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Hydroxyde de nickel(II) — Wikipédia

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<span>Toxicité</span> </div> </a> <ul id="toc-Toxicité-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Notes_et_références" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#Notes_et_références"> <div class="vector-toc-text"> <span class="vector-toc-numb">6</span> <span>Notes et références</span> </div> </a> <ul id="toc-Notes_et_références-sublist" class="vector-toc-list"> </ul> </li> </ul> </div> </div> </nav> </div> </div> <div class="mw-content-container"> <main id="content" class="mw-body"> <header class="mw-body-header vector-page-titlebar"> <nav aria-label="Sommaire" class="vector-toc-landmark"> <div id="vector-page-titlebar-toc" class="vector-dropdown vector-page-titlebar-toc vector-button-flush-left" > <input type="checkbox" id="vector-page-titlebar-toc-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-page-titlebar-toc" class="vector-dropdown-checkbox " aria-label="Basculer la table des matières" > <label id="vector-page-titlebar-toc-label" for="vector-page-titlebar-toc-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only " aria-hidden="true" ><span class="vector-icon mw-ui-icon-listBullet mw-ui-icon-wikimedia-listBullet"></span> <span class="vector-dropdown-label-text">Basculer la table des matières</span> </label> <div class="vector-dropdown-content"> <div id="vector-page-titlebar-toc-unpinned-container" class="vector-unpinned-container"> </div> </div> </div> </nav> <h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">Hydroxyde de nickel(II)</span></h1> <div id="p-lang-btn" class="vector-dropdown mw-portlet mw-portlet-lang" > <input type="checkbox" id="p-lang-btn-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-p-lang-btn" class="vector-dropdown-checkbox mw-interlanguage-selector" aria-label="Aller à un article dans une autre langue. Disponible en 25 langues." > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-25" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">25 langues</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-af mw-list-item"><a href="https://af.wikipedia.org/wiki/Nikkelhidroksied" title="Nikkelhidroksied – afrikaans" lang="af" hreflang="af" data-title="Nikkelhidroksied" data-language-autonym="Afrikaans" data-language-local-name="afrikaans" class="interlanguage-link-target"><span>Afrikaans</span></a></li><li class="interlanguage-link interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D9%87%D9%8A%D8%AF%D8%B1%D9%88%D9%83%D8%B3%D9%8A%D8%AF_%D8%A7%D9%84%D9%86%D9%8A%D9%83%D9%84_%D8%A7%D9%84%D8%AB%D9%86%D8%A7%D8%A6%D9%8A" title="هيدروكسيد النيكل الثنائي – arabe" lang="ar" hreflang="ar" data-title="هيدروكسيد النيكل الثنائي" data-language-autonym="العربية" data-language-local-name="arabe" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-azb mw-list-item"><a href="https://azb.wikipedia.org/wiki/%D9%86%DB%8C%DA%A9%D9%84_(II)_%D9%87%DB%8C%D8%AF%D8%B1%D9%88%DA%A9%D8%B3%DB%8C%D8%AF" title="نیکل (II) هیدروکسید – South Azerbaijani" lang="azb" hreflang="azb" data-title="نیکل (II) هیدروکسید" data-language-autonym="تۆرکجه" data-language-local-name="South Azerbaijani" class="interlanguage-link-target"><span>تۆرکجه</span></a></li><li class="interlanguage-link interwiki-de mw-list-item"><a href="https://de.wikipedia.org/wiki/Nickel(II)-hydroxid" title="Nickel(II)-hydroxid – allemand" lang="de" hreflang="de" data-title="Nickel(II)-hydroxid" data-language-autonym="Deutsch" data-language-local-name="allemand" class="interlanguage-link-target"><span>Deutsch</span></a></li><li class="interlanguage-link interwiki-en mw-list-item"><a href="https://en.wikipedia.org/wiki/Nickel(II)_hydroxide" title="Nickel(II) hydroxide – anglais" lang="en" hreflang="en" data-title="Nickel(II) hydroxide" data-language-autonym="English" data-language-local-name="anglais" class="interlanguage-link-target"><span>English</span></a></li><li class="interlanguage-link interwiki-eo mw-list-item"><a href="https://eo.wikipedia.org/wiki/Nikela_(II)_hidroksido" title="Nikela (II) hidroksido – espéranto" lang="eo" hreflang="eo" data-title="Nikela (II) hidroksido" data-language-autonym="Esperanto" data-language-local-name="espéranto" class="interlanguage-link-target"><span>Esperanto</span></a></li><li class="interlanguage-link interwiki-es mw-list-item"><a href="https://es.wikipedia.org/wiki/Hidr%C3%B3xido_de_n%C3%ADquel(II)" title="Hidróxido de níquel(II) – espagnol" lang="es" hreflang="es" data-title="Hidróxido de níquel(II)" data-language-autonym="Español" data-language-local-name="espagnol" class="interlanguage-link-target"><span>Español</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%D9%86%DB%8C%DA%A9%D9%84_(II)_%D9%87%DB%8C%D8%AF%D8%B1%D9%88%DA%A9%D8%B3%DB%8C%D8%AF" title="نیکل (II) هیدروکسید – persan" lang="fa" hreflang="fa" data-title="نیکل (II) هیدروکسید" data-language-autonym="فارسی" data-language-local-name="persan" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fi mw-list-item"><a href="https://fi.wikipedia.org/wiki/Nikkelihydroksidi" title="Nikkelihydroksidi – finnois" lang="fi" hreflang="fi" data-title="Nikkelihydroksidi" data-language-autonym="Suomi" data-language-local-name="finnois" class="interlanguage-link-target"><span>Suomi</span></a></li><li class="interlanguage-link interwiki-hi mw-list-item"><a href="https://hi.wikipedia.org/wiki/%E0%A4%A8%E0%A4%BF%E0%A4%95%E0%A5%87%E0%A4%B2(II)_%E0%A4%B9%E0%A4%BE%E0%A4%87%E0%A4%A1%E0%A5%8D%E0%A4%B0%E0%A4%BE%E0%A4%95%E0%A5%8D%E0%A4%B8%E0%A4%BE%E0%A4%87%E0%A4%A1" title="निकेल(II) हाइड्राक्साइड – hindi" lang="hi" hreflang="hi" data-title="निकेल(II) हाइड्राक्साइड" data-language-autonym="हिन्दी" data-language-local-name="hindi" class="interlanguage-link-target"><span>हिन्दी</span></a></li><li class="interlanguage-link interwiki-id mw-list-item"><a href="https://id.wikipedia.org/wiki/Nikel(II)_hidroksida" title="Nikel(II) hidroksida – indonésien" lang="id" hreflang="id" data-title="Nikel(II) hidroksida" data-language-autonym="Bahasa Indonesia" data-language-local-name="indonésien" class="interlanguage-link-target"><span>Bahasa Indonesia</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E6%B0%B4%E9%85%B8%E5%8C%96%E3%83%8B%E3%83%83%E3%82%B1%E3%83%AB(II)" title="水酸化ニッケル(II) – japonais" lang="ja" hreflang="ja" data-title="水酸化ニッケル(II)" data-language-autonym="日本語" data-language-local-name="japonais" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-nl mw-list-item"><a href="https://nl.wikipedia.org/wiki/Nikkel(II)hydroxide" title="Nikkel(II)hydroxide – néerlandais" lang="nl" hreflang="nl" data-title="Nikkel(II)hydroxide" data-language-autonym="Nederlands" data-language-local-name="néerlandais" class="interlanguage-link-target"><span>Nederlands</span></a></li><li class="interlanguage-link interwiki-pl mw-list-item"><a href="https://pl.wikipedia.org/wiki/Wodorotlenek_niklu(II)" title="Wodorotlenek niklu(II) – polonais" lang="pl" hreflang="pl" data-title="Wodorotlenek niklu(II)" data-language-autonym="Polski" data-language-local-name="polonais" class="interlanguage-link-target"><span>Polski</span></a></li><li class="interlanguage-link interwiki-pt mw-list-item"><a href="https://pt.wikipedia.org/wiki/Hidr%C3%B3xido_de_n%C3%ADquel(II)" title="Hidróxido de níquel(II) – portugais" lang="pt" hreflang="pt" data-title="Hidróxido de níquel(II)" data-language-autonym="Português" data-language-local-name="portugais" class="interlanguage-link-target"><span>Português</span></a></li><li class="interlanguage-link interwiki-ro mw-list-item"><a href="https://ro.wikipedia.org/wiki/Hidroxid_de_nichel_(II)" title="Hidroxid de nichel (II) – roumain" lang="ro" hreflang="ro" data-title="Hidroxid de nichel (II)" data-language-autonym="Română" data-language-local-name="roumain" class="interlanguage-link-target"><span>Română</span></a></li><li class="interlanguage-link interwiki-ru mw-list-item"><a href="https://ru.wikipedia.org/wiki/%D0%93%D0%B8%D0%B4%D1%80%D0%BE%D0%BA%D1%81%D0%B8%D0%B4_%D0%BD%D0%B8%D0%BA%D0%B5%D0%BB%D1%8F(II)" title="Гидроксид никеля(II) – russe" lang="ru" hreflang="ru" data-title="Гидроксид никеля(II)" data-language-autonym="Русский" data-language-local-name="russe" class="interlanguage-link-target"><span>Русский</span></a></li><li class="interlanguage-link interwiki-sh mw-list-item"><a href="https://sh.wikipedia.org/wiki/Nikl(II)_hidroksid" title="Nikl(II) hidroksid – serbo-croate" lang="sh" hreflang="sh" data-title="Nikl(II) hidroksid" data-language-autonym="Srpskohrvatski / српскохрватски" data-language-local-name="serbo-croate" class="interlanguage-link-target"><span>Srpskohrvatski / српскохрватски</span></a></li><li class="interlanguage-link interwiki-simple mw-list-item"><a href="https://simple.wikipedia.org/wiki/Nickel(II)_hydroxide" title="Nickel(II) hydroxide – Simple English" lang="en-simple" hreflang="en-simple" data-title="Nickel(II) hydroxide" data-language-autonym="Simple English" data-language-local-name="Simple English" class="interlanguage-link-target"><span>Simple English</span></a></li><li class="interlanguage-link interwiki-sk mw-list-item"><a href="https://sk.wikipedia.org/wiki/Hydroxid_nikelnat%C3%BD" title="Hydroxid nikelnatý – slovaque" lang="sk" hreflang="sk" data-title="Hydroxid nikelnatý" data-language-autonym="Slovenčina" data-language-local-name="slovaque" class="interlanguage-link-target"><span>Slovenčina</span></a></li><li class="interlanguage-link interwiki-sr mw-list-item"><a href="https://sr.wikipedia.org/wiki/Nikl(II)_hidroksid" title="Nikl(II) hidroksid – serbe" lang="sr" hreflang="sr" data-title="Nikl(II) hidroksid" data-language-autonym="Српски / srpski" data-language-local-name="serbe" class="interlanguage-link-target"><span>Српски / srpski</span></a></li><li class="interlanguage-link interwiki-ta mw-list-item"><a href="https://ta.wikipedia.org/wiki/%E0%AE%A8%E0%AE%BF%E0%AE%95%E0%AF%8D%E0%AE%95%E0%AE%B2%E0%AF%8D(II)_%E0%AE%90%E0%AE%A4%E0%AE%B0%E0%AE%BE%E0%AE%95%E0%AF%8D%E0%AE%9A%E0%AF%88%E0%AE%9F%E0%AF%81" title="நிக்கல்(II) ஐதராக்சைடு – tamoul" lang="ta" hreflang="ta" data-title="நிக்கல்(II) ஐதராக்சைடு" data-language-autonym="தமிழ்" data-language-local-name="tamoul" class="interlanguage-link-target"><span>தமிழ்</span></a></li><li class="interlanguage-link interwiki-uk mw-list-item"><a href="https://uk.wikipedia.org/wiki/%D0%93%D1%96%D0%B4%D1%80%D0%BE%D0%BA%D1%81%D0%B8%D0%B4_%D0%BD%D1%96%D0%BA%D0%B5%D0%BB%D1%8E" title="Гідроксид нікелю – ukrainien" lang="uk" hreflang="uk" data-title="Гідроксид нікелю" data-language-autonym="Українська" data-language-local-name="ukrainien" class="interlanguage-link-target"><span>Українська</span></a></li><li class="interlanguage-link interwiki-vi mw-list-item"><a href="https://vi.wikipedia.org/wiki/Nickel(II)_hydroxide" title="Nickel(II) hydroxide – vietnamien" lang="vi" hreflang="vi" data-title="Nickel(II) hydroxide" data-language-autonym="Tiếng Việt" data-language-local-name="vietnamien" class="interlanguage-link-target"><span>Tiếng Việt</span></a></li><li class="interlanguage-link interwiki-zh mw-list-item"><a href="https://zh.wikipedia.org/wiki/%E6%B0%A2%E6%B0%A7%E5%8C%96%E9%95%8D" title="氢氧化镍 – chinois" lang="zh" hreflang="zh" data-title="氢氧化镍" data-language-autonym="中文" data-language-local-name="chinois" class="interlanguage-link-target"><span>中文</span></a></li> </ul> <div class="after-portlet after-portlet-lang"><span class="wb-langlinks-edit wb-langlinks-link"><a href="https://www.wikidata.org/wiki/Special:EntityPage/Q414637#sitelinks-wikipedia" title="Modifier les liens interlangues" class="wbc-editpage">Modifier les liens</a></span></div> </div> </div> </div> </header> <div class="vector-page-toolbar"> <div class="vector-page-toolbar-container"> <div id="left-navigation"> <nav aria-label="Espaces de noms"> <div id="p-associated-pages" class="vector-menu vector-menu-tabs mw-portlet mw-portlet-associated-pages" > <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li id="ca-nstab-main" class="selected 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data-mw-ve-target-container> <div class="vector-body-before-content"> <div class="mw-indicators"> </div> <div id="siteSub" class="noprint">Un article de Wikipédia, l&#039;encyclopédie libre.</div> </div> <div id="contentSub"><div id="mw-content-subtitle"></div></div> <div id="mw-content-text" class="mw-body-content"><div class="mw-content-ltr mw-parser-output" lang="fr" dir="ltr"><p class="mw-empty-elt"> </p> <table class="infobox_v2 infobox infobox--frwiki noarchive"> <tbody><tr> <td colspan="2" class="entete defaut" style="background-color:#FFDEAD;color:black;">Hydroxyde de nickel(II) </td></tr> <tr><td colspan="2" style="text-align:center; line-height: 1.5em;"><span typeof="mw:File/Frameless"><a href="/wiki/Fichier:Hydroxid_nikelnat%C3%BD.PNG" class="mw-file-description"><img alt="Image illustrative de l’article Hydroxyde de nickel(II)" src="//upload.wikimedia.org/wikipedia/commons/thumb/4/4b/Hydroxid_nikelnat%C3%BD.PNG/280px-Hydroxid_nikelnat%C3%BD.PNG" decoding="async" width="280" height="77" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/4/4b/Hydroxid_nikelnat%C3%BD.PNG/420px-Hydroxid_nikelnat%C3%BD.PNG 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/4/4b/Hydroxid_nikelnat%C3%BD.PNG/560px-Hydroxid_nikelnat%C3%BD.PNG 2x" data-file-width="595" data-file-height="163" /></a></span> </td></tr> <tr> <td colspan="2" style="text-align:center;">Hydroxyde de nickel(II) solide.</td> </tr><tr> <th colspan="2" style="padding:4px; text-align:center; background-color:#FFDEAD; color:#000000">Identification</th></tr> <tr> <th scope="row"><a href="/wiki/Nomenclature_de_l%27UICPA" title="Nomenclature de l&#39;UICPA">Nom UICPA</a> </th> <td><small>hydroxyde de nickel(II)</small> </td> </tr> <tr> <th scope="row"><a href="/wiki/Synonymie" title="Synonymie">Synonymes</a> </th> <td> <p>hydroxyde de nickel </p> </td> </tr> <tr> <th scope="row"><a href="/wiki/Num%C3%A9ro_CAS" title="Numéro CAS">N<sup>o</sup> CAS</a> </th> <td><span class="reflink plainlinksneverexpand nowrap noarchive"><a class="external text" href="//tools.wmflabs.org/magnustools/cas.php?cas=12054-48-7&amp;language=fr&amp;title=Hydroxyde_de_nickel(II)">12054-48-7</a></span> </td> </tr> <tr> <th scope="row"> N<sup>o</sup> <a href="/wiki/Agence_europ%C3%A9enne_des_produits_chimiques" title="Agence européenne des produits chimiques">ECHA</a> </th> <td><span class="plainlinks"><span class="noarchive"><a rel="nofollow" class="external text" href="https://echa.europa.eu/substance-information/-/substanceinfo/100.031.813">100.031.813</a></span></span></td> </tr> <tr> <th scope="row"><a href="/wiki/Num%C3%A9ro_CE" title="Numéro CE">N<sup>o</sup> CE</a> </th> <td>235-008-5 </td> </tr> <tr> <th scope="row"><a href="/wiki/Num%C3%A9ro_RTECS" title="Numéro RTECS">N<sup>o</sup> RTECS</a> </th> <td>QR648000 </td> </tr> <tr> <th scope="row"><a href="/wiki/Simplified_Molecular_Input_Line_Entry_System" title="Simplified Molecular Input Line Entry System">SMILES</a> </th> <td><div class="NavFrame" title="&#91;Afficher&#93;/&#91;Masquer&#93;" style="border: none; padding: 0;"><div class="NavContent" style="display: none; text-align: left;">[Ni+2].[OH-].[OH-] <br /><span class="reflink plainlinksneverexpand"><a rel="nofollow" class="external text" href="http://pubchem.ncbi.nlm.nih.gov/search/?smarts=%5BNi%2B2%5D.%5BOH-%5D.%5BOH-%5D">PubChem</a></span>, <span class="reflink plainlinksneverexpand"><a rel="nofollow" class="external text" href="http://chemapps.stolaf.edu/jmol/jmol.php?title=Hydroxyde+de+nickel%28II%29&amp;model=%5BNi%2B2%5D.%5BOH-%5D.%5BOH-%5D">vue 3D</a></span></div></div> </td> </tr> <tr> <th scope="row"><a href="/wiki/International_Chemical_Identifier" title="International Chemical Identifier">InChI</a> </th> <td><div class="NavFrame" title="&#91;Afficher&#93;/&#91;Masquer&#93;" style="border: none; padding: 0;"><div class="NavContent" style="display: none; text-align: left;"><b>InChI&#160;:</b> <span class="reflink plainlinksneverexpand"><a rel="nofollow" class="external text" href="http://chemapps.stolaf.edu/jmol/jmol.php?title=Hydroxyde+de+nickel%28II%29&amp;model=InChI%3D1%2FNi.2H2O%2Fh%3B2%2A1H2%2Fq%2B2%3B%3B%2Fp-2">vue 3D</a></span> <br />InChI&#61;1/Ni.2H2O/h;2*1H2/q+2;;/p-2 <br /><b>InChIKey&#160;:</b> <br />BFDHFSHZJLFAMC-NUQVWONBAJ <br /><b>Std. InChI&#160;:</b> <span class="reflink plainlinksneverexpand"><a rel="nofollow" class="external text" href="http://chemapps.stolaf.edu/jmol/jmol.php?title=Hydroxyde+de+nickel%28II%29&amp;model=InChI%3D1S%2FNi.2H2O%2Fh%3B2%2A1H2%2Fq%2B2%3B%3B%2Fp-2">vue 3D</a></span> <br />InChI&#61;1S/Ni.2H2O/h;2*1H2/q+2;;/p-2 <br /><b>Std. InChIKey&#160;:</b> <br />BFDHFSHZJLFAMC-UHFFFAOYSA-L</div></div> </td> </tr> <tr> <th scope="row">Apparence </th> <td>solide vert </td> </tr> <tr> <th colspan="2" style="padding:4px; text-align:center; background-color:#FFDEAD; color:#000000">Propriétés chimiques</th></tr> <tr> <th scope="row"><a href="/wiki/Formule_chimique" title="Formule chimique">Formule</a> </th> <td>Ni(OH)<sub>2</sub> </td> </tr> <tr> <th scope="row"><a href="/wiki/Masse_molaire" title="Masse molaire">Masse molaire</a> </th> <td>92,724&#160;<abbr class="abbr" title="gramme par mole">g/mol</abbr> </td> </tr> <tr> <th colspan="2" style="padding:4px; text-align:center; background-color:#f7efa8; color:#000000">Propriétés physiques</th></tr> <tr> <th scope="row"><a href="/wiki/Point_de_fusion" title="Point de fusion"><abbr class="abbr" title="Température">T°</abbr> fusion</a> </th> <td><span title="446 °F ou 503,2 K">230&#160;</span><abbr class="abbr" title="degré Celsius">°C</abbr><sup id="cite_ref-Fisher_1-0" class="reference"><a href="#cite_note-Fisher-1"><span class="cite_crochet">[</span>1<span class="cite_crochet">]</span></a></sup> </td> </tr> <tr> <th scope="row"><a href="/wiki/Solubilit%C3%A9" title="Solubilité">Solubilité</a> </th> <td>Insoluble dans l'eau<br />Soluble dans la soude concentrée<br />Soluble dans l'<a href="/wiki/Ammoniaque" title="Ammoniaque">ammoniaque</a> </td> </tr> <tr> <th colspan="2" style="padding:4px; text-align:center; background-color:#FFDEAD; color:#000000">Thermochimie</th></tr> <tr> <th scope="row">S<sup class="exposant">0</sup><small style="line-height: 1.5em; font-size: 80%;"><sub>solide</sub></small> </th> <td><span class="nowrap"><span title="">79</span>&#160;<span title="joule">J</span>·<span title="Kelvin">K</span><sup>-1</sup>·<span title="Mole">mol</span><sup>-1</sup></span><sup id="cite_ref-b1_2-0" class="reference"><a href="#cite_note-b1-2"><span class="cite_crochet">[</span>2<span class="cite_crochet">]</span></a></sup> </td> </tr> <tr> <th scope="row"><span style="margin:0;background: #eeeeee;padding:0;color:#000">Δ<small style="line-height:1.5em;font-size:80%"><sub>f</sub></small>H<sup class="exposant">0</sup><small style="line-height: 1.5em; font-size: 80%;"><sub>solide</sub></small></span> </th> <td><span class="nowrap"><span title="−5,575&#160;978&#160;526&#160;968&#160;9 eV ou −128&#160;585,09 cal(th)·mol⁻¹">−538</span>&#160;<span title="kilojoule">kJ</span>·<span title="Mole">mol</span><sup>-1</sup></span><sup id="cite_ref-b1_2-1" class="reference"><a href="#cite_note-b1-2"><span class="cite_crochet">[</span>2<span class="cite_crochet">]</span></a></sup> </td> </tr> <tr> <th colspan="2" style="padding:4px; text-align:center; background-color:#ffb4b4; color:#000000">Précautions</th></tr> <tr> <th colspan="2" style="padding:4px; text-align:center; background-color:#eeeeee; color:#000000"><a href="/wiki/Directive_67/548/EEC" title="Directive 67/548/EEC">Directive 67/548/EEC</a></th></tr> <tr> <td colspan="2" style="text-align:left;"><div style="text-align: center;"><div style="width: 60px; text-align:center; display: inline-block;"><span typeof="mw:File"><a href="/wiki/Fichier:Hazard_X.svg" class="mw-file-description" title="Nocif"><img alt="Nocif" src="//upload.wikimedia.org/wikipedia/commons/thumb/e/ed/Hazard_X.svg/50px-Hazard_X.svg.png" decoding="async" width="50" height="50" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/e/ed/Hazard_X.svg/75px-Hazard_X.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/e/ed/Hazard_X.svg/100px-Hazard_X.svg.png 2x" data-file-width="500" data-file-height="500" /></a></span><br />Xn</div><div style="width: 60px; text-align:center; display: inline-block;"><span typeof="mw:File"><a href="/wiki/Fichier:Hazard_N.svg" class="mw-file-description" title="Dangereux pour l’environnement"><img alt="Dangereux pour l’environnement" src="//upload.wikimedia.org/wikipedia/commons/thumb/6/6a/Hazard_N.svg/50px-Hazard_N.svg.png" decoding="async" width="50" height="50" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/6/6a/Hazard_N.svg/75px-Hazard_N.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/6/6a/Hazard_N.svg/100px-Hazard_N.svg.png 2x" data-file-width="500" data-file-height="500" /></a></span><br />N</div></div><div class="NavFrame" title="&#91;+&#93;/&#91;–&#93;" style="clear:left; border:none; padding: 0;"><div class="NavContent" style="display:none; text-align:left;"><b>Symboles</b>&#160;: <br /><b>Xn</b>&#160;: <a href="https://fr.wiktionary.org/wiki/nocif" class="extiw" title="wikt:nocif">Nocif</a><br /><b>N</b>&#160;: <a href="/wiki/Environnement" title="Environnement">Dangereux pour l’environnement</a><br /><br /><b>Phrases R</b>&#160;: <br /><b>R40</b>&#160;: Effet cancérogène suspecté. Risque possible d’effets irréversibles.<br /><b>R43</b>&#160;: Peut entraîner une sensibilisation par contact avec la peau.<br /><b>R20/22</b>&#160;: Nocif par inhalation et par ingestion.<br /><b>R50/53</b>&#160;: Très toxique pour les organismes aquatiques, peut entraîner des effets néfastes à long terme pour l’environnement aquatique.<br /><br /><b>Phrases S</b>&#160;: <br /><b>S22</b>&#160;: Ne pas respirer les poussières.<br /><b>S36</b>&#160;: Porter un vêtement de protection approprié.<br /><b>S60</b>&#160;: Éliminer le produit et son récipient comme un déchet dangereux.<br /><b>S61</b>&#160;: Éviter le rejet dans l’environnement. Consulter les instructions spéciales/la fiche de données de sécurité.<br /></div></div><br /><div style="clear:left;"><a href="/wiki/Phrases_de_risque" title="Phrases de risque">Phrases R</a>&#160;:&#160;<a href="/wiki/Phrases_de_risque#R20.2F22" title="Phrases de risque"><span title="Nocif par inhalation et par ingestion.">20/22, </span></a><a href="/wiki/Phrases_de_risque#R40" title="Phrases de risque"><span title="Effet cancérogène suspecté. Risque possible d’effets irréversibles">40, </span></a><a href="/wiki/Phrases_de_risque#R43" title="Phrases de risque"><span title="Peut entraîner une sensibilisation par contact avec la peau.">43, </span></a><a href="/wiki/Phrases_de_risque#R50.2F53" title="Phrases de risque"><span title="Très toxique pour les organismes aquatiques, peut entraîner des effets néfastes à long terme pour l’environnement aquatique.">50/53, </span></a></div><br /><div style="clear:left;"><a href="/wiki/Conseils_de_prudence" title="Conseils de prudence">Phrases S</a>&#160;:&#160;<a href="/wiki/Conseils_de_prudence#S22" title="Conseils de prudence"><span title="Ne pas respirer les poussières.">22, </span></a><a href="/wiki/Conseils_de_prudence#S36" title="Conseils de prudence"><span title="Porter un vêtement de protection approprié.">36, </span></a><a href="/wiki/Conseils_de_prudence#S60" title="Conseils de prudence"><span title="Éliminer le produit et son récipient comme un déchet dangereux.">60, </span></a><a href="/wiki/Conseils_de_prudence#S61" title="Conseils de prudence"><span title="Éviter le rejet dans l’environnement. Consulter les instructions spéciales/la fiche de données de sécurité.">61, </span></a></div></td> </tr><tr> <th colspan="2" style="padding:4px; text-align:center; background-color:#ffb4b4; color:#000000"><a href="/wiki/%C3%89cotoxicologie" title="Écotoxicologie">Écotoxicologie</a></th></tr> <tr> <th scope="row"><a href="/wiki/Dose_l%C3%A9tale_m%C3%A9diane" title="Dose létale médiane">DL<small style="line-height: 1.5em; font-size: 80%;"><sub>50</sub></small></a> </th> <td>1&#160;515&#160;<abbr class="abbr" title="milligramme par kilogramme">mg/kg</abbr> sur le rat en ingestion orale<sup id="cite_ref-Fisher_1-1" class="reference"><a href="#cite_note-Fisher-1"><span class="cite_crochet">[</span>1<span class="cite_crochet">]</span></a></sup> </td> </tr> <tr> <td colspan="2"><hr style="height:2px; background-color:#FFDEAD;" /></td></tr> <tr> <td colspan="2" style="text-align:center;">Unités du <a href="/wiki/Syst%C3%A8me_international_d%27unit%C3%A9s" title="Système international d&#39;unités">SI</a> et <a href="/wiki/Conditions_normales_de_temp%C3%A9rature_et_de_pression" title="Conditions normales de température et de pression"><abbr title="conditions normales de température et de pression">CNTP</abbr></a>, sauf indication contraire.</td> </tr><tr> <td class="navigation-only" colspan="2" style="border-top: 2px #FFDEAD solid; font-size: 80%; background:inherit; text-align: right;"><span class="plainlinks" style="float:left;"><a class="external text" href="https://fr.wikipedia.org/w/index.php?title=Hydroxyde_de_nickel(II)&amp;action=edit&amp;section=0"><span class="infodoc">modifier</span></a></span>&#160;<span typeof="mw:File"><a href="/wiki/Mod%C3%A8le:Infobox_Chimie" title="Consultez la documentation du modèle"><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/3/38/Info_Simple.svg/12px-Info_Simple.svg.png" decoding="async" width="12" height="12" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/3/38/Info_Simple.svg/18px-Info_Simple.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/3/38/Info_Simple.svg/24px-Info_Simple.svg.png 2x" data-file-width="512" data-file-height="512" /></a></span></td> </tr> </tbody></table> <p>L'<b>hydroxyde de nickel(II)</b> est un <a href="/wiki/Complexe_(chimie)" title="Complexe (chimie)">complexe</a> de <a href="/wiki/Nickel" title="Nickel">nickel</a> au <a href="/wiki/Degr%C3%A9_d%27oxydation" class="mw-redirect" title="Degré d&#39;oxydation">degré d'oxydation</a> II, de formule Ni(OH)<sub>2</sub>. Ses propriétés oxydo-réductrices en font un composé très utilisé dans l'industrie, particulièrement dans les <a href="/wiki/Batterie_d%27accumulateurs" title="Batterie d&#39;accumulateurs">batteries</a> rechargeables au nickel. </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="Polymorphisme">Polymorphisme</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyde_de_nickel(II)&amp;veaction=edit&amp;section=1" title="Modifier la section : Polymorphisme" class="mw-editsection-visualeditor"><span>modifier</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Hydroxyde_de_nickel(II)&amp;action=edit&amp;section=1" title="Modifier le code source de la section : Polymorphisme"><span>modifier le code</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>L'<a href="/wiki/Hydroxyde_m%C3%A9tallique" title="Hydroxyde métallique">hydroxyde</a> de nickel(II) est présent sous plusieurs <a href="/wiki/Polymorphisme_(chimie)" title="Polymorphisme (chimie)">polymorphes</a>. </p><p>La forme α est constituée de couches de Ni(OH)<sub>2</sub> entre lesquelles sont intercalés des anions ou des molécules d'eau<sup id="cite_ref-Oliva_3-0" class="reference"><a href="#cite_note-Oliva-3"><span class="cite_crochet">[</span>3<span class="cite_crochet">]</span></a></sup><sup class="reference cite_virgule">,</sup><sup id="cite_ref-Jeevandam_4-0" class="reference"><a href="#cite_note-Jeevandam-4"><span class="cite_crochet">[</span>4<span class="cite_crochet">]</span></a></sup>. La forme β est une structure <a href="/wiki/Hexagonal_compact" class="mw-redirect" title="Hexagonal compact">hexagonale compacte</a> d'ions Ni<sup>2+</sup> et OH<sup>−</sup><sup id="cite_ref-Oliva_3-1" class="reference"><a href="#cite_note-Oliva-3"><span class="cite_crochet">[</span>3<span class="cite_crochet">]</span></a></sup><sup class="reference cite_virgule">,</sup><sup id="cite_ref-Jeevandam_4-1" class="reference"><a href="#cite_note-Jeevandam-4"><span class="cite_crochet">[</span>4<span class="cite_crochet">]</span></a></sup>. En présence d'eau, la forme α évolue en forme β après <a href="/wiki/Dissolution_(chimie)" title="Dissolution (chimie)">dissolution</a> et <a href="/wiki/Cristallisation_(chimie)" class="mw-redirect" title="Cristallisation (chimie)">recristallisation</a><sup id="cite_ref-Oliva_3-2" class="reference"><a href="#cite_note-Oliva-3"><span class="cite_crochet">[</span>3<span class="cite_crochet">]</span></a></sup><sup class="reference cite_virgule">,</sup><sup id="cite_ref-Shukla_5-0" class="reference"><a href="#cite_note-Shukla-5"><span class="cite_crochet">[</span>5<span class="cite_crochet">]</span></a></sup>. Plusieurs structures d'hydroxyde de nickel γ ont été décrites, dans lesquels la distance inter-feuillet est plus importante<sup id="cite_ref-Oliva_3-3" class="reference"><a href="#cite_note-Oliva-3"><span class="cite_crochet">[</span>3<span class="cite_crochet">]</span></a></sup>. </p><p>Le minerai de Ni(OH)<sub>2</sub>, la <a href="/w/index.php?title=Th%C3%A9ophrastite&amp;action=edit&amp;redlink=1" class="new" title="Théophrastite (page inexistante)">théophrastite</a>, se trouve sous la forme d'un cristal d'un vert émeraude translucide<sup id="cite_ref-Marcopoulos_6-0" class="reference"><a href="#cite_note-Marcopoulos-6"><span class="cite_crochet">[</span>6<span class="cite_crochet">]</span></a></sup>. Une variante de ce minerai contenant du <a href="/wiki/Magn%C3%A9sium" title="Magnésium">magnésium</a> a été découverte à Hagdale, sur l'île de <a href="/wiki/Unst" title="Unst">Unst</a> dans les <a href="/wiki/Shetland" title="Shetland">Shetland</a><sup id="cite_ref-7" class="reference"><a href="#cite_note-7"><span class="cite_crochet">[</span>7<span class="cite_crochet">]</span></a></sup>. </p> <div class="mw-heading mw-heading2"><h2 id="Propriétés"><span id="Propri.C3.A9t.C3.A9s"></span>Propriétés</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyde_de_nickel(II)&amp;veaction=edit&amp;section=2" title="Modifier la section : Propriétés" class="mw-editsection-visualeditor"><span>modifier</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Hydroxyde_de_nickel(II)&amp;action=edit&amp;section=2" title="Modifier le code source de la section : Propriétés"><span>modifier le code</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="mw-heading mw-heading3"><h3 id="Solubilité"><span id="Solubilit.C3.A9"></span>Solubilité</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyde_de_nickel(II)&amp;veaction=edit&amp;section=3" title="Modifier la section : Solubilité" class="mw-editsection-visualeditor"><span>modifier</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Hydroxyde_de_nickel(II)&amp;action=edit&amp;section=3" title="Modifier le code source de la section : Solubilité"><span>modifier le code</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>L'hydroxyde de nickel(II) est insoluble dans l'eau<sup id="cite_ref-Housecroft730_8-0" class="reference"><a href="#cite_note-Housecroft730-8"><span class="cite_crochet">[</span>8<span class="cite_crochet">]</span></a></sup>. Il est soluble dans les solutions très concentrées d'<a href="/wiki/Hydroxyde_de_sodium" title="Hydroxyde de sodium">hydroxyde de sodium</a> où il forme le composé de formule Na<sub>2</sub>[Ni(OH)<sub>4</sub>]<sup id="cite_ref-Housecroft730_8-1" class="reference"><a href="#cite_note-Housecroft730-8"><span class="cite_crochet">[</span>8<span class="cite_crochet">]</span></a></sup>, et dans l'<a href="/wiki/Ammoniaque" title="Ammoniaque">ammoniaque</a> où il forme le composé soluble [Ni(NH<sub>3</sub>)<sub>6</sub>]<sup>2+</sup><sup id="cite_ref-Housecroft730_8-2" class="reference"><a href="#cite_note-Housecroft730-8"><span class="cite_crochet">[</span>8<span class="cite_crochet">]</span></a></sup>. </p> <div class="mw-heading mw-heading3"><h3 id="Oxydo-réduction"><span id="Oxydo-r.C3.A9duction"></span>Oxydo-réduction</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyde_de_nickel(II)&amp;veaction=edit&amp;section=4" title="Modifier la section : Oxydo-réduction" class="mw-editsection-visualeditor"><span>modifier</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Hydroxyde_de_nickel(II)&amp;action=edit&amp;section=4" title="Modifier le code source de la section : Oxydo-réduction"><span>modifier le code</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>L'hydroxyde de nickel(II) peut être oxydé en <a href="/wiki/Oxyhydroxyde_de_nickel(III)" class="mw-redirect" title="Oxyhydroxyde de nickel(III)">oxyhydroxyde de nickel(III)</a> Ni(O)OH par les hypochlorites alcalins<sup id="cite_ref-Housecroft730_8-3" class="reference"><a href="#cite_note-Housecroft730-8"><span class="cite_crochet">[</span>8<span class="cite_crochet">]</span></a></sup>. </p><p>Dans les batteries au nickel, cette oxydation est combinée à la réduction d'un métal en <a href="/wiki/Hydrure_m%C3%A9tallique" class="mw-redirect" title="Hydrure métallique">hydrure métallique</a> (MH) selon l'équation globale&#160;: </p> <dl><dd>Ni(OH)<sub>2</sub> + M → Ni(O)OH + MH.</dd></dl> <div class="mw-heading mw-heading2"><h2 id="Obtention">Obtention</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyde_de_nickel(II)&amp;veaction=edit&amp;section=5" title="Modifier la section : Obtention" class="mw-editsection-visualeditor"><span>modifier</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Hydroxyde_de_nickel(II)&amp;action=edit&amp;section=5" title="Modifier le code source de la section : Obtention"><span>modifier le code</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>La première synthèse de l'hydroxyde de nickel(II) a été proposée par Glemser et Einerhand, en faisant réagir du <a href="/w/index.php?title=Nitrate_de_nickel(II)&amp;action=edit&amp;redlink=1" class="new" title="Nitrate de nickel(II) (page inexistante)">nitrate de nickel(II)</a> avec de la <a href="/wiki/Hydroxyde_de_sodium" title="Hydroxyde de sodium">soude</a> et du <a href="/wiki/Peroxodisulfate" title="Peroxodisulfate">peroxodisulfate</a> de potassium<sup id="cite_ref-Oliva_3-4" class="reference"><a href="#cite_note-Oliva-3"><span class="cite_crochet">[</span>3<span class="cite_crochet">]</span></a></sup>. </p><p>L'ajout de soude sur les composés aqueux du nickel(II) entraine la formation de l'hydroxyde de nickel(II)<sup id="cite_ref-Housecroft730_8-4" class="reference"><a href="#cite_note-Housecroft730-8"><span class="cite_crochet">[</span>8<span class="cite_crochet">]</span></a></sup>. </p><p>De nombreuses autres voies de synthèse ont été proposées en fonction de l'application finale du composé. Ainsi, pour éviter le passage de la forme allotropique α à la forme β, Jeevandam <i>et al.</i> ont mis au point une synthèse <a href="/wiki/Sonochimie" title="Sonochimie">sonochimique</a> menant à des couches de Ni(OH)<sub>2</sub> avec des ions aluminium<sup id="cite_ref-Jeevandam_4-2" class="reference"><a href="#cite_note-Jeevandam-4"><span class="cite_crochet">[</span>4<span class="cite_crochet">]</span></a></sup>. </p> <div class="mw-heading mw-heading2"><h2 id="Utilisation">Utilisation</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyde_de_nickel(II)&amp;veaction=edit&amp;section=6" title="Modifier la section : Utilisation" class="mw-editsection-visualeditor"><span>modifier</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Hydroxyde_de_nickel(II)&amp;action=edit&amp;section=6" title="Modifier le code source de la section : Utilisation"><span>modifier le code</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>En raison de ces propriétés d'oxydo-réduction, l'hydroxyde de nickel(II) est très utilisé en <a href="/wiki/%C3%89lectrochimie" title="Électrochimie">électrochimie</a> et plus particulièrement dans la conception des batteries. </p><p>Les <a href="/wiki/Accumulateur_nickel-cadmium" title="Accumulateur nickel-cadmium">accumulateurs nickel-cadmium</a> et <a href="/wiki/Accumulateur_nickel-hydrure_m%C3%A9tallique" title="Accumulateur nickel-hydrure métallique">nickel-hydrure métallique</a> utilisent une <a href="/wiki/Anode" title="Anode">anode</a> en hydroxyde de nickel(II)<sup id="cite_ref-Housecroft278_9-0" class="reference"><a href="#cite_note-Housecroft278-9"><span class="cite_crochet">[</span>9<span class="cite_crochet">]</span></a></sup>. L'α-hydroxyde de nickel(II) est la forme allotropique qui possède la plus grande capacité théorique et est donc généralement utilisée en électrochimie. Cependant sa tendance à se transformer en la variété β en solution alcaline tend à faire développer des formes stabilisées pour améliorer l'usage industriel<sup id="cite_ref-Shukla_5-1" class="reference"><a href="#cite_note-Shukla-5"><span class="cite_crochet">[</span>5<span class="cite_crochet">]</span></a></sup>. </p> <div class="mw-heading mw-heading2"><h2 id="Toxicité"><span id="Toxicit.C3.A9"></span>Toxicité</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyde_de_nickel(II)&amp;veaction=edit&amp;section=7" title="Modifier la section : Toxicité" class="mw-editsection-visualeditor"><span>modifier</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Hydroxyde_de_nickel(II)&amp;action=edit&amp;section=7" title="Modifier le code source de la section : Toxicité"><span>modifier le code</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>La <a href="/wiki/Dose_l%C3%A9tale_m%C3%A9diane" title="Dose létale médiane">dose létale médiane</a> par ingestion de l'hydroxyde de nickel(II) est de 1&#160;515&#160;<abbr class="abbr" title="milligramme par kilogramme">mg/kg</abbr> sur le rat<sup id="cite_ref-Fisher_1-2" class="reference"><a href="#cite_note-Fisher-1"><span class="cite_crochet">[</span>1<span class="cite_crochet">]</span></a></sup>. Cette toxicité importante de l'hydroxyde par rapport aux autres composés du nickel(II) est peut-être due à son caractère insoluble et à sa concentration dans les cellules<sup id="cite_ref-Fletcher_10-0" class="reference"><a href="#cite_note-Fletcher-10"><span class="cite_crochet">[</span>10<span class="cite_crochet">]</span></a></sup>. Ces problèmes sanitaires ont entrainé une augmentation des projets de recherche visant à améliorer la <a href="/wiki/Densit%C3%A9_%C3%A9nerg%C3%A9tique" class="mw-redirect" title="Densité énergétique">densité énergétique</a> des électrodes contenant de l'hydroxyde de nickel(II), particulièrement par l'ajout d'<a href="/wiki/Hydroxyde_de_cobalt" class="mw-redirect" title="Hydroxyde de cobalt">hydroxyde de cobalt</a> ou de <a href="/wiki/Hydroxyde_de_calcium" title="Hydroxyde de calcium">calcium</a><sup id="cite_ref-Chen_11-0" class="reference"><a href="#cite_note-Chen-11"><span class="cite_crochet">[</span>11<span class="cite_crochet">]</span></a></sup>. </p> <div class="mw-heading mw-heading2"><h2 id="Notes_et_références"><span id="Notes_et_r.C3.A9f.C3.A9rences"></span>Notes et références</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Hydroxyde_de_nickel(II)&amp;veaction=edit&amp;section=8" title="Modifier la section : Notes et références" class="mw-editsection-visualeditor"><span>modifier</span></a><span class="mw-editsection-divider"> | </span><a href="/w/index.php?title=Hydroxyde_de_nickel(II)&amp;action=edit&amp;section=8" title="Modifier le code source de la section : Notes et références"><span>modifier le code</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><abbr class="abbr indicateur-langue" title="Langue : anglais">(en)</abbr> Cet article est partiellement ou en totalité issu de l’article de Wikipédia en anglais intitulé <span class="plainlinks">«&#160;<a class="external text" href="https://en.wikipedia.org/wiki/Nickel(II)_hydroxide?oldid=528137313">Nickel(II) hydroxide</a>&#160;» <small>(<a class="external text" href="https://en.wikipedia.org/wiki/Nickel(II)_hydroxide?action=history">voir la liste des auteurs</a>)</small></span>.</li></ul> <div class="references-small decimal" style=""><div class="mw-references-wrap mw-references-columns"><ol class="references"> <li id="cite_note-Fisher-1"><span class="mw-cite-backlink noprint">↑ <sup><a href="#cite_ref-Fisher_1-0">a</a> <a href="#cite_ref-Fisher_1-1">b</a> et <a href="#cite_ref-Fisher_1-2">c</a></sup> </span><span class="reference-text"><a rel="nofollow" class="external text" href="https://fscimage.fishersci.com/msds/53189.htm">fiche de sécurité fisher</a></span> </li> <li id="cite_note-b1-2"><span class="mw-cite-backlink noprint">↑ <sup><a href="#cite_ref-b1_2-0">a</a> et <a href="#cite_ref-b1_2-1">b</a></sup> </span><span class="reference-text"><span class="ouvrage" id="Zumdahl2009"><span class="ouvrage" id="Steven_S._Zumdahl2009"><abbr class="abbr indicateur-langue" title="Langue : anglais">(en)</abbr> Steven S. <span class="nom_auteur">Zumdahl</span>, <cite class="italique" lang="en">Chemical Principles</cite>, Houghton Mifflin Company, <time>2009</time>, <abbr class="abbr" title="sixième">6<sup>e</sup></abbr>&#160;<abbr class="abbr" title="édition">éd.</abbr>, 1200&#160;<abbr class="abbr" title="pages">p.</abbr> <small style="line-height:1em;">(<a href="/wiki/International_Standard_Book_Number" title="International Standard Book Number">ISBN</a>&#160;<a href="/wiki/Sp%C3%A9cial:Ouvrages_de_r%C3%A9f%C3%A9rence/978-0-618-94690-7" title="Spécial:Ouvrages de référence/978-0-618-94690-7"><span class="nowrap">978-0-618-94690-7</span></a> et <a href="/wiki/Sp%C3%A9cial:Ouvrages_de_r%C3%A9f%C3%A9rence/0-618-94690-X" title="Spécial:Ouvrages de référence/0-618-94690-X"><span class="nowrap">0-618-94690-X</span></a>, <a rel="nofollow" class="external text" href="https://books.google.com/books?id=2OxrDtDaSqIC&amp;printsec=frontcover">lire en ligne</a>)</small>, A22<span class="Z3988" title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&amp;rft.genre=book&amp;rft.btitle=Chemical+Principles&amp;rft.pub=Houghton+Mifflin+Company&amp;rft.edition=6&amp;rft.aulast=Zumdahl&amp;rft.aufirst=Steven+S.&amp;rft.date=2009&amp;rft.pages=A22&amp;rft.tpages=1200&amp;rft.isbn=978-0-618-94690-7&amp;rfr_id=info%3Asid%2Ffr.wikipedia.org%3AHydroxyde+de+nickel%28II%29"></span></span></span></span> </li> <li id="cite_note-Oliva-3"><span class="mw-cite-backlink noprint">↑ <sup><a href="#cite_ref-Oliva_3-0">a</a> <a href="#cite_ref-Oliva_3-1">b</a> <a href="#cite_ref-Oliva_3-2">c</a> <a href="#cite_ref-Oliva_3-3">d</a> et <a href="#cite_ref-Oliva_3-4">e</a></sup> </span><span class="reference-text">Oliva, P.; Leonardi, J.; Laurent, J.F., <i>Journal of Power Sources</i>. 1982, 8, 229-255.</span> </li> <li id="cite_note-Jeevandam-4"><span class="mw-cite-backlink noprint">↑ <sup><a href="#cite_ref-Jeevandam_4-0">a</a> <a href="#cite_ref-Jeevandam_4-1">b</a> et <a href="#cite_ref-Jeevandam_4-2">c</a></sup> </span><span class="reference-text">Jeevanandam, P.; Koltypin, Y.; Gedanken, A., <i>Am. Chem. Soc. Nano Letters</i>. 2001, 1, 263-266.</span> </li> <li id="cite_note-Shukla-5"><span class="mw-cite-backlink noprint">↑ <sup><a href="#cite_ref-Shukla_5-0">a</a> et <a href="#cite_ref-Shukla_5-1">b</a></sup> </span><span class="reference-text">Shukla, A.K.; Kumar, V.G.; Munichandriah, N. J., <i>Electrochem. Soc.</i> 1994, 141, 2956-2959.</span> </li> <li id="cite_note-Marcopoulos-6"><span class="mw-cite-backlink noprint"><a href="#cite_ref-Marcopoulos_6-0">↑</a> </span><span class="reference-text">Marcopoulos, T.; Economou, M. <i>American Mineralogist</i>, 1980, 66, 1020-1021.</span> </li> <li id="cite_note-7"><span class="mw-cite-backlink noprint"><a href="#cite_ref-7">↑</a> </span><span class="reference-text">Livingston, A. et Bish, D. L. (March 1982) <i>On the new mineral theophrastite, a nickel hydroxide, from Unst, Shetland, Scotland</i>. <i>Mineralogical Magazine</i>. <b>6</b> <abbr class="abbr" title="numéro">n<sup>o</sup></abbr>&#160;338.</span> </li> <li id="cite_note-Housecroft730-8"><span class="mw-cite-backlink noprint">↑ <sup><a href="#cite_ref-Housecroft730_8-0">a</a> <a href="#cite_ref-Housecroft730_8-1">b</a> <a href="#cite_ref-Housecroft730_8-2">c</a> <a href="#cite_ref-Housecroft730_8-3">d</a> et <a href="#cite_ref-Housecroft730_8-4">e</a></sup> </span><span class="reference-text"><span class="ouvrage" id="HousecroftSharpe2010"><span class="ouvrage" id="Catherine_HousecroftAlan_Sharpe2010">Catherine <span class="nom_auteur">Housecroft</span> et Alan <span class="nom_auteur">Sharpe</span> (<abbr class="abbr" title="traduction">trad.</abbr>&#160;de l'anglais par André Pousse), <cite class="italique">Chimie inorganique</cite>, Bruxelles/Paris, <a href="/wiki/De_Boeck" title="De Boeck">De Boeck</a>, <time class="nowrap" datetime="2010-09" data-sort-value="2010-09">septembre 2010</time>, 1097&#160;<abbr class="abbr" title="pages">p.</abbr> <small style="line-height:1em;">(<a href="/wiki/International_Standard_Book_Number" title="International Standard Book Number">ISBN</a>&#160;<a href="/wiki/Sp%C3%A9cial:Ouvrages_de_r%C3%A9f%C3%A9rence/978-2-8041-6218-4" title="Spécial:Ouvrages de référence/978-2-8041-6218-4"><span class="nowrap">978-2-8041-6218-4</span></a>, <a rel="nofollow" class="external text" href="https://books.google.com/books?id=Q00mDwAAQBAJ&amp;printsec=frontcover">lire en ligne</a>)</small>, <abbr class="abbr" title="page">p.</abbr>&#160;730<span class="Z3988" title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&amp;rft.genre=book&amp;rft.btitle=Chimie+inorganique&amp;rft.place=Bruxelles%2FParis&amp;rft.pub=De+Boeck&amp;rft.aulast=Housecroft&amp;rft.aufirst=Catherine&amp;rft.au=Sharpe%2C+Alan&amp;rft.date=2010-09&amp;rft.pages=730&amp;rft.tpages=1097&amp;rft.isbn=978-2-8041-6218-4&amp;rfr_id=info%3Asid%2Ffr.wikipedia.org%3AHydroxyde+de+nickel%28II%29"></span></span></span></span> </li> <li id="cite_note-Housecroft278-9"><span class="mw-cite-backlink noprint"><a href="#cite_ref-Housecroft278_9-0">↑</a> </span><span class="reference-text"><span class="ouvrage" id="HousecroftSharpe2010"><span class="ouvrage" id="Catherine_HousecroftAlan_Sharpe2010">Catherine <span class="nom_auteur">Housecroft</span> et Alan <span class="nom_auteur">Sharpe</span> (<abbr class="abbr" title="traduction">trad.</abbr>&#160;de l'anglais par André Pousse), <cite class="italique">Chimie inorganique</cite>, Bruxelles/Paris, <a href="/wiki/De_Boeck" title="De Boeck">De Boeck</a>, <time class="nowrap" datetime="2010-09" data-sort-value="2010-09">septembre 2010</time>, 1097&#160;<abbr class="abbr" title="pages">p.</abbr> <small style="line-height:1em;">(<a href="/wiki/International_Standard_Book_Number" title="International Standard Book Number">ISBN</a>&#160;<a href="/wiki/Sp%C3%A9cial:Ouvrages_de_r%C3%A9f%C3%A9rence/978-2-8041-6218-4" title="Spécial:Ouvrages de référence/978-2-8041-6218-4"><span class="nowrap">978-2-8041-6218-4</span></a>, <a rel="nofollow" class="external text" href="https://books.google.com/books?id=Q00mDwAAQBAJ&amp;printsec=frontcover">lire en ligne</a>)</small>, <abbr class="abbr" title="page">p.</abbr>&#160;278<span class="Z3988" title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&amp;rft.genre=book&amp;rft.btitle=Chimie+inorganique&amp;rft.place=Bruxelles%2FParis&amp;rft.pub=De+Boeck&amp;rft.aulast=Housecroft&amp;rft.aufirst=Catherine&amp;rft.au=Sharpe%2C+Alan&amp;rft.date=2010-09&amp;rft.pages=278&amp;rft.tpages=1097&amp;rft.isbn=978-2-8041-6218-4&amp;rfr_id=info%3Asid%2Ffr.wikipedia.org%3AHydroxyde+de+nickel%28II%29"></span></span></span></span> </li> <li id="cite_note-Fletcher-10"><span class="mw-cite-backlink noprint"><a href="#cite_ref-Fletcher_10-0">↑</a> </span><span class="reference-text">Fletcher, G.G.; Rossetto, F.E.; Turnbull, J.D.; Nieboer, E., <i>Environmental Health Perspectives</i>. 1994, 102, 69-74.</span> </li> <li id="cite_note-Chen-11"><span class="mw-cite-backlink noprint"><a href="#cite_ref-Chen_11-0">↑</a> </span><span class="reference-text">Chen, J.; Bradhurst, D.H.; Dou, S.X.; Liu, H.K., <i>J. Electrochem. Soc.</i> 1999. 146, 3606-3612.</span> </li> </ol></div> </div> <div class="navbox-container" style="clear:both;"> <table class="navbox collapsible noprint autocollapse" style=""> <tbody><tr><th class="navbox-title" colspan="2" style=""><div style="float:left; width:6em; text-align:left"><div class="noprint plainlinks nowrap tnavbar" style="padding:0; font-size:xx-small; color:var(--color-emphasized, #000000);"><a href="/wiki/Mod%C3%A8le:Palette_Compos%C3%A9s_du_nickel" title="Modèle:Palette Composés du nickel"><abbr class="abbr" title="Voir ce modèle.">v</abbr></a>&#160;· <a class="external text" href="https://fr.wikipedia.org/w/index.php?title=Mod%C3%A8le:Palette_Compos%C3%A9s_du_nickel&amp;action=edit"><abbr class="abbr" title="Modifier ce modèle. Merci de prévisualiser avant de sauvegarder.">m</abbr></a></div></div><div style="font-size:110%"><a href="/wiki/Liste_de_compos%C3%A9s_inorganiques_N#Nickel" title="Liste de composés inorganiques N">Composés</a> du <a href="/wiki/Nickel" title="Nickel">nickel</a></div></th> </tr> <tr> <th class="navbox-group" style="width:40px">Ni(0)</th> <td class="navbox-list" style=""><div class="liste-horizontale"> <ul><li><a href="/wiki/T%C3%A9tracarbonyle_de_nickel" title="Tétracarbonyle de nickel">Ni(CO)<sub>4</sub></a></li> <li><a href="/wiki/Bis(1,5-cyclooctadi%C3%A8ne)nickel" title="Bis(1,5-cyclooctadiène)nickel">Ni(COD)<sub>2</sub></a></li></ul> </div></td> </tr> <tr> <th class="navbox-group" style="width:40px">Ni(II)</th> <td class="navbox-list navbox-even" style=""><div class="liste-horizontale"> <ul><li><a href="/w/index.php?title=Bromure_de_nickel(II)&amp;action=edit&amp;redlink=1" class="new" title="Bromure de nickel(II) (page inexistante)">NiBr<sub>2</sub></a></li> <li><a href="/wiki/Carbonate_de_nickel(II)" title="Carbonate de nickel(II)">NiCO<sub>3</sub></a></li> <li><a href="/wiki/Chlorure_de_nickel(II)" title="Chlorure de nickel(II)">NiCl<sub>2</sub></a></li> <li><a href="/w/index.php?title=Chromate_de_nickel&amp;action=edit&amp;redlink=1" class="new" title="Chromate de nickel (page inexistante)">NiCrO<sub>4</sub></a></li> <li><a href="/wiki/Fluorure_de_nickel(II)" title="Fluorure de nickel(II)">NiF<sub>2</sub></a></li> <li><a href="/wiki/Iodure_de_nickel(II)" title="Iodure de nickel(II)">NiI<sub>2</sub></a></li> <li><a href="/w/index.php?title=Nitrite_de_nickel(II)&amp;action=edit&amp;redlink=1" class="new" title="Nitrite de nickel(II) (page inexistante)">Ni(NO<sub>2</sub>)<sub>2</sub></a></li> <li><a href="/w/index.php?title=Nitrate_de_nickel(II)&amp;action=edit&amp;redlink=1" class="new" title="Nitrate de nickel(II) (page inexistante)">Ni(NO<sub>3</sub>)<sub>2</sub></a></li> <li><a href="/wiki/Oxyde_de_nickel(II)" title="Oxyde de nickel(II)">NiO</a></li> <li><a class="mw-selflink selflink">Ni(OH)<sub>2</sub></a></li> <li><a href="/wiki/Sulfure_de_nickel" title="Sulfure de nickel">NiS</a></li> <li><a href="/wiki/Sulfate_de_nickel(II)" title="Sulfate de nickel(II)">NiSO<sub>4</sub></a></li> <li><a href="/w/index.php?title=Titanate_de_nickel(II)&amp;action=edit&amp;redlink=1" class="new" title="Titanate de nickel(II) (page inexistante)">NiTiO<sub>3</sub></a></li></ul> </div></td> </tr> <tr> <th class="navbox-group" style="width:40px">Ni(III)</th> <td class="navbox-list" style=""><div class="liste-horizontale"> <ul><li><a href="/wiki/Oxyde_de_nickel(III)" title="Oxyde de nickel(III)">Ni<sub>2</sub>O<sub>3</sub></a></li> <li><a href="/wiki/Oxyhydroxyde_de_nickel" title="Oxyhydroxyde de nickel">NiOHO</a></li></ul> </div></td> </tr> <tr> <th class="navbox-group" style="width:40px">Ni(IV)</th> <td class="navbox-list navbox-even" style=""><div class="liste-horizontale"> <ul><li><a href="/wiki/Hexafluoronick%C3%A9late(IV)_de_potassium" title="Hexafluoronickélate(IV) de potassium">K<sub>2</sub>NiF<sub>6</sub></a></li> <li><a href="/wiki/Oxyde_de_nickel(IV)" title="Oxyde de nickel(IV)">NiO<sub>2</sub></a></li></ul> </div></td> </tr> </tbody></table> <table class="navbox collapsible noprint autocollapse" style=""> <tbody><tr><th class="navbox-title" colspan="2" style=""><div style="float:left; width:6em; text-align:left"><div class="noprint plainlinks nowrap tnavbar" style="padding:0; font-size:xx-small; color:var(--color-emphasized, #000000);"><a href="/wiki/Mod%C3%A8le:Palette_Hydroxydes" title="Modèle:Palette Hydroxydes"><abbr class="abbr" title="Voir ce modèle.">v</abbr></a>&#160;· <a class="external text" href="https://fr.wikipedia.org/w/index.php?title=Mod%C3%A8le:Palette_Hydroxydes&amp;action=edit"><abbr class="abbr" title="Modifier ce modèle. Merci de prévisualiser avant de sauvegarder.">m</abbr></a></div></div><div style="font-size:110%"><a href="/wiki/Hydroxyde" title="Hydroxyde">Hydroxydes</a></div></th> </tr> <tr> <td class="navbox-list" style="text-align:center;" colspan="2"><div class="liste-horizontale"> <ul><li><a href="/wiki/Hydroxyde_d%27argent(I)" title="Hydroxyde d&#39;argent(I)">AgOH</a></li> <li><a href="/wiki/Hydroxyde_d%27aluminium" title="Hydroxyde d&#39;aluminium">Al(OH)<sub>3</sub></a></li> <li><a href="/wiki/Hydroxyde_d%27or(III)" title="Hydroxyde d&#39;or(III)">Au(OH)<sub>3</sub></a></li> <li><a href="/wiki/Hydroxyde_de_bore" class="mw-redirect" title="Hydroxyde de bore">B(OH)<sub>3</sub></a></li> <li><a href="/wiki/Hydroxyde_de_baryum" title="Hydroxyde de baryum">Ba(OH)<sub>2</sub></a></li> <li><a href="/wiki/Hydroxyde_de_b%C3%A9ryllium" title="Hydroxyde de béryllium">Be(OH)<sub>2</sub></a></li> <li><a href="/wiki/Hydroxyde_de_bismuth" title="Hydroxyde de bismuth">Bi(OH)<sub>3</sub></a></li> <li><a href="/wiki/Hydroxyde_de_calcium" title="Hydroxyde de calcium">Ca(OH)<sub>2</sub></a></li> <li><a href="/wiki/Hydroxyde_de_cadmium" title="Hydroxyde de cadmium">Cd(OH)<sub>2</sub></a></li> <li><a href="/wiki/Hydroxyde_de_curium" title="Hydroxyde de curium">Cm(OH)<sub>3</sub></a></li> <li><a href="/wiki/Hydroxyde_de_cobalt(II)" title="Hydroxyde de cobalt(II)">Co(OH)<sub>2</sub></a></li> <li><a href="/w/index.php?title=Hydroxyde_de_cobalt(III)&amp;action=edit&amp;redlink=1" class="new" title="Hydroxyde de cobalt(III) (page inexistante)">Co(OH)<sub>3</sub></a></li> <li><a href="/wiki/Hydroxyde_de_chrome(III)" title="Hydroxyde de chrome(III)">Cr(OH)<sub>3</sub></a></li> <li><a href="/wiki/Hydroxyde_de_c%C3%A9sium" title="Hydroxyde de césium">CsOH</a></li> <li><a href="/wiki/Hydroxyde_de_cuivre(I)" title="Hydroxyde de cuivre(I)">Cu(OH)</a></li> <li><a href="/wiki/Hydroxyde_de_cuivre(II)" title="Hydroxyde de cuivre(II)">Cu(OH)<sub>2</sub></a></li> <li><a href="/wiki/Hydroxyde_de_fer(II)" title="Hydroxyde de fer(II)">Fe(OH)<sub>2</sub></a></li> <li><a href="/wiki/Hydroxyde_de_fer(III)" title="Hydroxyde de fer(III)">Fe(OH)<sub>3</sub></a></li> <li><a href="/wiki/Hydroxyde_de_gallium(III)" title="Hydroxyde de gallium(III)">Ga(OH)<sub>3</sub></a></li> <li><a href="/wiki/Hydroxyde_de_germanium(II)" title="Hydroxyde de germanium(II)">Ge(OH)<sub>2</sub></a></li> <li><a href="/wiki/Mol%C3%A9cule_d%27eau" title="Molécule d&#39;eau">H<sub>2</sub>O</a></li> <li><a href="/wiki/Hydroxyde_d%27indium(III)" title="Hydroxyde d&#39;indium(III)">In(OH)<sub>3</sub></a></li> <li><a href="/wiki/Hydroxyde_de_potassium" title="Hydroxyde de potassium">KOH</a></li> <li><a href="/wiki/Hydroxyde_de_lanthane" title="Hydroxyde de lanthane">La(OH)<sub>3</sub></a></li> <li><a href="/wiki/Hydroxyde_de_lithium" title="Hydroxyde de lithium">LiOH</a></li> <li><a href="/wiki/Hydroxyde_de_magn%C3%A9sium" title="Hydroxyde de magnésium">Mg(OH)<sub>2</sub></a></li> <li><a href="/wiki/Hydroxyde_de_mangan%C3%A8se(II)" title="Hydroxyde de manganèse(II)">Mn(OH)<sub>2</sub></a></li> <li><a href="/wiki/Hydroxyde_de_sodium" title="Hydroxyde de sodium">NaOH</a></li> <li><a class="mw-selflink selflink">Ni(OH)<sub>2</sub></a></li> <li><a href="/wiki/Hydroxyde_de_plomb(II)" title="Hydroxyde de plomb(II)">Pb(OH)<sub>2</sub></a></li> <li><a href="/wiki/Hydroxyde_de_rubidium" title="Hydroxyde de rubidium">RbOH</a></li> <li><a href="/wiki/Hydroxyde_de_rhodium(III)" title="Hydroxyde de rhodium(III)">Rh(OH)<sub>3</sub></a></li> <li><a href="/wiki/Hydroxyde_de_silicium" class="mw-redirect" title="Hydroxyde de silicium">Si(OH)<sub>4</sub></a></li> <li><a href="/w/index.php?title=Hydroxyde_d%27%C3%A9tain(II)&amp;action=edit&amp;redlink=1" class="new" title="Hydroxyde d&#39;étain(II) (page inexistante)">Sn(OH)<sub>2</sub></a></li> <li><a href="/w/index.php?title=Hydroxyde_d%27%C3%A9tain(IV)&amp;action=edit&amp;redlink=1" class="new" title="Hydroxyde d&#39;étain(IV) (page inexistante)">Sn(OH)<sub>4</sub></a></li> <li><a href="/wiki/Hydroxyde_de_strontium" title="Hydroxyde de strontium">Sr(OH)<sub>2</sub></a></li> <li><a href="/wiki/Hydroxyde_de_thallium(I)" title="Hydroxyde de thallium(I)">TlOH</a></li> <li><a href="/w/index.php?title=Hydroxyde_de_thallium(III)&amp;action=edit&amp;redlink=1" class="new" title="Hydroxyde de thallium(III) (page inexistante)">Tl(OH)<sub>3</sub></a></li> <li><a href="/wiki/Hydroxyde_d%27uranyle" title="Hydroxyde d&#39;uranyle">UO<sub>2</sub>(OH)<sub>2</sub></a></li> <li><a href="/wiki/Hydroxyde_de_zinc" title="Hydroxyde de zinc">Zn(OH)<sub>2</sub></a></li> <li><a href="/wiki/Hydroxyde_de_zirconium" title="Hydroxyde de zirconium">Zr(OH)<sub>4</sub></a></li></ul> </div></td> </tr> </tbody></table> </div> <ul id="bandeau-portail" class="bandeau-portail"><li><span class="bandeau-portail-element"><span class="bandeau-portail-icone"><span class="noviewer" typeof="mw:File"><a href="/wiki/Portail:Chimie" title="Portail de la 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