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(PDF) Study of the cure kinetics and water absorption of the DGEBA/ODA resin | anita hassanpour - Academia.edu

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class="ds-work-card--work-title">Study of the cure kinetics and water absorption of the DGEBA/ODA resin</h1><div class="ds-work-card--work-authors ds-work-card--detail"><a class="ds-work-card--author js-wsj-grid-card-author ds2-5-body-md ds2-5-body-link" data-author-id="48618147" href="https://independent.academia.edu/anitahassanpour"><img alt="Profile image of anita hassanpour" class="ds-work-card--author-avatar" src="//a.academia-assets.com/images/s65_no_pic.png" />anita hassanpour</a></div><p class="ds-work-card--detail ds2-5-body-sm">2007, Iranian Polymer Journal</p><div class="ds-work-card--button-container"><button class="ds2-5-button js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;continue-reading-button--work-card&quot;,&quot;attachmentId&quot;:90453063,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;workUrl&quot;:&quot;https://www.academia.edu/85883228/Study_of_the_cure_kinetics_and_water_absorption_of_the_DGEBA_ODA_resin&quot;}">See full 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ds-top-related-works--container"><h2 class="ds-related-content--heading">Related papers</h2><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="0" data-entity-id="5305306" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/5305306/Isothermal_cure_kinetics_of_a_diglycidyl_ether_of_bisphenol_A_1_3_bisaminomethylcyclohexane_DGEBA_1_3BAC_epoxy_resin_system">Isothermal cure kinetics of a diglycidyl ether of bisphenol A/1,3-bisaminomethylcyclohexane (DGEBA/1,3BAC) epoxy resin system</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="7312082" href="https://independent.academia.edu/lopezjoaquin">joaquin lopez</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Journal of Applied Polymer Science, 1995</p><p class="ds-related-work--abstract ds2-5-body-sm">By employing differential scaning calorimetry, DSC, we have studied, under isothermal conditions, the kinetics of the cure reaction for a system containing a diglycidyl ether of bisphenol A (DGEBA) and 1,3-bisaminomethylcyclohexane (1,3-BAC) as a curing agent, over the temperature range of 60–110°C. We have determined the conversions reached at several cure temperatures and the reaction rates. The experimental data, showing an autocatalytic behavior, were compared with the model proposed by Kamal, which includes two rate constants, k1 and k2, and two reaction orders, m and n. This model gives a good description of cure kinetics up to the onset of vitrification. The activation energies for these rate constants were 44–57 kJ/mol. The reaction orders present a moderate change but their sum is in the range 2.5–3. Diffusion control is incorporated to describe the cure in the latter stages (postivitrification region). By combining the autocatalytic model and a diffusion factor, it was possible to predict the cure kinetics over the whole range of conversion. © 1995 John Wiley &amp; Sons, Inc.</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Isothermal cure kinetics of a diglycidyl ether of bisphenol A/1,3-bisaminomethylcyclohexane (DGEBA/1,3BAC) epoxy resin system&quot;,&quot;attachmentId&quot;:49355821,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/5305306/Isothermal_cure_kinetics_of_a_diglycidyl_ether_of_bisphenol_A_1_3_bisaminomethylcyclohexane_DGEBA_1_3BAC_epoxy_resin_system&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/5305306/Isothermal_cure_kinetics_of_a_diglycidyl_ether_of_bisphenol_A_1_3_bisaminomethylcyclohexane_DGEBA_1_3BAC_epoxy_resin_system"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="1" data-entity-id="89757093" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/89757093/Studies_of_Cure_Kinetics_and_Chemical_Resistance_of_the_Cured_Products_of_DGEBA_with_Aromatic_Diamines">Studies of Cure Kinetics and Chemical Resistance of the Cured Products of DGEBA with Aromatic Diamines</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="51223810" href="https://independent.academia.edu/HosseinBehmadi">Hossein Behmadi</a></div><p class="ds-related-work--metadata ds2-5-body-xs">2006</p><p class="ds-related-work--abstract ds2-5-body-sm">An investigation is conducted into the non-isothermal kinetics of the curing reaction of diglycidyl ether of bisphenol A (DGEBA) epoxy resin with two novel aromatic diamines, 4,4´-diaminostilbene (DAS) and 4,4´-diaminoazobenzene (DAAB), as curing agents. Kinetics analysis of the curing reaction of DGEBA with two different concentrations (29 wt% =0.13 mol% and 19 wt%=0.09 mol%) of the curing agents was studied using non-isothermal differential scanning calorimetry (DSC) technique. Two methods (Ozawa and Kissinger) for analysis of the scanning DSC data were applied to calculate the kinetic parameters and compared with kinetic parameters obtained from isothermal DSC tests using Kamal method. Activation energies in the range of 52.5-59.5 kJ/mol were obtained for both DGEBA/curing agent systems. The water absorption and resistance of the cured products against solutions of H 2 SO 4 and NaOH were also studied. Water uptake curves for both systems are similar. 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translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="7" data-entity-id="7095341" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/7095341/Curing_kinetics_and_thermal_stability_of_diglycidyl_ether_of_bisphenol">Curing kinetics and thermal stability of diglycidyl ether of bisphenol</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="12189830" href="https://independent.academia.edu/PoojaSharma71">Pooja Sharma</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Journal of Thermal Analysis and Calorimetry, 2008</p><p class="ds-related-work--abstract ds2-5-body-sm">Curing kinetics of diglycidyl ether of bisphenol-A (DGEBA) in the presence of varying molar ratios of aromatic imide-amines and 4,4′-diaminodiphenylsulfone (DDS) were investigated by the dynamic differential scanning calorimetry. The imide-amines were prepared by reacting 1 mole of benzophenone 3,3′,4,4′-tetracarboxylic acid dianhydride (B) with 2.5 moles of 4,4′-diaminodiphenyl ether (E)/ or 4,4′-diaminodiphenyl methane (M)/ or 4,4′-diaminodiphenylsulfone (S) and designated as BE/ or BM/ or BS. The mixture of imide-amines and DDS at ratio of 0:1, 0.25:0.75, 0.5:0.5, 0.75:0.25 and 1:0 were used to investigate the curing behaviour of DGEBA. The multiple heating rate method (5, 10, 15 and 20°C min−1) was used to study the curing kinetics of epoxy resins. The peak exotherm temperature was found to be dependent on the heating rate, structure of imide-amines as well as on the ratio of imide-amine: DDS used. A broad exotherm was observed in the temperature range of 180–230°C on curing with mixture of imide-amines and DDS. Curing of DGEBA with mixture of imide-amines and/or DDS resulted in a decrease in characteristic curing temperatures. Activation energy of curing reaction as determined in accordance to the Ozawa’s method was found to be dependent on the structure of amine. The thermal stability of the isothermally cured resins was also evaluated using dynamic thermogravimetry in a nitrogen atmosphere. The char yield was highest in case of resins cured using mixture of DDS: BS (0.25:0.75; EBS-3), DDS: BM (0.5: 0.5; EBM-2) and DDS: BE (0.5: 0.5; EBE-2).</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Curing kinetics and thermal stability of diglycidyl ether of bisphenol&quot;,&quot;attachmentId&quot;:48601912,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/7095341/Curing_kinetics_and_thermal_stability_of_diglycidyl_ether_of_bisphenol&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/7095341/Curing_kinetics_and_thermal_stability_of_diglycidyl_ether_of_bisphenol"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="8" data-entity-id="27156542" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/27156542/Nonisothermal_cure_kinetics_of_DGEBA_with_novel_aromatic_diamine">Nonisothermal cure kinetics of DGEBA with novel aromatic diamine</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="51223810" href="https://independent.academia.edu/HosseinBehmadi">Hossein Behmadi</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Journal of Applied Polymer Science, 2007</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Nonisothermal cure kinetics of DGEBA with novel aromatic diamine&quot;,&quot;attachmentId&quot;:47405970,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/27156542/Nonisothermal_cure_kinetics_of_DGEBA_with_novel_aromatic_diamine&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/27156542/Nonisothermal_cure_kinetics_of_DGEBA_with_novel_aromatic_diamine"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="9" data-entity-id="28800101" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/28800101/Cure_kinetics_of_a_diglycidyl_ether_of_bisphenol_a_epoxy_network_n_0_with_isophorone_diamine">Cure kinetics of a diglycidyl ether of bisphenol a epoxy network ( n = 0) with isophorone diamine</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="33291173" href="https://utfsm.academia.edu/CarlosCastro">Carlos Castro</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Journal of Applied Polymer Science, 2007</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" 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Tripathi</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Journal of Applied Polymer Science, 2009</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Cure kinetics of ternary blends of epoxy resins studied by nonisothermal DSC data&quot;,&quot;attachmentId&quot;:50042789,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/4084167/Cure_kinetics_of_ternary_blends_of_epoxy_resins_studied_by_nonisothermal_DSC_data&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-related-work-grid-card-view-pdf" href="https://www.academia.edu/4084167/Cure_kinetics_of_ternary_blends_of_epoxy_resins_studied_by_nonisothermal_DSC_data"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-related-work-sidebar-card" data-collection-position="3" data-entity-id="97505921" data-sort-order="default"><a class="ds-related-work--title js-related-work-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/97505921/Curing_kinetics_and_mechanical_properties_of_fast_curing_epoxy_resins_with_isophorone_diamine_and_N_3_aminopropyl_imidazole">Curing kinetics and mechanical properties of fast curing epoxy resins with isophorone diamine and N ‐(3‐aminopropyl)‐imidazole</a><div class="ds-related-work--metadata"><a class="js-related-work-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="259032690" href="https://independent.academia.edu/YanfeiZHANG16">Yanfei ZHANG</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Journal of Applied Polymer Science, 2019</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Curing kinetics and mechanical properties of fast curing epoxy resins with isophorone diamine and N ‐(3‐aminopropyl)‐imidazole&quot;,&quot;attachmentId&quot;:99108779,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/97505921/Curing_kinetics_and_mechanical_properties_of_fast_curing_epoxy_resins_with_isophorone_diamine_and_N_3_aminopropyl_imidazole&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-related-work-grid-card-view-pdf" href="https://www.academia.edu/97505921/Curing_kinetics_and_mechanical_properties_of_fast_curing_epoxy_resins_with_isophorone_diamine_and_N_3_aminopropyl_imidazole"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-related-work-sidebar-card" data-collection-position="4" data-entity-id="117179527" data-sort-order="default"><a class="ds-related-work--title js-related-work-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/117179527/Effects_of_diffusion_on_the_kinetic_study_and_TTT_cure_diagram_for_an_epoxy_diamine_system">Effects of diffusion on the kinetic study and TTT cure diagram for an epoxy/diamine system</a><div class="ds-related-work--metadata"><a class="js-related-work-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="45089310" href="https://independent.academia.edu/FragaFrancisco">Francisco Fraga López</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Journal of Applied Polymer Science, 1998</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Effects of diffusion on the kinetic study and TTT cure diagram for an epoxy/diamine system&quot;,&quot;attachmentId&quot;:113104819,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/117179527/Effects_of_diffusion_on_the_kinetic_study_and_TTT_cure_diagram_for_an_epoxy_diamine_system&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free 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data-author-id="15448249" href="https://independent.academia.edu/choudharyveena">veena choudhary</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Journal of Applied Polymer Science, 2007</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;Curing and thermal behavior of DGEBA in presence of dianhydrides and aromatic diamine&quot;,&quot;attachmentId&quot;:116081731,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/121113362/Curing_and_thermal_behavior_of_DGEBA_in_presence_of_dianhydrides_and_aromatic_diamine&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link 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