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class="vector-dropdown-label-text">开关目录</span> </label> <div class="vector-dropdown-content"> <div id="vector-page-titlebar-toc-unpinned-container" class="vector-unpinned-container"> </div> </div> </div> </nav> <h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">六氟化鎝</span></h1> <div id="p-lang-btn" class="vector-dropdown mw-portlet mw-portlet-lang" > <input type="checkbox" id="p-lang-btn-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-p-lang-btn" class="vector-dropdown-checkbox mw-interlanguage-selector" aria-label="前往另一种语言写成的文章。12种语言可用" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-12" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">12种语言</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-azb mw-list-item"><a href="https://azb.wikipedia.org/wiki/%D9%87%D9%82%D8%B2%D8%A7%D9%81%D9%84%D9%88%D8%B1%DB%8C%D8%AF_%D8%AA%DA%A9%D9%86%D8%B3%DB%8C%D9%88%D9%85" title="هقزافلورید تکنسیوم – South Azerbaijani" lang="azb" hreflang="azb" data-title="هقزافلورید تکنسیوم" data-language-autonym="تۆرکجه" data-language-local-name="South Azerbaijani" class="interlanguage-link-target"><span>تۆرکجه</span></a></li><li class="interlanguage-link interwiki-cs mw-list-item"><a href="https://cs.wikipedia.org/wiki/Fluorid_techneciov%C3%BD" title="Fluorid techneciový – 捷克语" lang="cs" hreflang="cs" data-title="Fluorid techneciový" data-language-autonym="Čeština" data-language-local-name="捷克语" class="interlanguage-link-target"><span>Čeština</span></a></li><li class="interlanguage-link interwiki-de mw-list-item"><a href="https://de.wikipedia.org/wiki/Technetium(VI)-fluorid" title="Technetium(VI)-fluorid – 德语" lang="de" hreflang="de" data-title="Technetium(VI)-fluorid" data-language-autonym="Deutsch" data-language-local-name="德语" class="interlanguage-link-target"><span>Deutsch</span></a></li><li class="interlanguage-link interwiki-en mw-list-item"><a href="https://en.wikipedia.org/wiki/Technetium_hexafluoride" title="Technetium hexafluoride – 英语" lang="en" hreflang="en" data-title="Technetium hexafluoride" data-language-autonym="English" data-language-local-name="英语" class="interlanguage-link-target"><span>English</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%D9%87%DA%AF%D8%B2%D8%A7%D9%81%D9%84%D9%88%D8%B1%DB%8C%D8%AF_%D8%AA%DA%A9%D9%86%D8%B3%DB%8C%D9%85" title="هگزافلورید تکنسیم – 波斯语" lang="fa" hreflang="fa" data-title="هگزافلورید تکنسیم" data-language-autonym="فارسی" data-language-local-name="波斯语" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fi mw-list-item"><a href="https://fi.wikipedia.org/wiki/Teknetiumheksafluoridi" title="Teknetiumheksafluoridi – 芬兰语" lang="fi" hreflang="fi" data-title="Teknetiumheksafluoridi" data-language-autonym="Suomi" data-language-local-name="芬兰语" class="interlanguage-link-target"><span>Suomi</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/Hexafluorure_de_techn%C3%A9tium" title="Hexafluorure de technétium – 法语" lang="fr" hreflang="fr" data-title="Hexafluorure de technétium" data-language-autonym="Français" data-language-local-name="法语" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E5%85%AD%E3%83%95%E3%83%83%E5%8C%96%E3%83%86%E3%82%AF%E3%83%8D%E3%83%81%E3%82%A6%E3%83%A0" title="六フッ化テクネチウム – 日语" lang="ja" hreflang="ja" data-title="六フッ化テクネチウム" data-language-autonym="日本語" data-language-local-name="日语" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-nl mw-list-item"><a href="https://nl.wikipedia.org/wiki/Technetium(VI)fluoride" title="Technetium(VI)fluoride – 荷兰语" lang="nl" hreflang="nl" data-title="Technetium(VI)fluoride" data-language-autonym="Nederlands" data-language-local-name="荷兰语" class="interlanguage-link-target"><span>Nederlands</span></a></li><li class="interlanguage-link interwiki-pt mw-list-item"><a href="https://pt.wikipedia.org/wiki/Fluoreto_de_tecn%C3%A9cio(VI)" title="Fluoreto de tecnécio(VI) – 葡萄牙语" lang="pt" hreflang="pt" data-title="Fluoreto de tecnécio(VI)" data-language-autonym="Português" data-language-local-name="葡萄牙语" class="interlanguage-link-target"><span>Português</span></a></li><li class="interlanguage-link interwiki-ru mw-list-item"><a href="https://ru.wikipedia.org/wiki/%D0%A4%D1%82%D0%BE%D1%80%D0%B8%D0%B4_%D1%82%D0%B5%D1%85%D0%BD%D0%B5%D1%86%D0%B8%D1%8F(VI)" title="Фторид технеция(VI) – 俄语" lang="ru" hreflang="ru" data-title="Фторид технеция(VI)" data-language-autonym="Русский" data-language-local-name="俄语" class="interlanguage-link-target"><span>Русский</span></a></li><li class="interlanguage-link interwiki-vi mw-list-item"><a href="https://vi.wikipedia.org/wiki/Techneti(VI)_fluoride" title="Techneti(VI) fluoride – 越南语" lang="vi" hreflang="vi" data-title="Techneti(VI) fluoride" data-language-autonym="Tiếng Việt" data-language-local-name="越南语" class="interlanguage-link-target"><span>Tiếng Việt</span></a></li> </ul> <div class="after-portlet after-portlet-lang"><span class="wb-langlinks-edit wb-langlinks-link"><a href="https://www.wikidata.org/wiki/Special:EntityPage/Q416177#sitelinks-wikipedia" title="编辑跨语言链接" class="wbc-editpage">编辑链接</a></span></div> </div> </div> </div> </header> <div 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data-noteta-code="zh-hans:六氟化锝;zh-hk:六氟化鍀;zh-tw:六氟化鎝;"></div><div class="noteTA-local"><div data-noteta-code="zh-hans:锝;zh-hk:鍀;zh-tw:鎝;"></div></div></div> <style data-mw-deduplicate="TemplateStyles:r84001320">.mw-parser-output .ib-chembox{border-collapse:collapse;text-align:left}.mw-parser-output .ib-chembox td,.mw-parser-output .ib-chembox th{border:1px solid #a2a9b1;width:40%}.mw-parser-output .ib-chembox td+td{width:60%}</style> <table class="infobox ib-chembox nounderlines" cellspacing="0" cellpadding="3" rules="all" style="background-color:#f0f0f0; float:right; margin: 0 0 1em 1em; border-color: #aaaaaa; border-style:solid; border:1px; border-collapse:collapse; empty-cells:show; width:305px; font-size:90%;"> <tbody><tr> <th colspan="2" style="font-size:120%; text-align:center; background:#d6e0dc;">六氟化鎝 </th></tr> <tr> <td colspan="2" style="background:#ffffff; text-align:center;"><span typeof="mw:File"><a href="/wiki/File:Technetium-hexafluoride-2D.png" class="mw-file-description"><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/a/aa/Technetium-hexafluoride-2D.png/120px-Technetium-hexafluoride-2D.png" decoding="async" width="120" height="128" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/a/aa/Technetium-hexafluoride-2D.png/180px-Technetium-hexafluoride-2D.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/a/aa/Technetium-hexafluoride-2D.png/240px-Technetium-hexafluoride-2D.png 2x" data-file-width="1031" data-file-height="1100" /></a></span> </td></tr> <tr> <td colspan="2" style="max-width:305px; word-wrap: break-word; text-align: center;"><a href="/wiki/IUPAC%E5%91%BD%E5%90%8D%E6%B3%95" title="IUPAC命名法">IUPAC名</a><br />Technetium(VI) fluoride </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">识别 </th></tr> <tr> <td><a href="/wiki/CAS%E5%8F%B7" title="CAS号">CAS号</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=13842-93-8">13842-93-8</a></span> <sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup> </td></tr> <tr> <td><a href="/wiki/PubChem" title="PubChem">PubChem</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="https://pubchem.ncbi.nlm.nih.gov/compound/57470148">57470148</a></span> </td></tr> <tr> <td><a href="/wiki/SMILES" class="mw-redirect" title="SMILES">SMILES</a> </td> <td><div style="word-break:break-all;"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold;"><div> </div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0;"><li style="line-height: inherit; margin: 0"><span lang="en">F[Tc](F)(F)(F)(F)F</span></li></ul> </div></div> </td></tr> <tr> <td><a href="/wiki/%E5%9B%BD%E9%99%85%E5%8C%96%E5%90%88%E7%89%A9%E6%A0%87%E8%AF%86" title="国际化合物标识">InChIKey</a> </td> <td><small>PRVOBRCYHYXCMU-UHFFFAOYSA-H</small> </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">性质 </th></tr> <tr> <td><a href="/wiki/%E5%8C%96%E5%AD%A6%E5%BC%8F" title="化学式">化学式</a> </td> <td><span lang="en">TcF<sub>6</sub></span> </td></tr> <tr> <td><a href="/wiki/%E6%91%A9%E5%B0%94%E8%B4%A8%E9%87%8F" title="摩尔质量">摩尔质量</a> </td> <td>212 g/mol (<sup>98</sup>Tc) g·mol⁻¹ </td></tr> <tr> <td>外观 </td> <td>金黃色晶體<sup id="cite_ref-CRC_HANDBOOK_TcF6_1-0" class="reference"><a href="#cite_note-CRC_HANDBOOK_TcF6-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td><a href="/wiki/%E5%AF%86%E5%BA%A6" title="密度">密度</a> </td> <td>3.58 g/cm<sup>3</sup> (−140 °C、固態)<sup id="cite_ref-D_BLOCK_XF6_2-0" class="reference"><a href="#cite_note-D_BLOCK_XF6-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> </td></tr> <tr> <td><a href="/wiki/%E7%86%94%E7%82%B9" title="熔点">熔点</a> </td> <td>37.4 °C（311 K） </td></tr> <tr> <td><a href="/wiki/%E6%B2%B8%E7%82%B9" title="沸点">沸点</a> </td> <td>55.3 °C（328 K） </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">结构 </th></tr> <tr> <td><a href="/wiki/%E6%99%B6%E4%BD%93%E7%BB%93%E6%9E%84" title="晶体结构">晶体结构</a> </td> <td><a href="/wiki/%E7%AB%8B%E6%96%B9%E6%99%B6%E7%B3%BB" title="立方晶系">立方晶系</a> </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">危险性 </th></tr> <tr> <td><a href="/wiki/%E5%8D%B1%E9%99%A9%E7%89%A9%E8%B4%A8%E7%9A%84%E5%88%86%E7%B1%BB%E3%80%81%E5%8C%85%E8%A3%85%E3%80%81%E6%A0%87%E7%A4%BA%E6%8C%87%E4%BB%A4" class="mw-redirect" title="危险物质的分类、包装、标示指令">欧盟分类</a> </td> <td>不在名單中 </td></tr> <tr> <td style="background:#D6E0DC; text-align:center;" colspan="2">若非注明，所有数据均出自<a href="/wiki/%E6%A0%87%E5%87%86%E7%8A%B6%E6%80%81" title="标准状态">标准状态（25 ℃，100 kPa）</a>下。 </td></tr></tbody></table> <p><b>六氟化鎝</b>是一個低熔點的金黃色<a href="/wiki/%E7%84%A1%E6%A9%9F%E5%8C%96%E5%90%88%E7%89%A9" class="mw-redirect" title="無機化合物">無機化合物</a><sup id="cite_ref-CRC_HANDBOOK_TcF6_1-1" class="reference"><a href="#cite_note-CRC_HANDBOOK_TcF6-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>，其<a href="/wiki/%E5%8C%96%E5%AD%B8%E5%BC%8F" class="mw-redirect" title="化學式">化學式</a>為TcF<sub>6</sub>，發現於1961年<sup id="cite_ref-selig1_3-0" class="reference"><a href="#cite_note-selig1-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup>。在這化合物中，鎝有+6價，是目前發現的<a href="/wiki/%E9%8E%9D" class="mw-redirect" title="鎝">鎝</a>化合物中，<a href="/wiki/%E6%B0%A7%E5%8C%96%E5%83%B9" class="mw-redirect" title="氧化價">氧化價</a>最高的2個鹵化物之一，另一個是六氯化鎝（Technetium(VI) chloride, TcCl<sub>6</sub>）。其中，這裡的鎝與形成<a href="/wiki/%E4%B8%83%E6%B0%9F%E5%8C%96%E9%93%BC" title="七氟化铼">七氟化錸</a>（ReF<sub>7</sub>）的錸不同<sup id="cite_ref-4" class="reference"><a href="#cite_note-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup>。六氟化鎝會出現在<a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E9%88%BE" title="六氟化鈾">六氟化鈾</a>的雜質中，因為鎝是鈾的裂變產物。 </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="製備"><span id=".E8.A3.BD.E5.82.99"></span>製備</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%85%AD%E6%B0%9F%E5%8C%96%E9%8E%9D&action=edit&section=1" title="编辑章节：製備"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>製備六氟化鎝的方式是將<a href="/wiki/%E9%8E%9D" class="mw-redirect" title="鎝">鎝金屬</a>和過量的氟氣（F<sub>2</sub>）加熱到攝氏400度。<sup id="cite_ref-selig1_3-1" class="reference"><a href="#cite_note-selig1-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> </p> <dl><dd>Tc + 3 <span class="chemf nowrap">F<span style="line-height:1.2em;text-indent:0em;display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;font-size:70%;text-align:left"><br />2</span></span> → <span class="chemf nowrap">TcF<span style="line-height:1.2em;text-indent:0em;display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;font-size:70%;text-align:left"><br />6</span></span></dd></dl> <div class="mw-heading mw-heading2"><h2 id="特徵"><span id=".E7.89.B9.E5.BE.B5"></span>特徵</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%85%AD%E6%B0%9F%E5%8C%96%E9%8E%9D&action=edit&section=2" title="编辑章节：特徵"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>六氟化鎝在<a href="/wiki/%E5%AE%A4%E6%BA%AB" class="mw-redirect" title="室溫">室溫</a>下為金黃色固體。其熔點较低，約為37.4℃<sup id="cite_ref-CRC_HANDBOOK_TcF6_1-2" class="reference"><a href="#cite_note-CRC_HANDBOOK_TcF6-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>，當環境溫度高於38℃就會熔化，沸點為55.3℃<sup id="cite_ref-CRC_HANDBOOK_TcF6_1-3" class="reference"><a href="#cite_note-CRC_HANDBOOK_TcF6-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup>，其在標準狀態下液相的範圍不大，僅有17.9℃。 </p><p>六氟化鎝在−4.54 °C會發生一次相變，高於該溫度時，晶體結構為立方晶系，其晶格常數 <i>a</i> 為 6.16 Å<sup id="cite_ref-5" class="reference"><a href="#cite_note-5"><span class="cite-bracket">[</span>註 1<span class="cite-bracket">]</span></a></sup>。每<a href="/wiki/%E5%96%AE%E4%BD%8D%E6%99%B6%E6%A0%BC" class="mw-redirect" title="單位晶格">單位晶格</a>有兩個<span class="ilh-all" data-orig-title="化学式单位" data-lang-code="en" data-lang-name="英语" data-foreign-title="Formula unit"><span class="ilh-page"><a href="/w/index.php?title=%E5%8C%96%E5%AD%A6%E5%BC%8F%E5%8D%95%E4%BD%8D&action=edit&redlink=1" class="new" title="化学式单位（页面不存在）">化学式单位</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">英语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://en.wikipedia.org/wiki/Formula_unit" class="extiw" title="en:Formula unit"><span lang="en" dir="auto">Formula unit</span></a></span>）</span></span><sup id="cite_ref-in_this_case,_discrete_molecules_6-0" class="reference"><a href="#cite_note-in_this_case,_discrete_molecules-6"><span class="cite-bracket">[</span>註 2<span class="cite-bracket">]</span></a></sup>，其密度為3.02 g·cm<sup>−3</sup>；而低於該溫度時，晶體結構為正交晶系，其晶格常數<i>a</i> 為 9.55 <a href="/wiki/%E5%9F%83" class="mw-redirect" title="埃">Å</a>、<i>b</i> 為 8.74 Å,、<i>c</i> 為 5.02 Å<sup id="cite_ref-7" class="reference"><a href="#cite_note-7"><span class="cite-bracket">[</span>註 3<span class="cite-bracket">]</span></a></sup>。每<a href="/wiki/%E5%96%AE%E4%BD%8D%E6%99%B6%E6%A0%BC" class="mw-redirect" title="單位晶格">單位晶格</a>有四個<span class="ilh-all" data-orig-title="化学式单位" data-lang-code="en" data-lang-name="英语" data-foreign-title="Formula unit"><span class="ilh-page"><a href="/w/index.php?title=%E5%8C%96%E5%AD%A6%E5%BC%8F%E5%8D%95%E4%BD%8D&action=edit&redlink=1" class="new" title="化学式单位（页面不存在）">化学式单位</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">英语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://en.wikipedia.org/wiki/Formula_unit" class="extiw" title="en:Formula unit"><span lang="en" dir="auto">Formula unit</span></a></span>）</span></span><sup id="cite_ref-in_this_case,_discrete_molecules_6-1" class="reference"><a href="#cite_note-in_this_case,_discrete_molecules-6"><span class="cite-bracket">[</span>註 2<span class="cite-bracket">]</span></a></sup>，其密度為3.38 g·cm<sup>−3</sup>。而當溫度降到了攝氏−140℃時，晶格雖然保持為正交晶系，但晶格常數改變了，<i>a</i> 變為 9.360 <a href="/wiki/%E5%9F%83" class="mw-redirect" title="埃">Å</a>、<i>b</i> 變為 8.517 Å而<i>c</i> 則變為 4.934 Å，密度也改變了，變為3.58 g·cm<sup>−3</sup>。<sup id="cite_ref-D_BLOCK_XF6_2-1" class="reference"><a href="#cite_note-D_BLOCK_XF6-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> </p><p>而TcF<sub>6</sub>的分子本身<sup id="cite_ref-8" class="reference"><a href="#cite_note-8"><span class="cite-bracket">[</span>註 4<span class="cite-bracket">]</span></a></sup>的分子結構為<a href="/wiki/%E5%85%AB%E9%9D%A2%E4%BD%93%E5%BD%A2%E5%88%86%E5%AD%90%E6%9E%84%E5%9E%8B" title="八面体形分子构型">八面体形分子构型</a>，點群為八面體對稱（<span class="ilh-all" data-orig-title="八面體對稱性" data-lang-code="en" data-lang-name="英语" data-foreign-title="octahedral symmetry"><span class="ilh-page"><a href="/w/index.php?title=%E5%85%AB%E9%9D%A2%E9%AB%94%E5%B0%8D%E7%A8%B1%E6%80%A7&action=edit&redlink=1" class="new" title="八面體對稱性（页面不存在）">O<sub>h</sub></a></span><span class="noprint ilh-comment">（<span class="ilh-lang">英语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://en.wikipedia.org/wiki/octahedral_symmetry" class="extiw" title="en:octahedral symmetry"><span lang="en" dir="auto">octahedral symmetry</span></a></span>）</span></span>）、Tc-F鍵的鍵長為1.812Å<sup id="cite_ref-D_BLOCK_XF6_2-2" class="reference"><a href="#cite_note-D_BLOCK_XF6-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup>、其磁矩測量值為0.45 <a href="/wiki/%E7%8E%BB%E5%B0%94%E7%A3%81%E5%AD%90" title="玻尔磁子"><i>μ</i><sub>B</sub></a><sup id="cite_ref-9" class="reference"><a href="#cite_note-9"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup>。 </p> <div class="mw-heading mw-heading2"><h2 id="性質"><span id=".E6.80.A7.E8.B3.AA"></span>性質</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%85%AD%E6%B0%9F%E5%8C%96%E9%8E%9D&action=edit&section=3" title="编辑章节：性質"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>由於鎝沒有穩定的同位素，因此六氟化鎝具有放射性，常溫下為黃色固體。 </p> <div class="mw-heading mw-heading3"><h3 id="物理"><span id=".E7.89.A9.E7.90.86"></span>物理</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%85%AD%E6%B0%9F%E5%8C%96%E9%8E%9D&action=edit&section=4" title="编辑章节：物理"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>六氟化鎝在<a href="/wiki/%E7%BA%A2%E5%A4%96%E5%85%89%E8%B0%B1%E5%AD%A6" title="红外光谱学">红外光谱学</a>和<a href="/wiki/%E6%8B%89%E6%9B%BC%E5%85%89%E8%AD%9C%E5%AD%B8" title="拉曼光譜學">拉曼光譜學</a>的測定下呈現<a href="/wiki/%E5%85%AB%E9%9D%A2%E4%BD%93%E5%BD%A2%E5%88%86%E5%AD%90%E6%9E%84%E5%9E%8B" title="八面体形分子构型">八面体形分子构型</a><sup id="cite_ref-10" class="reference"><a href="#cite_note-10"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-11" class="reference"><a href="#cite_note-11"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup>。在低溫下，六氟化鎝和其他金屬的六氟化物（如六氟化銠、六氟化鋨）一樣，會從室溫的高對稱性立方晶系結構轉換成正交晶系結構<sup id="cite_ref-12" class="reference"><a href="#cite_note-12"><span class="cite-bracket">[</span>8<span class="cite-bracket">]</span></a></sup>。其磁矩初步測量的數值約為0.45<a href="/wiki/%E7%8E%BB%E5%B0%94%E7%A3%81%E5%AD%90" title="玻尔磁子"><i>μ</i><sub>B</sub></a>，比預期的d<sup>1</sup>八面體化合物來得低<sup id="cite_ref-13" class="reference"><a href="#cite_note-13"><span class="cite-bracket">[</span>9<span class="cite-bracket">]</span></a></sup>。 </p> <div class="mw-heading mw-heading3"><h3 id="化學"><span id=".E5.8C.96.E5.AD.B8"></span>化學</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%85%AD%E6%B0%9F%E5%8C%96%E9%8E%9D&action=edit&section=5" title="编辑章节：化學"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>六氟化鎝在五氟化碘（IF<sub>5</sub>）溶液中能與鹼性的氯反應形成六氟化物 <sup id="cite_ref-14" class="reference"><a href="#cite_note-14"><span class="cite-bracket">[</span>10<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-15" class="reference"><a href="#cite_note-15"><span class="cite-bracket">[</span>11<span class="cite-bracket">]</span></a></sup>。六氟化鎝會在氫氧化鈉的水溶液（NaOH<sub>(aq)</sub>）中水解，並形成黑色的二氧化鎝（TcO<sub>2</sub>）沉澱<sup id="cite_ref-selig1_3-2" class="reference"><a href="#cite_note-selig1-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> 。在氟化氫（HF）溶液中，六氟化鎝會與氟化肼（hydrazinium fluoride、N<sub>2</sub>H<sub>5</sub>F）反應，得到N<sub>2</sub>H<sub>6</sub>TcF<sub>6</sub>或N<sub>2</sub>H<sub>6</sub>(TcF<sub>6</sub>)<sub>2</sub><sup id="cite_ref-16" class="reference"><a href="#cite_note-16"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup>。 </p> <div class="mw-heading mw-heading2"><h2 id="註解"><span id=".E8.A8.BB.E8.A7.A3"></span>註解</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%85%AD%E6%B0%9F%E5%8C%96%E9%8E%9D&action=edit&section=6" title="编辑章节：註解"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <style data-mw-deduplicate="TemplateStyles:r80540462">.mw-parser-output .refbegin{font-size:90%;margin-bottom:0.5em}.mw-parser-output .refbegin-hanging-indents>ul{margin-left:0}.mw-parser-output .refbegin-hanging-indents>ul>li{margin-left:0;padding-left:3.2em;text-indent:-3.2em}.mw-parser-output .refbegin-hanging-indents ul,.mw-parser-output .refbegin-hanging-indents ul li{list-style:none}@media(max-width:720px){.mw-parser-output .refbegin-hanging-indents>ul>li{padding-left:1.6em;text-indent:-1.6em}}.mw-parser-output .refbegin-columns{margin-top:0.3em}.mw-parser-output .refbegin-columns ul{margin-top:0}.mw-parser-output .refbegin-columns li{page-break-inside:avoid;break-inside:avoid-column}.mw-parser-output .refbegin-100{font-size:100%}</style><div class="refbegin" style=""> <div class="reflist" style="list-style-type: decimal;"> <ol class="references"> <li id="cite_note-5"><span class="mw-cite-backlink"><b><a href="#cite_ref-5">^</a></b></span> <span class="reference-text">於攝氏10度測量</span> </li> <li id="cite_note-in_this_case,_discrete_molecules-6"><span class="mw-cite-backlink">^ <a href="#cite_ref-in_this_case,_discrete_molecules_6-0"><sup><b>2.0</b></sup></a> <a href="#cite_ref-in_this_case,_discrete_molecules_6-1"><sup><b>2.1</b></sup></a></span> <span class="reference-text">在這種情況下是離散分子</span> </li> <li id="cite_note-7"><span class="mw-cite-backlink"><b><a href="#cite_ref-7">^</a></b></span> <span class="reference-text">於攝氏-19度測量</span> </li> <li id="cite_note-8"><span class="mw-cite-backlink"><b><a href="#cite_ref-8">^</a></b></span> <span class="reference-text">這種形式（單一分子）對於液相或氣相重要</span> </li> </ol></div> </div> <div class="mw-heading mw-heading2"><h2 id="參考文獻"><span id=".E5.8F.83.E8.80.83.E6.96.87.E7.8D.BB"></span>參考文獻</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%85%AD%E6%B0%9F%E5%8C%96%E9%8E%9D&action=edit&section=7" title="编辑章节：參考文獻"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="reflist" style="list-style-type: decimal;"> <ol class="references"> <li id="cite_note-CRC_HANDBOOK_TcF6-1"><span class="mw-cite-backlink">^ <a href="#cite_ref-CRC_HANDBOOK_TcF6_1-0"><sup><b>1.0</b></sup></a> <a href="#cite_ref-CRC_HANDBOOK_TcF6_1-1"><sup><b>1.1</b></sup></a> <a href="#cite_ref-CRC_HANDBOOK_TcF6_1-2"><sup><b>1.2</b></sup></a> <a href="#cite_ref-CRC_HANDBOOK_TcF6_1-3"><sup><b>1.3</b></sup></a></span> <span class="reference-text"><i><a href="/wiki/CRC_Handbook_of_Chemistry_and_Physics" class="mw-redirect" title="CRC Handbook of Chemistry and Physics">CRC Handbook of Chemistry and Physics</a></i>, 90th Edition, CRC Press, Boca Raton, Florida, 2009, <style data-mw-deduplicate="TemplateStyles:r61200749">.mw-parser-output cite.citation{font-style:inherit}.mw-parser-output .citation q{quotes:"\"""\"""'""'"}.mw-parser-output .citation .cs1-lock-free a{background:url("//upload.wikimedia.org/wikipedia/commons/thumb/6/65/Lock-green.svg/9px-Lock-green.svg.png")no-repeat;background-position:right .1em center}.mw-parser-output .citation .cs1-lock-limited a,.mw-parser-output .citation .cs1-lock-registration a{background:url("//upload.wikimedia.org/wikipedia/commons/thumb/d/d6/Lock-gray-alt-2.svg/9px-Lock-gray-alt-2.svg.png")no-repeat;background-position:right .1em center}.mw-parser-output .citation .cs1-lock-subscription a{background:url("//upload.wikimedia.org/wikipedia/commons/thumb/a/aa/Lock-red-alt-2.svg/9px-Lock-red-alt-2.svg.png")no-repeat;background-position:right .1em center}.mw-parser-output .cs1-subscription,.mw-parser-output .cs1-registration{color:#555}.mw-parser-output .cs1-subscription span,.mw-parser-output .cs1-registration span{border-bottom:1px dotted;cursor:help}.mw-parser-output .cs1-ws-icon a{background:url("//upload.wikimedia.org/wikipedia/commons/thumb/4/4c/Wikisource-logo.svg/12px-Wikisource-logo.svg.png")no-repeat;background-position:right .1em center}.mw-parser-output code.cs1-code{color:inherit;background:inherit;border:inherit;padding:inherit}.mw-parser-output .cs1-hidden-error{display:none;font-size:100%}.mw-parser-output .cs1-visible-error{font-size:100%}.mw-parser-output .cs1-maint{display:none;color:#33aa33;margin-left:0.3em}.mw-parser-output .cs1-subscription,.mw-parser-output .cs1-registration,.mw-parser-output .cs1-format{font-size:95%}.mw-parser-output .cs1-kern-left,.mw-parser-output .cs1-kern-wl-left{padding-left:0.2em}.mw-parser-output .cs1-kern-right,.mw-parser-output .cs1-kern-wl-right{padding-right:0.2em}</style><a href="/wiki/%E5%9B%BD%E9%99%85%E6%A0%87%E5%87%86%E4%B9%A6%E5%8F%B7" title="国际标准书号">ISBN</a> <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/978-1-4200-9084-0" title="Special:网络书源/978-1-4200-9084-0">978-1-4200-9084-0</a>, Section 4, <i>Physical Constants of Inorganic Compounds</i>, p. 4-93.</span> </li> <li id="cite_note-D_BLOCK_XF6-2"><span class="mw-cite-backlink">^ <a href="#cite_ref-D_BLOCK_XF6_2-0"><sup><b>2.0</b></sup></a> <a href="#cite_ref-D_BLOCK_XF6_2-1"><sup><b>2.1</b></sup></a> <a href="#cite_ref-D_BLOCK_XF6_2-2"><sup><b>2.2</b></sup></a></span> <span class="reference-text"><cite class="citation journal">Drews, T.; Supeł, J.; Hagenbach, A.; Seppelt, K. Solid State Molecular Structures of Transition Metal Hexafluorides. <a href="/wiki/Inorganic_Chemistry_(journal)" class="mw-redirect" title="Inorganic Chemistry (journal)">Inorganic Chemistry</a>. 2006, <b>45</b> (9): 3782–3788. <a rel="nofollow" class="external text" href="//www.ncbi.nlm.nih.gov/pubmed/16634614"><span title="公共医学识别码">PMID 16634614</span></a>. <a rel="nofollow" class="external text" href="https://doi.org/10.1021%2Fic052029f"><span title="數位物件識別號">doi:10.1021/ic052029f</span></a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E5%85%AD%E6%B0%9F%E5%8C%96%E9%8E%9D&rft.atitle=Solid+State+Molecular+Structures+of+Transition+Metal+Hexafluorides&rft.au=Hagenbach%2C+A.&rft.au=Seppelt%2C+K.&rft.au=Supe%C5%82%2C+J.&rft.aufirst=T.&rft.aulast=Drews&rft.date=2006&rft.genre=article&rft.issue=9&rft.jtitle=Inorganic+Chemistry&rft.pages=3782-3788&rft.volume=45&rft_id=info%3Adoi%2F10.1021%2Fic052029f&rft_id=info%3Apmid%2F16634614&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-selig1-3"><span class="mw-cite-backlink">^ <a href="#cite_ref-selig1_3-0"><sup><b>3.0</b></sup></a> <a href="#cite_ref-selig1_3-1"><sup><b>3.1</b></sup></a> <a href="#cite_ref-selig1_3-2"><sup><b>3.2</b></sup></a></span> <span class="reference-text"><cite class="citation journal">Selig, H.; Chernick, C.L.; Malm, J.G. The Preparation and Properties of TcF<sub>6</sub>. Journal of Inorganic and Nuclear Chemistry. 1961, <b>19</b> (3–4): 377–381.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E5%85%AD%E6%B0%9F%E5%8C%96%E9%8E%9D&rft.atitle=The+Preparation+and+Properties+of+TcF%3Csub%3E6%3C%2Fsub%3E&rft.au=Chernick%2C+C.L.&rft.au=Malm%2C+J.G.&rft.au=Selig%2C+H.&rft.date=1961&rft.genre=article&rft.issue=3%E2%80%934&rft.jtitle=Journal+of+Inorganic+and+Nuclear+Chemistry&rft.pages=377-381&rft.volume=19&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-4"><span class="mw-cite-backlink"><b><a href="#cite_ref-4">^</a></b></span> <span class="reference-text"><cite class="citation book">Greenwood, N. N.; Earnshaw, A. <span></span><i>Chemistry of the Elements</i><span></span> 2nd. Oxford:Butterworth-Heinemann. 1997. <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/0-7506-3365-4" title="Special:网络书源/0-7506-3365-4"><span title="国际标准书号">ISBN</span> 0-7506-3365-4</a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E5%85%AD%E6%B0%9F%E5%8C%96%E9%8E%9D&rft.au=Earnshaw%2C+A.&rft.au=Greenwood%2C+N.+N.&rft.btitle=Chemistry+of+the+Elements&rft.date=1997&rft.edition=2nd&rft.genre=book&rft.isbn=0-7506-3365-4&rft.pub=Oxford%3AButterworth-Heinemann&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-9"><span class="mw-cite-backlink"><b><a href="#cite_ref-9">^</a></b></span> <span class="reference-text"><cite class="citation journal">Selig, H.; Cafasso, F. A.; <a href="/w/index.php?title=Dieter_M._Gruen&action=edit&redlink=1" class="new" title="Dieter M. Gruen（页面不存在）">Gruen, D. M.</a>; Malm, J. G. Magnetic Susceptibility of ReF<sub>6</sub>. <a href="/wiki/Journal_of_Chemical_Physics" class="mw-redirect" title="Journal of Chemical Physics">Journal of Chemical Physics</a>. 1962, <b>36</b> (12): 3440. <a rel="nofollow" class="external text" href="https://ui.adsabs.harvard.edu/abs/1962JChPh..36.3440S"><span title="Bibcode">Bibcode:1962JChPh..36.3440S</span></a>. <a rel="nofollow" class="external text" href="https://doi.org/10.1063%2F1.1732477"><span title="數位物件識別號">doi:10.1063/1.1732477</span></a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E5%85%AD%E6%B0%9F%E5%8C%96%E9%8E%9D&rft.atitle=Magnetic+Susceptibility+of+ReF%3Csub%3E6%3C%2Fsub%3E&rft.au=Cafasso%2C+F.+A.&rft.au=Gruen%2C+D.+M.&rft.au=Malm%2C+J.+G.&rft.aufirst=H.&rft.aulast=Selig&rft.date=1962&rft.genre=article&rft.issue=12&rft.jtitle=Journal+of+Chemical+Physics&rft.pages=3440&rft.volume=36&rft_id=info%3Abibcode%2F1962JChPh..36.3440S&rft_id=info%3Adoi%2F10.1063%2F1.1732477&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-10"><span class="mw-cite-backlink"><b><a href="#cite_ref-10">^</a></b></span> <span class="reference-text"><cite class="citation journal">Howard H. 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Journal of Chemical Physics. 1962, <b>36</b> (11): 2888–2890. <a rel="nofollow" class="external text" href="https://ui.adsabs.harvard.edu/abs/1962JChPh..36.2888C"><span title="Bibcode">Bibcode:1962JChPh..36.2888C</span></a>. <a rel="nofollow" class="external text" href="https://doi.org/10.1063%2F1.1732396"><span title="數位物件識別號">doi:10.1063/1.1732396</span></a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E5%85%AD%E6%B0%9F%E5%8C%96%E9%8E%9D&rft.atitle=Vibrational+Spectra+of+MoF%3Csub%3E6%3C%2Fsub%3E+and+TcF%3Csub%3E6%3C%2Fsub%3E&rft.au=Henry+Selig&rft.au=Howard+H.+Claassen&rft.au=John+G.+Malm&rft.date=1962&rft.genre=article&rft.issue=11&rft.jtitle=Journal+of+Chemical+Physics&rft.pages=2888-2890&rft.volume=36&rft_id=info%3Abibcode%2F1962JChPh..36.2888C&rft_id=info%3Adoi%2F10.1063%2F1.1732396&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-11"><span class="mw-cite-backlink"><b><a href="#cite_ref-11">^</a></b></span> <span class="reference-text"><cite class="citation journal">Howard H. Claassen; Gordon L. Goodman; John H. Holloway & Henry Selig. Raman Spectra of MoF<sub>6</sub>, TcF<sub>6</sub>, ReF<sub>6</sub>, UF<sub>6</sub>, SF<sub>6</sub>, SeF<sub>6</sub>, and TeF<sub>6</sub> in the Vapor State. Journal of Chemical Physics. 1970, <b>53</b> (1): 341–348. <a rel="nofollow" class="external text" href="https://ui.adsabs.harvard.edu/abs/1970JChPh..53..341C"><span title="Bibcode">Bibcode:1970JChPh..53..341C</span></a>. <a rel="nofollow" class="external text" href="https://doi.org/10.1063%2F1.1673786"><span title="數位物件識別號">doi:10.1063/1.1673786</span></a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E5%85%AD%E6%B0%9F%E5%8C%96%E9%8E%9D&rft.atitle=Raman+Spectra+of+MoF%3Csub%3E6%3C%2Fsub%3E%2C+TcF%3Csub%3E6%3C%2Fsub%3E%2C+ReF%3Csub%3E6%3C%2Fsub%3E%2C+UF%3Csub%3E6%3C%2Fsub%3E%2C+SF%3Csub%3E6%3C%2Fsub%3E%2C+SeF%3Csub%3E6%3C%2Fsub%3E%2C+and+TeF%3Csub%3E6%3C%2Fsub%3E+in+the+Vapor+State&rft.au=Gordon+L.+Goodman&rft.au=Henry+Selig&rft.au=Howard+H.+Claassen&rft.au=John+H.+Holloway&rft.date=1970&rft.genre=article&rft.issue=1&rft.jtitle=Journal+of+Chemical+Physics&rft.pages=341-348&rft.volume=53&rft_id=info%3Abibcode%2F1970JChPh..53..341C&rft_id=info%3Adoi%2F10.1063%2F1.1673786&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-12"><span class="mw-cite-backlink"><b><a href="#cite_ref-12">^</a></b></span> <span class="reference-text"><cite class="citation journal">Siegel S & Northrop DA. X-Ray Diffraction Studies of Some Transition Metal Hexafluorides. Inorganic Chemistry. 1966, <b>5</b> (12): 2187–2188. <a rel="nofollow" class="external text" href="https://doi.org/10.1021%2Fic50046a025"><span title="數位物件識別號">doi:10.1021/ic50046a025</span></a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E5%85%AD%E6%B0%9F%E5%8C%96%E9%8E%9D&rft.atitle=X-Ray+Diffraction+Studies+of+Some+Transition+Metal+Hexafluorides&rft.au=Northrop%2C+DA&rft.aufirst=S&rft.aulast=Siegel&rft.date=1966&rft.genre=article&rft.issue=12&rft.jtitle=Inorganic+Chemistry&rft.pages=2187-2188&rft.volume=5&rft_id=info%3Adoi%2F10.1021%2Fic50046a025&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-13"><span class="mw-cite-backlink"><b><a href="#cite_ref-13">^</a></b></span> <span class="reference-text"><cite class="citation journal">Selig, H; Cafasso, F A.; Gruen, D M.; Malm, J G. 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Journal of Chemical Physics. 1962, <b>36</b> (12): 3440–3444. <a rel="nofollow" class="external text" href="https://ui.adsabs.harvard.edu/abs/1962JChPh..36.3440S"><span title="Bibcode">Bibcode:1962JChPh..36.3440S</span></a>. <a rel="nofollow" class="external text" href="https://doi.org/10.1063%2F1.1732477"><span title="數位物件識別號">doi:10.1063/1.1732477</span></a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E5%85%AD%E6%B0%9F%E5%8C%96%E9%8E%9D&rft.atitle=Magnetic+Susceptibility+of+ReF%3Csub%3E6%3C%2Fsub%3E&rft.au=Cafasso%2C+F+A.&rft.au=Gruen%2C+D+M.&rft.au=Malm%2C+J+G.&rft.au=Selig%2C+H&rft.date=1962&rft.genre=article&rft.issue=12&rft.jtitle=Journal+of+Chemical+Physics&rft.pages=3440-3444&rft.volume=36&rft_id=info%3Abibcode%2F1962JChPh..36.3440S&rft_id=info%3Adoi%2F10.1063%2F1.1732477&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-14"><span class="mw-cite-backlink"><b><a href="#cite_ref-14">^</a></b></span> <span class="reference-text"><cite class="citation journal">Edwards, A. 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Inorganic Chemistry. 1967, <b>6</b> (10): 1775–1783. <a rel="nofollow" class="external text" href="https://doi.org/10.1021%2Fic50056a004"><span title="數位物件識別號">doi:10.1021/ic50056a004</span></a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E5%85%AD%E6%B0%9F%E5%8C%96%E9%8E%9D&rft.atitle=Hydrazinium%28%2B2%29+Hexafluorometalates%28IV%29+and+-%28V%29+in+the+4d+and+5d+Transition+Series&rft.au=Frlec+B&rft.au=Hyman+H.H&rft.au=Selig+H&rft.date=1967&rft.genre=article&rft.issue=10&rft.jtitle=Inorganic+Chemistry&rft.pages=1775-1783&rft.volume=6&rft_id=info%3Adoi%2F10.1021%2Fic50056a004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> </ol></div> <div class="navbox-styles"><style data-mw-deduplicate="TemplateStyles:r84265675">.mw-parser-output .hlist dl,.mw-parser-output .hlist ol,.mw-parser-output .hlist ul{margin:0;padding:0}.mw-parser-output .hlist dd,.mw-parser-output .hlist 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ul{display:inline-block;white-space:nowrap;line-height:inherit}.mw-parser-output .navbar-brackets::before{margin-right:-0.125em;content:"[ "}.mw-parser-output .navbar-brackets::after{margin-left:-0.125em;content:" ]"}.mw-parser-output .navbar li{word-spacing:-0.125em}.mw-parser-output .navbar a>span,.mw-parser-output .navbar a>abbr{text-decoration:inherit}.mw-parser-output .navbar-mini abbr{font-variant:small-caps;border-bottom:none;text-decoration:none;cursor:inherit}.mw-parser-output .navbar-ct-full{font-size:110%;margin:0 8em}.mw-parser-output .navbar-ct-mini{font-size:110%;margin:0 5em}html.skin-theme-clientpref-night .mw-parser-output .navbar li a abbr{color:var(--color-base)!important}@media(prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .navbar li a abbr{color:var(--color-base)!important}}@media print{.mw-parser-output .navbar{display:none!important}}</style><div class="navbar plainlinks hlist navbar-mini"><ul><li class="nv-view"><a href="/wiki/Template:%E9%94%9D%E5%8C%96%E5%90%88%E7%89%A9" title="Template:锝化合物"><abbr title="查看该模板">查</abbr></a></li><li class="nv-talk"><a href="/wiki/Template_talk:%E9%94%9D%E5%8C%96%E5%90%88%E7%89%A9" title="Template talk:锝化合物"><abbr title="讨论该模板">论</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:%E7%BC%96%E8%BE%91%E9%A1%B5%E9%9D%A2/Template:%E9%94%9D%E5%8C%96%E5%90%88%E7%89%A9" title="Special:编辑页面/Template:锝化合物"><abbr title="编辑该模板">编</abbr></a></li></ul></div><div id="锝化合物" style="font-size:110%;margin:0 5em"><a href="/wiki/%E9%94%9D%E5%8C%96%E5%90%88%E7%89%A9" title="锝化合物">锝化合物</a></div></th></tr><tr><th scope="row" class="navbox-group" style="width:1%">锝(I)</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/w/index.php?title=%E5%85%AD%E6%B0%B0%E5%90%88%E9%94%9D(I)%E9%85%B8%E9%92%BE&action=edit&redlink=1" class="new" title="六氰合锝(I)酸钾（页面不存在）">K<sub>5</sub>[Tc(CN)<sub>6</sub>]</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">锝(III)</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E4%B8%89%E6%BA%B4%E5%8C%96%E9%94%9D" title="三溴化锝">TcBr<sub>3</sub></a></li> <li><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%94%9D" title="三氯化锝">TcCl<sub>3</sub></a></li> <li><a href="/wiki/%E4%BA%8C%E6%B0%AF%E5%8C%96%E5%9B%9B%E4%B9%99%E9%85%B8%E4%BA%8C%E9%94%9D" title="二氯化四乙酸二锝">Tc<sub>2</sub>(OAc)<sub>4</sub>Cl<sub>2</sub></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">锝(IV)</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%8E%9D" title="四氯化鎝">TcCl<sub>4</sub></a></li> <li><a href="/wiki/%E5%9B%9B%E6%BA%B4%E5%8C%96%E9%94%9D" title="四溴化锝">TcBr<sub>4</sub></a></li> <li><a href="/wiki/%E4%BA%8C%E6%B0%A7%E5%8C%96%E9%94%9D" title="二氧化锝">TcO<sub>2</sub></a></li> <li><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%94%9D" title="二硫化锝">TcS<sub>2</sub></a></li> <li><span class="ilh-all" data-orig-title="六氯合锝(IV)酸钾" data-lang-code="ru" data-lang-name="俄语" data-foreign-title="Гексахлоротехнетат калия"><span class="ilh-page"><a href="/w/index.php?title=%E5%85%AD%E6%B0%AF%E5%90%88%E9%94%9D(IV)%E9%85%B8%E9%92%BE&action=edit&redlink=1" class="new" title="六氯合锝(IV)酸钾（页面不存在）">K<sub>2</sub>[TcCl<sub>6</sub>]</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">俄语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://ru.wikipedia.org/wiki/%D0%93%D0%B5%D0%BA%D1%81%D0%B0%D1%85%D0%BB%D0%BE%D1%80%D0%BE%D1%82%D0%B5%D1%85%D0%BD%D0%B5%D1%82%D0%B0%D1%82_%D0%BA%D0%B0%D0%BB%D0%B8%D1%8F" class="extiw" title="ru:Гексахлоротехнетат калия"><span lang="ru" dir="auto">Гексахлоротехнетат калия</span></a></span>）</span></span></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">锝(V)</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E9%8E%9D(V)%E9%85%B8%E9%88%89" title="鎝(V)酸鈉">NaTcO<sub>3</sub></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">锝(VI)</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a class="mw-selflink selflink">TcF<sub>6</sub></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">锝(VII)</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E4%B8%83%E6%B0%A7%E5%8C%96%E4%BA%8C%E9%94%9D" title="七氧化二锝">Tc<sub>2</sub>O<sub>7</sub></a></li> <li><span class="ilh-all" data-orig-title="七硫化二锝" data-lang-code="ru" data-lang-name="俄语" data-foreign-title="Сульфид технеция(VII)"><span class="ilh-page"><a href="/w/index.php?title=%E4%B8%83%E7%A1%AB%E5%8C%96%E4%BA%8C%E9%94%9D&action=edit&redlink=1" class="new" title="七硫化二锝（页面不存在）">Tc<sub>2</sub>S<sub>7</sub></a></span><span class="noprint ilh-comment">（<span class="ilh-lang">俄语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://ru.wikipedia.org/wiki/%D0%A1%D1%83%D0%BB%D1%8C%D1%84%D0%B8%D0%B4_%D1%82%D0%B5%D1%85%D0%BD%D0%B5%D1%86%D0%B8%D1%8F(VII)" class="extiw" title="ru:Сульфид технеция(VII)"><span lang="ru" dir="auto">Сульфид технеция(VII)</span></a></span>）</span></span></li> <li><a href="/wiki/%E9%AB%98%E9%94%9D%E9%85%B8" title="高锝酸">HTcO<sub>4</sub></a></li> <li><a href="/wiki/%E9%81%8E%E9%8E%9D%E9%85%B8%E9%88%89" title="過鎝酸鈉">NaTcO<sub>4</sub></a></li> <li><a href="/wiki/%E9%AB%98%E9%94%9D%E9%85%B8%E9%92%BE" title="高锝酸钾">KTcO<sub>4</sub></a></li> <li><a href="/wiki/%E9%AB%98%E9%94%9D%E9%85%B8%E9%93%B7" title="高锝酸铷">RbTcO<sub>4</sub></a></li> <li><a href="/wiki/%E9%AB%98%E9%94%9D%E9%85%B8%E9%93%AF" title="高锝酸铯">CsTcO<sub>4</sub></a></li> <li><a href="/wiki/%E9%AB%98%E9%94%9D%E9%85%B8%E9%93%B5" title="高锝酸铵">NH<sub>4</sub>TcO<sub>4</sub></a></li> <li><a href="/wiki/%E9%AB%98%E9%94%9D%E9%85%B0%E6%B0%9F" title="高锝酰氟">TcO<sub>3</sub>F</a></li> <li><span class="ilh-all" data-orig-title="高锝酰氯" data-lang-code="ru" data-lang-name="俄语" data-foreign-title="Триоксихлорид технеция"><span class="ilh-page"><a href="/w/index.php?title=%E9%AB%98%E9%94%9D%E9%85%B0%E6%B0%AF&action=edit&redlink=1" class="new" title="高锝酰氯（页面不存在）">TcO<sub>3</sub>Cl</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">俄语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://ru.wikipedia.org/wiki/%D0%A2%D1%80%D0%B8%D0%BE%D0%BA%D1%81%D0%B8%D1%85%D0%BB%D0%BE%D1%80%D0%B8%D0%B4_%D1%82%D0%B5%D1%85%D0%BD%D0%B5%D1%86%D0%B8%D1%8F" class="extiw" title="ru:Триоксихлорид технеция"><span lang="ru" dir="auto">Триоксихлорид технеция</span></a></span>）</span></span></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">非整数价态</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E6%B0%AF%E5%8C%96%E5%9B%9B%E4%B9%99%E9%85%B8%E4%BA%8C%E9%94%9D" title="氯化四乙酸二锝">Tc<sub>2</sub>(OAc)<sub>4</sub>Cl</a></li> <li><a href="/wiki/%E6%BA%B4%E5%8C%96%E5%9B%9B%E4%B9%99%E9%85%B8%E4%BA%8C%E9%94%9D" title="溴化四乙酸二锝">Tc<sub>2</sub>(OAc)<sub>4</sub>Br</a></li></ul> </div></td></tr></tbody></table></div> <div class="navbox-styles"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84265675"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84261037"></div><div role="navigation" class="navbox" aria-labelledby="六氟化物" style="padding:3px"><table class="nowraplinks mw-collapsible mw-collapsed navbox-inner" style="border-spacing:0;background:transparent;color:inherit"><tbody><tr><th scope="col" class="collapsible-title navbox-title" colspan="2"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84265675"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84244141"><div class="navbar plainlinks hlist navbar-mini"><ul><li class="nv-view"><a href="/wiki/Template:%E5%85%AD%E6%B0%9F%E5%8C%96%E7%89%A9" title="Template:六氟化物"><abbr title="查看该模板">查</abbr></a></li><li class="nv-talk"><a href="/wiki/Template_talk:%E5%85%AD%E6%B0%9F%E5%8C%96%E7%89%A9" title="Template talk:六氟化物"><abbr title="讨论该模板">论</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:%E7%BC%96%E8%BE%91%E9%A1%B5%E9%9D%A2/Template:%E5%85%AD%E6%B0%9F%E5%8C%96%E7%89%A9" title="Special:编辑页面/Template:六氟化物"><abbr title="编辑该模板">编</abbr></a></li></ul></div><div id="六氟化物" style="font-size:110%;margin:0 5em"><span style="vertical-align:1px;"><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E7%89%A9" title="六氟化物">六氟化物</a></span></div></th></tr><tr><th scope="row" class="navbox-group" style="width:1%">已知的六氟化物</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/%E6%B0%A7%E6%97%8F%E5%85%83%E7%B4%A0" title="氧族元素">氧族元素</a>六氟化物</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E7%A1%AB" title="六氟化硫">SF<sub>6</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E7%A1%92" title="六氟化硒">SeF<sub>6</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E7%A2%B2" title="六氟化碲">TeF<sub>6</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E9%92%8B" title="六氟化钋">PoF<sub>6</sub></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/%E7%A8%80%E6%9C%89%E6%B0%94%E4%BD%93" title="稀有气体">稀有气体</a>六氟化物</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E6%B0%99" title="六氟化氙">XeF<sub>6</sub></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/%E8%BF%87%E6%B8%A1%E9%87%91%E5%B1%9E" title="过渡金属">过渡金属</a>六氟化物</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E9%92%BC" title="六氟化钼">MoF<sub>6</sub></a></li> <li><a class="mw-selflink selflink">TcF<sub>6</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E9%92%8C" title="六氟化钌">RuF<sub>6</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E9%93%91" title="六氟化铑">RhF<sub>6</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E9%92%A8" title="六氟化钨">WF<sub>6</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E9%93%BC" title="六氟化铼">ReF<sub>6</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E9%94%87" title="六氟化锇">OsF<sub>6</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E9%93%B1" title="六氟化铱">IrF<sub>6</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E9%93%82" title="六氟化铂">PtF<sub>6</sub></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/%E9%94%95%E7%B3%BB%E5%85%83%E7%B4%A0" title="锕系元素">锕系元素</a>六氟化物</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E9%88%BE" title="六氟化鈾">UF<sub>6</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E9%95%8E" title="六氟化镎">NpF<sub>6</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E9%92%9A" title="六氟化钚">PuF<sub>6</sub></a></li></ul> </div></td></tr></tbody></table><div></div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">理论上存在的六氟化物</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E6%B0%AA" title="六氟化氪">KrF<sub>6</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E6%B0%A1" title="六氟化氡">RnF<sub>6</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E9%93%AC" title="六氟化铬">CrF<sub>6</sub></a></li> <li><a href="/w/index.php?title=%E5%85%AD%E6%B0%9F%E5%8C%96%E9%92%AF&action=edit&redlink=1" class="new" title="六氟化钯（页面不存在）">PdF<sub>6</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E9%95%85" title="六氟化镅">AmF<sub>6</sub></a></li> <li><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E9%94%94" title="六氟化锔">CmF<sub>6</sub></a></li></ul> </div></td></tr></tbody></table></div>    </div><noscript><img src="https://login.wikimedia.org/wiki/Special:CentralAutoLogin/start?type=1x1" alt="" width="1" height="1" style="border: none; position: absolute;"></noscript> <div class="printfooter" data-nosnippet="">检索自“<a dir="ltr" href="https://zh.wikipedia.org/w/index.php?title=六氟化鎝&oldid=77061285">https://zh.wikipedia.org/w/index.php?title=六氟化鎝&oldid=77061285</a>”</div></div> <div id="catlinks" class="catlinks" data-mw="interface"><div id="mw-normal-catlinks" class="mw-normal-catlinks"><a href="/wiki/Special:%E9%A1%B5%E9%9D%A2%E5%88%86%E7%B1%BB" title="Special:页面分类">分类</a>：<ul><li><a href="/wiki/Category:%E5%85%AD%E6%B0%9F%E5%8C%96%E7%89%A9" title="Category:六氟化物">六氟化物</a></li><li><a href="/wiki/Category:%E5%85%AB%E9%9D%A2%E4%BD%93%E5%BD%A2%E5%88%86%E5%AD%90" title="Category:八面体形分子">八面体形分子</a></li><li><a href="/wiki/Category:%E5%8D%A4%E5%8C%96%E9%94%9D" title="Category:卤化锝">卤化锝</a></li><li><a href="/wiki/Category:1960%E5%B9%B4%E4%BB%A3%E5%8F%91%E7%8E%B0%E7%9A%84%E7%89%A9%E8%B4%A8" title="Category:1960年代发现的物质">1960年代发现的物质</a></li></ul></div><div id="mw-hidden-catlinks" class="mw-hidden-catlinks mw-hidden-cats-hidden">隐藏分类：<ul><li><a href="/wiki/Category:%E7%84%A1CAS%E8%99%9F%E9%87%8D%E5%AE%9A%E5%90%91%E7%9A%84%E7%89%A9%E8%B3%AA%E6%A2%9D%E7%9B%AE" title="Category:無CAS號重定向的物質條目">無CAS號重定向的物質條目</a></li><li><a href="/wiki/Category:%E5%90%AB%E6%9C%89%E6%9C%AA%E6%A0%A1%E5%B0%8DCAS%E8%99%9F%E7%9A%84%E6%A2%9D%E7%9B%AE" title="Category:含有未校對CAS號的條目">含有未校對CAS號的條目</a></li><li><a href="/wiki/Category:%E6%97%A0%E9%99%84%E5%8A%A0%E6%95%B0%E6%8D%AE%E9%A1%B5%E7%9A%84%E5%8C%96%E5%AD%A6%E6%9D%A1%E7%9B%AE" title="Category:无附加数据页的化学条目">无附加数据页的化学条目</a></li></ul></div></div> </div> 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