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Coman</h3></div><div class="js-work-strip profile--work_container" data-work-id="114732642"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/114732642/HPLC_PDA_versus_GC_MS_in_the_analysis_of_paracetamol_and_non_steroidal_anti_inflammatory_drugs_in_wastewater"><img alt="Research paper thumbnail of HPLC-PDA versus GC-MS in the analysis of paracetamol and non-steroidal anti-inflammatory drugs in wastewater" class="work-thumbnail" src="https://attachments.academia-assets.com/111349364/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/114732642/HPLC_PDA_versus_GC_MS_in_the_analysis_of_paracetamol_and_non_steroidal_anti_inflammatory_drugs_in_wastewater">HPLC-PDA versus GC-MS in the analysis of paracetamol and non-steroidal anti-inflammatory drugs in wastewater</a></div><div class="wp-workCard_item"><span>Studia Universitatis Babeș-Bolyai Chemia</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="1058b222c681e325f55ef49b304c54e9" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":111349364,"asset_id":114732642,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/111349364/download_file?st=MTczMjQyOTM5MCw4LjIyMi4yMDguMTQ2&s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="114732642"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="114732642"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 114732642; 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="93149010"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/93149010/Diffuse_Water_Pollution_by_Anthraquinone_and_Azo_Dyes_in_Environment_Importantly_Alters_Foliage_Volatiles_Carotenoids_and_Physiology_in_Wheat_Triticum_aestivum_"><img alt="Research paper thumbnail of Diffuse Water Pollution by Anthraquinone and Azo Dyes in Environment Importantly Alters Foliage Volatiles, Carotenoids and Physiology in Wheat (Triticum aestivum)" class="work-thumbnail" src="https://attachments.academia-assets.com/95967123/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/93149010/Diffuse_Water_Pollution_by_Anthraquinone_and_Azo_Dyes_in_Environment_Importantly_Alters_Foliage_Volatiles_Carotenoids_and_Physiology_in_Wheat_Triticum_aestivum_">Diffuse Water Pollution by Anthraquinone and Azo Dyes in Environment Importantly Alters Foliage Volatiles, Carotenoids and Physiology in Wheat (Triticum aestivum)</a></div><div class="wp-workCard_item"><span>Water, Air, &amp; 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This paper reports an application of the comprehensive GC×GC/qMS for the evaluation of the lipids removal mechanism in different wastewater treatment plants in order to assess the role of different physical and biological processes over the removal mechanism. For this purpose, the content and fats profile in wastewater were analyzed and calculated. For the separation of the fatty acid methyl esters (FAMEs) enclosed on the fats, two combinations of the capillary columns coated with non-polar/polar and polar/non-polar phases were applied. The validated proposed GC×GC/qMS method presented satisfactory results in terms of repeatability (coefficient of variation lower than 15%), linearity (ranging from 0.5 to 10 μg mL−1), limit of detection (LOD) and limit of quantification (LOQ). In order to increase the consistency of the results, statistical analysis regarding the composition of the fats in both influent and effluent were performed. The results of performed experiments showed that, in the wastewater plant which contains only a physical trap, the removal mechanism is based on the adsorption of fats onto particulate matter, while in the wastewater plants which include a biological trap, the removal mechanism combines the adsorption of fats on the particulate matter in the physical trap with the biodegradation of fats with bacterial activated sludge in the biological trap. As a result, the composition of fats during the biological treatment is modified due to the β-oxidation and other microbial bioconversion processes which through an aerobic biodegradation process destroys the mono- and poly-unsaturated fatty acids and promotes the accumulation of saturated long chain fatty acids.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="87285098"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="87285098"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 87285098; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=87285098]").text(description); $(".js-view-count[data-work-id=87285098]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 87285098; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='87285098']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 87285098, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=87285098]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":87285098,"title":"Characterization of the fate of lipids in wastewater treatment using a comprehensive GC×GC/qMS and statistical approach","translated_title":"","metadata":{"abstract":"ABSTRACT Lipids, characterized as oils, greases, fats or long-chain fatty acids are an important organic component of municipal wastewater, their removal being the main concern in wastewater treatment. 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We used the CaCO3 template to synthesize non-toxic CaCO3/BSA particles as microtemplates by coprecipitating a CaCl2 solution that contains dissolved BSA, with an equimolar Na2CO3 solution. The microcapsules shell is assembled through a layer-by-layer deposition technique of calcium cross-linked k-carrageenan hydrogel alternating with polyelectrolite complex hydrogel formed via electrostatic interactions between k-carrageenan and chitosan. After the removal of CaCO3 through Ca2+ complexation with EDTA, and by a slightly treatment with HCl diluted solution, the BSA core is turned into a BSA gel through a thermal treatment. The BSA gel microcapsules were then loaded with curcumin, through a diffusion process from curcumin ethanolic solution. 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Drawn by capilla...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">During the layer chromatographic process the sample is separated into fractions. Drawn by capillary forces, the developing solvent (mobile-phase) migrates through the thin layer (stationary phase) over a distance defined by the solvent front that is inversely related to the solvent flow velocity. Considering that the physical properties of the dielectric liquids are influenced by the electric fields and the capillary tubes can be used to simulate and to understand the solvent displacement through porous media, we obtained interesting results by applying transversal alternating electric fields over them. 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Porous media with a high dielectric constant with alumina and barium titanate were prepared and tested.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="84102398"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="84102398"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 84102398; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=84102398]").text(description); $(".js-view-count[data-work-id=84102398]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 84102398; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='84102398']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 84102398, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=84102398]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":84102398,"title":"Layer dielectrochromatography—under external alternating current, LDEC","translated_title":"","metadata":{"abstract":"During the layer chromatographic process the sample is separated into fractions. 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Considering that the physical properties of the dielectric liquids are influenced by the electric fields and the capillary tubes can be used to simulate and to understand the solvent displacement through porous media, we obtained interesting results by applying transversal alternating electric fields over them. These electric fields, applied in equi- or counter-current arrangement, can influence the solvent front velocity and the solute migration distance, generating two phenomena, dielectroosmotic flow and dielectrophoresis, which applied to the classical thin-layer chromatography are the basis of the layer dielectrochromatography (LDEC). To investigate LDEC principles, a horizontal and a vertical LDEC chamber were conceived, handmade and used for tests with lipophilic and hydrophilic dyes. To obtain electric fields of different geometries, five armatures of different shapes were created and investigated. Porous media with a high dielectric constant with alumina and barium titanate were prepared and tested.","internal_url":"https://www.academia.edu/84102398/Layer_dielectrochromatography_under_external_alternating_current_LDEC","translated_internal_url":"","created_at":"2022-08-03T08:54:30.384-07:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":42735394,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[],"slug":"Layer_dielectrochromatography_under_external_alternating_current_LDEC","translated_slug":"","page_count":null,"language":"en","content_type":"Work","owner":{"id":42735394,"first_name":"V.","middle_initials":null,"last_name":"Coman","page_name":"VComan1","domain_name":"independent","created_at":"2016-02-05T11:36:45.431-08:00","display_name":"V. Coman","url":"https://independent.academia.edu/VComan1"},"attachments":[],"research_interests":[{"id":523,"name":"Chemistry","url":"https://www.academia.edu/Documents/in/Chemistry"},{"id":897823,"name":"Elsevier","url":"https://www.academia.edu/Documents/in/Elsevier"}],"urls":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="83367834"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/83367834/Determination_of_purine_derivatives_in_bovine_urine_using_rapid_chromatographic_techniques"><img alt="Research paper thumbnail of Determination of purine derivatives in bovine urine using rapid chromatographic techniques" class="work-thumbnail" src="https://attachments.academia-assets.com/88734355/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/83367834/Determination_of_purine_derivatives_in_bovine_urine_using_rapid_chromatographic_techniques">Determination of purine derivatives in bovine urine using rapid chromatographic techniques</a></div><div class="wp-workCard_item"><span>Archiva Zootechnica</span><span>, 2009</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="98c858d09c555174cf259a2188df215f" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":88734355,"asset_id":83367834,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/88734355/download_file?st=MTczMjQyOTM5MCw4LjIyMi4yMDguMTQ2&s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="83367834"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="83367834"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 83367834; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=83367834]").text(description); $(".js-view-count[data-work-id=83367834]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 83367834; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='83367834']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 83367834, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "98c858d09c555174cf259a2188df215f" } } $('.js-work-strip[data-work-id=83367834]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":83367834,"title":"Determination of purine derivatives in bovine urine using rapid chromatographic techniques","translated_title":"","metadata":{"publisher":"ibna.ro","grobid_abstract":"In this study, two techniques (HPLC-UV and TLC) were assessed as alternatives to the analysis of purine derivatives (allantoin, uric acid, xanthine and hypoxanthine) using classical spectrometry method, still largely used in SouthEastern Europe. With HPLC technique, very good calibration curves were obtained for all four purine derivatives (r\u003e0.999). Also, detection limits were satisfactory: ≥ 7.5 µg/mL for allantoin, ≥ 2.7 µg/mL for uric acid, ≥ 5.5 µg/mL for xanthine and ≥ 10.02 µg/mL for hypoxanthine. The analysis of urine samples taken from dairy cows gave results which were in the range of literature data for allantoin and uric acid, but not for hypoxanthine (whose concentration was much higher than values reported in literature). TLC technique allowed good separation of standards and elaboration of good calibration curves (r\u003e0.984). Detection limits were too high, if the whole range of values reported in literature for the concentrations purine derivatives in ruminants' urine is taken into account. Moreover, on urine samples the spots of creatinie overlapped the spots of uric acids, impairing the quantitative estimation of purine derivatives. It is concluded that HPLC technique can be used to assess the concentration of allantoin and uric acid in the urine of cows. The TLC technique can be used qualitatively, further studies on samples preparation and procedure being needed in order to use it for quantitative determinations.","publication_date":{"day":null,"month":null,"year":2009,"errors":{}},"publication_name":"Archiva Zootechnica","grobid_abstract_attachment_id":88734355},"translated_abstract":null,"internal_url":"https://www.academia.edu/83367834/Determination_of_purine_derivatives_in_bovine_urine_using_rapid_chromatographic_techniques","translated_internal_url":"","created_at":"2022-07-18T10:17:57.987-07:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":42735394,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[{"id":88734355,"title":"","file_type":"pdf","scribd_thumbnail_url":"https://attachments.academia-assets.com/88734355/thumbnails/1.jpg","file_name":"AZ_2012-4_05_20Vlassa.pdf","download_url":"https://www.academia.edu/attachments/88734355/download_file?st=MTczMjQyOTM5MCw4LjIyMi4yMDguMTQ2&","bulk_download_file_name":"Determination_of_purine_derivatives_in_b.pdf","bulk_download_url":"https://d1wqtxts1xzle7.cloudfront.net/88734355/AZ_2012-4_05_20Vlassa-libre.pdf?1658167457=\u0026response-content-disposition=attachment%3B+filename%3DDetermination_of_purine_derivatives_in_b.pdf\u0026Expires=1732432990\u0026Signature=COjP62E7kR3Akq3HonWkZ0mNwgCic6yzF1iP0Ym1CLodh7RgyQbrYznpIoRRRAq1XfHUgFMTxMvh7ktgNpYFKOHP3ySbvhUgVPEEc~y69Xlx-yVvWErRXHiTjDFm5G0Ls4JNNWhtoqMKeJtX63p1dQyGmBLPzyoVLIN5gvRWA~5-VqOgbNkH3hkSdWz-KNjmGA6P6XOy6ZGm8IWM53kCApzlyuE8t-QWnAzuUKve8LhBGOHYpEmWoqGfjnl4Uyovya7WSILoZvBYDhkOW-5la7GdNj8RHxGqfpBajs9N8rMB1-fV5Z7csoY~bK6q9QlUyBjNQJNl4yFPuP-bBY5GnQ__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA"}],"slug":"Determination_of_purine_derivatives_in_bovine_urine_using_rapid_chromatographic_techniques","translated_slug":"","page_count":12,"language":"en","content_type":"Work","owner":{"id":42735394,"first_name":"V.","middle_initials":null,"last_name":"Coman","page_name":"VComan1","domain_name":"independent","created_at":"2016-02-05T11:36:45.431-08:00","display_name":"V. 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I. Preliminary results" class="work-thumbnail" src="https://attachments.academia-assets.com/87921335/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/82109993/Horizontal_planar_dielectrochromatography_I_Preliminary_results">Horizontal planar dielectrochromatography. I. Preliminary results</a></div><div class="wp-workCard_item"><span>JPC - Journal of Planar Chromatography - Modern TLC</span><span>, 2002</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="accf9e90f199cec9597321dd9fbd7231" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":87921335,"asset_id":82109993,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/87921335/download_file?st=MTczMjQyOTM5MSw4LjIyMi4yMDguMTQ2&s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="82109993"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="82109993"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 82109993; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=82109993]").text(description); $(".js-view-count[data-work-id=82109993]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 82109993; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='82109993']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 82109993, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "accf9e90f199cec9597321dd9fbd7231" } } $('.js-work-strip[data-work-id=82109993]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":82109993,"title":"Horizontal planar dielectrochromatography. 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In this paper, a horizontal chromatographic chamber has been constructed and has been used to study experimentally the principles of planar dielectrochromatography, in particular the increase of the mobile phase front velocity and the dielectrophoretic force generated at granule level on different ready-touse Macherey-Nagel plates.","publication_date":{"day":null,"month":null,"year":2002,"errors":{}},"publication_name":"JPC - Journal of Planar Chromatography - Modern TLC","grobid_abstract_attachment_id":87921335},"translated_abstract":null,"internal_url":"https://www.academia.edu/82109993/Horizontal_planar_dielectrochromatography_I_Preliminary_results","translated_internal_url":"","created_at":"2022-06-23T09:57:17.404-07:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":42735394,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[{"id":87921335,"title":"","file_type":"pdf","scribd_thumbnail_url":"https://attachments.academia-assets.com/87921335/thumbnails/1.jpg","file_name":"JPC.15.2002.6.620220623-1-1djdlf.pdf","download_url":"https://www.academia.edu/attachments/87921335/download_file?st=MTczMjQyOTM5MSw4LjIyMi4yMDguMTQ2&","bulk_download_file_name":"Horizontal_planar_dielectrochromatograph.pdf","bulk_download_url":"https://d1wqtxts1xzle7.cloudfront.net/87921335/JPC.15.2002.6.620220623-1-1djdlf-libre.pdf?1656003599=\u0026response-content-disposition=attachment%3B+filename%3DHorizontal_planar_dielectrochromatograph.pdf\u0026Expires=1732432991\u0026Signature=epzc6e7uPZa4PHK182O9EDIjDWlSNtmm9~5XVvSuBHtkrsRytwFiftRlQ86VA-ZjY53~VU6ORw8n~qYsXVZgbqetFEQUS3pOPzra~I00BZoCdImcYnDMzcZOHbmU6nF8Oc0cSo-rcan~MHI4cuxGKwrsfI3d5vKKRNaDqHlXQA~R4xuso0XtKO2YAVScAZ-i5pu36kHKa2TMciS3bIvZ~-kp8pB5odAx-alWodynSI0ynt7FVg-TuaCqgHpZDqt8N2wtHHv-UsIy~lEK-6UrPpqfYIOv1-v3BZr4tjMIi2zDAhWVVXv7SB8LaN0p0U-nLnltoVJK99C3F92nT7zC8w__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA"}],"slug":"Horizontal_planar_dielectrochromatography_I_Preliminary_results","translated_slug":"","page_count":4,"language":"en","content_type":"Work","owner":{"id":42735394,"first_name":"V.","middle_initials":null,"last_name":"Coman","page_name":"VComan1","domain_name":"independent","created_at":"2016-02-05T11:36:45.431-08:00","display_name":"V. 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Coman","url":"https://independent.academia.edu/VComan1"},"attachments":[],"research_interests":[],"urls":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="87285099"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/87285099/CO_2_Cryogenic_Modulation_in_Comprehensive_Two_Dimensional_Gas_Chromatography_Influence_of_the_stationary_phase_used_for_trapping"><img alt="Research paper thumbnail of CO 2 Cryogenic Modulation in Comprehensive Two Dimensional Gas Chromatography Influence of the stationary phase used for trapping" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" rel="nofollow" href="https://www.academia.edu/87285099/CO_2_Cryogenic_Modulation_in_Comprehensive_Two_Dimensional_Gas_Chromatography_Influence_of_the_stationary_phase_used_for_trapping">CO 2 Cryogenic Modulation in Comprehensive Two Dimensional Gas Chromatography Influence of the stationary phase used for trapping</a></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">MIHAIL SIMION BELDEAN-GALEA1*, DIDIER THIEBAUT2, JEROME VIAL2, PATRICK SASSIAT2, MARIANNE BOUZIGE...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">MIHAIL SIMION BELDEAN-GALEA1*, DIDIER THIEBAUT2, JEROME VIAL2, PATRICK SASSIAT2, MARIANNE BOUZIGE3, MARIA-VIRGINIA COMAN4 1 Babeo-Bolyai University, Faculty of Environmental Science and Engineering, 30 Fântânele Street, 400294 Cluj-Napoca, Romania 2 LECA, UMR-CNRS PECSA 7195, Ecole Superieure de Physique et de Chimie Industrielles, ParisTech, 10 Vauquelin Street, 75231 Paris Cedex 05, France 3 ALTADIS, Fleury les Aubrais, France 4 Babeo-Bolyai University, Raluca Ripan Institute for Research in Chemistry, 30 Fântânele Street, 400294, Cluj-Napoca, Romania</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="87285099"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="87285099"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 87285099; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=87285099]").text(description); $(".js-view-count[data-work-id=87285099]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 87285099; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='87285099']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 87285099, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=87285099]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":87285099,"title":"CO 2 Cryogenic Modulation in Comprehensive Two Dimensional Gas Chromatography Influence of the stationary phase used for trapping","translated_title":"","metadata":{"abstract":"MIHAIL SIMION BELDEAN-GALEA1*, DIDIER THIEBAUT2, JEROME VIAL2, PATRICK SASSIAT2, MARIANNE BOUZIGE3, MARIA-VIRGINIA COMAN4 1 Babeo-Bolyai University, Faculty of Environmental Science and Engineering, 30 Fântânele Street, 400294 Cluj-Napoca, Romania 2 LECA, UMR-CNRS PECSA 7195, Ecole Superieure de Physique et de Chimie Industrielles, ParisTech, 10 Vauquelin Street, 75231 Paris Cedex 05, France 3 ALTADIS, Fleury les Aubrais, France 4 Babeo-Bolyai University, Raluca Ripan Institute for Research in Chemistry, 30 Fântânele Street, 400294, Cluj-Napoca, Romania","publication_date":{"day":null,"month":null,"year":2012,"errors":{}}},"translated_abstract":"MIHAIL SIMION BELDEAN-GALEA1*, DIDIER THIEBAUT2, JEROME VIAL2, PATRICK SASSIAT2, MARIANNE BOUZIGE3, MARIA-VIRGINIA COMAN4 1 Babeo-Bolyai University, Faculty of Environmental Science and Engineering, 30 Fântânele Street, 400294 Cluj-Napoca, Romania 2 LECA, UMR-CNRS PECSA 7195, Ecole Superieure de Physique et de Chimie Industrielles, ParisTech, 10 Vauquelin Street, 75231 Paris Cedex 05, France 3 ALTADIS, Fleury les Aubrais, France 4 Babeo-Bolyai University, Raluca Ripan Institute for Research in Chemistry, 30 Fântânele Street, 400294, Cluj-Napoca, Romania","internal_url":"https://www.academia.edu/87285099/CO_2_Cryogenic_Modulation_in_Comprehensive_Two_Dimensional_Gas_Chromatography_Influence_of_the_stationary_phase_used_for_trapping","translated_internal_url":"","created_at":"2022-09-25T12:53:01.329-07:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":42735394,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[],"slug":"CO_2_Cryogenic_Modulation_in_Comprehensive_Two_Dimensional_Gas_Chromatography_Influence_of_the_stationary_phase_used_for_trapping","translated_slug":"","page_count":null,"language":"en","content_type":"Work","owner":{"id":42735394,"first_name":"V.","middle_initials":null,"last_name":"Coman","page_name":"VComan1","domain_name":"independent","created_at":"2016-02-05T11:36:45.431-08:00","display_name":"V. Coman","url":"https://independent.academia.edu/VComan1"},"attachments":[],"research_interests":[{"id":511,"name":"Materials Science","url":"https://www.academia.edu/Documents/in/Materials_Science"},{"id":456380,"name":"Trapping","url":"https://www.academia.edu/Documents/in/Trapping"}],"urls":[{"id":24165618,"url":"http://www.revistadechimie.ro/pdf/SIMION%20BELDEAN.pdf%208%2012.pdf"}]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="87285098"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/87285098/Characterization_of_the_fate_of_lipids_in_wastewater_treatment_using_a_comprehensive_GC_GC_qMS_and_statistical_approach"><img alt="Research paper thumbnail of Characterization of the fate of lipids in wastewater treatment using a comprehensive GC×GC/qMS and statistical approach" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/87285098/Characterization_of_the_fate_of_lipids_in_wastewater_treatment_using_a_comprehensive_GC_GC_qMS_and_statistical_approach">Characterization of the fate of lipids in wastewater treatment using a comprehensive GC×GC/qMS and statistical approach</a></div><div class="wp-workCard_item"><span>Analytical Methods</span><span>, 2013</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">ABSTRACT Lipids, characterized as oils, greases, fats or long-chain fatty acids are an important ...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">ABSTRACT Lipids, characterized as oils, greases, fats or long-chain fatty acids are an important organic component of municipal wastewater, their removal being the main concern in wastewater treatment. This paper reports an application of the comprehensive GC×GC/qMS for the evaluation of the lipids removal mechanism in different wastewater treatment plants in order to assess the role of different physical and biological processes over the removal mechanism. For this purpose, the content and fats profile in wastewater were analyzed and calculated. For the separation of the fatty acid methyl esters (FAMEs) enclosed on the fats, two combinations of the capillary columns coated with non-polar/polar and polar/non-polar phases were applied. The validated proposed GC×GC/qMS method presented satisfactory results in terms of repeatability (coefficient of variation lower than 15%), linearity (ranging from 0.5 to 10 μg mL−1), limit of detection (LOD) and limit of quantification (LOQ). In order to increase the consistency of the results, statistical analysis regarding the composition of the fats in both influent and effluent were performed. The results of performed experiments showed that, in the wastewater plant which contains only a physical trap, the removal mechanism is based on the adsorption of fats onto particulate matter, while in the wastewater plants which include a biological trap, the removal mechanism combines the adsorption of fats on the particulate matter in the physical trap with the biodegradation of fats with bacterial activated sludge in the biological trap. As a result, the composition of fats during the biological treatment is modified due to the β-oxidation and other microbial bioconversion processes which through an aerobic biodegradation process destroys the mono- and poly-unsaturated fatty acids and promotes the accumulation of saturated long chain fatty acids.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="87285098"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="87285098"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 87285098; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=87285098]").text(description); $(".js-view-count[data-work-id=87285098]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 87285098; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='87285098']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 87285098, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=87285098]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":87285098,"title":"Characterization of the fate of lipids in wastewater treatment using a comprehensive GC×GC/qMS and statistical approach","translated_title":"","metadata":{"abstract":"ABSTRACT Lipids, characterized as oils, greases, fats or long-chain fatty acids are an important organic component of municipal wastewater, their removal being the main concern in wastewater treatment. This paper reports an application of the comprehensive GC×GC/qMS for the evaluation of the lipids removal mechanism in different wastewater treatment plants in order to assess the role of different physical and biological processes over the removal mechanism. For this purpose, the content and fats profile in wastewater were analyzed and calculated. For the separation of the fatty acid methyl esters (FAMEs) enclosed on the fats, two combinations of the capillary columns coated with non-polar/polar and polar/non-polar phases were applied. The validated proposed GC×GC/qMS method presented satisfactory results in terms of repeatability (coefficient of variation lower than 15%), linearity (ranging from 0.5 to 10 μg mL−1), limit of detection (LOD) and limit of quantification (LOQ). In order to increase the consistency of the results, statistical analysis regarding the composition of the fats in both influent and effluent were performed. The results of performed experiments showed that, in the wastewater plant which contains only a physical trap, the removal mechanism is based on the adsorption of fats onto particulate matter, while in the wastewater plants which include a biological trap, the removal mechanism combines the adsorption of fats on the particulate matter in the physical trap with the biodegradation of fats with bacterial activated sludge in the biological trap. As a result, the composition of fats during the biological treatment is modified due to the β-oxidation and other microbial bioconversion processes which through an aerobic biodegradation process destroys the mono- and poly-unsaturated fatty acids and promotes the accumulation of saturated long chain fatty acids.","publisher":"Royal Society of Chemistry (RSC)","publication_date":{"day":null,"month":null,"year":2013,"errors":{}},"publication_name":"Analytical Methods"},"translated_abstract":"ABSTRACT Lipids, characterized as oils, greases, fats or long-chain fatty acids are an important organic component of municipal wastewater, their removal being the main concern in wastewater treatment. This paper reports an application of the comprehensive GC×GC/qMS for the evaluation of the lipids removal mechanism in different wastewater treatment plants in order to assess the role of different physical and biological processes over the removal mechanism. For this purpose, the content and fats profile in wastewater were analyzed and calculated. For the separation of the fatty acid methyl esters (FAMEs) enclosed on the fats, two combinations of the capillary columns coated with non-polar/polar and polar/non-polar phases were applied. The validated proposed GC×GC/qMS method presented satisfactory results in terms of repeatability (coefficient of variation lower than 15%), linearity (ranging from 0.5 to 10 μg mL−1), limit of detection (LOD) and limit of quantification (LOQ). In order to increase the consistency of the results, statistical analysis regarding the composition of the fats in both influent and effluent were performed. The results of performed experiments showed that, in the wastewater plant which contains only a physical trap, the removal mechanism is based on the adsorption of fats onto particulate matter, while in the wastewater plants which include a biological trap, the removal mechanism combines the adsorption of fats on the particulate matter in the physical trap with the biodegradation of fats with bacterial activated sludge in the biological trap. As a result, the composition of fats during the biological treatment is modified due to the β-oxidation and other microbial bioconversion processes which through an aerobic biodegradation process destroys the mono- and poly-unsaturated fatty acids and promotes the accumulation of saturated long chain fatty acids.","internal_url":"https://www.academia.edu/87285098/Characterization_of_the_fate_of_lipids_in_wastewater_treatment_using_a_comprehensive_GC_GC_qMS_and_statistical_approach","translated_internal_url":"","created_at":"2022-09-25T12:53:01.104-07:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":42735394,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[],"slug":"Characterization_of_the_fate_of_lipids_in_wastewater_treatment_using_a_comprehensive_GC_GC_qMS_and_statistical_approach","translated_slug":"","page_count":null,"language":"en","content_type":"Work","owner":{"id":42735394,"first_name":"V.","middle_initials":null,"last_name":"Coman","page_name":"VComan1","domain_name":"independent","created_at":"2016-02-05T11:36:45.431-08:00","display_name":"V. 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The main vibrational bands characteristic to major constituents of bones, that is collagen and calcium phosphate, were identified. Mature deer antler has the same constituents. The relative content of the organics in different bones was evaluated from Raman spectra as an integration ratio between the ν(CH) bands at 2825-3080 cm -1 and the ν1[PO4] 3- band centered at 960 cm -1 . This ratio decreases in the order: mature deer antler &gt; human skull &gt; fish &gt; pig. The thermal behaviour of bones was investigated by infrared spectroscopy. Heating of powdered bones produces at 200 o C the diminishing of the organic component, marked by the reduced intensity of the amide III band observed at 1239 cm -1 . 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We used the CaCO3 template to synthesize non-toxic CaCO3/BSA particles as microtemplates by coprecipitating a CaCl2 solution that contains dissolved BSA, with an equimolar Na2CO3 solution. The microcapsules shell is assembled through a layer-by-layer deposition technique of calcium cross-linked k-carrageenan hydrogel alternating with polyelectrolite complex hydrogel formed via electrostatic interactions between k-carrageenan and chitosan. After the removal of CaCO3 through Ca2+ complexation with EDTA, and by a slightly treatment with HCl diluted solution, the BSA core is turned into a BSA gel through a thermal treatment. The BSA gel microcapsules were then loaded with curcumin, through a diffusion process from curcumin ethanolic solution. 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Drawn by capilla...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">During the layer chromatographic process the sample is separated into fractions. Drawn by capillary forces, the developing solvent (mobile-phase) migrates through the thin layer (stationary phase) over a distance defined by the solvent front that is inversely related to the solvent flow velocity. Considering that the physical properties of the dielectric liquids are influenced by the electric fields and the capillary tubes can be used to simulate and to understand the solvent displacement through porous media, we obtained interesting results by applying transversal alternating electric fields over them. 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Considering that the physical properties of the dielectric liquids are influenced by the electric fields and the capillary tubes can be used to simulate and to understand the solvent displacement through porous media, we obtained interesting results by applying transversal alternating electric fields over them. These electric fields, applied in equi- or counter-current arrangement, can influence the solvent front velocity and the solute migration distance, generating two phenomena, dielectroosmotic flow and dielectrophoresis, which applied to the classical thin-layer chromatography are the basis of the layer dielectrochromatography (LDEC). To investigate LDEC principles, a horizontal and a vertical LDEC chamber were conceived, handmade and used for tests with lipophilic and hydrophilic dyes. To obtain electric fields of different geometries, five armatures of different shapes were created and investigated. Porous media with a high dielectric constant with alumina and barium titanate were prepared and tested.","internal_url":"https://www.academia.edu/84102398/Layer_dielectrochromatography_under_external_alternating_current_LDEC","translated_internal_url":"","created_at":"2022-08-03T08:54:30.384-07:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":42735394,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[],"slug":"Layer_dielectrochromatography_under_external_alternating_current_LDEC","translated_slug":"","page_count":null,"language":"en","content_type":"Work","owner":{"id":42735394,"first_name":"V.","middle_initials":null,"last_name":"Coman","page_name":"VComan1","domain_name":"independent","created_at":"2016-02-05T11:36:45.431-08:00","display_name":"V. Coman","url":"https://independent.academia.edu/VComan1"},"attachments":[],"research_interests":[{"id":523,"name":"Chemistry","url":"https://www.academia.edu/Documents/in/Chemistry"},{"id":897823,"name":"Elsevier","url":"https://www.academia.edu/Documents/in/Elsevier"}],"urls":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="83367834"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/83367834/Determination_of_purine_derivatives_in_bovine_urine_using_rapid_chromatographic_techniques"><img alt="Research paper thumbnail of Determination of purine derivatives in bovine urine using rapid chromatographic techniques" class="work-thumbnail" src="https://attachments.academia-assets.com/88734355/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/83367834/Determination_of_purine_derivatives_in_bovine_urine_using_rapid_chromatographic_techniques">Determination of purine derivatives in bovine urine using rapid chromatographic techniques</a></div><div class="wp-workCard_item"><span>Archiva Zootechnica</span><span>, 2009</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="98c858d09c555174cf259a2188df215f" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":88734355,"asset_id":83367834,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/88734355/download_file?st=MTczMjQyOTM5MSw4LjIyMi4yMDguMTQ2&st=MTczMjQyOTM5MCw4LjIyMi4yMDguMTQ2&s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="83367834"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="83367834"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 83367834; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=83367834]").text(description); $(".js-view-count[data-work-id=83367834]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 83367834; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='83367834']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 83367834, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "98c858d09c555174cf259a2188df215f" } } $('.js-work-strip[data-work-id=83367834]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":83367834,"title":"Determination of purine derivatives in bovine urine using rapid chromatographic techniques","translated_title":"","metadata":{"publisher":"ibna.ro","grobid_abstract":"In this study, two techniques (HPLC-UV and TLC) were assessed as alternatives to the analysis of purine derivatives (allantoin, uric acid, xanthine and hypoxanthine) using classical spectrometry method, still largely used in SouthEastern Europe. With HPLC technique, very good calibration curves were obtained for all four purine derivatives (r\u003e0.999). Also, detection limits were satisfactory: ≥ 7.5 µg/mL for allantoin, ≥ 2.7 µg/mL for uric acid, ≥ 5.5 µg/mL for xanthine and ≥ 10.02 µg/mL for hypoxanthine. The analysis of urine samples taken from dairy cows gave results which were in the range of literature data for allantoin and uric acid, but not for hypoxanthine (whose concentration was much higher than values reported in literature). TLC technique allowed good separation of standards and elaboration of good calibration curves (r\u003e0.984). Detection limits were too high, if the whole range of values reported in literature for the concentrations purine derivatives in ruminants' urine is taken into account. Moreover, on urine samples the spots of creatinie overlapped the spots of uric acids, impairing the quantitative estimation of purine derivatives. It is concluded that HPLC technique can be used to assess the concentration of allantoin and uric acid in the urine of cows. The TLC technique can be used qualitatively, further studies on samples preparation and procedure being needed in order to use it for quantitative determinations.","publication_date":{"day":null,"month":null,"year":2009,"errors":{}},"publication_name":"Archiva Zootechnica","grobid_abstract_attachment_id":88734355},"translated_abstract":null,"internal_url":"https://www.academia.edu/83367834/Determination_of_purine_derivatives_in_bovine_urine_using_rapid_chromatographic_techniques","translated_internal_url":"","created_at":"2022-07-18T10:17:57.987-07:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":42735394,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[{"id":88734355,"title":"","file_type":"pdf","scribd_thumbnail_url":"https://attachments.academia-assets.com/88734355/thumbnails/1.jpg","file_name":"AZ_2012-4_05_20Vlassa.pdf","download_url":"https://www.academia.edu/attachments/88734355/download_file?st=MTczMjQyOTM5MSw4LjIyMi4yMDguMTQ2&st=MTczMjQyOTM5MCw4LjIyMi4yMDguMTQ2&","bulk_download_file_name":"Determination_of_purine_derivatives_in_b.pdf","bulk_download_url":"https://d1wqtxts1xzle7.cloudfront.net/88734355/AZ_2012-4_05_20Vlassa-libre.pdf?1658167457=\u0026response-content-disposition=attachment%3B+filename%3DDetermination_of_purine_derivatives_in_b.pdf\u0026Expires=1732432990\u0026Signature=COjP62E7kR3Akq3HonWkZ0mNwgCic6yzF1iP0Ym1CLodh7RgyQbrYznpIoRRRAq1XfHUgFMTxMvh7ktgNpYFKOHP3ySbvhUgVPEEc~y69Xlx-yVvWErRXHiTjDFm5G0Ls4JNNWhtoqMKeJtX63p1dQyGmBLPzyoVLIN5gvRWA~5-VqOgbNkH3hkSdWz-KNjmGA6P6XOy6ZGm8IWM53kCApzlyuE8t-QWnAzuUKve8LhBGOHYpEmWoqGfjnl4Uyovya7WSILoZvBYDhkOW-5la7GdNj8RHxGqfpBajs9N8rMB1-fV5Z7csoY~bK6q9QlUyBjNQJNl4yFPuP-bBY5GnQ__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA"}],"slug":"Determination_of_purine_derivatives_in_bovine_urine_using_rapid_chromatographic_techniques","translated_slug":"","page_count":12,"language":"en","content_type":"Work","owner":{"id":42735394,"first_name":"V.","middle_initials":null,"last_name":"Coman","page_name":"VComan1","domain_name":"independent","created_at":"2016-02-05T11:36:45.431-08:00","display_name":"V. 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I. Preliminary results" class="work-thumbnail" src="https://attachments.academia-assets.com/87921335/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/82109993/Horizontal_planar_dielectrochromatography_I_Preliminary_results">Horizontal planar dielectrochromatography. I. Preliminary results</a></div><div class="wp-workCard_item"><span>JPC - Journal of Planar Chromatography - Modern TLC</span><span>, 2002</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="accf9e90f199cec9597321dd9fbd7231" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":87921335,"asset_id":82109993,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/87921335/download_file?st=MTczMjQyOTM5MSw4LjIyMi4yMDguMTQ2&st=MTczMjQyOTM5MSw4LjIyMi4yMDguMTQ2&s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="82109993"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span><span id="work-strip-rankings-button-container"></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="82109993"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 82109993; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=82109993]").text(description); $(".js-view-count[data-work-id=82109993]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 82109993; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='82109993']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span><span><script>$(function() { new Works.PaperRankView({ workId: 82109993, container: "", }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-f77ea15d77ce96025a6048a514272ad8becbad23c641fc2b3bd6e24ca6ff1932.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "accf9e90f199cec9597321dd9fbd7231" } } $('.js-work-strip[data-work-id=82109993]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":82109993,"title":"Horizontal planar dielectrochromatography. 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In this paper, a horizontal chromatographic chamber has been constructed and has been used to study experimentally the principles of planar dielectrochromatography, in particular the increase of the mobile phase front velocity and the dielectrophoretic force generated at granule level on different ready-touse Macherey-Nagel plates.","publication_date":{"day":null,"month":null,"year":2002,"errors":{}},"publication_name":"JPC - Journal of Planar Chromatography - Modern TLC","grobid_abstract_attachment_id":87921335},"translated_abstract":null,"internal_url":"https://www.academia.edu/82109993/Horizontal_planar_dielectrochromatography_I_Preliminary_results","translated_internal_url":"","created_at":"2022-06-23T09:57:17.404-07:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":42735394,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[],"downloadable_attachments":[{"id":87921335,"title":"","file_type":"pdf","scribd_thumbnail_url":"https://attachments.academia-assets.com/87921335/thumbnails/1.jpg","file_name":"JPC.15.2002.6.620220623-1-1djdlf.pdf","download_url":"https://www.academia.edu/attachments/87921335/download_file?st=MTczMjQyOTM5MSw4LjIyMi4yMDguMTQ2&st=MTczMjQyOTM5MSw4LjIyMi4yMDguMTQ2&","bulk_download_file_name":"Horizontal_planar_dielectrochromatograph.pdf","bulk_download_url":"https://d1wqtxts1xzle7.cloudfront.net/87921335/JPC.15.2002.6.620220623-1-1djdlf-libre.pdf?1656003599=\u0026response-content-disposition=attachment%3B+filename%3DHorizontal_planar_dielectrochromatograph.pdf\u0026Expires=1732432991\u0026Signature=epzc6e7uPZa4PHK182O9EDIjDWlSNtmm9~5XVvSuBHtkrsRytwFiftRlQ86VA-ZjY53~VU6ORw8n~qYsXVZgbqetFEQUS3pOPzra~I00BZoCdImcYnDMzcZOHbmU6nF8Oc0cSo-rcan~MHI4cuxGKwrsfI3d5vKKRNaDqHlXQA~R4xuso0XtKO2YAVScAZ-i5pu36kHKa2TMciS3bIvZ~-kp8pB5odAx-alWodynSI0ynt7FVg-TuaCqgHpZDqt8N2wtHHv-UsIy~lEK-6UrPpqfYIOv1-v3BZr4tjMIi2zDAhWVVXv7SB8LaN0p0U-nLnltoVJK99C3F92nT7zC8w__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA"}],"slug":"Horizontal_planar_dielectrochromatography_I_Preliminary_results","translated_slug":"","page_count":4,"language":"en","content_type":"Work","owner":{"id":42735394,"first_name":"V.","middle_initials":null,"last_name":"Coman","page_name":"VComan1","domain_name":"independent","created_at":"2016-02-05T11:36:45.431-08:00","display_name":"V. 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