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tungsten tellurite glasses</title> <meta name="description" content="Search results for: fluoro tungsten tellurite glasses"> <meta name="keywords" content="fluoro tungsten tellurite glasses"> <meta name="viewport" content="width=device-width, initial-scale=1, minimum-scale=1, maximum-scale=1, user-scalable=no"> <meta charset="utf-8"> <link href="https://cdn.waset.org/favicon.ico" type="image/x-icon" rel="shortcut icon"> <link href="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/css/bootstrap.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/plugins/fontawesome/css/all.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/css/site.css?v=150220211555" rel="stylesheet"> </head> <body> <header> <div class="container"> <nav class="navbar navbar-expand-lg navbar-light"> <a class="navbar-brand" href="https://waset.org"> <img src="https://cdn.waset.org/static/images/wasetc.png" alt="Open Science Research Excellence" title="Open Science Research Excellence" 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action="https://publications.waset.org/abstracts/search"> <div id="custom-search-input"> <div class="input-group"> <i class="fas fa-search"></i> <input type="text" class="search-query" name="q" placeholder="Author, Title, Abstract, Keywords" value="fluoro tungsten tellurite glasses"> <input type="submit" class="btn_search" value="Search"> </div> </div> </form> </div> </div> <div class="row mt-3"> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Commenced</strong> in January 2007</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Frequency:</strong> Monthly</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Edition:</strong> International</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Paper Count:</strong> 256</div> </div> </div> </div> <h1 class="mt-3 mb-3 text-center" style="font-size:1.6rem;">Search results for: fluoro tungsten tellurite glasses</h1> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">256</span> Composition Dependent Spectroscopic Studies of Sm3+-Doped Alkali Fluoro Tungsten Tellurite Glasses</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=K.%20Swapna">K. Swapna</a>, <a href="https://publications.waset.org/abstracts/search?q=Sk.%20Mahamuda"> Sk. Mahamuda</a>, <a href="https://publications.waset.org/abstracts/search?q=Ch"> Ch</a>, <a href="https://publications.waset.org/abstracts/search?q=Annapurna"> Annapurna</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20Srinivasa%20Rao"> A. Srinivasa Rao</a>, <a href="https://publications.waset.org/abstracts/search?q=G.%20Vijaya%20Prakash"> G. Vijaya Prakash</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Samarium ions doped Alkali Fluoro Tungsten Tellurite (AFTT) Glasses have been prepared by using the melt quenching technique and characterized through various spectroscopic techniques such as optical absorption, excitation, emission and decay spectral studies. From the measured absorption spectra of Sm3+ ions in AFTT glasses, the optical band gap and Urbach energies have been evaluated. The spectroscopic parameters such as oscillator strengths (f), Judd-Ofelt (J-O) intensity parameters (Ωλ), spontaneous emission probability (AR), branching ratios (βR) and radiative lifetimes (τR) of various excited levels have been determined from the absorption spectrum by using J-O analysis. A strong luminescence in the reddish-orange spectral region has been observed for all the Sm3+ ions doped AFTT glasses. It consisting four emission transitions occurring from the 4G5/2metastable state to the lower lying states 6H5/2, 6H7/2, 6H9/2 and 6H11/2 upon exciting the sample with a 478 nm line of an argon ion laser. The stimulated emission cross-sections (σe) and branching ratios (βmeas) were estimated from the emission spectra for all emission transitions. Correlation of the radiative lifetime with the experimental lifetime measured from the day curves allows us to measure the quantum efficiency of the prepared glasses. In order to know the colour emission of the prepared glasses under near UV excitation, the emission intensities were analyzed using CIE 1931 colour chromaticity diagram. The aforementioned spectral studies carried out on Sm3+ ions doped AFTT glasses allowed us to conclude that, these glasses are best suited for orange-red visible lasers. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=fluoro%20tungsten%20tellurite%20glasses" title="fluoro tungsten tellurite glasses">fluoro tungsten tellurite glasses</a>, <a href="https://publications.waset.org/abstracts/search?q=judd-ofelt%20intensity%20parameters" title=" judd-ofelt intensity parameters"> judd-ofelt intensity parameters</a>, <a href="https://publications.waset.org/abstracts/search?q=lifetime" title=" lifetime"> lifetime</a>, <a href="https://publications.waset.org/abstracts/search?q=stimulated%20emission%20cross-section" title=" stimulated emission cross-section"> stimulated emission cross-section</a> </p> <a href="https://publications.waset.org/abstracts/43867/composition-dependent-spectroscopic-studies-of-sm3-doped-alkali-fluoro-tungsten-tellurite-glasses" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/43867.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">277</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">255</span> Dy3+ Ions Doped Single and Mixed Alkali Fluoro Tungstunate Tellurite Glasses for Laser and White LED Applications</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Allam%20Srinivasa%20Rao">Allam Srinivasa Rao</a>, <a href="https://publications.waset.org/abstracts/search?q=Ch.%20Annapurna%20Devi"> Ch. Annapurna Devi</a>, <a href="https://publications.waset.org/abstracts/search?q=G.%20Vijaya%20Prakash"> G. Vijaya Prakash</a> </p> <p class="card-text"><strong>Abstract:</strong></p> A new-fangled series of white light emitting 1 mol% of Dy3+ ions doped Single-Alklai and Mixed-Alkai fluoro tungstunate tellurite glasses have been prepared using melt quenching technique and their spectroscopic behaviour was investigated by studying XRD, optical absorption, photoluminescence and lifetime measurements. The bonding parameter studies reveal the ionic nature of the Dy-O bond in the present glasses. From the absorption spectra, the Judd–Ofelt (J-O) intensity parameters have been determined which are used to explore the nature of bonding and symmetry orientation of the Dy–ligand field environment. The evaluated J-O parameters (Ω_4>Ω_2>Ω_6) for all the glasses are following the same trend. The photoluminescence spectra of all the glasses exhibit two intensified peaks in blue and Yellow regions corresponding to the transitions 4F9/2→6H15/2 (483 nm) and 4F9/2→6H13/2 (575 nm) respectively. From the photoluminescence spectra, it is observed that the luminescence intensity is maximum for Dy3+ ion doped potassium combination of fluoro tungstunate tellurite glass (TeWK: 1Dy). The J-O intensity parameters have been used to determine the various radiative properties for the different emission transitions from the 4F9/2 fluorescent level. The highest emission cross-section and branching ratio values observed for the 4F9/2→6H15/2 and 4F9/2→6H13/2 transitions suggest the possible laser action in the visible region from these glasses. By using the experimental lifetimes (τ_exp) measured from the decay spectral features and radiative lifetimes (τ_R), the quantum efficiencies (η) for all the glasses have been evaluated. Among all the glasses, the potassium combined fluoro tungstunate tellurite (TeWK:1Dy) glass has the highest quantum efficiency (94.6%). The CIE colour chromaticity coordinates (x, y), (u, v), colour correlated temperature (CCT) and Y/B ratio were also estimated from the photoluminescence spectra for different compositions of glasses. The (x, y) and (u, v) chromaticity colour coordinates fall within the white light region and the white light can be tuned by varying the composition of the glass. From all these studies, we are suggesting that the 1 mol% of Dy3+ ions doped TeWK glass is more suitable for lasing and White-LED applications. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=dysprosium" title="dysprosium">dysprosium</a>, <a href="https://publications.waset.org/abstracts/search?q=Judd-Ofelt%20parameters" title=" Judd-Ofelt parameters"> Judd-Ofelt parameters</a>, <a href="https://publications.waset.org/abstracts/search?q=photo%20luminescence" title=" photo luminescence"> photo luminescence</a>, <a href="https://publications.waset.org/abstracts/search?q=tellurite%20glasses" title=" tellurite glasses"> tellurite glasses</a> </p> <a href="https://publications.waset.org/abstracts/46832/dy3-ions-doped-single-and-mixed-alkali-fluoro-tungstunate-tellurite-glasses-for-laser-and-white-led-applications" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/46832.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">224</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">254</span> Photoluminescence and Spectroscopic Studies of Tm3+ Ions Doped Lead Tungsten Tellurite Glasses for Visible Red and Near-Ir Laser Applications</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=M.%20Venkateswarlu">M. Venkateswarlu</a>, <a href="https://publications.waset.org/abstracts/search?q=Srinivasa%20Rao%20Allam"> Srinivasa Rao Allam</a>, <a href="https://publications.waset.org/abstracts/search?q=S.%20K.%20Mahamuda"> S. K. Mahamuda</a>, <a href="https://publications.waset.org/abstracts/search?q=K.%20Swapna"> K. Swapna</a>, <a href="https://publications.waset.org/abstracts/search?q=G.%20Vijaya%20Prakash"> G. Vijaya Prakash</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Lead Tungsten Tellurite (LTT) glasses doped with different concentrations of Tm3+ ions were prepared by using melt quenching technique and characterized through optical absorption, photoluminescence and decay spectral studies to know the feasibility of using these glasses as luminescent devices in visible Red and NIR regions. By using optical absorption spectral data, the energy band gaps for all the glasses were evaluated and were found to be in the range of 2.34-2.59 eV; which is very useful for the construction of optical devices. Judd-Ofelt (J-O)theory has been applied to the optical absorption spectral profiles to calculate the J-O intensity parameters Ωλ (λ=2, 4 and 6) and consecutively used to evaluate various radiative properties such as radiative transition probability (AR), radiative lifetimes (τ_R) and branching ratios (β_R) for the prominent luminescent levels. The luminescence spectra for all the LTT glass samples have shown two intense peaks in bright red and Near Infrared regions at 650 nm (1G4→3F4) and 800 nm (3H4→3H6) respectively for which effective bandwidths (〖Δλ〗_P), experimental branching ratios (β_exp) and stimulated emission cross-sections (σ_se) are evaluated. The decay profiles for all the glasses were also recorded to measure the quantum efficiency of the prepared LTT glasses by coupling the radiative and experimental lifetimes. From the measured emission cross-sections, quantum efficiency and CIE chromaticity coordinates, it was found that 0.5 mol% of Tm3+ ions doped LTT glass is most suitable for generating bright visible red and NIR lasers to operate at 650 and 800 nm respectively. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=glasses" title="glasses">glasses</a>, <a href="https://publications.waset.org/abstracts/search?q=JO%20parameters" title=" JO parameters"> JO parameters</a>, <a href="https://publications.waset.org/abstracts/search?q=optical%20materials" title=" optical materials"> optical materials</a>, <a href="https://publications.waset.org/abstracts/search?q=thullium" title=" thullium"> thullium</a> </p> <a href="https://publications.waset.org/abstracts/47260/photoluminescence-and-spectroscopic-studies-of-tm3-ions-doped-lead-tungsten-tellurite-glasses-for-visible-red-and-near-ir-laser-applications" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/47260.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">252</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">253</span> Sliver Nanoparticles Enhanced Visible and Near Infrared Emission of Er³+ Ions Doped Lithium Tungsten Tellurite Glasses </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Sachin%20Mahajan">Sachin Mahajan</a>, <a href="https://publications.waset.org/abstracts/search?q=Ghizal%20Ansari"> Ghizal Ansari</a> </p> <p class="card-text"><strong>Abstract:</strong></p> TeO2-WO3-Li2O glass doped erbium ions (1mol %) and embedded silver nanoparticles( Ag NPs) has successfully been prepared by melt quenching technique and increasing the heat-treatment duration. The amorphous nature of the glass is determined by X-ray diffraction method, and the presences of silver nanoparticles are confirmed using Transmission Electron Microscopy analysis. TEM image reveals that the Ag NPs are dispersed homogeneously with average size 18 nm. From the UV-Vis absorption spectra, the surface plasmon resonance (SPR) peaks are detected at 550 and 578 nm. Under 980 nm excitation wavelengths, enhancement of red upconversion fluorescence and near-infrared broadband emission around 1550nm of Er3+ ions doped tellurite glasses containing Ag NPs have been observed. The observed enhancement of Er3+ emission is mainly attributed to the local field effects of Ag NPs causes an intensified electromagnetic field around NPs. For observed enhancement involved mechanisms are discussed. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=erbium%20ions" title="erbium ions">erbium ions</a>, <a href="https://publications.waset.org/abstracts/search?q=silver%20nanoparticle" title=" silver nanoparticle"> silver nanoparticle</a>, <a href="https://publications.waset.org/abstracts/search?q=surface%20plasmon%20resonance" title=" surface plasmon resonance"> surface plasmon resonance</a>, <a href="https://publications.waset.org/abstracts/search?q=upconversion%20emission" title=" upconversion emission"> upconversion emission</a> </p> <a href="https://publications.waset.org/abstracts/54627/sliver-nanoparticles-enhanced-visible-and-near-infrared-emission-of-er3-ions-doped-lithium-tungsten-tellurite-glasses" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/54627.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">590</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">252</span> Simulation of Acoustic Properties of Borate and Tellurite Glasses</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=M.%20S.%20Gaafar">M. S. Gaafar</a>, <a href="https://publications.waset.org/abstracts/search?q=S.%20Y.%20Marzouk"> S. Y. Marzouk</a>, <a href="https://publications.waset.org/abstracts/search?q=I.%20S.%20Mahmoud"> I. S. Mahmoud</a>, <a href="https://publications.waset.org/abstracts/search?q=S.%20Al-Zobaidi"> S. Al-Zobaidi</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Makishima and Mackenzie model was used to simulation of acoustic properties (longitudinal and shear ultrasonic wave velocities, elastic moduli theoretically for many tellurite and borate glasses. The model was proposed mainly depending on the values of the experimentally measured density, which are obtained before. In this search work, we are trying to obtain the values of densities of amorphous glasses (as the density depends on the geometry of the network structure of these glasses). In addition, the problem of simulating the slope of linear regression between the experimentally determined bulk modulus and the product of packing density and experimental Young's modulus, were solved in this search work. The results showed good agreement between the experimentally measured values of densities and both ultrasonic wave velocities, and those theoretically determined. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=glasses" title="glasses">glasses</a>, <a href="https://publications.waset.org/abstracts/search?q=ultrasonic%20wave%20velocities" title=" ultrasonic wave velocities"> ultrasonic wave velocities</a>, <a href="https://publications.waset.org/abstracts/search?q=elastic%20modulus" title=" elastic modulus"> elastic modulus</a>, <a href="https://publications.waset.org/abstracts/search?q=Makishima%20%26%20Mackenzie%20Model" title=" Makishima & Mackenzie Model"> Makishima & Mackenzie Model</a> </p> <a href="https://publications.waset.org/abstracts/43461/simulation-of-acoustic-properties-of-borate-and-tellurite-glasses" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/43461.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">386</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">251</span> Development of Boro-Tellurite Glasses Enhanced with HfO2 for Radiation Shielding: Examination of Optical and Physical Characteristics</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Sleman%20Yahya%20Rasul">Sleman Yahya Rasul</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Due to their transparency, various types of glass are utilized in numerous applications where clear visibility is essential. One such application involves environments where radiography, radiotherapy, and X-ray devices are used, all of which involve exposure to radiation. As is well-known, radiation can be lethal to humans. Consequently, there is a need for glass that can absorb and block these harmful rays in such settings. Effective protection from radiation typically requires materials with high atomic numbers and densities. Currently, lead oxide-infused glasses are commonly used for this purpose, but due to the toxicity of lead oxide, there is a demand for safer alternatives. HfO2 has been selected as an additive for boro-tellurite (M1-M2-M3) glasses intended for radiation shielding because it has a high atomic number, high density, and is non-toxic. In this study, new glasses will be developed as alternatives to leaded glasses by incorporating x mol% HfO2 into the boro-tellurite glass structure. The glass compositions will be melted and quenched using the traditional method in an alumina crucible at temperatures between 900–1100°C. The resulting glasses will be evaluated for their elastic properties (including elastic modulus, shear modulus, bulk modulus, and Poisson ratio), density, hardness, and fracture toughness. X-ray diffraction (XRD) will be used to examine the amorphous nature of the glasses, while Differential Thermal Analysis (DTA) will provide thermal analysis. Optical properties will be assessed through UV-Vis and Photoluminescence Spectroscopy, and structural properties will be studied using Raman spectroscopy and FTIR spectroscopy. Additionally, the radiation shielding capabilities will be investigated by measuring parameters such as mass attenuation coefficient, half-value thickness, mean free path, effective atomic number (Z_eff), and effective electron density (N_e). The aim of this study is to develop new, lead-free glasses with excellent optical properties and high mechanical strength to replace the leaded glasses currently used for radiation shielding. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=boro-tellurite%20glasses" title="boro-tellurite glasses">boro-tellurite glasses</a>, <a href="https://publications.waset.org/abstracts/search?q=hfo2" title=" hfo2"> hfo2</a>, <a href="https://publications.waset.org/abstracts/search?q=radiation%20shielding" title=" radiation shielding"> radiation shielding</a>, <a href="https://publications.waset.org/abstracts/search?q=mechanical%20properties" title=" mechanical properties"> mechanical properties</a>, <a href="https://publications.waset.org/abstracts/search?q=elastic%20properties" title=" elastic properties"> elastic properties</a>, <a href="https://publications.waset.org/abstracts/search?q=optical%20properties" title=" optical properties"> optical properties</a> </p> <a href="https://publications.waset.org/abstracts/186303/development-of-boro-tellurite-glasses-enhanced-with-hfo2-for-radiation-shielding-examination-of-optical-and-physical-characteristics" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/186303.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">43</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">250</span> Gamma Irradiation Effect on Structural and Optical Properties of Bismuth-Boro-Tellurite Glasses</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Azuraida%20Amat">Azuraida Amat</a>, <a href="https://publications.waset.org/abstracts/search?q=Halimah%20Mohamed%20Kamari"> Halimah Mohamed Kamari</a>, <a href="https://publications.waset.org/abstracts/search?q=Che%20Azurahanim%20Che%20Abdullah"> Che Azurahanim Che Abdullah</a>, <a href="https://publications.waset.org/abstracts/search?q=Ishak%20Mansor"> Ishak Mansor</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The changes of the optical and structural properties of Bismuth-Boro-Tellurite glasses pre and post gamma irradiation were studied. Six glass samples, with different compositions [(TeO2)0.7 (B2O3)0.3]1-x (Bi2O3)x prepared by melt quenching method were irradiated with 25kGy gamma radiation at room temperature. The Fourier Transform Infrared Spectroscopy (FTIR) was used to explore the structural bonding in the prepared glass samples due to exposure, while UV-VIS Spectrophotometer was used to evaluate the changes in the optical properties before and after irradiation. Gamma irradiation causes a profound changes in the peak intensity as shown by FTIR spectra which is due to the breaking of the network bonding. Before gamma irradiation, the optical band gap, Eg value decreased from 2.44 eV to 2.15 eV with the addition of Bismuth content. The value kept decreasing (from 2.18 eV to 2.00 eV) following exposure to gamma radiation due to the increase of non-bridging oxygen (NBO) and the increase of defects in the glass. In conclusion, the glass with high content of Bi2O3 (0.30Bi) give the smallest Eg and show less changes in FTIR spectra after gamma irradiation, which indicate that this glass is more resistant to gamma radiation compared to other glasses. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=boro-tellurite" title="boro-tellurite">boro-tellurite</a>, <a href="https://publications.waset.org/abstracts/search?q=bismuth" title=" bismuth"> bismuth</a>, <a href="https://publications.waset.org/abstracts/search?q=gamma%20radiation" title=" gamma radiation"> gamma radiation</a>, <a href="https://publications.waset.org/abstracts/search?q=optical%20properties" title=" optical properties"> optical properties</a> </p> <a href="https://publications.waset.org/abstracts/25457/gamma-irradiation-effect-on-structural-and-optical-properties-of-bismuth-boro-tellurite-glasses" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/25457.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">427</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">249</span> Spectroscopic Studies of Dy³⁺ Ions in Alkaline-Earth Boro Tellurite Glasses for Optoelectronic Devices</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=K.%20Swapna">K. Swapna</a> </p> <p class="card-text"><strong>Abstract:</strong></p> A Series of Alkali-Earth Boro Tellurite (AEBT) glasses doped with different concentrations of Dy³⁺ ions have been prepared by using melt quenching technique and characterized through spectroscopic techniques such as optical absorption, excitation, emission and photoluminescence decay to understand their utility in optoelectronic devices such as lasers and white light emitting diodes (w-LEDs). Raman spectrum recorded for an undoped glass is used to measure the phonon energy of the host glass and various functional groups present in the host glass (AEBT). The intensities of the electronic transitions and the ligand environment around the Dy³⁺ ions were studied by applying Judd-Ofelt (J-O) theory to the recorded absorption spectra of the glasses. The evaluated J-O parameters are subsequently used to measure various radiative parameters such as transition probability (AR), radiative branching ratio (βR) and radiative lifetimes (τR) for the prominent fluorescent levels of Dy³⁺ ions in the as-prepared glasses. The luminescence spectra recorded at 387 nm excitation show three emission transitions (⁴F9/2→⁶H15/2 (blue), ⁴F9/2→⁶H13/2 (yellow) and ⁴F9/2 → ⁶H11/2 (red)) of which the yellow transition observed at 575 nm is found to be highly intense. The experimental branching ratio (βexp) and stimulated emission crosssection (σse) were measured from luminescence spectra. The experimental lifetimes (τexp) measured from the decay spectral profiles are combined with radiative lifetimes to measure quantum efficiencies of the as-prepared glasses. The yellow to blue intensity ratios and chromaticity color coordinates are found to vary with Dy³⁺ ion concentrations. The aforementioned results reveal that these glasses are aptly suitable for w-LEDs and laser devices. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=glasses" title="glasses">glasses</a>, <a href="https://publications.waset.org/abstracts/search?q=J-O%20parameters" title=" J-O parameters"> J-O parameters</a>, <a href="https://publications.waset.org/abstracts/search?q=photoluminescence" title=" photoluminescence"> photoluminescence</a>, <a href="https://publications.waset.org/abstracts/search?q=I-H%20model" title=" I-H model"> I-H model</a> </p> <a href="https://publications.waset.org/abstracts/88085/spectroscopic-studies-of-dy3-ions-in-alkaline-earth-boro-tellurite-glasses-for-optoelectronic-devices" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/88085.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">157</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">248</span> Spectroscopic and 1.08mm Laser Properties of Nd3+ Doped Oxy-Fluoro Borate Glasses</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Swapna%20Koneru">Swapna Koneru</a>, <a href="https://publications.waset.org/abstracts/search?q=Srinivasa%20Rao%20Allam"> Srinivasa Rao Allam</a>, <a href="https://publications.waset.org/abstracts/search?q=Vijaya%20Prakash%20Gaddem"> Vijaya Prakash Gaddem</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The different concentrations of neodymium-doped (Nd-doped) oxy fluoroborate (OFB) glasses were prepared by melt quenching method and characterized through optical absorption, emission and decay curve measurements to understand the lasing potentialities of these glasses. Optical absorption spectra were recorded and have been analyzed using Judd–Ofelt theory. The dipole strengths are parameterized in terms of three phenomenological Judd–Ofelt intensity parameters Ωλ (λ=2, 4 and 6) to elucidate the glassy matrix around Nd3+ ion as well as to determine the 4F3/2 metastable state radiative properties such as the transition probability (AR), radiative lifetime (τR), branching ratios (βR) and integrated absorption cross-section (σa) have been measured for most of the fluorescent levels of Nd3+. The emission spectra recorded for these glasses exhibit two peaks at 1085 and 1328 nm corresponding to 4F3/2 to 4I11/2 and 4I13/2 transitions have been obtained for all the glasses upon 808 nm diode laser excitation in the near infrared region. The emission intensity of the 4F3/2 to 4I11/2 transition increases with increase of Nd3+ concentration up to 1 mol% and then concentration quenching is observed for 2.0 mol% of Nd3+ concentration. The lifetimes for the 4F3/2 level are found to decrease with increase in Nd2O3 concentration in the glasses due to the concentration quenching. The decay curves of all these glasses show single exponential behavior. The spectroscopy of Nd3+ in these glasses is well understood and laser properties can be accurately determined from measured spectroscopic properties. The results obtained are compared with reports on similar glasses. The results indicate that the present glasses could be useful for 1.08 µm laser applications. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=glasses" title="glasses">glasses</a>, <a href="https://publications.waset.org/abstracts/search?q=luminescence" title=" luminescence"> luminescence</a>, <a href="https://publications.waset.org/abstracts/search?q=optical%20properties" title=" optical properties"> optical properties</a>, <a href="https://publications.waset.org/abstracts/search?q=photoluminescence%20spectroscopy" title=" photoluminescence spectroscopy "> photoluminescence spectroscopy </a> </p> <a href="https://publications.waset.org/abstracts/47257/spectroscopic-and-108mm-laser-properties-of-nd3-doped-oxy-fluoro-borate-glasses" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/47257.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">289</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">247</span> Crystallization in the TeO2 - Ta2O5 - Bi2O3 System: From Glass to Anti-Glass to Transparent Ceramic</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Hasnaa%20Benchorfi">Hasnaa Benchorfi</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The Tellurite glasses exhibit interesting properties, notably their low melting point (700-900°C), high refractive index (≈2), high transparency in the infrared region (up to 5−6 μm), interesting linear and non-linear optical properties and high rare earth ions solubility. These properties give tellurite glasses a great interest in various optical applications. Transparent ceramics present advantages compared to glasses, such as improved mechanical, thermal and optical properties. But, the elaboration process of these ceramics requires complex sintering conditions. The full crystallization of glass into transparent ceramics is an alternative to circumvent the technical challenges related to the ceramics obtained by conventional processing. In this work, a crystallization study of a specific glass composition in the system TeO2-Ta2O5-Bi2O3 shows structural transitions from the glass to the stabilization of an unreported anti-glass phase to a transparent ceramic upon heating. An anti-glass is a material with a cationic long-range order and a disordered anion sublattice. Thus, the X-ray diffraction patterns show sharp peaks, while the Raman bands are broad and similar to those of the parent glass. The structure and microstructure of the anti-glass and corresponding ceramic were characterized by Powder X-Ray Diffraction, Electron Back Scattered Diffraction, Transmission Electron Microscopy and Raman spectroscopy. The optical properties of the Er3+-doped samples are also discussed. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=glass" title="glass">glass</a>, <a href="https://publications.waset.org/abstracts/search?q=congruent%20crystallization" title=" congruent crystallization"> congruent crystallization</a>, <a href="https://publications.waset.org/abstracts/search?q=anti-glass" title=" anti-glass"> anti-glass</a>, <a href="https://publications.waset.org/abstracts/search?q=glass-ceramic" title=" glass-ceramic"> glass-ceramic</a>, <a href="https://publications.waset.org/abstracts/search?q=optics" title=" optics"> optics</a> </p> <a href="https://publications.waset.org/abstracts/167709/crystallization-in-the-teo2-ta2o5-bi2o3-system-from-glass-to-anti-glass-to-transparent-ceramic" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/167709.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">79</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">246</span> Liquid-Liquid Transitions in Strontium Tellurite Melts</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Rajinder%20Kaur">Rajinder Kaur</a>, <a href="https://publications.waset.org/abstracts/search?q=Atul%20Khanna"> Atul Khanna</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Transparent glass-ceramic and crystalline samples of the system: xSrO-(100-x)TeO2; x = 7.5 and 8.5 mol% were prepared by quenching the melts in the temperature range of 700 to 950oC. A very interesting effect of the temperature on the glass-forming ability (GFA) of strontium tellurite melts is observed,and it is found that the melts produce transparent glass-ceramics when it is solidified from lower temperatures in the range of 700-750oC, however, when the melts are cooled from higher temperatures in the range of 850-950oC, the GFA is significantly reduced andanti-glass and/or crystalline phases are produced on solidification.The effect of temperature on GFA of strontium tellurite melts is attributed to short-range structural transformations: TeO₄TeO₃ which procceds towards the right side with an increrase in temperature. This isomerization reaction lowers the melt viscosity and enhances the crystallization tedendency. It is concluded that the high-temperature strontium tellurite meltsfreeze faster into crystalline phases as compared to the melts at a lower temperature; the latter supercooland solidify into glassy phases. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=anti-glasss" title="anti-glasss">anti-glasss</a>, <a href="https://publications.waset.org/abstracts/search?q=ceramic" title=" ceramic"> ceramic</a>, <a href="https://publications.waset.org/abstracts/search?q=supercool%20liquid" title=" supercool liquid"> supercool liquid</a>, <a href="https://publications.waset.org/abstracts/search?q=raman%20spectroscopy" title=" raman spectroscopy"> raman spectroscopy</a> </p> <a href="https://publications.waset.org/abstracts/152495/liquid-liquid-transitions-in-strontium-tellurite-melts" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/152495.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">82</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">245</span> Effects of Phase and Morphology on the Electrochemical and Electrochromic Performances of Tungsten Oxide and Tungsten-Molybdenum Oxide Nanostructures</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Jinjoo%20Jung">Jinjoo Jung</a>, <a href="https://publications.waset.org/abstracts/search?q=Hayeon%20Won"> Hayeon Won</a>, <a href="https://publications.waset.org/abstracts/search?q=Doyeong%20Jeong"> Doyeong Jeong</a>, <a href="https://publications.waset.org/abstracts/search?q=Do%20Hyung%20Kim"> Do Hyung Kim</a> </p> <p class="card-text"><strong>Abstract:</strong></p> We present the electrochemical and electrochromic performance of the novel crystalline tungsten oxide and tungsten-molybdenum oxide nanostructures synthesized by utilizing solvo-thermal method with hexacarbonyl tungsten, hexacarbonyl molybdenum, and ethyl alcohol. The morphology and phase of the prepared products were highly dependent on the synthesis conditions such as synthesis and annealing temperature, synthesis time, and precursor ratio. The tungsten oxide nanostructures (TCNs) have urchin-like or spherical nanostructure with different phase of W18O49 and WO3. The morphology of tungsten-molybdenum oxide nanostructures (TMONs) is basically similar to that of TCNs. However, the morphology and phase of TMONs are more diverse and are strongly dependent on the composition ratios of W/Mo in the precursor. The electrochemical properties depending on their morphologies and phases of TCNs and TMONs are compared using cyclic voltammetry and galvanostatic charge/discharge tests. The relationship between the electrochromic performance and phase structures/morphologies of nanostructured TCNs and TMONs are systematically investigated. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=electrochemical" title="electrochemical">electrochemical</a>, <a href="https://publications.waset.org/abstracts/search?q=electrochromic" title=" electrochromic"> electrochromic</a>, <a href="https://publications.waset.org/abstracts/search?q=tungsten%20oxide" title=" tungsten oxide"> tungsten oxide</a>, <a href="https://publications.waset.org/abstracts/search?q=tungsten-molybdenum%20oxide" title=" tungsten-molybdenum oxide"> tungsten-molybdenum oxide</a> </p> <a href="https://publications.waset.org/abstracts/21623/effects-of-phase-and-morphology-on-the-electrochemical-and-electrochromic-performances-of-tungsten-oxide-and-tungsten-molybdenum-oxide-nanostructures" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/21623.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">590</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">244</span> Simulation of Immiscibility Regions in Sodium Borosilicate Glasses</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Djamila%20Aboutaleb">Djamila Aboutaleb</a>, <a href="https://publications.waset.org/abstracts/search?q=Brahim%20Safi"> Brahim Safi</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In this paper, sodium borosilicates glasses were prepared by melting in air. These heat-resistant transparent glasses have subjected subsequently isothermal treatments at different times, which have transformed them at opaque glass (milky white color). Such changes indicate that these glasses showed clearly phase separation (immiscibility). The immiscibility region in a sodium borosilicate ternary system was investigated in this work, i.e. to determine the regions from which some compositions can show phase separation. For this we went through the conditions of thermodynamic equilibrium, which were translated later by mathematical equations to find an approximate solution. The latter has been translated in a simulation which was established thereafter to find the immiscibility regions in this type of special glasses. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=sodium%20borosilicate" title="sodium borosilicate">sodium borosilicate</a>, <a href="https://publications.waset.org/abstracts/search?q=heat-resistant" title=" heat-resistant"> heat-resistant</a>, <a href="https://publications.waset.org/abstracts/search?q=isothermal%20treatments" title=" isothermal treatments"> isothermal treatments</a>, <a href="https://publications.waset.org/abstracts/search?q=immiscibility" title=" immiscibility"> immiscibility</a>, <a href="https://publications.waset.org/abstracts/search?q=thermodynamics" title=" thermodynamics"> thermodynamics</a> </p> <a href="https://publications.waset.org/abstracts/6617/simulation-of-immiscibility-regions-in-sodium-borosilicate-glasses" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/6617.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">337</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">243</span> Optical and Luminescence Studies on Dy³+ Singly Doped and Dy³+/Ce³+ Co-doped Alumina Borosilicate Glasses for Photonics Device Application</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=M.%20Monisha">M. Monisha</a>, <a href="https://publications.waset.org/abstracts/search?q=Sudha%20D.%20Kamath"> Sudha D. Kamath</a> </p> <p class="card-text"><strong>Abstract:</strong></p> We investigate the optical and photoluminescence properties from Dy³+ singly doped and Dy³+ co-doped with Ce³+alumino borosilicate glasses prepared using high temperature melt-quenching technique. The glass composition formula is 25SiO₂-(40-x-y)B2O₃-10Al₂O₃-15NaF-10ZnO-xDy₂O₃ yCe₂O₃ where, x = 0.5 mol% and y = 0, 0.1, and 0.5 mol%. The XRD study reveals the amorphous nature of both singly doped and co-doped glasses. Absorption study on Dy3+ singly doped glass shows nearly twelve absorption peaks arising from the ground level of Dy³+ ions (⁶H₁₅/₂) to various upper levels, and for Dy³+/Ce³+ co-doped glasses, few of the transitions in the visible region are suppressed. The absorption band edge is shifted towards the higher wavelength region on increasing Ce3+concentration. The decrease in indirect energy bandgap and increase in Urbach energy of the prepared glasses is observed due to codoping with Ce3+ ions. The photoluminescence studies on singly doped glass under 350 nm excitation showed three peaks at the blue (482 nm), yellow (575 nm), and red (663 nm) region. For codoped glasses, the emission peak at 403 nm is raised due to the 4d to 5f transition of Ce3+ ions. Lifetime values (ms) of co-doped glass is found to be higher than singly doped glass. Under 350 nm excitation, CIE coordinates of the co-doped glasses moved towards the bright white light region. The correlated color temperature (CCT) values were obtained in the range 4500 – 4700 K. Thus, the prepared glasses can be used for photonics device applications. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=absorption%20spectra" title="absorption spectra">absorption spectra</a>, <a href="https://publications.waset.org/abstracts/search?q=borosilicate%20glasses" title=" borosilicate glasses"> borosilicate glasses</a>, <a href="https://publications.waset.org/abstracts/search?q=Ce%C2%B3%2B" title=" Ce³+"> Ce³+</a>, <a href="https://publications.waset.org/abstracts/search?q=Dy%C2%B3%2B" title=" Dy³+"> Dy³+</a>, <a href="https://publications.waset.org/abstracts/search?q=photoluminescence" title=" photoluminescence"> photoluminescence</a> </p> <a href="https://publications.waset.org/abstracts/143577/optical-and-luminescence-studies-on-dy3-singly-doped-and-dy3ce3-co-doped-alumina-borosilicate-glasses-for-photonics-device-application" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/143577.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">149</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">242</span> Effect of N2 Pretreatment on the Properties of Tungsten Based Catalysts in Metathesis of Ethylene and 2-Butene</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Kriangkrai%20Aranyarat">Kriangkrai Aranyarat</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The effect of N2 pretreatment on the catalytic activity of tungsten-based catalysts was investigated in the metathesis of ethylene and trans-2-butene at 450oC and atmospheric pressure. The presence of tungsten active species was confirmed by UV-Vis and Raman spectroscopy. Compared to the WO3-based catalysts treated in air, higher amount of WO42- tetrahedral species and lower amount of WO3 crystalline species were observed on the N2-treated ones. These contribute to the higher conversion of 2-butene and propylene selectivity during 10 h time-on-stream. Moreover, N2 treatment led to lower amount of coke formation as revealed by TPO of the spent catalysts. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=metathesis" title="metathesis">metathesis</a>, <a href="https://publications.waset.org/abstracts/search?q=pretreatment" title=" pretreatment"> pretreatment</a>, <a href="https://publications.waset.org/abstracts/search?q=propylene" title=" propylene"> propylene</a>, <a href="https://publications.waset.org/abstracts/search?q=tungsten" title=" tungsten"> tungsten</a> </p> <a href="https://publications.waset.org/abstracts/25492/effect-of-n2-pretreatment-on-the-properties-of-tungsten-based-catalysts-in-metathesis-of-ethylene-and-2-butene" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/25492.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">468</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">241</span> Preparation and Characterization of Nickel-Tungsten Nanoparticles Using Microemulsion Mediated Synthesis</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=S.%20Pal">S. Pal</a>, <a href="https://publications.waset.org/abstracts/search?q=R.%20Singh"> R. Singh</a>, <a href="https://publications.waset.org/abstracts/search?q=S.%20Sivakumar"> S. Sivakumar</a>, <a href="https://publications.waset.org/abstracts/search?q=D.%20Kunzru"> D. Kunzru</a> </p> <p class="card-text"><strong>Abstract:</strong></p> AOT stabilized reverse micelles of deionized water, dispersed in isooctane have been used to synthesize bimetallic nickel tungsten nanoparticles. Prepared nanoparticles were supported on γ-Al2O3 followed by calcination at 500oC. Characterizations of the nanoparticles were done by TEM, XRD, FTIR, XRF, TGA and BET. XRF results showed that this method gave good composition control with W/Ni weight ratio equal to 3.2. TEM images showed particle size of 5-10 nm. Removal of surfactant after calcination was confirmed by TGA and FTIR. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=nanoparticles" title="nanoparticles">nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=reverse%20micelles" title=" reverse micelles"> reverse micelles</a>, <a href="https://publications.waset.org/abstracts/search?q=nickel" title=" nickel"> nickel</a>, <a href="https://publications.waset.org/abstracts/search?q=tungsten" title=" tungsten "> tungsten </a> </p> <a href="https://publications.waset.org/abstracts/19384/preparation-and-characterization-of-nickel-tungsten-nanoparticles-using-microemulsion-mediated-synthesis" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/19384.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">591</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">240</span> Study and Analyze of Metallic Glasses for Biomedical Applications: From Soft to Bone Tissue Engineering</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=A.%20Monfared">A. Monfared</a>, <a href="https://publications.waset.org/abstracts/search?q=S.%20Faghihi"> S. Faghihi</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Metallic glasses (MGs) are newcomers in the field of metals that show great potential for soft and bone tissue engineering due to the amorphous structure that endows unique properties. Up to now, various MGs based on Ti, Zr, Mg, Zn, Fe, Ca, and Sr in the form of a ribbon, bulk, thin-film, and powder have been investigated for biomedical purposes. This article reviews the compositions and biomedical properties of MGs as well as analyzes results in order to guide new approaches and future development of MGs. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=metallic%20glasses" title="metallic glasses">metallic glasses</a>, <a href="https://publications.waset.org/abstracts/search?q=biomaterials" title=" biomaterials"> biomaterials</a>, <a href="https://publications.waset.org/abstracts/search?q=biocompatibility" title=" biocompatibility"> biocompatibility</a>, <a href="https://publications.waset.org/abstracts/search?q=biocorrosion" title=" biocorrosion"> biocorrosion</a> </p> <a href="https://publications.waset.org/abstracts/142754/study-and-analyze-of-metallic-glasses-for-biomedical-applications-from-soft-to-bone-tissue-engineering" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/142754.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">213</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">239</span> Study on the Relationship between the Emission Property of Barium-Tungsten Cathode and Micro-Area Activity</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Zhen%20Qin">Zhen Qin</a>, <a href="https://publications.waset.org/abstracts/search?q=Yufei%20Peng"> Yufei Peng</a>, <a href="https://publications.waset.org/abstracts/search?q=Jianbei%20Li"> Jianbei Li</a>, <a href="https://publications.waset.org/abstracts/search?q=Jidong%20Long"> Jidong Long</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In order to study the activity of the coated aluminate barium-tungsten cathodes during activation, aging, poisoning and long-term use. Through a set of hot-cathode micro-area emission uniformity study device, we tested the micro-area emission performance of the cathode under different conditions. The change of activity of cathode micro-area was obtained. The influence of micro-area activity on the performance of the cathode was explained by the ageing model of barium-tungsten cathode. This helps to improve the design and process of the cathode and can point the way in finding the factors that affect life in the cathode operation. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=barium-tungsten%20cathode" title="barium-tungsten cathode">barium-tungsten cathode</a>, <a href="https://publications.waset.org/abstracts/search?q=ageing%20model" title=" ageing model"> ageing model</a>, <a href="https://publications.waset.org/abstracts/search?q=micro-area%20emission" title=" micro-area emission"> micro-area emission</a>, <a href="https://publications.waset.org/abstracts/search?q=emission%20uniformity" title=" emission uniformity"> emission uniformity</a> </p> <a href="https://publications.waset.org/abstracts/64095/study-on-the-relationship-between-the-emission-property-of-barium-tungsten-cathode-and-micro-area-activity" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/64095.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">408</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">238</span> The Chemical Transport Mechanism of Emitter Micro-Particles in Tungsten Electrode: A Metallurgical Study</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=G.%20Singh">G. Singh</a>, <a href="https://publications.waset.org/abstracts/search?q=H.Schuster"> H.Schuster</a>, <a href="https://publications.waset.org/abstracts/search?q=U.%20F%C3%BCssel"> U. Füssel</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The stability of electric arc and durability of electrode tip used in Tungsten Inert Gas (TIG) welding demand a metallurgical study about the chemical transport mechanism of emitter oxide particles in tungsten electrode during its real welding conditions. The tungsten electrodes doped with emitter oxides of rare earth oxides such as La₂O₃, Th₂O₃, Y₂O₃, CeO₂ and ZrO₂ feature a comparatively lower work function than tungsten and thus have superior emission characteristics due to lesser surface temperature of the cathode. The local change in concentration of these emitter particles in tungsten electrode due to high temperature diffusion (chemical transport) can change its functional properties like electrode temperature, work function, electron emission, and stability of the electrode tip shape. The resulting increment in tip surface temperature results in the electrode material loss. It was also observed that the tungsten recrystallizes to large grains at high temperature. When the shape of grain boundaries are granular in shape, the intergranular diffusion of oxide emitter particles takes more time to reach the electrode surface. In the experimental work, the microstructure of the used electrode's tip surface will be studied by scanning electron microscope and reflective X-ray technique in order to gauge the extent of the diffusion and chemical reaction of emitter particles. Besides, a simulated model is proposed to explain the effect of oxide particles diffusion on the electrode’s microstructure, electron emission characteristics, and electrode tip erosion. This model suggests metallurgical modifications in tungsten electrode to enhance its erosion resistance. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=rare-earth%20emitter%20particles" title="rare-earth emitter particles">rare-earth emitter particles</a>, <a href="https://publications.waset.org/abstracts/search?q=temperature-dependent%20diffusion" title=" temperature-dependent diffusion"> temperature-dependent diffusion</a>, <a href="https://publications.waset.org/abstracts/search?q=TIG%20welding" title=" TIG welding"> TIG welding</a>, <a href="https://publications.waset.org/abstracts/search?q=Tungsten%20electrode" title=" Tungsten electrode"> Tungsten electrode</a> </p> <a href="https://publications.waset.org/abstracts/89406/the-chemical-transport-mechanism-of-emitter-micro-particles-in-tungsten-electrode-a-metallurgical-study" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/89406.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">186</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">237</span> Structural Investigation of Na2O–B2O3–SiO2 Glasses Doped with NdF3</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=M.%20S.%20Gaafar">M. S. Gaafar</a>, <a href="https://publications.waset.org/abstracts/search?q=S.%20Y.%20Marzouk"> S. Y. Marzouk</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Sodium borosilicate glasses doped with different content of NdF3 mol % have been prepared by rapid quenching method. Ultrasonic velocities (both longitudinal and shear) measurements have been carried out at room temperature and at ultrasonic frequency of 4 MHz. Elastic moduli, Debye temperature, softening temperature and Poisson's ratio have been obtained as a function of NdF3 modifier content. Results showed that the elastic moduli, Debye temperature, softening temperature and Poisson's ratio have very slight change with the change of NdF3 mol % content. Based on FTIR spectroscopy and theoretical (Bond compression) model, quantitative analysis has been carried out in order to obtain more information about the structure of these glasses. The study indicated that the structure of these glasses is mainly composed of SiO4 units with four bridging oxygens (Q4), and with three bridging and one nonbridging oxygens (Q3). <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=borosilicate%20glasses" title="borosilicate glasses">borosilicate glasses</a>, <a href="https://publications.waset.org/abstracts/search?q=ultrasonic%20velocity" title=" ultrasonic velocity"> ultrasonic velocity</a>, <a href="https://publications.waset.org/abstracts/search?q=elastic%20moduli" title=" elastic moduli"> elastic moduli</a>, <a href="https://publications.waset.org/abstracts/search?q=FTIR%20spectroscopy" title=" FTIR spectroscopy"> FTIR spectroscopy</a>, <a href="https://publications.waset.org/abstracts/search?q=bond%20compression%20model" title=" bond compression model"> bond compression model</a> </p> <a href="https://publications.waset.org/abstracts/43470/structural-investigation-of-na2o-b2o3-sio2-glasses-doped-with-ndf3" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/43470.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">414</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">236</span> Gas Tungsten Arc Welded Joints of Cast Al-Mg-Sc Alloy</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=K.%20Subbaiah">K. Subbaiah</a>, <a href="https://publications.waset.org/abstracts/search?q=C.%20V.%20Jeyakumar"> C. V. Jeyakumar</a>, <a href="https://publications.waset.org/abstracts/search?q=S.%20R.%20Koteswara%20Rao"> S. R. Koteswara Rao</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Cast Aluminum-Magnesium-Scandium alloy was Gas Tungsten Arc (GTA) welded, and the microstructure and mechanical properties of the joint and its component parts were examined and analyzed. The global joint fractured in the base metal, and thus possessed slightly greater tensile strength than the base metal. These results clearly show that Gas Tungsten Arc welding is an optimum / suitable welding process for cast Aluminum-Magnesium-Scandium alloys. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=cast%20Al-Mg-Sc%20alloy" title="cast Al-Mg-Sc alloy">cast Al-Mg-Sc alloy</a>, <a href="https://publications.waset.org/abstracts/search?q=GTAW" title=" GTAW"> GTAW</a>, <a href="https://publications.waset.org/abstracts/search?q=microstructure" title=" microstructure"> microstructure</a>, <a href="https://publications.waset.org/abstracts/search?q=mechanical%20properties" title=" mechanical properties"> mechanical properties</a> </p> <a href="https://publications.waset.org/abstracts/18496/gas-tungsten-arc-welded-joints-of-cast-al-mg-sc-alloy" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/18496.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">412</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">235</span> Physical Properties and Elastic Studies of Fluoroaluminate Glasses Based on Alkali</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=C.%20Benhamideche">C. Benhamideche</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Fluoroaluminate glasses have been reported as the earliest heavy metal fluoride glasses. By comparison with flurozirconate glasses, they offer a set of similar optical features, but also some differences in their elastic and chemical properties. In practice they have been less developed because their stability against devitrification is smaller than that of the most stable fluoroziconates. The purpose of this study was to investigate glass formation in systems AlF3-YF3-PbF2-MgF2-MF2 (M= Li, Na, K). Synthesis was implemented at room atmosphere using the ammonium fluoride processing. After fining, the liquid was into a preheated brass mold, then annealed below the glass transition temperature for several hours. The samples were polished for optical measurements. Glass formation has been investigated in a systematic way, using pseudo ternary systems in order to allow parameters to vary at the same time. We have chosen the most stable glass compositions for the determination of the physical properties. These properties including characteristic temperatures, density and proprieties elastic. Glass stability increases in multicomponent glasses. Bulk samples have been prepared for physical characterization. These glasses have a potential interest for passive optical fibers because they are less sensitive to water attack than ZBLAN glass, mechanically stronger. It is expected they could have a larger damage threshold for laser power transmission. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=fluoride%20glass" title="fluoride glass">fluoride glass</a>, <a href="https://publications.waset.org/abstracts/search?q=aluminium%20fluoride" title=" aluminium fluoride"> aluminium fluoride</a>, <a href="https://publications.waset.org/abstracts/search?q=thermal%20properties" title=" thermal properties"> thermal properties</a>, <a href="https://publications.waset.org/abstracts/search?q=density" title=" density"> density</a>, <a href="https://publications.waset.org/abstracts/search?q=proprieties%20elastic" title=" proprieties elastic"> proprieties elastic</a> </p> <a href="https://publications.waset.org/abstracts/38380/physical-properties-and-elastic-studies-of-fluoroaluminate-glasses-based-on-alkali" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/38380.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">241</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">234</span> In-Vitro and Antibacterial Studies for Silicate-Phosphate Glasses Formed with Biosynthesized Silica </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Damandeep%20Kaur">Damandeep Kaur</a>, <a href="https://publications.waset.org/abstracts/search?q=O.P.%20Pandey"> O.P. Pandey</a>, <a href="https://publications.waset.org/abstracts/search?q=M.S.%20Reddy"> M.S. Reddy</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In the present research, bio-synthesisation of silica particles has been carried out successfully. For this purpose, agriculture waste rice husk (RH) has been utilized. Among several types of agriculture waste, RH is considered to be cost-effective and easily accessible. In the present investigation, a chemical approach has been followed to extract silica nanoparticles. X-Ray Diffraction (XRD) patterns indicated the amorphous nature of silica at lower temperature range. Silica and other mineral contents have been found using energy dispersive spectroscopy (EDS). Morphological and structural studies have been carried out with the use of Field Emission Scanning Electron Microscopy (FE-SEM) and Fourier Transform Infrared Transmission (FTIR) spectroscopy. Further, extracted silica from RH has been used for preparation of the glasses. The appearance of broad humps in XRD patterns confirmed the amorphous nature of prepared glasses. These glasses exhibited enhanced antibacterial effect against both Gram-positive and Gram-negative bacteria. The as-synthesized glass samples can be further used for physical and structural studies for drug loading applications. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=rice%20husk" title="rice husk">rice husk</a>, <a href="https://publications.waset.org/abstracts/search?q=biosynthesized%20silica" title=" biosynthesized silica"> biosynthesized silica</a>, <a href="https://publications.waset.org/abstracts/search?q=bioactive%20glasses" title=" bioactive glasses"> bioactive glasses</a>, <a href="https://publications.waset.org/abstracts/search?q=antibacterial%20studies" title=" antibacterial studies"> antibacterial studies</a> </p> <a href="https://publications.waset.org/abstracts/125359/in-vitro-and-antibacterial-studies-for-silicate-phosphate-glasses-formed-with-biosynthesized-silica" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/125359.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">114</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">233</span> Synthesis, Structure and Functional Characteristics of Solid Electrolytes Based on Lanthanum Niobates</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Maria%20V.%20Morozova">Maria V. Morozova</a>, <a href="https://publications.waset.org/abstracts/search?q=Yulia%20V.%20Emelyanova"> Yulia V. Emelyanova</a>, <a href="https://publications.waset.org/abstracts/search?q=Anastasia%20A.%20Levina"> Anastasia A. Levina</a>, <a href="https://publications.waset.org/abstracts/search?q=Elena%20S.%20Buyanova"> Elena S. Buyanova</a>, <a href="https://publications.waset.org/abstracts/search?q=Zoya%20A.%20Mikhaylovskaya"> Zoya A. Mikhaylovskaya</a>, <a href="https://publications.waset.org/abstracts/search?q=Sofia%20A.%20Petrova"> Sofia A. Petrova</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The solid solutions of lanthanum niobates substituted by yttrium, bismuth and tungsten were synthesized. The structure of the solid solutions is either LaNbO4-based monoclinic or BiNbO4-based triclinic. The series where niobium is substituted by tungsten on B site reveals phase-modulated structure. The values of cell parameters decrease with increasing the dopant concentration for all samples except the tungsten series although the latter show higher total conductivity. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=impedance%20spectroscopy" title="impedance spectroscopy">impedance spectroscopy</a>, <a href="https://publications.waset.org/abstracts/search?q=LaNbO4" title=" LaNbO4"> LaNbO4</a>, <a href="https://publications.waset.org/abstracts/search?q=lanthanum%20ortho-niobates" title=" lanthanum ortho-niobates"> lanthanum ortho-niobates</a>, <a href="https://publications.waset.org/abstracts/search?q=solid%20electrolyte" title=" solid electrolyte"> solid electrolyte</a> </p> <a href="https://publications.waset.org/abstracts/38426/synthesis-structure-and-functional-characteristics-of-solid-electrolytes-based-on-lanthanum-niobates" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/38426.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">482</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">232</span> Application of Recycled Tungsten Carbide Powder for Fabrication of Iron Based Powder Metallurgy Alloy</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Yukinori%20Taniguchi">Yukinori Taniguchi</a>, <a href="https://publications.waset.org/abstracts/search?q=Kazuyoshi%20Kurita"> Kazuyoshi Kurita</a>, <a href="https://publications.waset.org/abstracts/search?q=Kohei%20Mizuta"> Kohei Mizuta</a>, <a href="https://publications.waset.org/abstracts/search?q=Keigo%20Nishitani"> Keigo Nishitani</a>, <a href="https://publications.waset.org/abstracts/search?q=Ryuichi%20Fukuda"> Ryuichi Fukuda</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Tungsten carbide is widely used as a tool material in metal manufacturing process. Since tungsten is typical rare metal, establishment of recycle process of tungsten carbide tools and restore into cemented carbide material bring great impact to metal manufacturing industry. Recently, recycle process of tungsten carbide has been developed and established gradually. However, the demands for quality of cemented carbide tool are quite severe because hardness, toughness, anti-wear ability, heat resistance, fatigue strength and so on should be guaranteed for precision machining and tool life. Currently, it is hard to restore the recycled tungsten carbide powder entirely as raw material for new processed cemented carbide tool. In this study, to suggest positive use of recycled tungsten carbide powder, we have tried to fabricate a carbon based sintered steel which shows reinforced mechanical properties with recycled tungsten carbide powder. We have made set of newly designed sintered steels. Compression test of sintered specimen in density ratio of 0.85 (which means 15% porosity inside) has been conducted. As results, at least 1.7 times higher in nominal strength in the amount of 7.0 wt.% was shown in recycled WC powder. The strength reached to over 600 MPa for the Fe-WC-Co-Cu sintered alloy. Wear test has been conducted by using ball-on-disk type friction tester using 5 mm diameter ball with normal force of 2 N in the dry conditions. Wear amount after 1,000 m running distance shows that about 1.5 times longer life was shown in designed sintered alloy. Since results of tensile test showed that same tendency in previous testing, it is concluded that designed sintered alloy can be used for several mechanical parts with special strength and anti-wear ability in relatively low cost due to recycled tungsten carbide powder. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=tungsten%20carbide" title="tungsten carbide">tungsten carbide</a>, <a href="https://publications.waset.org/abstracts/search?q=recycle%20process" title=" recycle process"> recycle process</a>, <a href="https://publications.waset.org/abstracts/search?q=compression%20test" title=" compression test"> compression test</a>, <a href="https://publications.waset.org/abstracts/search?q=powder%20metallurgy" title=" powder metallurgy"> powder metallurgy</a>, <a href="https://publications.waset.org/abstracts/search?q=anti-wear%20ability" title=" anti-wear ability"> anti-wear ability</a> </p> <a href="https://publications.waset.org/abstracts/51013/application-of-recycled-tungsten-carbide-powder-for-fabrication-of-iron-based-powder-metallurgy-alloy" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/51013.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">249</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">231</span> Advancing Microstructure Evolution in Tungsten Through Rolling in Laser Powder Bed Fusion</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Narges%20Shayesteh%20Moghaddam">Narges Shayesteh Moghaddam</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Tungsten (W), a refractory metal known for its remarkably high melting temperature, offers tremendous potential for use in challenging environments prevalent in sectors such as space exploration, defense, and nuclear industries. Additive manufacturing, especially the Laser Powder-Bed Fusion (LPBF) technique, emerges as a beneficial method for fabricating tungsten parts. This technique enables the production of intricate components while simultaneously reducing production lead times and associated costs. However, the inherent brittleness of tungsten and its tendency to crack under high-temperature conditions pose significant challenges to the manufacturing process. Our research primarily focuses on the process of rolling tungsten parts in a layer-by-layer manner in LPBF and the subsequent changes in microstructure. Our objective is not only to identify the alterations in the microstructure but also to assess their implications on the physical properties and performance of the fabricated tungsten parts. To examine these aspects, we conducted an extensive series of experiments that included the fabrication of tungsten samples through LPBF and subsequent characterization using advanced materials analysis techniques. These investigations allowed us to scrutinize shifts in various microstructural features, including, but not limited to, grain size and grain boundaries occurring during the rolling process. The results of our study provide crucial insights into how specific factors, such as plastic deformation occurring during the rolling process, influence the microstructural characteristics of the fabricated parts. This information is vital as it provides a foundation for understanding how the parameters of the layer-by-layer rolling process affect the final tungsten parts. Our research significantly broadens the current understanding of microstructural evolution in tungsten parts produced via the layer-by-layer rolling process in LPBF. The insights obtained will play a pivotal role in refining and optimizing manufacturing parameters, thus improving the mechanical properties of tungsten parts and, therefore, enhancing their performance. Furthermore, these findings will contribute to the advancement of manufacturing techniques, facilitating the wider application of tungsten parts in various high-demand sectors. Through these advancements, this research represents a significant step towards harnessing the full potential of tungsten in high-temperature and high-stress applications. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=additive%20manufacturing" title="additive manufacturing">additive manufacturing</a>, <a href="https://publications.waset.org/abstracts/search?q=rolling" title=" rolling"> rolling</a>, <a href="https://publications.waset.org/abstracts/search?q=tungsten" title=" tungsten"> tungsten</a>, <a href="https://publications.waset.org/abstracts/search?q=refractory%20materials" title=" refractory materials"> refractory materials</a> </p> <a href="https://publications.waset.org/abstracts/169378/advancing-microstructure-evolution-in-tungsten-through-rolling-in-laser-powder-bed-fusion" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/169378.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">97</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">230</span> Spectroscopic Study of Eu³⁺ Ions Doped Potassium Lead Alumino Borate Glasses for Photonic Device Application</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Nisha%20Deopa">Nisha Deopa</a>, <a href="https://publications.waset.org/abstracts/search?q=Allam%20Srinivasa%20Rao"> Allam Srinivasa Rao</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Quaternary potassium lead alumino borate (KPbAlB) glasses doped with different concentration of Eu³⁺ ions have been synthesized by melt quench technique and characterized by X-ray diffraction (XRD), Scanning electron microscope (SEM), Photoluminescence (PL), Time-resolved photoluminescence (TRPL) and CIE-chromaticity co-ordinates to study their luminescence behavior. A broad hump was observed in XRD spectrum confirms glassy nature of as-prepared glasses. By using Judd-Ofelt (J-O) theory, various radiative parameters for the prominent fluorescent levels of Eu³⁺ have been investigated. The intense emission peak was observed at 613 nm (⁵D₀→⁷F₂) under 393 nm excitation, matches well with the excitation of n-UV LED chips. The decay profiles observed for ⁵D₀ level were exponential for lower Eu³⁺ ion concentration while non-exponential for higher concentration, which may be due to efficient energy transfer between Eu³⁺-Eu³⁺ through cross relaxation and subsequent quenching observed. From the emission cross-sections, branching ratios, quantum efficiency and CIE coordinates, it was concluded that 7 mol % of Eu³⁺ ion concentration (glass B) is optimum in KPbAlB glasses for photonic device application. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=energy%20transfer" title="energy transfer">energy transfer</a>, <a href="https://publications.waset.org/abstracts/search?q=glasses" title=" glasses"> glasses</a>, <a href="https://publications.waset.org/abstracts/search?q=J-O%20parameters" title=" J-O parameters"> J-O parameters</a>, <a href="https://publications.waset.org/abstracts/search?q=photoluminescence" title=" photoluminescence"> photoluminescence</a> </p> <a href="https://publications.waset.org/abstracts/88460/spectroscopic-study-of-eu3-ions-doped-potassium-lead-alumino-borate-glasses-for-photonic-device-application" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/88460.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">163</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">229</span> Spectroscopic Investigations of Nd³⁺ Doped Lithium Lead Alumino Borate Glasses for 1.06μM Laser Applications</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Nisha%20Deopa">Nisha Deopa</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20S.%20Rao"> A. S. Rao</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Neodymium doped lithium lead alumino borate glasses were synthesized with the molar composition 10Li₂O – 10PbO – (10-x) Al₂O₃ – 70B₂O₃ – xNd₂O₃ (where, x = 0.1, 0.5, 1.0, 1.5, 2.0 and 2.5 mol %) via conventional melt quenching technique to understand their lasing potentiality. From the absorption spectra, Judd-Ofelt intensity parameters along with various spectroscopic parameters have been estimated. The emission spectra recorded for the as-prepared glasses under investigation exhibit two emission transitions, ⁴F₃/₂→⁴I₁₁/₂ (1063 nm) and ⁴F₃/₂→⁴I₉/₂ (1350 nm) for which radiative parameters have been evaluated. The emission intensity increases with increase in Nd³⁺ ion concentration up to 1 mol %, and beyond concentration quenching took place. The decay profile shows single exponential nature for lower Nd³⁺ ions concentration and non-exponential for higher concentration. To elucidate the nature of energy transfer process, non-exponential decay curves were well fitted to Inokuti-Hirayama model. The relatively high values of emission cross-section, branching ratio, lifetimes and quantum efficiency suggest that 1.0 mol% of Nd³⁺ in LiPbAlB glasses is aptly suitable to generate lasing action in NIR region at 1063 nm. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=energy%20transfer" title="energy transfer">energy transfer</a>, <a href="https://publications.waset.org/abstracts/search?q=glasses" title=" glasses"> glasses</a>, <a href="https://publications.waset.org/abstracts/search?q=J-O%20parameters" title=" J-O parameters"> J-O parameters</a>, <a href="https://publications.waset.org/abstracts/search?q=photoluminescence" title=" photoluminescence"> photoluminescence</a> </p> <a href="https://publications.waset.org/abstracts/78288/spectroscopic-investigations-of-nd3-doped-lithium-lead-alumino-borate-glasses-for-106mm-laser-applications" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/78288.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">189</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">228</span> Interaction of Tungsten Tips with Laguerre-Gaussian Beams</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Abhisek%20Sinha">Abhisek Sinha</a>, <a href="https://publications.waset.org/abstracts/search?q=Debobrata%20Rajak"> Debobrata Rajak</a>, <a href="https://publications.waset.org/abstracts/search?q=Shilpa%20Rani"> Shilpa Rani</a>, <a href="https://publications.waset.org/abstracts/search?q=Ram%20Gopal"> Ram Gopal</a>, <a href="https://publications.waset.org/abstracts/search?q=Vandana%20Sharma"> Vandana Sharma</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The interaction of femtosecond laser pulses with metallic tips has been studied extensively, and they have proved to be a very good source of ultrashort electron pulses. A study of the interaction of femtosecond Laguerre-Gaussian (LG) laser modes with Tungsten tips is presented here. Laser pulses of 35 fs pulse durations were incident on Tungsten tips, and their electron emission rates were studied for LG (l=1, p=0) and Gaussian modes. A change in the order of the interaction for LG beams is reported, and the difference in the order of interaction is attributed to ponderomotive shifts in the energy levels corresponding to the enhanced near-field intensity supported by numerical simulations. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=femtosecond" title="femtosecond">femtosecond</a>, <a href="https://publications.waset.org/abstracts/search?q=Laguerre-Gaussian" title=" Laguerre-Gaussian"> Laguerre-Gaussian</a>, <a href="https://publications.waset.org/abstracts/search?q=OAM" title=" OAM"> OAM</a>, <a href="https://publications.waset.org/abstracts/search?q=tip" title=" tip"> tip</a> </p> <a href="https://publications.waset.org/abstracts/139164/interaction-of-tungsten-tips-with-laguerre-gaussian-beams" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/139164.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">265</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">227</span> Tungsten-Based Powders Produced in Plasma Systems</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Andrey%20V.%20Samokhin">Andrey V. Samokhin</a>, <a href="https://publications.waset.org/abstracts/search?q=Nikolay%20V.%20Alekseev"> Nikolay V. Alekseev</a>, <a href="https://publications.waset.org/abstracts/search?q=Mikhail%20A.%20Sinaiskii"> Mikhail A. Sinaiskii</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The report presents the results of R&D of plasma-chemical production of W, W-Cu, W-Ni-Fe nanopowders as well as spherical micropowders of these compounds for their use in modern 3D printing technologies. Plasma-chemical synthesis of nanopowdersis based on the reduction of tungsten oxide compounds powders in a stream of hydrogen-containing low-temperature thermal plasma generated in an electric arc plasma torch. The synthesis of W-Cu and W-Ni-Fe nanocompositesiscarried out using the reduction of a mixture of the metal oxides. Using the synthesized tungsten-based nanocomposites powders, spherical composite micropowders with a submicron structure canbe manufactured by spray dryinggranulation of nanopowder suspension and subsequent densification and spheroidization of granules by melting in a low-temperature thermal plasma flow. The DC arc plasma systems are usedfor the synthesis of nanopowdersas well as for the spheroidization of microgranuls. Plasma systems have a capacity of up to 1 kg/h for nanopowder and up to 5 kg/h for spheroidized powder. All synthesized nanopowders consist of aggregated particles with sizes less than 100 nm, and nanoparticles of W-Cu and W-Ni-Fe composites have core (W) –shell (Cu or Ni-Fe) structures. The resulting dense spherical microparticles with a size of 20-60 microns have a submicron structure with a uniform distribution of metals over the particle volume. The produced tungsten-based nano- and spherical micropowderscan be used to develop new materials and manufacture products using advanced modern technologies. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=plasma" title="plasma">plasma</a>, <a href="https://publications.waset.org/abstracts/search?q=powders" title=" powders"> powders</a>, <a href="https://publications.waset.org/abstracts/search?q=production" title=" production"> production</a>, <a href="https://publications.waset.org/abstracts/search?q=tungsten-based" title=" tungsten-based"> tungsten-based</a> </p> <a href="https://publications.waset.org/abstracts/147220/tungsten-based-powders-produced-in-plasma-systems" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/147220.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge 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