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去除生物毒性-毒性去除高浓度废水处理设备-北京安力斯环境科技股份有限公司
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仿宋_GB2312;">污水处理中的生物</span><strong><span style="font-size: 20px; font-family: 仿宋_GB2312;">毒性</span></strong></h2><p style="text-indent:28px"><span style="font-family: 等线; font-size: 18px;">废水中凡是能延缓或抑制微生物生长的化学物质,统称为有毒有害物质,简称毒物。这些毒物,从化学性质上来分可划分为有机物和无机物两大类。<strong>毒性去除</strong>,从处理的角度又可划分为能被生物处理段去除、转化的物质(如H2S)等,或称非稳定性毒物)和不能被生物处理段去除、转化的物质(如NaCl、汞、铜等,或称稳定性毒物)两大类。</span></p><h2><strong><span style="font-family: 仿宋_GB2312;font-size: 20px">2<span style="font-family:仿宋_GB2312">、有毒物质对微生物的影响</span></span></strong></h2><p style="text-indent:28px"><span style="font-family: 等线; font-size: 18px;">毒物对微生物的作用机制主要有如下方式:</span></p><p style="margin-left:56px"><span style="font-family: 等线; font-size: 18px;">1) 损伤细胞结构成分和细胞外膜。如:70%浓度的乙醇能使蛋白凝固达到杀菌作用;酚、甲酚、表面活性剂作用于细胞外膜,破坏细胞膜的半透性。</span></p><p style="margin-left:56px"><span style="font-family: 等线; font-size: 18px;">2) 损伤酶和重要代谢过程。一些重金属(铜、银、汞等)对酶有潜在的毒害作用,甚至在非常低的浓度下也起作用。这些重金属的盐类和有机化合物能与酶的-SH基结合,并改变这些蛋白质的三级和四级结构。</span></p><p style="margin-left:56px"><span style="font-family: 等线; font-size: 18px;">3) 竞争性抑制作用。当废水中存在一种化学结构与代谢物质相类似的有机物时便会发生。因为二者都能在酶的活性中心与酶相结合,它们的竞争将抑制中间产物的形成,使酶的催化反应速率降低。</span></p><p style="margin-left:56px"><span style="font-family: 等线; font-size: 18px;">4) 对细胞成分合成过程的抑制作用。当某些化学物质的结构类似于细胞成分的结构时,它们便会被细胞吸收并同化,结果是合成无功能的辅酶或导致生长停止。这种作用最典型的例子便是磺胺酸。</span></p><p style="margin-left:56px"><span style="font-family: 等线; font-size: 18px;">5) 抗生素对蛋白质合成的抑制作用。不少抗生素能专一地抑制原核生物的蛋白质合成,如<span style="color: rgb(51, 51, 51); font-family: Arial, sans-serif; font-size: 13px; background-color: rgb(255, 255, 255);">streptomycin</span>会抑制氨基酸正确结合于多肽上。</span></p><p style="margin-left:56px"><span style="font-family: 等线; font-size: 18px;">6) 抗生素对核酸的抑制作用。如丝裂霉系C会选择性地阻止DNA的合成,从而抑制微生物的生长。</span></p><p style="margin-left:56px"><span style="font-family: 等线; font-size: 18px;">7) 对细胞壁合成的抑制作用。如<span style="color: rgb(51, 51, 51); font-family: Arial, sans-serif; font-size: 13px; background-color: rgb(255, 255, 255);">Penicillin</span>便是通过干扰细胞壁的合成从而达到抑制微生物生长的效果。</span></p><p style="text-indent:28px"><span style="font-family: 等线; font-size: 18px;">当需处理的废水中毒物浓度超过允许范围时,须采取适当的工程措施加以解决、否则废水生物处理设施无法正常运行或启动。</span></p><p style="text-indent:28px"> </p><p style="text-align: center"><img style="max-width:800px;max-height:300%;" src="https://img68.hbzhan.com/cc947453cd6ce8aa0d713a65a2484554de7fa8f4330dfc70105143677d6b30076cc251c947e6cdc7.png" title="1图片1.png" alt="1图片1.png" /></p><p style="text-indent:28px"> </p><p style="text-indent: 32px; text-align: center;"><strong><span style="font-family: 仿宋_GB2312;font-size: 16px">图<span style="font-family:等线">1</span></span></strong><strong><span style="font-family: 等线;font-size: 16px"> </span></strong><strong><span style="font-family: 仿宋_GB2312;font-size: 16px">有毒化合物浓度对生物反应速率的影响</span></strong></p><p style="text-indent: 32px;"> </p><h2><strong><span style="font-family: 仿宋_GB2312;font-size: 20px">3<span style="font-family:仿宋_GB2312">、高级氧化去除生物毒性</span></span></strong></h2><p style="text-indent:28px"><span style="font-size: 18px;"><span style="font-family: 等线;">通过产生羟基自由基(·OH)对有机污染物进行氧化的反应统称为高级氧化工艺,简称AOPs。羟基自由基(·OH)与有机物发生</span><strong><span style="font-family: 等线;">开环、断键、氢抽提反应</span></strong><span style="font-family: 等线;">、</span><strong><span style="font-family: 等线;">加成反应</span></strong><span style="font-family: 等线;">、</span><strong><span style="font-family: 等线;">氧化分解反应</span></strong><span style="font-family: 等线;">、</span><strong><span style="font-family: 等线;">电子转移反应</span></strong><span style="font-family: 等线;">等过程使水中的有机污染物有效地分解,甚至转化为无害无机物,如二氧化碳和水等,使出水更容易进一步地进行生化处理,<strong style="font-family: 等线; font-size: 18px; text-indent: 28px; white-space: normal;">毒性去除</strong>。</span></span></p><p style="text-indent:28px"> </p><p style=";line-height:150%;margin-top:8px;margin-bottom:0;text-align:justify;text-justify:inter-ideograph;direction:ltr;unicode-bidi:embed"><span style="font-size: 18px; font-family: 等线;"> </span><strong><span style="font-size: 18px; font-family: 等线;">MPUV-H2O2技术介绍:</span></strong></p><p style=";line-height:150%;margin-top:8px;margin-bottom:0;text-align:justify;text-justify:inter-ideograph;direction:ltr;unicode-bidi:embed"><span style="font-size: 18px; font-family: 等线;"> 通过中压紫外灯照射水体中的H<sub>2</sub>O<sub>2</sub>,促进H<sub>2</sub>O<sub>2</sub>分解产生羟基自由基, 将有机污染物最终矿化为CO2和H2O,其中间产物具有较多含氧官能团,有效提高了废水的可生化性。</span></p><p style="text-indent: 28px; text-align: center;"><img src="https://img69.hbzhan.com/cc947453cd6ce8aa3b0652a5016baeb941a05eadd455e2b842d2d918827630cba5fdec0004a2ef14.png" title="image.png" alt="image.png" width="533" height="208" style="width: 533px; height: 208px;" /></p><p style="text-indent: 32px;"> </p><p style=";margin-top:0;margin-bottom:0;text-align:left;direction:ltr;unicode-bidi:embed"><span style="font-size: 18px; font-family: 等线;"> 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