Molecularly-thin anatase field-effect transistors fabricated through the solid state transformation of titania nanosheets

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Lett.; citation_volume=96; citation_pages=042107;citation_publication_date=2010; " /> <meta content=" We demonstrate the field-effect transistor (FET) operation of a molecularly-thin anatase phase produced through solid state transformation from Ti0.87O2 nanosheets. A monolayer Ti0.87O2 nanosheet with a thickness of 0.7 nm is a two-dimensional oxide insulator in which Ti vacancies are incorporated, rather than oxygen vacancies. Since the fabrication method, in general, largely affects the film quality, the anatase films derived from the Ti0.87O2 nanosheets show interesting characteristics, such as no photocurrent peak at ∼2 eV, which is related to oxygen vacancies, and a larger band gap of 3.8 eV. The 10 nm thick anatase FETs exhibit superior transport characteristics with a maximum mobility of ∼1.3 cm2 V−1 s−1 and a current on/off ratio of ∼105 at room temperature. The molecularly-thin anatase FET may provide new functionalities, such as field-effect control of catalytic properties. 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Click to view all articles in this issue." title="Issue 19, 2017">Issue 19, 2017</a> </div> <nav aria-label="Article"> <ul class="article-nav__bar"> <li> <a href="/en/Content/ArticleLanding/2017/NR/C7NR01148B"> Previous <span class="v-mobile-hide--inline">Article</span> </a> </li> <li> <a href="/en/Content/ArticleLanding/2017/NR/C7NR01548H"> Next <span class="v-mobile-hide--inline">Article</span> </a> </li> </ul> </nav> <div class="list-control"> <div class="list__collection--image"> <div class="list__item"> <a href="/en/journals/journal/nr" class="list__item-link"> <div class="list__image-col"> <img src="/en/Image/Get?imageInfo.ImageType=CoverIssue&imageInfo.ImageIdentifier.SerCode=NR&imageInfo.ImageIdentifier.IssueId=NR009019" id="imgLoader" alt="" class="list__item-img" height="88"> </div> <div class="list__text-col"> <div class="list__item-label"> <span class="page-head__context">From the journal:</span> <h3 class="h--heading3 no-heading">Nanoscale</h3> </div> </div> </a> </div> </div> </div> <br> </div> <article class="article-control"> <div class="article__title"> <h2 class="capsule__title fixpadv--m"> Molecularly-thin anatase field-effect transistors fabricated through the solid state transformation of titania nanosheets<a href="#fn1" title="Electronic supplementary information (ESI) available: EBSD analysis. See DOI: 10.1039/c7nr01305a">†</a> </h2> <div class="fixpadv--m crossmark-button"> <button type="button" data-target="crossmark"><img width="150" height="32" src="https://crossmark-cdn.crossref.org/widget/v2.0/logos/CROSSMARK_Color_horizontal.svg" alt="Check for updates" /></button> </div> </div> <div class="article__authors"> <span class="article__author-link"> <a href="/en/results?searchtext=Author%3AS.%20Sekizaki">S. Sekizaki</a>,<span><sup><i>a</i></sup></span>   </span> <span class="article__author-link"> <a href="/en/results?searchtext=Author%3AM.%20Osada">M. Osada</a><span><sup><i>b</i></sup></span>  and  </span> <span class="article__author-link"> <a href="/en/results?searchtext=Author%3AK.%20Nagashio">K. Nagashio</a> <span class="orcid ver-b"><a target="_blank" title="Select to open ORCID record for K. Nagashio (orcid.org/0000-0003-1181-8644) in a new window" href="https://orcid.org/0000-0003-1181-8644"><img src="https://www.rsc-cdn.org/pubs-core/2022.0.159/content/NewImages/orcid_16x16.png" alt="ORCID logo"></a></span> *<span><sup><i>ac</i></sup></span>   </span> </div> <div class="drawer-control fixpadv--m"> <a href="#" role="button" id="btnAuthorAffiliations" aria-expanded="false" aria-controls="pnlAuthorAffiliations" class="drawer__handle"> <span class="drawer__icon"></span> Author affiliations </a> <div class="drawer__content" id="pnlAuthorAffiliations" aria-labelledby="btnAuthorAffiliations"> <div> <p class="article__author-affiliation"> <span> * </span> <span> Corresponding authors </span> </p> <p class="article__author-affiliation"> <span> <sup>a</sup> </span> <span> Department of Materials Engineering, The University of Tokyo, Tokyo 113-8656, Japan <br /> <b>E-mail:</b> <a href="mailto:nagashio@material.t.u-tokyo.ac.jp" title="nagashio@material.t.u-tokyo.ac.jp">nagashio@material.t.u-tokyo.ac.jp</a> </span> </p> <p class="article__author-affiliation"> <span> <sup>b</sup> </span> <span> National Institute of Materials Science, Ibaraki 305-0044, Japan </span> </p> <p class="article__author-affiliation"> <span> <sup>c</sup> </span> <span> PRESTO, Japan Science and Technology Agency (JST), Tokyo 113-8656, Japan </span> </p> </div> </div> </div> <h3 class="h--heading3 article-abstract__heading">Abstract</h3> <div class="capsule__column-wrapper"> <div class="capsule__text"> <p xmlns="http://www.rsc.org/schema/rscart38">We demonstrate the field-effect transistor (FET) operation of a molecularly-thin anatase phase produced through solid state transformation from Ti<small><sub>0.87</sub></small>O<small><sub>2</sub></small> nanosheets. A monolayer Ti<small><sub>0.87</sub></small>O<small><sub>2</sub></small> nanosheet with a thickness of 0.7 nm is a two-dimensional oxide insulator in which Ti vacancies are incorporated, rather than oxygen vacancies. Since the fabrication method, in general, largely affects the film quality, the anatase films derived from the Ti<small><sub>0.87</sub></small>O<small><sub>2</sub></small> nanosheets show interesting characteristics, such as no photocurrent peak at ∼2 eV, which is related to oxygen vacancies, and a larger band gap of 3.8 eV. The 10 nm thick anatase FETs exhibit superior transport characteristics with a maximum mobility of ∼1.3 cm<small><sup>2</sup></small> V<small><sup>−1</sup></small> s<small><sup>−1</sup></small> and a current on/off ratio of ∼10<small><sup>5</sup></small> at room temperature. The molecularly-thin anatase FET may provide new functionalities, such as field-effect control of catalytic properties.</p> </div> <div class="capsule__article-image fixpadv--s"> <img src="/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C7NR01305A&imageInfo.ImageIdentifier.Year=2017" alt="Graphical abstract: Molecularly-thin anatase field-effect transistors fabricated through the solid state transformation of titania nanosheets" /> </div> </div> <p></p> <div id="pnlArticleAccess" class="article-access fixpadt--xxl" style="display: none; border: 0;"> <div class="article-access__inner" style="background-color: #F1F1F3;"> <div class="article-access__head fixpad--s"> You have access to this article </div> <div class="fixpad--xl"> <div id="pnlViewFullArticleButton" class="paywall__body text--centered"> <div id="pnlArticleLoading"> <span id="thtmlLoadingMessage"> <img src="https://www.rsc-cdn.org/pubs-core/2022.0.159/content/NewImages/Ajax-GA-Loader.gif" alt="" 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Molecularly-thin anatase field-effect transistors fabricated through the solid state transformation of titania nanosheets - Nanoscale (RSC Publishing)