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Your current IP address is 8.222.208.146. </p> <div class="paragraphbreak" style="margin-top:0.5em"></div><div style="font-size: 16px;"> <p>Even while globally blocked, you will <i>usually</i> still be able to edit pages on <a href="https://meta.wikimedia.org/wiki/" class="extiw" title="m:">Meta-Wiki</a>. </p> </div> <div class="paragraphbreak" style="margin-top:0.5em"></div><div style="font-size: 16px;"> <p>If you believe you were blocked by mistake, you can find additional information and instructions in the <a href="https://meta.wikimedia.org/wiki/Special:MyLanguage/No_open_proxies" class="extiw" title="m:Special:MyLanguage/No open proxies">No open proxies</a> global policy. Otherwise, to discuss the block please <a href="https://meta.wikimedia.org/wiki/Steward_requests/Global" class="extiw" title="m:Steward requests/Global">post a request for review on Meta-Wiki</a>. You could also send an email to the <a href="https://meta.wikimedia.org/wiki/Special:MyLanguage/Stewards" class="extiw" title="m:Special:MyLanguage/Stewards">stewards</a> <a href="https://meta.wikimedia.org/wiki/Special:MyLanguage/VRT" class="extiw" title="m:Special:MyLanguage/VRT">VRT</a> queue at <kbd>stewards@wikimedia.org</kbd> including all above details. </p> </div> <p>Other useful links: <a href="https://meta.wikimedia.org/wiki/Global_blocks" class="extiw" title="m:Global blocks">Global blocks</a> · <a href="/wiki/Help:I_have_been_blocked" title="Help:I have been blocked">Help:I have been blocked</a> </p> </div></li></ul><hr /> <div id="viewsourcetext">You can view and copy the source of this page:</div><textarea readonly="" accesskey="," id="wpTextbox1" cols="80" rows="25" style="" class="mw-editfont-monospace" lang="en" dir="ltr" name="wpTextbox1">== History == Before the widespread introduction of smokeless powder the use of gunpowder or black powder caused many problems on the battlefield. Military commanders since the [[Napoleonic Wars]] reported difficulty with giving orders on a battlefield obscured by the smoke of firing. [[Flag semaphore|Visual signals]] could not be seen through the thick smoke from the [[gunpowder]] used by the guns. Unless there was a strong wind, after a few shots, soldiers using gunpowder ammunition would have their view obscured by a huge cloud of smoke, and this problem became worse with increasing rate of fire. In 1884 during the [[Battle of Tamai]] Sudanese troops were able to break the square of British infantry armed with [[Martini–Henry|Martini–Henries]] because of that.<ref>{{cite book |last=Jones |first=Karen |url=https://books.google.com/books?id=WQ3ACwAAQBAJ&pg=PA244 |title=A Cultural History of Firearms in the Age of Empire |date=2016-03-16 |publisher=Routledge |isbn=978-1-317-18850-6}}</ref> [[Sharpshooter]]s firing from concealed positions risked revealing their locations with a cloud of smoke. Gunpowder burns in a relatively inefficient process that produces lower pressures, making it about one-third as powerful as the same amount of smokeless powder.<ref name="Shell" /> A significant portion of the combustion products from gunpowder are solids that are [[hygroscopic]], i.e. they attract moisture from the air and make cleaning mandatory after every use, in order to prevent water accumulation in the barrel that can lead to corrosion and premature failure. These solids are also behind gunpowder's tendency to produce severe [[fouling]] that causes [[breech-loading]] [[Action (firearms)|actions]] to jam and can make reloading difficult. === Nitroglycerine and guncotton === [[Nitroglycerine]] was synthesized by the Italian [[chemist]] [[Ascanio Sobrero]] in 1847.<ref name="Chemistry" />{{rp|195}} It was subsequently developed and manufactured by [[Alfred Nobel]] as an industrial explosive under the trademark "[[Dynamite]]", but even then it was unsuitable as a propellant: despite its energetic and smokeless qualities, it [[detonation|detonates]] at [[supersonic speed]], as opposed to [[deflagration|deflagrating]] smoothly at subsonic speeds, making it more liable to shatter a gun barrel rather than propel a projectile out of it. Nitroglycerine is also highly shock-sensitive, making it unfit to be carried in battlefield conditions. A major step forward was the invention of [[guncotton]], a nitrocellulose-based material, by German chemist [[Christian Friedrich Schönbein]] in 1846. He promoted its use as a blasting explosive<ref name="Handloading" />{{rp|28}} and sold manufacturing rights to the [[Austrian Empire]]. Guncotton was more powerful than gunpowder, but at the same time was once again somewhat more unstable. John Taylor obtained an English patent for guncotton; and John Hall & Sons began manufacture in [[Faversham]]. English interest languished after an explosion destroyed the Faversham factory in 1847. Austrian Baron [[Wilhelm Lenk von Wolfsberg]] built two guncotton plants producing artillery propellent, but it too was dangerous under field conditions, and guns that could fire thousands of rounds using black powder would reach the end of their service life after only a few hundred shots with the more powerful guncotton. Small arms could not withstand the pressures generated by guncotton. After one of the Austrian factories blew up in 1862, [[Stowmarket Guncotton Company|Thomas Prentice & Company]] began manufacturing guncotton in [[Stowmarket]] in 1863; and British [[War Office]] chemist Sir [[Frederick Abel]] began thorough research at [[Waltham Abbey Royal Gunpowder Mills]] leading to a manufacturing process that eliminated the impurities in nitrocellulose making it safer to produce and a stable product safer to handle. Abel patented this process in 1865 when the second Austrian guncotton factory exploded. After the Stowmarket factory exploded in 1871, Waltham Abbey began production of guncotton for [[torpedo]] and [[Naval mine|mine]] warheads.<ref name="sharpe" />{{rp|141–144}} === Improvements === [[file:Poudre B.JPG|thumb|An extruded stick powder]] In 1863, [[Prussia]]n artillery captain Johann F. E. Schultze patented a small-arms propellant of nitrated hardwood impregnated with [[saltpeter]] or [[barium nitrate]]. Prentice received an 1866 patent for a sporting powder of nitrated paper manufactured at Stowmarket, but ballistic uniformity suffered as the paper absorbed atmospheric moisture. In 1871, Frederick Volkmann received an Austrian patent for a colloided version of Schultze powder called ''Collodin'', which he manufactured near Vienna for use in sporting firearms. Austrian patents were not published at the time, and the Austrian Empire considered the operation a violation of the government monopoly on explosives manufacture and closed the Volkmann factory in 1875.<ref name="sharpe" />{{rp|141–144}} In 1882, the Explosives Company at Stowmarket patented an improved formulation of nitrated cotton gelatinised by ether-alcohol with nitrates of [[potassium]] and [[barium]]. These propellants were suitable for shotguns but not rifles,<ref name="Artillery" />{{rp|138–139}} because [[rifling]] results in resistance to a smooth expansion of the gas, which is reduced in [[smoothbore]] shotguns. In 1884, [[Paul Vieille]] invented a smokeless powder called [[Poudre B]] (short for ''poudre blanche'', white powder, as distinguished from [[gunpowder|black powder]])<ref name="Chemistry" />{{rp|289–292}} made from 68.2% insoluble [[nitrocellulose]], 29.8% soluble nitrocellulose gelatinized with [[diethyl ether|ether]] and 2% paraffin. This was adopted for the [[Lebel rifle]] chambered in [[8×50mmR Lebel]].<ref name="Artillery" />{{rp|139}} It was passed through rollers to form paper-thin sheets, which were cut into flakes of the desired size.<ref name="Chemistry" />{{rp|289–292}} The resulting [[propellant]], known as ''pyrocellulose'', contains somewhat less [[nitrogen]] than [[guncotton]] does, and is less volatile. A particularly good feature of the propellant is that it will not detonate unless it is compressed, making it very safe to handle under normal conditions. Vieille's powder revolutionized the effectiveness of small guns because it gave off almost no smoke and was three times more powerful than black powder. Higher [[muzzle velocity]] meant a flatter [[trajectory]] and less wind drift and bullet drop, making {{convert|1000|m|yd|0|abbr=on}} shots practicable. Since less powder was needed to propel a bullet, the [[Cartridge (firearms)|cartridge]] could be made smaller and lighter. This allowed troops to carry more ammunition for the same weight. Also, it would burn even when wet. Black powder ammunition had to be kept dry and was almost always stored and transported in watertight cartridges. Other European countries swiftly followed and started using their own versions of Poudre B, the first being Germany and Austria, which introduced new weapons in 1888. Subsequently, Poudre B was modified several times with various compounds being added and removed. [[Krupp]] began adding [[diphenylamine]] as a stabilizer in 1888.<ref name="sharpe" />{{rp|141–144}} Meanwhile, in 1887, [[Alfred Nobel]] obtained an English patent for a smokeless gunpowder he called [[ballistite]]. In this propellant the fibrous structure of cotton (nitro-cellulose) was destroyed by a [[nitroglycerine]] solution instead of a solvent.<ref name="Artillery" />{{rp|140}} In England in 1889, a similar powder was patented by [[Hiram Maxim]], and in the United States in 1890 by [[Hudson Maxim]].<ref name="patent-430212" /> Ballistite was patented in the United States in 1891. The Germans adopted ballistite for naval use in 1898, calling it WPC/98. The Italians adopted it as ''filite'', in cord instead of flake form—but, realising its drawbacks, changed to a formulation with nitroglycerine that they called ''solenite''. In 1891 the Russians tasked the chemist [[Mendeleev]] with finding a suitable propellant. He created nitrocellulose gelatinised by ether-alcohol, which produced more [[nitrogen]] and more uniform colloidal structure than the French use of nitro-cottons<ref name="smokeless powder" /> in Poudre B. He called it [[pyrocollodion]].<ref name="Artillery" />{{rp|140}} [[file:Cordite Filled Cartridge.JPG|thumb|Close-up of Cordite filaments in a [[.303 British]] rifle cartridge (manufactured in 1964)]] Britain conducted trials on all the various types of propellant brought to its attention, but was dissatisfied with them all and sought something superior to all existing types. In 1889, Sir [[Frederick Abel]], [[James Dewar]] and Dr W Kellner patented (Nos 5614 and 11,664 in the names of Abel and Dewar) a new formulation that was manufactured at the Royal Gunpowder Factory at Waltham Abbey. It entered British service in 1891 as [[Cordite]] Mark 1. Its main composition was 58% [[nitroglycerine]], 37% [[guncotton]] and 3% [[Petroleum jelly|mineral jelly]]. A modified version, Cordite MD, entered service in 1901, with the guncotton percentage increased to 65% and nitroglycerine reduced to 30%. This change reduced the combustion temperature and hence erosion and barrel wear. Cordite's advantages over gunpowder were reduced maximum pressure in the chamber (hence lighter breeches, etc.) but longer high pressure. Cordite could be made in any desired shape or size.<ref name="Artillery" />{{rp|141}} The creation of cordite led to a lengthy court battle between Nobel, Maxim, and another inventor over alleged British [[patent]] infringement. The Anglo-American Explosives Company began manufacturing its shotgun powder in [[Oakland, New Jersey]], in 1890. [[DuPont]] began producing guncotton at [[Carneys Point Township, New Jersey]], in 1891.<ref name="sharpe" />{{rp|146–149}} Charles E. Munroe of the [[Naval Torpedo Station]] in [[Newport, Rhode Island]], patented a formulation of guncotton colloided with nitrobenzene, called ''Indurite'', in 1891.<ref name="Chemistry" />{{rp|296–297}} Several United States firms began producing smokeless powder when [[Winchester Repeating Arms Company]] started loading sporting cartridges with Explosives Company powder in 1893. [[California Powder Works]] began producing a mixture of nitroglycerine and [[nitrocellulose]] with [[ammonium picrate]] as ''Peyton Powder'', Leonard Smokeless Powder Company began producing nitroglycerine–nitrocellulose ''Ruby'' powders, [[Laflin & Rand Powder Company|Laflin & Rand]] negotiated a license to produce ''Ballistite'', and DuPont started producing smokeless shotgun powder. The [[United States Army]] evaluated 25 varieties of smokeless powder and selected ''Ruby'' and ''Peyton Powders'' as the most suitable for use in the [[Krag–Jørgensen]] service rifle. ''Ruby'' was preferred, because tin-plating was required to protect brass cartridge cases from [[picric acid]] in the ''Peyton Powder''. Rather than paying the required royalties for ''Ballistite'', Laflin & Rand financed Leonard's reorganization as the American Smokeless Powder Company. United States Army Lieutenant Whistler assisted American Smokeless Powder Company factory superintendent Aspinwall in formulating an improved powder named W.A. for their efforts. W.A. smokeless powder was the standard for United States military service rifles from 1897 until 1908.<ref name="sharpe" />{{rp|146–149}} In 1897, United States Navy Lieutenant [[John Bernadou]] patented a nitrocellulose powder colloided with ether-alcohol.<ref name="Chemistry" />{{rp|296–297}} The Navy licensed or sold patents for this formulation to [[DuPont]] and the California Powder Works while retaining manufacturing rights for the [[Naval Powder Factory, Indian Head, Maryland]] constructed in 1900. The United States Army adopted the Navy single-base formulation in 1908 and began manufacture at [[Picatinny Arsenal]].<ref name="sharpe" />{{rp|146–149}} By that time Laflin & Rand had taken over the American Powder Company to protect their investment, and Laflin & Rand had been purchased by DuPont in 1902.<ref name="dupont" /> Upon securing a 99-year lease of the Explosives Company in 1903, DuPont enjoyed use of all significant smokeless powder patents in the United States, and was able to optimize production of smokeless powder.<ref name="sharpe" />{{rp|146–149}} When government anti-trust action forced divestiture in 1912, DuPont retained the nitrocellulose smokeless powder formulations used by the United States military and released the double-base formulations used in sporting ammunition to the reorganized [[Hercules Powder Company]]. These newer and more powerful propellants were more stable and thus safer to handle than Poudre B. </textarea><div class="templatesUsed"></div><p id="mw-returnto">Return to <a href="/wiki/Smokeless_powder" title="Smokeless powder">Smokeless powder</a>.</p> <!--esi <esi:include src="/esitest-fa8a495983347898/content" /> --><noscript><img src="https://login.wikimedia.org/wiki/Special:CentralAutoLogin/start?type=1x1&useformat=desktop" alt="" width="1" height="1" style="border: none; position: absolute;"></noscript> <div class="printfooter" data-nosnippet="">Retrieved from "<a dir="ltr" href="https://en.wikipedia.org/wiki/Smokeless_powder">https://en.wikipedia.org/wiki/Smokeless_powder</a>"</div></div> <div id="catlinks" class="catlinks catlinks-allhidden" data-mw="interface"></div> </div> </main> </div> <div class="mw-footer-container"> <footer id="footer" class="mw-footer" > <ul id="footer-info"> </ul> <ul id="footer-places"> <li id="footer-places-privacy"><a href="https://foundation.wikimedia.org/wiki/Special:MyLanguage/Policy:Privacy_policy">Privacy policy</a></li> <li id="footer-places-about"><a href="/wiki/Wikipedia:About">About Wikipedia</a></li> <li id="footer-places-disclaimers"><a href="/wiki/Wikipedia:General_disclaimer">Disclaimers</a></li> <li id="footer-places-contact"><a href="//en.wikipedia.org/wiki/Wikipedia:Contact_us">Contact Wikipedia</a></li> <li id="footer-places-wm-codeofconduct"><a href="https://foundation.wikimedia.org/wiki/Special:MyLanguage/Policy:Universal_Code_of_Conduct">Code of Conduct</a></li> <li id="footer-places-developers"><a href="https://developer.wikimedia.org">Developers</a></li> <li id="footer-places-statslink"><a href="https://stats.wikimedia.org/#/en.wikipedia.org">Statistics</a></li> <li id="footer-places-cookiestatement"><a href="https://foundation.wikimedia.org/wiki/Special:MyLanguage/Policy:Cookie_statement">Cookie statement</a></li> <li id="footer-places-mobileview"><a href="//en.m.wikipedia.org/w/index.php?title=Smokeless_powder&action=edit&section=1&mobileaction=toggle_view_mobile" class="noprint stopMobileRedirectToggle">Mobile view</a></li> </ul> <ul id="footer-icons" class="noprint"> <li id="footer-copyrightico"><a href="https://wikimediafoundation.org/" class="cdx-button cdx-button--fake-button cdx-button--size-large cdx-button--fake-button--enabled"><img src="/static/images/footer/wikimedia-button.svg" width="84" height="29" alt="Wikimedia Foundation" loading="lazy"></a></li> <li id="footer-poweredbyico"><a href="https://www.mediawiki.org/" class="cdx-button cdx-button--fake-button cdx-button--size-large cdx-button--fake-button--enabled"><img src="/w/resources/assets/poweredby_mediawiki.svg" alt="Powered by MediaWiki" width="88" height="31" loading="lazy"></a></li> </ul> </footer> </div> </div> </div> <div class="vector-settings" id="p-dock-bottom"> <ul></ul> </div><script>(RLQ=window.RLQ||[]).push(function(){mw.config.set({"wgHostname":"mw-web.codfw.main-5c59558b9d-pkbbq","wgBackendResponseTime":271,"wgPageParseReport":{"limitreport":{"cputime":"0.069","walltime":"0.092","ppvisitednodes":{"value":418,"limit":1000000},"postexpandincludesize":{"value":17740,"limit":2097152},"templateargumentsize":{"value":6556,"limit":2097152},"expansiondepth":{"value":9,"limit":100},"expensivefunctioncount":{"value":0,"limit":500},"unstrip-depth":{"value":0,"limit":20},"unstrip-size":{"value":469,"limit":5000000},"entityaccesscount":{"value":0,"limit":400},"timingprofile":["100.00% 64.241 1 -total"," 99.87% 64.157 2 Template:Blocked_text"," 41.66% 26.765 2 Template:Replace"," 38.94% 25.017 1 Template:Colocationwebhost"," 35.25% 22.642 1 Template:Hidden"," 14.85% 9.537 1 Template:Tlx"," 14.33% 9.206 1 Template:Hidden_begin"," 3.35% 2.153 1 MediaWiki:Wikimedia-globalblocking-blockedtext-mistake"," 1.96% 1.258 1 Template:Hidden_end"," 1.88% 1.209 1 MediaWiki:Wikimedia-globalblocking-blockedtext-mistake-email-steward"]},"scribunto":{"limitreport-timeusage":{"value":"0.014","limit":"10.000"},"limitreport-memusage":{"value":1043317,"limit":52428800}},"cachereport":{"origin":"mw-web.codfw.main-5c59558b9d-pkbbq","timestamp":"20241201032907","ttl":2592000,"transientcontent":false}}});});</script> </body> </html>