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Structure-Activity Relationship of Gold Catalysts on Alumina Supported Cu-Ce Oxides for CO and Volatile Organic Compound Oxidation
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/></div></noscript> <!-- /Yandex.Metrika counter --> <!-- Matomo --> <!-- End Matomo Code --> <title>Structure-Activity Relationship of Gold Catalysts on Alumina Supported Cu-Ce Oxides for CO and Volatile Organic Compound Oxidation</title> <meta name="description" content="Structure-Activity Relationship of Gold Catalysts on Alumina Supported Cu-Ce Oxides for CO and Volatile Organic Compound Oxidation"> <meta name="keywords" content="CO and VOCs oxidation, copper oxide, Ceria, gold catalysts"> <meta name="viewport" content="width=device-width, initial-scale=1, minimum-scale=1, maximum-scale=1, user-scalable=no"> <meta charset="utf-8"> <link href="https://cdn.waset.org/favicon.ico" type="image/x-icon" rel="shortcut icon"> <link href="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/css/bootstrap.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/plugins/fontawesome/css/all.min.css" rel="stylesheet"> <link 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Tabakova</a>, <a href="https://publications.waset.org/abstracts/search?q=Elitsa%20N.%20Kolentsova"> Elitsa N. Kolentsova</a>, <a href="https://publications.waset.org/abstracts/search?q=Dimitar%20Y.%20Dimitrov"> Dimitar Y. Dimitrov</a>, <a href="https://publications.waset.org/abstracts/search?q=Krasimir%20I.%20Ivanov"> Krasimir I. Ivanov</a>, <a href="https://publications.waset.org/abstracts/search?q=Yordanka%20G.%20Karakirova"> Yordanka G. Karakirova</a>, <a href="https://publications.waset.org/abstracts/search?q=Petya%20Cv.%20Petrova"> Petya Cv. Petrova</a>, <a href="https://publications.waset.org/abstracts/search?q=Georgi%20V.%20Avdeev"> Georgi V. Avdeev</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The catalytic oxidation of CO and volatile organic compounds (VOCs) is considered as one of the most efficient ways to reduce harmful emissions from various chemical industries. The effectiveness of gold-based catalysts for many reactions of environmental significance was proven during the past three decades. The aim of this work was to combine the favorable features of Au and Cu-Ce mixed oxides in the design of new catalytic materials of improved efficiency and economic viability for removal of air pollutants in waste gases from formaldehyde production. Supported oxides of copper and cerium with Cu: Ce molar ratio 2:1 and 1:5 were prepared by wet impregnation of g-alumina. Gold (2 wt.%) catalysts were synthesized by a deposition-precipitation method. Catalysts characterization was carried out by texture measurements, powder X-ray diffraction, temperature programmed reduction and electron paramagnetic resonance spectroscopy. The catalytic activity in the oxidation of CO, CH<sub>3</sub>OH and (CH<sub>3</sub>)<sub>2</sub>O was measured using continuous flow equipment with fixed bed reactor. Both Cu-Ce/alumina samples demonstrated similar catalytic behavior. The addition of gold caused significant enhancement of CO and methanol oxidation activity (100 % degree of CO and CH<sub>3</sub>OH conversion at about 60 and 140 <sup>o</sup>C, respectively). The composition of Cu-Ce mixed oxides affected the performance of gold-based samples considerably. Gold catalyst on Cu-Ce/γ-Al<sub>2</sub>O<sub>3</sub> 1:5 exhibited higher activity for CO and CH<sub>3</sub>OH oxidation in comparison with Au on Cu-Ce/γ-Al<sub>2</sub>O<sub>3</sub> 2:1. The better performance of Au/Cu-Ce 1:5 was related to the availability of highly dispersed gold particles and copper oxide clusters in close contact with ceria. <iframe src="https://publications.waset.org/abstracts/68871.pdf" style="width:100%; height:400px;" frameborder="0"></iframe> <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=CO%20and%20VOCs%20oxidation" title="CO and VOCs oxidation">CO and VOCs oxidation</a>, <a href="https://publications.waset.org/abstracts/search?q=copper%20oxide" title=" copper oxide"> copper oxide</a>, <a href="https://publications.waset.org/abstracts/search?q=Ceria" title=" Ceria"> Ceria</a>, <a href="https://publications.waset.org/abstracts/search?q=gold%20catalysts" title=" gold catalysts"> gold catalysts</a> </p> <a href="https://publications.waset.org/abstracts/68871/structure-activity-relationship-of-gold-catalysts-on-alumina-supported-cu-ce-oxides-for-co-and-volatile-organic-compound-oxidation" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/68871.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">318</span> </span> </div> </div> </div> </main> <footer> <div id="infolinks" class="pt-3 pb-2"> <div class="container"> <div style="background-color:#f5f5f5;" class="p-3"> <div class="row"> <div class="col-md-2"> <ul class="list-unstyled"> About <li><a href="https://waset.org/page/support">About Us</a></li> <li><a href="https://waset.org/page/support#legal-information">Legal</a></li> <li><a target="_blank" rel="nofollow" href="https://publications.waset.org/static/files/WASET-16th-foundational-anniversary.pdf">WASET celebrates its 16th 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