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free</title> <meta name="description" content="Search results for: metal free"> <meta name="keywords" content="metal free"> <meta name="viewport" content="width=device-width, initial-scale=1, minimum-scale=1, maximum-scale=1, user-scalable=no"> <meta charset="utf-8"> <link href="https://cdn.waset.org/favicon.ico" type="image/x-icon" rel="shortcut icon"> <link href="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/css/bootstrap.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/plugins/fontawesome/css/all.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/css/site.css?v=150220211555" rel="stylesheet"> </head> <body> <header> <div class="container"> <nav class="navbar navbar-expand-lg navbar-light"> <a class="navbar-brand" href="https://waset.org"> <img src="https://cdn.waset.org/static/images/wasetc.png" alt="Open Science Research Excellence" title="Open Science Research Excellence" /> </a> <button class="d-block d-lg-none navbar-toggler ml-auto" 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id="custom-search-input"> <div class="input-group"> <i class="fas fa-search"></i> <input type="text" class="search-query" name="q" placeholder="Author, Title, Abstract, Keywords" value="metal free"> <input type="submit" class="btn_search" value="Search"> </div> </div> </form> </div> </div> <div class="row mt-3"> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Commenced</strong> in January 2007</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Frequency:</strong> Monthly</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Edition:</strong> International</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Paper Count:</strong> 5747</div> </div> </div> </div> <h1 class="mt-3 mb-3 text-center" style="font-size:1.6rem;">Search results for: metal free</h1> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5747</span> Optimization of Catalyst Parameters to Get Chlorine Free Bimetallic Catalysts</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Noreen%20Sajjad%20Ghulam%20Hussain">Noreen Sajjad Ghulam Hussain</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Catalysts are prepared by simple physical mixing and thermal treatment of support and metal acetate precursors.The effect of metal ratio and metal loading to produce highly active catalyst for the oxidation of benzyl alcohol are studied. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=catalyst" title="catalyst">catalyst</a>, <a href="https://publications.waset.org/abstracts/search?q=acetates" title=" acetates"> acetates</a>, <a href="https://publications.waset.org/abstracts/search?q=benzyl%20alcohols" title=" benzyl alcohols "> benzyl alcohols </a> </p> <a href="https://publications.waset.org/abstracts/1867/optimization-of-catalyst-parameters-to-get-chlorine-free-bimetallic-catalysts" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/1867.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">437</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5746</span> A Study on the Vegetative and Osmolyte Accumulation of Capsicum frutescens L. under Zinc Metal Stress</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ja%E2%80%99afar%20Umar">Ja’afar Umar</a>, <a href="https://publications.waset.org/abstracts/search?q=Adamu%20Aliyu%20Aliero"> Adamu Aliyu Aliero</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Plant growth, biochemical parameters, zinc metal concentrations were determined for Capsicum frutescens L. in response to varied concentration of zinc metal. The plant exhibited a decline in the vegetative parameters measured. Free proline and glycine betaine content increases with increasing concentration of zinc metal and differ significantly (P<0.05). It can be concluded that the osmolyte (pro and GB) accumulations, and high length of stem and wide leaf expansion are possible indicator of tolerance to heavy metals (Zinc) in Capsicum frutescens. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=zinc%20metal" title="zinc metal">zinc metal</a>, <a href="https://publications.waset.org/abstracts/search?q=osmolyte" title=" osmolyte"> osmolyte</a>, <a href="https://publications.waset.org/abstracts/search?q=Capsicum%20frutescens" title=" Capsicum frutescens"> Capsicum frutescens</a>, <a href="https://publications.waset.org/abstracts/search?q=stress" title=" stress"> stress</a> </p> <a href="https://publications.waset.org/abstracts/28287/a-study-on-the-vegetative-and-osmolyte-accumulation-of-capsicum-frutescens-l-under-zinc-metal-stress" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/28287.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">486</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5745</span> One-Pot Facile Synthesis of N-Doped Graphene Synthesized from Paraphenylenediamine as Metal-Free Catalysts for the Oxygen Reduction Used for Alkaline Fuel Cells</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Leila%20Samiee">Leila Samiee</a>, <a href="https://publications.waset.org/abstracts/search?q=Amir%20Yadegari"> Amir Yadegari</a>, <a href="https://publications.waset.org/abstracts/search?q=Saeedeh%20Tasharrofi"> Saeedeh Tasharrofi</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In the work presented here, nitrogen-doped graphene materials were synthesized and used as metal-free electrocatalysts for oxygen reduction reaction (ORR) under alkaline conditions. Paraphenylenediamine was used as N precursor. The N-doped graphene was synthesized under hydrothermal treatment at 200°C. All the materials have been characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Transmission electron microscopy (TEM) and X-ray photo-electron spectroscopy (XPS). Moreover, for electrochemical evaluation of samples, Rotating Disk electrode (RDE) and Cyclic Voltammetry techniques (CV) were employed. The resulting material exhibits an outstanding catalytic activity for the oxygen reduction reaction (ORR) as well as excellent resistance towards methanol crossover effects, indicating their promising potential as ORR electrocatalysts for alkaline fuel cells. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=alkaline%20fuel%20cell" title="alkaline fuel cell">alkaline fuel cell</a>, <a href="https://publications.waset.org/abstracts/search?q=graphene" title=" graphene"> graphene</a>, <a href="https://publications.waset.org/abstracts/search?q=metal-free%20catalyst" title=" metal-free catalyst"> metal-free catalyst</a>, <a href="https://publications.waset.org/abstracts/search?q=paraphenylen%20diamine" title=" paraphenylen diamine"> paraphenylen diamine</a> </p> <a href="https://publications.waset.org/abstracts/36398/one-pot-facile-synthesis-of-n-doped-graphene-synthesized-from-paraphenylenediamine-as-metal-free-catalysts-for-the-oxygen-reduction-used-for-alkaline-fuel-cells" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/36398.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">479</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5744</span> Synthesis, Characterization and Anti-Microbial Study of Urethanized Poly Vinyl Alcohol Metal Complexes</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Maha%20A.%20Younus">Maha A. Younus</a>, <a href="https://publications.waset.org/abstracts/search?q=Dhefaf%20H.%20Badri"> Dhefaf H. Badri</a>, <a href="https://publications.waset.org/abstracts/search?q=Maha%20A.%20Al%20Abayaji"> Maha A. Al Abayaji</a>, <a href="https://publications.waset.org/abstracts/search?q=Taha%20M.%20Salih"> Taha M. Salih</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Polymer metal complexes of poly vinyl alcohol and Cu (II), Ni (II), Mn (II) and Co (III) were prepared from the reaction of PVA with three different percentages of urea. The compound was characterized by fourier transform infrared spectrometry (FTIR) analysis and differential scanning calorimetric (DSC) Analysis. It has been established that the polymer and its metal complexes showed good activities against nine pathogenic bacteria (Escherichia coli, Klebsiellapneumonae, Staphylococcusaureus, Staphylococcus Albus, Salmonella Typhoid, Pseudomonas Aeruginosa, Shigella Dysentery, Proteus Morgani, Brucella Militensis). The polymer metal complexes show activity higher than that of the free polymer. The increasing activities were in the order (polymer < pol-Mn< pol-Co < pol-Ni ˂ pol-Cu). The ability of these compounds to show antimicrobial properties suggests that they can be further evaluated for medicinal and/or environmental applications. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=antimicrobial%20activity" title="antimicrobial activity">antimicrobial activity</a>, <a href="https://publications.waset.org/abstracts/search?q=PVA" title=" PVA"> PVA</a>, <a href="https://publications.waset.org/abstracts/search?q=polymer-metal%20complex" title=" polymer-metal complex"> polymer-metal complex</a>, <a href="https://publications.waset.org/abstracts/search?q=urea" title=" urea"> urea</a> </p> <a href="https://publications.waset.org/abstracts/70839/synthesis-characterization-and-anti-microbial-study-of-urethanized-poly-vinyl-alcohol-metal-complexes" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/70839.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">338</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5743</span> Relaxation Dynamics of Quantum Emitters Resonantly Coupled to a Localized Surface Plasmon</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Khachatur%20V.%20Nerkararyan">Khachatur V. Nerkararyan</a>, <a href="https://publications.waset.org/abstracts/search?q=Sergey%20I.%20Bozhevolnyi"> Sergey I. Bozhevolnyi</a> </p> <p class="card-text"><strong>Abstract:</strong></p> We investigate relaxation dynamics of a quantum dipole emitter (QDE), e.g., a molecule or quantum dot, located near a metal nanoparticle (MNP) exhibiting a dipolar localized surface plasmon (LSP) resonance at the frequency of the QDE radiative transition. It is shown that under the condition of the QDE-MNP characteristic relaxation time being much shorter than that of the QDE in free-space but much longer than the LSP lifetime. It is also shown that energy dissipation in the QDE-MNP system is relatively weak with the probability of the photon emission being about 0.75, a number which, rather surprisingly, does not explicitly depend on the metal absorption characteristics. The degree of entanglement measured by the concurrency takes the maximum value, while the distances between the QDEs and metal ball approximately are equal. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=metal%20nanoparticle" title="metal nanoparticle">metal nanoparticle</a>, <a href="https://publications.waset.org/abstracts/search?q=localized%20surface%20plasmon" title=" localized surface plasmon"> localized surface plasmon</a>, <a href="https://publications.waset.org/abstracts/search?q=quantum%20dipole%20emitter" title=" quantum dipole emitter"> quantum dipole emitter</a>, <a href="https://publications.waset.org/abstracts/search?q=relaxation%20dynamics" title=" relaxation dynamics"> relaxation dynamics</a> </p> <a href="https://publications.waset.org/abstracts/28289/relaxation-dynamics-of-quantum-emitters-resonantly-coupled-to-a-localized-surface-plasmon" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/28289.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">452</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5742</span> Development of new Ecological Cleaning Process of Metal Sheets </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=L.%20M.%20L%C3%B3pez%20L%C3%B3pez">L. M. López López</a>, <a href="https://publications.waset.org/abstracts/search?q=J.%20V.%20Montesdeoca%20Contreras"> J. V. Montesdeoca Contreras</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20R.%20Cuji%20Fajardo"> A. R. Cuji Fajardo</a>, <a href="https://publications.waset.org/abstracts/search?q=L.%20E.%20Garz%C3%B3n%20Mu%C3%B1oz"> L. E. Garzón Muñoz</a>, <a href="https://publications.waset.org/abstracts/search?q=J.%20I.%20Fajardo%20Seminario"> J. I. Fajardo Seminario</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In this article a new method of cleaning process of metal sheets for household appliances was developed, using low-pressure cold plasma. In this context, this research consist in analyze the results of metal sheets cleaning process using plasma and compare with pickling process to determinate the efficiency of each process and the level of contamination produced. Surface Cleaning was evaluated by measuring the contact angle with deionized water, diiodo methane and ethylene glycol, for the calculus of the surface free energy by means of the Fowkes theories and Wu. Showing that low-pressure cold plasma is very efficient both in cleaning process how in environment impact. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=efficient%20use%20of%20plasma" title="efficient use of plasma">efficient use of plasma</a>, <a href="https://publications.waset.org/abstracts/search?q=ecological%20impact%20of%20plasma" title=" ecological impact of plasma"> ecological impact of plasma</a>, <a href="https://publications.waset.org/abstracts/search?q=metal%20sheets%20cleaning%20means" title=" metal sheets cleaning means"> metal sheets cleaning means</a>, <a href="https://publications.waset.org/abstracts/search?q=plasma%20cleaning%20process." title=" plasma cleaning process. "> plasma cleaning process. </a> </p> <a href="https://publications.waset.org/abstracts/30939/development-of-new-ecological-cleaning-process-of-metal-sheets" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/30939.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">355</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5741</span> Facile Synthesis of Metal Nanoparticles on Graphene via Galvanic Displacement Reaction for Sensing Application</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Juree%20Hong">Juree Hong</a>, <a href="https://publications.waset.org/abstracts/search?q=Sanggeun%20Lee"> Sanggeun Lee</a>, <a href="https://publications.waset.org/abstracts/search?q=Jungmok%20Seo"> Jungmok Seo</a>, <a href="https://publications.waset.org/abstracts/search?q=Taeyoon%20Lee"> Taeyoon Lee</a> </p> <p class="card-text"><strong>Abstract:</strong></p> We report a facile synthesis of metal nano particles (NPs) on graphene layer via galvanic displacement reaction between graphene-buffered copper (Cu) and metal ion-containing salts. Diverse metal NPs can be formed on graphene surface and their morphologies can be tailored by controlling the concentration of metal ion-containing salt and immersion time. The obtained metal NP-decorated single-layer graphene (SLG) has been used as hydrogen gas (H2) sensing material and exhibited highly sensitive response upon exposure to 2% of H2. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=metal%20nanoparticle" title="metal nanoparticle">metal nanoparticle</a>, <a href="https://publications.waset.org/abstracts/search?q=galvanic%20displacement%20reaction" title=" galvanic displacement reaction"> galvanic displacement reaction</a>, <a href="https://publications.waset.org/abstracts/search?q=graphene" title=" graphene"> graphene</a>, <a href="https://publications.waset.org/abstracts/search?q=hydrogen%20sensor" title=" hydrogen sensor"> hydrogen sensor</a> </p> <a href="https://publications.waset.org/abstracts/18400/facile-synthesis-of-metal-nanoparticles-on-graphene-via-galvanic-displacement-reaction-for-sensing-application" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/18400.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">425</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5740</span> Effect of Some Metal Ions on the Activity of Lipase Produced by Aspergillus Niger Cultured on Vitellaria Paradoxa Shells</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Abdulhakeem%20Sulyman">Abdulhakeem Sulyman</a>, <a href="https://publications.waset.org/abstracts/search?q=Olukotun%20Zainab"> Olukotun Zainab</a>, <a href="https://publications.waset.org/abstracts/search?q=Hammed%20Abdulquadri"> Hammed Abdulquadri</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Lipases (triacylglycerol acyl hydrolases) (EC 3.1.1.3) are class of enzymes that catalyses the hydrolysis of triglycerides to glycerol and free fatty acids. They account for up to 10% of the enzyme in the market and have a wide range of applications in biofuel production, detergent formulation, leather processing and in food and feed processing industry. This research was conducted to study the effect of some metal ions on the activity of purified lipase produced by Aspergillus niger cultured on Vitellaria paradoxa shells. Purified lipase in 12.5 mM p-NPL was incubated with different metal ions (Zn²⁺, Ca²⁺, Mn²⁺, Fe²⁺, Na⁺, K⁺ and Mg²⁺). The final concentrations of metal ions investigated were 0.1, 0.2, 0.3, 0.4, 0.5, 0.6, 0.7, 0.8, 0.9 and 1.0 mM. The results obtained from the study showed that Zn²⁺, Ca²⁺, Mn²⁺ and Fe²⁺ ions increased the activity of lipase up to 3.0, 3.0, 1.0, and 26.0 folds respectively. Lipase activity was partially inhibited by Na⁺ and Mg²⁺ with up to 88.5% and 83.7% loss of activity respectively. Lipase activity was also inhibited by K⁺ with up to 56.7% loss in the activity as compared to in the absence of metal ions. The study concluded that lipase produced by Aspergillus niger cultured on Vitellaria paradoxa shells can be activated by the presence of Zn²⁺, Ca²⁺, Mn²⁺ and Fe²⁺ and inhibited by Na⁺, K⁺ and Mg²⁺. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=Aspergillus%20niger" title="Aspergillus niger">Aspergillus niger</a>, <a href="https://publications.waset.org/abstracts/search?q=Vitellaria%20paradoxa" title=" Vitellaria paradoxa"> Vitellaria paradoxa</a>, <a href="https://publications.waset.org/abstracts/search?q=lipase" title=" lipase"> lipase</a>, <a href="https://publications.waset.org/abstracts/search?q=metal%20ions" title=" metal ions"> metal ions</a> </p> <a href="https://publications.waset.org/abstracts/111953/effect-of-some-metal-ions-on-the-activity-of-lipase-produced-by-aspergillus-niger-cultured-on-vitellaria-paradoxa-shells" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/111953.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">152</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5739</span> Organic Contaminant Degradation Using H₂O₂ Activated Biochar with Enhanced Persistent Free Radicals </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Kalyani%20Mer">Kalyani Mer</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Hydrogen peroxide (H₂O₂) is one of the most efficient and commonly used oxidants in in-situ chemical oxidation (ISCO) of organic contaminants. In the present study, we investigated the activation of H₂O₂ by heavy metal (nickel and lead metal ions) loaded biochar for phenol degradation in an aqueous solution (concentration = 100 mg/L). It was found that H₂O₂ can be effectively activated by biochar, which produces hydroxyl (•OH) radicals owing to an increase in the formation of persistent free radicals (PFRs) on biochar surface. Ultrasound treated (30s duration) biochar, chemically activated by 30% phosphoric acid and functionalized by diethanolamine (DEA) was used for the adsorption of heavy metal ions from aqueous solutions. It was found that modified biochar could remove almost 60% of nickel in eight hours; however, for lead, the removal efficiency reached up to 95% for the same time duration. The heavy metal loaded biochar was further used for the degradation of phenol in the absence and presence of H₂O₂ (20 mM), within 4 hours of reaction time. The removal efficiency values for phenol in the presence of H₂O₂ were 80.3% and 61.9%, respectively, by modified biochar loaded with nickel and lead metal ions. These results suggested that the biochar loaded with nickel exhibits a better removal capacity towards phenol than the lead loaded biochar when used in H₂O₂ based oxidation systems. Meanwhile, control experiments were set in the absence of any activating biochar, and the removal efficiency was found to be 19.1% when only H₂O₂ was added in the reaction solution. Overall, the proposed approach serves a dual purpose of using biochar for heavy metal ion removal and treatment of organic contaminants by further using the metal loaded biochar for H₂O₂ activation in ISCO processes. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=biochar" title="biochar">biochar</a>, <a href="https://publications.waset.org/abstracts/search?q=ultrasound" title=" ultrasound"> ultrasound</a>, <a href="https://publications.waset.org/abstracts/search?q=heavy%20metals" title=" heavy metals"> heavy metals</a>, <a href="https://publications.waset.org/abstracts/search?q=in-situ%20chemical%20oxidation" title=" in-situ chemical oxidation"> in-situ chemical oxidation</a>, <a href="https://publications.waset.org/abstracts/search?q=chemical%20activation" title=" chemical activation"> chemical activation</a> </p> <a href="https://publications.waset.org/abstracts/112706/organic-contaminant-degradation-using-h2o2-activated-biochar-with-enhanced-persistent-free-radicals" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/112706.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">135</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5738</span> Propane Dehydrogenation with Better Stability by a Modified Pt-Based Catalyst</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Napat%20Hataivichian">Napat Hataivichian</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The effect of transition metal doping on Pt/Al2O3 catalyst used in propane dehydrogenation reaction at 500˚C was studied. The preparation methods investigated were sequential impregnation (Pt followed by the 2nd metal or the 2nd metal followed by Pt) and co-impregnation. The metal contents of these catalysts were fixed as the weight ratio of Pt per the 2nd metal of around 0.075. These catalysts were characterized by N2-physisorption, TPR, CO-chemisorption and NH3-TPD. It was found that the impregnated 2nd metal had an effect upon reducibility of Pt due to its interaction with transition metal-containing structure. This was in agreement with the CO-chemisorption result that the presence of Pt metal, which is a result from Pt species reduction, was decreased. The total acidity of bimetallic catalysts is decreased but the strong acidity is slightly increased. It was found that the stability of bimetallic catalysts prepared by co-impregnation and sequential impregnation where the 2nd metal was impregnated before Pt were better than that of monometallic catalyst (undoped Pt one) due to the forming of Pt sites located on the transition metal-oxide modified surface. Among all preparation methods, the sequential impregnation method- having Pt impregnated before the 2nd metal gave the worst stability because this catalyst lacked the modified Pt sites and some fraction of Pt sites was covered by the 2nd metal. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=alumina" title="alumina">alumina</a>, <a href="https://publications.waset.org/abstracts/search?q=dehydrogenation" title=" dehydrogenation"> dehydrogenation</a>, <a href="https://publications.waset.org/abstracts/search?q=platinum" title=" platinum"> platinum</a>, <a href="https://publications.waset.org/abstracts/search?q=transition%20metal" title=" transition metal"> transition metal</a> </p> <a href="https://publications.waset.org/abstracts/25499/propane-dehydrogenation-with-better-stability-by-a-modified-pt-based-catalyst" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/25499.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">310</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5737</span> Preparation of Porous Metal Membrane by Thermal Annealing for Thin Film Encapsulation</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Jaibir%20Sharma">Jaibir Sharma</a>, <a href="https://publications.waset.org/abstracts/search?q=Lee%20JaeWung"> Lee JaeWung</a>, <a href="https://publications.waset.org/abstracts/search?q=Merugu%20Srinivas"> Merugu Srinivas</a>, <a href="https://publications.waset.org/abstracts/search?q=Navab%20Singh"> Navab Singh </a> </p> <p class="card-text"><strong>Abstract:</strong></p> This paper presents thermal annealing dewetting technique for the preparation of porous metal membrane for thin film encapsulation application. Thermal annealing dewetting experimental results reveal that pore size in porous metal membrane depend upon i.e. 1. The substrate on which metal is deposited for formation of porous metal cap membrane, 2. Melting point of metal used for porous metal cap layer membrane formation, 3. Thickness of metal used for cap layer, 4. Temperature used for porous metal membrane formation. Silver (Ag) was used as a metal for preparation of porous metal membrane by annealing the film at different temperature. Pores in porous silver film were analyzed using Scanning Electron Microscope (SEM). In order to check the usefulness of porous metal film for thin film encapsulation application, the porous silver film prepared on amorphous silicon (a-Si) was release using XeF2. Finally, guide line and structures are suggested to use this porous membrane for thin film encapsulation (TFE) application. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=dewetting" title="dewetting">dewetting</a>, <a href="https://publications.waset.org/abstracts/search?q=themal%20annealing" title=" themal annealing"> themal annealing</a>, <a href="https://publications.waset.org/abstracts/search?q=metal" title=" metal"> metal</a>, <a href="https://publications.waset.org/abstracts/search?q=melting%20point" title=" melting point"> melting point</a>, <a href="https://publications.waset.org/abstracts/search?q=porous" title=" porous"> porous</a> </p> <a href="https://publications.waset.org/abstracts/31602/preparation-of-porous-metal-membrane-by-thermal-annealing-for-thin-film-encapsulation" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/31602.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">658</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5736</span> Graphene-Intercalated P4Se3@CNF Hybrid Electrode for Sustainable Energy Storage Solution: Enabling High Energy Density and Ultra-long Cyclic Stability</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Daya%20Rani">Daya Rani</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Non-metal-based compounds have emerged as promising electrodes in recent years to replace scarce and expensive transition-metals for energy storage applications. Herein, a simple electro-spinning technique followed by carbonization is used to create tetraphosphorus triselenide(P4Se3)nano-flakes encapsulated in carbon nanofiber (P4Se3@CNF) to obtain a binder-free, metal-free and flexible hybrid electrode with high electrical conductivity and cyclic stability. A remarkable capacitive performance (5.5-folds@P4Se3) of 810Fg-1/<a href="/cdn-cgi/l/email-protection" class="__cf_email__" data-cfemail="447575766a7129052c23697504746a7d05236975">[email protected]</a> has been obtained using P4Se3@CNF electrode with an excellent rate capability compared to pristine(P4Se3) which is further supported by theoretical calculations via intercalating graphene within bare P4Se3 flakes inducing partial charge redistribution in hetero-structure. A flexible pouch-type hybrid-supercapacitor followed by coin-cell has been manufactured offering exceptional energy-density without sacrificing power density and ultra-long durability over 35000 and 100000-cycles with capacitance-retention of 99.77% and 100%, respectively. It has been demonstrated that as-fabricated device has practical usefulness towards renewable energy harvesting and storage via integrating commercial solar cell module with supercapattery array that can enlighten the blue LED approximately for 31minutes, rotate the homemade windmill device, power Arduino and glow “INST” against 2minutes of charging. This work demonstrates a facile route towards the development of metal-free electrochemical renewable energy storage/transfer devices offering an inevitable adoption in industrial platforms. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=metal%20free" title="metal free">metal free</a>, <a href="https://publications.waset.org/abstracts/search?q=carbon%20nano-fiber" title=" carbon nano-fiber"> carbon nano-fiber</a>, <a href="https://publications.waset.org/abstracts/search?q=pouch-type%20hybrid%20super-capacitor" title=" pouch-type hybrid super-capacitor"> pouch-type hybrid super-capacitor</a>, <a href="https://publications.waset.org/abstracts/search?q=nano-flakes" title=" nano-flakes"> nano-flakes</a> </p> <a href="https://publications.waset.org/abstracts/193022/graphene-intercalated-p4se3-at-cnf-hybrid-electrode-for-sustainable-energy-storage-solution-enabling-high-energy-density-and-ultra-long-cyclic-stability" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/193022.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">22</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5735</span> Effect of Vibration Amplitude and Welding Force on Weld Strength of Ultrasonic Metal Welding</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ziad.%20Sh.%20Al%20Sarraf">Ziad. Sh. Al Sarraf</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Ultrasonic metal welding has been the subject of ongoing research and development, most recently concentrating on metal joining in miniature devices, for example to allow solder-free wire bonding. As well as at the small scale, there are also opportunities to research the joining of thicker sheet metals and to widen the range of similar and dissimilar materials that can be successfully joined using this technology. This study presents the design, characterisation and test of a lateral-drive ultrasonic metal spot welding device. The ultrasonic metal spot welding horn is modelled using finite element analysis (FEA) and its vibration behaviour is characterised experimentally to ensure ultrasonic energy is delivered effectively to the weld coupon. The welding stack and fixtures are then designed and mounted on a test machine to allow a series of experiments to be conducted for various welding and ultrasonic parameters. Weld strength is subsequently analysed using tensile-shear tests. The results show how the weld strength is particularly sensitive to the combination of clamping force and ultrasonic vibration amplitude of the welding tip, but there are optimal combinations of these and also limits that must be clearly identified. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=ultrasonic%20welding" title="ultrasonic welding">ultrasonic welding</a>, <a href="https://publications.waset.org/abstracts/search?q=vibration%20amplitude" title=" vibration amplitude"> vibration amplitude</a>, <a href="https://publications.waset.org/abstracts/search?q=welding%20force" title=" welding force"> welding force</a>, <a href="https://publications.waset.org/abstracts/search?q=weld%20strength" title=" weld strength"> weld strength</a> </p> <a href="https://publications.waset.org/abstracts/41161/effect-of-vibration-amplitude-and-welding-force-on-weld-strength-of-ultrasonic-metal-welding" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/41161.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">368</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5734</span> Effect of Vesicular Arbuscular mycorrhiza on Phytoremedial Potential and Physiological Changes in Solanum melongena Plants Grown under Heavy Metal Stress</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ritu%20Chaturvedi">Ritu Chaturvedi</a>, <a href="https://publications.waset.org/abstracts/search?q=Mayank%20Varun"> Mayank Varun</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20S.%20Paul"> M. S. Paul</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Heavy metal contamination of soil is a growing area of concern since the soil is the matrix that supports flora and impacts humans directly. Phytoremediation of contaminated sites is gaining popularity due to its cost effectiveness and solar driven nature. Some hyperaccumulators have been identified for their potential. Metal-accumulating plants have various mechanisms to cope up with stress and one of them is increasing antioxidative capacity. The aim of this research is to assess the effect of Vesicular arbuscular mycorrhiza (VAM) application on the phytoremedial potential of Solanum melongena (Eggplant) and level of photosynthetic pigments along with antioxidative enzymes. Results showed that VAM application increased shoot length, root proliferation pattern of plants. The level of photosynthetic pigments, proline, SOD, CAT, APX altered significantly in response to heavy metal treatment. In conclusion, VAM increased the uptake of heavy metals which lead to the activation of the defense system in plants for scavenging free radicals. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=heavy%20metal" title="heavy metal">heavy metal</a>, <a href="https://publications.waset.org/abstracts/search?q=phytoextraction" title=" phytoextraction"> phytoextraction</a>, <a href="https://publications.waset.org/abstracts/search?q=phytostabilization" title=" phytostabilization"> phytostabilization</a>, <a href="https://publications.waset.org/abstracts/search?q=reactive%20oxygen%20species" title=" reactive oxygen species"> reactive oxygen species</a> </p> <a href="https://publications.waset.org/abstracts/63409/effect-of-vesicular-arbuscular-mycorrhiza-on-phytoremedial-potential-and-physiological-changes-in-solanum-melongena-plants-grown-under-heavy-metal-stress" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/63409.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">275</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5733</span> Equilibrium, Kinetics, and Thermodynamic Studies on Heavy Metal Biosorption by Trichoderma Species</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Sobia%20Mushtaq">Sobia Mushtaq</a>, <a href="https://publications.waset.org/abstracts/search?q=Firdaus%20E.%20Bareen"> Firdaus E. Bareen</a>, <a href="https://publications.waset.org/abstracts/search?q=Asma%20Tayyeb"> Asma Tayyeb</a> </p> <p class="card-text"><strong>Abstract:</strong></p> This study conducted to investigate the metal biosorption potential of indigenous Trichoderma species (T. harzianum KS05T01, T. longibrachiatum KS09T03, Trichoderma sp KS17T09., T. viridi KS17T011, T. atrobruneo KS21T014, and T. citrinoviride) that have been isolated from contaminated soil of Kasur Tannery Waste Management Agency. The effect of different biosorption parameters as initial metal ion concentration, pH, contact time , and temperature of incubation was investigated on the biosorption potential of these species. The metal removal efficiency and (E%) and metal uptake capacity (mg/g) increased along with the increase of initial metal concentration in media. The Trichoderma species can tolerate and survive under heavy metal stress up to 800mg/L. Among the two isotherm models were applied on the biosorption data, Langmuir isotherm model and Freundlich isotherm model, maximum correlation coefficients values (R 2 ) of 1was found for Langmuir model, which showed the better fitted model for the Trichoderma biosorption. The metal biosorption was increased with the increase of temperature and pH of the media. The maximum biosorption was observed between 25-30 o C and at pH 6.-7.5, while the biosorption rate was increased from 3-6 days of incubation, and then the rate of biosorption was slowed down. The biosorption data was better fitted for Pseudo kinetic first order during the initial days of biosorption. Thermodynamic parameters as standard Gibbs free energy (G), standard enthalpy change (H), and standard entropy (S) were calculated. The results confirmed the heavy metal biosorption by Trichoderma species was endothermic and spontaneous reaction in nature. The FTIR spectral analysis and SEM-EDX analysis of the treated and controlled mycelium revealed the changes in the active functional sites and morphological variations of the outer surface. The data analysis envisaged that high metal tolerance exhibited by Trichoderma species indicates its potential as efficacious and successful mediator for bioremediation of the heavy metal polluted environments. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=heavy%20metal" title="heavy metal">heavy metal</a>, <a href="https://publications.waset.org/abstracts/search?q=fungal%20biomass" title=" fungal biomass"> fungal biomass</a>, <a href="https://publications.waset.org/abstracts/search?q=biosorption" title=" biosorption"> biosorption</a>, <a href="https://publications.waset.org/abstracts/search?q=kinetics" title=" kinetics"> kinetics</a> </p> <a href="https://publications.waset.org/abstracts/146434/equilibrium-kinetics-and-thermodynamic-studies-on-heavy-metal-biosorption-by-trichoderma-species" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/146434.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">122</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5732</span> Synthesis of Pendent Compartmental Ligand Derived from Polymethacrylate of 3-Formylsalicylic Acid Schiff Base and Its Application Studies</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Dhivya%20Arumugam">Dhivya Arumugam</a>, <a href="https://publications.waset.org/abstracts/search?q=Kaliyappan%20Thananjeyan"> Kaliyappan Thananjeyan</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The monomer of (3-((4-(methacryloyloxy)phenylimino)methyl)-2-hydroxybenzoic acid) schiff base polymer was prepared by reacting methacryloyl chloride with imine compound derived from 3-formylsalisylic acid and 4- aminophenol. The monomer was polymerized in DMF at 70oC using benzoyl peroxide as free radical initiator. Polymer metal complex was obtained in DMF solution of polymer with aqueous solution of metal ions. The polymer and the polymer metal complex were characterized by elemental analysis and spectral studies. The elemental analysis data suggest that the metal to ligand ratio is 1:1 and hence, it acts as a binucleating compartmental ligand. The IR spectral data of these complexes suggest that the metals are coordinated through nitrogen of the imine group, the oxygen of carboxylate ion and the oxygen of the phenolic –OH group which also acts as the bridging ligand. The electronic spectra and magnetic moments of the polychelates shows that octahedral and square planar structure for Ni(II) and Cu(II) complexes respectively. X-ray diffraction studies revealed that polychelates are highly crystalline. The thermal and electrical properties, catalytic activity, structure property relationships are discussed. Further the synthesized polymer was used for metal uptake studies from waste water, which is one of the effective waste water treatment strategies. And also, the polymers and polychelates were investigated for antimicrobial activity with various microorganisms by using agar well diffusion method and the results have been discussed. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=acyclic%20compartmental%20ligands" title="acyclic compartmental ligands">acyclic compartmental ligands</a>, <a href="https://publications.waset.org/abstracts/search?q=binucleating%20ligand" title=" binucleating ligand"> binucleating ligand</a>, <a href="https://publications.waset.org/abstracts/search?q=3-formylsalicylic%20acid" title=" 3-formylsalicylic acid"> 3-formylsalicylic acid</a>, <a href="https://publications.waset.org/abstracts/search?q=free%20radical%20polymerization" title=" free radical polymerization"> free radical polymerization</a>, <a href="https://publications.waset.org/abstracts/search?q=polluting%20ions" title=" polluting ions"> polluting ions</a>, <a href="https://publications.waset.org/abstracts/search?q=polychelate" title=" polychelate"> polychelate</a> </p> <a href="https://publications.waset.org/abstracts/150724/synthesis-of-pendent-compartmental-ligand-derived-from-polymethacrylate-of-3-formylsalicylic-acid-schiff-base-and-its-application-studies" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/150724.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">127</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5731</span> Electrochemical/Electro-Catalytic Applications of Novel Alcohol Substituted Metallophthalocyanines</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ipek%20Gunay">Ipek Gunay</a>, <a href="https://publications.waset.org/abstracts/search?q=Efe%20B.%20Orman"> Efe B. Orman</a>, <a href="https://publications.waset.org/abstracts/search?q=Metin%20Ozer"> Metin Ozer</a>, <a href="https://publications.waset.org/abstracts/search?q=Bekir%20Salih"> Bekir Salih</a>, <a href="https://publications.waset.org/abstracts/search?q=Ali%20R.%20Ozkaya"> Ali R. Ozkaya</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Phthalocyanines with macrocyclic ring containing at least three heteroatoms have nine or more membered structures. Metal-free phthalocyanines react with metal salts to obtain chelate complexes. This is one of the most important features of metal-free phthalocyanine as ligand structure. Although phthalocyanines have very similar properties with porphyrins, they have some advantages such as lower cost, easy to prepare, and chemical and thermal stability. It’s known that Pc compounds have shown one-electron metal-and/or ligand-based reversible or quasi-reversible reduction and oxidation processes. The redox properties of phthalocyanines are critically related to the desirable properties of these compounds in their technological applications. Thus, Pc complexes have also been receiving increasing interest in the area of fuel cells due to their high electrocatalytic activity in dioxygen reduction and fuel cell applications. In this study, novel phthalocyanine complexes coordinated with Fe(II) and Co (II) to be used as catalyst were synthesized. Aiming this goal, a new nitrile ligand was synthesized starting from 4-hydroxy-3,5-dimethoxy benzyl alcohol and 4-nitrophthalonitrile in the presence of K2CO3 as catalyst. After the isolation of the new type of nitrile and metal complexes, the characterization of mentioned compounds was achieved by IR, H-NMR and UV-vis methods. In addition, the electrochemical behaviour of Pc complexes was identified by cyclic voltammetry, square wave voltammetry and in situ spectroelectrochemical measurements. Furthermore, the catalytic performances of Pc complexes for oxygen reduction were tested by dynamic voltammetry measurements, carried out by the combined system of rotating ring-disk electrode and potentiostat, in a medium similar to fuel-cell working conditions. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=phthalocyanine" title="phthalocyanine">phthalocyanine</a>, <a href="https://publications.waset.org/abstracts/search?q=electrocatalysis" title=" electrocatalysis"> electrocatalysis</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochemistry" title=" electrochemistry"> electrochemistry</a>, <a href="https://publications.waset.org/abstracts/search?q=in-situ%20spectroelectrochemistry" title=" in-situ spectroelectrochemistry"> in-situ spectroelectrochemistry</a> </p> <a href="https://publications.waset.org/abstracts/76061/electrochemicalelectro-catalytic-applications-of-novel-alcohol-substituted-metallophthalocyanines" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/76061.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">316</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5730</span> Heavy Metal Concentration in Orchard Area, Amphawa District, Samut Songkram Province, Thailand</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Sisuwan%20Kaseamsawat">Sisuwan Kaseamsawat</a>, <a href="https://publications.waset.org/abstracts/search?q=Sivapan%20Choo-In"> Sivapan Choo-In</a> </p> <p class="card-text"><strong>Abstract:</strong></p> A study was conducted in May to July 2013 with the aim of determination of heavy metal concentration in orchard area. 60 samples were collected and analyzed for Cadmium (Cd), Copper (Cu), Lead (Pb), and Zinc (Zn) by Atomic Absorption Spectrophotometer (AAS). The heavy metal concentrations in sediment of orchards, that use chemical for Cd (1.13 ± 0.26 mg/l), Cu (8.00 ± 1.05 mg/l), Pb (13.16 ± 2.01) and Zn (37.41 ± 3.20 mg/l). The heavy metal concentrations in sediment of the orchards, that do not use chemical for Cd (1.28 ± 0.50 mg/l), Cu (7.60 ± 1.20 mg/l), Pb (29.87 ± 4.88) and Zn (21.79 ± 2.98 mg/l). Statistical analysis between heavy metal in sediment from the orchard, that use chemical and the orchard, that not use chemical were difference statistic significant of 0.5 level of significant for Cd and Pb while no statistically difference for Cu and Zn. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=heavy%20metal" title="heavy metal">heavy metal</a>, <a href="https://publications.waset.org/abstracts/search?q=orchard" title=" orchard"> orchard</a>, <a href="https://publications.waset.org/abstracts/search?q=pollution%20and%20monitoring" title=" pollution and monitoring"> pollution and monitoring</a>, <a href="https://publications.waset.org/abstracts/search?q=sediment" title=" sediment"> sediment</a> </p> <a href="https://publications.waset.org/abstracts/8591/heavy-metal-concentration-in-orchard-area-amphawa-district-samut-songkram-province-thailand" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/8591.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">385</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5729</span> Use of Microbial Fuel Cell for Metal Recovery from Wastewater</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Surajbhan%20Sevda">Surajbhan Sevda</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Metal containing wastewater is generated in large quintiles due to rapid industrialization. Generally, the metal present in wastewater is not biodegradable and can be accumulated in living animals, humans and plant tissue, causing disorder and diseases. The conventional metal recovery methods include chemical, physical and biological methods, but these are chemical and energy intensive. The recent development in microbial fuel cell (MFC) technology provides a new approach for metal recovery; this technology offers a flexible platform for both reduction and oxidation reaction oriented process. The use of MFCs will be a new platform for more efficient and low energy approach for metal recovery from the wastewater. So far metal recover was extensively studied using chemical, physical and biological methods. The MFCs present a new and efficient approach for removing and recovering metals from different wastewater, suggesting the use of different electrode for metal recovery can be a new efficient and effective approach. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=metal%20recovery" title="metal recovery">metal recovery</a>, <a href="https://publications.waset.org/abstracts/search?q=microbial%20fuel%20cell" title=" microbial fuel cell"> microbial fuel cell</a>, <a href="https://publications.waset.org/abstracts/search?q=wastewater" title=" wastewater"> wastewater</a>, <a href="https://publications.waset.org/abstracts/search?q=bioelectricity" title=" bioelectricity"> bioelectricity</a> </p> <a href="https://publications.waset.org/abstracts/78731/use-of-microbial-fuel-cell-for-metal-recovery-from-wastewater" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/78731.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">218</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5728</span> Adsorption of Lead and Zinc Ions Onto Chemical Activated Millet Husk: Equilibrium and Kinetics Studies</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Hilary%20Rutto">Hilary Rutto</a>, <a href="https://publications.waset.org/abstracts/search?q=Linda%20Sibali"> Linda Sibali</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In this study, the adsorption of lead and zinc ions from aqueous solutions by modified millet husk has been investigated. The effects of different parameters, such as pH, adsorbent dosage, concentration, temperature, and contact time, have been investigated. The results of the experiments showed that the adsorption of both metal ions increased by increasing pH values up to 11. Adsorption process was initially fast. The adsorption rate decreased then until it reached to equilibrium time of 120 min for both lead and zinc ions. The Langmuir, Freundlich, Dubinin-Radushkevich (D-R), and thermodynamic models (Gibbs free energy) were used to determine the isotherm parameters associated with the adsorption process. The positive values of Gibbs free energy change indicated that reaction is not spontaneous. Experimental data were also evaluated in terms of kinetic characteristics of adsorption, and it was found that adsorption process for both metal ions followed pseudo-first order for zinc and pseudo-second-order for lead. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=zinc" title="zinc">zinc</a>, <a href="https://publications.waset.org/abstracts/search?q=lead" title=" lead"> lead</a>, <a href="https://publications.waset.org/abstracts/search?q=adsorption" title=" adsorption"> adsorption</a>, <a href="https://publications.waset.org/abstracts/search?q=millet%20husks" title=" millet husks"> millet husks</a> </p> <a href="https://publications.waset.org/abstracts/130830/adsorption-of-lead-and-zinc-ions-onto-chemical-activated-millet-husk-equilibrium-and-kinetics-studies" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/130830.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">168</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5727</span> A Review on the Mechanism Removal of Pesticides and Heavy Metal from Agricultural Runoff in Treatment Train</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=N.%20A.%20Ahmad%20Zubairi">N. A. Ahmad Zubairi</a>, <a href="https://publications.waset.org/abstracts/search?q=H.%20Takaijudin"> H. Takaijudin</a>, <a href="https://publications.waset.org/abstracts/search?q=K.%20W.%20Yusof"> K. W. Yusof</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Pesticides have been used widely over the world in agriculture to protect from pests and reduce crop losses. However, it affects the environment with toxic chemicals. Exceed of toxic constituents in the ecosystem will result in bad side effects. The hydrological cycle is related to the existence of pesticides and heavy metal which it can penetrate through varieties of sources into the soil or water bodies, especially runoff. Therefore, proper mechanisms of pesticide and heavy metal removal should be studied to improve the quality of ecosystem free or reduce from unwanted substances. This paper reviews the use of treatment train and its mechanisms to minimize pesticides and heavy metal from agricultural runoff. Organochlorine (OCL) is a common pesticide that was found in the agricultural runoff. OCL is one of the toxic chemicals that can disturb the ecosystem such as inhibiting plants' growth and harm human health by having symptoms as asthma, active cancer cell, vomit, diarrhea, etc. Thus, this unwanted contaminant gives disadvantages to the environment and needs treatment system. Hence, treatment train by bioretention system is suitable because removal efficiency achieves until 90% of pesticide removal with selected vegetated plant and additive. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=pesticides" title="pesticides">pesticides</a>, <a href="https://publications.waset.org/abstracts/search?q=heavy%20metal" title=" heavy metal"> heavy metal</a>, <a href="https://publications.waset.org/abstracts/search?q=agricultural%20runoff" title=" agricultural runoff"> agricultural runoff</a>, <a href="https://publications.waset.org/abstracts/search?q=bioretention" title=" bioretention"> bioretention</a>, <a href="https://publications.waset.org/abstracts/search?q=mechanism%20removal" title=" mechanism removal"> mechanism removal</a>, <a href="https://publications.waset.org/abstracts/search?q=treatment%20train" title=" treatment train"> treatment train</a> </p> <a href="https://publications.waset.org/abstracts/130426/a-review-on-the-mechanism-removal-of-pesticides-and-heavy-metal-from-agricultural-runoff-in-treatment-train" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/130426.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">159</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5726</span> In situ One-Step Synthesis of Graphene Quantum Dots-Metal Free and Zinc Phthalocyanines Conjugates: Investigation of Photophysicochemical Properties</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=G.%20Fomo">G. Fomo</a>, <a href="https://publications.waset.org/abstracts/search?q=O.%20J.%20Achadu"> O. J. Achadu</a>, <a href="https://publications.waset.org/abstracts/search?q=T.%20Nyokong"> T. Nyokong</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Nanoconjugates of graphene quantum dots (GQDs) and 4-(tetrakis-5-(trifluoromethyl)-2-mercaptopyridinephthalocyanine (H₂Pc(OPyF₃)₄) or 4-(tetrakis-5-(trifluoromethyl)-2-mercaptopyridinephthalocyaninato) zinc (II) (ZnPc(OPyF₃)₄) were synthesized via a novel in situ one-step route. The bottom-up approach for the prepared conjugates could ensure the intercalation of the phthalocyanines (Pcs) directly onto the edges or surface of the GQDs and or non-covalent coordination using the π-electron systems of both materials. The as-synthesized GQDs and their Pcs conjugates were characterized using different spectroscopic techniques and their photophysicochemical properties evaluated. The singlet oxygen quantum yields of the Pcs in the presence of GQDs were enhanced due to Förster resonance energy transfer (FRET) occurrence within the conjugated hybrids. Hence, these nanoconjugates are potential materials for photodynamic therapy (PDT) and photocatalysis applications. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=graphene%20quantum%20dots" title="graphene quantum dots">graphene quantum dots</a>, <a href="https://publications.waset.org/abstracts/search?q=metal%20free%20fluorinated%20phthalocyanine" title=" metal free fluorinated phthalocyanine"> metal free fluorinated phthalocyanine</a>, <a href="https://publications.waset.org/abstracts/search?q=zinc%20fluorinated%20phthalocyanine" title=" zinc fluorinated phthalocyanine"> zinc fluorinated phthalocyanine</a>, <a href="https://publications.waset.org/abstracts/search?q=photophysicochemical%20properties" title=" photophysicochemical properties "> photophysicochemical properties </a> </p> <a href="https://publications.waset.org/abstracts/73210/in-situ-one-step-synthesis-of-graphene-quantum-dots-metal-free-and-zinc-phthalocyanines-conjugates-investigation-of-photophysicochemical-properties" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/73210.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">182</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5725</span> Coordination Behavior, Theoretical Studies, and Biological Activity of Some Transition Metal Complexes with Oxime Ligands</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Noura%20Kichou">Noura Kichou</a>, <a href="https://publications.waset.org/abstracts/search?q=Manel%20Tafergguenit"> Manel Tafergguenit</a>, <a href="https://publications.waset.org/abstracts/search?q=Nabila%20Ghechtouli"> Nabila Ghechtouli</a>, <a href="https://publications.waset.org/abstracts/search?q=Zakia%20Hank"> Zakia Hank</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The aim of this work is to synthesize, characterize and evaluate the biological activity of two Ligands : glyoxime and dimethylglyoxime, and their metal Ni(II) chelates. The newly chelates were characterized by elemental analysis, IR, EPR, nuclear magnetic resonances (1H and 13C), and biological activity. The antibacterial and antifungal activities of the ligands and its metal complexes were screened against bacterial species (Staphylococcus aureus, Bacillus subtilis, and Escherichia coli) and fungi (Candida albicans). Ampicillin and amphotericin were used as references for antibacterial and antifungal studies. The activity data show that the metal complexes have a promising biological activity comparable with parent free ligand against bacterial and fungal species. A structural, energetic, and electronic theoretical study was carried out using the DFT method, with the functional B3LYP and the gaussian program 09. A complete optimization of geometries was made, followed by a calculation of the frequencies of the normal modes of vibration. The UV spectrum was also interpreted. The theoretical results were compared with the experimental data. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=glyoxime" title="glyoxime">glyoxime</a>, <a href="https://publications.waset.org/abstracts/search?q=dimetylglyoxime" title=" dimetylglyoxime"> dimetylglyoxime</a>, <a href="https://publications.waset.org/abstracts/search?q=nickel" title=" nickel"> nickel</a>, <a href="https://publications.waset.org/abstracts/search?q=antibacterial%20activity" title=" antibacterial activity"> antibacterial activity</a> </p> <a href="https://publications.waset.org/abstracts/157809/coordination-behavior-theoretical-studies-and-biological-activity-of-some-transition-metal-complexes-with-oxime-ligands" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/157809.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">107</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5724</span> Coordination Behavior, Theoretical studies and Biological Activity of Some Transition Metal Complexes with Oxime Ligands</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Noura%20Kichou">Noura Kichou</a>, <a href="https://publications.waset.org/abstracts/search?q=Manel%20Tafergguenit"> Manel Tafergguenit</a>, <a href="https://publications.waset.org/abstracts/search?q=Nabila%20Ghechtouli"> Nabila Ghechtouli</a>, <a href="https://publications.waset.org/abstracts/search?q=Zakia%20Hank"> Zakia Hank</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The aim of this work is to synthesize, characterize and evaluate the biological activity of two Ligands: glyoxime and dimethylglyoxime, and their metal Ni(II) chelates. The newly chelates were characterized by elemental analysis, IR, EPR, nuclear magnetic resonances (1H and 13C), and biological activity. The antibacterial and antifungal activities of the ligands and its metal complexes were screened against bacterial species (Staphylococcus aureus, Bacillus subtilis, and Escherichia coli) and fungi (Candida albicans). Ampicillin and amphotericin were used as references for antibacterial and antifungal studies. The activity data show that the metal complexes have a promising biological activity comparable with parent free ligand against bacterial and fungal species. A structural, energetic, and electronic theoretical study was carried out using the DFT method, with the functional B3LYP and the gaussian program 09. A complete optimization of geometries was made, followed by a calculation of the frequencies of the normal modes of vibration. The UV spectrum was also interpreted. The theoretical results were compared with the experimental data. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=glyoxime" title="glyoxime">glyoxime</a>, <a href="https://publications.waset.org/abstracts/search?q=dimetylglyoxime" title=" dimetylglyoxime"> dimetylglyoxime</a>, <a href="https://publications.waset.org/abstracts/search?q=nickel" title=" nickel"> nickel</a>, <a href="https://publications.waset.org/abstracts/search?q=antibacterial%20activity" title=" antibacterial activity"> antibacterial activity</a> </p> <a href="https://publications.waset.org/abstracts/157862/coordination-behavior-theoretical-studies-and-biological-activity-of-some-transition-metal-complexes-with-oxime-ligands" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/157862.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">112</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5723</span> Ag and Au Nanoparticles Fabrication in Cross-Linked Polymer Microgels for Their Comparative Catalytic Study</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Luqman%20Ali%20Shah">Luqman Ali Shah</a>, <a href="https://publications.waset.org/abstracts/search?q=Murtaza%20Sayed"> Murtaza Sayed</a>, <a href="https://publications.waset.org/abstracts/search?q=Mohammad%20Siddiq"> Mohammad Siddiq</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Three-dimensional cross-linked polymer microgels with temperature responsive N-isopropyl acrylamide (NIPAM) and pH-sensitive methacrylic acid (MAA) were successfully synthesized by free radical emulsion polymerization with different amount of MAA. Silver and gold nanoparticles with size of 6.5 and 3.5 nm (±0.5 nm) respectively were homogeneously reduced inside these materials by chemical reduction method at pH 2.78 and 8.36 for the preparation of hybrid materials. The samples were characterized by FTIR, DLS and TEM techniques. The catalytic activity of the hybrid materials was investigated for the reduction of 4-nitrophenol (4- NP) using NaBH4 as reducing agent by UV-visible spectroscopy. The hybrid polymer network synthesized at pH 8.36 shows enhanced catalytic efficiency compared to catalysts synthesized at pH 2.78. In this study, it has been explored that catalyst activity strongly depends on amount of MAA, synthesis pH and type of metal nanoparticles entrapped. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=cross-linked%20polymer%20microgels" title="cross-linked polymer microgels">cross-linked polymer microgels</a>, <a href="https://publications.waset.org/abstracts/search?q=free%20radical%20polymerization" title=" free radical polymerization"> free radical polymerization</a>, <a href="https://publications.waset.org/abstracts/search?q=metal%20nanoparticles" title=" metal nanoparticles"> metal nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=catalytic%20activity" title=" catalytic activity"> catalytic activity</a>, <a href="https://publications.waset.org/abstracts/search?q=comparative%20study" title=" comparative study"> comparative study</a> </p> <a href="https://publications.waset.org/abstracts/60410/ag-and-au-nanoparticles-fabrication-in-cross-linked-polymer-microgels-for-their-comparative-catalytic-study" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/60410.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">324</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5722</span> Investigation of Cylindrical Multi-Layer Hybrid Plasmonic Waveguides</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Prateeksha%20Sharma">Prateeksha Sharma</a>, <a href="https://publications.waset.org/abstracts/search?q=V.%20Dinesh%20Kumar"> V. Dinesh Kumar</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Performances of cylindrical multilayer hybrid plasmonic waveguides have been investigated in detail considering their structural and material aspects. Characteristics of hybrid metal insulator metal (HMIM) and hybrid insulator metal insulator (HIMI) waveguides have been compared on the basis of propagation length and confinement factor. Necessity of this study is to understand newer kind of waveguides that overcome the limitations of conventional waveguides. Investigation reveals that sub wavelength confinement can be obtained in two low dielectric spacer layers. This study provides gateway for many applications such as nano lasers, interconnects, bio sensors and optical trapping etc. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=hybrid%20insulator%20metal%20insulator" title="hybrid insulator metal insulator">hybrid insulator metal insulator</a>, <a href="https://publications.waset.org/abstracts/search?q=hybrid%20metal%20insulator%20metal" title=" hybrid metal insulator metal"> hybrid metal insulator metal</a>, <a href="https://publications.waset.org/abstracts/search?q=nano%20laser" title=" nano laser"> nano laser</a>, <a href="https://publications.waset.org/abstracts/search?q=surface%20plasmon%20polariton" title=" surface plasmon polariton"> surface plasmon polariton</a> </p> <a href="https://publications.waset.org/abstracts/33732/investigation-of-cylindrical-multi-layer-hybrid-plasmonic-waveguides" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/33732.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">427</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5721</span> A Systamatic Review on Experimental, FEM Analysis and Simulation of Metal Spinning Process</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Amol%20M.%20Jadhav">Amol M. Jadhav</a>, <a href="https://publications.waset.org/abstracts/search?q=Sharad%20S.%20Chudhari"> Sharad S. Chudhari</a>, <a href="https://publications.waset.org/abstracts/search?q=S.%20S.%20Khedkar"> S. S. Khedkar</a> </p> <p class="card-text"><strong>Abstract:</strong></p> This review presents a through survey of research paper work on the experimental analysis, FEM Analysis & simulation of the metal spinning process. In this literature survey all the papers being taken from Elsevier publication and most of the from journal of material processing technology. In a last two decade or so, metal spinning process gradually used as chip less formation for the production of engineering component in a small to medium batch quantities. The review aims to provide include into the experimentation, FEM analysis of various components, simulation of metal spinning process and act as guide for research working on metal spinning processes. The review of existing work has several gaps in current knowledge of metal spinning processes. The evaluation of experiment is thickness strain, the spinning force, the twisting angle, the surface roughness of the conventional & shear metal spinning process; the evaluation of FEM of metal spinning to path definition with sufficient fine mesh to capture behavior of work piece; The evaluation of feed rate of roller, direction of roller,& type of roller stimulated. The metal spinning process has the more flexible to produce a wider range of product shape & to form more challenge material. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=metal%20spinning" title="metal spinning">metal spinning</a>, <a href="https://publications.waset.org/abstracts/search?q=FEM%20analysis" title=" FEM analysis"> FEM analysis</a>, <a href="https://publications.waset.org/abstracts/search?q=simulation%20of%20metal%20spinning" title=" simulation of metal spinning"> simulation of metal spinning</a>, <a href="https://publications.waset.org/abstracts/search?q=mechanical%20engineering" title=" mechanical engineering"> mechanical engineering</a> </p> <a href="https://publications.waset.org/abstracts/17246/a-systamatic-review-on-experimental-fem-analysis-and-simulation-of-metal-spinning-process" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/17246.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">387</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5720</span> Porous Carbon Nanoparticels Co-Doped with Nitrogen and Iron as an Efficient Catalyst for Oxygen Reduction Reaction</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Bita%20Bayatsarmadi">Bita Bayatsarmadi</a>, <a href="https://publications.waset.org/abstracts/search?q=Shi-Zhang%20Qiao"> Shi-Zhang Qiao</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Oxygen reduction reaction (ORR) performance of iron and nitrogen co-doped porous carbon nanoparticles (Fe-NPC) with various physical and (electro) chemical properties have been investigated. Fe-NPC nanoparticles are synthesized via a facile soft-templating procedure by using Iron (III) chloride hexa-hydrate as iron precursor and aminophenol-formaldehyde resin as both carbon and nitrogen precursor. Fe-NPC nanoparticles shows high surface area (443.83 m2g-1), high pore volume (0.52 m3g-1), narrow mesopore size distribution (ca. 3.8 nm), high conductivity (IG/ID=1.04), high kinetic limiting current (11.71 mAcm-2) and more positive onset potential (-0.106 V) compared to metal-free NPC nanoparticles (-0.295V) which make it high efficient ORR metal-free catalysts in alkaline solution. This study may pave the way of feasibly designing iron and nitrogen containing carbon materials (Fe-N-C) for highly efficient oxygen reduction electro-catalysis. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=electro-catalyst" title="electro-catalyst">electro-catalyst</a>, <a href="https://publications.waset.org/abstracts/search?q=mesopore%20structure" title=" mesopore structure"> mesopore structure</a>, <a href="https://publications.waset.org/abstracts/search?q=oxygen%20reduction%20reaction" title=" oxygen reduction reaction"> oxygen reduction reaction</a>, <a href="https://publications.waset.org/abstracts/search?q=soft-template" title=" soft-template"> soft-template</a> </p> <a href="https://publications.waset.org/abstracts/30351/porous-carbon-nanoparticels-co-doped-with-nitrogen-and-iron-as-an-efficient-catalyst-for-oxygen-reduction-reaction" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/30351.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">379</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5719</span> Reduction in Hot Metal Silicon through Statistical Analysis at G-Blast Furnace, Tata Steel Jamshedpur </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Shoumodip%20Roy">Shoumodip Roy</a>, <a href="https://publications.waset.org/abstracts/search?q=Ankit%20Singhania"> Ankit Singhania</a>, <a href="https://publications.waset.org/abstracts/search?q=Santanu%20Mallick"> Santanu Mallick</a>, <a href="https://publications.waset.org/abstracts/search?q=Abhiram%20%20Jha"> Abhiram Jha</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20K.%20%20Agarwal"> M. K. Agarwal</a>, <a href="https://publications.waset.org/abstracts/search?q=R.%20V.%20Ramna"> R. V. Ramna</a>, <a href="https://publications.waset.org/abstracts/search?q=Uttam%20Singh"> Uttam Singh</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The quality of hot metal at any blast furnace is judged by the silicon content in it. Lower hot metal silicon not only enhances process efficiency at steel melting shops but also reduces hot metal costs. The Hot metal produced at G-Blast furnace Tata Steel Jamshedpur has a significantly higher Si content than Benchmark Blast furnaces. The higher content of hot metal Si is mainly due to inferior raw material quality than those used in benchmark blast furnaces. With minimum control over raw material quality, the only option left to control hot metal Si is via optimizing the furnace parameters. Therefore, in order to identify the levers to reduce hot metal Si, Data mining was carried out, and multiple regression models were developed. The statistical analysis revealed that Slag B3{(CaO+MgO)/SiO2}, Slag Alumina and Hot metal temperature are key controllable parameters affecting hot metal silicon. Contour Plots were used to determine the optimum range of levels identified through statistical analysis. A trial plan was formulated to operate relevant parameters, at G blast furnace, in the identified range to reduce hot metal silicon. This paper details out the process followed and subsequent reduction in hot metal silicon by 15% at G blast furnace. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=blast%20furnace" title="blast furnace">blast furnace</a>, <a href="https://publications.waset.org/abstracts/search?q=optimization" title=" optimization"> optimization</a>, <a href="https://publications.waset.org/abstracts/search?q=silicon" title=" silicon"> silicon</a>, <a href="https://publications.waset.org/abstracts/search?q=statistical%20tools" title=" statistical tools"> statistical tools</a> </p> <a href="https://publications.waset.org/abstracts/74955/reduction-in-hot-metal-silicon-through-statistical-analysis-at-g-blast-furnace-tata-steel-jamshedpur" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/74955.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">223</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5718</span> A Review on Aluminium Metal Matric Composites</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=V.%20Singh">V. Singh</a>, <a href="https://publications.waset.org/abstracts/search?q=S.%20Singh"> S. Singh</a>, <a href="https://publications.waset.org/abstracts/search?q=S.%20S.%20Garewal"> S. S. Garewal</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Metal matrix composites with aluminum as the matrix material have been heralded as the next great development in advanced engineering materials. Aluminum metal matrix composites (AMMC) refer to the class of light weight high performance material systems. Properties of AMMCs can be tailored to the demands of different industrial applications by suitable combinations of matrix, reinforcement and processing route. AMMC finds its application in automotive, aerospace, defense, sports and structural areas. This paper presents an overview of AMMC material systems on aspects relating to processing, types and applications with case studies. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=aluminum%20metal%20matrix%20composites" title="aluminum metal matrix composites">aluminum metal matrix composites</a>, <a href="https://publications.waset.org/abstracts/search?q=applications%20of%20aluminum%20metal%20matrix%20composites" title=" applications of aluminum metal matrix composites"> applications of aluminum metal matrix composites</a>, <a href="https://publications.waset.org/abstracts/search?q=lighting%20material%20processing%20of%20aluminum%20metal%20matrix%20composites" title=" lighting material processing of aluminum metal matrix composites"> lighting material processing of aluminum metal matrix composites</a> </p> <a href="https://publications.waset.org/abstracts/62849/a-review-on-aluminium-metal-matric-composites" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/62849.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">465</span> </span> </div> </div> <ul class="pagination"> <li class="page-item disabled"><span class="page-link">&lsaquo;</span></li> <li class="page-item active"><span class="page-link">1</span></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=metal%20free&page=2">2</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=metal%20free&page=3">3</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=metal%20free&page=4">4</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=metal%20free&page=5">5</a></li> <li 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