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Gillian Greenway | University of Hull - Academia.edu
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ds2-5-body-sm-bold ds2-5-body-link" href="https://independent.academia.edu/InnocentUdom">Innocent Udom</a></div></div><div class="suggested-user-card"><div class="suggested-user-card__avatar social-profile-avatar-container"><a data-nosnippet="" href="https://independent.academia.edu/manojtripathi32"><img class="profile-avatar u-positionAbsolute" alt="manoj tripathi related author profile picture" border="0" onerror="if (this.src != '//a.academia-assets.com/images/s200_no_pic.png') this.src = '//a.academia-assets.com/images/s200_no_pic.png';" width="200" height="200" src="https://0.academia-photos.com/146406449/41978460/33835488/s200_manoj.tripathi.jpg" /></a></div><div class="suggested-user-card__user-info"><a class="suggested-user-card__user-info__header ds2-5-body-sm-bold ds2-5-body-link" href="https://independent.academia.edu/manojtripathi32">manoj tripathi</a></div></div><div class="suggested-user-card"><div class="suggested-user-card__avatar social-profile-avatar-container"><a data-nosnippet="" href="https://yeungnam.academia.edu/ArghyaNarayanBanerjee"><img class="profile-avatar u-positionAbsolute" alt="Arghya Narayan Banerjee related author profile picture" border="0" onerror="if (this.src != '//a.academia-assets.com/images/s200_no_pic.png') this.src = '//a.academia-assets.com/images/s200_no_pic.png';" width="200" height="200" src="https://0.academia-photos.com/12866603/3645642/100111428/s200_arghya_narayan.banerjee.jpg" /></a></div><div class="suggested-user-card__user-info"><a class="suggested-user-card__user-info__header ds2-5-body-sm-bold ds2-5-body-link" href="https://yeungnam.academia.edu/ArghyaNarayanBanerjee">Arghya Narayan Banerjee</a><p class="suggested-user-card__user-info__subheader ds2-5-body-xs">Yeungnam University</p></div></div><div class="suggested-user-card"><div class="suggested-user-card__avatar social-profile-avatar-container"><a data-nosnippet="" href="https://independent.academia.edu/FlorinStoian"><img class="profile-avatar u-positionAbsolute" alt="Stoian Florin related author profile picture" border="0" onerror="if (this.src != '//a.academia-assets.com/images/s200_no_pic.png') this.src = '//a.academia-assets.com/images/s200_no_pic.png';" width="200" height="200" src="https://0.academia-photos.com/45857327/114337444/103615204/s200_stoian.florin.jpeg" /></a></div><div class="suggested-user-card__user-info"><a class="suggested-user-card__user-info__header ds2-5-body-sm-bold ds2-5-body-link" href="https://independent.academia.edu/FlorinStoian">Stoian Florin</a></div></div><div class="suggested-user-card"><div class="suggested-user-card__avatar social-profile-avatar-container"><a data-nosnippet="" href="https://independent.academia.edu/MohammedAlalem"><img class="profile-avatar u-positionAbsolute" alt="Mohammed Alalem related author profile picture" border="0" src="//a.academia-assets.com/images/s200_no_pic.png" /></a></div><div class="suggested-user-card__user-info"><a 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h3{font-size:16px;font-weight:500;line-height:20px}</style><div class="ri-section"><div class="ri-section-header"><span>Interests</span></div><div class="ri-tags-container"><a data-click-track="profile-user-info-expand-research-interests" data-has-card-for-ri-list="32827010" href="https://www.academia.edu/Documents/in/Sports_economics"><div id="js-react-on-rails-context" style="display:none" data-rails-context="{"inMailer":false,"i18nLocale":"en","i18nDefaultLocale":"en","href":"https://hull.academia.edu/GillianGreenway","location":"/GillianGreenway","scheme":"https","host":"hull.academia.edu","port":null,"pathname":"/GillianGreenway","search":null,"httpAcceptLanguage":null,"serverSide":false}"></div> <div class="js-react-on-rails-component" style="display:none" data-component-name="Pill" data-props="{"color":"gray","children":["Sports economics"]}" data-trace="false" data-dom-id="Pill-react-component-b15f4190-a46c-4d63-8d19-c42770d0fc11"></div> <div id="Pill-react-component-b15f4190-a46c-4d63-8d19-c42770d0fc11"></div> </a><a data-click-track="profile-user-info-expand-research-interests" data-has-card-for-ri-list="32827010" href="https://www.academia.edu/Documents/in/Fisheries_Science"><div class="js-react-on-rails-component" style="display:none" data-component-name="Pill" data-props="{"color":"gray","children":["Fisheries Science"]}" data-trace="false" data-dom-id="Pill-react-component-0f49b987-013f-47b6-bad4-3d95369e7069"></div> <div id="Pill-react-component-0f49b987-013f-47b6-bad4-3d95369e7069"></div> </a><a data-click-track="profile-user-info-expand-research-interests" data-has-card-for-ri-list="32827010" href="https://www.academia.edu/Documents/in/Chemistry"><div class="js-react-on-rails-component" style="display:none" data-component-name="Pill" data-props="{"color":"gray","children":["Chemistry"]}" data-trace="false" data-dom-id="Pill-react-component-4b151ef9-d715-4a23-945e-84a5ba4a0fc7"></div> <div id="Pill-react-component-4b151ef9-d715-4a23-945e-84a5ba4a0fc7"></div> </a></div></div></div></div><div class="right-panel-container"><div class="user-content-wrapper"><div class="uploads-container" id="social-redesign-work-container"><div class="upload-header"><h2 class="ds2-5-heading-sans-serif-xs">Uploads</h2></div><div class="documents-container backbone-social-profile-documents" style="width: 100%;"><div class="u-taCenter"></div><div class="profile--tab_content_container js-tab-pane tab-pane active" id="all"><div class="profile--tab_heading_container js-section-heading" data-section="Papers" id="Papers"><h3 class="profile--tab_heading_container">Papers by Gillian Greenway</h3></div><div class="js-work-strip profile--work_container" data-work-id="33316714"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/33316714/Photocatalytic_activity_of_surface_modified_TiO_2_RuO_2_SiO_2_nanoparticles_for_azo_dye_degradation"><img alt="Research paper thumbnail of Photocatalytic activity of surface modified TiO 2 /RuO 2 /SiO 2 nanoparticles for azo-dye degradation" class="work-thumbnail" src="https://attachments.academia-assets.com/53379416/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/33316714/Photocatalytic_activity_of_surface_modified_TiO_2_RuO_2_SiO_2_nanoparticles_for_azo_dye_degradation">Photocatalytic activity of surface modified TiO 2 /RuO 2 /SiO 2 nanoparticles for azo-dye degradation</a></div><div class="wp-workCard_item wp-workCard--coauthors"><span>by </span><span><a class="" data-click-track="profile-work-strip-authors" href="https://hull.academia.edu/ALEXIBHADON">ALEX IBHADON</a> and <a class="" data-click-track="profile-work-strip-authors" href="https://hull.academia.edu/GillianGreenway">Gillian Greenway</a></span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">SiO2/RuO2 modified high surface area titania dioxide nanoparticles prepared by hydrogen reduction...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">SiO2/RuO2 modified high surface area titania dioxide nanoparticles prepared by hydrogen reduction were examined for their catalytic properties towards the photodegradation of methyl orange (MO), a common water pollutant in the textile industry. The modified materials present enhanced photocatalytic activity and can decompose the MO faster than the unmodified TiO2. Results showed that doping with RuO2 only offered a marginal benefit over TiO2 alone. On the other hand, modification of TiO2with RuO2 and SiO2 resulted in a marked increase in the rate constant and the photodegradation efficiency. These results are consistent with the unique structural, morphologoical and surface characteristics of the composite titania dioxide/ruthenium dioxide/silicon dioxide materials. The lower the average particle size and roughness of the materials, the higher the percentage of photodecomposition and the rate constant. The surface doping and modification effects thus appears synergetic to the charge separation process and the photocatalytic results are explained on the basis of the mechanism that involves efficient separation of electron鈥揾ole pairs induced by the silicon dioxide particles. This enhances the ability of the modified TiO2 particles to effectively capture protons. Results also show that the modified nanoparticles can be used repeatedly over a long time without loss of efficiency.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="dbe5f9c34802c4330322fb95e76effd4" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":53379416,"asset_id":33316714,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/53379416/download_file?s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="33316714"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="33316714"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 33316714; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=33316714]").text(description); $(".js-view-count[data-work-id=33316714]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 33316714; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='33316714']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "dbe5f9c34802c4330322fb95e76effd4" } } $('.js-work-strip[data-work-id=33316714]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":33316714,"title":"Photocatalytic activity of surface modified TiO 2 /RuO 2 /SiO 2 nanoparticles for azo-dye degradation","translated_title":"","metadata":{"abstract":"SiO2/RuO2 modified high surface area titania dioxide nanoparticles prepared by hydrogen reduction were examined for their catalytic properties towards the photodegradation of methyl orange (MO), a common water pollutant in the textile industry. The modified materials present enhanced photocatalytic activity and can decompose the MO faster than the unmodified TiO2. Results showed that doping with RuO2 only offered a marginal benefit over TiO2 alone. On the other hand, modification of TiO2with RuO2 and SiO2 resulted in a marked increase in the rate constant and the photodegradation efficiency. These results are consistent with the unique structural, morphologoical and surface characteristics of the composite titania dioxide/ruthenium dioxide/silicon dioxide materials. The lower the average particle size and roughness of the materials, the higher the percentage of photodecomposition and the rate constant. The surface doping and modification effects thus appears synergetic to the charge separation process and the photocatalytic results are explained on the basis of the mechanism that involves efficient separation of electron鈥揾ole pairs induced by the silicon dioxide particles. This enhances the ability of the modified TiO2 particles to effectively capture protons. Results also show that the modified nanoparticles can be used repeatedly over a long time without loss of efficiency."},"translated_abstract":"SiO2/RuO2 modified high surface area titania dioxide nanoparticles prepared by hydrogen reduction were examined for their catalytic properties towards the photodegradation of methyl orange (MO), a common water pollutant in the textile industry. The modified materials present enhanced photocatalytic activity and can decompose the MO faster than the unmodified TiO2. Results showed that doping with RuO2 only offered a marginal benefit over TiO2 alone. On the other hand, modification of TiO2with RuO2 and SiO2 resulted in a marked increase in the rate constant and the photodegradation efficiency. These results are consistent with the unique structural, morphologoical and surface characteristics of the composite titania dioxide/ruthenium dioxide/silicon dioxide materials. The lower the average particle size and roughness of the materials, the higher the percentage of photodecomposition and the rate constant. The surface doping and modification effects thus appears synergetic to the charge separation process and the photocatalytic results are explained on the basis of the mechanism that involves efficient separation of electron鈥揾ole pairs induced by the silicon dioxide particles. This enhances the ability of the modified TiO2 particles to effectively capture protons. 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The modified materials present enhanced photocatalytic activity and can decompose the MO faster than the unmodified TiO2. Results showed that doping with RuO2 only offered a marginal benefit over TiO2 alone. On the other hand, modification of TiO2with RuO2 and SiO2 resulted in a marked increase in the rate constant and the photodegradation efficiency. These results are consistent with the unique structural, morphologoical and surface characteristics of the composite titania dioxide/ruthenium dioxide/silicon dioxide materials. The lower the average particle size and roughness of the materials, the higher the percentage of photodecomposition and the rate constant. The surface doping and modification effects thus appears synergetic to the charge separation process and the photocatalytic results are explained on the basis of the mechanism that involves efficient separation of electron鈥揾ole pairs induced by the silicon dioxide particles. 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Studi...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">Chromated copper arsenate (CCA) is a common wood preservative that has been used worldwide. Studies have shown that there are leaching risks of the preservative components arsenic, chromium and copper. These risks include contamination of soil and water, resulting in toxic effects to humans, animals, plants and ecosystems. This study investigates leaching of the preservative components following exposure of the wood waste as mulch to soil and water. Diffusive gradient in thin films (DGTs) were used to quantify leaching of potentially bioavailable/dissolved forms of the elements along the soil profile. Speciation of chromium was also carried out. All elements were found to leach out of the wood. The containers that included CCA-treated wood waste as a mulch leached higher levels of arsenic, chromium and copper than the controls. The distribution was highest in the top 5 cm of the soil profile and decreased with depth. DGTs proved to be a useful, novel technique for measuring in situ leaching and speciation from waste materials into the environment.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="53e22f8ec28be3453f85bd48149aa07f" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":37818251,"asset_id":5797895,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/37818251/download_file?s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="5797895"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="5797895"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 5797895; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=5797895]").text(description); $(".js-view-count[data-work-id=5797895]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 5797895; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='5797895']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "53e22f8ec28be3453f85bd48149aa07f" } } $('.js-work-strip[data-work-id=5797895]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":5797895,"title":"Diffusive gradient in thin films (DGT) for profiling leaching of CCA-treated wood waste mulch into the soil environment","translated_title":"","metadata":{"abstract":"Chromated copper arsenate (CCA) is a common wood preservative that has been used worldwide. Studies have shown that there are leaching risks of the preservative components arsenic, chromium and copper. These risks include contamination of soil and water, resulting in toxic effects to humans, animals, plants and ecosystems. This study investigates leaching of the preservative components following exposure of the wood waste as mulch to soil and water. Diffusive gradient in thin films (DGTs) were used to quantify leaching of potentially bioavailable/dissolved forms of the elements along the soil profile. Speciation of chromium was also carried out. All elements were found to leach out of the wood. The containers that included CCA-treated wood waste as a mulch leached higher levels of arsenic, chromium and copper than the controls. The distribution was highest in the top 5 cm of the soil profile and decreased with depth. DGTs proved to be a useful, novel technique for measuring in situ leaching and speciation from waste materials into the environment.","ai_title_tag":"DGT Method for Assessing CCA Wood Leaching","journal_name":"International Journal of Environmental Analytical Chemistry","publication_date":{"day":17,"month":1,"year":2014,"errors":{}}},"translated_abstract":"Chromated copper arsenate (CCA) is a common wood preservative that has been used worldwide. Studies have shown that there are leaching risks of the preservative components arsenic, chromium and copper. These risks include contamination of soil and water, resulting in toxic effects to humans, animals, plants and ecosystems. This study investigates leaching of the preservative components following exposure of the wood waste as mulch to soil and water. Diffusive gradient in thin films (DGTs) were used to quantify leaching of potentially bioavailable/dissolved forms of the elements along the soil profile. Speciation of chromium was also carried out. All elements were found to leach out of the wood. The containers that included CCA-treated wood waste as a mulch leached higher levels of arsenic, chromium and copper than the controls. The distribution was highest in the top 5 cm of the soil profile and decreased with depth. DGTs proved to be a useful, novel technique for measuring in situ leaching and speciation from waste materials into the environment.","internal_url":"https://www.academia.edu/5797895/Diffusive_gradient_in_thin_films_DGT_for_profiling_leaching_of_CCA_treated_wood_waste_mulch_into_the_soil_environment","translated_internal_url":"","created_at":"2014-01-21T21:43:20.926-08:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":138681,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[{"id":10397856,"work_id":5797895,"tagging_user_id":138681,"tagged_user_id":32827010,"co_author_invite_id":null,"email":"g***y@associates.hull.ac.uk","affiliation":"University of Hull","display_order":0,"name":"Gillian Greenway","title":"Diffusive gradient in thin films (DGT) for profiling leaching of CCA-treated wood waste mulch into the soil environment"}],"downloadable_attachments":[{"id":37818251,"title":"","file_type":"pdf","scribd_thumbnail_url":"https://attachments.academia-assets.com/37818251/thumbnails/1.jpg","file_name":"Mercer___Greenway__2014__DGT_and_CCA_leaching__IJEAC.pdf","download_url":"https://www.academia.edu/attachments/37818251/download_file","bulk_download_file_name":"Diffusive_gradient_in_thin_films_DGT_for.pdf","bulk_download_url":"https://d1wqtxts1xzle7.cloudfront.net/37818251/Mercer___Greenway__2014__DGT_and_CCA_leaching__IJEAC-libre.pdf?1433361254=\u0026response-content-disposition=attachment%3B+filename%3DDiffusive_gradient_in_thin_films_DGT_for.pdf\u0026Expires=1743161586\u0026Signature=ZQ-3CP1n2X0oHY1idEUDmKNzSAB7wb4JLNzCWQAg-kwA~RkpuZrlHMUfHm6L1d-faxiqtrAyoYB-vQPo58jl8pgyazj22znhNUUHK8rSoZztqpybR6H6n6pLIi2yhIMj3riK-RvL6~gL-Sn8ZzS~o2gzDb0o6JxZ4GETIw0eu2uLt2vYU~Bj-65n0y7rSozS2XZ03tewtoumG1y3EgK5WE~n4~xHUBEl-GIlVrdI4WrsW1gvjeX0-eNb7jV9nElkVdIuy9pT3AnoH-95AHUPh2qpLrwLnhxU4T4YcpzMOLhKiqLSwJf4kerfwcDe~Rf8wa3XhyEJmB9-RTrZngQSmQ__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA"}],"slug":"Diffusive_gradient_in_thin_films_DGT_for_profiling_leaching_of_CCA_treated_wood_waste_mulch_into_the_soil_environment","translated_slug":"","page_count":14,"language":"en","content_type":"Work","summary":"Chromated copper arsenate (CCA) is a common wood preservative that has been used worldwide. Studies have shown that there are leaching risks of the preservative components arsenic, chromium and copper. These risks include contamination of soil and water, resulting in toxic effects to humans, animals, plants and ecosystems. This study investigates leaching of the preservative components following exposure of the wood waste as mulch to soil and water. Diffusive gradient in thin films (DGTs) were used to quantify leaching of potentially bioavailable/dissolved forms of the elements along the soil profile. Speciation of chromium was also carried out. All elements were found to leach out of the wood. The containers that included CCA-treated wood waste as a mulch leached higher levels of arsenic, chromium and copper than the controls. The distribution was highest in the top 5 cm of the soil profile and decreased with depth. DGTs proved to be a useful, novel technique for measuring in situ leaching and speciation from waste materials into the environment.","owner":{"id":138681,"first_name":"Theresa","middle_initials":null,"last_name":"Mercer","page_name":"TheresaMercer","domain_name":"cranfield","created_at":"2010-02-27T04:17:56.330-08:00","display_name":"Theresa Mercer","url":"https://cranfield.academia.edu/TheresaMercer"},"attachments":[{"id":37818251,"title":"","file_type":"pdf","scribd_thumbnail_url":"https://attachments.academia-assets.com/37818251/thumbnails/1.jpg","file_name":"Mercer___Greenway__2014__DGT_and_CCA_leaching__IJEAC.pdf","download_url":"https://www.academia.edu/attachments/37818251/download_file","bulk_download_file_name":"Diffusive_gradient_in_thin_films_DGT_for.pdf","bulk_download_url":"https://d1wqtxts1xzle7.cloudfront.net/37818251/Mercer___Greenway__2014__DGT_and_CCA_leaching__IJEAC-libre.pdf?1433361254=\u0026response-content-disposition=attachment%3B+filename%3DDiffusive_gradient_in_thin_films_DGT_for.pdf\u0026Expires=1743161586\u0026Signature=ZQ-3CP1n2X0oHY1idEUDmKNzSAB7wb4JLNzCWQAg-kwA~RkpuZrlHMUfHm6L1d-faxiqtrAyoYB-vQPo58jl8pgyazj22znhNUUHK8rSoZztqpybR6H6n6pLIi2yhIMj3riK-RvL6~gL-Sn8ZzS~o2gzDb0o6JxZ4GETIw0eu2uLt2vYU~Bj-65n0y7rSozS2XZ03tewtoumG1y3EgK5WE~n4~xHUBEl-GIlVrdI4WrsW1gvjeX0-eNb7jV9nElkVdIuy9pT3AnoH-95AHUPh2qpLrwLnhxU4T4YcpzMOLhKiqLSwJf4kerfwcDe~Rf8wa3XhyEJmB9-RTrZngQSmQ__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA"}],"research_interests":[{"id":47477,"name":"Soil Pollution","url":"https://www.academia.edu/Documents/in/Soil_Pollution"},{"id":522129,"name":"Chromated Copper Arsenate","url":"https://www.academia.edu/Documents/in/Chromated_Copper_Arsenate"}],"urls":[{"id":2279824,"url":"http://www.tandfonline.com/doi/full/10.1080/03067319.2013.871712#.Ut_B39JFDMw"}]}, dispatcherData: dispatcherData }); 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The research highlights the advantages of immobilizing lipases to optimize enzyme activity and stability while reducing overall costs, thereby facilitating the separation and recovery of products. Various immobilization techniques are discussed, demonstrating significant improvements in reaction efficiencies when compared to traditional lipase immobilization methods. 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The cell viability was assessed for a range of nanoparticle concentrations and incubation times. We found that bare TiO2NPs affect the C. reinhardtii cell viability at much lower particle concentrations than for yeast. We observed an increase of the TiO2NPs toxicity upon illumination with UV light compared with that in dark conditions due to the oxidative stress of the produced reactive oxygen species. We also found an increased TiO2NPs nanotoxicity upon illumination with visible light which indicates that they may also interfere with the microalgae&#39;s photosynthetic system leading to decreased chlorophyll content upon exposure to TiO2NPs. The results indicate that the larger the hydrodynamic diameter of the TiO2NPs the lower is their nanotoxicity, with anatas...</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="9d3e614e3c028aa9a1f1ffe83af8e3a3" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":38103114,"asset_id":13684172,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/38103114/download_file?s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="13684172"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="13684172"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 13684172; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=13684172]").text(description); $(".js-view-count[data-work-id=13684172]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 13684172; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='13684172']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "9d3e614e3c028aa9a1f1ffe83af8e3a3" } } $('.js-work-strip[data-work-id=13684172]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":13684172,"title":"Nanotoxicity of polyelectrolyte-functionalized titania nanoparticles towards microalgae and yeast: role of the particle concentration, size and surface charge","translated_title":"","metadata":{"abstract":"We studied the nanotoxicity of titania nanoparticles (TiO2NPs) of various hydrodynamic diameters and crystallite sizes towards C. reinhardtii microalgae and S. cerevisiae (yeast) upon illumination with UV and visible light. 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Analytical Communications, May 1996, Vol33 ( I 71-1 74) 171 Elect rogenerated Chem il urn...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">Page 1. Analytical Communications, May 1996, Vol33 ( I 71-1 74) 171 Elect rogenerated Chem il urn inescence Determination of Some Local Anaesthetics Andrew W. Knight and Gillian M. Greenway School of Chemistry, University of Hull, Hull, North Humberside, UK HU6 7RX ...</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="13684170"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="13684170"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 13684170; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=13684170]").text(description); $(".js-view-count[data-work-id=13684170]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 13684170; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='13684170']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=13684170]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":13684170,"title":"Electrogenerated chemiluminescence determination of some local anaesthetics","translated_title":"","metadata":{"abstract":"Page 1. 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the future of water quality monitoring?</a></div><div class="wp-workCard_item wp-workCard--coauthors"><span>by </span><span><a class="" data-click-track="profile-work-strip-authors" href="https://hull.academia.edu/GillianGreenway">Gillian Greenway</a> and <a class="" data-click-track="profile-work-strip-authors" href="https://reading.academia.edu/AndrewWade">Andrew Wade</a></span></div><div class="wp-workCard_item"><span>Hydrology and Earth System Sciences Discussions</span><span>, 2012</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">This paper introduces new insights into the hydrochemical functioning of lowland river-systems us...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">This paper introduces new insights into the hydrochemical functioning of lowland river-systems using field-based spectrophotometric and electrode technologies. The streamwater concentrations of nitrogen species and phosphorus fractions were measured at hourly intervals on a continuous basis at two contrasting sites on tributaries of 5 the River Thames, one draining a rural catchment, the River Enborne, and one draining a more urban system, The Cut. The measurements complement those from an existing network of multi-parameter water quality sondes maintained across the Thames catchment and weekly monitoring based on grab samples. The results of the sub-daily monitoring show that streamwater phosphorus concentrations display highly complex, 10 seemingly chaotic, dynamics under storm conditions dependent on the antecedent catchment wetness, and that diurnal phosphorus and nitrogen cycles occur under low flow conditions. The diurnal patterns highlight the dominance of sewage inputs in controlling the streamwater phosphorus and nitrogen concentrations at low flows, even at a distance of 7 km from the nearest sewage works in the rural, River Enborne, and that 15 the time of sample collection is important when judging water quality against ecological thresholds or standards. An exhaustion of the supply of phosphorus from diffuse and septic tank sources during storm events was evident and load estimation was not improved by sub-daily monitoring beyond that achieved by daily sampling because of the eventual reduction in the phosphorus mass entering the stream during events. The 20 dominance of respiration over photosynthesis in The Cut indicated a prevalence of heterotrophic algae, and the seasonal patterns in respiration and photosynthesis corresponded with those of temperature and light in this nutrient over-enriched stream. These results highlight the utility of sub-daily water quality measurements but the deployment of modified wet-chemistry technologies into the field was limited by mains 25 electricity availability. A new approach is therefore needed to allow measurement of a wide range of analytes at a broader range of locations for the development of water 6459 quality web-sensor networks. The development and field deployment of a miniaturised "lab-on-a-chip" ion chromatograph is proposed and justified.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="fc61a09c948f9c2b6a0cf9a6de5b706a" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":45062958,"asset_id":13684166,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/45062958/download_file?s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="13684166"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="13684166"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 13684166; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=13684166]").text(description); $(".js-view-count[data-work-id=13684166]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 13684166; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='13684166']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "fc61a09c948f9c2b6a0cf9a6de5b706a" } } $('.js-work-strip[data-work-id=13684166]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":13684166,"title":"From existing in situ, high-resolution measurement technologies to lab-on-a-chip \u0026ndash; the future of water quality monitoring?","translated_title":"","metadata":{"grobid_abstract":"This paper introduces new insights into the hydrochemical functioning of lowland river-systems using field-based spectrophotometric and electrode technologies. 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The diurnal patterns highlight the dominance of sewage inputs in controlling the streamwater phosphorus and nitrogen concentrations at low flows, even at a distance of 7 km from the nearest sewage works in the rural, River Enborne, and that 15 the time of sample collection is important when judging water quality against ecological thresholds or standards. An exhaustion of the supply of phosphorus from diffuse and septic tank sources during storm events was evident and load estimation was not improved by sub-daily monitoring beyond that achieved by daily sampling because of the eventual reduction in the phosphorus mass entering the stream during events. The 20 dominance of respiration over photosynthesis in The Cut indicated a prevalence of heterotrophic algae, and the seasonal patterns in respiration and photosynthesis corresponded with those of temperature and light in this nutrient over-enriched stream. 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Flask experiments showed rapid uptake of Zn from the water column into biofilms. This uptake was not light dependant and suggests that chelation of Zn by negatively charged functional groups in extracellular polymeric substances (EPS) secreted within the biofilm are the key sink for Zn. Solid state analysis of the biofilm from the mesocosm system by scanning electron microscopy highlights the presence of calcite precipitates within the EPS, which may provide another sink for Zn. Long-term monitoring of flume systems showed area-adjusted removal rates of ~0.2 g Zn m-2 day-1, which is consistent with many other biologically-mediated mine water treatment systems. Diel (24 h) fluctuations in pH and Zn were observed over a 96 h intensive sampling period in the flumes. Practical considerations for establishing and maintaining biofilms under controlled conditions are also highlighted; these include regulation of light intensity and maintenance of flowing, low nutrient status waters.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="13684161"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="13684161"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 13684161; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=13684161]").text(description); $(".js-view-count[data-work-id=13684161]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 13684161; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='13684161']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=13684161]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":13684161,"title":"Zinc Uptake from Circumneutral Mine Drainage in Freshwater Biofilms: New Insights from In Vitro Experiments","translated_title":"","metadata":{"abstract":"ABSTRACT We present results from in vitro flask and flume experiments using freshwater biofilms sourced and cultivated from a mine-impacted stream in North Yorkshire, UK. 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> </div><div class="profile--tab_content_container js-tab-pane tab-pane" data-section-id="3160363" id="papers"><div class="js-work-strip profile--work_container" data-work-id="33316714"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/33316714/Photocatalytic_activity_of_surface_modified_TiO_2_RuO_2_SiO_2_nanoparticles_for_azo_dye_degradation"><img alt="Research paper thumbnail of Photocatalytic activity of surface modified TiO 2 /RuO 2 /SiO 2 nanoparticles for azo-dye degradation" class="work-thumbnail" src="https://attachments.academia-assets.com/53379416/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/33316714/Photocatalytic_activity_of_surface_modified_TiO_2_RuO_2_SiO_2_nanoparticles_for_azo_dye_degradation">Photocatalytic activity of surface modified TiO 2 /RuO 2 /SiO 2 nanoparticles for azo-dye degradation</a></div><div class="wp-workCard_item wp-workCard--coauthors"><span>by </span><span><a class="" data-click-track="profile-work-strip-authors" href="https://hull.academia.edu/ALEXIBHADON">ALEX IBHADON</a> and <a class="" data-click-track="profile-work-strip-authors" href="https://hull.academia.edu/GillianGreenway">Gillian Greenway</a></span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">SiO2/RuO2 modified high surface area titania dioxide nanoparticles prepared by hydrogen reduction...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">SiO2/RuO2 modified high surface area titania dioxide nanoparticles prepared by hydrogen reduction were examined for their catalytic properties towards the photodegradation of methyl orange (MO), a common water pollutant in the textile industry. The modified materials present enhanced photocatalytic activity and can decompose the MO faster than the unmodified TiO2. Results showed that doping with RuO2 only offered a marginal benefit over TiO2 alone. On the other hand, modification of TiO2with RuO2 and SiO2 resulted in a marked increase in the rate constant and the photodegradation efficiency. These results are consistent with the unique structural, morphologoical and surface characteristics of the composite titania dioxide/ruthenium dioxide/silicon dioxide materials. The lower the average particle size and roughness of the materials, the higher the percentage of photodecomposition and the rate constant. The surface doping and modification effects thus appears synergetic to the charge separation process and the photocatalytic results are explained on the basis of the mechanism that involves efficient separation of electron鈥揾ole pairs induced by the silicon dioxide particles. This enhances the ability of the modified TiO2 particles to effectively capture protons. Results also show that the modified nanoparticles can be used repeatedly over a long time without loss of efficiency.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="dbe5f9c34802c4330322fb95e76effd4" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":53379416,"asset_id":33316714,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/53379416/download_file?s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="33316714"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="33316714"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 33316714; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=33316714]").text(description); $(".js-view-count[data-work-id=33316714]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 33316714; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='33316714']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "dbe5f9c34802c4330322fb95e76effd4" } } $('.js-work-strip[data-work-id=33316714]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":33316714,"title":"Photocatalytic activity of surface modified TiO 2 /RuO 2 /SiO 2 nanoparticles for azo-dye degradation","translated_title":"","metadata":{"abstract":"SiO2/RuO2 modified high surface area titania dioxide nanoparticles prepared by hydrogen reduction were examined for their catalytic properties towards the photodegradation of methyl orange (MO), a common water pollutant in the textile industry. 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Studi...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">Chromated copper arsenate (CCA) is a common wood preservative that has been used worldwide. Studies have shown that there are leaching risks of the preservative components arsenic, chromium and copper. These risks include contamination of soil and water, resulting in toxic effects to humans, animals, plants and ecosystems. This study investigates leaching of the preservative components following exposure of the wood waste as mulch to soil and water. Diffusive gradient in thin films (DGTs) were used to quantify leaching of potentially bioavailable/dissolved forms of the elements along the soil profile. Speciation of chromium was also carried out. All elements were found to leach out of the wood. The containers that included CCA-treated wood waste as a mulch leached higher levels of arsenic, chromium and copper than the controls. The distribution was highest in the top 5 cm of the soil profile and decreased with depth. DGTs proved to be a useful, novel technique for measuring in situ leaching and speciation from waste materials into the environment.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="53e22f8ec28be3453f85bd48149aa07f" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":37818251,"asset_id":5797895,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/37818251/download_file?s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="5797895"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="5797895"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 5797895; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=5797895]").text(description); $(".js-view-count[data-work-id=5797895]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 5797895; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='5797895']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "53e22f8ec28be3453f85bd48149aa07f" } } $('.js-work-strip[data-work-id=5797895]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":5797895,"title":"Diffusive gradient in thin films (DGT) for profiling leaching of CCA-treated wood waste mulch into the soil environment","translated_title":"","metadata":{"abstract":"Chromated copper arsenate (CCA) is a common wood preservative that has been used worldwide. Studies have shown that there are leaching risks of the preservative components arsenic, chromium and copper. These risks include contamination of soil and water, resulting in toxic effects to humans, animals, plants and ecosystems. This study investigates leaching of the preservative components following exposure of the wood waste as mulch to soil and water. Diffusive gradient in thin films (DGTs) were used to quantify leaching of potentially bioavailable/dissolved forms of the elements along the soil profile. Speciation of chromium was also carried out. All elements were found to leach out of the wood. The containers that included CCA-treated wood waste as a mulch leached higher levels of arsenic, chromium and copper than the controls. The distribution was highest in the top 5 cm of the soil profile and decreased with depth. DGTs proved to be a useful, novel technique for measuring in situ leaching and speciation from waste materials into the environment.","ai_title_tag":"DGT Method for Assessing CCA Wood Leaching","journal_name":"International Journal of Environmental Analytical Chemistry","publication_date":{"day":17,"month":1,"year":2014,"errors":{}}},"translated_abstract":"Chromated copper arsenate (CCA) is a common wood preservative that has been used worldwide. Studies have shown that there are leaching risks of the preservative components arsenic, chromium and copper. These risks include contamination of soil and water, resulting in toxic effects to humans, animals, plants and ecosystems. This study investigates leaching of the preservative components following exposure of the wood waste as mulch to soil and water. Diffusive gradient in thin films (DGTs) were used to quantify leaching of potentially bioavailable/dissolved forms of the elements along the soil profile. Speciation of chromium was also carried out. All elements were found to leach out of the wood. The containers that included CCA-treated wood waste as a mulch leached higher levels of arsenic, chromium and copper than the controls. The distribution was highest in the top 5 cm of the soil profile and decreased with depth. DGTs proved to be a useful, novel technique for measuring in situ leaching and speciation from waste materials into the environment.","internal_url":"https://www.academia.edu/5797895/Diffusive_gradient_in_thin_films_DGT_for_profiling_leaching_of_CCA_treated_wood_waste_mulch_into_the_soil_environment","translated_internal_url":"","created_at":"2014-01-21T21:43:20.926-08:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":138681,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[{"id":10397856,"work_id":5797895,"tagging_user_id":138681,"tagged_user_id":32827010,"co_author_invite_id":null,"email":"g***y@associates.hull.ac.uk","affiliation":"University of Hull","display_order":0,"name":"Gillian Greenway","title":"Diffusive gradient in thin films (DGT) for profiling leaching of CCA-treated wood waste mulch into the soil environment"}],"downloadable_attachments":[{"id":37818251,"title":"","file_type":"pdf","scribd_thumbnail_url":"https://attachments.academia-assets.com/37818251/thumbnails/1.jpg","file_name":"Mercer___Greenway__2014__DGT_and_CCA_leaching__IJEAC.pdf","download_url":"https://www.academia.edu/attachments/37818251/download_file","bulk_download_file_name":"Diffusive_gradient_in_thin_films_DGT_for.pdf","bulk_download_url":"https://d1wqtxts1xzle7.cloudfront.net/37818251/Mercer___Greenway__2014__DGT_and_CCA_leaching__IJEAC-libre.pdf?1433361254=\u0026response-content-disposition=attachment%3B+filename%3DDiffusive_gradient_in_thin_films_DGT_for.pdf\u0026Expires=1743161586\u0026Signature=ZQ-3CP1n2X0oHY1idEUDmKNzSAB7wb4JLNzCWQAg-kwA~RkpuZrlHMUfHm6L1d-faxiqtrAyoYB-vQPo58jl8pgyazj22znhNUUHK8rSoZztqpybR6H6n6pLIi2yhIMj3riK-RvL6~gL-Sn8ZzS~o2gzDb0o6JxZ4GETIw0eu2uLt2vYU~Bj-65n0y7rSozS2XZ03tewtoumG1y3EgK5WE~n4~xHUBEl-GIlVrdI4WrsW1gvjeX0-eNb7jV9nElkVdIuy9pT3AnoH-95AHUPh2qpLrwLnhxU4T4YcpzMOLhKiqLSwJf4kerfwcDe~Rf8wa3XhyEJmB9-RTrZngQSmQ__\u0026Key-Pair-Id=APKAJLOHF5GGSLRBV4ZA"}],"slug":"Diffusive_gradient_in_thin_films_DGT_for_profiling_leaching_of_CCA_treated_wood_waste_mulch_into_the_soil_environment","translated_slug":"","page_count":14,"language":"en","content_type":"Work","summary":"Chromated copper arsenate (CCA) is a common wood preservative that has been used worldwide. Studies have shown that there are leaching risks of the preservative components arsenic, chromium and copper. These risks include contamination of soil and water, resulting in toxic effects to humans, animals, plants and ecosystems. This study investigates leaching of the preservative components following exposure of the wood waste as mulch to soil and water. Diffusive gradient in thin films (DGTs) were used to quantify leaching of potentially bioavailable/dissolved forms of the elements along the soil profile. Speciation of chromium was also carried out. All elements were found to leach out of the wood. The containers that included CCA-treated wood waste as a mulch leached higher levels of arsenic, chromium and copper than the controls. The distribution was highest in the top 5 cm of the soil profile and decreased with depth. 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="13684172"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/13684172/Nanotoxicity_of_polyelectrolyte_functionalized_titania_nanoparticles_towards_microalgae_and_yeast_role_of_the_particle_concentration_size_and_surface_charge"><img alt="Research paper thumbnail of Nanotoxicity of polyelectrolyte-functionalized titania nanoparticles towards microalgae and yeast: role of the particle concentration, size and surface charge" class="work-thumbnail" src="https://attachments.academia-assets.com/38103114/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/13684172/Nanotoxicity_of_polyelectrolyte_functionalized_titania_nanoparticles_towards_microalgae_and_yeast_role_of_the_particle_concentration_size_and_surface_charge">Nanotoxicity of polyelectrolyte-functionalized titania nanoparticles towards microalgae and yeast: role of the particle concentration, size and surface charge</a></div><div class="wp-workCard_item"><span>RSC Advances</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">We studied the nanotoxicity of titania nanoparticles (TiO2NPs) of various hydrodynamic diameters ...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">We studied the nanotoxicity of titania nanoparticles (TiO2NPs) of various hydrodynamic diameters and crystallite sizes towards C. reinhardtii microalgae and S. cerevisiae (yeast) upon illumination with UV and visible light. The cell viability was assessed for a range of nanoparticle concentrations and incubation times. We found that bare TiO2NPs affect the C. reinhardtii cell viability at much lower particle concentrations than for yeast. We observed an increase of the TiO2NPs toxicity upon illumination with UV light compared with that in dark conditions due to the oxidative stress of the produced reactive oxygen species. We also found an increased TiO2NPs nanotoxicity upon illumination with visible light which indicates that they may also interfere with the microalgae&#39;s photosynthetic system leading to decreased chlorophyll content upon exposure to TiO2NPs. The results indicate that the larger the hydrodynamic diameter of the TiO2NPs the lower is their nanotoxicity, with anatas...</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="9d3e614e3c028aa9a1f1ffe83af8e3a3" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":38103114,"asset_id":13684172,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/38103114/download_file?s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="13684172"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="13684172"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 13684172; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=13684172]").text(description); $(".js-view-count[data-work-id=13684172]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 13684172; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='13684172']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "9d3e614e3c028aa9a1f1ffe83af8e3a3" } } $('.js-work-strip[data-work-id=13684172]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":13684172,"title":"Nanotoxicity of polyelectrolyte-functionalized titania nanoparticles towards microalgae and yeast: role of the particle concentration, size and surface charge","translated_title":"","metadata":{"abstract":"We studied the nanotoxicity of titania nanoparticles (TiO2NPs) of various hydrodynamic diameters and crystallite sizes towards C. reinhardtii microalgae and S. cerevisiae (yeast) upon illumination with UV and visible light. The cell viability was assessed for a range of nanoparticle concentrations and incubation times. We found that bare TiO2NPs affect the C. reinhardtii cell viability at much lower particle concentrations than for yeast. We observed an increase of the TiO2NPs toxicity upon illumination with UV light compared with that in dark conditions due to the oxidative stress of the produced reactive oxygen species. We also found an increased TiO2NPs nanotoxicity upon illumination with visible light which indicates that they may also interfere with the microalgae\u0026#39;s photosynthetic system leading to decreased chlorophyll content upon exposure to TiO2NPs. The results indicate that the larger the hydrodynamic diameter of the TiO2NPs the lower is their nanotoxicity, with anatas...","publication_name":"RSC Advances"},"translated_abstract":"We studied the nanotoxicity of titania nanoparticles (TiO2NPs) of various hydrodynamic diameters and crystallite sizes towards C. reinhardtii microalgae and S. cerevisiae (yeast) upon illumination with UV and visible light. The cell viability was assessed for a range of nanoparticle concentrations and incubation times. We found that bare TiO2NPs affect the C. reinhardtii cell viability at much lower particle concentrations than for yeast. We observed an increase of the TiO2NPs toxicity upon illumination with UV light compared with that in dark conditions due to the oxidative stress of the produced reactive oxygen species. 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="13684166"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" href="https://www.academia.edu/13684166/From_existing_in_situ_high_resolution_measurement_technologies_to_lab_on_a_chip_and_ndash_the_future_of_water_quality_monitoring"><img alt="Research paper thumbnail of From existing in situ, high-resolution measurement technologies to lab-on-a-chip &ndash; the future of water quality monitoring?" class="work-thumbnail" src="https://attachments.academia-assets.com/45062958/thumbnails/1.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title"><a class="js-work-strip-work-link text-gray-darker" data-click-track="profile-work-strip-title" href="https://www.academia.edu/13684166/From_existing_in_situ_high_resolution_measurement_technologies_to_lab_on_a_chip_and_ndash_the_future_of_water_quality_monitoring">From existing in situ, high-resolution measurement technologies to lab-on-a-chip &ndash; the future of water quality monitoring?</a></div><div class="wp-workCard_item wp-workCard--coauthors"><span>by </span><span><a class="" data-click-track="profile-work-strip-authors" href="https://hull.academia.edu/GillianGreenway">Gillian Greenway</a> and <a class="" data-click-track="profile-work-strip-authors" href="https://reading.academia.edu/AndrewWade">Andrew Wade</a></span></div><div class="wp-workCard_item"><span>Hydrology and Earth System Sciences Discussions</span><span>, 2012</span></div><div class="wp-workCard_item"><span class="js-work-more-abstract-truncated">This paper introduces new insights into the hydrochemical functioning of lowland river-systems us...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">This paper introduces new insights into the hydrochemical functioning of lowland river-systems using field-based spectrophotometric and electrode technologies. The streamwater concentrations of nitrogen species and phosphorus fractions were measured at hourly intervals on a continuous basis at two contrasting sites on tributaries of 5 the River Thames, one draining a rural catchment, the River Enborne, and one draining a more urban system, The Cut. The measurements complement those from an existing network of multi-parameter water quality sondes maintained across the Thames catchment and weekly monitoring based on grab samples. The results of the sub-daily monitoring show that streamwater phosphorus concentrations display highly complex, 10 seemingly chaotic, dynamics under storm conditions dependent on the antecedent catchment wetness, and that diurnal phosphorus and nitrogen cycles occur under low flow conditions. The diurnal patterns highlight the dominance of sewage inputs in controlling the streamwater phosphorus and nitrogen concentrations at low flows, even at a distance of 7 km from the nearest sewage works in the rural, River Enborne, and that 15 the time of sample collection is important when judging water quality against ecological thresholds or standards. An exhaustion of the supply of phosphorus from diffuse and septic tank sources during storm events was evident and load estimation was not improved by sub-daily monitoring beyond that achieved by daily sampling because of the eventual reduction in the phosphorus mass entering the stream during events. The 20 dominance of respiration over photosynthesis in The Cut indicated a prevalence of heterotrophic algae, and the seasonal patterns in respiration and photosynthesis corresponded with those of temperature and light in this nutrient over-enriched stream. These results highlight the utility of sub-daily water quality measurements but the deployment of modified wet-chemistry technologies into the field was limited by mains 25 electricity availability. A new approach is therefore needed to allow measurement of a wide range of analytes at a broader range of locations for the development of water 6459 quality web-sensor networks. The development and field deployment of a miniaturised "lab-on-a-chip" ion chromatograph is proposed and justified.</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><a id="fc61a09c948f9c2b6a0cf9a6de5b706a" class="wp-workCard--action" rel="nofollow" data-click-track="profile-work-strip-download" data-download="{"attachment_id":45062958,"asset_id":13684166,"asset_type":"Work","button_location":"profile"}" href="https://www.academia.edu/attachments/45062958/download_file?s=profile"><span><i class="fa fa-arrow-down"></i></span><span>Download</span></a><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="13684166"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="13684166"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 13684166; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=13684166]").text(description); $(".js-view-count[data-work-id=13684166]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 13684166; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='13684166']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (true){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "fc61a09c948f9c2b6a0cf9a6de5b706a" } } $('.js-work-strip[data-work-id=13684166]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":13684166,"title":"From existing in situ, high-resolution measurement technologies to lab-on-a-chip \u0026ndash; the future of water quality monitoring?","translated_title":"","metadata":{"grobid_abstract":"This paper introduces new insights into the hydrochemical functioning of lowland river-systems using field-based spectrophotometric and electrode technologies. 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$(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="13684165"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/13684165/Interfacing_Microchip_CE_with_ICPMS_for_Element_Speciation"><img alt="Research paper thumbnail of Interfacing Microchip CE with ICPMS for Element Speciation" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title">Interfacing Microchip CE with ICPMS for Element Speciation</div><div class="wp-workCard_item wp-workCard--coauthors"><span>by </span><span><a class="" data-click-track="profile-work-strip-authors" href="https://hull.academia.edu/TomMcCreedy">Tom McCreedy</a> and <a class="" data-click-track="profile-work-strip-authors" href="https://hull.academia.edu/GillianGreenway">Gillian Greenway</a></span></div><div class="wp-workCard_item"><span>Micro Total Analysis Systems 2002</span><span>, 2002</span></div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="13684165"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="13684165"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 13684165; 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Greenway 1, Tom McCreedy 1, Anne Mari...</span><a class="js-work-more-abstract" data-broccoli-component="work_strip.more_abstract" data-click-track="profile-work-strip-more-abstract" href="javascript:;"><span> more </span><span><i class="fa fa-caret-down"></i></span></a><span class="js-work-more-abstract-untruncated hidden">Bongkot Ngamsom 1, Leanne Marle 1, Paul Watts 1, Gillian M. Greenway 1, Tom McCreedy 1, Anne Marie Hickey 2, and Jennifer A. 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Littlechild 2.(1) Department of Chemistry, University of Hull, Cottingham Road, Hull, HU6 7RX, United Kingdom,(2) Henry Wellcome Building ...","owner":{"id":32827010,"first_name":"Gillian","middle_initials":null,"last_name":"Greenway","page_name":"GillianGreenway","domain_name":"hull","created_at":"2015-07-06T00:35:46.325-07:00","display_name":"Gillian Greenway","url":"https://hull.academia.edu/GillianGreenway"},"attachments":[],"research_interests":[],"urls":[]}, dispatcherData: dispatcherData }); $(this).data('initialized', true); } }); $a.trackClickSource(".js-work-strip-work-link", "profile_work_strip") }); </script> <div class="js-work-strip profile--work_container" data-work-id="13684163"><div class="profile--work_thumbnail hidden-xs"><a class="js-work-strip-work-link" data-click-track="profile-work-strip-thumbnail" rel="nofollow" href="https://www.academia.edu/13684163/The_definitive_version_of_this_paper_is_available_in_the_Springer_journal_Environmental_Science_and_Pollution_Research_DOI_10_1007_s11356_013_1513_4"><img alt="Research paper thumbnail of The definitive version of this paper is available in the Springer journal Environmental Science and Pollution Research: DOI: 10.1007/s11356-013-1513-4" class="work-thumbnail" src="https://a.academia-assets.com/images/blank-paper.jpg" /></a></div><div class="wp-workCard wp-workCard_itemContainer"><div class="wp-workCard_item wp-workCard--title">The definitive version of this paper is available in the Springer journal Environmental Science and Pollution Research: DOI: 10.1007/s11356-013-1513-4</div><div class="wp-workCard_item wp-workCard--actions"><span class="work-strip-bookmark-button-container"></span><span class="wp-workCard--action visible-if-viewed-by-owner inline-block" style="display: none;"><span class="js-profile-work-strip-edit-button-wrapper profile-work-strip-edit-button-wrapper" data-work-id="13684163"><a class="js-profile-work-strip-edit-button" tabindex="0"><span><i class="fa fa-pencil"></i></span><span>Edit</span></a></span></span></div><div class="wp-workCard_item wp-workCard--stats"><span><span><span class="js-view-count view-count u-mr2x" data-work-id="13684163"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 13684163; 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window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=13684162]").text(description); $(".js-view-count[data-work-id=13684162]").attr('title', description).tooltip(); }); });</script></span></span><span><span class="percentile-widget hidden"><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 13684162; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-work-strip[data-work-id='13684162']"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></span></div><div id="work-strip-premium-row-container"></div></div></div><script> require.config({ waitSeconds: 90 })(["https://a.academia-assets.com/assets/wow_profile-a9bf3a2bc8c89fa2a77156577594264ee8a0f214d74241bc0fcd3f69f8d107ac.js","https://a.academia-assets.com/assets/work_edit-ad038b8c047c1a8d4fa01b402d530ff93c45fee2137a149a4a5398bc8ad67560.js"], function() { // from javascript_helper.rb var dispatcherData = {} if (false){ window.WowProfile.dispatcher = window.WowProfile.dispatcher || _.clone(Backbone.Events); dispatcherData = { dispatcher: window.WowProfile.dispatcher, downloadLinkId: "-1" } } $('.js-work-strip[data-work-id=13684162]').each(function() { if (!$(this).data('initialized')) { new WowProfile.WorkStripView({ el: this, workJSON: {"id":13684162,"title":"REFERENCE EDITION","translated_title":"","metadata":{},"translated_abstract":null,"internal_url":"https://www.academia.edu/13684162/REFERENCE_EDITION","translated_internal_url":"","created_at":"2015-07-06T00:39:57.819-07:00","preview_url":null,"current_user_can_edit":null,"current_user_is_owner":null,"owner_id":32827010,"coauthors_can_edit":true,"document_type":"paper","co_author_tags":[{"id":2380795,"work_id":13684162,"tagging_user_id":32827010,"tagged_user_id":null,"co_author_invite_id":440076,"email":"a***d@hull.ac.uk","display_order":0,"name":"A. 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Flask experiments showed rapid uptake of Zn from the water column into biofilms. This uptake was not light dependant and suggests that chelation of Zn by negatively charged functional groups in extracellular polymeric substances (EPS) secreted within the biofilm are the key sink for Zn. Solid state analysis of the biofilm from the mesocosm system by scanning electron microscopy highlights the presence of calcite precipitates within the EPS, which may provide another sink for Zn. Long-term monitoring of flume systems showed area-adjusted removal rates of ~0.2 g Zn m-2 day-1, which is consistent with many other biologically-mediated mine water treatment systems. Diel (24 h) fluctuations in pH and Zn were observed over a 96 h intensive sampling period in the flumes. 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