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class="ds2-5-heading-sans-serif-xs">Uploads</h2></div><div class="documents-container backbone-social-profile-documents" style="width: 100%;"><div class="u-taCenter"></div><div class="profile--tab_content_container js-tab-pane tab-pane active" id="all"><div class="profile--tab_heading_container js-section-heading" data-section="Papers" id="Papers"><h3 class="profile--tab_heading_container">Papers by Barbara Sieklucka</h3></div><div class="js-work-strip profile--work_container" data-work-id="103595039"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/103595039/CCDC_1054064_Experimental_Crystal_Structure_Determination"><img alt="Research paper thumbnail of CCDC 1054064: Experimental Crystal Structure Determination" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/103595039/CCDC_1054064_Experimental_Crystal_Structure_Determination">CCDC 1054064: Experimental Crystal Structure Determination</a></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">An entry from the Cambridge Structural Database, the world&#39;s repository for small molecule cr...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">An entry from the Cambridge Structural Database, the world&#39;s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="103595039"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="103595039"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 103595039; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); 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window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=103595035]").text(description); $(".js-view-count[data-work-id=103595035]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 103595035; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='103595035']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=103595035]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":103595035,"title":"ChemInform Abstract: Reactivity and Photoreactivity of Cyanocomplexes of the Transition Metals","internal_url":"https://www.academia.edu/103595035/ChemInform_Abstract_Reactivity_and_Photoreactivity_of_Cyanocomplexes_of_the_Transition_Metals","owner_id":245277346,"coauthors_can_edit":true,"owner":{"id":245277346,"first_name":"Barbara","middle_initials":null,"last_name":"Sieklucka","page_name":"BSieklucka","domain_name":"independent","created_at":"2022-11-14T02:22:08.495-08:00","display_name":"Barbara Sieklucka","url":"https://independent.academia.edu/BSieklucka"},"attachments":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="103595034"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/103595034/Studies_on_magnetic_properties_of_unique_molecular_magnet_Fe_II_pyrazole_4_2_Nb_IV_CN_8_4H_2_O_n"><img alt="Research paper thumbnail of Studies on magnetic properties of unique molecular magnet {[Fe II (pyrazole) 4 ] 2 [Nb IV (CN) 8 ]∙4H 2 O} n" class="work-thumbnail" src="https://attachments.academia-assets.com/103561372/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/103595034/Studies_on_magnetic_properties_of_unique_molecular_magnet_Fe_II_pyrazole_4_2_Nb_IV_CN_8_4H_2_O_n">Studies on magnetic properties of unique molecular magnet {[Fe II (pyrazole) 4 ] 2 [Nb IV (CN) 8 ]∙4H 2 O} n</a></div><div class="wp-workCard_item"><span>EPJ Web of Conferences</span><span>, 2013</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">In this paper magnetic properties of hybrid inorganic-organic compound {[Fe II (pyrazole) 4 ] 2 [...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">In this paper magnetic properties of hybrid inorganic-organic compound {[Fe II (pyrazole) 4 ] 2 [Nb IV (CN) 8 ]•4H 2 O} n are presented. This is a three dimensional molecular magnet with well localized magnetic moments, which make it a suitable candidate for testing magnetic models. In order to characterize the magnetic properties of the above compound we performed the AC/DC magnetometry in the range 0-5 T. The special attention was paid to the phase transition at 7.9 K. The study in magnetic field supports magnetic ordering below 7.9 K.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="25bfb8b9a153b60883403f92061603ba" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":103561372,"asset_id":103595034,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/103561372/download_file?s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="103595034"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="103595034"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 103595034; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=103595034]").text(description); $(".js-view-count[data-work-id=103595034]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 103595034; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='103595034']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "25bfb8b9a153b60883403f92061603ba" } } $('.js-work-strip[data-work-id=103595034]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":103595034,"title":"Studies on magnetic properties of unique molecular magnet {[Fe II (pyrazole) 4 ] 2 [Nb IV (CN) 8 ]∙4H 2 O} n","internal_url":"https://www.academia.edu/103595034/Studies_on_magnetic_properties_of_unique_molecular_magnet_Fe_II_pyrazole_4_2_Nb_IV_CN_8_4H_2_O_n","owner_id":245277346,"coauthors_can_edit":true,"owner":{"id":245277346,"first_name":"Barbara","middle_initials":null,"last_name":"Sieklucka","page_name":"BSieklucka","domain_name":"independent","created_at":"2022-11-14T02:22:08.495-08:00","display_name":"Barbara Sieklucka","url":"https://independent.academia.edu/BSieklucka"},"attachments":[{"id":103561372,"title":"","file_type":"pdf","scribd_thumbnail_url":"https://attachments.academia-assets.com/103561372/thumbnails/1.jpg","file_name":"3225171efd1949394228932c5b0cec90b724.pdf","download_url":"https://www.academia.edu/attachments/103561372/download_file","bulk_download_file_name":"Studies_on_magnetic_properties_of_unique.pdf","bulk_download_url":"https://d1wqtxts1xzle7.cloudfront.net/103561372/3225171efd1949394228932c5b0cec90b724-libre.pdf?1687238493=\u0026response-content-disposition=attachment%3B+filename%3DStudies_on_magnetic_properties_of_unique.pdf\u0026Expires=1741320397\u0026Signature=EWg4WSP7CKLDaajtQMhmwdWrovt8byGzvFhvaWMkiPo2z89yVb-GJN2sMcRl5hGDtOg1YCPdnV79xWREsBrZsB1oOeAor~1-Wu5uTQH2KByx5Pt2hvhQGnHW~MRk0x0tbnSp7HS9QgmSzCiXfxc~mmgyZiHbdV7G7JBtMahKPiN4g0z39hXqK5Ua8VBnfnoK06gtPi4FZBVBy3~0fOlHJmIURdqsUFLkxH7WVw3ltt3LB9HhtSKDqlWHaTqhJnRguPFg0hqjBgrhWqkHDzFrRHZFUWxYo7HdrDQcFq9Muw-pfzjsrl7FiAY8okzqAzBASY0bxTrs2CxeS2dsVIySoQ__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA"}]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="103595032"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/103595032/New_donor_acceptor_system_based_on_Pt_NH3_4_2_and_W_CN_8_3_ions"><img alt="Research paper thumbnail of New donor–acceptor system based on [Pt(NH3)4]2+ and [W(CN)8]3− ions" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/103595032/New_donor_acceptor_system_based_on_Pt_NH3_4_2_and_W_CN_8_3_ions">New donor–acceptor system based on [Pt(NH3)4]2+ and [W(CN)8]3− ions</a></div><div class="wp-workCard_item"><span>Journal of the Chemical Society, Dalton Transactions</span><span>, 1997</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">A new donor–acceptor system based on [Pt(NH 3 ) 4 ] 2+ and [W(CN) 8 ] 3- has been characterized i...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">A new donor–acceptor system based on [Pt(NH 3 ) 4 ] 2+ and [W(CN) 8 ] 3- has been characterized in aqueous solution and the solid state by spectroscopic and electrochemical techniques. In aqueous solution the 1∶1 ion pair {[Pt(NH 3 ) 4 ] 2+ ,[W(CN) 8 ] 3- } exhibits an outer-sphere metal-to-metal charge-transfer transition at 485 nm (e = 49 ± 2 dm 3 mol -1 cm -1 ) with association constant K A = 26 ± 3 dm 3 mol -1 at I = 0.45 mol dm -3 (KNO 3 ) and 298 K. Electrochemical measurements revealed a [W(CN) 8 ] 3-/4- reversible couple at +0.27 V (vs. saturated calomel electrode) in 0.1 mol dm -3 KNO 3 for the novel ion pair. The {[Pt(NH 3 ) 4 ] 2+ ,[W(CN) 8 ] 3- } system is paramagnetic in aqueous solution (g iso = 1.96 at 293 K). The results are interpreted using Hush theory (coupling parameters α 2 = 1.69 × 10 -4 and H if = 268 cm -1 , reorganization energy for the optical electron-transfer process χ = 164.6 kJ mol -1 , thermal activation barrier E th = 92.4 kJ mol -1 and electron-transfer rate constant k et = 3.3 × 10 -4 s -1 ) and compared with the corresponding parameters for other [M(CN) n ] 3-/4- couples. The bimetallic Pt–W system has been isolated in the solid state as [Pt(NH 3 ) 4 ] 2 [W(CN) 8 ][NO 3 ]·2H 2 O. The complex is paramagnetic (at 293 K g iso = 1.97; at 77 K g ⊥ = 1.96, g || = 1.98).</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="103595032"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="103595032"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 103595032; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=103595032]").text(description); $(".js-view-count[data-work-id=103595032]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 103595032; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='103595032']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=103595032]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":103595032,"title":"New donor–acceptor system based on [Pt(NH3)4]2+ and [W(CN)8]3− ions","internal_url":"https://www.academia.edu/103595032/New_donor_acceptor_system_based_on_Pt_NH3_4_2_and_W_CN_8_3_ions","owner_id":245277346,"coauthors_can_edit":true,"owner":{"id":245277346,"first_name":"Barbara","middle_initials":null,"last_name":"Sieklucka","page_name":"BSieklucka","domain_name":"independent","created_at":"2022-11-14T02:22:08.495-08:00","display_name":"Barbara Sieklucka","url":"https://independent.academia.edu/BSieklucka"},"attachments":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="103595030"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/103595030/Kinetics_and_mechanisms_of_the_oxidation_of_the_octacyanoniobate_III_ion_by_oxyanions_in_alkaline_aqueous_media"><img alt="Research paper thumbnail of Kinetics and mechanisms of the oxidation of the octacyanoniobate(III)ion by oxyanions in alkaline aqueous media" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/103595030/Kinetics_and_mechanisms_of_the_oxidation_of_the_octacyanoniobate_III_ion_by_oxyanions_in_alkaline_aqueous_media">Kinetics and mechanisms of the oxidation of the octacyanoniobate(III)ion by oxyanions in alkaline aqueous media</a></div><div class="wp-workCard_item"><span>Transition Metal Chemistry</span><span>, 1996</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">SummaryThe kinetics and mechanisms of the oxidation of Nb(CN)inf8sup5−by the oxyanions S2Oinf8sup...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">SummaryThe kinetics and mechanisms of the oxidation of Nb(CN)inf8sup5−by the oxyanions S2Oinf8sup2−, BrOinf3sup−, and IOinf4sup−have been investigated in alkaline aqueous media (pH 12). The second-order rate constant for the electron transfer reaction between Nb(CN)inf8sup5−and S2Oinf8sup2−at 25.0 °C, I = 0.36m (K+), is 11.1± 0.3 m−1s−1 with ΔH‡ = 30 ± 2kJmol−1 and ΔS‡ = - 125 + 7JK−1 mol−1. The rate constant for the oxidation of Nb(CN)inf8sup5−by BrOinf3sup−at 25.0 °C, I = 0.20m (Na+), is 2.39 ± 0.08m−1s−1 with ΔH‡ = 28 ± 2kJmol−1 and ΔS‡ = -139 ± 7JK−1mol−1. The oxidation of Nb(CN)inf8sup5−by IOinf4sup−proceeds by two parallel pathways involving the monomeric IOinf4sup−ion and the hydrated dimer H2I2Oinf10sup4−. The second-order rate constant for the oxidation of Nb(CN)inf8sup5−by monomeric IOinf4sup−at 5.0 °C, I = 0.050m (Na+), is (3.3 ± 0.6) × 103m−1s−1 with ΔH‡ = 75 ± 6 kJ mol−1 and ΔS‡ = 94 ± 15 J K−1 mol−1, while the rate constant for the oxidation by H2I2Oinf10sup4−is (1.8 ± 0.1) × 103m−1s−1 with ΔH‡ = 97 ± 5 kJ mol−1 and ΔS‡ = 166 ± 16 J K−1 mol−1 under the same reaction conditions. The rate constants for each of the oxidants employed display specific cation catalysis with the order of increasing rate constants: Li+ &lt; Na+ &lt; NHinf4sup+&lt; K+ &lt; Rb+ &lt; Cs+, in the same direction as the electronic polarizability of the cations. The results are discussed in terms of the outer-sphere electron-transfer processes and compared with the corresponding data and mechanisms reported for other metal-cyano reductants.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="103595030"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="103595030"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 103595030; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); 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</script> <div class="js-work-strip profile--work_container" data-work-id="103595025"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/103595025/Magnetocaloric_effect_and_critical_behaviour_in_Mn2_pyridazine_Nb_CN_8_molecular_compound_under_pressure"><img alt="Research paper thumbnail of Magnetocaloric effect and critical behaviour in Mn2–pyridazine–[Nb(CN)8] molecular compound under pressure" class="work-thumbnail" src="https://attachments.academia-assets.com/103561370/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/103595025/Magnetocaloric_effect_and_critical_behaviour_in_Mn2_pyridazine_Nb_CN_8_molecular_compound_under_pressure">Magnetocaloric effect and critical behaviour in Mn2–pyridazine–[Nb(CN)8] molecular compound under pressure</a></div><div class="wp-workCard_item"><span>Journal of Physics: Condensed Matter</span><span>, 2013</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">This is a PDF file of an article that has undergone enhancements after acceptance, such as the ad...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">This is a PDF file of an article that has undergone enhancements after acceptance, such as the addition of a cover page and metadata, and formatting for readability, but it is not yet the definitive version of record. 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="103595019"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/103595019/Photoreactivity_of_octacyanotungstate_V_ion_in_non_aqueous_solvents"><img alt="Research paper thumbnail of Photoreactivity of octacyanotungstate(V) ion in non-aqueous solvents" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/103595019/Photoreactivity_of_octacyanotungstate_V_ion_in_non_aqueous_solvents">Photoreactivity of octacyanotungstate(V) ion in non-aqueous solvents</a></div><div class="wp-workCard_item"><span>Inorganica Chimica Acta</span><span>, 1991</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">Abstract The CTTM photolysis of (TBA) 3 W(CN) 8 has been studied in MeOH, MeCN, DMF and Me 2 SO. ...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">Abstract The CTTM photolysis of (TBA) 3 W(CN) 8 has been studied in MeOH, MeCN, DMF and Me 2 SO. The quantum yields for the photochemical decomposition of W(CN) 8 3− are 0.50∓0.02, 0.46∓0.01, 0.42∓0.02 and 0.29∓0.03 in MeOH, MeCN, DMF and Me 2 SO, respectively. The detection of products has proved that photolysis induces a cyano ligand photolabilization in high quantum yield (φ CN− 0.33 in Me 2 SO) concomitant with photoproduction of W(VI) species. The process has been associated with the efficient population of LF excited state via internal conversion from CTTM excited state, leading to photolabilization and followed by inner-sphere redox process between generated reactive W(CN) 7 2− and parent W(CN) 8 3− according to W(CN) 7 2− +W(CN) 8 3− →(NC) 7 W V NCW V (CN) 7 5− →(NC) 7 W VI NCW IV (CN) 7 5− → W(CN) 7 − +W(CN) 8 4− , affording W VI (CN) 7 − as the dominant photoproduct.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="103595019"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="103595019"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 103595019; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=103595019]").text(description); $(".js-view-count[data-work-id=103595019]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 103595019; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='103595019']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); 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window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=103595015]").text(description); $(".js-view-count[data-work-id=103595015]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 103595015; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='103595015']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=103595015]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":103595015,"title":"XPS evidence for the photoproduction of tungsten(VI) cyano complexes in charge-transfer photochemistry of W(CN)83− ion in non-aqueous solvents","internal_url":"https://www.academia.edu/103595015/XPS_evidence_for_the_photoproduction_of_tungsten_VI_cyano_complexes_in_charge_transfer_photochemistry_of_W_CN_83_ion_in_non_aqueous_solvents","owner_id":245277346,"coauthors_can_edit":true,"owner":{"id":245277346,"first_name":"Barbara","middle_initials":null,"last_name":"Sieklucka","page_name":"BSieklucka","domain_name":"independent","created_at":"2022-11-14T02:22:08.495-08:00","display_name":"Barbara Sieklucka","url":"https://independent.academia.edu/BSieklucka"},"attachments":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="103594995"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/103594995/Reactivity_and_Photoreactivity_of_Cyanocomplexes_of_the_Transition_Metals"><img alt="Research paper thumbnail of Reactivity and Photoreactivity of Cyanocomplexes of the Transition Metals" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/103594995/Reactivity_and_Photoreactivity_of_Cyanocomplexes_of_the_Transition_Metals">Reactivity and Photoreactivity of Cyanocomplexes of the Transition Metals</a></div><div class="wp-workCard_item"><span>Progress in Reaction Kinetics and Mechanism</span><span>, 1999</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">The reactivity and photoreactivity of cyano complexes remain the subjects of extensive research. ...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">The reactivity and photoreactivity of cyano complexes remain the subjects of extensive research. The thermal processes of these systems are characterised by substitution reactions of M(CN)5Ln- and M(CN)4(H2O)Xn- ions as well as by formation of binuclear systems with homoleptic cyano complexes acting as the ligands. The redox processes involve electron self-exchange reactions of homoleptic cyano complexes, and electron transfer reactions with metal complexes, small inorganic species and organic compounds. The photophysical and photochemical behaviour of cyano complexes is characterised by energy and electron transfer processes, photosubstitution and photoredox reactions of monomeric and polynuclear cyano-bridged systems. The aim of this review article is to provide a survey of the literature on the kinetics of thermal and photochemical reactions of cyano complexes over the last ten years.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="103594995"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="103594995"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 103594995; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="100133164"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/100133164/Dehydration_Triggered_Charge_Transfer_and_High_Proton_Conductivity_in_H3O_NiIII_cyclam_MII_CN_6_M_Ru_Os_Cyanide_Bridged_Chains"><img alt="Research paper thumbnail of Dehydration-Triggered Charge Transfer and High Proton Conductivity in (H3O)[NiIII(cyclam)][MII(CN)6] (M = Ru, Os) Cyanide-Bridged Chains" class="work-thumbnail" src="https://attachments.academia-assets.com/101038539/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/100133164/Dehydration_Triggered_Charge_Transfer_and_High_Proton_Conductivity_in_H3O_NiIII_cyclam_MII_CN_6_M_Ru_Os_Cyanide_Bridged_Chains">Dehydration-Triggered Charge Transfer and High Proton Conductivity in (H3O)[NiIII(cyclam)][MII(CN)6] (M = Ru, Os) Cyanide-Bridged Chains</a></div><div class="wp-workCard_item"><span>Inorganic Chemistry</span><span>, 2018</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">The coexistence of dehydration-driven charge transfer, magnetic interactions, and high proton con...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">The coexistence of dehydration-driven charge transfer, magnetic interactions, and high proton conductivity was found in two bimetallic alternating CN-bridged chains {(H 3 O)[Ni III (cyclam)][M II (CN) 6 ]•5H 2 O} n (M = Ru (1), Os (2); cyclam = 1,4,8,11-tetraazacyclotetradecane). Dehydration of these materials causes structural transformation and triggers charge transfer between the metal centers: Ni III −NC−M II → Ni II −NC−M III. The CT process, whose extent is tuned by the change of the anionic building block, causes significant increase of magnetic moment, appearance of antiferromagnetic interactions, and noticeable changes in color. The high conductivity values of σ = 1.09 × 10 −3 (1) and 1.12 × 10 −3 S cm −1 (2) at 295 K and 100% relative humidity allow the classification of the materials as superionic conductors. The proton conduction occurs according to the Grotthuss mechanism as a hopping of protons between H-bonded water molecules due to the presence of the H 3 O + ions, which compensate negative charge of the coordination chains.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="5e0448d5b386c916e40152ba4c745d1c" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":101038539,"asset_id":100133164,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/101038539/download_file?s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="100133164"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="100133164"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 100133164; 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The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="90730354"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="90730354"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 90730354; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=90730354]").text(description); $(".js-view-count[data-work-id=90730354]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 90730354; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='90730354']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=90730354]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":90730354,"title":"CCDC 673225: Experimental Crystal Structure Determination","internal_url":"https://www.academia.edu/90730354/CCDC_673225_Experimental_Crystal_Structure_Determination","owner_id":245277346,"coauthors_can_edit":true,"owner":{"id":245277346,"first_name":"Barbara","middle_initials":null,"last_name":"Sieklucka","page_name":"BSieklucka","domain_name":"independent","created_at":"2022-11-14T02:22:08.495-08:00","display_name":"Barbara Sieklucka","url":"https://independent.academia.edu/BSieklucka"},"attachments":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="90730352"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/90730352/CCDC_809865_Experimental_Crystal_Structure_Determination"><img alt="Research paper thumbnail of CCDC 809865: Experimental Crystal Structure Determination" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/90730352/CCDC_809865_Experimental_Crystal_Structure_Determination">CCDC 809865: Experimental Crystal Structure Determination</a></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">An entry from the Cambridge Structural Database, the world&#39;s repository for small molecule cr...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">An entry from the Cambridge Structural Database, the world&#39;s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="90730352"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="90730352"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 90730352; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=90730352]").text(description); $(".js-view-count[data-work-id=90730352]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 90730352; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='90730352']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=90730352]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":90730352,"title":"CCDC 809865: Experimental Crystal Structure Determination","internal_url":"https://www.academia.edu/90730352/CCDC_809865_Experimental_Crystal_Structure_Determination","owner_id":245277346,"coauthors_can_edit":true,"owner":{"id":245277346,"first_name":"Barbara","middle_initials":null,"last_name":"Sieklucka","page_name":"BSieklucka","domain_name":"independent","created_at":"2022-11-14T02:22:08.495-08:00","display_name":"Barbara Sieklucka","url":"https://independent.academia.edu/BSieklucka"},"attachments":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="90730350"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/90730350/Towards_rationalizing_photoswitchable_behavior_of_Cu2IIMoIV_cyanido_bridged_molecule"><img alt="Research paper thumbnail of Towards rationalizing photoswitchable behavior of Cu2IIMoIV cyanido-bridged molecule" class="work-thumbnail" src="https://attachments.academia-assets.com/94212366/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/90730350/Towards_rationalizing_photoswitchable_behavior_of_Cu2IIMoIV_cyanido_bridged_molecule">Towards rationalizing photoswitchable behavior of Cu2IIMoIV cyanido-bridged molecule</a></div><div class="wp-workCard_item"><span>Journal of Magnetism and Magnetic Materials</span><span>, 2021</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">[Cu II (enpnen)] 2 [Mo IV (CN) 8 ]•7H 2 O (enpnen = N,N ′-bis(2-aminoethyl)-1,3-propanediamine) m...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">[Cu II (enpnen)] 2 [Mo IV (CN) 8 ]•7H 2 O (enpnen = N,N ′-bis(2-aminoethyl)-1,3-propanediamine) molecular cluster compound was subject to a series of irradiations with the light of 405 nm. On irradiation isothermal magnetization at 1.8 and 5 K in the field range 0-70 kOe as well as magnetic susceptibility in the temperature range of 2-300 K were subsequently detected. Both types of magnetic signals were next ana</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="4a91913bea4ebfb4f94bf1d1c06c3b01" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":94212366,"asset_id":90730350,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/94212366/download_file?s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="90730350"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="90730350"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 90730350; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=90730350]").text(description); $(".js-view-count[data-work-id=90730350]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 90730350; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='90730350']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="90730345"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/90730345/Octacyanidorhenate_V_Ion_as_an_Efficient_Linker_for_Hysteretic_Two_Step_Iron_II_Spin_Crossover_Switchable_by_Temperature_Light_and_Pressure"><img alt="Research paper thumbnail of Octacyanidorhenate(V) Ion as an Efficient Linker for Hysteretic Two‐Step Iron(II) Spin Crossover Switchable by Temperature, Light, and Pressure" class="work-thumbnail" src="https://attachments.academia-assets.com/94212365/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/90730345/Octacyanidorhenate_V_Ion_as_an_Efficient_Linker_for_Hysteretic_Two_Step_Iron_II_Spin_Crossover_Switchable_by_Temperature_Light_and_Pressure">Octacyanidorhenate(V) Ion as an Efficient Linker for Hysteretic Two‐Step Iron(II) Spin Crossover Switchable by Temperature, Light, and Pressure</a></div><div class="wp-workCard_item"><span>Angewandte Chemie International Edition</span><span>, 2020</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">We report the two-step hysteretic Fe(II) spin crossover (SCO) effect achieved in programmed layer...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">We report the two-step hysteretic Fe(II) spin crossover (SCO) effect achieved in programmed layered Cs{[Fe(3-CNpy)2] [Re(CN)8]}•H2O (1) assembly consisting of cyanido-bridged Fe II-Re V square grid sheets bonded by Cs + ions. The presence of two nonequivalent Fe II sites and the conjunction of 2-D bimetallic coordination network with non-covalent interlayer interactions involving Cs + , [Re V (CN)8] 3ions, and 3-CNpy ligands, leads to the occurrence of two steps of thermal SCO with strong cooperativity giving a double thermal hysteresis loop. The resulting spin transition phenomenon could be tuned by an external pressure giving the room temperature range of SCO as well as by visible light irradiation inducing an efficient recovery of the high spin Fe II state at low temperatures. In this report, we prove that octacyanidorhenate(V) ion is an outstanding metalloligand for inducing of cooperative multistep, multi-switchable Fe II SCO effect.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="99cd6a7eca016b0047154cadbf19b862" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":94212365,"asset_id":90730345,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/94212365/download_file?s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="90730345"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="90730345"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 90730345; 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The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="103595039"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="103595039"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 103595039; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); 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dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=103595035]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":103595035,"title":"ChemInform Abstract: Reactivity and Photoreactivity of Cyanocomplexes of the Transition Metals","internal_url":"https://www.academia.edu/103595035/ChemInform_Abstract_Reactivity_and_Photoreactivity_of_Cyanocomplexes_of_the_Transition_Metals","owner_id":245277346,"coauthors_can_edit":true,"owner":{"id":245277346,"first_name":"Barbara","middle_initials":null,"last_name":"Sieklucka","page_name":"BSieklucka","domain_name":"independent","created_at":"2022-11-14T02:22:08.495-08:00","display_name":"Barbara Sieklucka","url":"https://independent.academia.edu/BSieklucka"},"attachments":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="103595034"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/103595034/Studies_on_magnetic_properties_of_unique_molecular_magnet_Fe_II_pyrazole_4_2_Nb_IV_CN_8_4H_2_O_n"><img alt="Research paper thumbnail of Studies on magnetic properties of unique molecular magnet {[Fe II (pyrazole) 4 ] 2 [Nb IV (CN) 8 ]∙4H 2 O} n" class="work-thumbnail" src="https://attachments.academia-assets.com/103561372/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/103595034/Studies_on_magnetic_properties_of_unique_molecular_magnet_Fe_II_pyrazole_4_2_Nb_IV_CN_8_4H_2_O_n">Studies on magnetic properties of unique molecular magnet {[Fe II (pyrazole) 4 ] 2 [Nb IV (CN) 8 ]∙4H 2 O} n</a></div><div class="wp-workCard_item"><span>EPJ Web of Conferences</span><span>, 2013</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">In this paper magnetic properties of hybrid inorganic-organic compound {[Fe II (pyrazole) 4 ] 2 [...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">In this paper magnetic properties of hybrid inorganic-organic compound {[Fe II (pyrazole) 4 ] 2 [Nb IV (CN) 8 ]•4H 2 O} n are presented. This is a three dimensional molecular magnet with well localized magnetic moments, which make it a suitable candidate for testing magnetic models. In order to characterize the magnetic properties of the above compound we performed the AC/DC magnetometry in the range 0-5 T. The special attention was paid to the phase transition at 7.9 K. The study in magnetic field supports magnetic ordering below 7.9 K.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="25bfb8b9a153b60883403f92061603ba" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":103561372,"asset_id":103595034,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/103561372/download_file?s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="103595034"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="103595034"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 103595034; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=103595034]").text(description); $(".js-view-count[data-work-id=103595034]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 103595034; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='103595034']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "25bfb8b9a153b60883403f92061603ba" } } $('.js-work-strip[data-work-id=103595034]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":103595034,"title":"Studies on magnetic properties of unique molecular magnet {[Fe II (pyrazole) 4 ] 2 [Nb IV (CN) 8 ]∙4H 2 O} n","internal_url":"https://www.academia.edu/103595034/Studies_on_magnetic_properties_of_unique_molecular_magnet_Fe_II_pyrazole_4_2_Nb_IV_CN_8_4H_2_O_n","owner_id":245277346,"coauthors_can_edit":true,"owner":{"id":245277346,"first_name":"Barbara","middle_initials":null,"last_name":"Sieklucka","page_name":"BSieklucka","domain_name":"independent","created_at":"2022-11-14T02:22:08.495-08:00","display_name":"Barbara Sieklucka","url":"https://independent.academia.edu/BSieklucka"},"attachments":[{"id":103561372,"title":"","file_type":"pdf","scribd_thumbnail_url":"https://attachments.academia-assets.com/103561372/thumbnails/1.jpg","file_name":"3225171efd1949394228932c5b0cec90b724.pdf","download_url":"https://www.academia.edu/attachments/103561372/download_file","bulk_download_file_name":"Studies_on_magnetic_properties_of_unique.pdf","bulk_download_url":"https://d1wqtxts1xzle7.cloudfront.net/103561372/3225171efd1949394228932c5b0cec90b724-libre.pdf?1687238493=\u0026response-content-disposition=attachment%3B+filename%3DStudies_on_magnetic_properties_of_unique.pdf\u0026Expires=1741320397\u0026Signature=EWg4WSP7CKLDaajtQMhmwdWrovt8byGzvFhvaWMkiPo2z89yVb-GJN2sMcRl5hGDtOg1YCPdnV79xWREsBrZsB1oOeAor~1-Wu5uTQH2KByx5Pt2hvhQGnHW~MRk0x0tbnSp7HS9QgmSzCiXfxc~mmgyZiHbdV7G7JBtMahKPiN4g0z39hXqK5Ua8VBnfnoK06gtPi4FZBVBy3~0fOlHJmIURdqsUFLkxH7WVw3ltt3LB9HhtSKDqlWHaTqhJnRguPFg0hqjBgrhWqkHDzFrRHZFUWxYo7HdrDQcFq9Muw-pfzjsrl7FiAY8okzqAzBASY0bxTrs2CxeS2dsVIySoQ__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA"}]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="103595032"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/103595032/New_donor_acceptor_system_based_on_Pt_NH3_4_2_and_W_CN_8_3_ions"><img alt="Research paper thumbnail of New donor–acceptor system based on [Pt(NH3)4]2+ and [W(CN)8]3− ions" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/103595032/New_donor_acceptor_system_based_on_Pt_NH3_4_2_and_W_CN_8_3_ions">New donor–acceptor system based on [Pt(NH3)4]2+ and [W(CN)8]3− ions</a></div><div class="wp-workCard_item"><span>Journal of the Chemical Society, Dalton Transactions</span><span>, 1997</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">A new donor–acceptor system based on [Pt(NH 3 ) 4 ] 2+ and [W(CN) 8 ] 3- has been characterized i...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">A new donor–acceptor system based on [Pt(NH 3 ) 4 ] 2+ and [W(CN) 8 ] 3- has been characterized in aqueous solution and the solid state by spectroscopic and electrochemical techniques. In aqueous solution the 1∶1 ion pair {[Pt(NH 3 ) 4 ] 2+ ,[W(CN) 8 ] 3- } exhibits an outer-sphere metal-to-metal charge-transfer transition at 485 nm (e = 49 ± 2 dm 3 mol -1 cm -1 ) with association constant K A = 26 ± 3 dm 3 mol -1 at I = 0.45 mol dm -3 (KNO 3 ) and 298 K. Electrochemical measurements revealed a [W(CN) 8 ] 3-/4- reversible couple at +0.27 V (vs. saturated calomel electrode) in 0.1 mol dm -3 KNO 3 for the novel ion pair. The {[Pt(NH 3 ) 4 ] 2+ ,[W(CN) 8 ] 3- } system is paramagnetic in aqueous solution (g iso = 1.96 at 293 K). The results are interpreted using Hush theory (coupling parameters α 2 = 1.69 × 10 -4 and H if = 268 cm -1 , reorganization energy for the optical electron-transfer process χ = 164.6 kJ mol -1 , thermal activation barrier E th = 92.4 kJ mol -1 and electron-transfer rate constant k et = 3.3 × 10 -4 s -1 ) and compared with the corresponding parameters for other [M(CN) n ] 3-/4- couples. The bimetallic Pt–W system has been isolated in the solid state as [Pt(NH 3 ) 4 ] 2 [W(CN) 8 ][NO 3 ]·2H 2 O. The complex is paramagnetic (at 293 K g iso = 1.97; at 77 K g ⊥ = 1.96, g || = 1.98).</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="103595032"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="103595032"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 103595032; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=103595032]").text(description); $(".js-view-count[data-work-id=103595032]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 103595032; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='103595032']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=103595032]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":103595032,"title":"New donor–acceptor system based on [Pt(NH3)4]2+ and [W(CN)8]3− ions","internal_url":"https://www.academia.edu/103595032/New_donor_acceptor_system_based_on_Pt_NH3_4_2_and_W_CN_8_3_ions","owner_id":245277346,"coauthors_can_edit":true,"owner":{"id":245277346,"first_name":"Barbara","middle_initials":null,"last_name":"Sieklucka","page_name":"BSieklucka","domain_name":"independent","created_at":"2022-11-14T02:22:08.495-08:00","display_name":"Barbara Sieklucka","url":"https://independent.academia.edu/BSieklucka"},"attachments":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="103595030"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/103595030/Kinetics_and_mechanisms_of_the_oxidation_of_the_octacyanoniobate_III_ion_by_oxyanions_in_alkaline_aqueous_media"><img alt="Research paper thumbnail of Kinetics and mechanisms of the oxidation of the octacyanoniobate(III)ion by oxyanions in alkaline aqueous media" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/103595030/Kinetics_and_mechanisms_of_the_oxidation_of_the_octacyanoniobate_III_ion_by_oxyanions_in_alkaline_aqueous_media">Kinetics and mechanisms of the oxidation of the octacyanoniobate(III)ion by oxyanions in alkaline aqueous media</a></div><div class="wp-workCard_item"><span>Transition Metal Chemistry</span><span>, 1996</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">SummaryThe kinetics and mechanisms of the oxidation of Nb(CN)inf8sup5−by the oxyanions S2Oinf8sup...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">SummaryThe kinetics and mechanisms of the oxidation of Nb(CN)inf8sup5−by the oxyanions S2Oinf8sup2−, BrOinf3sup−, and IOinf4sup−have been investigated in alkaline aqueous media (pH 12). The second-order rate constant for the electron transfer reaction between Nb(CN)inf8sup5−and S2Oinf8sup2−at 25.0 °C, I = 0.36m (K+), is 11.1± 0.3 m−1s−1 with ΔH‡ = 30 ± 2kJmol−1 and ΔS‡ = - 125 + 7JK−1 mol−1. The rate constant for the oxidation of Nb(CN)inf8sup5−by BrOinf3sup−at 25.0 °C, I = 0.20m (Na+), is 2.39 ± 0.08m−1s−1 with ΔH‡ = 28 ± 2kJmol−1 and ΔS‡ = -139 ± 7JK−1mol−1. The oxidation of Nb(CN)inf8sup5−by IOinf4sup−proceeds by two parallel pathways involving the monomeric IOinf4sup−ion and the hydrated dimer H2I2Oinf10sup4−. The second-order rate constant for the oxidation of Nb(CN)inf8sup5−by monomeric IOinf4sup−at 5.0 °C, I = 0.050m (Na+), is (3.3 ± 0.6) × 103m−1s−1 with ΔH‡ = 75 ± 6 kJ mol−1 and ΔS‡ = 94 ± 15 J K−1 mol−1, while the rate constant for the oxidation by H2I2Oinf10sup4−is (1.8 ± 0.1) × 103m−1s−1 with ΔH‡ = 97 ± 5 kJ mol−1 and ΔS‡ = 166 ± 16 J K−1 mol−1 under the same reaction conditions. The rate constants for each of the oxidants employed display specific cation catalysis with the order of increasing rate constants: Li+ &lt; Na+ &lt; NHinf4sup+&lt; K+ &lt; Rb+ &lt; Cs+, in the same direction as the electronic polarizability of the cations. The results are discussed in terms of the outer-sphere electron-transfer processes and compared with the corresponding data and mechanisms reported for other metal-cyano reductants.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="103595030"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="103595030"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 103595030; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); 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</script> <div class="js-work-strip profile--work_container" data-work-id="103595025"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/103595025/Magnetocaloric_effect_and_critical_behaviour_in_Mn2_pyridazine_Nb_CN_8_molecular_compound_under_pressure"><img alt="Research paper thumbnail of Magnetocaloric effect and critical behaviour in Mn2–pyridazine–[Nb(CN)8] molecular compound under pressure" class="work-thumbnail" src="https://attachments.academia-assets.com/103561370/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/103595025/Magnetocaloric_effect_and_critical_behaviour_in_Mn2_pyridazine_Nb_CN_8_molecular_compound_under_pressure">Magnetocaloric effect and critical behaviour in Mn2–pyridazine–[Nb(CN)8] molecular compound under pressure</a></div><div class="wp-workCard_item"><span>Journal of Physics: Condensed Matter</span><span>, 2013</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">This is a PDF file of an article that has undergone enhancements after acceptance, such as the ad...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">This is a PDF file of an article that has undergone enhancements after acceptance, such as the addition of a cover page and metadata, and formatting for readability, but it is not yet the definitive version of record. 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="103595019"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/103595019/Photoreactivity_of_octacyanotungstate_V_ion_in_non_aqueous_solvents"><img alt="Research paper thumbnail of Photoreactivity of octacyanotungstate(V) ion in non-aqueous solvents" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/103595019/Photoreactivity_of_octacyanotungstate_V_ion_in_non_aqueous_solvents">Photoreactivity of octacyanotungstate(V) ion in non-aqueous solvents</a></div><div class="wp-workCard_item"><span>Inorganica Chimica Acta</span><span>, 1991</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">Abstract The CTTM photolysis of (TBA) 3 W(CN) 8 has been studied in MeOH, MeCN, DMF and Me 2 SO. ...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">Abstract The CTTM photolysis of (TBA) 3 W(CN) 8 has been studied in MeOH, MeCN, DMF and Me 2 SO. The quantum yields for the photochemical decomposition of W(CN) 8 3− are 0.50∓0.02, 0.46∓0.01, 0.42∓0.02 and 0.29∓0.03 in MeOH, MeCN, DMF and Me 2 SO, respectively. The detection of products has proved that photolysis induces a cyano ligand photolabilization in high quantum yield (φ CN− 0.33 in Me 2 SO) concomitant with photoproduction of W(VI) species. The process has been associated with the efficient population of LF excited state via internal conversion from CTTM excited state, leading to photolabilization and followed by inner-sphere redox process between generated reactive W(CN) 7 2− and parent W(CN) 8 3− according to W(CN) 7 2− +W(CN) 8 3− →(NC) 7 W V NCW V (CN) 7 5− →(NC) 7 W VI NCW IV (CN) 7 5− → W(CN) 7 − +W(CN) 8 4− , affording W VI (CN) 7 − as the dominant photoproduct.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="103595019"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="103595019"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 103595019; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=103595019]").text(description); $(".js-view-count[data-work-id=103595019]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 103595019; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='103595019']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); 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window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=103595015]").text(description); $(".js-view-count[data-work-id=103595015]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 103595015; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='103595015']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=103595015]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":103595015,"title":"XPS evidence for the photoproduction of tungsten(VI) cyano complexes in charge-transfer photochemistry of W(CN)83− ion in non-aqueous solvents","internal_url":"https://www.academia.edu/103595015/XPS_evidence_for_the_photoproduction_of_tungsten_VI_cyano_complexes_in_charge_transfer_photochemistry_of_W_CN_83_ion_in_non_aqueous_solvents","owner_id":245277346,"coauthors_can_edit":true,"owner":{"id":245277346,"first_name":"Barbara","middle_initials":null,"last_name":"Sieklucka","page_name":"BSieklucka","domain_name":"independent","created_at":"2022-11-14T02:22:08.495-08:00","display_name":"Barbara Sieklucka","url":"https://independent.academia.edu/BSieklucka"},"attachments":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="103594995"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/103594995/Reactivity_and_Photoreactivity_of_Cyanocomplexes_of_the_Transition_Metals"><img alt="Research paper thumbnail of Reactivity and Photoreactivity of Cyanocomplexes of the Transition Metals" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/103594995/Reactivity_and_Photoreactivity_of_Cyanocomplexes_of_the_Transition_Metals">Reactivity and Photoreactivity of Cyanocomplexes of the Transition Metals</a></div><div class="wp-workCard_item"><span>Progress in Reaction Kinetics and Mechanism</span><span>, 1999</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">The reactivity and photoreactivity of cyano complexes remain the subjects of extensive research. ...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">The reactivity and photoreactivity of cyano complexes remain the subjects of extensive research. The thermal processes of these systems are characterised by substitution reactions of M(CN)5Ln- and M(CN)4(H2O)Xn- ions as well as by formation of binuclear systems with homoleptic cyano complexes acting as the ligands. The redox processes involve electron self-exchange reactions of homoleptic cyano complexes, and electron transfer reactions with metal complexes, small inorganic species and organic compounds. The photophysical and photochemical behaviour of cyano complexes is characterised by energy and electron transfer processes, photosubstitution and photoredox reactions of monomeric and polynuclear cyano-bridged systems. The aim of this review article is to provide a survey of the literature on the kinetics of thermal and photochemical reactions of cyano complexes over the last ten years.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="103594995"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="103594995"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 103594995; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="100133164"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/100133164/Dehydration_Triggered_Charge_Transfer_and_High_Proton_Conductivity_in_H3O_NiIII_cyclam_MII_CN_6_M_Ru_Os_Cyanide_Bridged_Chains"><img alt="Research paper thumbnail of Dehydration-Triggered Charge Transfer and High Proton Conductivity in (H3O)[NiIII(cyclam)][MII(CN)6] (M = Ru, Os) Cyanide-Bridged Chains" class="work-thumbnail" src="https://attachments.academia-assets.com/101038539/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/100133164/Dehydration_Triggered_Charge_Transfer_and_High_Proton_Conductivity_in_H3O_NiIII_cyclam_MII_CN_6_M_Ru_Os_Cyanide_Bridged_Chains">Dehydration-Triggered Charge Transfer and High Proton Conductivity in (H3O)[NiIII(cyclam)][MII(CN)6] (M = Ru, Os) Cyanide-Bridged Chains</a></div><div class="wp-workCard_item"><span>Inorganic Chemistry</span><span>, 2018</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">The coexistence of dehydration-driven charge transfer, magnetic interactions, and high proton con...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">The coexistence of dehydration-driven charge transfer, magnetic interactions, and high proton conductivity was found in two bimetallic alternating CN-bridged chains {(H 3 O)[Ni III (cyclam)][M II (CN) 6 ]•5H 2 O} n (M = Ru (1), Os (2); cyclam = 1,4,8,11-tetraazacyclotetradecane). Dehydration of these materials causes structural transformation and triggers charge transfer between the metal centers: Ni III −NC−M II → Ni II −NC−M III. The CT process, whose extent is tuned by the change of the anionic building block, causes significant increase of magnetic moment, appearance of antiferromagnetic interactions, and noticeable changes in color. The high conductivity values of σ = 1.09 × 10 −3 (1) and 1.12 × 10 −3 S cm −1 (2) at 295 K and 100% relative humidity allow the classification of the materials as superionic conductors. The proton conduction occurs according to the Grotthuss mechanism as a hopping of protons between H-bonded water molecules due to the presence of the H 3 O + ions, which compensate negative charge of the coordination chains.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="5e0448d5b386c916e40152ba4c745d1c" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":101038539,"asset_id":100133164,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/101038539/download_file?s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="100133164"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="100133164"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 100133164; 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The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="90730354"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="90730354"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 90730354; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=90730354]").text(description); $(".js-view-count[data-work-id=90730354]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 90730354; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='90730354']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=90730354]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":90730354,"title":"CCDC 673225: Experimental Crystal Structure Determination","internal_url":"https://www.academia.edu/90730354/CCDC_673225_Experimental_Crystal_Structure_Determination","owner_id":245277346,"coauthors_can_edit":true,"owner":{"id":245277346,"first_name":"Barbara","middle_initials":null,"last_name":"Sieklucka","page_name":"BSieklucka","domain_name":"independent","created_at":"2022-11-14T02:22:08.495-08:00","display_name":"Barbara Sieklucka","url":"https://independent.academia.edu/BSieklucka"},"attachments":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="90730352"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/90730352/CCDC_809865_Experimental_Crystal_Structure_Determination"><img alt="Research paper thumbnail of CCDC 809865: Experimental Crystal Structure Determination" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/90730352/CCDC_809865_Experimental_Crystal_Structure_Determination">CCDC 809865: Experimental Crystal Structure Determination</a></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">An entry from the Cambridge Structural Database, the world&#39;s repository for small molecule cr...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">An entry from the Cambridge Structural Database, the world&#39;s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available from the CCDC and typically includes 3D coordinates, cell parameters, space group, experimental conditions and quality measures.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="90730352"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="90730352"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 90730352; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=90730352]").text(description); $(".js-view-count[data-work-id=90730352]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 90730352; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='90730352']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=90730352]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":90730352,"title":"CCDC 809865: Experimental Crystal Structure Determination","internal_url":"https://www.academia.edu/90730352/CCDC_809865_Experimental_Crystal_Structure_Determination","owner_id":245277346,"coauthors_can_edit":true,"owner":{"id":245277346,"first_name":"Barbara","middle_initials":null,"last_name":"Sieklucka","page_name":"BSieklucka","domain_name":"independent","created_at":"2022-11-14T02:22:08.495-08:00","display_name":"Barbara Sieklucka","url":"https://independent.academia.edu/BSieklucka"},"attachments":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="90730350"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/90730350/Towards_rationalizing_photoswitchable_behavior_of_Cu2IIMoIV_cyanido_bridged_molecule"><img alt="Research paper thumbnail of Towards rationalizing photoswitchable behavior of Cu2IIMoIV cyanido-bridged molecule" class="work-thumbnail" src="https://attachments.academia-assets.com/94212366/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/90730350/Towards_rationalizing_photoswitchable_behavior_of_Cu2IIMoIV_cyanido_bridged_molecule">Towards rationalizing photoswitchable behavior of Cu2IIMoIV cyanido-bridged molecule</a></div><div class="wp-workCard_item"><span>Journal of Magnetism and Magnetic Materials</span><span>, 2021</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">[Cu II (enpnen)] 2 [Mo IV (CN) 8 ]•7H 2 O (enpnen = N,N ′-bis(2-aminoethyl)-1,3-propanediamine) m...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">[Cu II (enpnen)] 2 [Mo IV (CN) 8 ]•7H 2 O (enpnen = N,N ′-bis(2-aminoethyl)-1,3-propanediamine) molecular cluster compound was subject to a series of irradiations with the light of 405 nm. On irradiation isothermal magnetization at 1.8 and 5 K in the field range 0-70 kOe as well as magnetic susceptibility in the temperature range of 2-300 K were subsequently detected. Both types of magnetic signals were next ana</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="4a91913bea4ebfb4f94bf1d1c06c3b01" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":94212366,"asset_id":90730350,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/94212366/download_file?s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="90730350"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="90730350"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 90730350; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=90730350]").text(description); $(".js-view-count[data-work-id=90730350]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 90730350; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='90730350']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="90730345"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/90730345/Octacyanidorhenate_V_Ion_as_an_Efficient_Linker_for_Hysteretic_Two_Step_Iron_II_Spin_Crossover_Switchable_by_Temperature_Light_and_Pressure"><img alt="Research paper thumbnail of Octacyanidorhenate(V) Ion as an Efficient Linker for Hysteretic Two‐Step Iron(II) Spin Crossover Switchable by Temperature, Light, and Pressure" class="work-thumbnail" src="https://attachments.academia-assets.com/94212365/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/90730345/Octacyanidorhenate_V_Ion_as_an_Efficient_Linker_for_Hysteretic_Two_Step_Iron_II_Spin_Crossover_Switchable_by_Temperature_Light_and_Pressure">Octacyanidorhenate(V) Ion as an Efficient Linker for Hysteretic Two‐Step Iron(II) Spin Crossover Switchable by Temperature, Light, and Pressure</a></div><div class="wp-workCard_item"><span>Angewandte Chemie International Edition</span><span>, 2020</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">We report the two-step hysteretic Fe(II) spin crossover (SCO) effect achieved in programmed layer...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">We report the two-step hysteretic Fe(II) spin crossover (SCO) effect achieved in programmed layered Cs{[Fe(3-CNpy)2] [Re(CN)8]}•H2O (1) assembly consisting of cyanido-bridged Fe II-Re V square grid sheets bonded by Cs + ions. The presence of two nonequivalent Fe II sites and the conjunction of 2-D bimetallic coordination network with non-covalent interlayer interactions involving Cs + , [Re V (CN)8] 3ions, and 3-CNpy ligands, leads to the occurrence of two steps of thermal SCO with strong cooperativity giving a double thermal hysteresis loop. The resulting spin transition phenomenon could be tuned by an external pressure giving the room temperature range of SCO as well as by visible light irradiation inducing an efficient recovery of the high spin Fe II state at low temperatures. In this report, we prove that octacyanidorhenate(V) ion is an outstanding metalloligand for inducing of cooperative multistep, multi-switchable Fe II SCO effect.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="99cd6a7eca016b0047154cadbf19b862" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":94212365,"asset_id":90730345,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/94212365/download_file?s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="90730345"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="90730345"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 90730345; 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