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(PDF) Magmatic-hydrothermal molybdenum isotope fractionation and its relevance to the igneous crustal signature | Thomas Pettke - Academia.edu

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The δ 98 Mo of the molybdenites ranges between -0.48‰ and 22 +0.40‰, with a median at -0.05‰. The median Mo isotope composition increases from early magmatic 23 (-0.29‰) to hydrothermal (-0.05‰) breccia mineralization (median bulk breccia = -0.17‰) to late 24 stockwork veining (+0.22‰). Moreover, variations of up to 0.34‰ are found between different 25 molybdenite crystals within an individual hand specimen. The rhyolite sample with 0.12 µg g -1 Mo has 26 δ 98 Mo = -0.57‰ and is lighter than all molybdenites from the Questa deposit, interpreted to represent the 27 igneous leftover after aqueous ore fluid exsolution. We recognize three Mo isotope fractionation processes 28 that occur between ca. 700 and 350°C, affecting the Mo isotope composition of magmatic-hydrothermal 29 molybdenites. ∆ 1 Mo: Minerals preferentially incorporate light Mo isotopes during progressive fractional 30 crystallization in subvolcanic magma reservoirs, leaving behind a melt enriched in heavy Mo isotopes. 31 ∆ 2 Mo: Magmatic-hydrothermal fluids preferentially incorporate heavy Mo isotopes upon fluid exsolution. 32 ∆ 3 Mo: Light Mo isotopes get preferentially incorporated in molybdenite during crystallization from an 33 aqueous fluid, leaving behind a hydrothermal fluid that gets heavier with progressive molybdenite 34 crystallization. The sum of all three fractionation processes produces molybdenites that record heavier 35 δ 98 Mo compositions than their source magmas. This implies that the mean δ 98 Mo of molybdenites 36 published so far (~0.4‰) likely represents a maximum value for the Mo isotope composition of 37 Phanerozoic igneous upper crust. 38 39","publication_date":"2014,,","grobid_abstract_attachment_id":"51030786"},"document_type":"paper","pre_hit_view_count_baseline":null,"quality":"high","language":"en","title":"Magmatic-hydrothermal molybdenum isotope fractionation and its relevance to the igneous crustal signature","broadcastable":true,"draft":null,"has_indexable_attachment":true,"indexable":true}}["work"]; window.loswp.workCoauthors = [38936760]; window.loswp.locale = "en"; window.loswp.countryCode = "SG"; window.loswp.cwvAbTestBucket = ""; window.loswp.designVariant = "ds_vanilla"; window.loswp.fullPageMobileSutdModalVariant = "control"; window.loswp.useOptimizedScribd4genScript = false; window.loswp.appleClientId = 'edu.academia.applesignon';</script><script defer="" src="https://accounts.google.com/gsi/client"></script><div 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