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Difluoride - Wikipedia

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data-event-name="pinnable-header.vector-toc.pin">move to sidebar</button> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-unpin-button" data-event-name="pinnable-header.vector-toc.unpin">hide</button> </div> <ul class="vector-toc-contents" id="mw-panel-toc-list"> <li id="toc-mw-content-text" class="vector-toc-list-item vector-toc-level-1"> <a href="#" class="vector-toc-link"> <div class="vector-toc-text">(Top)</div> </a> </li> <li id="toc-List_of_the_difluorides" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#List_of_the_difluorides"> <div class="vector-toc-text"> <span class="vector-toc-numb">1</span> <span>List of the difluorides</span> </div> </a> <button aria-controls="toc-List_of_the_difluorides-sublist" class="cdx-button cdx-button--weight-quiet cdx-button--icon-only vector-toc-toggle"> <span class="vector-icon mw-ui-icon-wikimedia-expand"></span> <span>Toggle List of the difluorides subsection</span> </button> <ul id="toc-List_of_the_difluorides-sublist" class="vector-toc-list"> <li id="toc-Alkaline_earth_metal_difluorides" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Alkaline_earth_metal_difluorides"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.1</span> <span>Alkaline earth metal difluorides</span> </div> </a> <ul id="toc-Alkaline_earth_metal_difluorides-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Lanthanide_difluorides" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Lanthanide_difluorides"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.2</span> <span>Lanthanide difluorides</span> </div> </a> <ul id="toc-Lanthanide_difluorides-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Transition_metal_difluorides" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Transition_metal_difluorides"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.3</span> <span>Transition metal difluorides</span> </div> </a> <ul id="toc-Transition_metal_difluorides-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Post-transition_metal_difluorides" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Post-transition_metal_difluorides"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.4</span> <span>Post-transition metal difluorides</span> </div> </a> <ul id="toc-Post-transition_metal_difluorides-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Nonmetal_and_metalloid_difluorides" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Nonmetal_and_metalloid_difluorides"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.5</span> <span>Nonmetal and metalloid difluorides</span> </div> </a> <ul id="toc-Nonmetal_and_metalloid_difluorides-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Noble_gas_difluorides" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Noble_gas_difluorides"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.6</span> <span>Noble gas difluorides</span> </div> </a> <ul id="toc-Noble_gas_difluorides-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Bifluorides" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Bifluorides"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.7</span> <span>Bifluorides</span> </div> </a> <ul id="toc-Bifluorides-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Organic_difluorides" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Organic_difluorides"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.8</span> <span>Organic difluorides</span> </div> </a> <ul id="toc-Organic_difluorides-sublist" class="vector-toc-list"> </ul> </li> </ul> </li> <li id="toc-References" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#References"> <div class="vector-toc-text"> <span class="vector-toc-numb">2</span> <span>References</span> </div> </a> <ul id="toc-References-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Bibliography" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#Bibliography"> <div class="vector-toc-text"> <span class="vector-toc-numb">3</span> <span>Bibliography</span> </div> </a> <ul id="toc-Bibliography-sublist" class="vector-toc-list"> </ul> </li> </ul> </div> </div> </nav> </div> </div> <div class="mw-content-container"> <main id="content" class="mw-body"> <header class="mw-body-header vector-page-titlebar"> <nav aria-label="Contents" class="vector-toc-landmark"> <div id="vector-page-titlebar-toc" class="vector-dropdown vector-page-titlebar-toc vector-button-flush-left" > <input 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<div class="vector-body-before-content"> <div class="mw-indicators"> </div> <div id="siteSub" class="noprint">From Wikipedia, the free encyclopedia</div> </div> <div id="contentSub"><div id="mw-content-subtitle"><span class="mw-redirectedfrom">(Redirected from <a href="/w/index.php?title=Helium_difluoride&amp;redirect=no" class="mw-redirect" title="Helium difluoride">Helium difluoride</a>)</span></div></div> <div id="mw-content-text" class="mw-body-content"><div class="mw-content-ltr mw-parser-output" lang="en" dir="ltr"><style data-mw-deduplicate="TemplateStyles:r1236090951">.mw-parser-output .hatnote{font-style:italic}.mw-parser-output div.hatnote{padding-left:1.6em;margin-bottom:0.5em}.mw-parser-output .hatnote i{font-style:normal}.mw-parser-output .hatnote+link+.hatnote{margin-top:-0.5em}@media print{body.ns-0 .mw-parser-output .hatnote{display:none!important}}</style><div role="note" class="hatnote navigation-not-searchable">Not to be confused with <a href="/wiki/Bifluoride" title="Bifluoride">Bifluoride</a>.</div> <table style="margin:1em 0 1em 2em; text-align:left; width:320px; float:right;" cellpadding="0" cellspacing="0"> <tbody><tr> <td colspan="2" style="text-align:center;"><b>Order and disorder in difluorides</b> </td></tr> <tr> <td style="width:155px; padding-right:5px;"><span typeof="mw:File"><a href="/wiki/File:Fluorite_unit_cell_(ionic)_-_cropped.png" class="mw-file-description"><img alt="A parallelogram-shaped outline with space-filling diatomic molecules (joined circles) arranged in two layers" src="//upload.wikimedia.org/wikipedia/commons/thumb/8/84/Fluorite_unit_cell_%28ionic%29_-_cropped.png/155px-Fluorite_unit_cell_%28ionic%29_-_cropped.png" decoding="async" width="155" height="163" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/8/84/Fluorite_unit_cell_%28ionic%29_-_cropped.png/233px-Fluorite_unit_cell_%28ionic%29_-_cropped.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/8/84/Fluorite_unit_cell_%28ionic%29_-_cropped.png/310px-Fluorite_unit_cell_%28ionic%29_-_cropped.png 2x" data-file-width="475" data-file-height="500" /></a></span> </td> <td style="width:155px; padding-left:5px;"><span typeof="mw:File"><a href="/wiki/File:BeF2_glass.svg" class="mw-file-description"><img alt="cube of 8 yellow atoms with white ones at the holes of the yellow structure" src="//upload.wikimedia.org/wikipedia/commons/thumb/e/e4/BeF2_glass.svg/155px-BeF2_glass.svg.png" decoding="async" width="155" height="171" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/e/e4/BeF2_glass.svg/233px-BeF2_glass.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/e/e4/BeF2_glass.svg/310px-BeF2_glass.svg.png 2x" data-file-width="500" data-file-height="550" /></a></span> </td></tr> <tr style="vertical-align:top;"> <td style="width:155px; padding-right:5px;">The fluorite structure </td> <td style="width:155px; padding-left:5px;">Beryllium fluoride glass </td></tr></tbody></table> <p><b>Difluorides</b> are chemical compounds with two <a href="/wiki/Fluorine" title="Fluorine">fluorine</a> atoms per molecule (or per formula unit). </p><p>Metal difluorides are all <a href="/wiki/Ionic_compound" class="mw-redirect" title="Ionic compound">ionic</a>. Despite being highly ionic, the <a href="/wiki/Alkaline_earth_metal" title="Alkaline earth metal">alkaline earth metal</a> difluorides generally have extremely high lattice stability and are thus <a href="/wiki/Solubility" title="Solubility">insoluble</a> in water. The exception is <a href="/wiki/Beryllium_difluoride" class="mw-redirect" title="Beryllium difluoride">beryllium difluoride</a>. In addition, many <a href="/wiki/Transition_metal" title="Transition metal">transition metal</a> difluorides are water-soluble. </p><p><a href="/wiki/CaF2" class="mw-redirect" title="CaF2">Calcium difluoride</a> is a notable compound. In the form of the mineral <a href="/wiki/Fluorite" title="Fluorite">fluorite</a> it is the major source of commercial fluorine. It also has an eponymic crystal structure, which is an end member of the spectrum starting from <a href="/wiki/Bixbyite" title="Bixbyite">bixbyite</a> and progressing through <a href="/wiki/Pyrochlore" title="Pyrochlore">pyrochlore</a>. </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="List_of_the_difluorides">List of the difluorides</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Difluoride&amp;action=edit&amp;section=1" title="Edit section: List of the difluorides"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Examples of the difluorides include: </p> <div class="mw-heading mw-heading3"><h3 id="Alkaline_earth_metal_difluorides">Alkaline earth metal difluorides</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Difluoride&amp;action=edit&amp;section=2" title="Edit section: Alkaline earth metal difluorides"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>The alkaline earth metals all exhibit the oxidation state +2, and form difluorides. The difluoride of <a href="/wiki/Radium" title="Radium">radium</a> is however not well established due to the element's high radioactivity. </p> <ul><li><a href="/wiki/Beryllium_difluoride" class="mw-redirect" title="Beryllium difluoride">Beryllium difluoride</a></li> <li><a href="/wiki/Magnesium_fluoride" title="Magnesium fluoride">Magnesium fluoride</a></li> <li><a href="/wiki/Calcium_fluoride" title="Calcium fluoride">Calcium fluoride</a></li> <li><a href="/wiki/Strontium_difluoride" class="mw-redirect" title="Strontium difluoride">Strontium difluoride</a></li> <li><a href="/wiki/Barium_fluoride" title="Barium fluoride">Barium fluoride</a></li> <li><a href="/wiki/Radium_fluoride" title="Radium fluoride">Radium fluoride</a></li></ul> <dl><dd><table class="wikitable sortable"> <caption>Solubility-related constants of alkaline earth metal fluorides </caption> <tbody><tr> <th>Metal<br /> </th> <th>M<sup>2+</sup> <a href="/wiki/Hydration_energy" title="Hydration energy">HE</a><sup id="cite_ref-FOOTNOTEWibergWibergHolleman2001XXXVI–XXXVII_1-0" class="reference"><a href="#cite_note-FOOTNOTEWibergWibergHolleman2001XXXVI–XXXVII-1"><span class="cite-bracket">&#91;</span>1<span class="cite-bracket">&#93;</span></a></sup> </th> <th>F<sup>−</sup> HE<sup id="cite_ref-FOOTNOTEWibergWibergHolleman2001XXXVI_2-0" class="reference"><a href="#cite_note-FOOTNOTEWibergWibergHolleman2001XXXVI-2"><span class="cite-bracket">&#91;</span>2<span class="cite-bracket">&#93;</span></a></sup> </th> <th>"MF<sub>2</sub>" unit<br />HE </th> <th>MF<sub>2</sub> lattice<br />energies (−kJ/mol)<sup id="cite_ref-FOOTNOTELide200412-23_3-0" class="reference"><a href="#cite_note-FOOTNOTELide200412-23-3"><span class="cite-bracket">&#91;</span>3<span class="cite-bracket">&#93;</span></a></sup> </th> <th>Solubility<br />(mol/L)<sup id="cite_ref-FOOTNOTEWibergWibergHolleman20011073_4-0" class="reference"><a href="#cite_note-FOOTNOTEWibergWibergHolleman20011073-4"><span class="cite-bracket">&#91;</span>4<span class="cite-bracket">&#93;</span></a></sup> </th></tr> <tr> <td>Be </td> <td>2,455 </td> <td>458 </td> <td>3,371 </td> <td>3,526 </td> <td>25 </td></tr> <tr> <td>Mg </td> <td>1,922 </td> <td>458 </td> <td>2,838 </td> <td>2,978 </td> <td>0.0012 </td></tr> <tr> <td>Ca </td> <td>1,577 </td> <td>458 </td> <td>2,493 </td> <td>2,651 </td> <td>0.0002 </td></tr> <tr> <td>Sr </td> <td>1,415 </td> <td>458 </td> <td>2,331 </td> <td>2,513 </td> <td>0.0008 </td></tr> <tr> <td>Ba </td> <td>1,361 </td> <td>458 </td> <td>2,277 </td> <td>2,373 </td> <td>0.006 </td></tr></tbody></table></dd></dl> <div style="clear:both;" class=""></div> <div class="mw-heading mw-heading3"><h3 id="Lanthanide_difluorides">Lanthanide difluorides</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Difluoride&amp;action=edit&amp;section=3" title="Edit section: Lanthanide difluorides"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a href="/w/index.php?title=Neodymium_difluoride&amp;action=edit&amp;redlink=1" class="new" title="Neodymium difluoride (page does not exist)">Neodymium difluoride</a><sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">&#91;<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (May 2024)">citation needed</span></a></i>&#93;</sup></li> <li><a href="/wiki/Samarium_difluoride" class="mw-redirect" title="Samarium difluoride">Samarium difluoride</a><sup id="cite_ref-laf_5-0" class="reference"><a href="#cite_note-laf-5"><span class="cite-bracket">&#91;</span>5<span class="cite-bracket">&#93;</span></a></sup></li> <li><a href="/wiki/Europium_difluoride" class="mw-redirect" title="Europium difluoride">Europium difluoride</a><sup id="cite_ref-laf_5-1" class="reference"><a href="#cite_note-laf-5"><span class="cite-bracket">&#91;</span>5<span class="cite-bracket">&#93;</span></a></sup></li> <li><a href="/w/index.php?title=Dysprosium_difluoride&amp;action=edit&amp;redlink=1" class="new" title="Dysprosium difluoride (page does not exist)">Dysprosium difluoride</a><sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">&#91;<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (May 2024)">citation needed</span></a></i>&#93;</sup></li> <li><a href="/wiki/Thulium_difluoride" class="mw-redirect" title="Thulium difluoride">Thulium difluoride</a><sup id="cite_ref-laf_5-2" class="reference"><a href="#cite_note-laf-5"><span class="cite-bracket">&#91;</span>5<span class="cite-bracket">&#93;</span></a></sup></li> <li><a href="/wiki/Ytterbium_difluoride" class="mw-redirect" title="Ytterbium difluoride">Ytterbium difluoride</a><sup id="cite_ref-6" class="reference"><a href="#cite_note-6"><span class="cite-bracket">&#91;</span>6<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-laf_5-3" class="reference"><a href="#cite_note-laf-5"><span class="cite-bracket">&#91;</span>5<span class="cite-bracket">&#93;</span></a></sup></li></ul> <div class="mw-heading mw-heading3"><h3 id="Transition_metal_difluorides">Transition metal difluorides</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Difluoride&amp;action=edit&amp;section=4" title="Edit section: Transition metal difluorides"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Compounds of the form MF<sub>2</sub>: </p> <ul><li><a href="/wiki/Cadmium_difluoride" class="mw-redirect" title="Cadmium difluoride">Cadmium difluoride</a></li> <li><a href="/wiki/Chromium(II)_fluoride" title="Chromium(II) fluoride">Chromium(II) fluoride</a></li> <li><a href="/wiki/Cobalt_difluoride" class="mw-redirect" title="Cobalt difluoride">Cobalt difluoride</a></li> <li><a href="/wiki/Copper(II)_fluoride" title="Copper(II) fluoride">Copper(II) fluoride</a></li> <li><a href="/wiki/Iron(II)_fluoride" title="Iron(II) fluoride">Iron(II) fluoride</a></li> <li><a href="/wiki/Manganese(II)_fluoride" title="Manganese(II) fluoride">Manganese(II) fluoride</a></li> <li><a href="/wiki/Mercury_difluoride" class="mw-redirect" title="Mercury difluoride">Mercury difluoride</a></li> <li><a href="/wiki/Nickel_difluoride" class="mw-redirect" title="Nickel difluoride">Nickel difluoride</a></li> <li><a href="/wiki/Palladium_difluoride" class="mw-redirect" title="Palladium difluoride">Palladium difluoride</a></li> <li><a href="/wiki/Platinum_difluoride" class="mw-redirect" title="Platinum difluoride">Platinum difluoride</a></li> <li><a href="/wiki/Silver_difluoride" class="mw-redirect" title="Silver difluoride">Silver difluoride</a></li> <li><a href="/wiki/Vanadium_difluoride" class="mw-redirect" title="Vanadium difluoride">Vanadium difluoride</a></li> <li><a href="/wiki/Zinc_difluoride" class="mw-redirect" title="Zinc difluoride">Zinc difluoride</a></li></ul> <div class="mw-heading mw-heading3"><h3 id="Post-transition_metal_difluorides">Post-transition metal difluorides</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Difluoride&amp;action=edit&amp;section=5" title="Edit section: Post-transition metal difluorides"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a href="/wiki/Lead_difluoride" class="mw-redirect" title="Lead difluoride">Lead difluoride</a></li> <li><a href="/wiki/Tin(II)_fluoride" title="Tin(II) fluoride">Tin(II) fluoride</a></li></ul> <div class="mw-heading mw-heading3"><h3 id="Nonmetal_and_metalloid_difluorides">Nonmetal and metalloid difluorides</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Difluoride&amp;action=edit&amp;section=6" title="Edit section: Nonmetal and metalloid difluorides"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a href="/wiki/Dinitrogen_difluoride" title="Dinitrogen difluoride">Dinitrogen difluoride</a></li> <li><a href="/wiki/Oxygen_difluoride" title="Oxygen difluoride">Oxygen difluoride</a></li> <li><a href="/wiki/Dioxygen_difluoride" title="Dioxygen difluoride">Dioxygen difluoride</a></li> <li><a href="/wiki/Selenoyl_difluoride" class="mw-redirect" title="Selenoyl difluoride">Selenoyl difluoride</a></li> <li><a href="/wiki/Sulfur_difluoride" title="Sulfur difluoride">Sulfur difluoride</a></li> <li><a href="/wiki/Disulfur_difluoride" title="Disulfur difluoride">Disulfur difluoride</a></li> <li><a href="/wiki/Thionyl_difluoride" class="mw-redirect" title="Thionyl difluoride">Thionyl difluoride</a></li> <li><a href="/wiki/Germanium_difluoride" title="Germanium difluoride">Germanium difluoride</a></li></ul> <div class="mw-heading mw-heading3"><h3 id="Noble_gas_difluorides">Noble gas difluorides</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Difluoride&amp;action=edit&amp;section=7" title="Edit section: Noble gas difluorides"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a href="/wiki/Helium_difluoride" class="mw-redirect" title="Helium difluoride">Helium difluoride</a> (hypothetical) <sup id="cite_ref-7" class="reference"><a href="#cite_note-7"><span class="cite-bracket">&#91;</span>7<span class="cite-bracket">&#93;</span></a></sup></li> <li><a href="/wiki/Argon_compounds#Argon_difluoride" title="Argon compounds"> Argon difluoride</a> (predicted)</li> <li><a href="/wiki/Krypton_difluoride" title="Krypton difluoride">Krypton difluoride</a></li> <li><a href="/wiki/Xenon_difluoride" title="Xenon difluoride">Xenon difluoride</a></li> <li><a href="/wiki/Radon_difluoride" title="Radon difluoride">Radon difluoride</a></li></ul> <div class="mw-heading mw-heading3"><h3 id="Bifluorides">Bifluorides</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Difluoride&amp;action=edit&amp;section=8" title="Edit section: Bifluorides"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>The <a href="/wiki/Bifluoride" title="Bifluoride">bifluorides</a> contain the two fluorine atoms in a <a href="/wiki/Covalent_bond" title="Covalent bond">covalently bound</a> HF<sub>2</sub><sup>−</sup> <a href="/wiki/Polyatomic_ion" title="Polyatomic ion">polyatomic ion</a> rather than as F<sup>−</sup> anions. </p> <ul><li><a href="/wiki/Ammonium_bifluoride" title="Ammonium bifluoride">Ammonium bifluoride</a></li> <li><a href="/wiki/Potassium_bifluoride" title="Potassium bifluoride">Potassium bifluoride</a></li> <li><a href="/wiki/Sodium_bifluoride" title="Sodium bifluoride">Sodium bifluoride</a></li></ul> <div class="mw-heading mw-heading3"><h3 id="Organic_difluorides">Organic difluorides</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Difluoride&amp;action=edit&amp;section=9" title="Edit section: Organic difluorides"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a href="/wiki/Ethanedioyl_difluoride" class="mw-redirect" title="Ethanedioyl difluoride">Ethanedioyl difluoride</a></li> <li><a href="/wiki/Ethylidene_difluoride" class="mw-redirect" title="Ethylidene difluoride">Ethylidene difluoride</a></li> <li><a href="/wiki/Carbonyl_difluoride" class="mw-redirect" title="Carbonyl difluoride">Carbonyl difluoride</a></li> <li><a href="/wiki/Carbon_dibromide_difluoride" class="mw-redirect" title="Carbon dibromide difluoride">Carbon dibromide difluoride</a> (dibromodifluoromethane)</li> <li><a href="/wiki/Carbon_dichloride_difluoride" class="mw-redirect" title="Carbon dichloride difluoride">Carbon dichloride difluoride</a> (dichlorodifluormethane)</li> <li><a href="/wiki/Methyl_difluoride" class="mw-redirect" title="Methyl difluoride">Methyl difluoride</a></li> <li><a href="/wiki/Methylphosphonyl_difluoride" title="Methylphosphonyl difluoride">Methylphosphonyl difluoride</a></li> <li><a href="/wiki/Polyvinylidene_difluoride" class="mw-redirect" title="Polyvinylidene difluoride">Polyvinylidene difluoride</a></li></ul> <div class="mw-heading mw-heading2"><h2 id="References">References</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Difluoride&amp;action=edit&amp;section=10" title="Edit section: References"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <style data-mw-deduplicate="TemplateStyles:r1239543626">.mw-parser-output .reflist{margin-bottom:0.5em;list-style-type:decimal}@media screen{.mw-parser-output .reflist{font-size:90%}}.mw-parser-output .reflist .references{font-size:100%;margin-bottom:0;list-style-type:inherit}.mw-parser-output .reflist-columns-2{column-width:30em}.mw-parser-output .reflist-columns-3{column-width:25em}.mw-parser-output .reflist-columns{margin-top:0.3em}.mw-parser-output .reflist-columns ol{margin-top:0}.mw-parser-output .reflist-columns li{page-break-inside:avoid;break-inside:avoid-column}.mw-parser-output .reflist-upper-alpha{list-style-type:upper-alpha}.mw-parser-output .reflist-upper-roman{list-style-type:upper-roman}.mw-parser-output .reflist-lower-alpha{list-style-type:lower-alpha}.mw-parser-output .reflist-lower-greek{list-style-type:lower-greek}.mw-parser-output .reflist-lower-roman{list-style-type:lower-roman}</style><div class="reflist"> <div class="mw-references-wrap"><ol class="references"> <li id="cite_note-FOOTNOTEWibergWibergHolleman2001XXXVI–XXXVII-1"><span class="mw-cite-backlink"><b><a href="#cite_ref-FOOTNOTEWibergWibergHolleman2001XXXVI–XXXVII_1-0">^</a></b></span> <span class="reference-text"><a href="#CITEREFWibergWibergHolleman2001">Wiberg, Wiberg &amp; Holleman 2001</a>, pp.&#160;XXXVI–XXXVII.</span> </li> <li id="cite_note-FOOTNOTEWibergWibergHolleman2001XXXVI-2"><span class="mw-cite-backlink"><b><a href="#cite_ref-FOOTNOTEWibergWibergHolleman2001XXXVI_2-0">^</a></b></span> <span class="reference-text"><a href="#CITEREFWibergWibergHolleman2001">Wiberg, Wiberg &amp; Holleman 2001</a>, p.&#160;XXXVI.</span> </li> <li id="cite_note-FOOTNOTELide200412-23-3"><span class="mw-cite-backlink"><b><a href="#cite_ref-FOOTNOTELide200412-23_3-0">^</a></b></span> <span class="reference-text"><a href="#CITEREFLide2004">Lide 2004</a>, p.&#160;12-23.</span> </li> <li id="cite_note-FOOTNOTEWibergWibergHolleman20011073-4"><span class="mw-cite-backlink"><b><a href="#cite_ref-FOOTNOTEWibergWibergHolleman20011073_4-0">^</a></b></span> <span class="reference-text"><a href="#CITEREFWibergWibergHolleman2001">Wiberg, Wiberg &amp; Holleman 2001</a>, p.&#160;1073.</span> </li> <li id="cite_note-laf-5"><span class="mw-cite-backlink">^ <a href="#cite_ref-laf_5-0"><sup><i><b>a</b></i></sup></a> <a href="#cite_ref-laf_5-1"><sup><i><b>b</b></i></sup></a> <a href="#cite_ref-laf_5-2"><sup><i><b>c</b></i></sup></a> <a href="#cite_ref-laf_5-3"><sup><i><b>d</b></i></sup></a></span> <span class="reference-text"><style data-mw-deduplicate="TemplateStyles:r1238218222">.mw-parser-output cite.citation{font-style:inherit;word-wrap:break-word}.mw-parser-output .citation q{quotes:"\"""\"""'""'"}.mw-parser-output .citation:target{background-color:rgba(0,127,255,0.133)}.mw-parser-output .id-lock-free.id-lock-free a{background:url("//upload.wikimedia.org/wikipedia/commons/6/65/Lock-green.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-limited.id-lock-limited a,.mw-parser-output .id-lock-registration.id-lock-registration a{background:url("//upload.wikimedia.org/wikipedia/commons/d/d6/Lock-gray-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-subscription.id-lock-subscription a{background:url("//upload.wikimedia.org/wikipedia/commons/a/aa/Lock-red-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .cs1-ws-icon a{background:url("//upload.wikimedia.org/wikipedia/commons/4/4c/Wikisource-logo.svg")right 0.1em center/12px no-repeat}body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-free a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-limited a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-registration a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-subscription a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .cs1-ws-icon a{background-size:contain;padding:0 1em 0 0}.mw-parser-output .cs1-code{color:inherit;background:inherit;border:none;padding:inherit}.mw-parser-output .cs1-hidden-error{display:none;color:var(--color-error,#d33)}.mw-parser-output .cs1-visible-error{color:var(--color-error,#d33)}.mw-parser-output .cs1-maint{display:none;color:#085;margin-left:0.3em}.mw-parser-output .cs1-kern-left{padding-left:0.2em}.mw-parser-output .cs1-kern-right{padding-right:0.2em}.mw-parser-output .citation .mw-selflink{font-weight:inherit}@media screen{.mw-parser-output .cs1-format{font-size:95%}html.skin-theme-clientpref-night .mw-parser-output .cs1-maint{color:#18911f}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .cs1-maint{color:#18911f}}</style><cite id="CITEREFMüller1991" class="citation book cs1">Müller, Bernd G. (1991). "Lanthanide Fluorides". <i>Synthesis of Lanthanide and Actinide Compounds</i>. Vol.&#160;2. pp.&#160;55–65. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1007%2F978-94-011-3758-4_2">10.1007/978-94-011-3758-4_2</a>.</cite><span title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&amp;rft.genre=bookitem&amp;rft.atitle=Lanthanide+Fluorides&amp;rft.btitle=Synthesis+of+Lanthanide+and+Actinide+Compounds&amp;rft.pages=55-65&amp;rft.date=1991&amp;rft_id=info%3Adoi%2F10.1007%2F978-94-011-3758-4_2&amp;rft.aulast=M%C3%BCller&amp;rft.aufirst=Bernd+G.&amp;rfr_id=info%3Asid%2Fen.wikipedia.org%3ADifluoride" class="Z3988"></span></span> </li> <li id="cite_note-6"><span class="mw-cite-backlink"><b><a href="#cite_ref-6">^</a></b></span> <span class="reference-text">Georg Brauer: Handbuch der Präparativen Anorganischen Chemie. 3., umgearb. Auflage. Band I. Enke, Stuttgart 1975, <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><a href="/wiki/ISBN_(identifier)" class="mw-redirect" title="ISBN (identifier)">ISBN</a>&#160;<a href="/wiki/Special:BookSources/3-432-02328-6" title="Special:BookSources/3-432-02328-6">3-432-02328-6</a>, p. 255.</span> </li> <li id="cite_note-7"><span class="mw-cite-backlink"><b><a href="#cite_ref-7">^</a></b></span> <span class="reference-text">Wu, R. Q. <a rel="nofollow" class="external text" href="https://pubs.aip.org/aip/adv/article/14/8/085007/3306241/HeF2-and-ArF2-molecules-from-first-principles">"HeF2 and ArF2 molecules from first-principles study"</a></span> </li> </ol></div></div> <div class="mw-heading mw-heading2"><h2 id="Bibliography">Bibliography</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Difluoride&amp;action=edit&amp;section=11" title="Edit section: Bibliography"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFGreenwoodEarnshaw1998" class="citation book cs1">Greenwood, N. N.; Earnshaw, A. (1998). <i>Chemistry of the Elements</i> (second&#160;ed.). Butterworth Heinemann. <a href="/wiki/ISBN_(identifier)" class="mw-redirect" title="ISBN (identifier)">ISBN</a>&#160;<a href="/wiki/Special:BookSources/0-7506-3365-4" title="Special:BookSources/0-7506-3365-4"><bdi>0-7506-3365-4</bdi></a>.</cite><span title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&amp;rft.genre=book&amp;rft.btitle=Chemistry+of+the+Elements&amp;rft.edition=second&amp;rft.pub=Butterworth+Heinemann&amp;rft.date=1998&amp;rft.isbn=0-7506-3365-4&amp;rft.aulast=Greenwood&amp;rft.aufirst=N.+N.&amp;rft.au=Earnshaw%2C+A.&amp;rfr_id=info%3Asid%2Fen.wikipedia.org%3ADifluoride" class="Z3988"></span></li> <li><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFLide2004" class="citation book cs1">Lide, David R. (2004). <span class="id-lock-registration" title="Free registration required"><a rel="nofollow" class="external text" href="https://archive.org/details/crchandbookofche81lide"><i>Handbook of chemistry and physics</i></a></span> (84th&#160;ed.). CRC Press. <a href="/wiki/ISBN_(identifier)" class="mw-redirect" title="ISBN (identifier)">ISBN</a>&#160;<a href="/wiki/Special:BookSources/0-8493-0566-7" title="Special:BookSources/0-8493-0566-7"><bdi>0-8493-0566-7</bdi></a>.</cite><span title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&amp;rft.genre=book&amp;rft.btitle=Handbook+of+chemistry+and+physics&amp;rft.edition=84th&amp;rft.pub=CRC+Press&amp;rft.date=2004&amp;rft.isbn=0-8493-0566-7&amp;rft.aulast=Lide&amp;rft.aufirst=David+R.&amp;rft_id=https%3A%2F%2Farchive.org%2Fdetails%2Fcrchandbookofche81lide&amp;rfr_id=info%3Asid%2Fen.wikipedia.org%3ADifluoride" class="Z3988"></span></li> <li><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFWibergWibergHolleman2001" class="citation book cs1">Wiberg, Egon; Wiberg, Nils; Holleman, Arnold Frederick (2001). <a rel="nofollow" class="external text" href="https://books.google.com/books?id=Mtth5g59dEIC"><i>Inorganic chemistry</i></a>. Academic Press. <a href="/wiki/ISBN_(identifier)" class="mw-redirect" title="ISBN (identifier)">ISBN</a>&#160;<a href="/wiki/Special:BookSources/978-0-12-352651-9" title="Special:BookSources/978-0-12-352651-9"><bdi>978-0-12-352651-9</bdi></a><span class="reference-accessdate">. Retrieved <span class="nowrap">3 March</span> 2011</span>.</cite><span title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&amp;rft.genre=book&amp;rft.btitle=Inorganic+chemistry&amp;rft.pub=Academic+Press&amp;rft.date=2001&amp;rft.isbn=978-0-12-352651-9&amp;rft.aulast=Wiberg&amp;rft.aufirst=Egon&amp;rft.au=Wiberg%2C+Nils&amp;rft.au=Holleman%2C+Arnold+Frederick&amp;rft_id=https%3A%2F%2Fbooks.google.com%2Fbooks%3Fid%3DMtth5g59dEIC&amp;rfr_id=info%3Asid%2Fen.wikipedia.org%3ADifluoride" class="Z3988"></span></li></ul> <style data-mw-deduplicate="TemplateStyles:r1097304697">.mw-parser-output .dmbox{display:flex;align-items:center;clear:both;margin:0.9em 1em;border-top:1px solid #ccc;border-bottom:1px solid #ccc;padding:0.25em 0.35em;font-style:italic}.mw-parser-output .dmbox>*{flex-shrink:0;margin:0 0.25em}.mw-parser-output .dmbox-body{flex-grow:1;flex-shrink:1;padding:0.1em 0}.mw-parser-output .dmbox-invalid-type{text-align:center}</style> <div role="note" id="setindexbox" class="metadata plainlinks dmbox dmbox-setindex"><span typeof="mw:File"><a href="/wiki/File:DAB_list_gray.svg" class="mw-file-description"><img alt="Disambiguation icon" src="//upload.wikimedia.org/wikipedia/commons/thumb/8/8c/DAB_list_gray.svg/30px-DAB_list_gray.svg.png" decoding="async" width="30" height="23" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/8/8c/DAB_list_gray.svg/45px-DAB_list_gray.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/8/8c/DAB_list_gray.svg/60px-DAB_list_gray.svg.png 2x" data-file-width="220" data-file-height="168" /></a></span><div class="dmbox-body"><div class="shortdescription nomobile noexcerpt noprint searchaux" style="display:none">Index of chemical compounds with the same name</div>This <a href="/wiki/Wikipedia:Set_index_articles" title="Wikipedia:Set index articles">set index article</a> lists <a href="/wiki/Chemical_compound" title="Chemical compound">chemical compounds</a> articles associated with the same name.<br /><small>If an <a class="external text" href="https://en.wikipedia.org/w/index.php?title=Special:WhatLinksHere/Difluoride&amp;namespace=0">internal link</a> led you here, you may wish to change the link to point directly to the intended article.</small></div> </div> <!-- NewPP limit report Parsed by mw‐web.codfw.main‐688fc9465‐t9h2n Cached time: 20241125161925 Cache expiry: 2592000 Reduced expiry: false Complications: [vary‐revision‐sha1, show‐toc] CPU time usage: 0.330 seconds Real time usage: 0.474 seconds Preprocessor visited node count: 1444/1000000 Post‐expand include size: 15869/2097152 bytes Template argument size: 2772/2097152 bytes Highest expansion depth: 16/100 Expensive parser function count: 4/500 Unstrip recursion depth: 1/20 Unstrip post‐expand size: 17890/5000000 bytes Lua time usage: 0.190/10.000 seconds Lua memory usage: 5924509/52428800 bytes Number of Wikibase entities loaded: 0/400 --> <!-- Transclusion expansion time report (%,ms,calls,template) 100.00% 421.039 1 -total 29.94% 126.063 1 Template:Reflist 24.97% 105.125 4 Template:Cite_book 23.14% 97.422 1 Template:Chemistry_index 20.80% 87.567 1 Template:Dmbox 18.71% 78.784 1 Template:Short_description 17.17% 72.313 2 Template:Cn 14.89% 62.687 2 Template:Fix 12.33% 51.923 1 Template:Confuse 11.84% 49.840 4 Template:Sfn --> <!-- Saved in parser cache with key enwiki:pcache:idhash:34148547-0!canonical and timestamp 20241125161925 and revision id 1258888048. 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