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</div> </div> <div class="vector-sticky-pinned-container"> <nav id="mw-panel-toc" aria-label="目录" data-event-name="ui.sidebar-toc" class="mw-table-of-contents-container vector-toc-landmark"> <div id="vector-toc-pinned-container" class="vector-pinned-container"> <div id="vector-toc" class="vector-toc vector-pinnable-element"> <div class="vector-pinnable-header vector-toc-pinnable-header vector-pinnable-header-pinned" data-feature-name="toc-pinned" data-pinnable-element-id="vector-toc" > <h2 class="vector-pinnable-header-label">目录</h2> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-pin-button" data-event-name="pinnable-header.vector-toc.pin">移至侧栏</button> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-unpin-button" data-event-name="pinnable-header.vector-toc.unpin">隐藏</button> </div> <ul class="vector-toc-contents" id="mw-panel-toc-list"> <li id="toc-mw-content-text" class="vector-toc-list-item vector-toc-level-1"> <a href="#" class="vector-toc-link"> <div class="vector-toc-text">序言</div> </a> </li> <li id="toc-制备" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#制备"> <div class="vector-toc-text"> <span class="vector-toc-numb">1</span> <span>制备</span> </div> </a> <button aria-controls="toc-制备-sublist" class="cdx-button cdx-button--weight-quiet cdx-button--icon-only vector-toc-toggle"> <span class="vector-icon mw-ui-icon-wikimedia-expand"></span> <span>开关制备子章节</span> </button> <ul id="toc-制备-sublist" class="vector-toc-list"> <li id="toc-P4S3" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#P4S3"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.1</span> <span>P<sub>4</sub>S<sub>3</sub></span> </div> </a> <ul id="toc-P4S3-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-P4S4" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#P4S4"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.2</span> <span>P<sub>4</sub>S<sub>4</sub></span> </div> </a> <ul id="toc-P4S4-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-P4S5" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#P4S5"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.3</span> <span>P<sub>4</sub>S<sub>5</sub></span> </div> </a> <ul id="toc-P4S5-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-P4S6" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#P4S6"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.4</span> <span>P<sub>4</sub>S<sub>6</sub></span> </div> </a> <ul id="toc-P4S6-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-P4S7" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#P4S7"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.5</span> <span>P<sub>4</sub>S<sub>7</sub></span> </div> </a> <ul id="toc-P4S7-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-P4S8" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#P4S8"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.6</span> <span>P<sub>4</sub>S<sub>8</sub></span> </div> </a> <ul id="toc-P4S8-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-P4S9" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#P4S9"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.7</span> <span>P<sub>4</sub>S<sub>9</sub></span> </div> </a> <ul id="toc-P4S9-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-P4S10" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#P4S10"> <div class="vector-toc-text"> <span class="vector-toc-numb">1.8</span> <span>P<sub>4</sub>S<sub>10</sub></span> </div> </a> <ul id="toc-P4S10-sublist" class="vector-toc-list"> </ul> </li> </ul> </li> <li id="toc-参考资料" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#参考资料"> <div class="vector-toc-text"> <span class="vector-toc-numb">2</span> <span>参考资料</span> </div> </a> <ul id="toc-参考资料-sublist" class="vector-toc-list"> </ul> </li> </ul> </div> </div> </nav> </div> </div> <div class="mw-content-container"> <main id="content" class="mw-body"> <header class="mw-body-header vector-page-titlebar"> <nav aria-label="目录" class="vector-toc-landmark"> <div id="vector-page-titlebar-toc" class="vector-dropdown vector-page-titlebar-toc vector-button-flush-left" > <input type="checkbox" id="vector-page-titlebar-toc-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-page-titlebar-toc" class="vector-dropdown-checkbox " aria-label="开关目录" > <label id="vector-page-titlebar-toc-label" for="vector-page-titlebar-toc-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only " aria-hidden="true" ><span class="vector-icon mw-ui-icon-listBullet mw-ui-icon-wikimedia-listBullet"></span> <span class="vector-dropdown-label-text">开关目录</span> </label> <div class="vector-dropdown-content"> <div id="vector-page-titlebar-toc-unpinned-container" class="vector-unpinned-container"> </div> </div> </div> </nav> <h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">磷的硫化物</span></h1> <div id="p-lang-btn" class="vector-dropdown mw-portlet mw-portlet-lang" > <input type="checkbox" id="p-lang-btn-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-p-lang-btn" class="vector-dropdown-checkbox mw-interlanguage-selector" aria-label="前往另一种语言写成的文章。6种语言可用" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-6" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">6种语言</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D9%83%D8%A8%D8%B1%D9%8A%D8%AA%D9%8A%D8%AF_%D8%A7%D9%84%D9%81%D8%B3%D9%81%D9%88%D8%B1" title="كبريتيد الفسفور – 阿拉伯语" lang="ar" hreflang="ar" data-title="كبريتيد الفسفور" data-language-autonym="العربية" data-language-local-name="阿拉伯语" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-en mw-list-item"><a href="https://en.wikipedia.org/wiki/Phosphorus_sulfides" title="Phosphorus sulfides – 英语" lang="en" hreflang="en" data-title="Phosphorus sulfides" data-language-autonym="English" data-language-local-name="英语" class="interlanguage-link-target"><span>English</span></a></li><li class="interlanguage-link interwiki-it mw-list-item"><a href="https://it.wikipedia.org/wiki/Solfuro_di_fosforo" title="Solfuro di fosforo – 意大利语" lang="it" hreflang="it" data-title="Solfuro di fosforo" data-language-autonym="Italiano" data-language-local-name="意大利语" class="interlanguage-link-target"><span>Italiano</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E7%A1%AB%E5%8C%96%E3%83%AA%E3%83%B3" title="硫化リン – 日语" lang="ja" hreflang="ja" data-title="硫化リン" data-language-autonym="日本語" data-language-local-name="日语" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-sr mw-list-item"><a href="https://sr.wikipedia.org/wiki/Difosfor_trisulfid" title="Difosfor trisulfid – 塞尔维亚语" lang="sr" hreflang="sr" data-title="Difosfor trisulfid" data-language-autonym="Српски / srpski" data-language-local-name="塞尔维亚语" class="interlanguage-link-target"><span>Српски / srpski</span></a></li><li class="interlanguage-link interwiki-uk mw-list-item"><a href="https://uk.wikipedia.org/wiki/%D0%A1%D1%83%D0%BB%D1%8C%D1%84%D1%96%D0%B4%D0%B8_%D1%84%D0%BE%D1%81%D1%84%D0%BE%D1%80%D1%83" title="Сульфіди фосфору – 乌克兰语" lang="uk" hreflang="uk" data-title="Сульфіди фосфору" data-language-autonym="Українська" data-language-local-name="乌克兰语" class="interlanguage-link-target"><span>Українська</span></a></li> </ul> <div class="after-portlet after-portlet-lang"><span class="wb-langlinks-edit wb-langlinks-link"><a href="https://www.wikidata.org/wiki/Special:EntityPage/Q3964300#sitelinks-wikipedia" title="编辑跨语言链接" class="wbc-editpage">编辑链接</a></span></div> </div> </div> </div> </header> <div class="vector-page-toolbar"> <div class="vector-page-toolbar-container"> <div id="left-navigation"> <nav aria-label="命名空间"> <div id="p-associated-pages" class="vector-menu vector-menu-tabs mw-portlet mw-portlet-associated-pages" > <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li id="ca-nstab-main" class="selected vector-tab-noicon mw-list-item"><a href="/wiki/%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9" title="浏览条目正文[c]" accesskey="c"><span>条目</span></a></li><li id="ca-talk" class="vector-tab-noicon mw-list-item"><a href="/wiki/Talk:%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9" rel="discussion" title="关于此页面的讨论[t]" accesskey="t"><span>讨论</span></a></li> </ul> </div> </div> <div id="vector-variants-dropdown" class="vector-dropdown " > <input type="checkbox" id="vector-variants-dropdown-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-variants-dropdown" class="vector-dropdown-checkbox " aria-label="更改语言变体" > <label id="vector-variants-dropdown-label" for="vector-variants-dropdown-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet" aria-hidden="true" ><span class="vector-dropdown-label-text">不转换</span> </label> <div class="vector-dropdown-content"> <div id="p-variants" class="vector-menu mw-portlet mw-portlet-variants" > <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li id="ca-varlang-0" class="selected ca-variants-zh mw-list-item"><a href="/zh/%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9" lang="zh" hreflang="zh"><span>不转换</span></a></li><li id="ca-varlang-1" class="ca-variants-zh-Hans mw-list-item"><a href="/zh-hans/%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9" lang="zh-Hans" hreflang="zh-Hans"><span>简体</span></a></li><li id="ca-varlang-2" class="ca-variants-zh-Hant mw-list-item"><a href="/zh-hant/%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9" lang="zh-Hant" hreflang="zh-Hant"><span>繁體</span></a></li><li id="ca-varlang-3" class="ca-variants-zh-Hans-CN mw-list-item"><a href="/zh-cn/%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9" lang="zh-Hans-CN" hreflang="zh-Hans-CN"><span>大陆简体</span></a></li><li id="ca-varlang-4" class="ca-variants-zh-Hant-HK mw-list-item"><a href="/zh-hk/%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9" lang="zh-Hant-HK" hreflang="zh-Hant-HK"><span>香港繁體</span></a></li><li id="ca-varlang-5" class="ca-variants-zh-Hant-MO mw-list-item"><a href="/zh-mo/%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9" lang="zh-Hant-MO" hreflang="zh-Hant-MO"><span>澳門繁體</span></a></li><li id="ca-varlang-6" class="ca-variants-zh-Hans-MY mw-list-item"><a href="/zh-my/%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9" lang="zh-Hans-MY" hreflang="zh-Hans-MY"><span>大马简体</span></a></li><li id="ca-varlang-7" class="ca-variants-zh-Hans-SG mw-list-item"><a href="/zh-sg/%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9" lang="zh-Hans-SG" hreflang="zh-Hans-SG"><span>新加坡简体</span></a></li><li id="ca-varlang-8" class="ca-variants-zh-Hant-TW mw-list-item"><a href="/zh-tw/%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9" lang="zh-Hant-TW" hreflang="zh-Hant-TW"><span>臺灣正體</span></a></li> </ul> </div> </div> </div> </div> </nav> </div> <div id="right-navigation" class="vector-collapsible"> <nav aria-label="查看"> <div id="p-views" class="vector-menu vector-menu-tabs mw-portlet mw-portlet-views" > <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li id="ca-view" class="selected vector-tab-noicon mw-list-item"><a href="/wiki/%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9"><span>阅读</span></a></li><li id="ca-edit" class="vector-tab-noicon mw-list-item"><a href="/w/index.php?title=%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9&action=edit" title="编辑该页面[e]" accesskey="e"><span>编辑</span></a></li><li id="ca-history" class="vector-tab-noicon mw-list-item"><a href="/w/index.php?title=%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9&action=history" title="本页面的早前版本。[h]" accesskey="h"><span>查看历史</span></a></li> </ul> </div> </div> </nav> <nav class="vector-page-tools-landmark" aria-label="页面工具"> <div id="vector-page-tools-dropdown" class="vector-dropdown vector-page-tools-dropdown" > <input 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</div> </nav> </div> </div> <div id="bodyContent" class="vector-body" aria-labelledby="firstHeading" data-mw-ve-target-container> <div class="vector-body-before-content"> <div class="mw-indicators"> </div> <div id="siteSub" class="noprint">维基百科，自由的百科全书</div> </div> <div id="contentSub"><div id="mw-content-subtitle"></div></div> <div id="mw-content-text" class="mw-body-content"><div class="mw-content-ltr mw-parser-output" lang="zh" dir="ltr"><p><b>磷的硫化物</b>是一类<a href="/wiki/%E6%97%A0%E6%9C%BA%E5%8C%96%E5%90%88%E7%89%A9" title="无机化合物">无机化合物</a>，只由<a href="/wiki/%E7%A3%B7" title="磷">磷</a>和<a href="/wiki/%E7%A1%AB" title="硫">硫</a>组成，通式为 P<sub>4</sub>S<sub>x</sub>（<i>x</i> ≤ 10）。其中两种磷的硫化物具有商业意义：<a href="/wiki/%E5%8D%81%E7%A1%AB%E5%8C%96%E5%9B%9B%E7%A3%B7" class="mw-redirect" title="十硫化四磷">十硫化四磷</a> (P<sub>4</sub>S<sub>10</sub>)的产量达到千吨规模，用于生产有机硫化合物；而<a href="/wiki/%E4%B8%89%E7%A1%AB%E5%8C%96%E5%9B%9B%E7%A3%B7" title="三硫化四磷">三硫化四磷</a> (P<sub>4</sub>S<sub>3</sub>)可用于制造<a href="/wiki/%E7%81%AB%E6%9F%B4" title="火柴">火柴</a>。 </p><p>除了 P<sub>4</sub>S<sub>3</sub> 和P<sub>4</sub>S<sub>10</sub>以外，还存在多种磷的硫化物。其中六种有<a href="/wiki/%E5%BC%82%E6%9E%84%E4%BD%93" class="mw-redirect" title="异构体">异构体</a>：P<sub>4</sub>S<sub>4</sub>、P<sub>4</sub>S<sub>5</sub>、P<sub>4</sub>S<sub>6</sub>、P<sub>4</sub>S<sub>7</sub>、P<sub>4</sub>S<sub>8</sub>和 P<sub>4</sub>S<sub>9</sub>。它们的异构体以希腊字母前缀区别。这些前缀是以发现顺序排列的，而不是结构。<sup id="cite_ref-1" class="reference"><a href="#cite_note-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> 所有已知的磷的硫化物分子的四个磷原子都为四面体型排列（类似<a href="/wiki/%E7%99%BD%E7%A3%B7" title="白磷">白磷</a>）。<sup id="cite_ref-2" class="reference"><a href="#cite_note-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> P<sub>4</sub>S<sub>2</sub> 也是已知的，不过在 −30 °C以上不稳定。<sup id="cite_ref-3" class="reference"><a href="#cite_note-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> </p> <figure class="mw-halign-center" typeof="mw:File/Thumb"><a href="/wiki/File:LowResP-Srings.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/6/6e/LowResP-Srings.png/500px-LowResP-Srings.png" decoding="async" width="500" height="528" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/6/6e/LowResP-Srings.png/750px-LowResP-Srings.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/6/6e/LowResP-Srings.png/1000px-LowResP-Srings.png 2x" data-file-width="1387" data-file-height="1464" /></a><figcaption>所有磷的硫化物的异构体</figcaption></figure> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="制备"><span id=".E5.88.B6.E5.A4.87"></span>制备</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9&action=edit&section=1" title="编辑章节：制备"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>磷的硫化物的主要制备方法是加热磷和硫的混合物。产物可以由 <sup>31</sup>P <a href="/wiki/%E6%A0%B8%E7%A3%81%E5%85%B1%E6%8C%AF%E6%B3%A2%E8%B0%B1%E6%B3%95" class="mw-redirect" title="核磁共振波谱法">核磁共振波谱法</a>分析。更具选择性的合成需要用<a href="/wiki/%E4%B8%89%E8%8B%AF%E5%9F%BA%E8%86%A6" title="三苯基膦">三苯基膦</a>脱硫，或是用<a href="/w/index.php?title=%E7%A1%AB%E5%8C%96%E4%B8%89%E8%8B%AF%E5%9F%BA%E8%83%82&action=edit&redlink=1" class="new" title="硫化三苯基胂（页面不存在）">硫化三苯基胂</a>硫化。<sup id="cite_ref-Jason_4-0" class="reference"><a href="#cite_note-Jason-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-5" class="reference"><a href="#cite_note-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="P4S3">P<sub>4</sub>S<sub>3</sub></h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9&action=edit&section=2" title="编辑章节：P4S3"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <style data-mw-deduplicate="TemplateStyles:r84833064">.mw-parser-output .hatnote{font-size:small}.mw-parser-output div.hatnote{padding-left:2em;margin-bottom:0.8em;margin-top:0.8em}.mw-parser-output .hatnote-notice-img::after{content:"\202f \202f \202f \202f "}.mw-parser-output .hatnote-notice-img-small::after{content:"\202f \202f "}.mw-parser-output .hatnote+link+.hatnote{margin-top:-0.5em}body.skin-minerva .mw-parser-output .hatnote-notice-img,body.skin-minerva .mw-parser-output .hatnote-notice-img-small{display:none}@media print{body.ns-0 .mw-parser-output .hatnote{display:none!important}}</style><div role="note" class="hatnote navigation-not-searchable">主条目：<a href="/wiki/%E4%B8%89%E7%A1%AB%E5%8C%96%E5%9B%9B%E7%A3%B7" title="三硫化四磷">三硫化四磷</a></div> <p><a href="/wiki/%E4%B8%89%E7%A1%AB%E5%8C%96%E5%9B%9B%E7%A3%B7" title="三硫化四磷">三硫化四磷</a>可以由红磷和硫在 450 K以上反应，<sup id="cite_ref-InorgChem_6-0" class="reference"><a href="#cite_note-InorgChem-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup> 然后用<a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E7%A2%B3" title="二硫化碳">二硫化碳</a>和<a href="/wiki/%E8%8B%AF" title="苯">苯</a>小心地<a href="/wiki/%E9%87%8D%E7%BB%93%E6%99%B6" title="重结晶">重结晶</a>。另一种制备方法是将白磷和硫在惰性、不易燃的溶剂里反应而成。<sup id="cite_ref-7" class="reference"><a href="#cite_note-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="P4S4">P<sub>4</sub>S<sub>4</sub></h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9&action=edit&section=3" title="编辑章节：P4S4"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>α型和β型的 P<sub>4</sub>S<sub>4</sub>可以由 P<sub>4</sub>S<sub>3</sub>I<sub>2</sub> 的对应异构体和((CH<sub>3</sub>)<sub>3</sub>Sn)<sub>2</sub>S 反应而成：<sup id="cite_ref-InorgChem_6-1" class="reference"><a href="#cite_note-InorgChem-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup> </p> <figure class="mw-halign-none" typeof="mw:File"><a href="/wiki/File:Preparation_scheme_of_P4S4_isomeric_forms.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/a/ad/Preparation_scheme_of_P4S4_isomeric_forms.png/600px-Preparation_scheme_of_P4S4_isomeric_forms.png" decoding="async" width="600" height="271" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/a/ad/Preparation_scheme_of_P4S4_isomeric_forms.png/900px-Preparation_scheme_of_P4S4_isomeric_forms.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/a/ad/Preparation_scheme_of_P4S4_isomeric_forms.png/1200px-Preparation_scheme_of_P4S4_isomeric_forms.png 2x" data-file-width="4010" data-file-height="1814" /></a><figcaption></figcaption></figure> <p>反应前体 P<sub>4</sub>S<sub>3</sub>I<sub>2</sub> 则可以由化学计量的磷、硫和碘反应而成。 </p> <div class="mw-heading mw-heading3"><h3 id="P4S5">P<sub>4</sub>S<sub>5</sub></h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9&action=edit&section=4" title="编辑章节：P4S5"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>P<sub>4</sub>S<sub>5</sub> 可以由化学计量的 P<sub>4</sub>S<sub>3</sub> 和硫的二硫化碳溶液在光照和催化量的<a href="/wiki/%E7%A2%98" title="碘">碘</a>下反应而成。<sup id="cite_ref-8" class="reference"><a href="#cite_note-8"><span class="cite-bracket">[</span>8<span class="cite-bracket">]</span></a></sup>产物可以通过使用<span class="ilh-all" data-orig-title="磷-31核磁共振波谱法" data-lang-code="en" data-lang-name="英语" data-foreign-title="31P NMR spectroscopy"><span class="ilh-page"><a href="/w/index.php?title=%E7%A3%B7-31%E6%A0%B8%E7%A3%81%E5%85%B1%E6%8C%AF%E6%B3%A2%E8%B0%B1%E6%B3%95&action=edit&redlink=1" class="new" title="磷-31核磁共振波谱法（页面不存在）">磷-31核磁共振波谱法</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">英语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://en.wikipedia.org/wiki/31P_NMR_spectroscopy" class="extiw" title="en:31P NMR spectroscopy"><span lang="en" dir="auto">31P NMR spectroscopy</span></a></span>）</span></span>分析。 </p><p>α-P<sub>4</sub>S<sub>5</sub> 可以通过 P<sub>4</sub>S<sub>10</sub>和红磷的<a href="/wiki/%E5%85%89%E5%8C%96%E5%AD%A6%E5%8F%8D%E5%BA%94" class="mw-redirect" title="光化学反应">光化学反应</a>而成。<sup id="cite_ref-InorgChem_6-2" class="reference"><a href="#cite_note-InorgChem-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup> P<sub>4</sub>S<sub>5</sub> 是对热不稳定的，会在达到熔点之前<a href="/wiki/%E6%AD%A7%E5%8C%96" class="mw-redirect" title="歧化">歧化</a>成 P<sub>4</sub>S<sub>3</sub> 和 P<sub>4</sub>S<sub>7</sub>。<sup id="cite_ref-Elements_9-0" class="reference"><a href="#cite_note-Elements-9"><span class="cite-bracket">[</span>9<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="P4S6">P<sub>4</sub>S<sub>6</sub></h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9&action=edit&section=5" title="编辑章节：P4S6"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>P<sub>4</sub>S<sub>6</sub> 可以由 P<sub>4</sub>S<sub>7</sub> 被<a href="/wiki/%E4%B8%89%E8%8B%AF%E5%9F%BA%E8%86%A6" title="三苯基膦">三苯基膦</a>夺走一个硫原子而成：<sup id="cite_ref-InorgChem_6-3" class="reference"><a href="#cite_note-InorgChem-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup> </p> <dl><dd>P<sub>4</sub>S<sub>7</sub> + <a href="/wiki/%E8%8B%AF%E5%9F%BA" title="苯基">Ph</a><sub>3</sub>P → P<sub>4</sub>S<sub>6</sub> + <a href="/wiki/%E4%B8%89%E8%8B%AF%E5%9F%BA%E7%A1%AB%E5%8C%96%E8%86%A6" title="三苯基硫化膦">Ph<sub>3</sub>PS</a></dd></dl> <p>α-P<sub>4</sub>S<sub>5</sub> 和溶于二硫化碳的Ph<sub>3</sub>AsS 反应，也可以得到 α-P<sub>4</sub>S<sub>6</sub>。<sup id="cite_ref-Jason_4-1" class="reference"><a href="#cite_note-Jason-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup>两种新的六硫化四磷异构体δ-P<sub>4</sub>S<sub>6</sub> 和ε-P<sub>4</sub>S<sub>6</sub>可以由 α-P<sub>4</sub>S<sub>4</sub> 和溶于二硫化碳的Ph<sub>3</sub>SbS 反应而成。<sup id="cite_ref-Encyclo_10-0" class="reference"><a href="#cite_note-Encyclo-10"><span class="cite-bracket">[</span>10<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="P4S7">P<sub>4</sub>S<sub>7</sub></h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9&action=edit&section=6" title="编辑章节：P4S7"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>P<sub>4</sub>S<sub>7</sub> 可以由磷和硫直接反应而成，是最容易提纯的磷的硫化物之一。<sup id="cite_ref-11" class="reference"><a href="#cite_note-11"><span class="cite-bracket">[</span>11<span class="cite-bracket">]</span></a></sup> </p> <dl><dd>4 P + 7 S → P<sub>4</sub>S<sub>7</sub></dd></dl> <div class="mw-heading mw-heading3"><h3 id="P4S8">P<sub>4</sub>S<sub>8</sub></h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9&action=edit&section=7" title="编辑章节：P4S8"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>β-P<sub>4</sub>S<sub>8</sub>可以由 α-P<sub>4</sub>S<sub>7</sub> 和溶于二硫化碳的 Ph<sub>3</sub>AsS 反应而成，会产生α-P<sub>4</sub>S<sub>7</sub> 和β-P<sub>4</sub>S<sub>8</sub>的混合物。<sup id="cite_ref-Jason_4-2" class="reference"><a href="#cite_note-Jason-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="P4S9">P<sub>4</sub>S<sub>9</sub></h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9&action=edit&section=8" title="编辑章节：P4S9"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>P<sub>4</sub>S<sub>9</sub> 的制备有两种方法。一种方法是 P<sub>4</sub>S<sub>3</sub>和过量的硫加热反应而成。<sup id="cite_ref-InorgChem_6-4" class="reference"><a href="#cite_note-InorgChem-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup> </p><p>另一种方法则是以1:2 的比例混合P<sub>4</sub>S<sub>7</sub> 和 P<sub>4</sub>S<sub>10</sub>，会产生 P<sub>4</sub>S<sub>9</sub>。这个反应为可逆反应：<sup id="cite_ref-Encyclo_10-1" class="reference"><a href="#cite_note-Encyclo-10"><span class="cite-bracket">[</span>10<span class="cite-bracket">]</span></a></sup> </p> <dl><dd>P<sub>4</sub>S<sub>7</sub> + 2 P<sub>4</sub>S<sub>10</sub> ⇌ 3 P<sub>4</sub>S<sub>9</sub></dd></dl> <div class="mw-heading mw-heading3"><h3 id="P4S10">P<sub>4</sub>S<sub>10</sub></h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9&action=edit&section=9" title="编辑章节：P4S10"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84833064"><div role="note" class="hatnote navigation-not-searchable">主条目：<a href="/wiki/%E5%8D%81%E7%A1%AB%E5%8C%96%E5%9B%9B%E7%A3%B7" class="mw-redirect" title="十硫化四磷">十硫化四磷</a></div> <p><a href="/wiki/%E5%8D%81%E7%A1%AB%E5%8C%96%E5%9B%9B%E7%A3%B7" class="mw-redirect" title="十硫化四磷">P<sub>4</sub>S<sub>10</sub></a>是最稳定的磷的硫化物之一。它可以通过在真空管中，将白磷和硫加热到 570 K 以上而成。<sup id="cite_ref-12" class="reference"><a href="#cite_note-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup> </p> <dl><dd>P<sub>4</sub> + 10 S → P<sub>4</sub>S<sub>10</sub></dd></dl> <div class="mw-heading mw-heading2"><h2 id="参考资料"><span id=".E5.8F.82.E8.80.83.E8.B5.84.E6.96.99"></span>参考资料</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9&action=edit&section=10" title="编辑章节：参考资料"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <ol class="references"> <li id="cite_note-1"><span class="mw-cite-backlink"><b><a href="#cite_ref-1">^</a></b></span> <span class="reference-text"><cite class="citation journal">Jason, M. E.; Ngo, T.; Rahman, S. Products and Mechanisms in the Oxidation of Phosphorus by Sulfur at Low Temperature. <a href="/wiki/Inorg._Chem." class="mw-redirect" title="Inorg. Chem.">Inorg. Chem.</a> 1997, <b>36</b> (12): 2633–2640. <a rel="nofollow" class="external text" href="https://doi.org/10.1021%2Fic9614879"><span title="數位物件識別號">doi:10.1021/ic9614879</span></a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9&rft.atitle=Products+and+Mechanisms+in+the+Oxidation+of+Phosphorus+by+Sulfur+at+Low+Temperature&rft.au=Jason%2C+M.+E.&rft.au=Ngo%2C+T.&rft.au=Rahman%2C+S.&rft.date=1997&rft.genre=article&rft.issue=12&rft.jtitle=Inorg.+Chem.&rft.pages=2633-2640&rft.volume=36&rft_id=info%3Adoi%2F10.1021%2Fic9614879&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-2"><span class="mw-cite-backlink"><b><a href="#cite_ref-2">^</a></b></span> <span class="reference-text">Holleman, A. F.; Wiberg, E. <i>Inorganic Chemistry</i>. Academic Press: San Diego, 2001. <style data-mw-deduplicate="TemplateStyles:r61200749">.mw-parser-output cite.citation{font-style:inherit}.mw-parser-output .citation q{quotes:"\"""\"""'""'"}.mw-parser-output .citation .cs1-lock-free a{background:url("//upload.wikimedia.org/wikipedia/commons/thumb/6/65/Lock-green.svg/9px-Lock-green.svg.png")no-repeat;background-position:right .1em center}.mw-parser-output .citation .cs1-lock-limited a,.mw-parser-output .citation .cs1-lock-registration a{background:url("//upload.wikimedia.org/wikipedia/commons/thumb/d/d6/Lock-gray-alt-2.svg/9px-Lock-gray-alt-2.svg.png")no-repeat;background-position:right .1em center}.mw-parser-output .citation .cs1-lock-subscription a{background:url("//upload.wikimedia.org/wikipedia/commons/thumb/a/aa/Lock-red-alt-2.svg/9px-Lock-red-alt-2.svg.png")no-repeat;background-position:right .1em center}.mw-parser-output .cs1-subscription,.mw-parser-output .cs1-registration{color:#555}.mw-parser-output .cs1-subscription span,.mw-parser-output .cs1-registration span{border-bottom:1px dotted;cursor:help}.mw-parser-output .cs1-ws-icon a{background:url("//upload.wikimedia.org/wikipedia/commons/thumb/4/4c/Wikisource-logo.svg/12px-Wikisource-logo.svg.png")no-repeat;background-position:right .1em center}.mw-parser-output code.cs1-code{color:inherit;background:inherit;border:inherit;padding:inherit}.mw-parser-output .cs1-hidden-error{display:none;font-size:100%}.mw-parser-output .cs1-visible-error{font-size:100%}.mw-parser-output .cs1-maint{display:none;color:#33aa33;margin-left:0.3em}.mw-parser-output .cs1-subscription,.mw-parser-output .cs1-registration,.mw-parser-output .cs1-format{font-size:95%}.mw-parser-output .cs1-kern-left,.mw-parser-output .cs1-kern-wl-left{padding-left:0.2em}.mw-parser-output .cs1-kern-right,.mw-parser-output .cs1-kern-wl-right{padding-right:0.2em}</style><a href="/wiki/%E5%9B%BD%E9%99%85%E6%A0%87%E5%87%86%E4%B9%A6%E5%8F%B7" title="国际标准书号">ISBN</a> <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/0-12-352651-5" title="Special:网络书源/0-12-352651-5">0-12-352651-5</a>.</span> </li> <li id="cite_note-3"><span class="mw-cite-backlink"><b><a href="#cite_ref-3">^</a></b></span> <span class="reference-text">Heal, H. G. <i>The Inorganic Heterocyclic Chemistry of Sulfur, Nitrogen, and Phosphorus</i> Academic Press: London; 1980 <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r61200749"><a href="/wiki/%E5%9B%BD%E9%99%85%E6%A0%87%E5%87%86%E4%B9%A6%E5%8F%B7" title="国际标准书号">ISBN</a> <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/0-12-335680-6" title="Special:网络书源/0-12-335680-6">0-12-335680-6</a>.</span> </li> <li id="cite_note-Jason-4"><span class="mw-cite-backlink">^ <a href="#cite_ref-Jason_4-0"><sup><b>4.0</b></sup></a> <a href="#cite_ref-Jason_4-1"><sup><b>4.1</b></sup></a> <a href="#cite_ref-Jason_4-2"><sup><b>4.2</b></sup></a></span> <span class="reference-text"><cite class="citation journal">Jason, M. E. Transfer of Sulfur from Arsenic and Antimony Sulfides to Phosphorus Sulfides. Rational Syntheses of Several Less-Common P<sub>4</sub>S<sub>n</sub> Species. <a href="/wiki/Inorg._Chem." class="mw-redirect" title="Inorg. Chem.">Inorg. Chem.</a> 1997, <b>36</b> (12): 2641–2646. <a rel="nofollow" class="external text" href="https://doi.org/10.1021%2Fic9614881"><span title="數位物件識別號">doi:10.1021/ic9614881</span></a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9&rft.atitle=Transfer+of+Sulfur+from+Arsenic+and+Antimony+Sulfides+to+Phosphorus+Sulfides.+Rational+Syntheses+of+Several+Less-Common+P%3Csub%3E4%3C%2Fsub%3ES%3Csub%3En%3C%2Fsub%3E+Species&rft.au=Jason%2C+M.+E.&rft.date=1997&rft.genre=article&rft.issue=12&rft.jtitle=Inorg.+Chem.&rft.pages=2641-2646&rft.volume=36&rft_id=info%3Adoi%2F10.1021%2Fic9614881&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-5"><span class="mw-cite-backlink"><b><a href="#cite_ref-5">^</a></b></span> <span class="reference-text"><cite class="citation journal">Nowottnick, H.; Blachnik, R. Zwei neue Phosphorsulfide (Two New Phosphorus Sulfides). <a href="/w/index.php?title=Zeitschrift_f%C3%BCr_anorganische_und_allgemeine_Chemie&action=edit&redlink=1" class="new" title="Zeitschrift für anorganische und allgemeine Chemie（页面不存在）">Zeitschrift für anorganische und allgemeine Chemie</a>. 1999, <b>625</b> (12): 1966–1968. <a rel="nofollow" class="external text" href="https://doi.org/10.1002%2F%28SICI%291521-3749%28199912%29625%3A12%3C1966%3A%3AAID-ZAAC1966%3E3.0.CO%3B2-B"><span title="數位物件識別號">doi:10.1002/(SICI)1521-3749(199912)625:12<1966::AID-ZAAC1966>3.0.CO;2-B</span></a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9&rft.atitle=Zwei+neue+Phosphorsulfide+%28Two+New+Phosphorus+Sulfides%29&rft.au=Blachnik%2C+R.&rft.au=Nowottnick%2C+H.&rft.date=1999&rft.genre=article&rft.issue=12&rft.jtitle=Zeitschrift+f%C3%BCr+anorganische+und+allgemeine+Chemie&rft.pages=1966-1968&rft.volume=625&rft_id=info%3Adoi%2F10.1002%2F%28SICI%291521-3749%28199912%29625%3A12%3C1966%3A%3AAID-ZAAC1966%3E3.0.CO%3B2-B&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-InorgChem-6"><span class="mw-cite-backlink">^ <a href="#cite_ref-InorgChem_6-0"><sup><b>6.0</b></sup></a> <a href="#cite_ref-InorgChem_6-1"><sup><b>6.1</b></sup></a> <a href="#cite_ref-InorgChem_6-2"><sup><b>6.2</b></sup></a> <a href="#cite_ref-InorgChem_6-3"><sup><b>6.3</b></sup></a> <a href="#cite_ref-InorgChem_6-4"><sup><b>6.4</b></sup></a></span> <span class="reference-text"><cite class="citation book">Catherine E. Housecroft; Alan G. Sharpe. Chapter 15: The group 15 elements. Inorganic Chemistry, 3rd Edition. Pearson. 2008: 484. <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/978-0-13-175553-6" title="Special:网络书源/978-0-13-175553-6"><span title="国际标准书号">ISBN</span> 978-0-13-175553-6</a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9&rft.atitle=Chapter+15%3A+The+group+15+elements&rft.au=Alan+G.+Sharpe&rft.au=Catherine+E.+Housecroft&rft.btitle=Inorganic+Chemistry%2C+3rd+Edition&rft.date=2008&rft.genre=bookitem&rft.isbn=978-0-13-175553-6&rft.pages=484&rft.pub=Pearson&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-7"><span class="mw-cite-backlink"><b><a href="#cite_ref-7">^</a></b></span> <span class="reference-text">"Phosphorus trisulfide" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 563.</span> </li> <li id="cite_note-8"><span class="mw-cite-backlink"><b><a href="#cite_ref-8">^</a></b></span> <span class="reference-text">"Phosphorus pentasulfide" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 565.</span> </li> <li id="cite_note-Elements-9"><span class="mw-cite-backlink"><b><a href="#cite_ref-Elements_9-0">^</a></b></span> <span class="reference-text"><cite class="citation book">A. Earnshaw; Norman Greenwood. Phosphorus. Chemistry of the elements, 2nd edition. Butterworth Heinemann. 2002: 508. <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/0750633654" title="Special:网络书源/0750633654"><span title="国际标准书号">ISBN</span> 0750633654</a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9&rft.atitle=Phosphorus&rft.au=A.+Earnshaw&rft.au=Norman+Greenwood&rft.btitle=Chemistry+of+the+elements%2C+2nd+edition&rft.date=2002&rft.genre=bookitem&rft.isbn=0750633654&rft.pages=508&rft.pub=Butterworth+Heinemann&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-Encyclo-10"><span class="mw-cite-backlink">^ <a href="#cite_ref-Encyclo_10-0"><sup><b>10.0</b></sup></a> <a href="#cite_ref-Encyclo_10-1"><sup><b>10.1</b></sup></a></span> <span class="reference-text"><cite class="citation book">R. Bruce King. Phosphorus. Encyclopedia of Inorganic Chemistry, 2nd edition. Wiley. 2005: 3711. <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/9780470862100" title="Special:网络书源/9780470862100"><span title="国际标准书号">ISBN</span> 9780470862100</a>.</cite><span title="ctx_ver=Z39.88-2004&rfr_id=info%3Asid%2Fzh.wikipedia.org%3A%E7%A3%B7%E7%9A%84%E7%A1%AB%E5%8C%96%E7%89%A9&rft.atitle=Phosphorus&rft.au=R.+Bruce+King&rft.btitle=Encyclopedia+of+Inorganic+Chemistry%2C+2nd+edition&rft.date=2005&rft.genre=bookitem&rft.isbn=9780470862100&rft.pages=3711&rft.pub=Wiley&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook" class="Z3988"><span style="display:none;"> </span></span></span> </li> <li id="cite_note-11"><span class="mw-cite-backlink"><b><a href="#cite_ref-11">^</a></b></span> <span class="reference-text">"Phosphorus heptasulfide" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 566.</span> </li> <li id="cite_note-12"><span class="mw-cite-backlink"><b><a href="#cite_ref-12">^</a></b></span> <span class="reference-text">"Diphosphorus pentasulfide" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 567.</span> </li> </ol> <div class="navbox-styles"><style data-mw-deduplicate="TemplateStyles:r84265675">.mw-parser-output .hlist dl,.mw-parser-output .hlist ol,.mw-parser-output .hlist ul{margin:0;padding:0}.mw-parser-output .hlist dd,.mw-parser-output .hlist dt,.mw-parser-output .hlist li{margin:0;display:inline}.mw-parser-output .hlist.inline,.mw-parser-output .hlist.inline dl,.mw-parser-output .hlist.inline ol,.mw-parser-output .hlist.inline ul,.mw-parser-output .hlist dl dl,.mw-parser-output .hlist dl ol,.mw-parser-output .hlist dl ul,.mw-parser-output .hlist ol dl,.mw-parser-output .hlist ol ol,.mw-parser-output .hlist ol ul,.mw-parser-output .hlist ul dl,.mw-parser-output .hlist ul ol,.mw-parser-output .hlist ul ul{display:inline}.mw-parser-output .hlist .mw-empty-li{display:none}.mw-parser-output .hlist dt::after{content:" :"}.mw-parser-output .hlist dd::after,.mw-parser-output .hlist li::after{content:" · ";font-weight:bold}.mw-parser-output .hlist-pipe 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title="化合物">化合物</a></div></th></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/%E6%B0%A2%E5%8C%96%E7%89%A9" title="氢化物">氢化物</a></th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E7%A3%B7%E5%8C%96%E6%B0%A2" title="磷化氢">磷化氢</a>（PH<sub>3</sub>）</li> <li><a href="/wiki/%E4%BA%8C%E7%A3%B7%E7%83%B7" class="mw-redirect" title="二磷烷">二磷烷</a>（P<sub>2</sub>H<sub>4</sub>）</li> <li><a href="/wiki/%E4%B8%89%E8%86%A6" title="三膦">三膦</a>（P<sub>3</sub>H<sub>5</sub>）</li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/%E6%B0%A7%E5%8C%96%E7%89%A9" title="氧化物">氧化物</a></th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E4%B8%89%E6%B0%A7%E5%8C%96%E4%BA%8C%E7%A3%B7" title="三氧化二磷">三氧化二磷</a>（P<sub>4</sub>O<sub>6</sub>）</li> <li><a href="/wiki/%E4%BA%94%E6%B0%A7%E5%8C%96%E4%BA%8C%E7%A3%B7" title="五氧化二磷">五氧化二磷</a>（P<sub>4</sub>O<sub>10</sub>）</li> <li><a href="/wiki/%E7%A3%B7%E7%9A%84%E6%B0%A7%E5%8C%96%E7%89%A9" class="mw-redirect mw-disambig" title="磷的氧化物">其它</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/%E7%A1%AB%E5%8C%96%E7%89%A9" title="硫化物">硫化物</a></th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E4%B8%89%E7%A1%AB%E5%8C%96%E5%9B%9B%E7%A3%B7" title="三硫化四磷">三硫化四磷</a>（P<sub>4</sub>S<sub>3</sub>）</li> <li><a href="/wiki/%E4%BA%94%E7%A1%AB%E5%8C%96%E4%BA%8C%E7%A3%B7" title="五硫化二磷">五硫化二磷</a>（P<sub>4</sub>S<sub>10</sub>）</li> <li><a href="/w/index.php?title=%E4%B8%83%E7%A1%AB%E5%8C%96%E5%9B%9B%E7%A3%B7&action=edit&redlink=1" class="new" title="七硫化四磷（页面不存在）">七硫化四磷</a>（P<sub>4</sub>S<sub>7</sub>）</li> <li><a class="mw-selflink selflink">其它</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/%E5%8D%A4%E5%8C%96%E7%89%A9" title="卤化物">卤化物</a></th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th scope="row" class="navbox-group" style="width:1%">三卤化磷</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E4%B8%89%E6%B0%9F%E5%8C%96%E7%A3%B7" title="三氟化磷">三氟化磷</a>（PF<sub>3</sub>）</li> <li><a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E7%A3%B7" title="三氯化磷">三氯化磷</a>（PCl<sub>3</sub>）</li> <li><a href="/wiki/%E4%B8%89%E6%BA%B4%E5%8C%96%E7%A3%B7" title="三溴化磷">三溴化磷</a>（PBr<sub>3</sub>）</li> <li><a href="/wiki/%E4%B8%89%E7%A2%98%E5%8C%96%E7%A3%B7" title="三碘化磷">三碘化磷</a>（PI<sub>3</sub>）</li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">五卤化磷</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E4%BA%94%E6%B0%9F%E5%8C%96%E7%A3%B7" title="五氟化磷">五氟化磷</a>（PF<sub>5</sub>）</li> <li><a href="/wiki/%E4%BA%94%E6%B0%AF%E5%8C%96%E7%A3%B7" title="五氯化磷">五氯化磷</a>（PCl<sub>5</sub>）</li> <li><a href="/wiki/%E4%BA%94%E6%BA%B4%E5%8C%96%E7%A3%B7" title="五溴化磷">五溴化磷</a>（PBr<sub>5</sub>）</li> <li><a href="/wiki/%E4%BA%94%E7%A2%98%E5%8C%96%E7%A3%B7" title="五碘化磷">五碘化磷</a>（PI<sub>5</sub>）</li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">磷酰卤</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E4%B8%89%E6%B0%9F%E6%B0%A7%E7%A3%B7" title="三氟氧磷">三氟氧磷</a>（POF<sub>3</sub>）</li> <li><a href="/wiki/%E4%B8%89%E6%B0%AF%E6%B0%A7%E7%A3%B7" title="三氯氧磷">三氯氧磷</a>（POCl<sub>3</sub>）</li> <li><a href="/wiki/%E4%B8%89%E6%BA%B4%E6%B0%A7%E7%A3%B7" title="三溴氧磷">三溴氧磷</a>（POBr<sub>3</sub>）</li></ul> </div></td></tr></tbody></table><div></div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/%E5%90%AB%E6%B0%A7%E9%85%B8" title="含氧酸">含氧酸</a>及<a href="/w/index.php?title=%E5%90%AB%E6%B0%A7%E9%85%B8%E7%9B%90&action=edit&redlink=1" class="new" title="含氧酸盐（页面不存在）">含氧酸盐</a></th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/%E5%90%AB%E6%B0%A7%E9%85%B8" title="含氧酸">含氧酸</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E6%AC%A1%E7%A3%B7%E9%85%B8" title="次磷酸">次磷酸</a>（H<sub>3</sub>PO<sub>2</sub>）</li> <li><a href="/wiki/%E4%BA%9E%E7%A3%B7%E9%85%B8" title="亞磷酸">亚磷酸</a>（H<sub>3</sub>PO<sub>3</sub>）</li> <li><a href="/wiki/%E8%BF%9E%E4%BA%8C%E7%A3%B7%E9%85%B8" title="连二磷酸">连二磷酸</a>（H<sub>4</sub>P<sub>2</sub>O<sub>6</sub>）</li> <li><a href="/wiki/%E5%81%8F%E7%A3%B7%E9%85%B8" title="偏磷酸">偏磷酸</a>（HPO<sub>3</sub>）</li> <li><a href="/wiki/%E7%A3%B7%E9%85%B8" title="磷酸">磷酸</a>（H<sub>3</sub>PO<sub>4</sub>）</li> <li><a href="/wiki/%E7%84%A6%E7%A3%B7%E9%85%B8" title="焦磷酸">焦磷酸</a>（H<sub>4</sub>P<sub>2</sub>O<sub>7</sub>）</li> <li><a href="/w/index.php?title=%E4%BA%8C%E5%81%8F%E7%A3%B7%E9%85%B8&action=edit&redlink=1" class="new" title="二偏磷酸（页面不存在）">二偏磷酸</a>（(HPO<sub>2</sub>)<sub>2</sub>）</li> <li><a href="/w/index.php?title=%E7%8E%AF%E5%81%8F%E7%A3%B7%E9%85%B8&action=edit&redlink=1" class="new" title="环偏磷酸（页面不存在）">环偏磷酸</a></li> <li><a href="/wiki/%E8%BF%87%E7%A3%B7%E9%85%B8" class="mw-redirect" title="过磷酸">过磷酸</a></li> <li><a href="/wiki/%E5%A4%9A%E8%81%9A%E7%A3%B7%E9%85%B8" title="多聚磷酸">多聚磷酸</a>（H(OPOOH)<sub><i>n</i></sub>OH）</li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/w/index.php?title=%E5%90%AB%E6%B0%A7%E9%85%B8%E7%9B%90&action=edit&redlink=1" class="new" title="含氧酸盐（页面不存在）">含氧酸盐</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E7%A3%B7%E9%85%B8%E4%BA%8C%E6%B0%A2%E9%93%9D" title="磷酸二氢铝">磷酸二氫铝</a>（Al(H<sub>2</sub>PO<sub>4</sub>)<sub>3</sub>）</li> <li><a href="/wiki/%E7%A3%B7%E9%85%B8%E4%BA%8C%E6%B0%A2%E9%92%99" title="磷酸二氢钙">磷酸二氫钙</a>（Ca(H<sub>2</sub>PO<sub>4</sub>)<sub>2</sub>）</li> <li><a href="/wiki/%E7%A3%B7%E9%85%B8%E4%B8%80%E6%B0%AB%E9%88%A3" class="mw-redirect" title="磷酸一氫鈣">磷酸一氫鈣</a>（CaHPO<sub>4</sub>）</li> <li><a href="/wiki/%E7%A3%B7%E9%85%B8%E9%92%99" title="磷酸钙">磷酸钙</a>（Ca<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub>）</li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/w/index.php?title=%E7%BC%A9%E5%90%88%E7%9B%90&action=edit&redlink=1" class="new" title="缩合盐（页面不存在）">缩合盐</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/w/index.php?title=%E7%A0%B7%E7%A3%B7%E9%85%B8%E7%9B%90&action=edit&redlink=1" class="new" title="砷磷酸盐（页面不存在）">砷磷酸盐</a></li> <li><a href="/w/index.php?title=%E7%A1%AB%E7%A3%B7%E9%85%B8%E7%9B%90&action=edit&redlink=1" class="new" title="硫磷酸盐（页面不存在）">硫磷酸盐</a></li> <li><a href="/w/index.php?title=%E7%A1%85%E7%A3%B7%E9%85%B8%E7%9B%90&action=edit&redlink=1" class="new" title="硅磷酸盐（页面不存在）">硅磷酸盐</a></li> <li><a href="/w/index.php?title=%E9%93%AC%E7%A3%B7%E9%85%B8%E7%9B%90&action=edit&redlink=1" class="new" title="铬磷酸盐（页面不存在）">铬磷酸盐</a></li> <li><a href="/w/index.php?title=%E9%92%92%E7%A3%B7%E9%85%B8%E7%9B%90&action=edit&redlink=1" class="new" title="钒磷酸盐（页面不存在）">钒磷酸盐</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">其他</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/w/index.php?title=%E7%A1%AB%E4%BB%A3%E7%A3%B7%E9%85%B8&action=edit&redlink=1" class="new" title="硫代磷酸（页面不存在）">硫代磷酸</a></li> <li><a href="/wiki/%E6%9D%82%E5%A4%9A%E9%85%B8" title="杂多酸">杂多酸</a></li> <li><a href="/w/index.php?title=%E8%BF%87%E6%B0%A7%E7%A3%B7%E9%85%B8%E7%9B%90&action=edit&redlink=1" class="new" title="过氧磷酸盐（页面不存在）">过氧磷酸盐</a></li></ul> </div></td></tr></tbody></table><div></div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">氮磷化合物</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/w/index.php?title=%E4%B8%89%E6%B0%A8%E5%9F%BA%E7%A3%B7&action=edit&redlink=1" class="new" title="三氨基磷（页面不存在）">三氨基磷</a></li> <li><a href="/w/index.php?title=%E5%8D%95%E7%A3%B7%E6%B0%AE%E7%83%AF&action=edit&redlink=1" class="new" title="单磷氮烯（页面不存在）">单磷氮烯</a></li> <li><a href="/w/index.php?title=%E7%8E%AF%E4%BA%8C%E7%A3%B7%E6%B0%AE%E7%83%AF&action=edit&redlink=1" class="new" title="环二磷氮烯（页面不存在）">环二磷氮烯</a></li> <li><a href="/w/index.php?title=%E7%8E%AF%E8%81%9A%E7%A3%B7%E6%B0%AE%E7%83%AF&action=edit&redlink=1" class="new" title="环聚磷氮烯（页面不存在）">环聚磷氮烯</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">其他磷化合物</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E4%BA%94%E7%A1%92%E5%8C%96%E4%BA%8C%E7%A3%B7" title="五硒化二磷">五硒化二磷</a>（P<sub>2</sub>Se<sub>5</sub>）</li> <li><a href="/wiki/%E7%A3%B7%E5%8C%96%E9%93%9D" title="磷化铝">磷化铝</a>（AlP）</li> <li><a href="/wiki/Template:%E7%A3%B7%E5%8C%96%E7%89%A9" title="Template:磷化物">其它磷化物</a></li></ul> </div></td></tr></tbody></table></div> <div class="navbox-styles"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84265675"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84261037"></div><div role="navigation" class="navbox" aria-labelledby="硫化物" style="padding:3px"><table class="nowraplinks mw-collapsible mw-collapsed navbox-inner" style="border-spacing:0;background:transparent;color:inherit"><tbody><tr><th scope="col" class="collapsible-title navbox-title" colspan="2"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84265675"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84244141"><div class="navbar plainlinks hlist navbar-mini"><ul><li class="nv-view"><a href="/wiki/Template:%E7%A1%AB%E5%8C%96%E7%89%A9" title="Template:硫化物"><abbr title="查看该模板">查</abbr></a></li><li class="nv-talk"><a href="/wiki/Template_talk:%E7%A1%AB%E5%8C%96%E7%89%A9" title="Template talk:硫化物"><abbr title="讨论该模板">论</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:%E7%BC%96%E8%BE%91%E9%A1%B5%E9%9D%A2/Template:%E7%A1%AB%E5%8C%96%E7%89%A9" title="Special:编辑页面/Template:硫化物"><abbr title="编辑该模板">编</abbr></a></li></ul></div><div id="硫化物" style="font-size:110%;margin:0 5em"><b><a href="/wiki/%E7%A1%AB%E5%8C%96%E7%89%A9" title="硫化物">硫化物</a></b></div></th></tr><tr><td colspan="2" class="navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <table style="width:100%;margin:0 auto;"> <tbody><tr style="background-color:mistyrose;vertical-align:top"> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E6%B0%AB" title="硫化氫">H<sub>2</sub>S</a><br /><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E6%B0%AB" title="二硫化氫">H<sub>2</sub>S<sub>2</sub></a> </td> <td style="background-color:white;border:none"> </td> <td style="background-color:white;border:none" colspan="10" rowspan="3"> </td> <td style="background-color:white;border:none" colspan="5"> </td> <td>He </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%94%82" title="硫化锂">Li<sub>2</sub>S</a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%93%8D" title="硫化铍">BeS</a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E7%A1%BC" title="硫化硼">B<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E7%A2%B3" title="二硫化碳">CS<sub>2</sub></a><br /><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E4%B8%89%E7%A2%B3" title="二硫化三碳">C<sub>3</sub>S<sub>2</sub></a><br /><a href="/wiki/%E4%BA%8C%E7%94%B2%E7%A1%AB%E9%86%9A" title="二甲硫醚">(CH<sub>3</sub>)<sub>2</sub>S</a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%93%B5" title="硫化铵">(NH<sub>4</sub>)<sub>2</sub>S</a> </td> <td>O </td> <td>F </td> <td>Ne </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%92%A0" title="硫化钠">Na<sub>2</sub>S</a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%95%81" title="硫化镁">MgS</a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%93%9D" title="硫化铝">Al<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/%E4%B8%80%E7%A1%AB%E5%8C%96%E7%9F%BD" title="一硫化矽">SiS</a><br /><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E7%A1%85" title="二硫化硅">SiS<sub>2</sub></a> </td> <td><a href="/wiki/%E4%B8%89%E7%A1%AB%E5%8C%96%E5%9B%9B%E7%A3%B7" title="三硫化四磷">P<sub>4</sub>S<sub>3</sub></a><br /><a href="/wiki/%E4%BA%94%E7%A1%AB%E5%8C%96%E4%BA%8C%E7%A3%B7" title="五硫化二磷">P<sub>2</sub>S<sub>5</sub></a><br /><a class="mw-selflink selflink">P<sub>4</sub>S<sub>x</sub></a> </td> <td><a href="/wiki/%E7%A1%AB" title="硫">S</a> </td> <td>Cl </td> <td>Ar </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%92%BE" title="硫化钾">K<sub>2</sub>S</a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%92%99" title="硫化钙">CaS</a> </td> <td><a href="/wiki/%E4%B8%80%E7%A1%AB%E5%8C%96%E9%92%AA" title="一硫化钪">ScS</a><br /><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%92%AA" title="硫化钪">Sc<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%92%9B" title="二硫化钛">TiS<sub>2</sub></a> </td> <td><a href="/w/index.php?title=%E4%B8%80%E7%A1%AB%E5%8C%96%E9%92%92&action=edit&redlink=1" class="new" title="一硫化钒（页面不存在）">VS</a><br /><a href="/w/index.php?title=%E4%B8%89%E7%A1%AB%E5%8C%96%E4%BA%8C%E9%92%92&action=edit&redlink=1" class="new" title="三硫化二钒（页面不存在）">V<sub>2</sub>S<sub>3</sub></a><br /><a href="/w/index.php?title=%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%92%92&action=edit&redlink=1" class="new" title="二硫化钒（页面不存在）">VS<sub>2</sub></a><br /><a href="/w/index.php?title=%E4%BA%94%E7%A1%AB%E5%8C%96%E4%BA%8C%E9%92%92&action=edit&redlink=1" class="new" title="五硫化二钒（页面不存在）">V<sub>2</sub>S<sub>5</sub></a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E4%BA%9A%E9%93%AC" title="硫化亚铬">CrS</a><br /><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%93%AC" title="硫化铬">Cr<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%94%B0" title="硫化锰">MnS</a><br /><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%94%B0" title="二硫化锰">MnS<sub>2</sub></a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E4%BA%9A%E9%93%81" title="硫化亚铁">FeS</a><br /><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E4%BA%9E%E9%90%B5" title="二硫化亞鐵">FeS<sub>2</sub></a><br /><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%90%B5" title="硫化鐵">Fe<sub>2</sub>S<sub>3</sub></a><br /><a href="/wiki/%E5%9B%9B%E7%A1%AB%E5%8C%96%E4%B8%89%E9%93%81" title="四硫化三铁">Fe<sub>3</sub>S<sub>4</sub></a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%92%B4" title="硫化钴">CoS</a><br /><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%92%B4" title="二硫化钴">CoS<sub>2</sub></a><br /><a href="/wiki/%E5%9B%9B%E7%A1%AB%E5%8C%96%E4%B8%89%E9%92%B4" title="四硫化三钴">Co<sub>3</sub>S<sub>4</sub></a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%95%8D" title="硫化镍">NiS</a><br /><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%95%8D" title="二硫化镍">NiS<sub>2</sub></a><br /><a href="/w/index.php?title=%E5%9B%9B%E7%A1%AB%E5%8C%96%E4%B8%89%E9%95%8D&action=edit&redlink=1" class="new" title="四硫化三镍（页面不存在）">Ni<sub>3</sub>S<sub>4</sub></a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E4%BA%9E%E9%8A%85" title="硫化亞銅">Cu<sub>2</sub>S</a><br /><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%8A%85" title="硫化銅">CuS</a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%94%8C" title="硫化锌">ZnS</a> </td> <td><a href="/w/index.php?title=%E4%B8%80%E7%A1%AB%E5%8C%96%E4%BA%8C%E9%95%93&action=edit&redlink=1" class="new" title="一硫化二镓（页面不存在）">Ga<sub>2</sub>S</a><br /><a href="/wiki/%E4%B8%80%E7%A1%AB%E5%8C%96%E9%95%93" title="一硫化镓">GaS</a><br /><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%95%93" title="硫化镓">Ga<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/%E4%B8%80%E7%A1%AB%E5%8C%96%E9%94%97" title="一硫化锗">GeS</a><br /><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%8D%BA" title="二硫化鍺">GeS<sub>2</sub></a> </td> <td><a href="/wiki/%E4%B8%89%E7%A1%AB%E5%8C%96%E4%BA%8C%E7%A0%B7" title="三硫化二砷">As<sub>2</sub>S<sub>3</sub></a><br /><a href="/wiki/%E5%9B%9B%E7%A1%AB%E5%8C%96%E5%9B%9B%E7%A0%B7" title="四硫化四砷">As<sub>4</sub>S<sub>4</sub></a><br /><a href="/w/index.php?title=%E4%BA%94%E7%A1%AB%E5%8C%96%E4%BA%8C%E7%A0%B7&action=edit&redlink=1" class="new" title="五硫化二砷（页面不存在）">As<sub>2</sub>S<sub>5</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E7%A1%92" title="二硫化硒">SeS<sub>2</sub></a> </td> <td>Br </td> <td>Kr </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%8A%A3" title="硫化銣">Rb<sub>2</sub>S</a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%8D%B6" title="硫化鍶">SrS</a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%92%87" title="硫化钇">Y<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%94%86" title="二硫化锆">ZrS<sub>2</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%93%8C" title="二硫化铌">NbS<sub>2</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%92%BC" title="二硫化钼">MoS<sub>2</sub></a><br /><a href="/wiki/%E4%B8%89%E7%A1%AB%E5%8C%96%E9%92%BC" title="三硫化钼">MoS<sub>3</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%94%9D" title="二硫化锝">TcS<sub>2</sub></a><br /><a href="/w/index.php?title=%E4%B8%83%E7%A1%AB%E5%8C%96%E4%BA%8C%E9%94%9D&action=edit&redlink=1" class="new" title="七硫化二锝（页面不存在）"><span class="chemf nowrap">Tc<span style="line-height:1.2em;text-indent:0em;display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;font-size:70%;text-align:left"><br />2</span>S<span style="line-height:1.2em;text-indent:0em;display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;font-size:70%;text-align:left"><br />7</span></span></a> </td> <td><span class="ilh-all" data-orig-title="二硫化钌" data-lang-code="en" data-lang-name="英语" data-foreign-title="Ruthenium sulfide"><span class="ilh-page"><a href="/w/index.php?title=%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%92%8C&action=edit&redlink=1" class="new" title="二硫化钌（页面不存在）">RuS<sub>2</sub></a></span><span class="noprint ilh-comment">（<span class="ilh-lang">英语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://en.wikipedia.org/wiki/Ruthenium_sulfide" class="extiw" title="en:Ruthenium sulfide"><span lang="en" dir="auto">Ruthenium sulfide</span></a></span>）</span></span> </td> <td><a href="/wiki/%E4%B8%89%E7%A1%AB%E5%8C%96%E4%BA%8C%E9%93%91" title="三硫化二铑"><span class="chemf nowrap">Rh<span style="line-height:1.2em;text-indent:0em;display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;font-size:70%;text-align:left"><br />2</span>S<span style="line-height:1.2em;text-indent:0em;display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;font-size:70%;text-align:left"><br />3</span></span></a><br /><a href="/w/index.php?title=%E5%9B%9B%E7%A1%AB%E5%8C%96%E4%B8%89%E9%93%91&action=edit&redlink=1" class="new" title="四硫化三铑（页面不存在）">Rh<sub>3</sub>S<sub>4</sub></a><br /><a href="/w/index.php?title=%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%93%91&action=edit&redlink=1" class="new" title="二硫化铑（页面不存在）">RhS<sub>2</sub></a><br /><span class="ilh-all" data-orig-title="十五硫化十七铑" data-lang-code="ru" data-lang-name="俄语" data-foreign-title="Пентадекасульфид гептадекародия"><span class="ilh-page"><a href="/w/index.php?title=%E5%8D%81%E4%BA%94%E7%A1%AB%E5%8C%96%E5%8D%81%E4%B8%83%E9%93%91&action=edit&redlink=1" class="new" title="十五硫化十七铑（页面不存在）">Rh<sub>17</sub>S<sub>15</sub></a></span><span class="noprint ilh-comment">（<span class="ilh-lang">俄语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://ru.wikipedia.org/wiki/%D0%9F%D0%B5%D0%BD%D1%82%D0%B0%D0%B4%D0%B5%D0%BA%D0%B0%D1%81%D1%83%D0%BB%D1%8C%D1%84%D0%B8%D0%B4_%D0%B3%D0%B5%D0%BF%D1%82%D0%B0%D0%B4%D0%B5%D0%BA%D0%B0%D1%80%D0%BE%D0%B4%D0%B8%D1%8F" class="extiw" title="ru:Пентадекасульфид гептадекародия"><span lang="ru" dir="auto">Пентадекасульфид гептадекародия</span></a></span>）</span></span> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%92%AF" title="硫化钯">PdS</a><br /><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%92%AF" title="二硫化钯">PdS<sub>2</sub></a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%93%B6" title="硫化银">Ag<sub>2</sub>S</a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%95%89" title="硫化镉">CdS</a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%93%9F" title="硫化铟">In<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E4%BA%9A%E9%94%A1" title="硫化亚锡">SnS</a><br /><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%94%A1" title="二硫化锡">SnS<sub>2</sub></a> </td> <td><a href="/wiki/%E4%B8%89%E7%A1%AB%E5%8C%96%E4%BA%8C%E9%94%91" title="三硫化二锑">Sb<sub>2</sub>S<sub>3</sub></a><br /><a href="/wiki/%E4%BA%94%E7%A1%AB%E5%8C%96%E4%BA%8C%E9%94%91" title="五硫化二锑">Sb<sub>2</sub>S<sub>5</sub></a> </td> <td>Te </td> <td>I </td> <td>Xe </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%8A%AB" title="硫化銫">Cs<sub>2</sub>S</a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%92%A1" title="硫化钡">BaS</a><br /><a href="/wiki/%E5%A4%9A%E7%A1%AB%E5%8C%96%E9%92%A1" title="多硫化钡">BaS<sub>x</sub></a> </td> <td style="background-color:white;border:none"><span title="镧系元素" style="font-family: Courier, monospace;">镧系</span> </td> <td><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%93%AA" title="二硫化铪">HfS<sub>2</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%92%BD" title="二硫化钽">TaS<sub>2</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%92%A8" title="二硫化钨">WS<sub>2</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%93%BC" title="二硫化铼">ReS<sub>2</sub></a><br /><a href="/wiki/%E4%B8%83%E7%A1%AB%E5%8C%96%E4%BA%8C%E9%93%BC" title="七硫化二铼">Re<sub>2</sub>S<sub>7</sub></a> </td> <td><a href="/w/index.php?title=%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%94%87&action=edit&redlink=1" class="new" title="二硫化锇（页面不存在）">OsS<sub>2</sub></a><br /><a href="/w/index.php?title=%E5%9B%9B%E7%A1%AB%E5%8C%96%E9%94%87&action=edit&redlink=1" class="new" title="四硫化锇（页面不存在）">OsS<sub>4</sub></a> </td> <td><a href="/wiki/%E4%B8%89%E7%A1%AB%E5%8C%96%E4%BA%8C%E9%93%B1" title="三硫化二铱"><span class="chemf nowrap">Ir<span style="line-height:1.2em;text-indent:0em;display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;font-size:70%;text-align:left"><br />2</span>S<span style="line-height:1.2em;text-indent:0em;display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;font-size:70%;text-align:left"><br />3</span></span></a><br /><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%93%B1" title="二硫化铱">IrS<sub>2</sub></a> </td> <td><a href="/wiki/%E4%B8%80%E7%A1%AB%E5%8C%96%E9%93%82" title="一硫化铂">PtS</a><br /><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%93%82" title="二硫化铂">PtS<sub>2</sub></a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E4%BA%9A%E9%87%91" title="硫化亚金">Au<sub>2</sub>S</a><br /><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%87%91" title="硫化金">Au<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E6%B1%9E" title="硫化汞">HgS</a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E4%BA%9A%E9%93%8A" title="硫化亚铊">Tl<sub>2</sub>S</a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%93%85" title="硫化铅">PbS</a><br /><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%93%85" title="二硫化铅">PbS<sub>2</sub></a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%93%8B" title="硫化铋">Bi<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%92%8B" title="硫化钋">PoS</a> </td> <td>At </td> <td>Rn </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td>Fr </td> <td>Ra </td> <td style="background-color:white;border:none"><span title="锕系元素" style="font-family: Courier, monospace;">锕系</span> </td> <td>Rf </td> <td>Db </td> <td>Sg </td> <td>Bh </td> <td>Hs </td> <td>Mt </td> <td>Ds </td> <td>Rg </td> <td>Cn </td> <td>Nh </td> <td>Fl </td> <td>Mc </td> <td>Lv </td> <td>Ts </td> <td>Og </td></tr> <tr> <td style="background-color:white;border:none" rowspan="3"> </td> <td style="background-color:white;border:none" colspan="1"> </td> <td style="background-color:white;border:none">↓ </td> <td style="background-color:white;border:none" colspan="14"> </td> <td style="background-color:white;border:none" rowspan="3"> </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td style="background-color:white;border:none"><span title="镧系元素" style="font-family: Courier, monospace;">镧系</span> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%95%A7" title="硫化镧">La<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/%E4%B8%80%E7%A1%AB%E5%8C%96%E9%93%88" title="一硫化铈">CeS</a><br /><a href="/wiki/%E4%B8%89%E7%A1%AB%E5%8C%96%E4%BA%8C%E9%93%88" title="三硫化二铈">Ce<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%95%A8" title="硫化镨">Pr<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%92%95" title="硫化钕">Nd<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%92%B7" title="硫化钷">Pm<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/w/index.php?title=%E4%B8%80%E7%A1%AB%E5%8C%96%E9%92%90&action=edit&redlink=1" class="new" title="一硫化钐（页面不存在）">SmS</a><br /><a href="/wiki/%E4%B8%89%E7%A1%AB%E5%8C%96%E4%BA%8C%E9%92%90" title="三硫化二钐">Sm<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E4%BA%9A%E9%93%95" title="硫化亚铕">EuS</a><br /><a href="/w/index.php?title=%E7%A1%AB%E5%8C%96%E9%93%95&action=edit&redlink=1" class="new" title="硫化铕（页面不存在）">Eu<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/w/index.php?title=%E7%A1%AB%E5%8C%96%E9%92%86&action=edit&redlink=1" class="new" title="硫化钆（页面不存在）">Gd<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/w/index.php?title=%E7%A1%AB%E5%8C%96%E9%93%BD&action=edit&redlink=1" class="new" title="硫化铽（页面不存在）">Tb<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/w/index.php?title=%E7%A1%AB%E5%8C%96%E9%95%9D&action=edit&redlink=1" class="new" title="硫化镝（页面不存在）">Dy<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%92%AC" title="硫化钬">Ho<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/w/index.php?title=%E7%A1%AB%E5%8C%96%E9%93%92&action=edit&redlink=1" class="new" title="硫化铒（页面不存在）">Er<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%93%A5" title="硫化铥">Tm<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%95%B1" title="硫化镱">Yb<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/w/index.php?title=%E7%A1%AB%E5%8C%96%E9%95%A5&action=edit&redlink=1" class="new" title="硫化镥（页面不存在）">Lu<sub>2</sub>S<sub>3</sub></a> </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td style="background-color:white;border:none"><span title="锕系元素" style="font-family: Courier, monospace;">锕系</span> </td> <td><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%94%95" title="硫化锕">Ac<sub>2</sub>S<sub>3</sub></a> </td> <td><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%92%8D" title="二硫化钍">ThS<sub>2</sub></a> </td> <td>Pa </td> <td><span class="ilh-all" data-orig-title="一硫化鈾" data-lang-code="en" data-lang-name="英语" data-foreign-title="Uranium monosulfide"><span class="ilh-page"><a href="/w/index.php?title=%E4%B8%80%E7%A1%AB%E5%8C%96%E9%88%BE&action=edit&redlink=1" class="new" title="一硫化鈾（页面不存在）">US</a></span><span class="noprint ilh-comment">（<span class="ilh-lang">英语</span><span class="ilh-colon">：</span><span class="ilh-link"><a href="https://en.wikipedia.org/wiki/Uranium_monosulfide" class="extiw" title="en:Uranium monosulfide"><span lang="en" dir="auto">Uranium monosulfide</span></a></span>）</span></span><br /><a href="/wiki/%E4%B8%89%E7%A1%AB%E5%8C%96%E4%BA%8C%E9%93%80" title="三硫化二铀">U<sub>2</sub>S<sub>3</sub></a><br /><a href="/wiki/%E4%BA%8C%E7%A1%AB%E5%8C%96%E9%93%80" title="二硫化铀">US<sub>2</sub></a> </td> <td>Np </td> <td>Pu </td> <td>Am </td> <td>Cm </td> <td>Bk </td> <td>Cf </td> <td>Es </td> <td>Fm </td> <td>Md </td> <td>No </td> <td>Lr </td></tr></tbody></table> </div></td></tr></tbody></table></div>    </div><noscript><img src="https://login.wikimedia.org/wiki/Special:CentralAutoLogin/start?type=1x1" alt="" width="1" height="1" style="border: none; position: absolute;"></noscript> <div class="printfooter" data-nosnippet="">检索自“<a dir="ltr" href="https://zh.wikipedia.org/w/index.php?title=磷的硫化物&oldid=80149770">https://zh.wikipedia.org/w/index.php?title=磷的硫化物&oldid=80149770</a>”</div></div> <div id="catlinks" class="catlinks" data-mw="interface"><div id="mw-normal-catlinks" class="mw-normal-catlinks"><a href="/wiki/Special:%E9%A1%B5%E9%9D%A2%E5%88%86%E7%B1%BB" title="Special:页面分类">分类</a>：<ul><li><a href="/wiki/Category:%E6%97%A0%E6%9C%BA%E7%A3%B7%E5%8C%96%E5%90%88%E7%89%A9" title="Category:无机磷化合物">无机磷化合物</a></li><li><a href="/wiki/Category:%E7%A1%AB%E5%8C%96%E7%89%A9" 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