18 intervertebral disc from 15 patients, acquired in surgical procedure of due to the degenerative disease with Atomic Absorption Spectrometry content of Al, Cd, Co, Pb, Cu, Ni, Mo, Mg, Zn was evaluated. Results. Only 4 of the trace elements were detected in all samples. The correlation analysis showed significant positive age correlation with Al and negative in case of Co. Among elements significant positive correlation was observed between Al/Pb, Co/Mo, Al/Mg, Al/Zn Pb/Zn and Mg/Zn. Negative correlation was observed in Al/Co, Cd/Mg, Co/Mg, Mo/Mg, Co/Zn and Mo/Zn. Conclusions. This study is the first to our knowledge that profiles the elements in intervertebral disc in patients with degenerative changes. We have confirmed significant differences between the trace element contents in intervertebral disc and other tissue. It can be ground for further investigation.","publication":"Annals of Agricultural and Environmental Medicine","publication_with_fallback":"Annals of Agricultural and Environmental Medicine","downloadable_attachments":[{"id":39438970,"asset_id":17291925,"asset_type":"Work","always_allow_download":false,"scribd_thumbnail_url":"https://attachments.academia-assets.com/39438970/thumbnails/1.jpg","download_url":"https://d1wqtxts1xzle7.cloudfront.net/39438970/Analysis_of_trace_element_in_interverteb20151026-1009-rj0nsz-libre.pdf?1445896111=\u0026response-content-disposition=attachment%3B+filename%3DAnalysis_of_trace_element_in_interverteb.pdf\u0026Expires=1740115693\u0026Signature=NIwNEBLWF1fjLK9pPa-mQatOKtF4SQoJ28JUDFf3r2SfI00YdU07uJVzK6eHtdTJIif9~iFHCutxJ4wIZPeFIvyM5rAiqK38u5ZdlNlu~X7PKHzUdTvNXkEcgwZoKbks6-SJn2Gfoc8aNaYYvSF04Lk9iMQs8YMaClSjMuoZ7nBHNDtoWwk83PxFrRl5EuIuv5h~TfSUdwHeddP705SV2E1Uwrexw5y1OyfgJIR6DNbJy8UeWYhBrgCS6O~EdvorB89f02QoLnLE0U7~L45ZPdwBnFnapBwwCVj1m37ss7MR1oCuDqM5ETUYwSJOYgAGVe4dwKGRi~EaLt4P2UF9fA__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA","download_file_url":"https://www.academia.edu/attachments/39438970/download_file?st=MTc0MDE2MTYzMyw4LjIyMi4yMDguMTQ2&","full_thumbnail_url":"https://0.academia-photos.com/attachment_thumbnails/39438970/mini_magick20190222-22904-1yf24l4.png?1550899950"}],"downloadable_attachments_with_full_thumbnails":[{"id":39438970,"asset_id":17291925,"asset_type":"Work","always_allow_download":false,"scribd_thumbnail_url":"https://attachments.academia-assets.com/39438970/thumbnails/1.jpg","download_url":"https://d1wqtxts1xzle7.cloudfront.net/39438970/Analysis_of_trace_element_in_interverteb20151026-1009-rj0nsz-libre.pdf?1445896111=\u0026response-content-disposition=attachment%3B+filename%3DAnalysis_of_trace_element_in_interverteb.pdf\u0026Expires=1740115693\u0026Signature=NIwNEBLWF1fjLK9pPa-mQatOKtF4SQoJ28JUDFf3r2SfI00YdU07uJVzK6eHtdTJIif9~iFHCutxJ4wIZPeFIvyM5rAiqK38u5ZdlNlu~X7PKHzUdTvNXkEcgwZoKbks6-SJn2Gfoc8aNaYYvSF04Lk9iMQs8YMaClSjMuoZ7nBHNDtoWwk83PxFrRl5EuIuv5h~TfSUdwHeddP705SV2E1Uwrexw5y1OyfgJIR6DNbJy8UeWYhBrgCS6O~EdvorB89f02QoLnLE0U7~L45ZPdwBnFnapBwwCVj1m37ss7MR1oCuDqM5ETUYwSJOYgAGVe4dwKGRi~EaLt4P2UF9fA__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA","download_file_url":"https://www.academia.edu/attachments/39438970/download_file?st=MTc0MDE2MTYzMyw4LjIyMi4yMDguMTQ2&","full_thumbnail_url":"https://0.academia-photos.com/attachment_thumbnails/39438970/mini_magick20190222-22904-1yf24l4.png?1550899950"}],"has_pdf":true,"has_fulltext":true,"page_count":6,"ordered_authors":[{"id":36962588,"first_name":"Marcin","last_name":"Frankowski","domain_name":"amu","page_name":"MarcinFrankowski","display_name":"Marcin Frankowski","profile_url":"https://amu.academia.edu/MarcinFrankowski","photo":"https://0.academia-photos.com/36962588/10534304/11756240/s65_marcin.frankowski.jpg"}],"research_interests":[{"id":58054,"name":"Environmental Sciences","url":"https://www.academia.edu/Documents/in/Environmental_Sciences","nofollow":true}],"publication_year":2015,"publication_year_with_fallback":2015,"paper_rank":null,"all_time_views":16,"active_discussion":{}}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_17302316 coauthored" data-work_id="17302316" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/17302316/Effects_of_rainy_season_on_mobilization_of_contaminants_from_tsunami_deposits_left_in_a_coastal_zone_of_Thailand_by_the_26_December_2004_tsunami">Effects of rainy season on mobilization of contaminants from tsunami deposits left in a coastal zone of Thailand by the 26 December 2004 tsunami</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">... Witold Szczucin´ski Æ Przemysław Niedzielski Æ Lidia Kozak Æ Marcin Frankowski Æ Anetta Zioła Æ Stanisław Lorenc ... 2006; Siripong 2006; Szczucin´ski et al. ... P. Niedzielski 4 L. Kozak 4 M. Frankowski 4 A. Zioła Department of Water... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_17302316" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">... Witold Szczucin´ski Æ Przemysław Niedzielski Æ Lidia Kozak Æ Marcin Frankowski Æ Anetta Zioła Æ Stanisław Lorenc ... 2006; Siripong 2006; Szczucin´ski et al. ... P. Niedzielski 4 L. Kozak 4 M. Frankowski 4 A. 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Witold Szczucin´ski Æ Przemysław Niedzielski Æ Lidia Kozak Æ Marcin Frankowski Æ Anetta Zioła Æ Stanisław Lorenc ... 2006; Siripong 2006; Szczucin´ski et al. ... P. Niedzielski 4 L. Kozak 4 M. Frankowski 4 A. 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Geology","url":"https://www.academia.edu/Documents/in/Environmental_Geology","nofollow":true},{"id":6227,"name":"Arsenic","url":"https://www.academia.edu/Documents/in/Arsenic","nofollow":true},{"id":37344,"name":"Earth and Environmental Sciences","url":"https://www.academia.edu/Documents/in/Earth_and_Environmental_Sciences","nofollow":true},{"id":57433,"name":"Seasonality","url":"https://www.academia.edu/Documents/in/Seasonality"},{"id":111050,"name":"Heavy Metal","url":"https://www.academia.edu/Documents/in/Heavy_Metal"},{"id":477461,"name":"Coastal Zone","url":"https://www.academia.edu/Documents/in/Coastal_Zone"},{"id":554780,"name":"Interdisciplinary Engineering","url":"https://www.academia.edu/Documents/in/Interdisciplinary_Engineering"},{"id":598869,"name":"Water soluble polymers","url":"https://www.academia.edu/Documents/in/Water_soluble_polymers"},{"id":1133132,"name":"Environmental","url":"https://www.academia.edu/Documents/in/Environmental"}],"publication_year":2007,"publication_year_with_fallback":2007,"paper_rank":null,"all_time_views":21,"active_discussion":{}}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_17392942 coauthored" data-work_id="17392942" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/17392942/Mercury_in_precipitation_over_the_coastal_zone_of_the_southern_Baltic_Sea_Poland">Mercury in precipitation over the coastal zone of the southern Baltic Sea, Poland</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">An investigation of atmospheric mercury was conducted in the urban coastal zone of the Gulf of Gdansk (Baltic Sea, Poland) in 2008. Rainwater samples were collected in bulk samplers and Hg concentration was determined using AAS method.... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_17392942" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">An investigation of atmospheric mercury was conducted in the urban coastal zone of the Gulf of Gdansk (Baltic Sea, Poland) in 2008. Rainwater samples were collected in bulk samplers and Hg concentration was determined using AAS method. Total mercury concentration ranged from 1.9 to 14.8 ng l −1 (the mean was 8.3 ng l −1 with standard deviation ±3.7), out of which about 34 % were water-soluble Hg(II) forms. Distribution of Hg species in rainwater was related to both the emission source and the atmospheric processes. During the sampling period, two maxima of Hg concentration in precipitation were observed: the first in the cold season and the second one in the warm season. Elevated concentrations of Hg in wintertime precipitation were generally the result of local urban atmospheric emission connected with the following anthropogenic sources: intensive combustion of fossil fuels in domestic furnaces, individual power/heat generating plants, and motor vehicles. During summertime, Hg°reemitted from contaminated land and sea surfaces was photochemically oxidized by active atmospheric substances (e.g., hydroxyl radicals, hydrogen peroxide, halogens) and could be an additional source of atmospherically deposited Hg. The results presented in this work indicate that rainwater Hg concentration and deposition values are not much higher in comparison with other urban locations along the Baltic Sea basin and other coastal cities. However, the elevated mercury concentration in rainwater and, consequently, higher deposition ratio could appear occasionally as an effect of intensive anthropogenic emissions (domestic heating) and/or photochemical reactions.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/17392942" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="62ba5380433b81eb78ac67152939b319" rel="nofollow" data-download="{"attachment_id":39483276,"asset_id":17392942,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/39483276/download_file?st=MTc0MDE2MTYzMyw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="37927730" href="https://independent.academia.edu/ArturKowalski3">Artur Kowalski</a><script data-card-contents-for-user="37927730" type="text/json">{"id":37927730,"first_name":"Artur","last_name":"Kowalski","domain_name":"independent","page_name":"ArturKowalski3","display_name":"Artur Kowalski","profile_url":"https://independent.academia.edu/ArturKowalski3","photo":"/images/s65_no_pic.png"}</script></span></span><span class="u-displayInlineBlock InlineList-item-text"> and <span class="u-textDecorationUnderline u-clickable InlineList-item-text js-work-more-authors-17392942">+2</span><div class="hidden js-additional-users-17392942"><div><span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a href="https://amu.academia.edu/MarcinFrankowski">Marcin Frankowski</a></span></div><div><span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a href="https://independent.academia.edu/LucynaFalkowska">Lucyna Falkowska</a></span></div></div></span><script>(function(){ var popoverSettings = { el: $('.js-work-more-authors-17392942'), placement: 'bottom', hide_delay: 200, html: true, content: function(){ return $('.js-additional-users-17392942').html(); 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Rainwater samples were collected in bulk samplers and Hg concentration was determined using AAS method. Total mercury concentration ranged from 1.9 to 14.8 ng l −1 (the mean was 8.3 ng l −1 with standard deviation ±3.7), out of which about 34 % were water-soluble Hg(II) forms. Distribution of Hg species in rainwater was related to both the emission source and the atmospheric processes. During the sampling period, two maxima of Hg concentration in precipitation were observed: the first in the cold season and the second one in the warm season. Elevated concentrations of Hg in wintertime precipitation were generally the result of local urban atmospheric emission connected with the following anthropogenic sources: intensive combustion of fossil fuels in domestic furnaces, individual power/heat generating plants, and motor vehicles. During summertime, Hg°reemitted from contaminated land and sea surfaces was photochemically oxidized by active atmospheric substances (e.g., hydroxyl radicals, hydrogen peroxide, halogens) and could be an additional source of atmospherically deposited Hg. The results presented in this work indicate that rainwater Hg concentration and deposition values are not much higher in comparison with other urban locations along the Baltic Sea basin and other coastal cities. 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})();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_17392943" data-work_id="17392943" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/17392943/Trace_element_distribution_in_the_snow_cover_from_an_urban_area_in_central_Poland">Trace element distribution in the snow cover from an urban area in central Poland</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">This work presents the first results from winter field campaigns focusing on trace metals and metalloid chemistry in the snow cover from an urbanized region in central Poland. Samples were collected between January and March 2013 and... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_17392943" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">This work presents the first results from winter field campaigns focusing on trace metals and metalloid chemistry in the snow cover from an urbanized region in central Poland. Samples were collected between January and March 2013 and trace element concentrations were determined using GF-AAS. A large inter-seasonal variability depending on anthropogenic emission, depositional processes, and meteorological conditions was observed. The highest concentration (in μg L(-1)) was reported for Pb (34.90), followed by Ni (31.37), Zn (31.00), Cu (13.71), Cr (2.36), As (1.58), and Cd (0.25). In addition, several major anthropogenic sources were identified based on principal component analysis (PCA), among which the most significant was the activity of industry and coal combustion for residential heating. It was stated that elevated concentrations of some trace metals in snow samples were associated with frequent occurrence of south and southeast advection of highly polluted air masses toward th...</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/17392943" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="8a6061c8038cfdc21ad7de387851d8e6" rel="nofollow" data-download="{"attachment_id":42263365,"asset_id":17392943,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/42263365/download_file?st=MTc0MDE2MTYzMyw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="36962588" href="https://amu.academia.edu/MarcinFrankowski">Marcin Frankowski</a><script data-card-contents-for-user="36962588" type="text/json">{"id":36962588,"first_name":"Marcin","last_name":"Frankowski","domain_name":"amu","page_name":"MarcinFrankowski","display_name":"Marcin Frankowski","profile_url":"https://amu.academia.edu/MarcinFrankowski","photo":"https://0.academia-photos.com/36962588/10534304/11756240/s65_marcin.frankowski.jpg"}</script></span></span></li><li class="js-paper-rank-work_17392943 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="17392943"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 17392943, container: ".js-paper-rank-work_17392943", }); 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data-work_id="25247971" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/25247971/Pronin_Pelechaty_Apolinarska_Pukacz_Frankowski_2016">Pronin Pelechaty Apolinarska Pukacz Frankowski 2016</a></div></div><div class="u-pb4x u-mt3x"></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/25247971" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="f1a95ccf790361dad5c40f95e055aca2" rel="nofollow" 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