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itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/13652380/Balance_y_Seguridad_Energ%C3%A9tica_del_Reino_Unido_de_Gran_Breta%C3%B1a_e_Irlanda_del_Norte">Balance y Seguridad Energética del Reino Unido de Gran Bretaña e Irlanda del Norte</a></div></div><div class="u-pb4x u-mt3x"></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/13652380" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="8fe49ee23def0f4632640d865b17e874" rel="nofollow" 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type="text/json">{"id":44507,"name":"Nuclear","url":"https://www.academia.edu/Documents/in/Nuclear?f_ri=5303","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="47107" href="https://www.academia.edu/Documents/in/UK">UK</a>, <script data-card-contents-for-ri="47107" type="text/json">{"id":47107,"name":"UK","url":"https://www.academia.edu/Documents/in/UK?f_ri=5303","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="64547" href="https://www.academia.edu/Documents/in/Petr%C3%B3leo">Petróleo</a><script data-card-contents-for-ri="64547" type="text/json">{"id":64547,"name":"Petróleo","url":"https://www.academia.edu/Documents/in/Petr%C3%B3leo?f_ri=5303","nofollow":false}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=13652380]'), work: {"id":13652380,"title":"Balance y Seguridad Energética del Reino Unido de Gran Bretaña e Irlanda del 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data-has-card-for-ri="5303" href="https://www.academia.edu/Documents/in/Carbon">Carbon</a>, <script data-card-contents-for-ri="5303" type="text/json">{"id":5303,"name":"Carbon","url":"https://www.academia.edu/Documents/in/Carbon?f_ri=5303","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="226492" href="https://www.academia.edu/Documents/in/Nuclear_Fuel_Cycle">Nuclear Fuel Cycle</a>, <script data-card-contents-for-ri="226492" type="text/json">{"id":226492,"name":"Nuclear Fuel Cycle","url":"https://www.academia.edu/Documents/in/Nuclear_Fuel_Cycle?f_ri=5303","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="235705" href="https://www.academia.edu/Documents/in/Clearance">Clearance</a>, <script data-card-contents-for-ri="235705" type="text/json">{"id":235705,"name":"Clearance","url":"https://www.academia.edu/Documents/in/Clearance?f_ri=5303","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="387453" 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Recent progress in using the tools of genetics, molecular genetics and genetic engineering to dissect triterpene metabolism in the cytosol,... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_51397528" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Terpenes and sterols are complex molecules synthesized by equally complex biosynthetic pathways. 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class="u-positionAbsolute" data-has-card-for-ri-list="21433311"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">16</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="4377" href="https://www.academia.edu/Documents/in/Membranes">Membranes</a>, <script data-card-contents-for-ri="4377" type="text/json">{"id":4377,"name":"Membranes","url":"https://www.academia.edu/Documents/in/Membranes?f_ri=5303","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="4630" href="https://www.academia.edu/Documents/in/Dairy_Science">Dairy Science</a>, <script data-card-contents-for-ri="4630" type="text/json">{"id":4630,"name":"Dairy Science","url":"https://www.academia.edu/Documents/in/Dairy_Science?f_ri=5303","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="5303" href="https://www.academia.edu/Documents/in/Carbon">Carbon</a>, <script data-card-contents-for-ri="5303" type="text/json">{"id":5303,"name":"Carbon","url":"https://www.academia.edu/Documents/in/Carbon?f_ri=5303","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="12124" href="https://www.academia.edu/Documents/in/Filtration">Filtration</a><script data-card-contents-for-ri="12124" type="text/json">{"id":12124,"name":"Filtration","url":"https://www.academia.edu/Documents/in/Filtration?f_ri=5303","nofollow":false}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=21433311]'), work: {"id":21433311,"title":"Performance assessment of membrane distillation for skim milk and whey 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Chromatography","url":"https://www.academia.edu/Documents/in/High_Pressure_Liquid_Chromatography?f_ri=5303"},{"id":291038,"name":"Pressure","url":"https://www.academia.edu/Documents/in/Pressure?f_ri=5303"},{"id":343667,"name":"Theoretical Models","url":"https://www.academia.edu/Documents/in/Theoretical_Models?f_ri=5303"},{"id":573653,"name":"Food Sciences","url":"https://www.academia.edu/Documents/in/Food_Sciences?f_ri=5303"},{"id":781097,"name":"Lactose","url":"https://www.academia.edu/Documents/in/Lactose?f_ri=5303"},{"id":844702,"name":"Food Handling \u0026 Hygiene","url":"https://www.academia.edu/Documents/in/Food_Handling_and_Hygiene?f_ri=5303"},{"id":1885346,"name":"Milk proteins","url":"https://www.academia.edu/Documents/in/Milk_proteins?f_ri=5303"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_20553545" data-work_id="20553545" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/20553545/Vibrational_spectroscopic_analysis_of_2_chlorotoluene_and_2_bromotoluene_a_combined_experimental_and_theoretical_study">Vibrational spectroscopic analysis of 2-chlorotoluene and 2-bromotoluene: a combined experimental and theoretical study</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">In this work, the vibrational spectral analysis was carried out using Raman and infrared spectroscopy in the range 100-4000 cm(-1) and 50-4000 cm(-1), respectively, for the title molecules. The molecular structure, fundamental vibrational... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_20553545" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">In this work, the vibrational spectral analysis was carried out using Raman and infrared spectroscopy in the range 100-4000 cm(-1) and 50-4000 cm(-1), respectively, for the title molecules. The molecular structure, fundamental vibrational frequencies and intensity of the vibrational bands are interpreted with the aid of structure optimizations and normal coordinate force field calculations based on Hartee Fock (HF) and density functional theory (DFT) method and different basis sets combination. The complete vibrational assignments of wave numbers were made on the basis of potential energy distribution (PED). The scaled B3LYP/6-311++G(d,p) results show the best agreement with the experimental values over the other methods. The effects due to the substitutions of methyl group and halogen bond were investigated. The results of the calculations were applied to simulated spectra of the title compounds, which show excellent agreement with observed spectra.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/20553545" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="110b8b61aca00a641c2f6f0679be6aef" rel="nofollow" data-download="{"attachment_id":41433674,"asset_id":20553545,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/41433674/download_file?st=MTczMjc0MjY1Myw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="954802" href="https://pondiuni.academia.edu/sengenyperiandy">sengeny periandy</a><script data-card-contents-for-user="954802" type="text/json">{"id":954802,"first_name":"sengeny","last_name":"periandy","domain_name":"pondiuni","page_name":"sengenyperiandy","display_name":"sengeny periandy","profile_url":"https://pondiuni.academia.edu/sengenyperiandy?f_ri=5303","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_20553545 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="20553545"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 20553545, container: ".js-paper-rank-work_20553545", }); 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$(".js-view-count[data-work-id=20553545]").text(description); $(".js-view-count-work_20553545").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_20553545").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="20553545"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">18</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="524" href="https://www.academia.edu/Documents/in/Analytical_Chemistry">Analytical Chemistry</a>, <script data-card-contents-for-ri="524" type="text/json">{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry?f_ri=5303","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="2066" href="https://www.academia.edu/Documents/in/Research_Design">Research Design</a>, <script data-card-contents-for-ri="2066" type="text/json">{"id":2066,"name":"Research Design","url":"https://www.academia.edu/Documents/in/Research_Design?f_ri=5303","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="5303" href="https://www.academia.edu/Documents/in/Carbon">Carbon</a>, <script data-card-contents-for-ri="5303" type="text/json">{"id":5303,"name":"Carbon","url":"https://www.academia.edu/Documents/in/Carbon?f_ri=5303","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="6811" href="https://www.academia.edu/Documents/in/Quantum_Theory">Quantum Theory</a><script data-card-contents-for-ri="6811" type="text/json">{"id":6811,"name":"Quantum Theory","url":"https://www.academia.edu/Documents/in/Quantum_Theory?f_ri=5303","nofollow":false}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=20553545]'), work: {"id":20553545,"title":"Vibrational spectroscopic analysis of 2-chlorotoluene and 2-bromotoluene: a combined experimental and theoretical study","created_at":"2016-01-22T07:58:27.499-08:00","url":"https://www.academia.edu/20553545/Vibrational_spectroscopic_analysis_of_2_chlorotoluene_and_2_bromotoluene_a_combined_experimental_and_theoretical_study?f_ri=5303","dom_id":"work_20553545","summary":"In this work, the vibrational spectral analysis was carried out using Raman and infrared spectroscopy in the range 100-4000 cm(-1) and 50-4000 cm(-1), respectively, for the title molecules. The molecular structure, fundamental vibrational frequencies and intensity of the vibrational bands are interpreted with the aid of structure optimizations and normal coordinate force field calculations based on Hartee Fock (HF) and density functional theory (DFT) method and different basis sets combination. The complete vibrational assignments of wave numbers were made on the basis of potential energy distribution (PED). The scaled B3LYP/6-311++G(d,p) results show the best agreement with the experimental values over the other methods. The effects due to the substitutions of methyl group and halogen bond were investigated. The results of the calculations were applied to simulated spectra of the title compounds, which show excellent agreement with observed spectra.","downloadable_attachments":[{"id":41433674,"asset_id":20553545,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":954802,"first_name":"sengeny","last_name":"periandy","domain_name":"pondiuni","page_name":"sengenyperiandy","display_name":"sengeny periandy","profile_url":"https://pondiuni.academia.edu/sengenyperiandy?f_ri=5303","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry?f_ri=5303","nofollow":false},{"id":2066,"name":"Research Design","url":"https://www.academia.edu/Documents/in/Research_Design?f_ri=5303","nofollow":false},{"id":5303,"name":"Carbon","url":"https://www.academia.edu/Documents/in/Carbon?f_ri=5303","nofollow":false},{"id":6811,"name":"Quantum Theory","url":"https://www.academia.edu/Documents/in/Quantum_Theory?f_ri=5303","nofollow":false},{"id":23077,"name":"Vibration","url":"https://www.academia.edu/Documents/in/Vibration?f_ri=5303"},{"id":78842,"name":"Infrared spectroscopy","url":"https://www.academia.edu/Documents/in/Infrared_spectroscopy?f_ri=5303"},{"id":95360,"name":"Spectral analysis","url":"https://www.academia.edu/Documents/in/Spectral_analysis?f_ri=5303"},{"id":219723,"name":"Phenol","url":"https://www.academia.edu/Documents/in/Phenol?f_ri=5303"},{"id":296798,"name":"Hydrogen Bonding","url":"https://www.academia.edu/Documents/in/Hydrogen_Bonding?f_ri=5303"},{"id":335361,"name":"Infrared","url":"https://www.academia.edu/Documents/in/Infrared?f_ri=5303"},{"id":343667,"name":"Theoretical Models","url":"https://www.academia.edu/Documents/in/Theoretical_Models?f_ri=5303"},{"id":444844,"name":"Spectrum analysis","url":"https://www.academia.edu/Documents/in/Spectrum_analysis?f_ri=5303"},{"id":591104,"name":"Chlorine","url":"https://www.academia.edu/Documents/in/Chlorine?f_ri=5303"},{"id":649537,"name":"Molecular Conformation","url":"https://www.academia.edu/Documents/in/Molecular_Conformation?f_ri=5303"},{"id":963891,"name":"Toluene","url":"https://www.academia.edu/Documents/in/Toluene?f_ri=5303"},{"id":1136570,"name":"Force Field Analysis","url":"https://www.academia.edu/Documents/in/Force_Field_Analysis?f_ri=5303"},{"id":1435495,"name":"Potential Energy","url":"https://www.academia.edu/Documents/in/Potential_Energy?f_ri=5303"},{"id":1724844,"name":"Molecular Structure","url":"https://www.academia.edu/Documents/in/Molecular_Structure?f_ri=5303"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_19870780 coauthored" data-work_id="19870780" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/19870780/Flux_quantification_in_central_carbon_metabolism_of_Catharanthus_roseus_hairy_roots_by_13C_labeling_and_comprehensive_bondomer_balancing">Flux quantification in central carbon metabolism of Catharanthus roseus hairy roots by 13C labeling and comprehensive bondomer balancing</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Methods for accurate and efficient quantification of metabolic fluxes are desirable in plant metabolic engineering and systems biology. Toward this objective, we introduce the application of... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_19870780" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Methods for accurate and efficient quantification of metabolic fluxes are desirable in plant metabolic engineering and systems biology. Toward this objective, we introduce the application of &amp;amp;amp;amp;amp;amp;amp;quot;bondomers&amp;amp;amp;amp;amp;amp;amp;quot;, a computationally efficient and intuitively appealing alternative to the commonly used isotopomer concept, to flux evaluation in plants, by using Catharanthus roseus hairy roots as a model system. We cultured the hairy roots on (5% w/w U-(13)C, 95% w/w naturally abundant) sucrose, and acquired two-dimensional [(13)C, (1)H] and [(1)H, (1)H] NMR spectra of hydrolyzed aqueous extract from the hairy roots. Analysis of these spectra yielded a data set of 116 bondomers of beta-glucans and proteinogenic amino acids from the hairy roots. Fluxes were evaluated from the bondomer data by using comprehensive bondomer balancing. We identified most fluxes in a three-compartmental model of central carbon metabolism with good precision. We observed parallel pentose phosphate pathways in the cytosol and the plastid with significantly different fluxes. The anaplerotic fluxes between phosphoenolpyruvate and oxaloacetate in the cytosol and between malate and pyruvate in the mitochondrion were relatively high (60.1+/-2.5 mol per 100 mol sucrose uptake, or 22.5+/-0.5 mol per 100 mol mitochondrial pyruvate dehydrogenase flux). The development of a comprehensive flux analysis tool for this plant hairy root system is expected to be valuable in assessing the metabolic impact of genetic or environmental changes, and this methodology can be extended to other plant systems.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/19870780" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="258260102a7ddedc60687816f934efaf" rel="nofollow" data-download="{"attachment_id":42005375,"asset_id":19870780,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/42005375/download_file?st=MTczMjc0MjY1Myw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="40793008" href="https://independent.academia.edu/GaneshSriram1">Ganesh Sriram</a><script data-card-contents-for-user="40793008" type="text/json">{"id":40793008,"first_name":"Ganesh","last_name":"Sriram","domain_name":"independent","page_name":"GaneshSriram1","display_name":"Ganesh Sriram","profile_url":"https://independent.academia.edu/GaneshSriram1?f_ri=5303","photo":"/images/s65_no_pic.png"}</script></span></span><span class="u-displayInlineBlock InlineList-item-text"> and <span class="u-textDecorationUnderline u-clickable InlineList-item-text js-work-more-authors-19870780">+1</span><div class="hidden js-additional-users-19870780"><div><span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a href="https://independent.academia.edu/JacquelineShanks">Jacqueline Shanks</a></span></div></div></span><script>(function(){ var popoverSettings = { el: $('.js-work-more-authors-19870780'), placement: 'bottom', hide_delay: 200, html: true, content: function(){ return $('.js-additional-users-19870780').html(); 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Toward this objective, we introduce the application of \u0026amp;amp;amp;amp;amp;amp;amp;quot;bondomers\u0026amp;amp;amp;amp;amp;amp;amp;quot;, a computationally efficient and intuitively appealing alternative to the commonly used isotopomer concept, to flux evaluation in plants, by using Catharanthus roseus hairy roots as a model system. We cultured the hairy roots on (5% w/w U-(13)C, 95% w/w naturally abundant) sucrose, and acquired two-dimensional [(13)C, (1)H] and [(1)H, (1)H] NMR spectra of hydrolyzed aqueous extract from the hairy roots. Analysis of these spectra yielded a data set of 116 bondomers of beta-glucans and proteinogenic amino acids from the hairy roots. Fluxes were evaluated from the bondomer data by using comprehensive bondomer balancing. We identified most fluxes in a three-compartmental model of central carbon metabolism with good precision. We observed parallel pentose phosphate pathways in the cytosol and the plastid with significantly different fluxes. The anaplerotic fluxes between phosphoenolpyruvate and oxaloacetate in the cytosol and between malate and pyruvate in the mitochondrion were relatively high (60.1+/-2.5 mol per 100 mol sucrose uptake, or 22.5+/-0.5 mol per 100 mol mitochondrial pyruvate dehydrogenase flux). The development of a comprehensive flux analysis tool for this plant hairy root system is expected to be valuable in assessing the metabolic impact of genetic or environmental changes, and this methodology can be extended to other plant systems.","downloadable_attachments":[{"id":42005375,"asset_id":19870780,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":40793008,"first_name":"Ganesh","last_name":"Sriram","domain_name":"independent","page_name":"GaneshSriram1","display_name":"Ganesh Sriram","profile_url":"https://independent.academia.edu/GaneshSriram1?f_ri=5303","photo":"/images/s65_no_pic.png"},{"id":40681176,"first_name":"Jacqueline","last_name":"Shanks","domain_name":"independent","page_name":"JacquelineShanks","display_name":"Jacqueline Shanks","profile_url":"https://independent.academia.edu/JacquelineShanks?f_ri=5303","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":156,"name":"Genetics","url":"https://www.academia.edu/Documents/in/Genetics?f_ri=5303","nofollow":false},{"id":3057,"name":"Phytochemistry","url":"https://www.academia.edu/Documents/in/Phytochemistry?f_ri=5303","nofollow":false},{"id":5303,"name":"Carbon","url":"https://www.academia.edu/Documents/in/Carbon?f_ri=5303","nofollow":false},{"id":5411,"name":"Biomass","url":"https://www.academia.edu/Documents/in/Biomass?f_ri=5303","nofollow":false},{"id":11623,"name":"Metabolic Engineering","url":"https://www.academia.edu/Documents/in/Metabolic_Engineering?f_ri=5303"},{"id":19744,"name":"System Biology","url":"https://www.academia.edu/Documents/in/System_Biology?f_ri=5303"},{"id":28157,"name":"Environmental Change","url":"https://www.academia.edu/Documents/in/Environmental_Change?f_ri=5303"},{"id":47884,"name":"Biological Sciences","url":"https://www.academia.edu/Documents/in/Biological_Sciences?f_ri=5303"},{"id":78117,"name":"Carbon Isotopes","url":"https://www.academia.edu/Documents/in/Carbon_Isotopes?f_ri=5303"},{"id":162196,"name":"Sucrose","url":"https://www.academia.edu/Documents/in/Sucrose?f_ri=5303"},{"id":202399,"name":"Plant Roots","url":"https://www.academia.edu/Documents/in/Plant_Roots?f_ri=5303"},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=5303"},{"id":354056,"name":"Plant extracts","url":"https://www.academia.edu/Documents/in/Plant_extracts?f_ri=5303"},{"id":434746,"name":"Model System","url":"https://www.academia.edu/Documents/in/Model_System?f_ri=5303"},{"id":490116,"name":"Carbon Metabolism","url":"https://www.academia.edu/Documents/in/Carbon_Metabolism?f_ri=5303"},{"id":585573,"name":"Amino Acid Profile","url":"https://www.academia.edu/Documents/in/Amino_Acid_Profile?f_ri=5303"},{"id":859230,"name":"Catharanthus Roseus","url":"https://www.academia.edu/Documents/in/Catharanthus_Roseus?f_ri=5303"},{"id":1174953,"name":"Aqueous Extract","url":"https://www.academia.edu/Documents/in/Aqueous_Extract?f_ri=5303"},{"id":1954742,"name":"Pentose Phosphate Pathway","url":"https://www.academia.edu/Documents/in/Pentose_Phosphate_Pathway?f_ri=5303"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_12205046" data-work_id="12205046" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/12205046/Stability_of_organic_carbon_in_deep_soil_layers_controlled_by_fresh_carbon_supply">Stability of organic carbon in deep soil layers controlled by fresh carbon supply</a></div></div><div class="u-pb4x u-mt3x"></div><ul class="InlineList u-ph0x u-fs13"><li 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Barot","profile_url":"https://independent.academia.edu/S%C3%A9bastienBarot?f_ri=5303","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":140,"name":"Pharmacology","url":"https://www.academia.edu/Documents/in/Pharmacology?f_ri=5303","nofollow":false},{"id":145,"name":"Biochemistry","url":"https://www.academia.edu/Documents/in/Biochemistry?f_ri=5303","nofollow":false},{"id":146,"name":"Bioinformatics","url":"https://www.academia.edu/Documents/in/Bioinformatics?f_ri=5303","nofollow":false},{"id":155,"name":"Evolutionary Biology","url":"https://www.academia.edu/Documents/in/Evolutionary_Biology?f_ri=5303","nofollow":false},{"id":156,"name":"Genetics","url":"https://www.academia.edu/Documents/in/Genetics?f_ri=5303"},{"id":158,"name":"Marine Biology","url":"https://www.academia.edu/Documents/in/Marine_Biology?f_ri=5303"},{"id":161,"name":"Neuroscience","url":"https://www.academia.edu/Documents/in/Neuroscience?f_ri=5303"},{"id":402,"name":"Environmental 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data-work_id="77537705" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/77537705/_title_Diamond_like_carbon_films_by_pulsed_laser_deposition_with_additional_laser_irradiation_to_plume_title_"><title>Diamond-like carbon films by pulsed laser deposition with additional laser irradiation to plume</title></a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">A novel technique for synthesizing a diamond-like carbon (DLC) film by pulsed laser deposition (PLD) is proposed. In the technique, additional lasers irradiated the plume in order to increase the density of the ionic carbon. By... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_77537705" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">A novel technique for synthesizing a diamond-like carbon (DLC) film by pulsed laser deposition (PLD) is proposed. In the technique, additional lasers irradiated the plume in order to increase the density of the ionic carbon. By irradiating with an ArF excimer laser, the emission intensity of the atomic carbon was increased greatly. By irradiating with the third harmonic output and the fundamental output of an Nd:YAG laser, the emission intensity of the atomic and ionic carbon also increased greatly. The sp3 content increased from 51% without to 76% with two additional irradiation of the fundamental output of two Nd:YAG laser beams. The differences in the binding energy and surface morphology between the films with and without the irradiation of the additional lasers to the plume were observed by X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM), respectively.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/77537705" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="217093728" href="https://independent.academia.edu/TatsuyaShinozaki">Tatsuya Shinozaki</a><script data-card-contents-for-user="217093728" type="text/json">{"id":217093728,"first_name":"Tatsuya","last_name":"Shinozaki","domain_name":"independent","page_name":"TatsuyaShinozaki","display_name":"Tatsuya Shinozaki","profile_url":"https://independent.academia.edu/TatsuyaShinozaki?f_ri=5303","photo":"https://0.academia-photos.com/217093728/75437308/63947981/s65_tatsuya.shinozaki.jpeg"}</script></span></span></li><li class="js-paper-rank-work_77537705 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="77537705"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 77537705, container: ".js-paper-rank-work_77537705", }); 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$(".js-view-count[data-work-id=77537705]").text(description); $(".js-view-count-work_77537705").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_77537705").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="77537705"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">8</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="5303" href="https://www.academia.edu/Documents/in/Carbon">Carbon</a>, <script data-card-contents-for-ri="5303" type="text/json">{"id":5303,"name":"Carbon","url":"https://www.academia.edu/Documents/in/Carbon?f_ri=5303","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="24373" href="https://www.academia.edu/Documents/in/Atomic_Force_Microscopy">Atomic Force Microscopy</a>, <script data-card-contents-for-ri="24373" type="text/json">{"id":24373,"name":"Atomic Force Microscopy","url":"https://www.academia.edu/Documents/in/Atomic_Force_Microscopy?f_ri=5303","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="66343" href="https://www.academia.edu/Documents/in/Pulsed_Laser_Deposition">Pulsed Laser Deposition</a>, <script data-card-contents-for-ri="66343" type="text/json">{"id":66343,"name":"Pulsed Laser Deposition","url":"https://www.academia.edu/Documents/in/Pulsed_Laser_Deposition?f_ri=5303","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="124930" href="https://www.academia.edu/Documents/in/Diamond_Like_Carbon">Diamond Like Carbon</a><script data-card-contents-for-ri="124930" type="text/json">{"id":124930,"name":"Diamond Like Carbon","url":"https://www.academia.edu/Documents/in/Diamond_Like_Carbon?f_ri=5303","nofollow":false}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=77537705]'), work: {"id":77537705,"title":"\u003ctitle\u003eDiamond-like carbon films by pulsed laser deposition with additional laser irradiation to plume\u003c/title\u003e","created_at":"2022-04-25T01:40:22.114-07:00","url":"https://www.academia.edu/77537705/_title_Diamond_like_carbon_films_by_pulsed_laser_deposition_with_additional_laser_irradiation_to_plume_title_?f_ri=5303","dom_id":"work_77537705","summary":"A novel technique for synthesizing a diamond-like carbon (DLC) film by pulsed laser deposition (PLD) is proposed. In the technique, additional lasers irradiated the plume in order to increase the density of the ionic carbon. By irradiating with an ArF excimer laser, the emission intensity of the atomic carbon was increased greatly. By irradiating with the third harmonic output and the fundamental output of an Nd:YAG laser, the emission intensity of the atomic and ionic carbon also increased greatly. The sp3 content increased from 51% without to 76% with two additional irradiation of the fundamental output of two Nd:YAG laser beams. The differences in the binding energy and surface morphology between the films with and without the irradiation of the additional lasers to the plume were observed by X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM), respectively.","downloadable_attachments":[],"ordered_authors":[{"id":217093728,"first_name":"Tatsuya","last_name":"Shinozaki","domain_name":"independent","page_name":"TatsuyaShinozaki","display_name":"Tatsuya Shinozaki","profile_url":"https://independent.academia.edu/TatsuyaShinozaki?f_ri=5303","photo":"https://0.academia-photos.com/217093728/75437308/63947981/s65_tatsuya.shinozaki.jpeg"}],"research_interests":[{"id":5303,"name":"Carbon","url":"https://www.academia.edu/Documents/in/Carbon?f_ri=5303","nofollow":false},{"id":24373,"name":"Atomic Force Microscopy","url":"https://www.academia.edu/Documents/in/Atomic_Force_Microscopy?f_ri=5303","nofollow":false},{"id":66343,"name":"Pulsed Laser Deposition","url":"https://www.academia.edu/Documents/in/Pulsed_Laser_Deposition?f_ri=5303","nofollow":false},{"id":124930,"name":"Diamond Like Carbon","url":"https://www.academia.edu/Documents/in/Diamond_Like_Carbon?f_ri=5303","nofollow":false},{"id":210333,"name":"Photoemission Spectroscopy","url":"https://www.academia.edu/Documents/in/Photoemission_Spectroscopy?f_ri=5303"},{"id":250583,"name":"Diamond","url":"https://www.academia.edu/Documents/in/Diamond?f_ri=5303"},{"id":482288,"name":"Binding Energy","url":"https://www.academia.edu/Documents/in/Binding_Energy?f_ri=5303"},{"id":902639,"name":"X Ray Photoelectron Spectroscopy","url":"https://www.academia.edu/Documents/in/X_Ray_Photoelectron_Spectroscopy?f_ri=5303"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_75469034" data-work_id="75469034" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/75469034/Sensitive_and_selective_determination_of_hydroxychloroquine_in_the_presence_of_uric_acid_using_a_new_nanostructure_self_assembled_monolayer_modified_electrode_optimization_by_multivariate_data_analysis">Sensitive and selective determination of hydroxychloroquine in the presence of uric acid using a new nanostructure self-assembled monolayer modified electrode: optimization by multivariate data analysis</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest">A highly sensitive electrochemical nanosensor was developed using covalent modification of a glassy carbon electrode (GCE) by self-assembly of a novel Schiff base.</div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button 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class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Evaluation of emerging diesel-particulate emissions control technology will require analytical procedures capable of continuous measurement of transient organic and elemental carbon emissions. Procedures based on the flame ionization... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_73374979" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Evaluation of emerging diesel-particulate emissions control technology will require analytical procedures capable of continuous measurement of transient organic and elemental carbon emissions. Procedures based on the flame ionization properties of organic carbon and ...</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/73374979" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="2d81acb239946dc4e255ca15aa700c40" rel="nofollow" data-download="{"attachment_id":81919772,"asset_id":73374979,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/81919772/download_file?st=MTczMjc0MjY1Myw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="120112543" href="https://independent.academia.edu/FahadKing5">Fahad King</a><script data-card-contents-for-user="120112543" type="text/json">{"id":120112543,"first_name":"Fahad","last_name":"King","domain_name":"independent","page_name":"FahadKing5","display_name":"Fahad King","profile_url":"https://independent.academia.edu/FahadKing5?f_ri=5303","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_73374979 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="73374979"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 73374979, container: ".js-paper-rank-work_73374979", }); 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synthesis chamber design is sufficient to obtain metal (Fe, Co or Ni) filled carbon nanotubes (CNT) with high filling efficiency and controlled morphology. Samples are formed by... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_75059636" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">We demonstrate that a single zone furnace with a modified synthesis chamber design is sufficient to obtain metal (Fe, Co or Ni) filled carbon nanotubes (CNT) with high filling efficiency and controlled morphology. Samples are formed by pyrolysis of metallocenes, a synthesis technique that otherwise requires a dual zone furnace. Respective metallocene in all three cases are sublimed in powder form, a crucial factor for obtaining high filling efficiency. While Fe@CNT is routinely produced using this technique, well-formed Ni@CNT or Co@CNT samples are reported for the first time. This is achieved by sublimation of nickelocene (or cobaltocene) in combination with &#39;camphor&#39;. These samples exhibit some of the highest saturation magnetization (Ms) values, at least an order of magnitude higher than that reported for Ni or Co filled CNT, by aerosol assisted pyrolysis. The results also elucidate on why Ni or Co@CNT are relatively difficult to obtain by pyrolyzing powder metallocene al...</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/75059636" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="f063a169a5c5be48fead89babb244340" rel="nofollow" data-download="{"attachment_id":82981772,"asset_id":75059636,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/82981772/download_file?st=MTczMjc0MjY1Myw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="42836537" href="https://iiserpune.academia.edu/AakankshaKapoor">Aakanksha Kapoor</a><script data-card-contents-for-user="42836537" type="text/json">{"id":42836537,"first_name":"Aakanksha","last_name":"Kapoor","domain_name":"iiserpune","page_name":"AakankshaKapoor","display_name":"Aakanksha Kapoor","profile_url":"https://iiserpune.academia.edu/AakankshaKapoor?f_ri=5303","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_75059636 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="75059636"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 75059636, container: ".js-paper-rank-work_75059636", }); 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Samples are formed by pyrolysis of metallocenes, a synthesis technique that otherwise requires a dual zone furnace. Respective metallocene in all three cases are sublimed in powder form, a crucial factor for obtaining high filling efficiency. While Fe@CNT is routinely produced using this technique, well-formed Ni@CNT or Co@CNT samples are reported for the first time. This is achieved by sublimation of nickelocene (or cobaltocene) in combination with \u0026#39;camphor\u0026#39;. These samples exhibit some of the highest saturation magnetization (Ms) values, at least an order of magnitude higher than that reported for Ni or Co filled CNT, by aerosol assisted pyrolysis. The results also elucidate on why Ni or Co@CNT are relatively difficult to obtain by pyrolyzing powder metallocene al...","downloadable_attachments":[{"id":82981772,"asset_id":75059636,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":42836537,"first_name":"Aakanksha","last_name":"Kapoor","domain_name":"iiserpune","page_name":"AakankshaKapoor","display_name":"Aakanksha Kapoor","profile_url":"https://iiserpune.academia.edu/AakankshaKapoor?f_ri=5303","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=5303","nofollow":false},{"id":5303,"name":"Carbon","url":"https://www.academia.edu/Documents/in/Carbon?f_ri=5303","nofollow":false},{"id":118582,"name":"Physical sciences","url":"https://www.academia.edu/Documents/in/Physical_sciences?f_ri=5303","nofollow":false},{"id":260118,"name":"CHEMICAL 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class="summarized">The risk of colorectal cancer (CRC) may be influenced by aberrant DNA methylation and altered nucleotide synthesis and repair, possibly caused by impaired dietary folate intake as well as by polymorphic variants in one-carbon metabolism... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_73140618" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The risk of colorectal cancer (CRC) may be influenced by aberrant DNA methylation and altered nucleotide synthesis and repair, possibly caused by impaired dietary folate intake as well as by polymorphic variants in one-carbon metabolism genes. A case–control study using seventy-one CRC patients and eighty unrelated healthy controls was carried out to assess the genetic association of fifteen SNP and one insertion in nine genes belonging to the folate pathway. Polymorphism selection was based on literature data, and included those which have a known or suspected functional impact on cancer and missense polymorphisms that are most likely to alter protein function. Genotyping was performed by real-time PCR and PCR followed by restriction analysis. The likelihood ratio statistic indicated that most of the polymorphisms were not associated with the risk of CRC. 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