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Volatility (chemistry) - Wikipedia
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class="vector-toc-numb">3.2</span> <span>Perfume</span> </div> </a> <ul id="toc-Perfume-sublist" class="vector-toc-list"> </ul> </li> </ul> </li> <li id="toc-See_also" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#See_also"> <div class="vector-toc-text"> <span class="vector-toc-numb">4</span> <span>See also</span> </div> </a> <ul id="toc-See_also-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-References" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#References"> <div class="vector-toc-text"> <span class="vector-toc-numb">5</span> <span>References</span> </div> </a> <ul id="toc-References-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-External_links" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#External_links"> <div class="vector-toc-text"> <span class="vector-toc-numb">6</span> <span>External links</span> </div> </a> <ul id="toc-External_links-sublist" class="vector-toc-list"> </ul> </li> </ul> </div> </div> </nav> </div> </div> <div class="mw-content-container"> <main id="content" class="mw-body"> <header class="mw-body-header vector-page-titlebar"> <nav aria-label="Contents" class="vector-toc-landmark"> <div id="vector-page-titlebar-toc" class="vector-dropdown vector-page-titlebar-toc vector-button-flush-left" > <input type="checkbox" id="vector-page-titlebar-toc-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-page-titlebar-toc" class="vector-dropdown-checkbox " aria-label="Toggle the table of contents" > <label id="vector-page-titlebar-toc-label" for="vector-page-titlebar-toc-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only " aria-hidden="true" ><span class="vector-icon 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Available in 29 languages" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-29" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">29 languages</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D8%AA%D8%B7%D8%A7%D9%8A%D8%B1%D9%8A%D8%A9" title="تطايرية – Arabic" lang="ar" hreflang="ar" data-title="تطايرية" data-language-autonym="العربية" data-language-local-name="Arabic" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-bn mw-list-item"><a href="https://bn.wikipedia.org/wiki/%E0%A6%89%E0%A6%A6%E0%A7%8D%E0%A6%AC%E0%A6%BE%E0%A6%AF%E0%A6%BC%E0%A6%BF%E0%A6%A4%E0%A6%BE" title="উদ্বায়িতা – Bangla" lang="bn" hreflang="bn" data-title="উদ্বায়িতা" data-language-autonym="বাংলা" data-language-local-name="Bangla" class="interlanguage-link-target"><span>বাংলা</span></a></li><li class="interlanguage-link interwiki-ca mw-list-item"><a href="https://ca.wikipedia.org/wiki/Volatilitat" title="Volatilitat – Catalan" lang="ca" hreflang="ca" data-title="Volatilitat" data-language-autonym="Català" data-language-local-name="Catalan" class="interlanguage-link-target"><span>Català</span></a></li><li class="interlanguage-link interwiki-cs mw-list-item"><a href="https://cs.wikipedia.org/wiki/T%C4%9Bkavost" title="Těkavost – Czech" lang="cs" hreflang="cs" data-title="Těkavost" data-language-autonym="Čeština" data-language-local-name="Czech" class="interlanguage-link-target"><span>Čeština</span></a></li><li class="interlanguage-link interwiki-ary mw-list-item"><a href="https://ary.wikipedia.org/wiki/%D8%AA%D8%B7%D8%A7%D9%8A%D8%B1%D9%8A%D8%AA_(%D8%B4%D9%8A%D9%85%D9%8A)" title="تطايريت (شيمي) – Moroccan Arabic" lang="ary" hreflang="ary" data-title="تطايريت (شيمي)" data-language-autonym="الدارجة" data-language-local-name="Moroccan Arabic" class="interlanguage-link-target"><span>الدارجة</span></a></li><li class="interlanguage-link interwiki-de mw-list-item"><a href="https://de.wikipedia.org/wiki/Fl%C3%BCchtigkeit" title="Flüchtigkeit – German" lang="de" hreflang="de" data-title="Flüchtigkeit" data-language-autonym="Deutsch" data-language-local-name="German" class="interlanguage-link-target"><span>Deutsch</span></a></li><li class="interlanguage-link interwiki-et mw-list-item"><a href="https://et.wikipedia.org/wiki/Lenduvus" title="Lenduvus – Estonian" lang="et" hreflang="et" data-title="Lenduvus" data-language-autonym="Eesti" data-language-local-name="Estonian" class="interlanguage-link-target"><span>Eesti</span></a></li><li class="interlanguage-link interwiki-el mw-list-item"><a href="https://el.wikipedia.org/wiki/%CE%A0%CF%84%CE%B7%CF%84%CE%B9%CE%BA%CF%8C%CF%84%CE%B7%CF%84%CE%B1" title="Πτητικότητα – Greek" lang="el" hreflang="el" data-title="Πτητικότητα" data-language-autonym="Ελληνικά" data-language-local-name="Greek" class="interlanguage-link-target"><span>Ελληνικά</span></a></li><li class="interlanguage-link interwiki-es mw-list-item"><a href="https://es.wikipedia.org/wiki/Volatilidad_(qu%C3%ADmica)" title="Volatilidad (química) – Spanish" lang="es" hreflang="es" data-title="Volatilidad (química)" data-language-autonym="Español" data-language-local-name="Spanish" class="interlanguage-link-target"><span>Español</span></a></li><li class="interlanguage-link interwiki-eu mw-list-item"><a href="https://eu.wikipedia.org/wiki/Lurrunkortasun" title="Lurrunkortasun – Basque" lang="eu" hreflang="eu" data-title="Lurrunkortasun" data-language-autonym="Euskara" data-language-local-name="Basque" class="interlanguage-link-target"><span>Euskara</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%D9%81%D8%B1%D8%A7%D8%B1%DB%8C%D8%AA_(%D8%B4%DB%8C%D9%85%DB%8C)" title="فراریت (شیمی) – Persian" lang="fa" hreflang="fa" data-title="فراریت (شیمی)" data-language-autonym="فارسی" data-language-local-name="Persian" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/Volatilit%C3%A9_(chimie)" title="Volatilité (chimie) – French" lang="fr" hreflang="fr" data-title="Volatilité (chimie)" data-language-autonym="Français" data-language-local-name="French" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-ko mw-list-item"><a href="https://ko.wikipedia.org/wiki/%ED%9C%98%EB%B0%9C%EC%84%B1" title="휘발성 – Korean" lang="ko" hreflang="ko" data-title="휘발성" data-language-autonym="한국어" data-language-local-name="Korean" class="interlanguage-link-target"><span>한국어</span></a></li><li class="interlanguage-link interwiki-hy mw-list-item"><a href="https://hy.wikipedia.org/wiki/%D5%91%D5%B6%D5%A4%D5%A5%D5%AC%D5%AB%D5%B8%D6%82%D5%A9%D5%B5%D5%B8%D6%82%D5%B6" title="Ցնդելիություն – Armenian" lang="hy" hreflang="hy" data-title="Ցնդելիություն" data-language-autonym="Հայերեն" data-language-local-name="Armenian" class="interlanguage-link-target"><span>Հայերեն</span></a></li><li class="interlanguage-link interwiki-hi mw-list-item"><a href="https://hi.wikipedia.org/wiki/%E0%A4%B5%E0%A4%BE%E0%A4%B7%E0%A5%8D%E0%A4%AA%E0%A4%B6%E0%A5%80%E0%A4%B2%E0%A4%A4%E0%A4%BE_(%E0%A4%B0%E0%A4%B8%E0%A4%BE%E0%A4%AF%E0%A4%A8%E0%A4%BF%E0%A4%95%E0%A5%80)" title="वाष्पशीलता (रसायनिकी) – Hindi" lang="hi" hreflang="hi" data-title="वाष्पशीलता (रसायनिकी)" data-language-autonym="हिन्दी" data-language-local-name="Hindi" class="interlanguage-link-target"><span>हिन्दी</span></a></li><li class="interlanguage-link interwiki-id mw-list-item"><a href="https://id.wikipedia.org/wiki/Volatilitas_(kimia)" title="Volatilitas (kimia) – Indonesian" lang="id" hreflang="id" data-title="Volatilitas (kimia)" data-language-autonym="Bahasa Indonesia" data-language-local-name="Indonesian" class="interlanguage-link-target"><span>Bahasa Indonesia</span></a></li><li class="interlanguage-link interwiki-it mw-list-item"><a href="https://it.wikipedia.org/wiki/Volatilit%C3%A0_(chimica)" title="Volatilità (chimica) – Italian" lang="it" hreflang="it" data-title="Volatilità (chimica)" data-language-autonym="Italiano" data-language-local-name="Italian" class="interlanguage-link-target"><span>Italiano</span></a></li><li class="interlanguage-link interwiki-he mw-list-item"><a href="https://he.wikipedia.org/wiki/%D7%A0%D7%93%D7%99%D7%A4%D7%95%D7%AA_(%D7%9B%D7%99%D7%9E%D7%99%D7%94)" title="נדיפות (כימיה) – Hebrew" lang="he" hreflang="he" data-title="נדיפות (כימיה)" data-language-autonym="עברית" data-language-local-name="Hebrew" class="interlanguage-link-target"><span>עברית</span></a></li><li class="interlanguage-link interwiki-ms mw-list-item"><a href="https://ms.wikipedia.org/wiki/Kemeruapan" title="Kemeruapan – Malay" lang="ms" hreflang="ms" data-title="Kemeruapan" data-language-autonym="Bahasa Melayu" data-language-local-name="Malay" class="interlanguage-link-target"><span>Bahasa Melayu</span></a></li><li class="interlanguage-link interwiki-nl mw-list-item"><a href="https://nl.wikipedia.org/wiki/Vluchtigheid_(stof)" title="Vluchtigheid (stof) – Dutch" lang="nl" hreflang="nl" data-title="Vluchtigheid (stof)" data-language-autonym="Nederlands" data-language-local-name="Dutch" class="interlanguage-link-target"><span>Nederlands</span></a></li><li class="interlanguage-link interwiki-pl mw-list-item"><a href="https://pl.wikipedia.org/wiki/Lotno%C5%9B%C4%87_(ciecz)" title="Lotność (ciecz) – Polish" lang="pl" hreflang="pl" data-title="Lotność (ciecz)" data-language-autonym="Polski" data-language-local-name="Polish" class="interlanguage-link-target"><span>Polski</span></a></li><li class="interlanguage-link interwiki-pt mw-list-item"><a href="https://pt.wikipedia.org/wiki/Volatilidade" title="Volatilidade – Portuguese" lang="pt" hreflang="pt" data-title="Volatilidade" data-language-autonym="Português" data-language-local-name="Portuguese" class="interlanguage-link-target"><span>Português</span></a></li><li class="interlanguage-link interwiki-ro mw-list-item"><a href="https://ro.wikipedia.org/wiki/Punct_de_evaporare" title="Punct de evaporare – Romanian" lang="ro" hreflang="ro" data-title="Punct de evaporare" data-language-autonym="Română" data-language-local-name="Romanian" class="interlanguage-link-target"><span>Română</span></a></li><li class="interlanguage-link interwiki-sq mw-list-item"><a href="https://sq.wikipedia.org/wiki/Fluria_(kimi)" title="Fluria (kimi) – Albanian" lang="sq" hreflang="sq" data-title="Fluria (kimi)" data-language-autonym="Shqip" data-language-local-name="Albanian" class="interlanguage-link-target"><span>Shqip</span></a></li><li class="interlanguage-link interwiki-sv mw-list-item"><a href="https://sv.wikipedia.org/wiki/Flyktighet" title="Flyktighet – Swedish" lang="sv" hreflang="sv" data-title="Flyktighet" data-language-autonym="Svenska" data-language-local-name="Swedish" class="interlanguage-link-target"><span>Svenska</span></a></li><li class="interlanguage-link interwiki-th mw-list-item"><a href="https://th.wikipedia.org/wiki/%E0%B8%AA%E0%B8%A1%E0%B8%9A%E0%B8%B1%E0%B8%95%E0%B8%B4%E0%B8%81%E0%B8%B2%E0%B8%A3%E0%B8%A3%E0%B8%B0%E0%B9%80%E0%B8%AB%E0%B8%A2%E0%B8%87%E0%B9%88%E0%B8%B2%E0%B8%A2" title="สมบัติการระเหยง่าย – Thai" lang="th" hreflang="th" data-title="สมบัติการระเหยง่าย" data-language-autonym="ไทย" data-language-local-name="Thai" class="interlanguage-link-target"><span>ไทย</span></a></li><li class="interlanguage-link interwiki-tr mw-list-item"><a href="https://tr.wikipedia.org/wiki/U%C3%A7uculuk" title="Uçuculuk – Turkish" lang="tr" hreflang="tr" data-title="Uçuculuk" data-language-autonym="Türkçe" data-language-local-name="Turkish" class="interlanguage-link-target"><span>Türkçe</span></a></li><li class="interlanguage-link interwiki-uk mw-list-item"><a href="https://uk.wikipedia.org/wiki/%D0%9B%D0%B5%D1%82%D0%BA%D1%96%D1%81%D1%82%D1%8C" title="Леткість – Ukrainian" lang="uk" hreflang="uk" data-title="Леткість" data-language-autonym="Українська" data-language-local-name="Ukrainian" class="interlanguage-link-target"><span>Українська</span></a></li><li class="interlanguage-link interwiki-zh mw-list-item"><a href="https://zh.wikipedia.org/wiki/%E6%8F%AE%E7%99%BC%E6%80%A7" title="揮發性 – Chinese" lang="zh" hreflang="zh" data-title="揮發性" data-language-autonym="中文" data-language-local-name="Chinese" class="interlanguage-link-target"><span>中文</span></a></li> </ul> <div class="after-portlet after-portlet-lang"><span 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<div id="mw-content-text" class="mw-body-content"><div class="mw-content-ltr mw-parser-output" lang="en" dir="ltr"><div class="shortdescription nomobile noexcerpt noprint searchaux" style="display:none">Tendency of a substance to vaporize</div> <figure class="mw-default-size" typeof="mw:File/Thumb"><a href="/wiki/File:Bromine_in_a_vial.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/d/dd/Bromine_in_a_vial.png/220px-Bromine_in_a_vial.png" decoding="async" width="220" height="294" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/d/dd/Bromine_in_a_vial.png/330px-Bromine_in_a_vial.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/d/dd/Bromine_in_a_vial.png/440px-Bromine_in_a_vial.png 2x" data-file-width="518" data-file-height="693" /></a><figcaption><a href="/wiki/Bromine" title="Bromine">Bromine</a> liquid readily transitions to vapor at room temperature, indicating high volatility</figcaption></figure> <p>In <a href="/wiki/Chemistry" title="Chemistry">chemistry</a>, <b>volatility</b> is a material quality which describes how readily a substance <a href="/wiki/Vaporization" title="Vaporization">vaporizes</a>. At a given <a href="/wiki/Temperature" title="Temperature">temperature</a> and <a href="/wiki/Pressure" title="Pressure">pressure</a>, a substance with high volatility is more likely to exist as a <a href="/wiki/Vapour" class="mw-redirect" title="Vapour">vapour</a>, while a substance with low volatility is more likely to be a <a href="/wiki/Liquid" title="Liquid">liquid</a> or <a href="/wiki/Solid" title="Solid">solid</a>. Volatility can also describe the tendency of a vapor to <a href="/wiki/Condense" class="mw-redirect" title="Condense">condense</a> into a liquid or solid; less volatile substances will more readily condense from a vapor than highly volatile ones.<sup id="cite_ref-:1_1-0" class="reference"><a href="#cite_note-:1-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> Differences in volatility can be observed by comparing how fast substances within a group evaporate (or <a href="/wiki/Sublimation_(phase_transition)" title="Sublimation (phase transition)">sublimate</a> in the case of solids) when exposed to the atmosphere. A highly volatile substance such as rubbing alcohol (<a href="/wiki/Isopropyl_alcohol" title="Isopropyl alcohol">isopropyl alcohol</a>) will quickly evaporate, while a substance with low volatility such as <a href="/wiki/Canola_oil" class="mw-redirect" title="Canola oil">vegetable oil</a> will remain condensed.<sup id="cite_ref-2" class="reference"><a href="#cite_note-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> In general, solids are much less volatile than liquids, but there are some exceptions. Solids that sublimate (change directly from solid to vapor) such as dry ice (solid <a href="/wiki/Carbon_dioxide" title="Carbon dioxide">carbon dioxide</a>) or <a href="/wiki/Iodine" title="Iodine">iodine</a> can vaporize at a similar rate as some liquids under standard conditions.<sup id="cite_ref-:0_3-0" class="reference"><a href="#cite_note-:0-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="Description">Description</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Volatility_(chemistry)&action=edit&section=1" title="Edit section: Description"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Volatility itself has no defined numerical value, but it is often described using vapor pressures or boiling points (for liquids). High vapor pressures indicate a high volatility, while high boiling points indicate low volatility. Vapor pressures and boiling points are often presented in tables and charts that can be used to compare chemicals of interest. Volatility data is typically found through experimentation over a range of temperatures and pressures. </p> <div class="mw-heading mw-heading3"><h3 id="Vapor_pressure">Vapor pressure</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Volatility_(chemistry)&action=edit&section=2" title="Edit section: Vapor pressure"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <figure typeof="mw:File/Thumb"><a href="/wiki/File:Vapor_pressure_chart.svg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/1/16/Vapor_pressure_chart.svg/169px-Vapor_pressure_chart.svg.png" decoding="async" width="169" height="254" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/1/16/Vapor_pressure_chart.svg/254px-Vapor_pressure_chart.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/1/16/Vapor_pressure_chart.svg/338px-Vapor_pressure_chart.svg.png 2x" data-file-width="512" data-file-height="768" /></a><figcaption>A log-lin vapor pressure chart for various liquids</figcaption></figure> <p><a href="/wiki/Vapor_pressure" title="Vapor pressure">Vapor pressure</a> is a measurement of how readily a condensed phase forms a vapor at a given temperature. A substance enclosed in a sealed vessel initially at vacuum (no air inside) will quickly fill any empty space with vapor. After the system reaches equilibrium and the rate of evaporation matches the rate of condensation, the vapor pressure can be measured. Increasing the temperature increases the amount of vapor that is formed and thus the vapor pressure. In a mixture, each substance contributes to the overall vapor pressure of the mixture, with more volatile compounds making a larger contribution. </p> <div class="mw-heading mw-heading3"><h3 id="Boiling_point">Boiling point</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Volatility_(chemistry)&action=edit&section=3" title="Edit section: Boiling point"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p><a href="/wiki/Boiling_point" title="Boiling point">Boiling point</a> is the temperature at which the vapor pressure of a liquid is equal to the surrounding pressure, causing the liquid to rapidly evaporate, or boil. It is closely related to vapor pressure, but is dependent on pressure. The normal boiling point is the boiling point at atmospheric pressure, but it can also be reported at higher and lower pressures.<sup id="cite_ref-:0_3-1" class="reference"><a href="#cite_note-:0-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Contributing_factors">Contributing factors</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Volatility_(chemistry)&action=edit&section=4" title="Edit section: Contributing factors"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="mw-heading mw-heading3"><h3 id="Intermolecular_forces">Intermolecular forces</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Volatility_(chemistry)&action=edit&section=5" title="Edit section: Intermolecular forces"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <figure class="mw-default-size" typeof="mw:File/Thumb"><a href="/wiki/File:AlkaneBoilingMeltingPoint.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/8/82/AlkaneBoilingMeltingPoint.png/310px-AlkaneBoilingMeltingPoint.png" decoding="async" width="310" height="155" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/8/82/AlkaneBoilingMeltingPoint.png/465px-AlkaneBoilingMeltingPoint.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/8/82/AlkaneBoilingMeltingPoint.png/620px-AlkaneBoilingMeltingPoint.png 2x" data-file-width="704" data-file-height="352" /></a><figcaption>Normal boiling point (red) and melting point (blue) of linear <a href="/wiki/Alkane" title="Alkane">alkanes</a> vs. number of carbon atoms.</figcaption></figure> <p>An important factor influencing a substance's volatility is the strength of the interactions between its molecules. Attractive forces between molecules are what holds materials together, and materials with stronger <a href="/wiki/Intermolecular_force" title="Intermolecular force">intermolecular forces</a>, such as most solids, are typically not very volatile. <a href="/wiki/Ethanol" title="Ethanol">Ethanol</a> and <a href="/wiki/Dimethyl_ether" title="Dimethyl ether">dimethyl ether</a>, two chemicals with the same formula (C<sub>2</sub>H<sub>6</sub>O), have different volatilities due to the different interactions that occur between their molecules in the liquid phase: ethanol molecules are capable of <a href="/wiki/Hydrogen_bonding" class="mw-redirect" title="Hydrogen bonding">hydrogen bonding</a> while dimethyl ether molecules are not.<sup id="cite_ref-4" class="reference"><a href="#cite_note-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> The result in an overall stronger attractive force between the ethanol molecules, making it the less volatile substance of the two. </p> <div class="mw-heading mw-heading3"><h3 id="Molecular_weight">Molecular weight</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Volatility_(chemistry)&action=edit&section=6" title="Edit section: Molecular weight"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>In general, volatility tends to decrease with increasing <a href="/wiki/Molecular_mass" title="Molecular mass">molecular mass</a> because larger molecules can participate in more intermolecular bonding,<sup id="cite_ref-5" class="reference"><a href="#cite_note-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> although other factors such as structure and polarity play a significant role. The effect of molecular mass can be partially isolated by comparing chemicals of similar structure (i.e. esters, alkanes, etc.). For instance, linear <a href="/wiki/Alkane" title="Alkane">alkanes</a> exhibit decreasing volatility as the number of carbons in the chain increases. </p> <div class="mw-heading mw-heading2"><h2 id="Applications">Applications</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Volatility_(chemistry)&action=edit&section=7" title="Edit section: Applications"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="mw-heading mw-heading3"><h3 id="Distillation">Distillation</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Volatility_(chemistry)&action=edit&section=8" title="Edit section: Distillation"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <figure class="mw-default-size" typeof="mw:File/Thumb"><a href="/wiki/File:Crude_Oil_Distillation-en.svg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/6/6e/Crude_Oil_Distillation-en.svg/170px-Crude_Oil_Distillation-en.svg.png" decoding="async" width="170" height="224" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/6/6e/Crude_Oil_Distillation-en.svg/255px-Crude_Oil_Distillation-en.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/6/6e/Crude_Oil_Distillation-en.svg/340px-Crude_Oil_Distillation-en.svg.png 2x" data-file-width="260" data-file-height="342" /></a><figcaption>A crude oil distillation column.</figcaption></figure> <p>Knowledge of volatility is often useful in the separation of components from a mixture. When a mixture of condensed substances contains multiple substances with different levels of volatility, its temperature and pressure can be manipulated such that the more volatile components change to a vapor while the less volatile substances remain in the liquid or solid phase. The newly formed vapor can then be discarded or condensed into a separate container. When the vapors are collected, this process is known as <a href="/wiki/Distillation" title="Distillation">distillation</a>.<sup id="cite_ref-6" class="reference"><a href="#cite_note-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup> </p><p>The process of <a href="/wiki/Petroleum_refining_processes" title="Petroleum refining processes">petroleum refinement</a> utilizes a technique known as <a href="/wiki/Fractional_distillation" title="Fractional distillation">fractional distillation</a>, which allows several chemicals of varying volatility to be separated in a single step. <a href="/wiki/Crude_oil" class="mw-redirect" title="Crude oil">Crude oil</a> entering a refinery is composed of many useful chemicals that need to be separated. The crude oil flows into a distillation tower and is heated up, which allows the more volatile components such as <a href="/wiki/Butane" title="Butane">butane</a> and <a href="/wiki/Kerosene" title="Kerosene">kerosene</a> to vaporize. These vapors move up the tower and eventually come in contact with cold surfaces, which causes them to condense and be collected. The most volatile chemical condense at the top of the column while the least volatile chemicals to vaporize condense in the lowest portion.<sup id="cite_ref-:1_1-1" class="reference"><a href="#cite_note-:1-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> On the right is a picture illustrating the design of a <a href="/wiki/Distillation_tower" class="mw-redirect" title="Distillation tower">distillation tower</a>. </p><p>The difference in volatility between water and ethanol has traditionally been used in the refinement of <a href="/wiki/Drinking_alcohol" class="mw-redirect" title="Drinking alcohol">drinking alcohol</a>. In order to increase the concentration of <a href="/wiki/Ethanol" title="Ethanol">ethanol</a> in the product, alcohol makers would heat the initial alcohol mixture to a temperature where most of the ethanol vaporizes while most of the water remains liquid. The ethanol vapor is then collected and condensed in a separate container, resulting in a much more concentrated product.<sup id="cite_ref-7" class="reference"><a href="#cite_note-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="Perfume">Perfume</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Volatility_(chemistry)&action=edit&section=9" title="Edit section: Perfume"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Volatility is an important consideration when crafting <a href="/wiki/Perfume" title="Perfume">perfumes</a>. Humans detect <a href="/wiki/Odor" title="Odor">odors</a> when <a href="/wiki/Aroma_compound" title="Aroma compound">aromatic vapors</a> come in contact with receptors in the nose. Ingredients that vaporize quickly after being applied will produce fragrant vapors for a short time before the oils evaporate. Slow-evaporating ingredients can stay on the skin for weeks or even months, but may not produce enough vapors to produce a strong aroma. To prevent these problems, perfume designers carefully consider the volatility of essential oils and other ingredients in their perfumes. Appropriate evaporation rates are achieved by modifying the amount of highly volatile and non-volatile ingredients used.<sup id="cite_ref-8" class="reference"><a href="#cite_note-8"><span class="cite-bracket">[</span>8<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="See_also">See also</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Volatility_(chemistry)&action=edit&section=10" title="Edit section: See also"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a href="/wiki/Clausius%E2%80%93Clapeyron_relation" title="Clausius–Clapeyron relation">Clausius–Clapeyron relation</a></li> <li><a href="/wiki/Distillation" title="Distillation">Distillation</a></li> <li><a href="/wiki/Fractional_distillation" title="Fractional distillation">Fractional distillation</a></li> <li><a href="/wiki/Partial_pressure" title="Partial pressure">Partial pressure</a></li> <li><a href="/wiki/Raoult%27s_law" title="Raoult's law">Raoult's law</a></li> <li><a href="/wiki/Relative_volatility" title="Relative volatility">Relative volatility</a></li> <li><a href="/wiki/Vapor%E2%80%93liquid_equilibrium" title="Vapor–liquid equilibrium">Vapor–liquid equilibrium</a></li> <li><a href="/wiki/Volatile_organic_compound" title="Volatile organic compound">Volatile organic compound</a></li></ul> <div class="mw-heading mw-heading2"><h2 id="References">References</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Volatility_(chemistry)&action=edit&section=11" title="Edit section: References"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <style data-mw-deduplicate="TemplateStyles:r1239543626">.mw-parser-output .reflist{margin-bottom:0.5em;list-style-type:decimal}@media screen{.mw-parser-output .reflist{font-size:90%}}.mw-parser-output .reflist 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class="reference-text"><style data-mw-deduplicate="TemplateStyles:r1238218222">.mw-parser-output cite.citation{font-style:inherit;word-wrap:break-word}.mw-parser-output .citation q{quotes:"\"""\"""'""'"}.mw-parser-output .citation:target{background-color:rgba(0,127,255,0.133)}.mw-parser-output .id-lock-free.id-lock-free a{background:url("//upload.wikimedia.org/wikipedia/commons/6/65/Lock-green.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-limited.id-lock-limited a,.mw-parser-output .id-lock-registration.id-lock-registration a{background:url("//upload.wikimedia.org/wikipedia/commons/d/d6/Lock-gray-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-subscription.id-lock-subscription a{background:url("//upload.wikimedia.org/wikipedia/commons/a/aa/Lock-red-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .cs1-ws-icon a{background:url("//upload.wikimedia.org/wikipedia/commons/4/4c/Wikisource-logo.svg")right 0.1em center/12px 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.cs1-format{font-size:95%}html.skin-theme-clientpref-night .mw-parser-output .cs1-maint{color:#18911f}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .cs1-maint{color:#18911f}}</style><cite id="CITEREFFelder2015" class="citation book cs1">Felder, Richard (2015). <i>Elementary Principles of Chemical Processes</i>. John Wiley & Sons. pp. 279–281. <a href="/wiki/ISBN_(identifier)" class="mw-redirect" title="ISBN (identifier)">ISBN</a> <a href="/wiki/Special:BookSources/978-1-119-17764-7" title="Special:BookSources/978-1-119-17764-7"><bdi>978-1-119-17764-7</bdi></a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=book&rft.btitle=Elementary+Principles+of+Chemical+Processes&rft.pages=279-281&rft.pub=John+Wiley+%26+Sons&rft.date=2015&rft.isbn=978-1-119-17764-7&rft.aulast=Felder&rft.aufirst=Richard&rfr_id=info%3Asid%2Fen.wikipedia.org%3AVolatility+%28chemistry%29" class="Z3988"></span></span> </li> <li id="cite_note-2"><span class="mw-cite-backlink"><b><a href="#cite_ref-2">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFKoretsky2013" class="citation book cs1">Koretsky, Milo D. (2013). <i>Engineering and Chemical Thermodynamics</i>. John Wiley & Sons. pp. 639–641.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=book&rft.btitle=Engineering+and+Chemical+Thermodynamics&rft.pages=639-641&rft.pub=John+Wiley+%26+Sons&rft.date=2013&rft.aulast=Koretsky&rft.aufirst=Milo+D.&rfr_id=info%3Asid%2Fen.wikipedia.org%3AVolatility+%28chemistry%29" class="Z3988"></span></span> </li> <li id="cite_note-:0-3"><span class="mw-cite-backlink">^ <a href="#cite_ref-:0_3-0"><sup><i><b>a</b></i></sup></a> <a href="#cite_ref-:0_3-1"><sup><i><b>b</b></i></sup></a></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFZumdahl2007" class="citation book cs1">Zumdahl, Steven S. (2007). <span class="id-lock-limited" title="Free access subject to limited trial, subscription normally required"><a rel="nofollow" class="external text" href="https://archive.org/details/chemistryseventh00zumd"><i>Chemistry</i></a></span>. Houghton Mifflin. pp. <a rel="nofollow" class="external text" href="https://archive.org/details/chemistryseventh00zumd/page/n484">460</a>-466. <a href="/wiki/ISBN_(identifier)" class="mw-redirect" title="ISBN (identifier)">ISBN</a> <a href="/wiki/Special:BookSources/978-0-618-52844-8" title="Special:BookSources/978-0-618-52844-8"><bdi>978-0-618-52844-8</bdi></a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=book&rft.btitle=Chemistry&rft.pages=460-466&rft.pub=Houghton+Mifflin&rft.date=2007&rft.isbn=978-0-618-52844-8&rft.aulast=Zumdahl&rft.aufirst=Steven+S.&rft_id=https%3A%2F%2Farchive.org%2Fdetails%2Fchemistryseventh00zumd&rfr_id=info%3Asid%2Fen.wikipedia.org%3AVolatility+%28chemistry%29" class="Z3988"></span></span> </li> <li id="cite_note-4"><span class="mw-cite-backlink"><b><a href="#cite_ref-4">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFAtkins2013" class="citation book cs1">Atkins, Peter (2013). <i>Chemical Principles</i>. New York: W.H. Freeman and Company. pp. 368–369. <a href="/wiki/ISBN_(identifier)" class="mw-redirect" title="ISBN (identifier)">ISBN</a> <a href="/wiki/Special:BookSources/978-1-319-07903-1" title="Special:BookSources/978-1-319-07903-1"><bdi>978-1-319-07903-1</bdi></a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=book&rft.btitle=Chemical+Principles&rft.place=New+York&rft.pages=368-369&rft.pub=W.H.+Freeman+and+Company&rft.date=2013&rft.isbn=978-1-319-07903-1&rft.aulast=Atkins&rft.aufirst=Peter&rfr_id=info%3Asid%2Fen.wikipedia.org%3AVolatility+%28chemistry%29" class="Z3988"></span></span> </li> <li id="cite_note-5"><span class="mw-cite-backlink"><b><a href="#cite_ref-5">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite class="citation web cs1"><a rel="nofollow" class="external text" href="https://web.archive.org/web/20230207204010/http://chemistry.elmhurst.edu/vchembook/501hcboilingpts.html">"Hydrocarbon boiling points"</a>. Archived from <a rel="nofollow" class="external text" href="http://chemistry.elmhurst.edu/vchembook/501hcboilingpts.html">the original</a> on 7 February 2023<span class="reference-accessdate">. Retrieved <span class="nowrap">28 April</span> 2021</span>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=unknown&rft.btitle=Hydrocarbon+boiling+points&rft_id=http%3A%2F%2Fchemistry.elmhurst.edu%2Fvchembook%2F501hcboilingpts.html&rfr_id=info%3Asid%2Fen.wikipedia.org%3AVolatility+%28chemistry%29" class="Z3988"></span></span> </li> <li id="cite_note-6"><span class="mw-cite-backlink"><b><a href="#cite_ref-6">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFArmarego2009" class="citation book cs1">Armarego, Wilfred L. F. (2009). <span class="id-lock-limited" title="Free access subject to limited trial, subscription normally required"><a rel="nofollow" class="external text" href="https://archive.org/details/purificationlabo00arma"><i>Purification of Laboratory Chemicals</i></a></span>. Elsevier. pp. <a rel="nofollow" class="external text" href="https://archive.org/details/purificationlabo00arma/page/n17">9</a>-12. <a href="/wiki/ISBN_(identifier)" class="mw-redirect" title="ISBN (identifier)">ISBN</a> <a href="/wiki/Special:BookSources/978-1-85617-567-8" title="Special:BookSources/978-1-85617-567-8"><bdi>978-1-85617-567-8</bdi></a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=book&rft.btitle=Purification+of+Laboratory+Chemicals&rft.pages=9-12&rft.pub=Elsevier&rft.date=2009&rft.isbn=978-1-85617-567-8&rft.aulast=Armarego&rft.aufirst=Wilfred+L.+F.&rft_id=https%3A%2F%2Farchive.org%2Fdetails%2Fpurificationlabo00arma&rfr_id=info%3Asid%2Fen.wikipedia.org%3AVolatility+%28chemistry%29" class="Z3988"></span></span> </li> <li id="cite_note-7"><span class="mw-cite-backlink"><b><a href="#cite_ref-7">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFKvaalen" class="citation web cs1">Kvaalen, Eric. <a rel="nofollow" class="external text" href="https://www.extension.purdue.edu/extmedia/AE/AE-117.html">"Alcohol Distillation: Basic Principles, Equipment, Performance Relationships, and Safety"</a>. <i>Purdue</i>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=unknown&rft.jtitle=Purdue&rft.atitle=Alcohol+Distillation%3A+Basic+Principles%2C+Equipment%2C+Performance+Relationships%2C+and+Safety&rft.aulast=Kvaalen&rft.aufirst=Eric&rft_id=https%3A%2F%2Fwww.extension.purdue.edu%2Fextmedia%2FAE%2FAE-117.html&rfr_id=info%3Asid%2Fen.wikipedia.org%3AVolatility+%28chemistry%29" class="Z3988"></span></span> </li> <li id="cite_note-8"><span class="mw-cite-backlink"><b><a href="#cite_ref-8">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFSell2006" class="citation book cs1">Sell, Charles (2006). <span class="id-lock-limited" title="Free access subject to limited trial, subscription normally required"><a rel="nofollow" class="external text" href="https://archive.org/details/chemistryfragran00sell"><i>The Chemistry of Fragrances</i></a></span>. UK: The Royal Society of Chemistry. pp. <a rel="nofollow" class="external text" href="https://archive.org/details/chemistryfragran00sell/page/n217">200</a>-202. <a href="/wiki/ISBN_(identifier)" class="mw-redirect" title="ISBN (identifier)">ISBN</a> <a href="/wiki/Special:BookSources/978-0-85404-824-3" title="Special:BookSources/978-0-85404-824-3"><bdi>978-0-85404-824-3</bdi></a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=book&rft.btitle=The+Chemistry+of+Fragrances&rft.place=UK&rft.pages=200-202&rft.pub=The+Royal+Society+of+Chemistry&rft.date=2006&rft.isbn=978-0-85404-824-3&rft.aulast=Sell&rft.aufirst=Charles&rft_id=https%3A%2F%2Farchive.org%2Fdetails%2Fchemistryfragran00sell&rfr_id=info%3Asid%2Fen.wikipedia.org%3AVolatility+%28chemistry%29" class="Z3988"></span></span> </li> </ol></div></div> <div class="mw-heading mw-heading2"><h2 id="External_links">External links</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Volatility_(chemistry)&action=edit&section=12" title="Edit section: External links"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a rel="nofollow" class="external text" href="http://www.ilpi.com/msds/ref/volatility.html">Volatility from ilpi.com</a></li> <li><a href="https://en.wiktionary.org/wiki/volatile" class="extiw" title="wikt:volatile">Definition of volatile from Wiktionary</a></li></ul> <div class="navbox-styles"><style data-mw-deduplicate="TemplateStyles:r1129693374">.mw-parser-output .hlist dl,.mw-parser-output .hlist ol,.mw-parser-output .hlist ul{margin:0;padding:0}.mw-parser-output .hlist dd,.mw-parser-output .hlist dt,.mw-parser-output .hlist li{margin:0;display:inline}.mw-parser-output .hlist.inline,.mw-parser-output .hlist.inline dl,.mw-parser-output .hlist.inline ol,.mw-parser-output .hlist.inline ul,.mw-parser-output .hlist dl dl,.mw-parser-output .hlist dl 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<li><a href="/wiki/Plasma_(physics)" title="Plasma (physics)">Plasma</a></li></ul> </div></td><td class="noviewer navbox-image" rowspan="7" style="width:1px;padding:0 0 0 2px"><div><span typeof="mw:File"><a href="/wiki/File:Phase_change_-_en.svg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/0/0b/Phase_change_-_en.svg/150px-Phase_change_-_en.svg.png" decoding="async" width="150" height="159" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/0/0b/Phase_change_-_en.svg/225px-Phase_change_-_en.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/0/0b/Phase_change_-_en.svg/300px-Phase_change_-_en.svg.png 2x" data-file-width="493" data-file-height="524" /></a></span></div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">Low energy</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Bose%E2%80%93Einstein_condensate" title="Bose–Einstein condensate">Bose–Einstein condensate</a></li> <li><a href="/wiki/Fermionic_condensate" title="Fermionic condensate">Fermionic condensate</a></li> <li><a href="/wiki/Degenerate_matter" title="Degenerate matter">Degenerate matter</a></li> <li><a href="/wiki/Quantum_Hall_effect" title="Quantum Hall effect">Quantum Hall</a></li> <li><a href="/wiki/Rydberg_matter" title="Rydberg matter">Rydberg matter</a></li> <li><a href="/wiki/Strange_matter" title="Strange matter">Strange matter</a></li> <li><a href="/wiki/Superfluidity" title="Superfluidity">Superfluid</a></li> <li><a href="/wiki/Supersolid" title="Supersolid">Supersolid</a></li> <li><a href="/wiki/Photonic_molecule" title="Photonic molecule">Photonic molecule</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">High energy</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/QCD_matter" title="QCD matter">QCD matter</a></li> <li><a href="/wiki/Quark%E2%80%93gluon_plasma" title="Quark–gluon plasma">Quark–gluon plasma</a></li> <li><a href="/wiki/Color-glass_condensate" title="Color-glass condensate">Color-glass condensate</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">Other states</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Colloid" title="Colloid">Colloid</a></li> <li><a href="/wiki/Crystal" title="Crystal">Crystal</a></li> <li><a href="/wiki/Liquid_crystal" title="Liquid crystal">Liquid crystal</a></li> <li><a href="/wiki/Time_crystal" title="Time crystal">Time crystal</a></li> <li><a href="/wiki/Quantum_spin_liquid" title="Quantum spin liquid">Quantum spin liquid</a></li> <li><a href="/wiki/Exotic_matter" title="Exotic matter">Exotic matter</a></li> <li><a href="/wiki/Programmable_matter" title="Programmable matter">Programmable matter</a></li> <li><a href="/wiki/Dark_matter" title="Dark matter">Dark matter</a></li> <li><a href="/wiki/Antimatter" title="Antimatter">Antimatter</a></li> <li>Magnetically ordered <ul><li><a href="/wiki/Antiferromagnetism" title="Antiferromagnetism">Antiferromagnet</a></li> <li><a href="/wiki/Ferrimagnetism" title="Ferrimagnetism">Ferrimagnet</a></li> <li><a href="/wiki/Ferromagnetism" title="Ferromagnetism">Ferromagnet</a></li></ul></li> <li><a href="/wiki/String-net_liquid" title="String-net liquid">String-net liquid</a></li> <li><a href="/wiki/Superglass" title="Superglass">Superglass</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Phase_transitions" class="mw-redirect" title="Phase transitions">Phase transitions</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Boiling" title="Boiling">Boiling</a></li> <li><a href="/wiki/Boiling_point" title="Boiling point">Boiling point</a></li> <li><a href="/wiki/Condensation" title="Condensation">Condensation</a></li> <li><a href="/wiki/Critical_line_(thermodynamics)" title="Critical line (thermodynamics)">Critical line</a></li> <li><a href="/wiki/Critical_point_(thermodynamics)" title="Critical point (thermodynamics)">Critical point</a></li> <li><a href="/wiki/Crystallization" title="Crystallization">Crystallization</a></li> <li><a href="/wiki/Deposition_(phase_transition)" title="Deposition (phase transition)">Deposition</a></li> <li><a href="/wiki/Evaporation" title="Evaporation">Evaporation</a></li> <li><a href="/wiki/Flash_evaporation" title="Flash evaporation">Flash evaporation</a></li> <li><a href="/wiki/Freezing" title="Freezing">Freezing</a></li> <li><a href="/wiki/Chemical_ionization" title="Chemical ionization">Chemical ionization</a></li> <li><a href="/wiki/Ionization" title="Ionization">Ionization</a></li> <li><a href="/wiki/Lambda_point" title="Lambda point">Lambda point</a></li> <li><a href="/wiki/Melting" title="Melting">Melting</a></li> <li><a href="/wiki/Melting_point" title="Melting point">Melting point</a></li> <li><a href="/wiki/Plasma_recombination" title="Plasma recombination">Recombination</a></li> <li><a href="/wiki/Regelation" title="Regelation">Regelation</a></li> <li><a href="/wiki/Vapor%E2%80%93liquid_equilibrium" title="Vapor–liquid equilibrium">Saturated fluid</a></li> <li><a href="/wiki/Sublimation_(phase_transition)" title="Sublimation (phase transition)">Sublimation</a></li> <li><a href="/wiki/Supercooling" title="Supercooling">Supercooling</a></li> <li><a href="/wiki/Triple_point" title="Triple point">Triple point</a></li> <li><a href="/wiki/Vaporization" title="Vaporization">Vaporization</a></li> <li><a href="/wiki/Vitrification" title="Vitrification">Vitrification</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">Quantities</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Enthalpy_of_fusion" title="Enthalpy of fusion">Enthalpy of fusion</a></li> <li><a href="/wiki/Enthalpy_of_sublimation" title="Enthalpy of sublimation">Enthalpy of sublimation</a></li> <li><a href="/wiki/Enthalpy_of_vaporization" title="Enthalpy of vaporization">Enthalpy of vaporization</a></li> <li><a href="/wiki/Latent_heat" title="Latent heat">Latent heat</a></li> <li><a href="/wiki/Latent_internal_energy" title="Latent internal energy">Latent internal energy</a></li> <li><a href="/wiki/Trouton%27s_rule" title="Trouton's rule">Trouton's rule</a></li> <li><a class="mw-selflink selflink">Volatility</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">Concepts</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Baryonic_matter" class="mw-redirect" title="Baryonic matter">Baryonic matter</a></li> <li><a href="/wiki/Binodal" title="Binodal">Binodal</a></li> <li><a href="/wiki/Compressed_fluid" title="Compressed fluid">Compressed fluid</a></li> <li><a href="/wiki/Cooling_curve" title="Cooling curve">Cooling curve</a></li> <li><a href="/wiki/Equation_of_state" title="Equation of state">Equation of state</a></li> <li><a href="/wiki/Leidenfrost_effect" title="Leidenfrost effect">Leidenfrost effect</a></li> <li><a href="/wiki/Macroscopic_quantum_phenomena" title="Macroscopic quantum phenomena">Macroscopic quantum phenomena</a></li> <li><a href="/wiki/Mpemba_effect" title="Mpemba effect">Mpemba effect</a></li> <li><a href="/wiki/Order_and_disorder_(physics)" class="mw-redirect" title="Order and disorder (physics)">Order and disorder (physics)</a></li> <li><a href="/wiki/Spinodal" title="Spinodal">Spinodal</a></li> <li><a href="/wiki/Superconductivity" title="Superconductivity">Superconductivity</a></li> <li><a href="/wiki/Superheated_water" title="Superheated water">Superheated vapor</a></li> <li><a href="/wiki/Superheating" title="Superheating">Superheating</a></li> <li><a href="/wiki/Thermo-dielectric_effect" title="Thermo-dielectric effect">Thermo-dielectric effect</a></li></ul> </div></td></tr></tbody></table></div> <!-- NewPP limit report Parsed by mw‐web.codfw.main‐f69cdc8f6‐ps8jv Cached time: 20241122143359 Cache expiry: 2592000 Reduced expiry: false Complications: [vary‐revision‐sha1, show‐toc] CPU time usage: 0.275 seconds Real time usage: 0.352 seconds Preprocessor visited node count: 721/1000000 Post‐expand include size: 27349/2097152 bytes Template argument size: 510/2097152 bytes Highest expansion depth: 8/100 Expensive parser function count: 1/500 Unstrip recursion depth: 1/20 Unstrip post‐expand size: 36910/5000000 bytes Lua time usage: 0.179/10.000 seconds Lua memory usage: 4866136/52428800 bytes Number of Wikibase 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