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.tap\:transition-transform{transition-duration:.15s;transition-property:transform;transition-timing-function:cubic-bezier(.4,0,.2,1)}.slider-tap .tap\:duration-300{transition-duration:.3s}.slider-tooltip-focus:not(.slider-focused) .tt-focus\:hidden{display:none!important}.slider-tooltip-focus.slider-focused:not(.slider-tooltip-hidden) .tt-focused\:block{display:block!important}.slider-tooltip-drag:not(.slider-state-drag) .tt-drag\:hidden{display:none!important}.slider-tooltip-drag.slider-state-drag .tt-dragging\:block\:not\(\.slider-tooltip-hidden\){display:block!important}@media not all and (min-width:1280px){.max-xl\:w-full{width:100%}}@media not all and (min-width:1024px){.max-lg\:items-center{align-items:center}.max-lg\:gap-x-6{-moz-column-gap:1.5rem;column-gap:1.5rem}.max-lg\:pt-lg{padding-top:1.5rem;padding-top:var(--spacing-lg)}}@media 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items-center whitespace-nowrap text-xs leading-normal"><!--[-->Article<!--]--></span><!--[--><!----><!--]--><!----></div><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 border border-color-bold px-2 text-color-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Chemistry and Materials Science<!--]--></span><!--[--><!----><!--]--><!----></div><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 border border-color-bold px-2 text-color-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Electronic, Optical and Magnetic Materials<!--]--></span><!--[--><!----><!--]--><!----></div></div><div class="flex" data-v-240dfb06><button class="m-button m-button--sm m-button--tertiary rounded mr-md after:hidden" type="button" data-v-240dfb06><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="download" style="" width="16" height="16" viewBox="0 0 16 16" data-v-240dfb06></svg><!--]--><!--[--> Download PDF <!--]--><!----><!----><!--[--><!----><!--]--></span></button><button class="m-button m-button--sm m-button--tertiary rounded after:hidden" type="button" data-v-240dfb06><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="format_quote" style="" width="16" height="16" viewBox="0 0 16 16" data-v-240dfb06></svg><!--]--><!--[--> Cite <!--]--><!----><!----><!--[--><!----><!--]--></span></button></div></div><a href="/manuscript/202411.1970/v1" class="" data-v-240dfb06><h5 class="m-heading text-inherit m-h5 font-normal pt-sm hover:text-color-link-bold" data-v-240dfb06>Construction of Hybrid ZnO/SnO2 N&ndash;N Heterojunction with Hierarchical Porous Biomorphic Nanostructure as a High-Response Sensor for Methanol Gas</h5></a><div class="flex pt-sm flex-wrap gap-sm" data-v-240dfb06><!--[--><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Zong-Lai Liu<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Zhao Yang<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Bing Liu<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Ya-Nan Chen<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Wei Feng<!----><!--]--></p></div><!--]--><!--[--><!--]--><!----></div><div class="w-full relative overflow-hidden pt-sm" data-v-240dfb06><div><div class="clamp-3"><!--[--><div class="inline abstract-content" data-v-240dfb06>Abstract: <p>A novel hierarchical porous biomorphic ZnO/SnO has been facilely synthesized in one step using bagasse as bio-template. The structural features of the ZnO/SnO2 n&ndash;n heterostructures were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), and X-ray photoelectron spectroscopy (XPS). The results revealed that the as-prepared ZnO/SnO2 retained the original pore morphology of the bagasse material, and the ZnO/SnO2 was demonstrated with higher sensing performance as compared with the pure SnO2. Particularly, when molar ratio SnO2:ZnO=1:1, the sensor displayed the highest response, showing an excellent response value of 37 under 100 ppm methanol at 340℃. Meanwhile, ZnO/SnO2 composite exhibit good gas selectivity and stability to methanol, which can mainly be attributed to the formation of n-n junctions between SnO2 and ZnO, high capability of absorbed oxygen species of the ZnO/SnO2 composite.</p></div><!--]--></div><div class="invisible absolute"><!--[--><div class="inline abstract-content" data-v-240dfb06>Abstract: <p>A novel hierarchical porous biomorphic ZnO/SnO has been facilely synthesized in one step using bagasse as bio-template. The structural features of the ZnO/SnO2 n&ndash;n heterostructures were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), and X-ray photoelectron spectroscopy (XPS). The results revealed that the as-prepared ZnO/SnO2 retained the original pore morphology of the bagasse material, and the ZnO/SnO2 was demonstrated with higher sensing performance as compared with the pure SnO2. Particularly, when molar ratio SnO2:ZnO=1:1, the sensor displayed the highest response, showing an excellent response value of 37 under 100 ppm methanol at 340℃. Meanwhile, ZnO/SnO2 composite exhibit good gas selectivity and stability to methanol, which can mainly be attributed to the formation of n-n junctions between SnO2 and ZnO, high capability of absorbed oxygen species of the ZnO/SnO2 composite.</p></div><!--]--></div></div><div style="display:none;" class="absolute right-0 bottom-0"><span><span class="inline-block align-middle w-6 h-4 bg-gradient-to-r from-transparent to-white"></span><span class="bg-white">... </span></span><button class="m-button m-button--sm m-button--tertiary rounded !inline-flex after:hidden bg-white" type="button"><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><!----><!--]--><!--[-->Show more <!--]--><!----><!----><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="keyboard_arrow_down" style="" width="16" height="16" viewBox="0 0 16 16"></svg><!--]--></span></button></div></div><div class="pt-sm text-color-subtle flex gap-x-sm gap-y-sm flex-col lg:flex-row" data-v-240dfb06><p class="m-text text-sm" data-v-240dfb06><!--[--> Posted: 27 November 2024<!--]--></p><p class="m-text text-sm underline cursor-pointer" data-v-240dfb06><!--[--><a href="https://doi.org/10.20944/preprints202411.1970.v1" rel="noopener noreferrer" data-v-240dfb06><span data-v-240dfb06>https://doi.org/</span>10.20944/preprints202411.1970.v1</a><!--]--></p></div></div><div data-v-240dfb06><!----></div></div><div data-v-240dfb06><div class="border-b border-color-default pb-md mb-sm" data-v-240dfb06><div class="pt-md lg:pt-lg lg:flex justify-between space-y-xs" data-v-240dfb06><div class="flex flex-wrap gap-x-xs gap-y-xs" data-v-240dfb06><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 bg-content-subtler text-color-default px-2 !bg-surface-disabled" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Review<!--]--></span><!--[--><!----><!--]--><!----></div><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 border border-color-bold px-2 text-color-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Polymers and Plastics<!--]--></span><!--[--><!----><!--]--><!----></div><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 border border-color-bold px-2 text-color-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Chemistry and Materials Science<!--]--></span><!--[--><!----><!--]--><!----></div></div><div class="flex" data-v-240dfb06><button class="m-button m-button--sm m-button--tertiary rounded mr-md after:hidden" type="button" data-v-240dfb06><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="download" style="" width="16" height="16" viewBox="0 0 16 16" data-v-240dfb06></svg><!--]--><!--[--> Download PDF <!--]--><!----><!----><!--[--><!----><!--]--></span></button><button class="m-button m-button--sm m-button--tertiary rounded after:hidden" type="button" data-v-240dfb06><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="format_quote" style="" width="16" height="16" viewBox="0 0 16 16" data-v-240dfb06></svg><!--]--><!--[--> Cite <!--]--><!----><!----><!--[--><!----><!--]--></span></button></div></div><a href="/manuscript/202411.2013/v1" class="" data-v-240dfb06><h5 class="m-heading text-inherit m-h5 font-normal pt-sm hover:text-color-link-bold" data-v-240dfb06>Smart Polymer Composites for Electrical Heating: A Review</h5></a><div class="flex pt-sm flex-wrap gap-sm" data-v-240dfb06><!--[--><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Alexandr Viktorovich Shchegolkov<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Aleksei Viktorovich Shchegolkov<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Vladimir Vladimirovich Kaminskii<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Maxim Alexandrovich Chumak<!----><!--]--></p></div><!--]--><!--[--><!--]--><!----></div><div class="w-full relative overflow-hidden pt-sm" data-v-240dfb06><div><div class="clamp-3"><!--[--><div class="inline abstract-content" data-v-240dfb06>Abstract: The paper presents an overview of conductive polymer composites based on thermosets, ther-moplastics and elastomers modified with carbon nanotubes (CNT). To impart conductive prop-erties to polymers, metal or carbon dispersed materials or their combinations are used. The in-troduction of dispersed materials into polymers is associated with their microstructural proper-ties, as well as polymerization methods. Such polymerization methods as melt mixing, solution technology, introduction of fillers into the liquid phase of the composite with subsequent polymerization due to the use of a catalyst are known. Polymer composites that are capable of conducting electric current and changing their properties under the influence of an electric field, i.e. having one or more functional purposes, are called &quot;smart&quot; or intelligent. One of such applications is electric heating elements with the function of adaptive power consumption or the effect of self-regulation of temperature depending on the surrounding conditions. A wide variety of polymers and dispersed materials with conductive properties determine a wide range of func-tional capabilities of the composite, including a positive temperature coefficient of resistance, which is necessary to control temperature properties. The most effective filler in a polymer for obtaining a composite with specified properties are carbon nanomaterials, in particular CNTs. This is due to the fact that CNTs are a nanosized material that has a high bulk density with a low mass, which allows achieving high electrical conductivity. Calculation of model parameters of polymer composites containing carbon nanostructures can be carried out using neural networks and ma-chine learning, which provide a fundamentally new result.</div><!--]--></div><div class="invisible absolute"><!--[--><div class="inline abstract-content" data-v-240dfb06>Abstract: The paper presents an overview of conductive polymer composites based on thermosets, ther-moplastics and elastomers modified with carbon nanotubes (CNT). To impart conductive prop-erties to polymers, metal or carbon dispersed materials or their combinations are used. The in-troduction of dispersed materials into polymers is associated with their microstructural proper-ties, as well as polymerization methods. Such polymerization methods as melt mixing, solution technology, introduction of fillers into the liquid phase of the composite with subsequent polymerization due to the use of a catalyst are known. Polymer composites that are capable of conducting electric current and changing their properties under the influence of an electric field, i.e. having one or more functional purposes, are called &quot;smart&quot; or intelligent. One of such applications is electric heating elements with the function of adaptive power consumption or the effect of self-regulation of temperature depending on the surrounding conditions. A wide variety of polymers and dispersed materials with conductive properties determine a wide range of func-tional capabilities of the composite, including a positive temperature coefficient of resistance, which is necessary to control temperature properties. The most effective filler in a polymer for obtaining a composite with specified properties are carbon nanomaterials, in particular CNTs. This is due to the fact that CNTs are a nanosized material that has a high bulk density with a low mass, which allows achieving high electrical conductivity. Calculation of model parameters of polymer composites containing carbon nanostructures can be carried out using neural networks and ma-chine learning, which provide a fundamentally new result.</div><!--]--></div></div><div style="display:none;" class="absolute right-0 bottom-0"><span><span class="inline-block align-middle w-6 h-4 bg-gradient-to-r from-transparent to-white"></span><span class="bg-white">... </span></span><button class="m-button m-button--sm m-button--tertiary rounded !inline-flex after:hidden bg-white" type="button"><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><!----><!--]--><!--[-->Show more <!--]--><!----><!----><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="keyboard_arrow_down" style="" width="16" height="16" viewBox="0 0 16 16"></svg><!--]--></span></button></div></div><div class="pt-sm text-color-subtle flex gap-x-sm gap-y-sm flex-col lg:flex-row" data-v-240dfb06><p class="m-text text-sm" data-v-240dfb06><!--[--> Posted: 26 November 2024<!--]--></p><p class="m-text text-sm underline cursor-pointer" data-v-240dfb06><!--[--><a href="https://doi.org/10.20944/preprints202411.2013.v1" rel="noopener noreferrer" data-v-240dfb06><span data-v-240dfb06>https://doi.org/</span>10.20944/preprints202411.2013.v1</a><!--]--></p></div></div><div data-v-240dfb06><!----></div></div><div data-v-240dfb06><div class="border-b border-color-default pb-md mb-sm" data-v-240dfb06><div class="pt-md lg:pt-lg lg:flex justify-between space-y-xs" data-v-240dfb06><div class="flex flex-wrap gap-x-xs gap-y-xs" data-v-240dfb06><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 bg-content-subtler text-color-default px-2 !bg-surface-disabled" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Review<!--]--></span><!--[--><!----><!--]--><!----></div><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 border border-color-bold px-2 text-color-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Nanotechnology<!--]--></span><!--[--><!----><!--]--><!----></div><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 border border-color-bold px-2 text-color-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Chemistry and Materials Science<!--]--></span><!--[--><!----><!--]--><!----></div></div><div class="flex" data-v-240dfb06><button class="m-button m-button--sm m-button--tertiary rounded mr-md after:hidden" type="button" data-v-240dfb06><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="download" style="" width="16" height="16" viewBox="0 0 16 16" data-v-240dfb06></svg><!--]--><!--[--> Download PDF <!--]--><!----><!----><!--[--><!----><!--]--></span></button><button class="m-button m-button--sm m-button--tertiary rounded after:hidden" type="button" data-v-240dfb06><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="format_quote" style="" width="16" height="16" viewBox="0 0 16 16" data-v-240dfb06></svg><!--]--><!--[--> Cite <!--]--><!----><!----><!--[--><!----><!--]--></span></button></div></div><a href="/manuscript/202411.1966/v1" class="" data-v-240dfb06><h5 class="m-heading text-inherit m-h5 font-normal pt-sm hover:text-color-link-bold" data-v-240dfb06>Harnessing Radiation for Nanotechnology: A Comprehensive Review of Techniques, Innovations and Application</h5></a><div class="flex pt-sm flex-wrap gap-sm" data-v-240dfb06><!--[--><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Mobinul Islam<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Md. Shahriar Ahmed<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Sua Yun<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Hae Yong Kim<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Kyung-Wan Nam<!----><!--]--></p></div><!--]--><!--[--><!--]--><!----></div><div class="w-full relative overflow-hidden pt-sm" data-v-240dfb06><div><div class="clamp-3"><!--[--><div class="inline abstract-content" data-v-240dfb06>Abstract: Nanomaterial properties such as size, structure, and composition can be controlled by manipulating radiation, such as gamma rays, X-rays, and electron beams. This control allows scientists to create materials with desired properties that can be used in a wide range of applications, from electronics to medicine. This use of radiation for nanotechnology is revolutionizing the way we design and manufacture materials. Additionally, radiation-induced nanomaterials are more cost-effective and energy-efficient. This technology is also having a positive impact on the environment, as materials are being produced with fewer emissions, less energy, and less waste. This cutting-edge technology is opening up new possibilities and has become an attractive option for many industries, from medical advancements to energy storage. It is also helping to make the world a better place by reducing our carbon footprint and preserving natural resources. This review aims to meticulously point out the synthesis approach and highlights significant progress in generating radiation-induced nanomaterials with tunable and complex morphologies. This comprehensive review article is essential for researchers to design innovative materials for advancements in health care, electronics, energy storage, and environmental remediation.</div><!--]--></div><div class="invisible absolute"><!--[--><div class="inline abstract-content" data-v-240dfb06>Abstract: Nanomaterial properties such as size, structure, and composition can be controlled by manipulating radiation, such as gamma rays, X-rays, and electron beams. This control allows scientists to create materials with desired properties that can be used in a wide range of applications, from electronics to medicine. This use of radiation for nanotechnology is revolutionizing the way we design and manufacture materials. Additionally, radiation-induced nanomaterials are more cost-effective and energy-efficient. This technology is also having a positive impact on the environment, as materials are being produced with fewer emissions, less energy, and less waste. This cutting-edge technology is opening up new possibilities and has become an attractive option for many industries, from medical advancements to energy storage. It is also helping to make the world a better place by reducing our carbon footprint and preserving natural resources. This review aims to meticulously point out the synthesis approach and highlights significant progress in generating radiation-induced nanomaterials with tunable and complex morphologies. This comprehensive review article is essential for researchers to design innovative materials for advancements in health care, electronics, energy storage, and environmental remediation.</div><!--]--></div></div><div style="display:none;" class="absolute right-0 bottom-0"><span><span class="inline-block align-middle w-6 h-4 bg-gradient-to-r from-transparent to-white"></span><span class="bg-white">... </span></span><button class="m-button m-button--sm m-button--tertiary rounded !inline-flex after:hidden bg-white" type="button"><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><!----><!--]--><!--[-->Show more <!--]--><!----><!----><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="keyboard_arrow_down" style="" width="16" height="16" viewBox="0 0 16 16"></svg><!--]--></span></button></div></div><div class="pt-sm text-color-subtle flex gap-x-sm gap-y-sm flex-col lg:flex-row" data-v-240dfb06><p class="m-text text-sm" data-v-240dfb06><!--[--> Posted: 26 November 2024<!--]--></p><p class="m-text text-sm underline cursor-pointer" data-v-240dfb06><!--[--><a href="https://doi.org/10.20944/preprints202411.1966.v1" rel="noopener noreferrer" data-v-240dfb06><span data-v-240dfb06>https://doi.org/</span>10.20944/preprints202411.1966.v1</a><!--]--></p></div></div><div data-v-240dfb06><!----></div></div><div data-v-240dfb06><div class="border-b border-color-default pb-md mb-sm" data-v-240dfb06><div class="pt-md lg:pt-lg lg:flex justify-between space-y-xs" data-v-240dfb06><div class="flex flex-wrap gap-x-xs gap-y-xs" data-v-240dfb06><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 bg-content-subtler text-color-default px-2 !bg-surface-disabled" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Article<!--]--></span><!--[--><!----><!--]--><!----></div><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 border border-color-bold px-2 text-color-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Analytical Chemistry<!--]--></span><!--[--><!----><!--]--><!----></div><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 border border-color-bold px-2 text-color-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Chemistry and Materials Science<!--]--></span><!--[--><!----><!--]--><!----></div></div><div class="flex" data-v-240dfb06><button class="m-button m-button--sm m-button--tertiary rounded mr-md after:hidden" type="button" data-v-240dfb06><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="download" style="" width="16" height="16" viewBox="0 0 16 16" data-v-240dfb06></svg><!--]--><!--[--> Download PDF <!--]--><!----><!----><!--[--><!----><!--]--></span></button><button class="m-button m-button--sm m-button--tertiary rounded after:hidden" type="button" data-v-240dfb06><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="format_quote" style="" width="16" height="16" viewBox="0 0 16 16" data-v-240dfb06></svg><!--]--><!--[--> Cite <!--]--><!----><!----><!--[--><!----><!--]--></span></button></div></div><a href="/manuscript/202411.1919/v1" class="" data-v-240dfb06><h5 class="m-heading text-inherit m-h5 font-normal pt-sm hover:text-color-link-bold" data-v-240dfb06>Simultaneous Determination of the Main Aromatic Com-pounds and Divanillin in Vanilla planifolia Jacks. ex Andrews by HPLC-DAD</h5></a><div class="flex pt-sm flex-wrap gap-sm" data-v-240dfb06><!--[--><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Yunuen Erandy Torres-Zamudio<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Guadalupe del Carmen Rodríguez-Jimenes<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Gerardo Fernández Barbero<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Araceli Pérez-Silva<!----><!--]--></p></div><!--]--><!--[--><!--]--><!----></div><div class="w-full relative overflow-hidden pt-sm" data-v-240dfb06><div><div class="clamp-3"><!--[--><div class="inline abstract-content" data-v-240dfb06>Abstract: <p>Vanilla planifolia Jacks. ex Andrews pods can lose up to 50% of their vanillin during curing. One explanation for this is the transformation of vanillin due to enzyme action, such as peroxidases, which generate the formation of dimers like divanillin. Therefore, in this work, a simultaneous high-performance liquid chromatography method (HPLC-DAD) was developed and validated for the separation and quantification of the main compounds present in Vanilla planifolia Jacks. ex Andrews and divanillin. The separation of 9 compounds of interest was achieved within 15 minutes using a Zorbax Eclipse XDB-C18 column (250 mm x 4.6 mm i.d., 5 &mu;m particle size). The variables optimized included the mobile phase (water as solvent A, methanol as solvent B, and acidified water, 10&ndash;2 M H3PO4, as solvent C), the separation gradient, and the column tempera-ture (40-60 &deg;C). The maximum divanillin content was 0.02 g/100 g d.w. in a sample from Papantla de Olarte. Chromatographic performance evaluation revealed excellent resolution, retention factor, and selectivity. The method was successfully validated in terms of limits of detection and quantification, linearity, and precision, as well as its application to cured pods, with evidence of divanillin presence in all analyzed sample.</p></div><!--]--></div><div class="invisible absolute"><!--[--><div class="inline abstract-content" data-v-240dfb06>Abstract: <p>Vanilla planifolia Jacks. ex Andrews pods can lose up to 50% of their vanillin during curing. One explanation for this is the transformation of vanillin due to enzyme action, such as peroxidases, which generate the formation of dimers like divanillin. Therefore, in this work, a simultaneous high-performance liquid chromatography method (HPLC-DAD) was developed and validated for the separation and quantification of the main compounds present in Vanilla planifolia Jacks. ex Andrews and divanillin. The separation of 9 compounds of interest was achieved within 15 minutes using a Zorbax Eclipse XDB-C18 column (250 mm x 4.6 mm i.d., 5 &mu;m particle size). The variables optimized included the mobile phase (water as solvent A, methanol as solvent B, and acidified water, 10&ndash;2 M H3PO4, as solvent C), the separation gradient, and the column tempera-ture (40-60 &deg;C). The maximum divanillin content was 0.02 g/100 g d.w. in a sample from Papantla de Olarte. Chromatographic performance evaluation revealed excellent resolution, retention factor, and selectivity. The method was successfully validated in terms of limits of detection and quantification, linearity, and precision, as well as its application to cured pods, with evidence of divanillin presence in all analyzed sample.</p></div><!--]--></div></div><div style="display:none;" class="absolute right-0 bottom-0"><span><span class="inline-block align-middle w-6 h-4 bg-gradient-to-r from-transparent to-white"></span><span class="bg-white">... </span></span><button class="m-button m-button--sm m-button--tertiary rounded !inline-flex after:hidden bg-white" type="button"><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><!----><!--]--><!--[-->Show more <!--]--><!----><!----><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="keyboard_arrow_down" style="" width="16" height="16" viewBox="0 0 16 16"></svg><!--]--></span></button></div></div><div class="pt-sm text-color-subtle flex gap-x-sm gap-y-sm flex-col lg:flex-row" data-v-240dfb06><p class="m-text text-sm" data-v-240dfb06><!--[--> Posted: 26 November 2024<!--]--></p><p class="m-text text-sm underline cursor-pointer" data-v-240dfb06><!--[--><a href="https://doi.org/10.20944/preprints202411.1919.v1" rel="noopener noreferrer" data-v-240dfb06><span data-v-240dfb06>https://doi.org/</span>10.20944/preprints202411.1919.v1</a><!--]--></p></div></div><div data-v-240dfb06><!----></div></div><div data-v-240dfb06><div class="border-b border-color-default pb-md mb-sm" data-v-240dfb06><div class="pt-md lg:pt-lg lg:flex justify-between space-y-xs" data-v-240dfb06><div class="flex flex-wrap gap-x-xs gap-y-xs" data-v-240dfb06><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 bg-content-subtler text-color-default px-2 !bg-surface-disabled" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Article<!--]--></span><!--[--><!----><!--]--><!----></div><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 border border-color-bold px-2 text-color-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Applied Chemistry<!--]--></span><!--[--><!----><!--]--><!----></div><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 border border-color-bold px-2 text-color-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Chemistry and Materials Science<!--]--></span><!--[--><!----><!--]--><!----></div></div><div class="flex" data-v-240dfb06><button class="m-button m-button--sm m-button--tertiary rounded mr-md after:hidden" type="button" data-v-240dfb06><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="download" style="" width="16" height="16" viewBox="0 0 16 16" data-v-240dfb06></svg><!--]--><!--[--> Download PDF <!--]--><!----><!----><!--[--><!----><!--]--></span></button><button class="m-button m-button--sm m-button--tertiary rounded after:hidden" type="button" data-v-240dfb06><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="format_quote" style="" width="16" height="16" viewBox="0 0 16 16" data-v-240dfb06></svg><!--]--><!--[--> Cite <!--]--><!----><!----><!--[--><!----><!--]--></span></button></div></div><a href="/manuscript/202411.1973/v1" class="" data-v-240dfb06><h5 class="m-heading text-inherit m-h5 font-normal pt-sm hover:text-color-link-bold" data-v-240dfb06>Extraction of &szlig;-Carotene from Pumpkin (Curcubita moschata) and Spinach (Spinacia oleracea) Using Environmentally Friendly Deep Eutectic Solvents (DESs)</h5></a><div class="flex pt-sm flex-wrap gap-sm" data-v-240dfb06><!--[--><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Koray Tanrıver<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Mehmet Bilgin<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Selin Şahin Sevgili<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->İrem Toprakçı Yüksel<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Ebru Kurtulbaş Şahin<!----><!--]--></p></div><!--]--><!--[--><!--]--><!----></div><div class="w-full relative overflow-hidden pt-sm" data-v-240dfb06><div><div class="clamp-3"><!--[--><div class="inline abstract-content" data-v-240dfb06>Abstract: There is an increasing demand for antioxidants, nutraceuticals and natural colorants. ß-Carotene is one of the commonly used commodities which fits description. ß-Carotene is a highly hydrophobic molecule; therefore, commercial extraction processes generally use highly non-polar solvents and these are barely environmentally friendly chemicals. The aim of this research was to develop effective and sustainable extraction processes for ß-Carotene from pumpkin and spinach using environmentally friendly green chemicals. A series of deep eutectic solvents with L-menthol and carboxylic aliphatic acids were synthesized for extraction of β-carotene from pumpkin and spinach via mechanical mixing (MMAE) and homogenization assisted extraction (HAE). Response surface methodology and ANOVA analyses were used to analyze the data. Menthol:Propionic Acid DESs had the best effect on the extraction of ß-Carotene (11.528 μg-ß-Carotene/gr-pumpkin for MMAE, 8.966 μg-ß-Carotene/gr-pumpkin for HAE, 16.924 μg-ß-Carotene/gr-spinach for MMAE and 18.870 μg-ß-Carotene/gr-spinach for HAE) under the optimal conditions (HBD molar ratio: 0.6452, 15 min. for MMAE of ß-Carotene from pumpkin, HBD molar ratio: 0.6198, 30.0 sec., 7061 rpm for HAE of ß-Carotene from pumpkin, HBD molar ratio: 0.8000, 60 min. for MMAE of ß-Carotene from spinach, HBD molar ratio: 0.8000, 120.0 sec., 7000 rpm for HAE of ß-Carotene from spinach).</div><!--]--></div><div class="invisible absolute"><!--[--><div class="inline abstract-content" data-v-240dfb06>Abstract: There is an increasing demand for antioxidants, nutraceuticals and natural colorants. ß-Carotene is one of the commonly used commodities which fits description. ß-Carotene is a highly hydrophobic molecule; therefore, commercial extraction processes generally use highly non-polar solvents and these are barely environmentally friendly chemicals. The aim of this research was to develop effective and sustainable extraction processes for ß-Carotene from pumpkin and spinach using environmentally friendly green chemicals. A series of deep eutectic solvents with L-menthol and carboxylic aliphatic acids were synthesized for extraction of β-carotene from pumpkin and spinach via mechanical mixing (MMAE) and homogenization assisted extraction (HAE). Response surface methodology and ANOVA analyses were used to analyze the data. Menthol:Propionic Acid DESs had the best effect on the extraction of ß-Carotene (11.528 μg-ß-Carotene/gr-pumpkin for MMAE, 8.966 μg-ß-Carotene/gr-pumpkin for HAE, 16.924 μg-ß-Carotene/gr-spinach for MMAE and 18.870 μg-ß-Carotene/gr-spinach for HAE) under the optimal conditions (HBD molar ratio: 0.6452, 15 min. for MMAE of ß-Carotene from pumpkin, HBD molar ratio: 0.6198, 30.0 sec., 7061 rpm for HAE of ß-Carotene from pumpkin, HBD molar ratio: 0.8000, 60 min. for MMAE of ß-Carotene from spinach, HBD molar ratio: 0.8000, 120.0 sec., 7000 rpm for HAE of ß-Carotene from spinach).</div><!--]--></div></div><div style="display:none;" class="absolute right-0 bottom-0"><span><span class="inline-block align-middle w-6 h-4 bg-gradient-to-r from-transparent to-white"></span><span class="bg-white">... </span></span><button class="m-button m-button--sm m-button--tertiary rounded !inline-flex after:hidden bg-white" type="button"><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><!----><!--]--><!--[-->Show more <!--]--><!----><!----><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="keyboard_arrow_down" style="" width="16" height="16" viewBox="0 0 16 16"></svg><!--]--></span></button></div></div><div class="pt-sm text-color-subtle flex gap-x-sm gap-y-sm flex-col lg:flex-row" data-v-240dfb06><p class="m-text text-sm" data-v-240dfb06><!--[--> Posted: 26 November 2024<!--]--></p><p class="m-text text-sm underline cursor-pointer" data-v-240dfb06><!--[--><a href="https://doi.org/10.20944/preprints202411.1973.v1" rel="noopener noreferrer" data-v-240dfb06><span data-v-240dfb06>https://doi.org/</span>10.20944/preprints202411.1973.v1</a><!--]--></p></div></div><div data-v-240dfb06><!----></div></div><div data-v-240dfb06><div class="border-b border-color-default pb-md mb-sm" data-v-240dfb06><div class="pt-md lg:pt-lg lg:flex justify-between space-y-xs" data-v-240dfb06><div class="flex flex-wrap gap-x-xs gap-y-xs" data-v-240dfb06><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 bg-content-subtler text-color-default px-2 !bg-surface-disabled" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Article<!--]--></span><!--[--><!----><!--]--><!----></div><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 border border-color-bold px-2 text-color-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Polymers and Plastics<!--]--></span><!--[--><!----><!--]--><!----></div><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 border border-color-bold px-2 text-color-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Chemistry and Materials Science<!--]--></span><!--[--><!----><!--]--><!----></div></div><div class="flex" data-v-240dfb06><button class="m-button m-button--sm m-button--tertiary rounded mr-md after:hidden" type="button" data-v-240dfb06><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="download" style="" width="16" height="16" viewBox="0 0 16 16" data-v-240dfb06></svg><!--]--><!--[--> Download PDF <!--]--><!----><!----><!--[--><!----><!--]--></span></button><button class="m-button m-button--sm m-button--tertiary rounded after:hidden" type="button" data-v-240dfb06><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="format_quote" style="" width="16" height="16" viewBox="0 0 16 16" data-v-240dfb06></svg><!--]--><!--[--> Cite <!--]--><!----><!----><!--[--><!----><!--]--></span></button></div></div><a href="/manuscript/202411.2006/v1" class="" data-v-240dfb06><h5 class="m-heading text-inherit m-h5 font-normal pt-sm hover:text-color-link-bold" data-v-240dfb06>Influence of Fresh Latex Coagulation on the Parameter Characteristics of the Yeoh Hyperelastic Constitutive Model for Natural Rubber</h5></a><div class="flex pt-sm flex-wrap gap-sm" data-v-240dfb06><!--[--><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Li Ding<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Honghai Huang<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Yuekun Wang<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Jianwei Li<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Hongxing Gui<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Yongping Chen<!----><!--]--></p></div><!--]--><!--[--><!--]--><!----></div><div class="w-full relative overflow-hidden pt-sm" data-v-240dfb06><div><div class="clamp-3"><!--[--><div class="inline abstract-content" data-v-240dfb06>Abstract: Currently, natural rubber is an irreplaceable and important strategic material. Coagulation of fresh latex is one of the key processes in natural rubber processing, which directly affects the properties of natural rubber and its derived materials. Based on tensile experiments and the Yeoh model, the effects of natural coagulation, enzyme coagulation, acid coagulation, microbial coagulation, and enzyme-assisted microbial coagulation modes on the superelastic ontological relationships of natural rubber were analyzed in detail. Given the limitations of the Yeoh model in describing the mechanical behavior in the low-strain region, a strain-rate-related factor was introduced and a more accurate hyperelastic constitutive relationship of natural rubber was established. The results demonstrate that the Yeoh model effectively characterizes the mechanical behavior of natural rubber carbon black composites in the moderate and high-strain regions. Additionally, the material characteristics reflected by the model parameters align with those observed in cyclic tensile tests The performance of rubber under small, medium, and large deformations is different for different coagulation methods. The modulus of natural coagulation rubber is the highest in small deformations, the modulus of enzyme coagulation rubber is the highest in medium deformations and the modulus of enzyme-assisted microbial coagulation rubber is the highest in large deformations so that the appropriate coagulation method can be selected according to the degree of deformation of the rubber required by application scenarios in the practical application. Following the incorporation of a strain-rate-related factor, the modified Yeoh model provides accurate predictions of stress-strain curves across different tensile speeds within the low-strain range.</div><!--]--></div><div class="invisible absolute"><!--[--><div class="inline abstract-content" data-v-240dfb06>Abstract: Currently, natural rubber is an irreplaceable and important strategic material. Coagulation of fresh latex is one of the key processes in natural rubber processing, which directly affects the properties of natural rubber and its derived materials. Based on tensile experiments and the Yeoh model, the effects of natural coagulation, enzyme coagulation, acid coagulation, microbial coagulation, and enzyme-assisted microbial coagulation modes on the superelastic ontological relationships of natural rubber were analyzed in detail. Given the limitations of the Yeoh model in describing the mechanical behavior in the low-strain region, a strain-rate-related factor was introduced and a more accurate hyperelastic constitutive relationship of natural rubber was established. The results demonstrate that the Yeoh model effectively characterizes the mechanical behavior of natural rubber carbon black composites in the moderate and high-strain regions. Additionally, the material characteristics reflected by the model parameters align with those observed in cyclic tensile tests The performance of rubber under small, medium, and large deformations is different for different coagulation methods. The modulus of natural coagulation rubber is the highest in small deformations, the modulus of enzyme coagulation rubber is the highest in medium deformations and the modulus of enzyme-assisted microbial coagulation rubber is the highest in large deformations so that the appropriate coagulation method can be selected according to the degree of deformation of the rubber required by application scenarios in the practical application. Following the incorporation of a strain-rate-related factor, the modified Yeoh model provides accurate predictions of stress-strain curves across different tensile speeds within the low-strain range.</div><!--]--></div></div><div style="display:none;" class="absolute right-0 bottom-0"><span><span class="inline-block align-middle w-6 h-4 bg-gradient-to-r from-transparent to-white"></span><span class="bg-white">... </span></span><button class="m-button m-button--sm m-button--tertiary rounded !inline-flex after:hidden bg-white" type="button"><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><!----><!--]--><!--[-->Show more <!--]--><!----><!----><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="keyboard_arrow_down" style="" width="16" height="16" viewBox="0 0 16 16"></svg><!--]--></span></button></div></div><div class="pt-sm text-color-subtle flex gap-x-sm gap-y-sm flex-col lg:flex-row" data-v-240dfb06><p class="m-text text-sm" data-v-240dfb06><!--[--> Posted: 26 November 2024<!--]--></p><p class="m-text text-sm underline cursor-pointer" data-v-240dfb06><!--[--><a href="https://doi.org/10.20944/preprints202411.2006.v1" rel="noopener noreferrer" data-v-240dfb06><span data-v-240dfb06>https://doi.org/</span>10.20944/preprints202411.2006.v1</a><!--]--></p></div></div><div data-v-240dfb06><!----></div></div><div data-v-240dfb06><div class="border-b border-color-default pb-md mb-sm" data-v-240dfb06><div class="pt-md lg:pt-lg lg:flex justify-between space-y-xs" data-v-240dfb06><div class="flex flex-wrap gap-x-xs gap-y-xs" data-v-240dfb06><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 bg-content-subtler text-color-default px-2 !bg-surface-disabled" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Article<!--]--></span><!--[--><!----><!--]--><!----></div><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 border border-color-bold px-2 text-color-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Inorganic and Nuclear Chemistry<!--]--></span><!--[--><!----><!--]--><!----></div><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 border border-color-bold px-2 text-color-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Chemistry and Materials Science<!--]--></span><!--[--><!----><!--]--><!----></div></div><div class="flex" data-v-240dfb06><button class="m-button m-button--sm m-button--tertiary rounded mr-md after:hidden" type="button" data-v-240dfb06><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="download" style="" width="16" height="16" viewBox="0 0 16 16" data-v-240dfb06></svg><!--]--><!--[--> Download PDF <!--]--><!----><!----><!--[--><!----><!--]--></span></button><button class="m-button m-button--sm m-button--tertiary rounded after:hidden" type="button" data-v-240dfb06><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="format_quote" style="" width="16" height="16" viewBox="0 0 16 16" data-v-240dfb06></svg><!--]--><!--[--> Cite <!--]--><!----><!----><!--[--><!----><!--]--></span></button></div></div><a href="/manuscript/202411.1986/v1" class="" data-v-240dfb06><h5 class="m-heading text-inherit m-h5 font-normal pt-sm hover:text-color-link-bold" data-v-240dfb06>A Trinuclear Co(II) Complex Based on the Tris-dioxolene Triphenylene Non Innocent Bridge: Complementary Redox, Magnetic Behavior and Theoretical Calculations</h5></a><div class="flex pt-sm flex-wrap gap-sm" data-v-240dfb06><!--[--><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Aristide Colin<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Yiting Wang<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->François Lambert<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Nathalie Bridonneau<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Nicolas Suaud<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Régis Guillot<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Eric Rivière<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Zakaria Halime<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Nathalie Guihéry<span data-v-240dfb06>,</span><!--]--></p></div><!--]--><!--[--><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Shin-ichi Ohkoshi<!--]--></p></div><!--]--><div data-v-240dfb06><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 bg-content-subtler text-color-default px-2 bg-info-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->+1 authors<!--]--></span><!--[--><!----><!--]--><!----></div></div></div><div class="w-full relative overflow-hidden pt-sm" data-v-240dfb06><div><div class="clamp-3"><!--[--><div class="inline abstract-content" data-v-240dfb06>Abstract: A trinuclear Co(II)-containing complex was assembled using the non-innocent hexahydroxytriphenylene bridging ligand. Cyclovoltammetry and spectro-electrochemistry studies revealed that the central ligand can sustain five reversible redox events leading to different spices with diverse optical behavior. Complementary analysis of the molecular structure confirmed by ab initio theoretical calculations are consistent with the bridge in the tris-semiquinone (sq) state for the trinuclear complex. The exchange coupling among the electrons of the bridge results in a spin doublet (s = ½) localized close to one of the three Co(II) ions, as suggested by the experimental magnetic data. The central doublet undergoes one large antiferromagnetic exchange coupling with one Co(II) and almost no coupling with the two other metal ions.</div><!--]--></div><div class="invisible absolute"><!--[--><div class="inline abstract-content" data-v-240dfb06>Abstract: A trinuclear Co(II)-containing complex was assembled using the non-innocent hexahydroxytriphenylene bridging ligand. Cyclovoltammetry and spectro-electrochemistry studies revealed that the central ligand can sustain five reversible redox events leading to different spices with diverse optical behavior. Complementary analysis of the molecular structure confirmed by ab initio theoretical calculations are consistent with the bridge in the tris-semiquinone (sq) state for the trinuclear complex. The exchange coupling among the electrons of the bridge results in a spin doublet (s = ½) localized close to one of the three Co(II) ions, as suggested by the experimental magnetic data. The central doublet undergoes one large antiferromagnetic exchange coupling with one Co(II) and almost no coupling with the two other metal ions.</div><!--]--></div></div><div style="display:none;" class="absolute right-0 bottom-0"><span><span class="inline-block align-middle w-6 h-4 bg-gradient-to-r from-transparent to-white"></span><span class="bg-white">... </span></span><button class="m-button m-button--sm m-button--tertiary rounded !inline-flex after:hidden bg-white" type="button"><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><!----><!--]--><!--[-->Show more <!--]--><!----><!----><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="keyboard_arrow_down" style="" width="16" height="16" viewBox="0 0 16 16"></svg><!--]--></span></button></div></div><div class="pt-sm text-color-subtle flex gap-x-sm gap-y-sm flex-col lg:flex-row" data-v-240dfb06><p class="m-text text-sm" data-v-240dfb06><!--[--> Posted: 26 November 2024<!--]--></p><p class="m-text text-sm underline cursor-pointer" data-v-240dfb06><!--[--><a href="https://doi.org/10.20944/preprints202411.1986.v1" rel="noopener noreferrer" data-v-240dfb06><span data-v-240dfb06>https://doi.org/</span>10.20944/preprints202411.1986.v1</a><!--]--></p></div></div><div data-v-240dfb06><!----></div></div><div data-v-240dfb06><div class="border-b border-color-default pb-md mb-sm" data-v-240dfb06><div class="pt-md lg:pt-lg lg:flex justify-between space-y-xs" data-v-240dfb06><div class="flex flex-wrap gap-x-xs gap-y-xs" data-v-240dfb06><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 bg-content-subtler text-color-default px-2 !bg-surface-disabled" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Article<!--]--></span><!--[--><!----><!--]--><!----></div><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 border border-color-bold px-2 text-color-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Nanotechnology<!--]--></span><!--[--><!----><!--]--><!----></div><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 border border-color-bold px-2 text-color-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Chemistry and Materials Science<!--]--></span><!--[--><!----><!--]--><!----></div></div><div class="flex" data-v-240dfb06><button class="m-button m-button--sm m-button--tertiary rounded mr-md after:hidden" type="button" data-v-240dfb06><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="download" style="" width="16" height="16" viewBox="0 0 16 16" data-v-240dfb06></svg><!--]--><!--[--> Download PDF <!--]--><!----><!----><!--[--><!----><!--]--></span></button><button class="m-button m-button--sm m-button--tertiary rounded after:hidden" type="button" data-v-240dfb06><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="format_quote" style="" width="16" height="16" viewBox="0 0 16 16" data-v-240dfb06></svg><!--]--><!--[--> Cite <!--]--><!----><!----><!--[--><!----><!--]--></span></button></div></div><a href="/manuscript/202411.1987/v1" class="" data-v-240dfb06><h5 class="m-heading text-inherit m-h5 font-normal pt-sm hover:text-color-link-bold" data-v-240dfb06>Ultrasound-Assisted Synthesis of SnS<sub>2</sub> Quantum Dots Using Acetone as Solvent</h5></a><div class="flex pt-sm flex-wrap gap-sm" data-v-240dfb06><!--[--><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Grzegorz Matyszczak<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Krzysztof Krawczyk<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Albert Yedzikhanau<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Cezariusz Jastrzębski<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Piotr Dluzewski<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Aleksandra Fidler<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Tomasz Płociński<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Krystyna Ławniczak-Jabłońska<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Anna Wolska<span data-v-240dfb06>,</span><!--]--></p></div><!--]--><!--[--><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Aleksandra Drzewiecka-Antonik<!--]--></p></div><!--]--><!----></div><div class="w-full relative overflow-hidden pt-sm" data-v-240dfb06><div><div class="clamp-3"><!--[--><div class="inline abstract-content" data-v-240dfb06>Abstract: <p>A sonochemical synthesis of SnS2 quantum dots using acetone as a solvent is investigated. Two different tin sources (SnCl2∙2H2O or SnCl4∙5H2O) as well as two different sulphur sources (thioacetamide or Na2S2O3) were applied. The sonication time was also varied between 60 and 120 minutes. Resulting products of syntheses were characterized with the following techniques: powder X-ray diffraction, electron microscopy (SEM and HR-TEM), Raman and FT-IR spectroscopies, the Tauc method, and X-ray photoelectron spectroscopy. Obtained SnS2 nanostructures were in the form of quantum dots in the case of synthesis lasting 60 minutes (size of crystallites in the range of 3.5 &ndash; 7 nm) and in the form of elongated nanorods of length c.a. 25-30 nm and width of 5-6 nm in the case of synthesis lasting 120 minutes. XPS analyses revealed that the surface of the obtained products contained significant amount of tin at the second oxidation state (i. e. SnS). The quantum dots produced in the synthesis lasting 60 minutes showed value of energy bandgap of 2.7 eV indicating potential applications in photocatalysis.</p></div><!--]--></div><div class="invisible absolute"><!--[--><div class="inline abstract-content" data-v-240dfb06>Abstract: <p>A sonochemical synthesis of SnS2 quantum dots using acetone as a solvent is investigated. Two different tin sources (SnCl2∙2H2O or SnCl4∙5H2O) as well as two different sulphur sources (thioacetamide or Na2S2O3) were applied. The sonication time was also varied between 60 and 120 minutes. Resulting products of syntheses were characterized with the following techniques: powder X-ray diffraction, electron microscopy (SEM and HR-TEM), Raman and FT-IR spectroscopies, the Tauc method, and X-ray photoelectron spectroscopy. Obtained SnS2 nanostructures were in the form of quantum dots in the case of synthesis lasting 60 minutes (size of crystallites in the range of 3.5 &ndash; 7 nm) and in the form of elongated nanorods of length c.a. 25-30 nm and width of 5-6 nm in the case of synthesis lasting 120 minutes. XPS analyses revealed that the surface of the obtained products contained significant amount of tin at the second oxidation state (i. e. SnS). The quantum dots produced in the synthesis lasting 60 minutes showed value of energy bandgap of 2.7 eV indicating potential applications in photocatalysis.</p></div><!--]--></div></div><div style="display:none;" class="absolute right-0 bottom-0"><span><span class="inline-block align-middle w-6 h-4 bg-gradient-to-r from-transparent to-white"></span><span class="bg-white">... </span></span><button class="m-button m-button--sm m-button--tertiary rounded !inline-flex after:hidden bg-white" type="button"><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><!----><!--]--><!--[-->Show more <!--]--><!----><!----><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="keyboard_arrow_down" style="" width="16" height="16" viewBox="0 0 16 16"></svg><!--]--></span></button></div></div><div class="pt-sm text-color-subtle flex gap-x-sm gap-y-sm flex-col lg:flex-row" data-v-240dfb06><p class="m-text text-sm" data-v-240dfb06><!--[--> Posted: 26 November 2024<!--]--></p><p class="m-text text-sm underline cursor-pointer" data-v-240dfb06><!--[--><a href="https://doi.org/10.20944/preprints202411.1987.v1" rel="noopener noreferrer" data-v-240dfb06><span data-v-240dfb06>https://doi.org/</span>10.20944/preprints202411.1987.v1</a><!--]--></p></div></div><div data-v-240dfb06><!----></div></div><div data-v-240dfb06><div class="border-b border-color-default pb-md mb-sm" data-v-240dfb06><div class="pt-md lg:pt-lg lg:flex justify-between space-y-xs" data-v-240dfb06><div class="flex flex-wrap gap-x-xs gap-y-xs" data-v-240dfb06><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 bg-content-subtler text-color-default px-2 !bg-surface-disabled" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Article<!--]--></span><!--[--><!----><!--]--><!----></div><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 border border-color-bold px-2 text-color-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Electronic, Optical and Magnetic Materials<!--]--></span><!--[--><!----><!--]--><!----></div><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 border border-color-bold px-2 text-color-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Chemistry and Materials Science<!--]--></span><!--[--><!----><!--]--><!----></div></div><div class="flex" data-v-240dfb06><button class="m-button m-button--sm m-button--tertiary rounded mr-md after:hidden" type="button" data-v-240dfb06><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="download" style="" width="16" height="16" viewBox="0 0 16 16" data-v-240dfb06></svg><!--]--><!--[--> Download PDF <!--]--><!----><!----><!--[--><!----><!--]--></span></button><button class="m-button m-button--sm m-button--tertiary rounded after:hidden" type="button" data-v-240dfb06><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="format_quote" style="" width="16" height="16" viewBox="0 0 16 16" data-v-240dfb06></svg><!--]--><!--[--> Cite <!--]--><!----><!----><!--[--><!----><!--]--></span></button></div></div><a href="/manuscript/202411.1983/v1" class="" data-v-240dfb06><h5 class="m-heading text-inherit m-h5 font-normal pt-sm hover:text-color-link-bold" data-v-240dfb06>An Organic-Inorganic Hybrid Semiconducting Quantum Spin Liquid Candidate: (BEDT-TTF)<sub>3</sub>[Cu<sub>2</sub>(m-C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]·2CH<sub>3</sub>CH<sub>2</sub>OH</h5></a><div class="flex pt-sm flex-wrap gap-sm" data-v-240dfb06><!--[--><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Bin Zhang<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Yan Zhang<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Dongwei Wang<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Zheming Wang<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Guancai Chang<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Zengqiang Gao<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Yanjun Guo<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Fen Liu<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Zhijuan Zhao<span data-v-240dfb06>,</span><!--]--></p></div><!--]--><!--[--><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Xiaoyu Zhang<!--]--></p></div><!--]--><div data-v-240dfb06><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 bg-content-subtler text-color-default px-2 bg-info-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->+12 authors<!--]--></span><!--[--><!----><!--]--><!----></div></div></div><div class="w-full relative overflow-hidden pt-sm" data-v-240dfb06><div><div class="clamp-3"><!--[--><div class="inline abstract-content" data-v-240dfb06>Abstract: The organic-inorganic hybrid (BEDT-TTF)3[Cu2(m-C2O4)3]·2CH3CH2OH (I)was synthesized using the electrocrystallization method. It composes q21-phase organic donor layer and an inorganic antiferromagnetic honeycomb lattice with the Jahn-Teller distortion. The disordered solvent molecules CH3CH2OH are present within the cavities of the honeycomb lattice. The formal charge of donor molecules was assigned to +2/3 based on bond lengths in TTF core and corresponded to Raman spectra. Jahn-Teller effect on conductivity and magnetization is studied. It is a semiconductor with srt = 0.04 S/cm and Ea = 40 meV. No long-range ordering is observed above 2 K from zero-field cooling/field cooling magnetization and confirmed by specific heat measurement. The spin frustration with f &amp;gt; 10 from the antiferromagnetic copper-oxalate-framework was observed. It is a candidate for quantum spin liquid.</div><!--]--></div><div class="invisible absolute"><!--[--><div class="inline abstract-content" data-v-240dfb06>Abstract: The organic-inorganic hybrid (BEDT-TTF)3[Cu2(m-C2O4)3]·2CH3CH2OH (I)was synthesized using the electrocrystallization method. It composes q21-phase organic donor layer and an inorganic antiferromagnetic honeycomb lattice with the Jahn-Teller distortion. The disordered solvent molecules CH3CH2OH are present within the cavities of the honeycomb lattice. The formal charge of donor molecules was assigned to +2/3 based on bond lengths in TTF core and corresponded to Raman spectra. Jahn-Teller effect on conductivity and magnetization is studied. It is a semiconductor with srt = 0.04 S/cm and Ea = 40 meV. No long-range ordering is observed above 2 K from zero-field cooling/field cooling magnetization and confirmed by specific heat measurement. The spin frustration with f &amp;gt; 10 from the antiferromagnetic copper-oxalate-framework was observed. It is a candidate for quantum spin liquid.</div><!--]--></div></div><div style="display:none;" class="absolute right-0 bottom-0"><span><span class="inline-block align-middle w-6 h-4 bg-gradient-to-r from-transparent to-white"></span><span class="bg-white">... </span></span><button class="m-button m-button--sm m-button--tertiary rounded !inline-flex after:hidden bg-white" type="button"><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><!----><!--]--><!--[-->Show more <!--]--><!----><!----><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="keyboard_arrow_down" style="" width="16" height="16" viewBox="0 0 16 16"></svg><!--]--></span></button></div></div><div class="pt-sm text-color-subtle flex gap-x-sm gap-y-sm flex-col lg:flex-row" data-v-240dfb06><p class="m-text text-sm" data-v-240dfb06><!--[--> Posted: 26 November 2024<!--]--></p><p class="m-text text-sm underline cursor-pointer" data-v-240dfb06><!--[--><a href="https://doi.org/10.20944/preprints202411.1983.v1" rel="noopener noreferrer" data-v-240dfb06><span data-v-240dfb06>https://doi.org/</span>10.20944/preprints202411.1983.v1</a><!--]--></p></div></div><div data-v-240dfb06><!----></div></div><div data-v-240dfb06><div class="border-b border-color-default pb-md mb-sm" data-v-240dfb06><div class="pt-md lg:pt-lg lg:flex justify-between space-y-xs" data-v-240dfb06><div class="flex flex-wrap gap-x-xs gap-y-xs" data-v-240dfb06><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 bg-content-subtler text-color-default px-2 !bg-surface-disabled" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Short Note<!--]--></span><!--[--><!----><!--]--><!----></div><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 border border-color-bold px-2 text-color-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Medicinal Chemistry<!--]--></span><!--[--><!----><!--]--><!----></div><div class="m-tag flex items-center gap-2 rounded py-0.5 h-6 border border-color-bold px-2 text-color-subtlest" data-v-240dfb06><!--[--><!----><!--]--><span class="flex items-center whitespace-nowrap text-xs leading-normal"><!--[-->Chemistry and Materials Science<!--]--></span><!--[--><!----><!--]--><!----></div></div><div class="flex" data-v-240dfb06><button class="m-button m-button--sm m-button--tertiary rounded mr-md after:hidden" type="button" data-v-240dfb06><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="download" style="" width="16" height="16" viewBox="0 0 16 16" data-v-240dfb06></svg><!--]--><!--[--> Download PDF <!--]--><!----><!----><!--[--><!----><!--]--></span></button><button class="m-button m-button--sm m-button--tertiary rounded after:hidden" type="button" data-v-240dfb06><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="format_quote" style="" width="16" height="16" viewBox="0 0 16 16" data-v-240dfb06></svg><!--]--><!--[--> Cite <!--]--><!----><!----><!--[--><!----><!--]--></span></button></div></div><a href="/manuscript/202411.1934/v1" class="" data-v-240dfb06><h5 class="m-heading text-inherit m-h5 font-normal pt-sm hover:text-color-link-bold" data-v-240dfb06>17&beta;-Hydroxy-2-oxa-5&alpha;-androstan-3-one</h5></a><div class="flex pt-sm flex-wrap gap-sm" data-v-240dfb06><!--[--><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Savina Stoyanova<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Georgi Dinkov<span data-v-240dfb06>,</span><!--]--></p></div><div class="flex items-center" data-v-240dfb06><p class="m-text text-sm text-color-subtlest" data-v-240dfb06><!--[-->Milen G. Bogdanov<!----><!--]--></p></div><!--]--><!--[--><!--]--><!----></div><div class="w-full relative overflow-hidden pt-sm" data-v-240dfb06><div><div class="clamp-3"><!--[--><div class="inline abstract-content" data-v-240dfb06>Abstract: <p>We have successfully synthesized a 2-oxa androstane derivative, 17&beta;-hydroxy-2-oxa-5&alpha;-androstan-3-one (6), and confirmed its structure using NMR spectroscopy and mass spectrometry.</p></div><!--]--></div><div class="invisible absolute"><!--[--><div class="inline abstract-content" data-v-240dfb06>Abstract: <p>We have successfully synthesized a 2-oxa androstane derivative, 17&beta;-hydroxy-2-oxa-5&alpha;-androstan-3-one (6), and confirmed its structure using NMR spectroscopy and mass spectrometry.</p></div><!--]--></div></div><div style="display:none;" class="absolute right-0 bottom-0"><span><span class="inline-block align-middle w-6 h-4 bg-gradient-to-r from-transparent to-white"></span><span class="bg-white">... </span></span><button class="m-button m-button--sm m-button--tertiary rounded !inline-flex after:hidden bg-white" type="button"><!----><span class="inline-flex h-full w-full items-center gap-2 whitespace-nowrap justify-center"><!--[--><!----><!--]--><!--[-->Show more <!--]--><!----><!----><!--[--><svg xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink" aria-hidden="true" role="img" data-testid="keyboard_arrow_down" style="" width="16" height="16" viewBox="0 0 16 16"></svg><!--]--></span></button></div></div><div class="pt-sm text-color-subtle flex gap-x-sm gap-y-sm flex-col lg:flex-row" data-v-240dfb06><p class="m-text text-sm" data-v-240dfb06><!--[--> Posted: 26 November 2024<!--]--></p><p class="m-text text-sm underline cursor-pointer" data-v-240dfb06><!--[--><a href="https://doi.org/10.20944/preprints202411.1934.v1" rel="noopener noreferrer" data-v-240dfb06><span data-v-240dfb06>https://doi.org/</span>10.20944/preprints202411.1934.v1</a><!--]--></p></div></div><div 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Stay engaged with research that explores social issues, cultural dynamics, and economic systems, enriching our understanding of human interactions.","social-sciences",{"code":41,"msg":124,"data":125},"",{"total":126,"rows":127,"filters":480},6483,[128,157,184,212,236,265,295,340,381,458],{"views":41,"true_downloads":41,"true_views":41,"downloads":41,"id":129,"version":7,"hash_key":130,"article_type":131,"subject":132,"top_subject":70,"title":133,"abstract":134,"keywords":135,"doi":136,"published_at":137,"download_url":138,"like_url":139,"authors":140,"score":7,"liked":156},"202411.1970","7d027bec5c5ea26b340721f9a26e1187","Article","Electronic, Optical and Magnetic Materials","Construction of Hybrid ZnO/SnO2 N&ndash;N Heterojunction with Hierarchical Porous Biomorphic Nanostructure as a High-Response Sensor for Methanol Gas","\u003Cp>A novel hierarchical porous biomorphic ZnO/SnO has been facilely synthesized in one step using bagasse as bio-template. The structural features of the ZnO/SnO2 n&ndash;n heterostructures were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), and X-ray photoelectron spectroscopy (XPS). The results revealed that the as-prepared ZnO/SnO2 retained the original pore morphology of the bagasse material, and the ZnO/SnO2 was demonstrated with higher sensing performance as compared with the pure SnO2. Particularly, when molar ratio SnO2:ZnO=1:1, the sensor displayed the highest response, showing an excellent response value of 37 under 100 ppm methanol at 340℃. Meanwhile, ZnO/SnO2 composite exhibit good gas selectivity and stability to methanol, which can mainly be attributed to the formation of n-n junctions between SnO2 and ZnO, high capability of absorbed oxygen species of the ZnO/SnO2 composite.\u003C/p>","ZnO/SnO2; Composite material; Gas sensor; Methanol gas; n&ndash;n heterojunction","10.20944/preprints202411.1970.v1","2024-11-27T02:05:14Z","/frontend/manuscript/7d027bec5c5ea26b340721f9a26e1187/download_pub","/frontend/user/manuscript/7d027bec5c5ea26b340721f9a26e1187/like_toggle",[141,144,147,150,153],{"name":142,"email":143},"Zong-Lai Liu","liuzonglai@ccit.edu.cn",{"name":145,"email":146},"Zhao Yang","1353706932@qq.com",{"name":148,"email":149},"Bing Liu","hkliubing6698@wzu.edu.cn",{"name":151,"email":152},"Ya-Nan Chen","chenyn061@nenu.edu.cn",{"name":154,"email":155},"Wei Feng","weifeng@jlu.edu.cn",false,{"views":158,"true_downloads":159,"true_views":158,"downloads":159,"id":160,"version":7,"hash_key":161,"article_type":162,"subject":70,"top_subject":163,"title":164,"abstract":165,"keywords":166,"doi":167,"published_at":168,"download_url":169,"like_url":170,"authors":171,"score":7,"liked":156},2,3,"202411.2013","b892773b749023107c77104d39fe8f8e","Review","Polymers and Plastics","Smart Polymer Composites for Electrical Heating: A Review","The paper presents an overview of conductive polymer composites based on thermosets, ther-moplastics and elastomers modified with carbon nanotubes (CNT). To impart conductive prop-erties to polymers, metal or carbon dispersed materials or their combinations are used. The in-troduction of dispersed materials into polymers is associated with their microstructural proper-ties, as well as polymerization methods. Such polymerization methods as melt mixing, solution technology, introduction of fillers into the liquid phase of the composite with subsequent polymerization due to the use of a catalyst are known. Polymer composites that are capable of conducting electric current and changing their properties under the influence of an electric field, i.e. having one or more functional purposes, are called &quot;smart&quot; or intelligent. One of such applications is electric heating elements with the function of adaptive power consumption or the effect of self-regulation of temperature depending on the surrounding conditions. A wide variety of polymers and dispersed materials with conductive properties determine a wide range of func-tional capabilities of the composite, including a positive temperature coefficient of resistance, which is necessary to control temperature properties. The most effective filler in a polymer for obtaining a composite with specified properties are carbon nanomaterials, in particular CNTs. This is due to the fact that CNTs are a nanosized material that has a high bulk density with a low mass, which allows achieving high electrical conductivity. Calculation of model parameters of polymer composites containing carbon nanostructures can be carried out using neural networks and ma-chine learning, which provide a fundamentally new result.","polymer; electrical conductivity; nanocomposite; carbon nanomaterials; carbon&nbsp;nanotubes; temperature self‐regulation; positive drag coefficient; neural networks","10.20944/preprints202411.2013.v1","2024-11-26T13:19:05Z","/frontend/manuscript/b892773b749023107c77104d39fe8f8e/download_pub","/frontend/user/manuscript/b892773b749023107c77104d39fe8f8e/like_toggle",[172,175,178,181],{"name":173,"email":174},"Alexandr Viktorovich Shchegolkov","energynano@yandex.ru",{"name":176,"email":177},"Aleksei Viktorovich Shchegolkov","alexxx5000@mail.ru",{"name":179,"email":180},"Vladimir Vladimirovich Kaminskii","kam-vladimiro@yandex.ru",{"name":182,"email":183},"Maxim Alexandrovich Chumak","equilibrium2027@yandex.ru",{"views":7,"true_downloads":185,"true_views":7,"downloads":185,"id":186,"version":7,"hash_key":187,"article_type":162,"subject":70,"top_subject":188,"title":189,"abstract":190,"keywords":191,"doi":192,"published_at":193,"download_url":194,"like_url":195,"authors":196,"score":7,"liked":156},4,"202411.1966","0b62c0a577833a7d6f79e6ae6d71baf5","Nanotechnology","Harnessing Radiation for Nanotechnology: A Comprehensive Review of Techniques, Innovations and Application","Nanomaterial properties such as size, structure, and composition can be controlled by manipulating radiation, such as gamma rays, X-rays, and electron beams. This control allows scientists to create materials with desired properties that can be used in a wide range of applications, from electronics to medicine. This use of radiation for nanotechnology is revolutionizing the way we design and manufacture materials. Additionally, radiation-induced nanomaterials are more cost-effective and energy-efficient. This technology is also having a positive impact on the environment, as materials are being produced with fewer emissions, less energy, and less waste. This cutting-edge technology is opening up new possibilities and has become an attractive option for many industries, from medical advancements to energy storage. It is also helping to make the world a better place by reducing our carbon footprint and preserving natural resources. This review aims to meticulously point out the synthesis approach and highlights significant progress in generating radiation-induced nanomaterials with tunable and complex morphologies. This comprehensive review article is essential for researchers to design innovative materials for advancements in health care, electronics, energy storage, and environmental remediation.","Nano material; electron beam irradiation; gamma radiation; X-ray beam; Application of nanomaterials; metallic nanoparticle","10.20944/preprints202411.1966.v1","2024-11-26T12:46:44Z","/frontend/manuscript/0b62c0a577833a7d6f79e6ae6d71baf5/download_pub","/frontend/user/manuscript/0b62c0a577833a7d6f79e6ae6d71baf5/like_toggle",[197,200,203,206,209],{"name":198,"email":199},"Mobinul Islam","mobin85@dongguk.edu",{"name":201,"email":202},"Md. Shahriar Ahmed","shahriar.che.sust@gmail.com",{"name":204,"email":205},"Sua Yun","suanet50@gmail.com",{"name":207,"email":208},"Hae Yong Kim","2142eogks@gmail.com",{"name":210,"email":211},"Kyung-Wan Nam","knam@dongguk.edu",{"views":185,"true_downloads":159,"true_views":185,"downloads":159,"id":213,"version":7,"hash_key":214,"article_type":131,"subject":70,"top_subject":215,"title":216,"abstract":217,"keywords":218,"doi":219,"published_at":220,"download_url":221,"like_url":222,"authors":223,"score":7,"liked":156},"202411.1919","97d209277f26611ccd86baee5fb5febb","Analytical Chemistry","Simultaneous Determination of the Main Aromatic Com-pounds and Divanillin in Vanilla planifolia Jacks. ex Andrews by HPLC-DAD","\u003Cp>Vanilla planifolia Jacks. ex Andrews pods can lose up to 50% of their vanillin during curing. One explanation for this is the transformation of vanillin due to enzyme action, such as peroxidases, which generate the formation of dimers like divanillin. Therefore, in this work, a simultaneous high-performance liquid chromatography method (HPLC-DAD) was developed and validated for the separation and quantification of the main compounds present in Vanilla planifolia Jacks. ex Andrews and divanillin. The separation of 9 compounds of interest was achieved within 15 minutes using a Zorbax Eclipse XDB-C18 column (250 mm x 4.6 mm i.d., 5 &mu;m particle size). The variables optimized included the mobile phase (water as solvent A, methanol as solvent B, and acidified water, 10&ndash;2 M H3PO4, as solvent C), the separation gradient, and the column tempera-ture (40-60 &deg;C). The maximum divanillin content was 0.02 g/100 g d.w. in a sample from Papantla de Olarte. Chromatographic performance evaluation revealed excellent resolution, retention factor, and selectivity. The method was successfully validated in terms of limits of detection and quantification, linearity, and precision, as well as its application to cured pods, with evidence of divanillin presence in all analyzed sample.\u003C/p>","aromatic compounds; divanillin; HPLC‐DAD; phenols; validation; Vanilla planifolia","10.20944/preprints202411.1919.v1","2024-11-26T12:43:04Z","/frontend/manuscript/97d209277f26611ccd86baee5fb5febb/download_pub","/frontend/user/manuscript/97d209277f26611ccd86baee5fb5febb/like_toggle",[224,227,230,233],{"name":225,"email":226},"Yunuen Erandy Torres-Zamudio","d20020011@veracruz.tecnm.mx",{"name":228,"email":229},"Guadalupe del Carmen Rodríguez-Jimenes","guadalupe.rj@veracruz.tecnm.mx",{"name":231,"email":232},"Gerardo Fernández Barbero","gerardo.fernandez@uca.es",{"name":234,"email":235},"Araceli Pérez-Silva","araceli.ps@tuxtepec.tecnm.mx",{"views":237,"true_downloads":238,"true_views":237,"downloads":238,"id":239,"version":7,"hash_key":240,"article_type":131,"subject":70,"top_subject":241,"title":242,"abstract":243,"keywords":244,"doi":245,"published_at":246,"download_url":247,"like_url":248,"authors":249,"score":7,"liked":156},6,7,"202411.1973","f6fd592b9b7ae83892917e39b0a3a8b0","Applied Chemistry","Extraction of &szlig;-Carotene from Pumpkin (Curcubita moschata) and Spinach (Spinacia oleracea) Using Environmentally Friendly Deep Eutectic Solvents (DESs)","There is an increasing demand for antioxidants, nutraceuticals and natural colorants. ß-Carotene is one of the commonly used commodities which fits description. ß-Carotene is a highly hydrophobic molecule; therefore, commercial extraction processes generally use highly non-polar solvents and these are barely environmentally friendly chemicals. The aim of this research was to develop effective and sustainable extraction processes for ß-Carotene from pumpkin and spinach using environmentally friendly green chemicals. A series of deep eutectic solvents with L-menthol and carboxylic aliphatic acids were synthesized for extraction of β-carotene from pumpkin and spinach via mechanical mixing (MMAE) and homogenization assisted extraction (HAE). Response surface methodology and ANOVA analyses were used to analyze the data. Menthol:Propionic Acid DESs had the best effect on the extraction of ß-Carotene (11.528 μg-ß-Carotene/gr-pumpkin for MMAE, 8.966 μg-ß-Carotene/gr-pumpkin for HAE, 16.924 μg-ß-Carotene/gr-spinach for MMAE and 18.870 μg-ß-Carotene/gr-spinach for HAE) under the optimal conditions (HBD molar ratio: 0.6452, 15 min. for MMAE of ß-Carotene from pumpkin, HBD molar ratio: 0.6198, 30.0 sec., 7061 rpm for HAE of ß-Carotene from pumpkin, HBD molar ratio: 0.8000, 60 min. for MMAE of ß-Carotene from spinach, HBD molar ratio: 0.8000, 120.0 sec., 7000 rpm for HAE of ß-Carotene from spinach).","ß-carotene; deep eutectic solvents; menthol; acetic acid; propionic acid; butyric acid; pumpkin; spinach; extraction; biomass","10.20944/preprints202411.1973.v1","2024-11-26T12:06:11Z","/frontend/manuscript/f6fd592b9b7ae83892917e39b0a3a8b0/download_pub","/frontend/user/manuscript/f6fd592b9b7ae83892917e39b0a3a8b0/like_toggle",[250,253,256,259,262],{"name":251,"email":252},"Koray Tanrıver","koray.tanriver@ogr.iuc.edu.tr",{"name":254,"email":255},"Mehmet Bilgin","mbilgin@iuc.edu.tr",{"name":257,"email":258},"Selin Şahin Sevgili","selins@iuc.edu.tr",{"name":260,"email":261},"İrem Toprakçı Yüksel","irem.toprakciyuksel@iuc.edu.tr",{"name":263,"email":264},"Ebru Kurtulbaş Şahin","ebru.kurtulbas@iuc.edu.tr",{"views":266,"true_downloads":159,"true_views":266,"downloads":159,"id":267,"version":7,"hash_key":268,"article_type":131,"subject":70,"top_subject":163,"title":269,"abstract":270,"keywords":271,"doi":272,"published_at":273,"download_url":274,"like_url":275,"authors":276,"score":7,"liked":156},5,"202411.2006","3ca9048f67f554cd6f0a6faf54d5c33b","Influence of Fresh Latex Coagulation on the Parameter Characteristics of the Yeoh Hyperelastic Constitutive Model for Natural Rubber","Currently, natural rubber is an irreplaceable and important strategic material. Coagulation of fresh latex is one of the key processes in natural rubber processing, which directly affects the properties of natural rubber and its derived materials. Based on tensile experiments and the Yeoh model, the effects of natural coagulation, enzyme coagulation, acid coagulation, microbial coagulation, and enzyme-assisted microbial coagulation modes on the superelastic ontological relationships of natural rubber were analyzed in detail. Given the limitations of the Yeoh model in describing the mechanical behavior in the low-strain region, a strain-rate-related factor was introduced and a more accurate hyperelastic constitutive relationship of natural rubber was established. The results demonstrate that the Yeoh model effectively characterizes the mechanical behavior of natural rubber carbon black composites in the moderate and high-strain regions. Additionally, the material characteristics reflected by the model parameters align with those observed in cyclic tensile tests The performance of rubber under small, medium, and large deformations is different for different coagulation methods. The modulus of natural coagulation rubber is the highest in small deformations, the modulus of enzyme coagulation rubber is the highest in medium deformations and the modulus of enzyme-assisted microbial coagulation rubber is the highest in large deformations so that the appropriate coagulation method can be selected according to the degree of deformation of the rubber required by application scenarios in the practical application. Following the incorporation of a strain-rate-related factor, the modified Yeoh model provides accurate predictions of stress-strain curves across different tensile speeds within the low-strain range.","natural rubber (NR); coagulation; constitutive model; Yeoh model; properties","10.20944/preprints202411.2006.v1","2024-11-26T10:48:57Z","/frontend/manuscript/3ca9048f67f554cd6f0a6faf54d5c33b/download_pub","/frontend/user/manuscript/3ca9048f67f554cd6f0a6faf54d5c33b/like_toggle",[277,280,283,286,289,292],{"name":278,"email":279},"Li Ding","gdzjding@163.com",{"name":281,"email":282},"Honghai Huang","345416303@qq.com",{"name":284,"email":285},"Yuekun Wang","8854878149@qq.com",{"name":287,"email":288},"Jianwei Li","1024654293@qq.com",{"name":290,"email":291},"Hongxing Gui","guihongxing@263.net",{"name":293,"email":294},"Yongping Chen","chenyp@hainanu.edu.cn",{"views":238,"true_downloads":266,"true_views":238,"downloads":266,"id":296,"version":7,"hash_key":297,"article_type":131,"subject":70,"top_subject":298,"title":299,"abstract":300,"keywords":301,"doi":302,"published_at":303,"download_url":304,"like_url":305,"authors":306,"score":7,"liked":156},"202411.1986","cc53e7b6d66a2a71767367ab1413376a","Inorganic and Nuclear Chemistry","A Trinuclear Co(II) Complex Based on the Tris-dioxolene Triphenylene Non Innocent Bridge: Complementary Redox, Magnetic Behavior and Theoretical Calculations","A trinuclear Co(II)-containing complex was assembled using the non-innocent hexahydroxytriphenylene bridging ligand. Cyclovoltammetry and spectro-electrochemistry studies revealed that the central ligand can sustain five reversible redox events leading to different spices with diverse optical behavior. Complementary analysis of the molecular structure confirmed by ab initio theoretical calculations are consistent with the bridge in the tris-semiquinone (sq) state for the trinuclear complex. The exchange coupling among the electrons of the bridge results in a spin doublet (s = ½) localized close to one of the three Co(II) ions, as suggested by the experimental magnetic data. The central doublet undergoes one large antiferromagnetic exchange coupling with one Co(II) and almost no coupling with the two other metal ions.","hexahydroxytriphenylene; non-innocent bridge; trinuclear Co complex; spectroelectrochemistry; Co magnetism; ab initio calculations","10.20944/preprints202411.1986.v1","2024-11-26T10:11:24Z","/frontend/manuscript/cc53e7b6d66a2a71767367ab1413376a/download_pub","/frontend/user/manuscript/cc53e7b6d66a2a71767367ab1413376a/like_toggle",[307,310,313,316,319,322,325,328,331,334,337],{"name":308,"email":309},"Aristide Colin","aristide.colin@universite-paris-saclay.fr",{"name":311,"email":312},"Yiting Wang","yitingwang527829@outlook.com",{"name":314,"email":315},"François Lambert","francois.lambert.saclay@gmail.com",{"name":317,"email":318},"Nathalie Bridonneau","nathalie.bridonneau@universite-paris-saclay.fr",{"name":320,"email":321},"Nicolas Suaud","suaud@irsamc.ups-tlse.fr",{"name":323,"email":324},"Régis Guillot","regis.guillot@universite-paris-saclay.fr",{"name":326,"email":327},"Eric Rivière","eric.riviere@universite-paris-saclay.fr",{"name":329,"email":330},"Zakaria Halime","zakaria.halime@universite-paris-saclay.fr",{"name":332,"email":333},"Nathalie Guihéry","nathalie.guihery@irsamc.ups-tlse.fr",{"name":335,"email":336},"Shin-ichi Ohkoshi","ohkoshi@chem.s.u-tokyo.ac.jp",{"name":338,"email":339},"Talal Mallah","talal.mallah@universite-paris-saclay.fr",{"views":238,"true_downloads":185,"true_views":238,"downloads":185,"id":341,"version":7,"hash_key":342,"article_type":131,"subject":70,"top_subject":188,"title":343,"abstract":344,"keywords":345,"doi":346,"published_at":347,"download_url":348,"like_url":349,"authors":350,"score":7,"liked":156},"202411.1987","a772a5b303329c80e4f0b82a524d1729","Ultrasound-Assisted Synthesis of SnS\u003Csub>2\u003C/sub> Quantum Dots Using Acetone as Solvent","\u003Cp>A sonochemical synthesis of SnS2 quantum dots using acetone as a solvent is investigated. Two different tin sources (SnCl2∙2H2O or SnCl4∙5H2O) as well as two different sulphur sources (thioacetamide or Na2S2O3) were applied. The sonication time was also varied between 60 and 120 minutes. Resulting products of syntheses were characterized with the following techniques: powder X-ray diffraction, electron microscopy (SEM and HR-TEM), Raman and FT-IR spectroscopies, the Tauc method, and X-ray photoelectron spectroscopy. Obtained SnS2 nanostructures were in the form of quantum dots in the case of synthesis lasting 60 minutes (size of crystallites in the range of 3.5 &ndash; 7 nm) and in the form of elongated nanorods of length c.a. 25-30 nm and width of 5-6 nm in the case of synthesis lasting 120 minutes. XPS analyses revealed that the surface of the obtained products contained significant amount of tin at the second oxidation state (i. e. SnS). The quantum dots produced in the synthesis lasting 60 minutes showed value of energy bandgap of 2.7 eV indicating potential applications in photocatalysis.\u003C/p>","sonochemistry; quantum dots; tin(IV) sulphide","10.20944/preprints202411.1987.v1","2024-11-26T09:15:31Z","/frontend/manuscript/a772a5b303329c80e4f0b82a524d1729/download_pub","/frontend/user/manuscript/a772a5b303329c80e4f0b82a524d1729/like_toggle",[351,354,357,360,363,366,369,372,375,378],{"name":352,"email":353},"Grzegorz Matyszczak","grzegorz.matyszczak@pw.edu.pl",{"name":355,"email":356},"Krzysztof Krawczyk","krzysztof.krawczyk@pw.edu.pl",{"name":358,"email":359},"Albert Yedzikhanau","albert.yedzikhanau.stud@pw.edu.pl",{"name":361,"email":362},"Cezariusz Jastrzębski","cezariusz.jastrzebski@pw.edu.pl",{"name":364,"email":365},"Piotr Dluzewski","dluzew@ifpan.edu.pl",{"name":367,"email":368},"Aleksandra Fidler","afidler@ifpan.edu.pl",{"name":370,"email":371},"Tomasz Płociński","tomasz.plocinski@pw.edu.pl",{"name":373,"email":374},"Krystyna Ławniczak-Jabłońska","jablo@ifpan.edu.pl",{"name":376,"email":377},"Anna Wolska","wolska@ifpan.edu.pl",{"name":379,"email":380},"Aleksandra Drzewiecka-Antonik","adrzew@ifpan.edu.pl",{"views":266,"true_downloads":238,"true_views":266,"downloads":238,"id":382,"version":7,"hash_key":383,"article_type":131,"subject":70,"top_subject":132,"title":384,"abstract":385,"keywords":386,"doi":387,"published_at":388,"download_url":389,"like_url":390,"authors":391,"score":7,"liked":156},"202411.1983","2d03277c50715bf76f3126a1d0917a1a","An Organic-Inorganic Hybrid Semiconducting Quantum Spin Liquid Candidate: (BEDT-TTF)\u003Csub>3\u003C/sub>[Cu\u003Csub>2\u003C/sub>(m-C\u003Csub>2\u003C/sub>O\u003Csub>4\u003C/sub>)\u003Csub>3\u003C/sub>]·2CH\u003Csub>3\u003C/sub>CH\u003Csub>2\u003C/sub>OH","The organic-inorganic hybrid (BEDT-TTF)3[Cu2(m-C2O4)3]·2CH3CH2OH (I)was synthesized using the electrocrystallization method. It composes q21-phase organic donor layer and an inorganic antiferromagnetic honeycomb lattice with the Jahn-Teller distortion. The disordered solvent molecules CH3CH2OH are present within the cavities of the honeycomb lattice. The formal charge of donor molecules was assigned to +2/3 based on bond lengths in TTF core and corresponded to Raman spectra. Jahn-Teller effect on conductivity and magnetization is studied. It is a semiconductor with srt = 0.04 S/cm and Ea = 40 meV. No long-range ordering is observed above 2 K from zero-field cooling/field cooling magnetization and confirmed by specific heat measurement. The spin frustration with f &amp;gt; 10 from the antiferromagnetic copper-oxalate-framework was observed. It is a candidate for quantum spin liquid.","Jahn-Teller effect; Cu(II); oxalate; single crystal; conductivity; spin frustration; quantum spin liquid candidate","10.20944/preprints202411.1983.v1","2024-11-26T08:45:58Z","/frontend/manuscript/2d03277c50715bf76f3126a1d0917a1a/download_pub","/frontend/user/manuscript/2d03277c50715bf76f3126a1d0917a1a/like_toggle",[392,395,398,401,404,407,410,413,416,419,422,425,428,431,434,437,440,443,446,449,452,455],{"name":393,"email":394},"Bin Zhang","zhangbin@iccas.ac.cn",{"name":396,"email":397},"Yan Zhang","zhang_yan@pku.edu.cn",{"name":399,"email":400},"Dongwei Wang","wangdw@nanoctr.cn",{"name":402,"email":403},"Zheming Wang","wangzm@pku.edu.cn",{"name":405,"email":406},"Guancai Chang","changgc@iphy.ac.cn",{"name":408,"email":409},"Zengqiang Gao","gaozq@iphy.ac.cn",{"name":411,"email":412},"Yanjun Guo","guoyj@nanoctr.cn",{"name":414,"email":415},"Fen Liu","fenliu@iccas.ac.cn",{"name":417,"email":418},"Zhijuan Zhao","zhaozj@iccas.ac.cn",{"name":420,"email":421},"Xiaoyu Zhang","xyiuzhang@iccas.ac.cn",{"name":423,"email":424},"Baolong Qu","qu-bao-long@126.com",{"name":426,"email":427},"Peng Xu","xup@iccas.ac.cn",{"name":429,"email":430},"Jiaou Wang","wangjo@iphy.ac.cn",{"name":432,"email":433},"Fenliang Dong","dongfl@nanoctr.cn",{"name":435,"email":436},"Tongling Liang","ltl@iccas.ac.cn",{"name":438,"email":439},"Yang Sun","syou047113@iccas.ac.cn",{"name":441,"email":442},"Deliang Yang","stmydl@iccas.ac.cn",{"name":444,"email":445},"Qiaolian Li","liliqolian@iccas.ac.cn",{"name":447,"email":448},"Xiaofei Luo","luoxiaofei@iccas.ac.cn",{"name":450,"email":451},"Mei Liu","liumei@iccas.ac.cn",{"name":453,"email":454},"Rongjuan Feng","fengrongjuan@iccas.ac.cn",{"name":456,"email":457},"Xueying Zhang","snozhang@iccas.ac.cn",{"views":266,"true_downloads":238,"true_views":266,"downloads":238,"id":459,"version":7,"hash_key":460,"article_type":461,"subject":70,"top_subject":462,"title":463,"abstract":464,"keywords":465,"doi":466,"published_at":467,"download_url":468,"like_url":469,"authors":470,"score":7,"liked":156},"202411.1934","f107b9aa0a6afe49f5b481387a4e95a6","Short Note","Medicinal Chemistry","17&beta;-Hydroxy-2-oxa-5&alpha;-androstan-3-one","\u003Cp>We have successfully synthesized a 2-oxa androstane derivative, 17&beta;-hydroxy-2-oxa-5&alpha;-androstan-3-one (6), and confirmed its structure using NMR spectroscopy and mass spectrometry.\u003C/p>","steroids; oxasteroids; androgenic-anabolic steroids; dihydrotestosterone","10.20944/preprints202411.1934.v1","2024-11-26T06:59:59Z","/frontend/manuscript/f107b9aa0a6afe49f5b481387a4e95a6/download_pub","/frontend/user/manuscript/f107b9aa0a6afe49f5b481387a4e95a6/like_toggle",[471,474,477],{"name":472,"email":473},"Savina Stoyanova","savina_si@abv.bg",{"name":475,"email":476},"Georgi Dinkov","dinkovg@georgetown.edu",{"name":478,"email":479},"Milen G. 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