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id="toc-High_pressure_hydrogenation_of_aluminium-sublist" class="vector-toc-list"> </ul> </li> </ul> </li> <li id="toc-Reactions" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#Reactions"> <div class="vector-toc-text"> <span class="vector-toc-numb">4</span> <span>Reactions</span> </div> </a> <button aria-controls="toc-Reactions-sublist" class="cdx-button cdx-button--weight-quiet cdx-button--icon-only vector-toc-toggle"> <span class="vector-icon mw-ui-icon-wikimedia-expand"></span> <span>Toggle Reactions subsection</span> </button> <ul id="toc-Reactions-sublist" class="vector-toc-list"> <li id="toc-Formation_of_adducts_with_Lewis_bases" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Formation_of_adducts_with_Lewis_bases"> <div class="vector-toc-text"> <span class="vector-toc-numb">4.1</span> <span>Formation of adducts with Lewis bases</span> </div> </a> <ul id="toc-Formation_of_adducts_with_Lewis_bases-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Reduction_of_functional_groups" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Reduction_of_functional_groups"> <div class="vector-toc-text"> <span class="vector-toc-numb">4.2</span> <span>Reduction of functional groups</span> </div> </a> <ul id="toc-Reduction_of_functional_groups-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Hydroalumination" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Hydroalumination"> <div class="vector-toc-text"> <span class="vector-toc-numb">4.3</span> <span>Hydroalumination</span> </div> </a> <ul id="toc-Hydroalumination-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Fuel" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Fuel"> <div class="vector-toc-text"> <span class="vector-toc-numb">4.4</span> <span>Fuel</span> </div> </a> <ul id="toc-Fuel-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Deposition" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Deposition"> <div class="vector-toc-text"> <span class="vector-toc-numb">4.5</span> <span>Deposition</span> </div> </a> <ul id="toc-Deposition-sublist" class="vector-toc-list"> </ul> </li> </ul> </li> <li id="toc-References" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#References"> <div class="vector-toc-text"> <span class="vector-toc-numb">5</span> <span>References</span> </div> </a> <ul id="toc-References-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-External_links" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#External_links"> <div class="vector-toc-text"> <span class="vector-toc-numb">6</span> <span>External links</span> </div> </a> <ul id="toc-External_links-sublist" class="vector-toc-list"> </ul> </li> </ul> </div> </div> </nav> </div> </div> <div class="mw-content-container"> <main id="content" class="mw-body"> <header class="mw-body-header vector-page-titlebar"> <nav aria-label="Contents" class="vector-toc-landmark"> <div id="vector-page-titlebar-toc" class="vector-dropdown vector-page-titlebar-toc vector-button-flush-left" > <input type="checkbox" id="vector-page-titlebar-toc-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-page-titlebar-toc" class="vector-dropdown-checkbox " aria-label="Toggle the table of contents" > <label id="vector-page-titlebar-toc-label" for="vector-page-titlebar-toc-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only " aria-hidden="true" ><span class="vector-icon mw-ui-icon-listBullet mw-ui-icon-wikimedia-listBullet"></span> <span class="vector-dropdown-label-text">Toggle the table of contents</span> </label> <div class="vector-dropdown-content"> <div id="vector-page-titlebar-toc-unpinned-container" class="vector-unpinned-container"> </div> </div> </div> </nav> <h1 id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">Aluminium hydride</span></h1> <div id="p-lang-btn" class="vector-dropdown mw-portlet mw-portlet-lang" > <input type="checkbox" id="p-lang-btn-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-p-lang-btn" class="vector-dropdown-checkbox mw-interlanguage-selector" aria-label="Go to an article in another language. Available in 26 languages" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-26" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">26 languages</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D9%87%D9%8A%D8%AF%D8%B1%D9%8A%D8%AF_%D8%A7%D9%84%D8%A3%D9%84%D9%88%D9%85%D9%86%D9%8A%D9%88%D9%85" title="هيدريد الألومنيوم – Arabic" lang="ar" hreflang="ar" data-title="هيدريد الألومنيوم" data-language-autonym="العربية" data-language-local-name="Arabic" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-azb mw-list-item"><a href="https://azb.wikipedia.org/wiki/%D9%87%DB%8C%D8%AF%D8%B1%DB%8C%D8%AF_%D8%A2%D9%84%D9%88%D9%85%DB%8C%D9%86%DB%8C%D9%88%D9%85" title="هیدرید آلومینیوم – South Azerbaijani" lang="azb" hreflang="azb" data-title="هیدرید آلومینیوم" data-language-autonym="تۆرکجه" data-language-local-name="South Azerbaijani" class="interlanguage-link-target"><span>تۆرکجه</span></a></li><li class="interlanguage-link interwiki-ca mw-list-item"><a href="https://ca.wikipedia.org/wiki/Hidrur_d%27alumini" title="Hidrur d'alumini – Catalan" lang="ca" hreflang="ca" data-title="Hidrur d'alumini" data-language-autonym="Català" data-language-local-name="Catalan" class="interlanguage-link-target"><span>Català</span></a></li><li class="interlanguage-link interwiki-cs mw-list-item"><a href="https://cs.wikipedia.org/wiki/Alan_(chemie)" title="Alan (chemie) – Czech" lang="cs" hreflang="cs" data-title="Alan (chemie)" data-language-autonym="Čeština" data-language-local-name="Czech" class="interlanguage-link-target"><span>Čeština</span></a></li><li class="interlanguage-link interwiki-de mw-list-item"><a href="https://de.wikipedia.org/wiki/Aluminiumhydrid" title="Aluminiumhydrid – German" lang="de" hreflang="de" data-title="Aluminiumhydrid" data-language-autonym="Deutsch" data-language-local-name="German" class="interlanguage-link-target"><span>Deutsch</span></a></li><li class="interlanguage-link interwiki-es mw-list-item"><a href="https://es.wikipedia.org/wiki/Hidruro_de_aluminio" title="Hidruro de aluminio – Spanish" lang="es" hreflang="es" data-title="Hidruro de aluminio" data-language-autonym="Español" data-language-local-name="Spanish" class="interlanguage-link-target"><span>Español</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%D9%87%DB%8C%D8%AF%D8%B1%DB%8C%D8%AF_%D8%A2%D9%84%D9%88%D9%85%DB%8C%D9%86%DB%8C%D9%88%D9%85" title="هیدرید آلومینیوم – Persian" lang="fa" hreflang="fa" data-title="هیدرید آلومینیوم" data-language-autonym="فارسی" data-language-local-name="Persian" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/Hydrure_d%27aluminium" title="Hydrure d'aluminium – French" lang="fr" hreflang="fr" data-title="Hydrure d'aluminium" data-language-autonym="Français" data-language-local-name="French" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-hi mw-list-item"><a href="https://hi.wikipedia.org/wiki/%E0%A4%85%E0%A4%B2%E0%A5%8D%E0%A4%AF%E0%A5%81%E0%A4%AE%E0%A4%BF%E0%A4%A8%E0%A4%BF%E0%A4%AF%E0%A4%AE_%E0%A4%B9%E0%A4%BE%E0%A4%87%E0%A4%A1%E0%A5%8D%E0%A4%B0%E0%A4%BE%E0%A4%87%E0%A4%A1" title="अल्युमिनियम हाइड्राइड – Hindi" lang="hi" hreflang="hi" data-title="अल्युमिनियम हाइड्राइड" data-language-autonym="हिन्दी" data-language-local-name="Hindi" class="interlanguage-link-target"><span>हिन्दी</span></a></li><li class="interlanguage-link interwiki-it mw-list-item"><a href="https://it.wikipedia.org/wiki/Idruro_di_alluminio" title="Idruro di alluminio – Italian" lang="it" hreflang="it" data-title="Idruro di alluminio" data-language-autonym="Italiano" data-language-local-name="Italian" class="interlanguage-link-target"><span>Italiano</span></a></li><li class="interlanguage-link interwiki-mk mw-list-item"><a href="https://mk.wikipedia.org/wiki/%D0%90%D0%BB%D1%83%D0%BC%D0%B8%D0%BD%D0%B8%D1%83%D0%BC_%D1%85%D0%B8%D0%B4%D1%80%D0%B8%D0%B4" title="Алуминиум хидрид – Macedonian" lang="mk" hreflang="mk" data-title="Алуминиум хидрид" data-language-autonym="Македонски" data-language-local-name="Macedonian" class="interlanguage-link-target"><span>Македонски</span></a></li><li class="interlanguage-link interwiki-nl mw-list-item"><a href="https://nl.wikipedia.org/wiki/Aluminiumhydride" title="Aluminiumhydride – Dutch" lang="nl" hreflang="nl" data-title="Aluminiumhydride" data-language-autonym="Nederlands" data-language-local-name="Dutch" class="interlanguage-link-target"><span>Nederlands</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E6%B0%B4%E7%B4%A0%E5%8C%96%E3%82%A2%E3%83%AB%E3%83%9F%E3%83%8B%E3%82%A6%E3%83%A0" title="水素化アルミニウム – Japanese" lang="ja" hreflang="ja" data-title="水素化アルミニウム" data-language-autonym="日本語" data-language-local-name="Japanese" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-no mw-list-item"><a href="https://no.wikipedia.org/wiki/Alan" title="Alan – Norwegian Bokmål" lang="nb" hreflang="nb" data-title="Alan" data-language-autonym="Norsk bokmål" data-language-local-name="Norwegian Bokmål" class="interlanguage-link-target"><span>Norsk bokmål</span></a></li><li class="interlanguage-link interwiki-uz mw-list-item"><a href="https://uz.wikipedia.org/wiki/Aluminiy_gidrid" title="Aluminiy gidrid – Uzbek" lang="uz" hreflang="uz" data-title="Aluminiy gidrid" data-language-autonym="Oʻzbekcha / ўзбекча" data-language-local-name="Uzbek" class="interlanguage-link-target"><span>Oʻzbekcha / ўзбекча</span></a></li><li class="interlanguage-link interwiki-ru mw-list-item"><a href="https://ru.wikipedia.org/wiki/%D0%93%D0%B8%D0%B4%D1%80%D0%B8%D0%B4_%D0%B0%D0%BB%D1%8E%D0%BC%D0%B8%D0%BD%D0%B8%D1%8F" title="Гидрид алюминия – Russian" lang="ru" hreflang="ru" data-title="Гидрид алюминия" data-language-autonym="Русский" data-language-local-name="Russian" class="interlanguage-link-target"><span>Русский</span></a></li><li class="interlanguage-link interwiki-sl mw-list-item"><a href="https://sl.wikipedia.org/wiki/Aluminijev_hidrid" title="Aluminijev hidrid – Slovenian" lang="sl" hreflang="sl" data-title="Aluminijev hidrid" data-language-autonym="Slovenščina" data-language-local-name="Slovenian" class="interlanguage-link-target"><span>Slovenščina</span></a></li><li class="interlanguage-link interwiki-sr mw-list-item"><a href="https://sr.wikipedia.org/wiki/Aluminijum_hidrid" title="Aluminijum hidrid – Serbian" lang="sr" hreflang="sr" data-title="Aluminijum hidrid" data-language-autonym="Српски / srpski" data-language-local-name="Serbian" class="interlanguage-link-target"><span>Српски / srpski</span></a></li><li class="interlanguage-link interwiki-sh mw-list-item"><a href="https://sh.wikipedia.org/wiki/Aluminijum_hidrid" title="Aluminijum hidrid – Serbo-Croatian" lang="sh" hreflang="sh" data-title="Aluminijum hidrid" data-language-autonym="Srpskohrvatski / српскохрватски" data-language-local-name="Serbo-Croatian" class="interlanguage-link-target"><span>Srpskohrvatski / српскохрватски</span></a></li><li class="interlanguage-link interwiki-fi mw-list-item"><a href="https://fi.wikipedia.org/wiki/Alumiinihydridi" title="Alumiinihydridi – Finnish" lang="fi" hreflang="fi" data-title="Alumiinihydridi" data-language-autonym="Suomi" data-language-local-name="Finnish" class="interlanguage-link-target"><span>Suomi</span></a></li><li class="interlanguage-link interwiki-sv mw-list-item"><a href="https://sv.wikipedia.org/wiki/Aluminiumhydrid" title="Aluminiumhydrid – Swedish" lang="sv" hreflang="sv" data-title="Aluminiumhydrid" data-language-autonym="Svenska" data-language-local-name="Swedish" class="interlanguage-link-target"><span>Svenska</span></a></li><li class="interlanguage-link interwiki-ta mw-list-item"><a href="https://ta.wikipedia.org/wiki/%E0%AE%85%E0%AE%B2%E0%AF%81%E0%AE%AE%E0%AE%BF%E0%AE%A9%E0%AE%BF%E0%AE%AF%E0%AE%AE%E0%AF%8D_%E0%AE%90%E0%AE%A4%E0%AE%B0%E0%AF%88%E0%AE%9F%E0%AF%81" title="அலுமினியம் ஐதரைடு – Tamil" lang="ta" hreflang="ta" data-title="அலுமினியம் ஐதரைடு" data-language-autonym="தமிழ்" data-language-local-name="Tamil" class="interlanguage-link-target"><span>தமிழ்</span></a></li><li class="interlanguage-link interwiki-tr mw-list-item"><a href="https://tr.wikipedia.org/wiki/Al%C3%BCminyum_hidr%C3%BCr" title="Alüminyum hidrür – Turkish" lang="tr" hreflang="tr" data-title="Alüminyum hidrür" data-language-autonym="Türkçe" data-language-local-name="Turkish" class="interlanguage-link-target"><span>Türkçe</span></a></li><li class="interlanguage-link interwiki-uk mw-list-item"><a href="https://uk.wikipedia.org/wiki/%D0%93%D1%96%D0%B4%D1%80%D0%B8%D0%B4_%D0%B0%D0%BB%D1%8E%D0%BC%D1%96%D0%BD%D1%96%D1%8E" title="Гідрид алюмінію – Ukrainian" lang="uk" hreflang="uk" data-title="Гідрид алюмінію" data-language-autonym="Українська" data-language-local-name="Ukrainian" class="interlanguage-link-target"><span>Українська</span></a></li><li class="interlanguage-link interwiki-vi mw-list-item"><a href="https://vi.wikipedia.org/wiki/Nh%C3%B4m_hydride" title="Nhôm hydride – Vietnamese" lang="vi" hreflang="vi" data-title="Nhôm hydride" data-language-autonym="Tiếng Việt" data-language-local-name="Vietnamese" class="interlanguage-link-target"><span>Tiếng Việt</span></a></li><li class="interlanguage-link interwiki-zh mw-list-item"><a href="https://zh.wikipedia.org/wiki/%E6%B0%A2%E5%8C%96%E9%93%9D" title="氢化铝 – Chinese" lang="zh" hreflang="zh" data-title="氢化铝" data-language-autonym="中文" data-language-local-name="Chinese" class="interlanguage-link-target"><span>中文</span></a></li> </ul> <div class="after-portlet after-portlet-lang"><span class="wb-langlinks-edit wb-langlinks-link"><a href="https://www.wikidata.org/wiki/Special:EntityPage/Q412361#sitelinks-wikipedia" title="Edit interlanguage links" class="wbc-editpage">Edit links</a></span></div> </div> </div> </div> </header> <div class="vector-page-toolbar"> <div class="vector-page-toolbar-container"> <div id="left-navigation"> <nav aria-label="Namespaces"> <div id="p-associated-pages" class="vector-menu vector-menu-tabs mw-portlet mw-portlet-associated-pages" > <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li id="ca-nstab-main" class="selected vector-tab-noicon mw-list-item"><a href="/wiki/Aluminium_hydride" title="View the content page 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typeof="mw:File"><a href="/wiki/File:Aluminium-hydride-unit-cell-3D-vdW.png" class="mw-file-description" title="Unit cell spacefill model of aluminium hydride"><img alt="Unit cell spacefill model of aluminium hydride" src="//upload.wikimedia.org/wikipedia/commons/thumb/4/46/Aluminium-hydride-unit-cell-3D-vdW.png/220px-Aluminium-hydride-unit-cell-3D-vdW.png" decoding="async" width="220" height="310" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/4/46/Aluminium-hydride-unit-cell-3D-vdW.png/330px-Aluminium-hydride-unit-cell-3D-vdW.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/4/46/Aluminium-hydride-unit-cell-3D-vdW.png/440px-Aluminium-hydride-unit-cell-3D-vdW.png 2x" data-file-width="780" data-file-height="1100" /></a></span> </td></tr> <tr> <th colspan="2" style="background: #f8eaba; text-align: center;">Names </th></tr> <tr> <td colspan="2" style="text-align:left;"><a href="/wiki/Preferred_IUPAC_name" title="Preferred IUPAC name">Preferred IUPAC name</a> <div style="max-width:22em; word-wrap:break-word; padding-left:1.7em;"><div style="display: inline-block; line-height: 1.2em; padding: .1em 0; max-width:22em;">Aluminium hydride</div></div> </td></tr> <tr> <td colspan="2" style="text-align:left;"><a href="/wiki/Chemical_nomenclature#Systematic_name" title="Chemical nomenclature">Systematic IUPAC name</a> <div style="max-width:22em; word-wrap:break-word; padding-left:1.7em;"><div style="display: inline-block; line-height: 1.2em; padding: .1em 0; max-width:22em;">Alumane</div></div> </td></tr> <tr> <td colspan="2" style="text-align:left;">Other names <div style="max-width:22em; word-wrap:break-word; padding-left:1.7em;"><style data-mw-deduplicate="TemplateStyles:r1126788409">.mw-parser-output .plainlist ol,.mw-parser-output .plainlist ul{line-height:inherit;list-style:none;margin:0;padding:0}.mw-parser-output .plainlist ol li,.mw-parser-output .plainlist ul li{margin-bottom:0}</style><div class="plainlist"><ul><li>Alane</li><li>Aluminic hydride</li><li>Aluminium(III) hydride</li><li>Aluminium trihydride</li><li>Trihydridoaluminium</li></ul></div></div> </td></tr> <tr> <th colspan="2" style="background: #f8eaba; text-align: center;">Identifiers </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/CAS_Registry_Number" title="CAS Registry Number">CAS Number</a></div> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="commonchemistry.cas.org"><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=7784-21-6">7784-21-6</a></span><sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></li></ul></div> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">3D model (<a href="/wiki/JSmol" class="mw-redirect" title="JSmol">JSmol</a>)</div> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="chemapps.stolaf.edu (3D interactive model)"><a rel="nofollow" class="external text" href="https://chemapps.stolaf.edu/jmol/jmol.php?model=%5BAlH3%5D">Interactive image</a></span></li></ul></div> </td></tr> <tr> <td><a href="/wiki/ChEBI" title="ChEBI">ChEBI</a> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="www.ebi.ac.uk"><a rel="nofollow" class="external text" href="https://www.ebi.ac.uk/chebi/searchId.do?chebiId=30136">CHEBI:30136</a></span><sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></li></ul></div> </td></tr> <tr> <td><a href="/wiki/ChemSpider" title="ChemSpider">ChemSpider</a> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="www.chemspider.com"><a rel="nofollow" class="external text" href="https://www.chemspider.com/Chemical-Structure.13833.html">13833</a></span><sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></li><li><span title="www.chemspider.com"><a rel="nofollow" class="external text" href="https://www.chemspider.com/Chemical-Structure.17625618.html">17625618</a></span> (<sup>3</sup><i>H</i><sub>3</sub>)<sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></li></ul></div> </td></tr> <tr> <td><a href="/wiki/ECHA_InfoCard" class="mw-redirect" title="ECHA InfoCard"><span title="echa.europa.eu">ECHA InfoCard</span></a> </td> <td><a rel="nofollow" class="external text" href="https://echa.europa.eu/substance-information/-/substanceinfo/100.029.139">100.029.139</a> <span class="mw-valign-text-top noprint" typeof="mw:File/Frameless"><a href="https://www.wikidata.org/wiki/Q412361#P2566" title="Edit this at Wikidata"><img alt="Edit this at Wikidata" src="//upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/10px-OOjs_UI_icon_edit-ltr-progressive.svg.png" decoding="async" width="10" height="10" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/15px-OOjs_UI_icon_edit-ltr-progressive.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/20px-OOjs_UI_icon_edit-ltr-progressive.svg.png 2x" data-file-width="20" data-file-height="20" /></a></span> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Gmelin_database" title="Gmelin database">Gmelin Reference</a></div> </td> <td>245 </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/PubChem" title="PubChem">PubChem</a> <abbr title="Compound ID">CID</abbr></div> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="pubchem.ncbi.nlm.nih.gov"><a rel="nofollow" class="external text" href="https://pubchem.ncbi.nlm.nih.gov/compound/14488">14488</a></span></li><li><span title="pubchem.ncbi.nlm.nih.gov"><a rel="nofollow" class="external text" href="https://pubchem.ncbi.nlm.nih.gov/compound/14399066">14399066</a></span> (<sup>2</sup><i>H</i><sub>3</sub>)</li><li><span title="pubchem.ncbi.nlm.nih.gov"><a rel="nofollow" class="external text" href="https://pubchem.ncbi.nlm.nih.gov/compound/16721258">16721258</a></span> (<sup>3</sup><i>H</i><sub>3</sub>)</li></ul></div> </td></tr> <tr> <td><a href="/wiki/Unique_Ingredient_Identifier" title="Unique Ingredient Identifier">UNII</a> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="precision.fda.gov"><a rel="nofollow" class="external text" href="https://precision.fda.gov/uniisearch/srs/unii/KZJ3T010RQ">KZJ3T010RQ</a></span><sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></li></ul></div> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/CompTox_Chemicals_Dashboard" title="CompTox Chemicals Dashboard">CompTox Dashboard</a> <span style="font-weight:normal">(<abbr title="U.S. Environmental Protection Agency">EPA</abbr>)</span></div> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="comptox.epa.gov"><a rel="nofollow" class="external text" href="https://comptox.epa.gov/dashboard/chemical/details/DTXSID80895037">DTXSID80895037</a> <span class="mw-valign-text-top noprint" typeof="mw:File/Frameless"><a href="https://www.wikidata.org/wiki/Q412361#P3117" title="Edit this at Wikidata"><img alt="Edit this at Wikidata" src="//upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/10px-OOjs_UI_icon_edit-ltr-progressive.svg.png" decoding="async" width="10" height="10" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/15px-OOjs_UI_icon_edit-ltr-progressive.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/20px-OOjs_UI_icon_edit-ltr-progressive.svg.png 2x" data-file-width="20" data-file-height="20" /></a></span></span></li></ul></div> </td></tr> <tr> <td colspan="2"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold; text-align:left; font-weight:normal; background:transparent;"><div><a href="/wiki/International_Chemical_Identifier" title="International Chemical Identifier">InChI</a></div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0; word-break:break-all;"><li style="line-height: inherit; margin: 0"><div style="border-top:1px solid #ccc; padding:0.2em 0 0.2em 1.5em; text-align:left;"><div style="word-wrap:break-word; text-indent:-1.5em; font-size:97%; line-height:120%;">InChI=1S/Al.3H<sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></div><div style="word-wrap:break-word; text-indent:-1.5em; font-size:97%; line-height:120%;">Key: AZDRQVAHHNSJOQ-UHFFFAOYSA-N<sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></div></div></li><li style="line-height: inherit; margin: 0"><div style="border-top:1px solid #ccc; padding:0.2em 0 0.2em 1.5em; text-align:left;"><div style="word-wrap:break-word; text-indent:-1.5em; font-size:97%; line-height:120%;">InChI=1S/Al.3H</div><div style="word-wrap:break-word; text-indent:-1.5em; font-size:97%; line-height:120%;">Key: AZDRQVAHHNSJOQ-UHFFFAOYSA-N</div></div></li><li style="line-height: inherit; margin: 0"><div style="border-top:1px solid #ccc; padding:0.2em 0 0.2em 1.5em; text-align:left;"><div style="word-wrap:break-word; text-indent:-1.5em; font-size:97%; line-height:120%;">InChI=1/Al.3H/rAlH3/h1H3</div><div style="word-wrap:break-word; text-indent:-1.5em; font-size:97%; line-height:120%;">Key: AZDRQVAHHNSJOQ-FSBNLZEDAV</div></div></li></ul> </div> </td></tr> <tr> <td colspan="2"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold; text-align:left; font-weight:normal; background:transparent;"><div><a href="/wiki/Simplified_molecular-input_line-entry_system" class="mw-redirect" title="Simplified molecular-input line-entry system">SMILES</a></div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0; word-break:break-all;"><li style="line-height: inherit; margin: 0"><div style="border-top:1px solid #ccc; padding:0.2em 0 0.2em 1.6em; word-wrap:break-word; text-indent:-1.5em; text-align:left; font-size:97%; line-height:120%;">[AlH3]</div></li></ul> </div> </td></tr> <tr> <th colspan="2" style="background: #f8eaba; text-align: center;">Properties </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Chemical_formula" title="Chemical formula">Chemical formula</a></div> </td> <td><span title="Aluminium">Al</span><span title="Hydrogen">H</span><sub>3</sub> </td></tr> <tr> <td><a href="/wiki/Molar_mass" title="Molar mass">Molar mass</a> </td> <td><span class="nowrap"><span data-sort-value="7001300060000000000♠"></span>30.006</span> g·mol<sup>−1</sup>   </td></tr> <tr> <td>Appearance </td> <td>white crystalline solid, non-volatile, highly polymerized, needle-like crystals </td></tr> <tr> <td><a href="/wiki/Density" title="Density">Density</a> </td> <td>1.477 g/cm<sup>3</sup>, solid </td></tr> <tr> <td><a href="/wiki/Melting_point" title="Melting point">Melting point</a> </td> <td>150 °C (302 °F; 423 K) starts decomposing at 105 °C (221 °F) </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Aqueous_solution" title="Aqueous solution">Solubility in water</a></div> </td> <td>reacts </td></tr> <tr> <td><a href="/wiki/Solubility" title="Solubility">Solubility</a> </td> <td>soluble in <a href="/wiki/Diethyl_ether" title="Diethyl ether">ether</a> <br /> reacts in <a href="/wiki/Ethanol" title="Ethanol">ethanol</a> </td></tr> <tr> <th colspan="2" style="background: #f8eaba; text-align: center;">Thermochemistry </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Heat_capacity" title="Heat capacity">Heat capacity</a> <span style="font-size:112%;">(<i>C</i>)</span></div> </td> <td>40.2 J/(mol·K) </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Standard_molar_entropy" title="Standard molar entropy">Std molar<br />entropy</a> <span style="font-size:112%;">(<i>S</i><sup>⦵</sup><sub>298</sub>)</span></div> </td> <td>30 J/(mol·K) </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Standard_enthalpy_change_of_formation" class="mw-redirect" title="Standard enthalpy change of formation">Std enthalpy of<br />formation</a> <span style="font-size:112%;">(Δ<sub>f</sub><i>H</i><sup>⦵</sup><sub>298</sub>)</span></div> </td> <td>−11.4 kJ/mol </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Gibbs_free_energy#Standard_energy_change_of_formation" title="Gibbs free energy">Gibbs free energy</a> <span style="font-size:112%;">(Δ<sub>f</sub><i>G</i><sup>⦵</sup>)</span></div> </td> <td>46.4 kJ/mol </td></tr> <tr> <th colspan="2" style="background: #f8eaba; text-align: center;">Related compounds </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">Related compounds</div> </td> <td><a href="/wiki/Lithium_aluminium_hydride" title="Lithium aluminium hydride">Lithium aluminium hydride</a>, <a href="/wiki/Diborane" title="Diborane">diborane</a> </td></tr> <tr> <td colspan="2" style="text-align:left; background:#f8eaba; border:1px solid #a2a9b1;"><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">Except where otherwise noted, data are given for materials in their <a href="/wiki/Standard_state" title="Standard state">standard state</a> (at 25 °C [77 °F], 100 kPa).</div> <div style="margin-top: 0.3em;"><div style="text-align:center;"><span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/12px-Yes_check.svg.png" decoding="async" width="12" height="12" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/18px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/24px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span> <span class="reflink plainlinks nourlexpansion"><a class="external text" href="https://en.wikipedia.org/w/index.php?title=Special:ComparePages&rev1=477001731&page2=Aluminium+hydride">verify</a></span> (<a href="/wiki/Wikipedia:WikiProject_Chemicals/Chembox_validation" title="Wikipedia:WikiProject Chemicals/Chembox validation">what is</a> <sup><span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span><span typeof="mw:File"><span><img alt="☒" src="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/7px-X_mark.svg.png" decoding="async" width="7" height="8" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/11px-X_mark.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/14px-X_mark.svg.png 2x" data-file-width="525" data-file-height="600" /></span></span><span style="display:none">N</span></sup> ?) </div></div> <div style="margin-top: 0.3em; text-align: center;"><a href="/wiki/Wikipedia:Chemical_infobox#References" title="Wikipedia:Chemical infobox">Infobox references</a></div> </td></tr> </tbody></table><div class="shortdescription nomobile noexcerpt noprint searchaux" style="display:none">Chemical compound</div> <p><b>Aluminium hydride</b> (also known as <b>alane</b> and <b>alumane</b>) is an <a href="/wiki/Inorganic_compound" title="Inorganic compound">inorganic compound</a> with the <a href="/wiki/Chemical_formula" title="Chemical formula">formula</a> <style data-mw-deduplicate="TemplateStyles:r1123817410">.mw-parser-output .template-chem2-su{display:inline-block;font-size:80%;line-height:1;vertical-align:-0.35em}.mw-parser-output .template-chem2-su>span{display:block;text-align:left}.mw-parser-output sub.template-chem2-sub{font-size:80%;vertical-align:-0.35em}.mw-parser-output sup.template-chem2-sup{font-size:80%;vertical-align:0.65em}</style><span class="chemf nowrap"><a href="/wiki/Aluminium" title="Aluminium">Al</a><a href="/wiki/Hydrogen" title="Hydrogen">H</a><sub class="template-chem2-sub">3</sub></span>. Alane and its derivatives are part of a family of common <a href="/wiki/Redox" title="Redox">reducing</a> reagents in <a href="/wiki/Organic_synthesis" title="Organic synthesis">organic synthesis</a> based around <a href="/wiki/Group_13_hydride" title="Group 13 hydride">group 13 hydrides</a>.<sup id="cite_ref-1" class="reference"><a href="#cite_note-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> In solution—typically in ethereal solvents such <a href="/wiki/Tetrahydrofuran" title="Tetrahydrofuran">tetrahydrofuran</a> or <a href="/wiki/Diethyl_ether" title="Diethyl ether">diethyl ether</a>—aluminium hydride forms complexes with <a href="/wiki/Lewis_base" class="mw-redirect" title="Lewis base">Lewis bases</a>, and reacts selectively with particular organic <a href="/wiki/Functional_group" title="Functional group">functional groups</a> (e.g., with <a href="/wiki/Carboxylic_acid" title="Carboxylic acid">carboxylic acids</a> and <a href="/wiki/Ester" title="Ester">esters</a> over <a href="/wiki/Organic_halide" class="mw-redirect" title="Organic halide">organic halides</a> and <a href="/wiki/Nitro_group" class="mw-redirect" title="Nitro group">nitro groups</a>), and although it is not a reagent of choice, it can react with carbon-carbon multiple bonds (i.e., through <a href="/wiki/Alkenylaluminium_compounds" title="Alkenylaluminium compounds">hydroalumination</a>). Given its density, and with hydrogen content on the order of 10% by weight,<sup id="cite_ref-h2storage_2-0" class="reference"><a href="#cite_note-h2storage-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> some forms of alane are, as of 2016,<sup id="cite_ref-3" class="reference"><a href="#cite_note-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> active candidates for storing hydrogen and so for power generation in fuel cell applications, including electric vehicles.<sup class="noprint Inline-Template" style="white-space:nowrap;">[<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources in the body of the article. (July 2022)">not verified in body</span></a></i>]</sup> As of 2006 it was noted that further research was required to identify an efficient, economical way to reverse the process, regenerating alane from spent aluminium product. </p><p>Solid aluminium hydride, or alane, is colorless and nonvolatile, and in its most common reagent form it is a highly <a href="/wiki/Polymer" title="Polymer">polymerized</a> species (i.e., has multiple <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">AlH<sub class="template-chem2-sub">3</sub></span> units that are self-associated); it melts with decomposition at 110 °C.<sup id="cite_ref-EROSv08_4-0" class="reference"><a href="#cite_note-EROSv08-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> While not spontaneously flammable, alane solids and solutions require precautions in use akin to other highly flammable <a href="/wiki/Metal_hydride" class="mw-redirect" title="Metal hydride">metal hydrides</a>, and must be handled and stored with the active exclusion of moisture. Alane decomposes on exposure to air (principally because of adventitious moisture), though <a href="/wiki/Passivation_(chemistry)" title="Passivation (chemistry)"> passivation</a> — here, allowing for development of an inert surface coating — greatly diminishes the rate of decomposition of alane preparations.<sup class="noprint Inline-Template" style="white-space:nowrap;">[<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources in the body of the article. (July 2022)">not verified in body</span></a></i>]</sup> </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="Form_and_structure">Form and structure</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Aluminium_hydride&action=edit&section=1" title="Edit section: Form and structure"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <style data-mw-deduplicate="TemplateStyles:r1251242444">.mw-parser-output .ambox{border:1px solid #a2a9b1;border-left:10px solid #36c;background-color:#fbfbfb;box-sizing:border-box}.mw-parser-output .ambox+link+.ambox,.mw-parser-output .ambox+link+style+.ambox,.mw-parser-output .ambox+link+link+.ambox,.mw-parser-output .ambox+.mw-empty-elt+link+.ambox,.mw-parser-output .ambox+.mw-empty-elt+link+style+.ambox,.mw-parser-output .ambox+.mw-empty-elt+link+link+.ambox{margin-top:-1px}html body.mediawiki .mw-parser-output .ambox.mbox-small-left{margin:4px 1em 4px 0;overflow:hidden;width:238px;border-collapse:collapse;font-size:88%;line-height:1.25em}.mw-parser-output .ambox-speedy{border-left:10px solid #b32424;background-color:#fee7e6}.mw-parser-output .ambox-delete{border-left:10px solid #b32424}.mw-parser-output .ambox-content{border-left:10px solid #f28500}.mw-parser-output .ambox-style{border-left:10px solid #fc3}.mw-parser-output .ambox-move{border-left:10px solid #9932cc}.mw-parser-output .ambox-protection{border-left:10px solid #a2a9b1}.mw-parser-output .ambox .mbox-text{border:none;padding:0.25em 0.5em;width:100%}.mw-parser-output .ambox .mbox-image{border:none;padding:2px 0 2px 0.5em;text-align:center}.mw-parser-output .ambox .mbox-imageright{border:none;padding:2px 0.5em 2px 0;text-align:center}.mw-parser-output .ambox .mbox-empty-cell{border:none;padding:0;width:1px}.mw-parser-output .ambox .mbox-image-div{width:52px}@media(min-width:720px){.mw-parser-output .ambox{margin:0 10%}}@media print{body.ns-0 .mw-parser-output .ambox{display:none!important}}</style><table class="box-More_citations_needed_section plainlinks metadata ambox ambox-content ambox-Refimprove" role="presentation"><tbody><tr><td class="mbox-image"><div class="mbox-image-div"><span typeof="mw:File"><a href="/wiki/File:Question_book-new.svg" class="mw-file-description"><img alt="" src="//upload.wikimedia.org/wikipedia/en/thumb/9/99/Question_book-new.svg/50px-Question_book-new.svg.png" decoding="async" width="50" height="39" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/9/99/Question_book-new.svg/75px-Question_book-new.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/9/99/Question_book-new.svg/100px-Question_book-new.svg.png 2x" data-file-width="512" data-file-height="399" /></a></span></div></td><td class="mbox-text"><div class="mbox-text-span">This section <b>needs additional citations for <a href="/wiki/Wikipedia:Verifiability" title="Wikipedia:Verifiability">verification</a></b>.<span class="hide-when-compact"> Please help <a href="/wiki/Special:EditPage/Aluminium_hydride" title="Special:EditPage/Aluminium hydride">improve this article</a> by <a href="/wiki/Help:Referencing_for_beginners" title="Help:Referencing for beginners">adding citations to reliable sources</a> in this section. Unsourced material may be challenged and removed.</span> <span class="date-container"><i>(<span class="date">July 2022</span>)</i></span><span class="hide-when-compact"><i> (<small><a href="/wiki/Help:Maintenance_template_removal" title="Help:Maintenance template removal">Learn how and when to remove this message</a></small>)</i></span></div></td></tr></tbody></table> <p>Alane is a colorless and nonvolatile solid that melts with decomposition at 110 °C;<sup id="cite_ref-EROSv08_4-1" class="reference"><a href="#cite_note-EROSv08-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> sufficiently large samples may be further heated to complete decomposition at 150 °C.<sup id="cite_ref-HS5p401_5-0" class="reference"><a href="#cite_note-HS5p401-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> The solid form, however, often presents as a white solid that may be tinted grey (with decreasing reagent particle size or increasing impurity levels).<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">[<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (July 2022)">citation needed</span></a></i>]</sup> This coloration arises from a thin surface <a href="/wiki/Passivation_(chemistry)" title="Passivation (chemistry)">passivation</a> layer of aluminium oxide or hydroxide.<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">[<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (July 2022)">citation needed</span></a></i>]</sup> </p><p>Under common laboratory conditions, alane is "highly polymeric", structurally.<sup id="cite_ref-EROSv08_4-2" class="reference"><a href="#cite_note-EROSv08-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> This is sometimes indicated with the formula <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">(AlH<sub class="template-chem2-sub">3</sub>)<sub class="template-chem2-sub"><i>n</i></sub></span>, where <i>n</i> is left unspecified.<sup id="cite_ref-6" class="reference"><a href="#cite_note-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup><sup class="noprint Inline-Template noprint Template-Fact" style="white-space:nowrap;">[<i><a href="/wiki/Wikipedia:No_original_research#Primary,_secondary_and_tertiary_sources" title="Wikipedia:No original research"><span title="This claim needs references to reliable secondary sources. (February 2024)">non-primary source needed</span></a></i>]</sup> Preparations of alane dissolve in <a href="/wiki/Tetrahydrofuran" title="Tetrahydrofuran">tetrahydrofuran</a> (THF) or <a href="/wiki/Diethyl_ether" title="Diethyl ether">diethyl ether</a> (ether),<sup id="cite_ref-EROSv08_4-3" class="reference"><a href="#cite_note-EROSv08-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> from which pure allotropes precipitate.<sup id="cite_ref-lund_7-0" class="reference"><a href="#cite_note-lund-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup><sup class="noprint Inline-Template noprint Template-Fact" style="white-space:nowrap;">[<i><a href="/wiki/Wikipedia:No_original_research#Primary,_secondary_and_tertiary_sources" title="Wikipedia:No original research"><span title="This claim needs references to reliable secondary sources. (July 2022)">non-primary source needed</span></a></i>]</sup> </p><p>Structurally, alane can adopt numerous <a href="/wiki/Polymorphism_(materials_science)" class="mw-redirect" title="Polymorphism (materials science)">polymorphic forms</a>. By 2006, "at least 7 non-solvated <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">AlH<sub class="template-chem2-sub">3</sub></span> phases" were known: α-, α’-, β-, γ-, ε-, and ζ-alanes;<sup id="cite_ref-h2storage_2-1" class="reference"><a href="#cite_note-h2storage-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> the δ- and θ-alanes have subsequently been discovered.<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">[<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (July 2022)">citation needed</span></a></i>]</sup> Each has a different structure, with α-alane being the most thermally stable polymorph.<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">[<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (July 2022)">citation needed</span></a></i>]</sup> For instance, <a href="/wiki/Crystallography" title="Crystallography">crystallographically</a>, α-alane adopts a cubic or rhombohedral morphology, while α’-alane forms needle-like crystals and γ-alane forms bundles of fused needles.<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">[<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (July 2022)">citation needed</span></a></i>]</sup> The crystal structure of α-alane has been determined, and features aluminium atoms surrounded by six octahedrally oriented hydrogen atoms that bridge to six other aluminium atoms (see table), where the Al-H distances are all equivalent (172 pm) and the Al-H-Al angle is 141°.<sup id="cite_ref-8" class="reference"><a href="#cite_note-8"><span class="cite-bracket">[</span>8<span class="cite-bracket">]</span></a></sup> </p> <table class="wikitable" width="auto" style="text-align: center"> <tbody><tr> <th colspan="6">Crystallographic Structure of α-<link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">AlH<sub class="template-chem2-sub">3</sub></span><sup id="cite_ref-Crystal_9-0" class="reference"><a href="#cite_note-Crystal-9"><span class="cite-bracket">[</span>9<span class="cite-bracket">]</span></a></sup> </th></tr> <tr style="background:#efefef;"> <th>The α-<link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">AlH<sub class="template-chem2-sub">3</sub></span> <a href="/wiki/Unit_cell" title="Unit cell">unit cell</a> </th> <th>Aluminium coordination </th> <th>Hydrogen coordination </th></tr> <tr> <td style="text-align:left;"><span typeof="mw:File"><a href="/wiki/File:Aluminium-hydride-unit-cell-3D-balls.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/f/fa/Aluminium-hydride-unit-cell-3D-balls.png/150px-Aluminium-hydride-unit-cell-3D-balls.png" decoding="async" width="150" height="228" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/f/fa/Aluminium-hydride-unit-cell-3D-balls.png/225px-Aluminium-hydride-unit-cell-3D-balls.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/f/fa/Aluminium-hydride-unit-cell-3D-balls.png/300px-Aluminium-hydride-unit-cell-3D-balls.png 2x" data-file-width="725" data-file-height="1100" /></a></span> </td> <td style="text-align:left;"><span typeof="mw:File"><a href="/wiki/File:Aluminium-hydride-Al-coordination-3D-balls.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/6/60/Aluminium-hydride-Al-coordination-3D-balls.png/125px-Aluminium-hydride-Al-coordination-3D-balls.png" decoding="async" width="125" height="136" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/6/60/Aluminium-hydride-Al-coordination-3D-balls.png/188px-Aluminium-hydride-Al-coordination-3D-balls.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/6/60/Aluminium-hydride-Al-coordination-3D-balls.png/250px-Aluminium-hydride-Al-coordination-3D-balls.png 2x" data-file-width="1013" data-file-height="1100" /></a></span> </td> <td style="text-align:center;"><span typeof="mw:File"><a href="/wiki/File:Aluminium-hydride-H-coordination-3D-balls.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/0/08/Aluminium-hydride-H-coordination-3D-balls.png/150px-Aluminium-hydride-H-coordination-3D-balls.png" decoding="async" width="150" height="61" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/0/08/Aluminium-hydride-H-coordination-3D-balls.png/225px-Aluminium-hydride-H-coordination-3D-balls.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/0/08/Aluminium-hydride-H-coordination-3D-balls.png/300px-Aluminium-hydride-H-coordination-3D-balls.png 2x" data-file-width="1100" data-file-height="444" /></a></span> </td></tr></tbody></table> <p>When β- and γ-alanes are produced together, they convert to α-alane upon heating, while δ-, ε-, and θ-alanes are produced in still other crystallization conditions; although they are less thermally stable, the δ-, ε-, and θ-alane polymorphs do not convert to α-alane upon heating.<sup id="cite_ref-lund_7-1" class="reference"><a href="#cite_note-lund-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup><sup class="noprint Inline-Template noprint noexcerpt Template-Fact" style="white-space:nowrap;">[<i><a href="/wiki/Wikipedia:NOTRS" class="mw-redirect" title="Wikipedia:NOTRS"><span title="This claim needs references to better sources. (July 2022)">better source needed</span></a></i>]</sup> </p><p>Under special conditions, non-polymeric alanes (i.e., molecular forms of it) can be prepared and studied. Monomeric <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">AlH<sub class="template-chem2-sub">3</sub></span> has been isolated at low temperature in a solid <a href="/wiki/Noble_gas" title="Noble gas">noble gas</a> matrix where it was shown to be planar.<sup id="cite_ref-10" class="reference"><a href="#cite_note-10"><span class="cite-bracket">[</span>10<span class="cite-bracket">]</span></a></sup> The dimeric form, <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">Al<sub class="template-chem2-sub">2</sub>H<sub class="template-chem2-sub">6</sub></span>, has been isolated in solid hydrogen, and it is <a href="/wiki/Isostructural" title="Isostructural">isostructural</a> with <a href="/wiki/Diborane" title="Diborane">diborane</a> (<link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">B<sub class="template-chem2-sub">2</sub>H<sub class="template-chem2-sub">6</sub></span>) and <a href="/wiki/Digallane" title="Digallane">digallane</a> (<link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">Ga<sub class="template-chem2-sub">2</sub>H<sub class="template-chem2-sub">6</sub></span>).<sup id="cite_ref-11" class="reference"><a href="#cite_note-11"><span class="cite-bracket">[</span>11<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-Pulham_12-0" class="reference"><a href="#cite_note-Pulham-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-13" class="reference"><a href="#cite_note-13"><span class="cite-bracket">[</span>13<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Handling">Handling</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Aluminium_hydride&action=edit&section=2" title="Edit section: Handling"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Alane is not spontaneously flammable.<sup id="cite_ref-14" class="reference"><a href="#cite_note-14"><span class="cite-bracket">[</span>14<span class="cite-bracket">]</span></a></sup> Even so, "similar handling and precautions as... exercised for <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">Li[AlH<sub class="template-chem2-sub">4</sub>]</span>" (the chemical reagent, <a href="/wiki/Lithium_aluminium_hydride" title="Lithium aluminium hydride">lithium aluminium hydride</a>) are recommended, as its "reactivity [is] comparable" to this related reducing reagent.<sup id="cite_ref-EROSv08_4-4" class="reference"><a href="#cite_note-EROSv08-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> For these reagents, both preparations in solutions and isolated solids are "highly flammable and must be stored in the absence of moisture".<sup id="cite_ref-EROSv04_15-0" class="reference"><a href="#cite_note-EROSv04-15"><span class="cite-bracket">[</span>15<span class="cite-bracket">]</span></a></sup> Laboratory guides recommend alane use inside a <a href="/wiki/Fume_hood" title="Fume hood">fume hood</a>.<sup id="cite_ref-EROSv08_4-5" class="reference"><a href="#cite_note-EROSv08-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup><sup class="noprint Inline-Template" style="white-space:nowrap;">[<i><a href="/wiki/Wikipedia:Please_clarify" title="Wikipedia:Please clarify"><span title="The reason for this is unclear. (July 2022)">why?</span></a></i>]</sup> Solids of this reagent type carry recommendations of handling "in a glove bag or <a href="/wiki/Glove_box" class="mw-redirect" title="Glove box">dry box</a>".<sup id="cite_ref-EROSv04_15-1" class="reference"><a href="#cite_note-EROSv04-15"><span class="cite-bracket">[</span>15<span class="cite-bracket">]</span></a></sup> After use, solution containers are typically sealed tightly with concomitant flushing with inert gas to exclude the oxygen and moisture of ambient air.<sup id="cite_ref-EROSv04_15-2" class="reference"><a href="#cite_note-EROSv04-15"><span class="cite-bracket">[</span>15<span class="cite-bracket">]</span></a></sup> </p><p><a href="/wiki/Passivation_(chemistry)" title="Passivation (chemistry)">Passivation</a><sup class="noprint Inline-Template" style="margin-left:0.1em; white-space:nowrap;">[<i><a href="/wiki/Wikipedia:Please_clarify" title="Wikipedia:Please clarify"><span title="The text near this tag may need clarification or removal of jargon. (July 2022)">clarification needed</span></a></i>]</sup> greatly diminishes the decomposition rate associated with alane preparations.<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">[<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (July 2022)">citation needed</span></a></i>]</sup> Passivated alane nevertheless retains a hazard classification of 4.3 (chemicals which in contact with water, emit flammable gases).<sup id="cite_ref-16" class="reference"><a href="#cite_note-16"><span class="cite-bracket">[</span>16<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="Reported_accidents">Reported accidents</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Aluminium_hydride&action=edit&section=3" title="Edit section: Reported accidents"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1251242444"><table class="box-Expand_section plainlinks metadata ambox ambox-content" role="presentation"><tbody><tr><td class="mbox-image"><div class="mbox-image-div"><span typeof="mw:File"><a href="/wiki/File:Wiki_letter_w_cropped.svg" class="mw-file-description"><img alt="[icon]" src="//upload.wikimedia.org/wikipedia/commons/thumb/1/1c/Wiki_letter_w_cropped.svg/44px-Wiki_letter_w_cropped.svg.png" decoding="async" width="44" height="31" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/1/1c/Wiki_letter_w_cropped.svg/66px-Wiki_letter_w_cropped.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/1/1c/Wiki_letter_w_cropped.svg/88px-Wiki_letter_w_cropped.svg.png 2x" data-file-width="44" data-file-height="31" /></a></span></div></td><td class="mbox-text"><div class="mbox-text-span">This section <b>needs expansion</b> with: a careful, source-derived presentation of accidents known to be associated with use of this agent, at small and large scale. You can help by <a class="external text" href="https://en.wikipedia.org/w/index.php?title=Aluminium_hydride&action=edit&section=">adding to it</a>. <span class="date-container"><i>(<span class="date">July 2022</span>)</i></span></div></td></tr></tbody></table> <p>Alane reductions are believed to proceed via an intermediate <a href="/wiki/Coordination_complex" title="Coordination complex">coordination complex</a>, with aluminum attached to the partially reduced functional group, and liberated when the reaction undergoes protic <a href="/wiki/Quenching_(chemistry)" class="mw-redirect" title="Quenching (chemistry)">quenching</a>. If the substrate is also <a href="/wiki/Fluoroalkane" class="mw-redirect" title="Fluoroalkane">fluorinated</a>, the intermediate may instead explode if exposed to a <a href="/w/index.php?title=Hot_spot_(fire_safety)&action=edit&redlink=1" class="new" title="Hot spot (fire safety) (page does not exist)">hot spot</a> above 60°C.<sup id="cite_ref-17" class="reference"><a href="#cite_note-17"><span class="cite-bracket">[</span>17<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Preparation">Preparation</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Aluminium_hydride&action=edit&section=4" title="Edit section: Preparation"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Aluminium hydrides and various complexes thereof have long been known.<sup id="cite_ref-18" class="reference"><a href="#cite_note-18"><span class="cite-bracket">[</span>18<span class="cite-bracket">]</span></a></sup> Its first synthesis was published in 1947, and a patent for the synthesis was assigned in 1999.<sup id="cite_ref-19" class="reference"><a href="#cite_note-19"><span class="cite-bracket">[</span>19<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-20" class="reference"><a href="#cite_note-20"><span class="cite-bracket">[</span>20<span class="cite-bracket">]</span></a></sup> Aluminium hydride is prepared by treating <a href="/wiki/Lithium_aluminium_hydride" title="Lithium aluminium hydride">lithium aluminium hydride</a> with <a href="/wiki/Aluminium_trichloride" class="mw-redirect" title="Aluminium trichloride">aluminium trichloride</a>.<sup id="cite_ref-21" class="reference"><a href="#cite_note-21"><span class="cite-bracket">[</span>21<span class="cite-bracket">]</span></a></sup> The procedure is intricate: attention must be given to the removal of <a href="/wiki/Lithium_chloride" title="Lithium chloride">lithium chloride</a>. </p> <dl><dd><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">3 Li[AlH<sub class="template-chem2-sub">4</sub>] + AlCl<sub class="template-chem2-sub">3</sub> → 4 AlH<sub class="template-chem2-sub">3</sub> + 3 LiCl</span></dd></dl> <p>The ether solution of alane requires immediate use, because polymeric material rapidly precipitates as a solid. Aluminium hydride solutions are known to degrade after 3 days. Aluminium hydride is more reactive than <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">Li[AlH<sub class="template-chem2-sub">4</sub>]</span>.<sup id="cite_ref-lund_7-2" class="reference"><a href="#cite_note-lund-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup> </p><p>Several other methods exist for the preparation of aluminium hydride: </p> <dl><dd><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">2 Li[AlH<sub class="template-chem2-sub">4</sub>] + BeCl<sub class="template-chem2-sub">2</sub> → 2 AlH<sub class="template-chem2-sub">3</sub> + Li<sub class="template-chem2-sub">2</sub>[BeH<sub class="template-chem2-sub">2</sub>Cl<sub class="template-chem2-sub">2</sub>]</span></dd> <dd><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">2 Li[AlH<sub class="template-chem2-sub">4</sub>] + H<sub class="template-chem2-sub">2</sub>SO<sub class="template-chem2-sub">4</sub> → 2 AlH<sub class="template-chem2-sub">3</sub> + Li<sub class="template-chem2-sub">2</sub>SO<sub class="template-chem2-sub">4</sub> + 2 H<sub class="template-chem2-sub">2</sub></span></dd> <dd><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">2 Li[AlH<sub class="template-chem2-sub">4</sub>] + ZnCl<sub class="template-chem2-sub">2</sub> → 2 AlH<sub class="template-chem2-sub">3</sub> + 2 LiCl + ZnH<sub class="template-chem2-sub">2</sub></span></dd> <dd><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">2 Li[AlH<sub class="template-chem2-sub">4</sub>] + I<sub class="template-chem2-sub">2</sub> → 2 AlH<sub class="template-chem2-sub">3</sub> + 2 LiI + H<sub class="template-chem2-sub">2</sub></span></dd></dl> <div class="mw-heading mw-heading3"><h3 id="Electrochemical_synthesis">Electrochemical synthesis</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Aluminium_hydride&action=edit&section=5" title="Edit section: Electrochemical synthesis"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Several groups have shown that alane can be produced <a href="/wiki/Electrochemistry" title="Electrochemistry">electrochemically</a>.<sup id="cite_ref-22" class="reference"><a href="#cite_note-22"><span class="cite-bracket">[</span>22<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-23" class="reference"><a href="#cite_note-23"><span class="cite-bracket">[</span>23<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-24" class="reference"><a href="#cite_note-24"><span class="cite-bracket">[</span>24<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-ReferenceA_25-0" class="reference"><a href="#cite_note-ReferenceA-25"><span class="cite-bracket">[</span>25<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-ReferenceB_26-0" class="reference"><a href="#cite_note-ReferenceB-26"><span class="cite-bracket">[</span>26<span class="cite-bracket">]</span></a></sup> Different electrochemical alane production methods have been patented.<sup id="cite_ref-27" class="reference"><a href="#cite_note-27"><span class="cite-bracket">[</span>27<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-28" class="reference"><a href="#cite_note-28"><span class="cite-bracket">[</span>28<span class="cite-bracket">]</span></a></sup> Electrochemically generating alane avoids chloride impurities. Two possible mechanisms are discussed for the formation of alane in Clasen's electrochemical cell containing <a href="/wiki/Tetrahydrofuran" title="Tetrahydrofuran">THF</a> as the solvent, <a href="/wiki/Sodium_aluminium_hydride" title="Sodium aluminium hydride">sodium aluminium hydride</a> as the electrolyte, an aluminium anode, and an iron (Fe) wire submerged in <a href="/wiki/Mercury_(element)" title="Mercury (element)">mercury</a> (Hg) as the cathode. The sodium forms an <a href="/wiki/Amalgam_(chemistry)" title="Amalgam (chemistry)">amalgam</a> with the Hg cathode preventing side reactions and the hydrogen produced in the first reaction could be captured and reacted back with the sodium mercury amalgam to produce sodium hydride. Clasen's system results in no loss of starting material. For insoluble anodes, reaction 1 occurs, while for soluble anodes, anodic dissolution is expected according to reaction 2: </p> <ol><li><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">[AlH<sub class="template-chem2-sub">4</sub>]<sup class="template-chem2-sup">−</sup></span> − <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap"><a href="/wiki/Electron" title="Electron">e<sup class="template-chem2-sup">−</sup></a> + <i>n</i> THF → AlH<sub class="template-chem2-sub">3</sub>·<i>n</i>THF + 1/<sub class="template-chem2-sub">2</sub> H<sub class="template-chem2-sub">2</sub></span></li> <li><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">3 [AlH<sub class="template-chem2-sub">4</sub>]<sup class="template-chem2-sup">−</sup> + Al</span> − <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">3 e<sup class="template-chem2-sup">−</sup> + 4<i>n</i> THF → 4 AlH<sub class="template-chem2-sub">3</sub>·<i>n</i>THF</span></li></ol> <p>In reaction 2, the aluminium anode is consumed, limiting the production of aluminium hydride for a given electrochemical cell. </p><p>The crystallization and recovery of aluminium hydride from electrochemically generated alane has been demonstrated.<sup id="cite_ref-ReferenceA_25-1" class="reference"><a href="#cite_note-ReferenceA-25"><span class="cite-bracket">[</span>25<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-ReferenceB_26-1" class="reference"><a href="#cite_note-ReferenceB-26"><span class="cite-bracket">[</span>26<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="High_pressure_hydrogenation_of_aluminium">High pressure hydrogenation of aluminium</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Aluminium_hydride&action=edit&section=6" title="Edit section: High pressure hydrogenation of aluminium"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>α-<link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">AlH<sub class="template-chem2-sub">3</sub></span> can be produced by hydrogenation of aluminium at 10 <a href="/wiki/GPa" class="mw-redirect" title="GPa">GPa</a> and 600 °C (1,112 °F). The reaction between the liquified hydrogen produces α-<link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">AlH<sub class="template-chem2-sub">3</sub></span> which could be recovered under ambient conditions.<sup id="cite_ref-SaitohSakurai2010_29-0" class="reference"><a href="#cite_note-SaitohSakurai2010-29"><span class="cite-bracket">[</span>29<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Reactions">Reactions</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Aluminium_hydride&action=edit&section=7" title="Edit section: Reactions"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="mw-heading mw-heading3"><h3 id="Formation_of_adducts_with_Lewis_bases">Formation of adducts with Lewis bases</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Aluminium_hydride&action=edit&section=8" title="Edit section: Formation of adducts with Lewis bases"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">AlH<sub class="template-chem2-sub">3</sub></span> readily forms adducts with strong <a href="/wiki/Lewis_acids_and_bases" title="Lewis acids and bases">Lewis bases</a>. For example, both 1:1 and 1:2 complexes form with <a href="/wiki/Trimethylamine" title="Trimethylamine">trimethylamine</a>. The 1:1 complex is tetrahedral in the gas phase,<sup id="cite_ref-greenwood_30-0" class="reference"><a href="#cite_note-greenwood-30"><span class="cite-bracket">[</span>30<span class="cite-bracket">]</span></a></sup> but in the solid phase it is dimeric with bridging hydrogen centres, <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">(N(CH<sub class="template-chem2-sub">3</sub>)<sub class="template-chem2-sub">3</sub>Al(μ-H))<sub class="template-chem2-sub">2</sub></span>.<sup id="cite_ref-31" class="reference"><a href="#cite_note-31"><span class="cite-bracket">[</span>31<span class="cite-bracket">]</span></a></sup> The 1:2 complex adopts a <a href="/wiki/Trigonal_bipyramid_molecular_geometry" class="mw-redirect" title="Trigonal bipyramid molecular geometry">trigonal bipyramidal structure</a>.<sup id="cite_ref-greenwood_30-1" class="reference"><a href="#cite_note-greenwood-30"><span class="cite-bracket">[</span>30<span class="cite-bracket">]</span></a></sup> Some adducts (e.g. dimethylethylamine alane, <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">(CH<sub class="template-chem2-sub">3</sub>CH<sub class="template-chem2-sub">2</sub>)(CH<sub class="template-chem2-sub">3</sub>)<sub class="template-chem2-sub">2</sub>N·AlH<sub class="template-chem2-sub">3</sub></span>) thermally decompose to give aluminium and may have use in <a href="/wiki/MOCVD" class="mw-redirect" title="MOCVD">MOCVD</a> applications.<sup id="cite_ref-32" class="reference"><a href="#cite_note-32"><span class="cite-bracket">[</span>32<span class="cite-bracket">]</span></a></sup> </p><p>Its complex with <a href="/wiki/Diethyl_ether" title="Diethyl ether">diethyl ether</a> forms according to the following stoichiometry: </p> <dl><dd><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">AlH<sub class="template-chem2-sub">3</sub> + (CH<sub class="template-chem2-sub">3</sub>CH<sub class="template-chem2-sub">2</sub>)<sub class="template-chem2-sub">2</sub>O → (CH<sub class="template-chem2-sub">3</sub>CH<sub class="template-chem2-sub">2</sub>)<sub class="template-chem2-sub">2</sub>O·AlH<sub class="template-chem2-sub">3</sub></span></dd></dl> <p>The reaction with <a href="/wiki/Lithium_hydride" title="Lithium hydride">lithium hydride</a> in ether produces <a href="/wiki/Lithium_aluminium_hydride" title="Lithium aluminium hydride">lithium aluminium hydride</a> (lithium alanate, lithium tetrahydridoaluminate): </p> <dl><dd><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">AlH<sub class="template-chem2-sub">3</sub> + LiH → Li[AlH<sub class="template-chem2-sub">4</sub>]</span></dd></dl> <p>Analogous alanates (e.g. <span class="chemf nowrap">Na<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">3</sub></span></span>AlH<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">6</sub></span></span></span>, <span class="chemf nowrap">Ca(AlH<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">4)</sub></span></span>)<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">2</sub></span></span></span>, <span class="chemf nowrap">SrAlH<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">5</sub></span></span></span>) exist with other alkali alkaline earth and some other metals.<sup id="cite_ref-33" class="reference"><a href="#cite_note-33"><span class="cite-bracket">[</span>33<span class="cite-bracket">]</span></a></sup> <span class="chemf nowrap">Li<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">3</sub></span></span>AlH<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">6</sub></span></span></span> is under investigation as a lithium ion cell anode material. </p> <div class="mw-heading mw-heading3"><h3 id="Reduction_of_functional_groups">Reduction of functional groups</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Aluminium_hydride&action=edit&section=9" title="Edit section: Reduction of functional groups"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>In organic chemistry, aluminium hydride is mainly used for the reduction of functional groups.<sup id="cite_ref-galatsis_34-0" class="reference"><a href="#cite_note-galatsis-34"><span class="cite-bracket">[</span>34<span class="cite-bracket">]</span></a></sup> In many ways, the reactivity of aluminium hydride is similar to that of <a href="/wiki/Lithium_aluminium_hydride" title="Lithium aluminium hydride">lithium aluminium hydride</a>. Aluminium hydride will reduce <a href="/wiki/Aldehyde" title="Aldehyde">aldehydes</a>, <a href="/wiki/Ketone" title="Ketone">ketones</a>, <a href="/wiki/Carboxylic_acid" title="Carboxylic acid">carboxylic acids</a>, <a href="/wiki/Anhydride" class="mw-redirect" title="Anhydride">anhydrides</a>, <a href="/wiki/Acid_chloride" class="mw-redirect" title="Acid chloride">acid chlorides</a>, <a href="/wiki/Ester" title="Ester">esters</a>, and <a href="/wiki/Lactone" title="Lactone">lactones</a> to their corresponding <a href="/wiki/Alcohol_(chemistry)" title="Alcohol (chemistry)">alcohols</a>. <a href="/wiki/Amide" title="Amide">Amides</a>, <a href="/wiki/Nitrile" title="Nitrile">nitriles</a>, and <a href="/wiki/Oxime" title="Oxime">oximes</a> are reduced to their corresponding <a href="/wiki/Amine" title="Amine">amines</a>. </p><p>In terms of functional group selectivity, alane differs from other hydride reagents. For example, in the following cyclohexanone reduction, <a href="/wiki/Lithium_aluminium_hydride" title="Lithium aluminium hydride">lithium aluminium hydride</a> gives a trans:cis ratio of 1.9 : 1, whereas aluminium hydride gives a trans:cis ratio of 7.3 : 1.<sup id="cite_ref-35" class="reference"><a href="#cite_note-35"><span class="cite-bracket">[</span>35<span class="cite-bracket">]</span></a></sup> </p> <figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:Functional_Group_Reduction_1.svg" class="mw-file-description" title="Stereoselective reduction of a substituted cyclohexanone using aluminium hydride"><img alt="Stereoselective reduction of a substituted cyclohexanone using aluminium hydride" src="//upload.wikimedia.org/wikipedia/commons/thumb/d/d7/Functional_Group_Reduction_1.svg/300px-Functional_Group_Reduction_1.svg.png" decoding="async" width="300" height="87" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/d/d7/Functional_Group_Reduction_1.svg/450px-Functional_Group_Reduction_1.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/d/d7/Functional_Group_Reduction_1.svg/600px-Functional_Group_Reduction_1.svg.png 2x" data-file-width="692" data-file-height="200" /></a><figcaption>Stereoselective reduction of a substituted cyclohexanone using aluminium hydride</figcaption></figure> <p>Alane enables the hydroxymethylation of certain ketones (that is the replacement of <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">C−H</span> by <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">C−CH<sub class="template-chem2-sub">2</sub>OH</span> at the <a href="/wiki/Alpha_carbon" class="mw-redirect" title="Alpha carbon">alpha position</a>).<sup id="cite_ref-36" class="reference"><a href="#cite_note-36"><span class="cite-bracket">[</span>36<span class="cite-bracket">]</span></a></sup> The ketone itself is not reduced as it is "protected" as its enolate. </p> <figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:Functional_Group_Reduction_2.svg" class="mw-file-description" title="Functional Group Reduction using aluminium hydride"><img alt="Functional Group Reduction using aluminium hydride" src="//upload.wikimedia.org/wikipedia/commons/thumb/6/67/Functional_Group_Reduction_2.svg/300px-Functional_Group_Reduction_2.svg.png" decoding="async" width="300" height="95" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/6/67/Functional_Group_Reduction_2.svg/450px-Functional_Group_Reduction_2.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/6/67/Functional_Group_Reduction_2.svg/600px-Functional_Group_Reduction_2.svg.png 2x" data-file-width="765" data-file-height="242" /></a><figcaption>Functional Group Reduction using aluminium hydride</figcaption></figure> <p><a href="/wiki/Organohalide" class="mw-redirect" title="Organohalide">Organohalides</a> are reduced slowly or not at all by aluminium hydride. Therefore, reactive functional groups such as <a href="/wiki/Carboxylic_acid" title="Carboxylic acid">carboxylic acids</a> can be reduced in the presence of halides.<sup id="cite_ref-37" class="reference"><a href="#cite_note-37"><span class="cite-bracket">[</span>37<span class="cite-bracket">]</span></a></sup> </p> <figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:Functional_Group_Reduction_3.svg" class="mw-file-description" title="Functional Group Reduction using aluminium hydride"><img alt="Functional Group Reduction using aluminium hydride" src="//upload.wikimedia.org/wikipedia/commons/thumb/4/49/Functional_Group_Reduction_3.svg/300px-Functional_Group_Reduction_3.svg.png" decoding="async" width="300" height="57" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/4/49/Functional_Group_Reduction_3.svg/450px-Functional_Group_Reduction_3.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/4/49/Functional_Group_Reduction_3.svg/600px-Functional_Group_Reduction_3.svg.png 2x" data-file-width="623" data-file-height="119" /></a><figcaption>Functional Group Reduction using aluminium hydride</figcaption></figure> <p><a href="/wiki/Nitro_group" class="mw-redirect" title="Nitro group">Nitro groups</a> are not reduced by aluminium hydride. Likewise, aluminium hydride can accomplish the reduction of an <a href="/wiki/Ester" title="Ester">ester</a> in the presence of nitro groups.<sup id="cite_ref-38" class="reference"><a href="#cite_note-38"><span class="cite-bracket">[</span>38<span class="cite-bracket">]</span></a></sup> </p> <figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:Functional_Group_Reduction_4.svg" class="mw-file-description" title="Ester reduction using aluminium hydride"><img alt="Ester reduction using aluminium hydride" src="//upload.wikimedia.org/wikipedia/commons/thumb/5/5c/Functional_Group_Reduction_4.svg/300px-Functional_Group_Reduction_4.svg.png" decoding="async" width="300" height="72" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/5/5c/Functional_Group_Reduction_4.svg/450px-Functional_Group_Reduction_4.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/5/5c/Functional_Group_Reduction_4.svg/600px-Functional_Group_Reduction_4.svg.png 2x" data-file-width="708" data-file-height="169" /></a><figcaption>Ester reduction using aluminium hydride</figcaption></figure> <p>Aluminium hydride can be used in the reduction of acetals to half protected diols.<sup id="cite_ref-39" class="reference"><a href="#cite_note-39"><span class="cite-bracket">[</span>39<span class="cite-bracket">]</span></a></sup> </p> <figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:Functional_Group_Reduction_5.svg" class="mw-file-description" title="Acetal reduction using aluminium hydride"><img alt="Acetal reduction using aluminium hydride" src="//upload.wikimedia.org/wikipedia/commons/thumb/f/fd/Functional_Group_Reduction_5.svg/300px-Functional_Group_Reduction_5.svg.png" decoding="async" width="300" height="81" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/f/fd/Functional_Group_Reduction_5.svg/450px-Functional_Group_Reduction_5.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/f/fd/Functional_Group_Reduction_5.svg/600px-Functional_Group_Reduction_5.svg.png 2x" data-file-width="497" data-file-height="135" /></a><figcaption>Acetal reduction using aluminium hydride</figcaption></figure> <p>Aluminium hydride can also be used in epoxide ring opening reaction as shown below.<sup id="cite_ref-40" class="reference"><a href="#cite_note-40"><span class="cite-bracket">[</span>40<span class="cite-bracket">]</span></a></sup> </p> <figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:Epoxide_Ring_Opening.jpg" class="mw-file-description" title="Epoxide reduction using aluminium hydride"><img alt="Epoxide reduction using aluminium hydride" src="//upload.wikimedia.org/wikipedia/commons/thumb/6/61/Epoxide_Ring_Opening.jpg/300px-Epoxide_Ring_Opening.jpg" decoding="async" width="300" height="68" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/6/61/Epoxide_Ring_Opening.jpg/450px-Epoxide_Ring_Opening.jpg 1.5x, //upload.wikimedia.org/wikipedia/commons/6/61/Epoxide_Ring_Opening.jpg 2x" data-file-width="481" data-file-height="109" /></a><figcaption>Epoxide reduction using aluminium hydride</figcaption></figure> <p>The allylic rearrangement reaction carried out using aluminium hydride is a <a href="/wiki/SN2_reaction" title="SN2 reaction">S<sub>N</sub>2</a> reaction, and it is not sterically demanding.<sup id="cite_ref-41" class="reference"><a href="#cite_note-41"><span class="cite-bracket">[</span>41<span class="cite-bracket">]</span></a></sup> </p> <figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:Allylic_rearrangement_reaction.svg" class="mw-file-description" title="Phosphine reduction using aluminium hydride"><img alt="Phosphine reduction using aluminium hydride" src="//upload.wikimedia.org/wikipedia/commons/thumb/b/b2/Allylic_rearrangement_reaction.svg/300px-Allylic_rearrangement_reaction.svg.png" decoding="async" width="300" height="66" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/b/b2/Allylic_rearrangement_reaction.svg/450px-Allylic_rearrangement_reaction.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/b/b2/Allylic_rearrangement_reaction.svg/600px-Allylic_rearrangement_reaction.svg.png 2x" data-file-width="421" data-file-height="92" /></a><figcaption>Phosphine reduction using aluminium hydride</figcaption></figure> <p>Aluminium hydride will reduce <a href="/wiki/Carbon_dioxide" title="Carbon dioxide">carbon dioxide</a> to <a href="/wiki/Methane" title="Methane">methane</a> with heating:<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">[<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (July 2022)">citation needed</span></a></i>]</sup> </p> <dl><dd><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">4 AlH<sub class="template-chem2-sub">3</sub> + 3 CO<sub class="template-chem2-sub">2</sub> → 3 CH<sub class="template-chem2-sub">4</sub> + 2 Al<sub class="template-chem2-sub">2</sub>O<sub class="template-chem2-sub">3</sub></span></dd></dl> <div class="mw-heading mw-heading3"><h3 id="Hydroalumination">Hydroalumination</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Aluminium_hydride&action=edit&section=10" title="Edit section: Hydroalumination"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1251242444"><table class="box-Expand_section plainlinks metadata ambox mbox-small-left ambox-content" role="presentation"><tbody><tr><td class="mbox-image"><span typeof="mw:File"><a href="/wiki/File:Wiki_letter_w_cropped.svg" class="mw-file-description"><img alt="[icon]" src="//upload.wikimedia.org/wikipedia/commons/thumb/1/1c/Wiki_letter_w_cropped.svg/20px-Wiki_letter_w_cropped.svg.png" decoding="async" width="20" height="14" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/1/1c/Wiki_letter_w_cropped.svg/30px-Wiki_letter_w_cropped.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/1/1c/Wiki_letter_w_cropped.svg/40px-Wiki_letter_w_cropped.svg.png 2x" data-file-width="44" data-file-height="31" /></a></span></td><td class="mbox-text"><div class="mbox-text-span">This section <b>needs expansion</b>. You can help by <a class="external text" href="https://en.wikipedia.org/w/index.php?title=Aluminium_hydride&action=edit&section=">adding to it</a>. <span class="date-container"><i>(<span class="date">July 2022</span>)</i></span></div></td></tr></tbody></table> <style data-mw-deduplicate="TemplateStyles:r1236090951">.mw-parser-output .hatnote{font-style:italic}.mw-parser-output div.hatnote{padding-left:1.6em;margin-bottom:0.5em}.mw-parser-output .hatnote i{font-style:normal}.mw-parser-output .hatnote+link+.hatnote{margin-top:-0.5em}@media print{body.ns-0 .mw-parser-output .hatnote{display:none!important}}</style><div role="note" class="hatnote navigation-not-searchable">See also: <a href="/wiki/Carbometalation#Carboalumination" title="Carbometalation">Carbometalation § Carboalumination</a></div> <p>Akin to <a href="/wiki/Hydroboration" title="Hydroboration">hydroboration</a>, aluminium hydride can, in the presence of <a href="/wiki/Titanium_tetrachloride" title="Titanium tetrachloride">titanium tetrachloride</a>, add across <a href="/wiki/Multiple_bond" class="mw-redirect" title="Multiple bond">multiple bonds</a>.<sup id="cite_ref-42" class="reference"><a href="#cite_note-42"><span class="cite-bracket">[</span>42<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-43" class="reference"><a href="#cite_note-43"><span class="cite-bracket">[</span>43<span class="cite-bracket">]</span></a></sup> When the multiple bond in question is a <a href="/wiki/Propargylic_alcohol" class="mw-redirect" title="Propargylic alcohol">propargylic alcohols</a>, the results are <a href="/wiki/Alkenylaluminium_compounds" title="Alkenylaluminium compounds">Alkenylaluminium compounds</a>.<sup id="cite_ref-44" class="reference"><a href="#cite_note-44"><span class="cite-bracket">[</span>44<span class="cite-bracket">]</span></a></sup> </p> <figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:Hydroalumination.svg" class="mw-file-description" title="Hydroalumination of 1-hexene"><img alt="Hydroalumination of 1-hexene" src="//upload.wikimedia.org/wikipedia/commons/thumb/c/c8/Hydroalumination.svg/300px-Hydroalumination.svg.png" decoding="async" width="300" height="23" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/c/c8/Hydroalumination.svg/450px-Hydroalumination.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/c/c8/Hydroalumination.svg/600px-Hydroalumination.svg.png 2x" data-file-width="545" data-file-height="41" /></a><figcaption>Hydroalumination of 1-hexene</figcaption></figure> <div class="mw-heading mw-heading3"><h3 id="Fuel">Fuel</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Aluminium_hydride&action=edit&section=11" title="Edit section: Fuel"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1251242444"><table class="box-Update plainlinks metadata ambox ambox-content ambox-Update" role="presentation"><tbody><tr><td class="mbox-image"><div class="mbox-image-div"><span typeof="mw:File"><span><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/5/53/Ambox_current_red_Americas.svg/42px-Ambox_current_red_Americas.svg.png" decoding="async" width="42" height="34" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/5/53/Ambox_current_red_Americas.svg/63px-Ambox_current_red_Americas.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/5/53/Ambox_current_red_Americas.svg/84px-Ambox_current_red_Americas.svg.png 2x" data-file-width="360" data-file-height="290" /></span></span></div></td><td class="mbox-text"><div class="mbox-text-span">This section needs to be <b>updated</b>.<span class="hide-when-compact"> Please help update this article to reflect recent events or newly available information.</span> <span class="date-container"><i>(<span class="date">July 2022</span>)</i></span></div></td></tr></tbody></table> <p>In its passivated form, alane is an active candidate for storing hydrogen, and can be used for efficient power generation via fuel cell applications, including fuel cell and electric vehicles and other lightweight power applications.<sup id="cite_ref-Liu_SolidFuel_45-0" class="reference"><a href="#cite_note-Liu_SolidFuel-45"><span class="cite-bracket">[</span>45<span class="cite-bracket">]</span></a></sup> <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">AlH<sub class="template-chem2-sub">3</sub></span> contains up 10.1% hydrogen by weight (at a density of 1.48 grams per milliliter),<sup id="cite_ref-h2storage_2-2" class="reference"><a href="#cite_note-h2storage-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> or twice the hydrogen density of liquid <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">H<sub class="template-chem2-sub">2</sub></span>.<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">[<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (July 2022)">citation needed</span></a></i>]</sup> As of 2006, <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">AlH<sub class="template-chem2-sub">3</sub></span> was described as a candidate for which "further research w[ould] be required to develop an efficient and economical process to regenerate [it] from the spent Al powder".<sup id="cite_ref-h2storage_2-3" class="reference"><a href="#cite_note-h2storage-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup><sup class="noprint Inline-Template" style="margin-left:0.1em; white-space:nowrap;">[<i><a href="/wiki/Wikipedia:Manual_of_Style/Dates_and_numbers#Chronological_items" title="Wikipedia:Manual of Style/Dates and numbers"><span title="The text near this tag is dated. (July 2022)">needs update</span></a></i>]</sup> </p><p>Alane is also a potential additive to solid <a href="/wiki/Rocket_fuel" class="mw-redirect" title="Rocket fuel">rocket fuel</a> and to explosive and pyrotechnic compositions <sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">[<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (July 2022)">citation needed</span></a></i>]</sup> due to its high hydrogen content and low dehydrogenation temperature.<sup id="cite_ref-Liu_SolidFuel_45-1" class="reference"><a href="#cite_note-Liu_SolidFuel-45"><span class="cite-bracket">[</span>45<span class="cite-bracket">]</span></a></sup> In its unpassivated form, alane is also a promising <a href="/wiki/Rocket_fuel" class="mw-redirect" title="Rocket fuel">rocket fuel</a> additive, capable of delivering impulse efficiency gains of up to 10%.<sup id="cite_ref-46" class="reference"><a href="#cite_note-46"><span class="cite-bracket">[</span>46<span class="cite-bracket">]</span></a></sup> However, <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">AlH<sub class="template-chem2-sub">3</sub></span> can degrade when stored at room temperature, and some of its crystal forms have "poor compatibility" with some fuel components.<sup id="cite_ref-Liu_SolidFuel_45-2" class="reference"><a href="#cite_note-Liu_SolidFuel-45"><span class="cite-bracket">[</span>45<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="Deposition">Deposition</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Aluminium_hydride&action=edit&section=12" title="Edit section: Deposition"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Heated alane releases hydrogen gas and produces a very fine thin film of aluminum metal.<sup id="cite_ref-HS5p401_5-1" class="reference"><a href="#cite_note-HS5p401-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="References">References</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Aluminium_hydride&action=edit&section=13" title="Edit section: References"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="mw-references-wrap mw-references-columns"><ol class="references"> <li id="cite_note-1"><span class="mw-cite-backlink"><b><a href="#cite_ref-1">^</a></b></span> <span class="reference-text"><style data-mw-deduplicate="TemplateStyles:r1238218222">.mw-parser-output cite.citation{font-style:inherit;word-wrap:break-word}.mw-parser-output .citation q{quotes:"\"""\"""'""'"}.mw-parser-output .citation:target{background-color:rgba(0,127,255,0.133)}.mw-parser-output .id-lock-free.id-lock-free a{background:url("//upload.wikimedia.org/wikipedia/commons/6/65/Lock-green.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-limited.id-lock-limited a,.mw-parser-output .id-lock-registration.id-lock-registration a{background:url("//upload.wikimedia.org/wikipedia/commons/d/d6/Lock-gray-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-subscription.id-lock-subscription a{background:url("//upload.wikimedia.org/wikipedia/commons/a/aa/Lock-red-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .cs1-ws-icon a{background:url("//upload.wikimedia.org/wikipedia/commons/4/4c/Wikisource-logo.svg")right 0.1em center/12px no-repeat}body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-free a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-limited a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-registration a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-subscription a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .cs1-ws-icon a{background-size:contain;padding:0 1em 0 0}.mw-parser-output .cs1-code{color:inherit;background:inherit;border:none;padding:inherit}.mw-parser-output .cs1-hidden-error{display:none;color:var(--color-error,#d33)}.mw-parser-output .cs1-visible-error{color:var(--color-error,#d33)}.mw-parser-output .cs1-maint{display:none;color:#085;margin-left:0.3em}.mw-parser-output .cs1-kern-left{padding-left:0.2em}.mw-parser-output .cs1-kern-right{padding-right:0.2em}.mw-parser-output .citation .mw-selflink{font-weight:inherit}@media screen{.mw-parser-output .cs1-format{font-size:95%}html.skin-theme-clientpref-night .mw-parser-output .cs1-maint{color:#18911f}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .cs1-maint{color:#18911f}}</style><cite id="CITEREFBrown,_H._C.Krishnamurthy,_S.1979" class="citation journal cs1">Brown, H. C.; Krishnamurthy, S. (1979). "Forty Years of Hydride Reductions". <i><a href="/wiki/Tetrahedron_(journal)" title="Tetrahedron (journal)">Tetrahedron</a></i>. <b>35</b> (5): 567–607. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1016%2F0040-4020%2879%2987003-9">10.1016/0040-4020(79)87003-9</a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.jtitle=Tetrahedron&rft.atitle=Forty+Years+of+Hydride+Reductions&rft.volume=35&rft.issue=5&rft.pages=567-607&rft.date=1979&rft_id=info%3Adoi%2F10.1016%2F0040-4020%2879%2987003-9&rft.au=Brown%2C+H.+C.&rft.au=Krishnamurthy%2C+S.&rfr_id=info%3Asid%2Fen.wikipedia.org%3AAluminium+hydride" class="Z3988"></span></span> </li> <li id="cite_note-h2storage-2"><span class="mw-cite-backlink">^ <a href="#cite_ref-h2storage_2-0"><sup><i><b>a</b></i></sup></a> <a href="#cite_ref-h2storage_2-1"><sup><i><b>b</b></i></sup></a> <a href="#cite_ref-h2storage_2-2"><sup><i><b>c</b></i></sup></a> <a href="#cite_ref-h2storage_2-3"><sup><i><b>d</b></i></sup></a></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFGraetz,_J..Reilly,_J..Sandrock,_G..Johnson,_J..2006" class="citation report cs1">Graetz, J..; Reilly, J..; Sandrock, G..; Johnson, J..; Zhou, W.-M.; Wegrzyn, J. (2006). <a rel="nofollow" class="external text" href="https://www.osti.gov/biblio/899889-UGd8IT/">Aluminum Hydride, A1H3, As a Hydrogen Storage Compound</a> (Report). Washington, D.C.: Office of Science and Technical Information [OSTI]. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.2172%2F899889">10.2172/899889</a>. <a href="/wiki/OSTI_(identifier)" class="mw-redirect" title="OSTI (identifier)">OSTI</a> <a rel="nofollow" class="external text" href="https://www.osti.gov/biblio/899889">899889</a><span class="reference-accessdate">. Retrieved <span class="nowrap">28 July</span> 2022</span>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=report&rft.btitle=Aluminum+Hydride%2C+A1H3%2C+As+a+Hydrogen+Storage+Compound&rft.place=Washington%2C+D.C.&rft.pub=Office+of+Science+and+Technical+Information+%5BOSTI%5D&rft.date=2006&rft_id=https%3A%2F%2Fwww.osti.gov%2Fbiblio%2F899889%23id-name%3DOSTI&rft_id=info%3Adoi%2F10.2172%2F899889&rft.au=Graetz%2C+J..&rft.au=Reilly%2C+J..&rft.au=Sandrock%2C+G..&rft.au=Johnson%2C+J..&rft.au=Zhou%2C+W.-M.&rft.au=Wegrzyn%2C+J.&rft_id=https%3A%2F%2Fwww.osti.gov%2Fbiblio%2F899889-UGd8IT%2F&rfr_id=info%3Asid%2Fen.wikipedia.org%3AAluminium+hydride" class="Z3988"></span></span> </li> <li id="cite_note-3"><span class="mw-cite-backlink"><b><a href="#cite_ref-3">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFLin-Lin_WangAditi_HerwadkarJason_M._ReichDuane_D._Johnson2016" class="citation journal cs1">Lin-Lin Wang; Aditi Herwadkar; Jason M. Reich; Duane D. Johnson; Stephen D. House; Pamela Peña-Martin; Angus A. Rockett; Ian M. Robertson; Shalabh Gupta; Vitalij K. Pecharsky (2016). <a rel="nofollow" class="external text" href="https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.201600338">"Towards Direct Synthesis of Alane: A Predicted Defect-Mediated Pathway Confirmed Experimentally"</a>. <i>ChemSusChem</i>. <b>9</b> (17): 2358–2364. <a href="/wiki/Bibcode_(identifier)" class="mw-redirect" title="Bibcode (identifier)">Bibcode</a>:<a rel="nofollow" class="external text" href="https://ui.adsabs.harvard.edu/abs/2016ChSCh...9.2358W">2016ChSCh...9.2358W</a>. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1002%2Fcssc.201600338">10.1002/cssc.201600338</a>. <a href="/wiki/PMID_(identifier)" class="mw-redirect" title="PMID (identifier)">PMID</a> <a rel="nofollow" class="external text" href="https://pubmed.ncbi.nlm.nih.gov/27535100">27535100</a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.jtitle=ChemSusChem&rft.atitle=Towards+Direct+Synthesis+of+Alane%3A+A+Predicted+Defect-Mediated+Pathway+Confirmed+Experimentally&rft.volume=9&rft.issue=17&rft.pages=2358-2364&rft.date=2016&rft_id=info%3Apmid%2F27535100&rft_id=info%3Adoi%2F10.1002%2Fcssc.201600338&rft_id=info%3Abibcode%2F2016ChSCh...9.2358W&rft.au=Lin-Lin+Wang&rft.au=Aditi+Herwadkar&rft.au=Jason+M.+Reich&rft.au=Duane+D.+Johnson&rft.au=Stephen+D.+House&rft.au=Pamela+Pe%C3%B1a-Martin&rft.au=Angus+A.+Rockett&rft.au=Ian+M.+Robertson&rft.au=Shalabh+Gupta&rft.au=Vitalij+K.+Pecharsky&rft_id=https%3A%2F%2Fchemistry-europe.onlinelibrary.wiley.com%2Fdoi%2F10.1002%2Fcssc.201600338&rfr_id=info%3Asid%2Fen.wikipedia.org%3AAluminium+hydride" class="Z3988"></span></span> </li> <li id="cite_note-EROSv08-4"><span class="mw-cite-backlink">^ <a href="#cite_ref-EROSv08_4-0"><sup><i><b>a</b></i></sup></a> <a href="#cite_ref-EROSv08_4-1"><sup><i><b>b</b></i></sup></a> <a href="#cite_ref-EROSv08_4-2"><sup><i><b>c</b></i></sup></a> <a href="#cite_ref-EROSv08_4-3"><sup><i><b>d</b></i></sup></a> <a href="#cite_ref-EROSv08_4-4"><sup><i><b>e</b></i></sup></a> <a href="#cite_ref-EROSv08_4-5"><sup><i><b>f</b></i></sup></a></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFGalatsisSintimWang2008" class="citation book cs1">Galatsis, P; Sintim, Herman O.; Wang J. (15 September 2008). "Aluminum Hydride". <span class="id-lock-subscription" title="Paid subscription required"><a rel="nofollow" class="external text" href="https://onlinelibrary.wiley.com/doi/10.1002/047084289X.ra082.pub2"><i>Encyclopedia of Reagents for Organic Synthesis</i></a></span> (online ed.). New York, N.Y.: John Wiley & Sons. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1002%2F047084289X.ra082.pub2">10.1002/047084289X.ra082.pub2</a>. <a href="/wiki/ISBN_(identifier)" class="mw-redirect" title="ISBN (identifier)">ISBN</a> <a href="/wiki/Special:BookSources/978-0471936237" title="Special:BookSources/978-0471936237"><bdi>978-0471936237</bdi></a><span class="reference-accessdate">. Retrieved <span class="nowrap">28 July</span> 2022</span>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=bookitem&rft.atitle=Aluminum+Hydride&rft.btitle=Encyclopedia+of+Reagents+for+Organic+Synthesis&rft.place=New+York%2C+N.Y.&rft.edition=online&rft.pub=John+Wiley+%26+Sons&rft.date=2008-09-15&rft_id=info%3Adoi%2F10.1002%2F047084289X.ra082.pub2&rft.isbn=978-0471936237&rft.aulast=Galatsis&rft.aufirst=P&rft.au=Sintim%2C+Herman+O.&rft.au=Wang+J.&rft_id=https%3A%2F%2Fonlinelibrary.wiley.com%2Fdoi%2F10.1002%2F047084289X.ra082.pub2&rfr_id=info%3Asid%2Fen.wikipedia.org%3AAluminium+hydride" class="Z3988"></span></span> </li> <li id="cite_note-HS5p401-5"><span class="mw-cite-backlink">^ <a href="#cite_ref-HS5p401_5-0"><sup><i><b>a</b></i></sup></a> <a href="#cite_ref-HS5p401_5-1"><sup><i><b>b</b></i></sup></a></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFHousecroftSharpe2018" class="citation book cs1">Housecroft, C. E.; Sharpe, A. G. (2018). <i>Inorganic Chemistry</i> (5th ed.). <a href="/wiki/Prentice-Hall" class="mw-redirect" title="Prentice-Hall">Prentice-Hall</a>. p. 401. <a href="/wiki/ISBN_(identifier)" class="mw-redirect" title="ISBN (identifier)">ISBN</a> <a href="/wiki/Special:BookSources/978-0273742753" title="Special:BookSources/978-0273742753"><bdi>978-0273742753</bdi></a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=book&rft.btitle=Inorganic+Chemistry&rft.pages=401&rft.edition=5th&rft.pub=Prentice-Hall&rft.date=2018&rft.isbn=978-0273742753&rft.aulast=Housecroft&rft.aufirst=C.+E.&rft.au=Sharpe%2C+A.+G.&rfr_id=info%3Asid%2Fen.wikipedia.org%3AAluminium+hydride" class="Z3988"></span></span> </li> <li id="cite_note-6"><span class="mw-cite-backlink"><b><a href="#cite_ref-6">^</a></b></span> <span class="reference-text">See, e.g., <a href="#CITEREFAndrewsWang2003">Andrews & Wang 2003</a>.</span> </li> <li id="cite_note-lund-7"><span class="mw-cite-backlink">^ <a href="#cite_ref-lund_7-0"><sup><i><b>a</b></i></sup></a> <a href="#cite_ref-lund_7-1"><sup><i><b>b</b></i></sup></a> <a href="#cite_ref-lund_7-2"><sup><i><b>c</b></i></sup></a></span> <span class="reference-text"><style data-mw-deduplicate="TemplateStyles:r1041539562">.mw-parser-output .citation{word-wrap:break-word}.mw-parser-output .citation:target{background-color:rgba(0,127,255,0.133)}</style><span class="citation patent" id="CITEREFLund,_G._K.;_Hanks,_J._M.;_Johnston,_H._E."><a rel="nofollow" class="external text" href="https://worldwide.espacenet.com/textdoc?DB=EPODOC&IDX=US2007066839">US application 2007066839</a>, Lund, G. K.; Hanks, J. M.; Johnston, H. E., "Method for the Production of α-Alane."</span><span class="Z3988" title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Apatent&rft.applnumber=2007066839&rft.cc=US&rft.title=Method+for+the+Production+of+%CE%B1-Alane.&rft.inventor=Lund%2C+G.+K.%3B+Hanks%2C+J.+M.%3B+Johnston%2C+H.+E."><span style="display: none;"> </span></span></span> </li> <li id="cite_note-8"><span class="mw-cite-backlink"><b><a href="#cite_ref-8">^</a></b></span> <span class="reference-text"><a href="#CITEREFTurleyRinn1969">Turley & Rinn 1969</a>. (Abstract) "The final Al⋯H distance of 1.72 Å, the participation of each Al in six bridges, and the equivalence of all Al⋯H distances suggest that 3c-2e bonding occurs." Angle is lasted as "Al(6)-H(5)-Al(4)" in Table IV.</span> </li> <li id="cite_note-Crystal-9"><span class="mw-cite-backlink"><b><a href="#cite_ref-Crystal_9-0">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFTurleyRinn1969" class="citation journal cs1">Turley, J. W.; Rinn, H. W. (1969). "The Crystal Structure of Aluminum Hydride". <i>Inorganic Chemistry</i>. <b>8</b> (1): 18–22. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1021%2Fic50071a005">10.1021/ic50071a005</a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.jtitle=Inorganic+Chemistry&rft.atitle=The+Crystal+Structure+of+Aluminum+Hydride&rft.volume=8&rft.issue=1&rft.pages=18-22&rft.date=1969&rft_id=info%3Adoi%2F10.1021%2Fic50071a005&rft.aulast=Turley&rft.aufirst=J.+W.&rft.au=Rinn%2C+H.+W.&rfr_id=info%3Asid%2Fen.wikipedia.org%3AAluminium+hydride" class="Z3988"></span></span> </li> <li id="cite_note-10"><span class="mw-cite-backlink"><b><a href="#cite_ref-10">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFKurth,_F._A.Eberlein,_R._A.Schnöckel,_H.-G.Downs,_A._J.1993" class="citation journal cs1">Kurth, F. A.; Eberlein, R. A.; Schnöckel, H.-G.; Downs, A. J.; Pulham, C. R. (1993). "Molecular Aluminium Trihydride, AlH<sub>3</sub>: Generation in a Solid Noble Gas Matrix and Characterisation by its Infrared Spectrum and <i>ab initio</i> Calculations". <i>Journal of the Chemical Society, Chemical Communications</i>. <b>1993</b> (16): 1302–1304. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1039%2FC39930001302">10.1039/C39930001302</a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.jtitle=Journal+of+the+Chemical+Society%2C+Chemical+Communications&rft.atitle=Molecular+Aluminium+Trihydride%2C+AlH%3Csub%3E3%3C%2Fsub%3E%3A+Generation+in+a+Solid+Noble+Gas+Matrix+and+Characterisation+by+its+Infrared+Spectrum+and+ab+initio+Calculations&rft.volume=1993&rft.issue=16&rft.pages=1302-1304&rft.date=1993&rft_id=info%3Adoi%2F10.1039%2FC39930001302&rft.au=Kurth%2C+F.+A.&rft.au=Eberlein%2C+R.+A.&rft.au=Schn%C3%B6ckel%2C+H.-G.&rft.au=Downs%2C+A.+J.&rft.au=Pulham%2C+C.+R.&rfr_id=info%3Asid%2Fen.wikipedia.org%3AAluminium+hydride" class="Z3988"></span> (Abstract) Broad-band photolysis of a solid noble gas matrix containing Al atoms and H<sub>2</sub> gives rise to the planar, monomeric AlH<sub>3</sub> molecule.</span> </li> <li id="cite_note-11"><span class="mw-cite-backlink"><b><a href="#cite_ref-11">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFAndrewsWang2003" class="citation journal cs1">Andrews, Lester; Wang Xuefeng (2003). "The Infrared Spectrum of Al<sub>2</sub>H<sub>6</sub> in Solid Hydrogen". <i>Science</i>. <b>299</b> (5615): 2049–2052. <a href="/wiki/Bibcode_(identifier)" class="mw-redirect" title="Bibcode (identifier)">Bibcode</a>:<a rel="nofollow" class="external text" href="https://ui.adsabs.harvard.edu/abs/2003Sci...299.2049A">2003Sci...299.2049A</a>. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1126%2Fscience.1082456">10.1126/science.1082456</a>. <a href="/wiki/JSTOR_(identifier)" class="mw-redirect" title="JSTOR (identifier)">JSTOR</a> <a rel="nofollow" class="external text" href="https://www.jstor.org/stable/3833717">3833717</a>. <a href="/wiki/PMID_(identifier)" class="mw-redirect" title="PMID (identifier)">PMID</a> <a rel="nofollow" class="external text" href="https://pubmed.ncbi.nlm.nih.gov/12663923">12663923</a>. <a href="/wiki/S2CID_(identifier)" class="mw-redirect" title="S2CID (identifier)">S2CID</a> <a rel="nofollow" class="external text" href="https://api.semanticscholar.org/CorpusID:45856199">45856199</a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.jtitle=Science&rft.atitle=The+Infrared+Spectrum+of+Al%3Csub%3E2%3C%2Fsub%3EH%3Csub%3E6%3C%2Fsub%3E+in+Solid+Hydrogen&rft.volume=299&rft.issue=5615&rft.pages=2049-2052&rft.date=2003&rft_id=https%3A%2F%2Fapi.semanticscholar.org%2FCorpusID%3A45856199%23id-name%3DS2CID&rft_id=info%3Abibcode%2F2003Sci...299.2049A&rft_id=info%3Apmid%2F12663923&rft_id=info%3Adoi%2F10.1126%2Fscience.1082456&rft_id=https%3A%2F%2Fwww.jstor.org%2Fstable%2F3833717%23id-name%3DJSTOR&rft.aulast=Andrews&rft.aufirst=Lester&rft.au=Wang+Xuefeng&rfr_id=info%3Asid%2Fen.wikipedia.org%3AAluminium+hydride" class="Z3988"></span> See also emendations at <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1126%2Fscience.300.5620.741a">10.1126/science.300.5620.741a</a>.</span> </li> <li id="cite_note-Pulham-12"><span class="mw-cite-backlink"><b><a href="#cite_ref-Pulham_12-0">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFPulham,_C._R.Downs,_A._J.Goode,_M._J.Rankin_D._W._H.1991" class="citation journal cs1">Pulham, C. R.; Downs, A. J.; Goode, M. J.; Rankin D. W. H.; Robertson, H. E. (1991). 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(2011). <a rel="nofollow" class="external text" href="https://doi.org/10.1051%2Feucass%2F201102353">"Overview of Hybrid Propulsion"</a>. <i>Progress in Propulsion Physics</i>. <b>2</b>: 353–374. <a href="/wiki/Bibcode_(identifier)" class="mw-redirect" title="Bibcode (identifier)">Bibcode</a>:<a rel="nofollow" class="external text" href="https://ui.adsabs.harvard.edu/abs/2011EUCAS...2..353C">2011EUCAS...2..353C</a>. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<span class="id-lock-free" title="Freely accessible"><a rel="nofollow" class="external text" href="https://doi.org/10.1051%2Feucass%2F201102353">10.1051/eucass/201102353</a></span>. <a href="/wiki/ISBN_(identifier)" class="mw-redirect" title="ISBN (identifier)">ISBN</a> <a href="/wiki/Special:BookSources/978-2-7598-0673-7" title="Special:BookSources/978-2-7598-0673-7"><bdi>978-2-7598-0673-7</bdi></a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.jtitle=Progress+in+Propulsion+Physics&rft.atitle=Overview+of+Hybrid+Propulsion&rft.volume=2&rft.pages=353-374&rft.date=2011&rft_id=info%3Adoi%2F10.1051%2Feucass%2F201102353&rft_id=info%3Abibcode%2F2011EUCAS...2..353C&rft.isbn=978-2-7598-0673-7&rft.aulast=Calabro&rft.aufirst=M.&rft_id=https%3A%2F%2Fdoi.org%2F10.1051%252Feucass%252F201102353&rfr_id=info%3Asid%2Fen.wikipedia.org%3AAluminium+hydride" class="Z3988"></span></span> </li> </ol></div> <div class="mw-heading mw-heading2"><h2 id="External_links">External links</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Aluminium_hydride&action=edit&section=14" title="Edit section: External links"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a rel="nofollow" class="external text" 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"}.mw-parser-output .navbar-brackets::after{margin-left:-0.125em;content:" ]"}.mw-parser-output .navbar li{word-spacing:-0.125em}.mw-parser-output .navbar a>span,.mw-parser-output .navbar a>abbr{text-decoration:inherit}.mw-parser-output .navbar-mini abbr{font-variant:small-caps;border-bottom:none;text-decoration:none;cursor:inherit}.mw-parser-output .navbar-ct-full{font-size:114%;margin:0 7em}.mw-parser-output .navbar-ct-mini{font-size:114%;margin:0 4em}html.skin-theme-clientpref-night .mw-parser-output .navbar li a abbr{color:var(--color-base)!important}@media(prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .navbar li a abbr{color:var(--color-base)!important}}@media print{.mw-parser-output .navbar{display:none!important}}</style><div class="navbar plainlinks hlist navbar-mini"><ul><li class="nv-view"><a href="/wiki/Template:Aluminium_compounds" title="Template:Aluminium compounds"><abbr title="View this template">v</abbr></a></li><li class="nv-talk"><a href="/wiki/Template_talk:Aluminium_compounds" title="Template talk:Aluminium compounds"><abbr title="Discuss this template">t</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:EditPage/Template:Aluminium_compounds" title="Special:EditPage/Template:Aluminium compounds"><abbr title="Edit this template">e</abbr></a></li></ul></div><div id="Aluminium_compounds" style="font-size:114%;margin:0 4em"><a href="/wiki/Aluminium_compounds" title="Aluminium compounds">Aluminium compounds</a></div></th></tr><tr><th scope="row" class="navbox-group" style="width:1%">Al(I)</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Aluminium_monobromide" title="Aluminium monobromide">AlBr</a></li> <li><a href="/wiki/Aluminium_monochloride" title="Aluminium monochloride">AlCl</a></li> <li><a href="/wiki/Aluminium_monofluoride" title="Aluminium monofluoride">AlF</a></li> <li><a href="/wiki/Aluminium_monoiodide" title="Aluminium monoiodide">AlI</a></li> <li><a href="/wiki/Aluminium(I)_oxide" title="Aluminium(I) oxide">Al<sub>2</sub>O</a></li> <li><a href="/wiki/Aluminium_monohydroxide" title="Aluminium monohydroxide">AlOH</a></li></ul> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Organoaluminium(I)_compounds" scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Organoaluminium" class="mw-redirect" title="Organoaluminium">Organoaluminium</a>(I) compounds</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"><a href="/wiki/(Pentamethylcyclopentadienyl)aluminium(I)" title="(Pentamethylcyclopentadienyl)aluminium(I)">Al(C<sub>5</sub>(CH<sub>3</sub>)<sub>5</sub>)</a></div></td></tr></tbody></table><div> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">Al(II)</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Aluminium_diboride" title="Aluminium diboride">AlB<sub>2</sub></a></li> <li><a href="/wiki/Aluminium_dodecaboride" title="Aluminium dodecaboride">AlB<sub>12</sub></a></li> <li><a href="/wiki/Aluminium(II)_oxide" title="Aluminium(II) oxide">AlO</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">Al(III)</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Aluminium_arsenide" title="Aluminium arsenide">AlAs</a></li> <li><a href="/wiki/Aluminium_borohydride" title="Aluminium borohydride">Al(BH<sub>4</sub>)<sub>3</sub></a></li> <li><a href="/wiki/Aluminium_bromide" title="Aluminium bromide">AlBr<sub>3</sub></a></li> <li><a href="/wiki/Aluminium_cyanide" title="Aluminium cyanide">Al(CN)<sub>3</sub></a></li> <li><a href="/wiki/Aluminium_chloride" title="Aluminium chloride">AlCl<sub>3</sub></a></li> <li><a href="/wiki/Sodium_tetrachloroaluminate" title="Sodium tetrachloroaluminate">NaAlCl<sub>4</sub></a></li> <li><a href="/wiki/Aluminium_fluoride" title="Aluminium fluoride">AlF<sub>3</sub></a></li> <li><a class="mw-selflink selflink">AlH<sub>3</sub></a></li> <li><a href="/wiki/Aluminium_iodide" title="Aluminium iodide">AlI<sub>3</sub></a></li> <li><a href="/wiki/Aluminium_nitride" title="Aluminium nitride">AlN</a></li> <li><a href="/wiki/Aluminium_nitrate" title="Aluminium nitrate">Al(NO<sub>3</sub>)<sub>3</sub></a></li> <li><a href="/wiki/Aluminium_carbonate" title="Aluminium carbonate">Al<sub>2</sub>(CO<sub>3</sub>)<sub>3</sub></a></li> <li><a href="/wiki/Aluminium_hydroxide" title="Aluminium hydroxide">Al(OH)<sub>3</sub></a></li> <li><a href="/wiki/Aluminium_monoacetate" title="Aluminium monoacetate">Al(OH)<sub>2</sub>OAc</a></li> <li><a href="/wiki/Aluminium_diacetate" title="Aluminium diacetate">Al(OH)(OAc)<sub>2</sub></a></li> <li><a href="/wiki/Aluminium_triacetate" title="Aluminium triacetate">Al(OAc)<sub>3</sub></a></li> <li><a href="/wiki/Aluminium_sulfacetate" title="Aluminium sulfacetate">Al<sub>2</sub>SO<sub>4</sub>(OAc)<sub>4</sub></a></li> <li><a href="/wiki/Aluminium_phosphide" title="Aluminium phosphide">AlP</a></li> <li><a href="/wiki/Aluminium_phosphate" title="Aluminium phosphate">AlPO<sub>4</sub></a></li> <li><a href="/wiki/Aluminium_antimonide" title="Aluminium antimonide">AlSb</a></li> <li><a href="/wiki/Aluminium_acetylacetonate" title="Aluminium acetylacetonate"> Al(C<sub>5</sub>H<sub>7</sub>O<sub>2</sub>)<sub>3</sub></a></li> <li><a href="/w/index.php?title=Aluminium_permanganate&action=edit&redlink=1" class="new" title="Aluminium permanganate (page does not exist)">Al(MnO<sub>4</sub>)<sub>3</sub></a></li> <li><a href="/wiki/Aluminium_molybdate" title="Aluminium molybdate">Al<sub>2</sub>(MoO<sub>4</sub>)<sub>3</sub></a></li> <li><a href="/wiki/Aluminium_oxide" title="Aluminium oxide">Al<sub>2</sub>O<sub>3</sub></a></li> <li><a href="/wiki/Aluminium_sulfide" title="Aluminium sulfide">Al<sub>2</sub>S<sub>3</sub></a></li> <li><a href="/wiki/Aluminium_sulfate" title="Aluminium sulfate">Al<sub>2</sub>(SO<sub>4</sub>)<sub>3</sub></a></li> <li><a href="/wiki/Aluminium_selenide" title="Aluminium selenide">Al<sub>2</sub>Se<sub>3</sub></a></li> <li><a href="/wiki/Aluminium_telluride" title="Aluminium telluride">Al<sub>2</sub>Te<sub>3</sub></a></li> <li><a href="/wiki/Aluminium_silicate" title="Aluminium silicate">Al<sub>2</sub>SiO<sub>5</sub></a></li> <li><a href="/wiki/Aluminium_arsenate" title="Aluminium arsenate">AlAsO<sub>4</sub></a></li> <li><a href="/wiki/Aluminium_carbide" title="Aluminium carbide">Al<sub>4</sub>C<sub>3</sub></a></li> <li><a href="/wiki/Aluminium_hydroxide_oxide" title="Aluminium hydroxide oxide">AlOHO</a></li> <li><a href="/wiki/Aluminium_monostearate" title="Aluminium monostearate">Al(OH)<sub>2</sub>CO<sub>2</sub>C<sub>17</sub>H<sub>5</sub></a></li> <li><a href="/wiki/Sodium_bis(2-methoxyethoxy)aluminumhydride" class="mw-redirect" title="Sodium bis(2-methoxyethoxy)aluminumhydride">NaAlH<sub>2</sub>(OC<sub>2</sub>H<sub>4</sub>OCH<sub>3</sub>)<sub>2</sub></a></li> <li><a href="/w/index.php?title=Lithium_bis(2-methoxyethoxy)aluminumhydride&action=edit&redlink=1" class="new" title="Lithium bis(2-methoxyethoxy)aluminumhydride (page does not exist)">LiAlH<sub>2</sub>(OC<sub>2</sub>H<sub>4</sub>OCH<sub>3</sub>)<sub>2</sub></a></li> <li><a href="/wiki/Potassium_aluminium_borate" title="Potassium aluminium borate">K<sub>2</sub>Al<sub>2</sub>B<sub>2</sub>O<sub>7</sub></a></li> <li><a href="/wiki/Potassium_hexafluoroaluminate" title="Potassium hexafluoroaluminate"><span class="chemf nowrap">K<sub class="template-chem2-sub">3</sub>AlF<sub class="template-chem2-sub">6</sub></span></a></li></ul> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Alum" title="Alum">Alums</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Ammonium_aluminium_sulfate" class="mw-redirect" title="Ammonium aluminium sulfate">(NH<sub>4</sub>)Al(SO<sub>4</sub>)<sub>2</sub></a></li> <li><a href="/wiki/Potassium_alum" title="Potassium alum">KAl(SO<sub>4</sub>)<sub>2</sub></a></li> <li><a href="/wiki/Sodium_aluminium_sulfate" class="mw-redirect" title="Sodium aluminium sulfate">NaAl(SO<sub>4</sub>)<sub>2</sub></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">Organoaluminium(III) compounds</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Aluminium_lactate" title="Aluminium lactate">Al(C<sub>3</sub>H<sub>5</sub>O<sub>3</sub>)<sub>3</sub></a></li> <li><a href="/wiki/Aluminium_laurate" title="Aluminium laurate"><span class="chemf nowrap">C<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">36</sub></span></span>H<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">69</sub></span></span>AlO<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">6</sub></span></span></span></a></li> <li><a href="/wiki/Trimethylaluminium" title="Trimethylaluminium">(Al(CH<sub>3</sub>)<sub>3</sub>)<sub>2</sub></a></li> <li><a href="/wiki/Triethylaluminium" title="Triethylaluminium">(Al(C<sub>2</sub>H<sub>5</sub>)<sub>3</sub>)<sub>2</sub></a></li> <li><a href="/wiki/Triisobutylaluminium" title="Triisobutylaluminium">Al(CH<sub>2</sub>CH(CH<sub>3</sub>)<sub>2</sub>)<sub>3</sub></a></li> <li><a href="/wiki/Diethylaluminium_chloride" title="Diethylaluminium chloride">Al(C<sub>2</sub>H<sub>5</sub>)<sub>2</sub>Cl</a></li> <li><a href="/wiki/Diethylaluminium_cyanide" title="Diethylaluminium cyanide">Al(C<sub>2</sub>H<sub>5</sub>)<sub>2</sub>CN</a></li> <li><a href="/wiki/Diisobutylaluminium_hydride" title="Diisobutylaluminium hydride">Al(CH<sub>2</sub>CH(CH<sub>3</sub>)<sub>2</sub>)<sub>2</sub>H</a></li> <li><a href="/wiki/Ethylaluminium_sesquichloride" title="Ethylaluminium sesquichloride">Al(C<sub>2</sub>H<sub>5</sub>)<sub>2</sub>Cl<sub>2</sub>C<sub>2</sub>H<sub>5</sub>Cl</a></li> <li><a href="/wiki/Tebbe%27s_reagent" title="Tebbe's reagent">Ti(C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>CH<sub>2</sub>ClAl(CH<sub>3</sub>)<sub>2</sub></a></li></ul> </div></td></tr></tbody></table><div> </div></td></tr></tbody></table></div> <div class="navbox-styles"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1129693374"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1236075235"></div><div role="navigation" class="navbox" aria-labelledby="Binary_compounds_of_hydrogen" style="padding:3px"><table class="nowraplinks mw-collapsible mw-collapsed navbox-inner" style="border-spacing:0;background:transparent;color:inherit"><tbody><tr><th scope="col" class="navbox-title" colspan="2"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1129693374"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1239400231"><div class="navbar plainlinks hlist navbar-mini"><ul><li class="nv-view"><a href="/wiki/Template:Hydrides_by_group" title="Template:Hydrides by group"><abbr title="View this template">v</abbr></a></li><li class="nv-talk"><a href="/wiki/Template_talk:Hydrides_by_group" title="Template talk:Hydrides by group"><abbr title="Discuss this template">t</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:EditPage/Template:Hydrides_by_group" title="Special:EditPage/Template:Hydrides by group"><abbr title="Edit this template">e</abbr></a></li></ul></div><div id="Binary_compounds_of_hydrogen" style="font-size:114%;margin:0 4em"><a href="/wiki/Binary_compounds_of_hydrogen" title="Binary compounds of hydrogen">Binary compounds of hydrogen</a></div></th></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Hydride#Ionic_hydrides" title="Hydride">Alkali metal <br />(Group 1) hydrides</a></th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Lithium_hydride" title="Lithium hydride">LiH</a></li> <li><a href="/wiki/Sodium_hydride" title="Sodium hydride">NaH</a></li> <li><a href="/wiki/Potassium_hydride" title="Potassium hydride">KH</a></li> <li><a href="/wiki/Rubidium_hydride" title="Rubidium hydride">RbH</a></li> <li><a href="/wiki/Caesium_hydride" title="Caesium hydride">CsH</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Hydride#Ionic_hydrides" title="Hydride">Alkaline <br />(Group 2) <br />earth hydrides</a></th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Monohydrides" scope="row" class="navbox-group" style="width:1%">Monohydrides</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Beryllium_monohydride" title="Beryllium monohydride">BeH</a></li> <li><a href="/wiki/Magnesium_monohydride" title="Magnesium monohydride">MgH</a></li> <li><a href="/wiki/Calcium_monohydride" title="Calcium monohydride">CaH</a></li> <li><a href="/w/index.php?title=Strontium_monohydride&action=edit&redlink=1" class="new" title="Strontium monohydride (page does not exist)">SrH</a></li> <li><a href="/w/index.php?title=Barium_monohydride&action=edit&redlink=1" class="new" title="Barium monohydride (page does not exist)">BaH</a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Dihydrides" scope="row" class="navbox-group" style="width:1%">Dihydrides</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Beryllium_hydride" title="Beryllium hydride">BeH<sub>2</sub></a></li> <li><a href="/wiki/Magnesium_hydride" title="Magnesium hydride">MgH<sub>2</sub></a></li> <li><a href="/wiki/Calcium_hydride" title="Calcium hydride">CaH<sub>2</sub></a></li> <li><a href="/wiki/Strontium_hydride" title="Strontium hydride">SrH<sub>2</sub></a></li> <li><a href="/wiki/Barium_hydride" title="Barium hydride">BaH<sub>2</sub></a></li></ul> </div></td></tr></tbody></table><div></div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Group_13_hydride" title="Group 13 hydride">Group 13 <br />hydrides</a></th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Boranes" scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Boranes" title="Boranes">Boranes</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Borane" title="Borane">BH<sub>3</sub></a></li> <li><a href="/wiki/Boron_monohydride" title="Boron monohydride">BH</a></li> <li><a href="/wiki/Diborane" title="Diborane">B<sub>2</sub>H<sub>6</sub></a></li> <li><a href="/wiki/Diborane(2)" title="Diborane(2)">B<sub>2</sub>H<sub>2</sub></a></li> <li><a href="/wiki/Diborane(4)" title="Diborane(4)">B<sub>2</sub>H<sub>4</sub></a></li> <li><a href="/wiki/Tetraborane" title="Tetraborane">B<sub>4</sub>H<sub>10</sub></a></li> <li><a href="/wiki/Pentaborane(9)" title="Pentaborane(9)">B<sub>5</sub>H<sub>9</sub></a></li> <li><a href="/wiki/Pentaborane(11)" title="Pentaborane(11)">B<sub>5</sub>H<sub>11</sub></a></li> <li><a href="/wiki/Hexaborane(10)" title="Hexaborane(10)">B<sub>6</sub>H<sub>10</sub></a></li> <li><a href="/wiki/Hexaborane(12)" title="Hexaborane(12)">B<sub>6</sub>H<sub>12</sub></a></li> <li><a href="/wiki/Decaborane" title="Decaborane">B<sub>10</sub>H<sub>14</sub></a></li> <li><a href="/wiki/Octadecaborane" title="Octadecaborane">B<sub>18</sub>H<sub>22</sub></a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Alanes" scope="row" class="navbox-group" style="width:1%">Alanes</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a class="mw-selflink selflink">AlH<sub>3</sub></a></li> <li><a href="/wiki/Dialane" title="Dialane">Al<sub>2</sub>H<sub>6</sub></a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Gallanes" scope="row" class="navbox-group" style="width:1%">Gallanes</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Gallane" title="Gallane">GaH<sub>3</sub></a></li> <li><a href="/wiki/Digallane" title="Digallane">Ga<sub>2</sub>H<sub>6</sub></a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Indiganes" scope="row" class="navbox-group" style="width:1%">Indiganes</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Indium_trihydride" title="Indium trihydride">InH<sub>3</sub></a></li> <li><a href="/w/index.php?title=Diindigane&action=edit&redlink=1" class="new" title="Diindigane (page does not exist)">In<sub>2</sub>H<sub>6</sub></a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Thallanes" scope="row" class="navbox-group" style="width:1%">Thallanes</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Thallane" title="Thallane">TlH<sub>3</sub></a></li> <li><a href="/w/index.php?title=Dithallane&action=edit&redlink=1" class="new" title="Dithallane (page does not exist)">Tl<sub>2</sub>H<sub>6</sub></a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Nihonanes_(predicted)" scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Nihonium" title="Nihonium">Nihonanes</a> (<i>predicted</i>)</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><i>NhH</i></li> <li><i>NhH<sub>3</sub></i></li> <li><i>Nh<sub>2</sub>H<sub>6</sub></i></li> <li><i>NhH<sub>5</sub></i></li></ul> </div></td></tr></tbody></table><div></div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Group_14_hydride" title="Group 14 hydride">Group 14 hydrides</a></th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Hydrocarbons" scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Hydrocarbon" title="Hydrocarbon">Hydrocarbons</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Alkane" title="Alkane">alkanes</a></li> <li><a href="/wiki/Alkene" title="Alkene">alkenes</a></li> <li><a href="/wiki/Alkyne" title="Alkyne">alkynes</a></li> <li><a href="/wiki/Cycloalkane" title="Cycloalkane">Cycloalkanes</a></li> <li><a href="/wiki/Cycloalkene" title="Cycloalkene">Cycloalkenes</a></li> <li><a href="/wiki/Cycloalkyne" title="Cycloalkyne">Cycloalkynes</a></li> <li><a href="/wiki/Annulenes" class="mw-redirect" title="Annulenes">Annulenes</a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><td colspan="2" class="navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Methylidyne_radical" title="Methylidyne radical">CH</a></li> <li><a href="/wiki/Methylene_(compound)" title="Methylene (compound)">CH<sub>2</sub></a></li> <li><a href="/wiki/Methyl_radical" title="Methyl radical">CH<sub>3</sub></a></li> <li><a href="/wiki/Ethynyl_radical" title="Ethynyl radical">C<sub>2</sub>H</a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Silanes" scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Silanes" title="Silanes">Silanes</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Silane" title="Silane">SiH<sub>4</sub></a></li> <li><a href="/wiki/Disilane" title="Disilane">Si<sub>2</sub>H<sub>6</sub></a></li> <li><a href="/wiki/Trisilane" title="Trisilane">Si<sub>3</sub>H<sub>8</sub></a></li> <li><a href="/wiki/Tetrasilane" title="Tetrasilane">Si<sub>4</sub>H<sub>10</sub></a></li> <li><a href="/wiki/Pentasilane" class="mw-redirect" title="Pentasilane">Si<sub>5</sub>H<sub>12</sub></a></li> <li><a href="/wiki/Hexasilane" class="mw-redirect" title="Hexasilane">Si<sub>6</sub>H<sub>14</sub></a></li> <li><a href="/w/index.php?title=Heptasilane&action=edit&redlink=1" class="new" title="Heptasilane (page does not exist)">Si<sub>7</sub>H<sub>16</sub></a></li> <li><a href="/w/index.php?title=Octasilane&action=edit&redlink=1" class="new" title="Octasilane (page does not exist)">Si<sub>8</sub>H<sub>18</sub></a></li> <li><a href="/w/index.php?title=Nonasilane&action=edit&redlink=1" class="new" title="Nonasilane (page does not exist)">Si<sub>9</sub>H<sub>20</sub></a></li> <li><a href="/w/index.php?title=Decasilane&action=edit&redlink=1" class="new" title="Decasilane (page does not exist)">Si<sub>10</sub>H<sub>22</sub></a></li> <li><a href="/wiki/Silanes" title="Silanes">more...</a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Silenes" scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Silenes" title="Silenes">Silenes</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Disilene" title="Disilene">Si<sub>2</sub>H<sub>4</sub></a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Silynes" scope="row" class="navbox-group" style="width:1%"><a href="/w/index.php?title=Silynes&action=edit&redlink=1" class="new" title="Silynes (page does not exist)">Silynes</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Disilyne" title="Disilyne">Si<sub>2</sub>H<sub>2</sub></a></li> <li><a href="/wiki/Silicon_monohydride" class="mw-redirect" title="Silicon monohydride">SiH</a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Germanes" scope="row" class="navbox-group" style="width:1%"><a href="/w/index.php?title=Germanes&action=edit&redlink=1" class="new" title="Germanes (page does not exist)">Germanes</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Germane" title="Germane">GeH<sub>4</sub></a></li> <li><a href="/wiki/Digermane" title="Digermane">Ge<sub>2</sub>H<sub>6</sub></a></li> <li><a href="/w/index.php?title=Trigermane&action=edit&redlink=1" class="new" title="Trigermane (page does not exist)">Ge<sub>3</sub>H<sub>8</sub></a></li> <li><a href="/w/index.php?title=Tetragermane&action=edit&redlink=1" class="new" title="Tetragermane (page does not exist)">Ge<sub>4</sub>H<sub>10</sub></a></li> <li><a href="/w/index.php?title=Pentagermane&action=edit&redlink=1" class="new" title="Pentagermane (page does not exist)">Ge<sub>5</sub>H<sub>12</sub></a></li></ul> </div></td></tr></tbody></table><div></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Stannanes" scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Stannanes" class="mw-redirect" title="Stannanes">Stannanes</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Stannane" title="Stannane">SnH<sub>4</sub></a></li> <li><a href="/w/index.php?title=Distannane&action=edit&redlink=1" class="new" title="Distannane (page does not exist)">Sn<sub>2</sub>H<sub>6</sub></a></li></ul> </div></td></tr></tbody></table><div></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Plumbanes" scope="row" class="navbox-group" style="width:1%">Plumbanes</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Plumbane" title="Plumbane">PbH<sub>4</sub></a></li></ul> </div></td></tr></tbody></table><div></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Flerovanes_(predicted)" scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Flerovium" title="Flerovium">Flerovanes</a> (<i>predicted</i>)</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><i>FlH</i></li> <li><i>FlH<sub>2</sub></i></li> <li><i>FlH<sub>4</sub></i></li></ul> </div></td></tr></tbody></table><div></div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Pnictogen_hydride" title="Pnictogen hydride">Pnictogen <br />(Group 15) hydrides</a></th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Azanes" scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Azane" title="Azane">Azanes</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Ammonia" title="Ammonia">NH<sub>3</sub></a></li> <li><a href="/wiki/Hydrazine" title="Hydrazine">N<sub>2</sub>H<sub>4</sub></a></li> <li><a href="/wiki/Triazane" title="Triazane">N<sub>3</sub>H<sub>5</sub></a></li> <li><a href="/w/index.php?title=Tetrazane&action=edit&redlink=1" class="new" title="Tetrazane (page does not exist)">N<sub>4</sub>H<sub>6</sub></a></li> <li><a href="/w/index.php?title=Pentazane&action=edit&redlink=1" class="new" title="Pentazane (page does not exist)">N<sub>5</sub>H<sub>7</sub></a></li> <li><a href="/w/index.php?title=Hexazane&action=edit&redlink=1" class="new" title="Hexazane (page does not exist)">N<sub>6</sub>H<sub>8</sub></a></li> <li><a href="/w/index.php?title=Heptazane&action=edit&redlink=1" class="new" title="Heptazane (page does not exist)">N<sub>7</sub>H<sub>9</sub></a></li> <li><a href="/w/index.php?title=Octazane&action=edit&redlink=1" class="new" title="Octazane (page does not exist)">N<sub>8</sub>H<sub>10</sub></a></li> <li><a href="/w/index.php?title=Nonazane&action=edit&redlink=1" class="new" title="Nonazane (page does not exist)">N<sub>9</sub>H<sub>11</sub></a></li> <li><a href="/w/index.php?title=Decazane&action=edit&redlink=1" class="new" title="Decazane (page does not exist)">N<sub>10</sub>H<sub>12</sub></a></li> <li><a href="/wiki/Azane" title="Azane">more...</a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Azenes" scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Azo_compound" title="Azo compound">Azenes</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Diazene" class="mw-redirect" title="Diazene">N<sub>2</sub>H<sub>2</sub></a></li> <li><a href="/wiki/Triazene" title="Triazene">N<sub>3</sub>H<sub>3</sub></a></li> <li><a href="/wiki/Tetrazene" title="Tetrazene">N<sub>4</sub>H<sub>4</sub></a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Phosphanes" scope="row" class="navbox-group" style="width:1%"><a href="/w/index.php?title=Phosphanes&action=edit&redlink=1" class="new" title="Phosphanes (page does not exist)">Phosphanes</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Phosphine" title="Phosphine">PH<sub>3</sub></a></li> <li><a href="/wiki/Diphosphane" title="Diphosphane">P<sub>2</sub>H<sub>4</sub></a></li> <li><a href="/wiki/Triphosphane" title="Triphosphane">P<sub>3</sub>H<sub>5</sub></a></li> <li><a href="/w/index.php?title=Tetraphosphane&action=edit&redlink=1" class="new" title="Tetraphosphane (page does not exist)">P<sub>4</sub>H<sub>6</sub></a></li> <li><a href="/w/index.php?title=Pentaphosphane&action=edit&redlink=1" class="new" title="Pentaphosphane (page does not exist)">P<sub>5</sub>H<sub>7</sub></a></li> <li><a href="/w/index.php?title=Hexaphosphane&action=edit&redlink=1" class="new" title="Hexaphosphane (page does not exist)">P<sub>6</sub>H<sub>8</sub></a></li> <li><a href="/w/index.php?title=Heptaphosphane&action=edit&redlink=1" class="new" title="Heptaphosphane (page does not exist)">P<sub>7</sub>H<sub>9</sub></a></li> <li><a href="/w/index.php?title=Octaphosphane&action=edit&redlink=1" class="new" title="Octaphosphane (page does not exist)">P<sub>8</sub>H<sub>10</sub></a></li> <li><a href="/w/index.php?title=Nonaphosphane&action=edit&redlink=1" class="new" title="Nonaphosphane (page does not exist)">P<sub>9</sub>H<sub>11</sub></a></li> <li><a href="/w/index.php?title=Decaphosphane&action=edit&redlink=1" class="new" title="Decaphosphane (page does not exist)">P<sub>10</sub>H<sub>12</sub></a></li> <li><a href="/w/index.php?title=Phosphanes&action=edit&redlink=1" class="new" title="Phosphanes (page does not exist)">more...</a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Phosphenes" scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Diphosphenes" title="Diphosphenes">Phosphenes</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Diphosphene" title="Diphosphene">P<sub>2</sub>H<sub>2</sub></a></li> <li><a href="/w/index.php?title=Triphosphene&action=edit&redlink=1" class="new" title="Triphosphene (page does not exist)">P<sub>3</sub>H<sub>3</sub></a></li> <li><a href="/w/index.php?title=Tetraphosphene&action=edit&redlink=1" class="new" title="Tetraphosphene (page does not exist)">P<sub>4</sub>H<sub>4</sub></a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Arsanes" scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Arsane" class="mw-redirect" title="Arsane">Arsanes</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Arsine" title="Arsine">AsH<sub>3</sub></a></li> <li><a href="/wiki/Diarsine" class="mw-redirect" title="Diarsine">As<sub>2</sub>H<sub>4</sub></a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Stibanes" scope="row" class="navbox-group" style="width:1%">Stibanes</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Stibine" title="Stibine">SbH<sub>3</sub></a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Bismuthanes" scope="row" class="navbox-group" style="width:1%">Bismuthanes</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Bismuthine" title="Bismuthine">BiH<sub>3</sub></a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Moscovanes" scope="row" class="navbox-group" style="width:1%">Moscovanes</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><i><a href="/wiki/Moscovium" title="Moscovium">McH<sub>3</sub></a></i> (<i>predicted</i>)</li></ul> </div></td></tr></tbody></table><div> <ul><li><a href="/wiki/Hydrazoic_acid" title="Hydrazoic acid">HN<sub>3</sub></a></li> <li><a href="/wiki/Imidogen" title="Imidogen">NH</a></li> <li><a href="/wiki/Pentazole" title="Pentazole">HN<sub>5</sub></a></li> <li><a href="/wiki/Nitrogen_pentahydride" title="Nitrogen pentahydride">NH<sub>5</sub></a> <i>(hypothetical)</i></li></ul></div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Hydrogen_chalcogenide" title="Hydrogen chalcogenide">Hydrogen <br />chalcogenides <br />(Group 16 hydrides)</a></th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Polyoxidanes" scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Hydrogen_polyoxide" title="Hydrogen polyoxide">Polyoxidanes</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <li><a href="/wiki/Properties_of_water" title="Properties of water">H<sub>2</sub>O</a></li> <li><a href="/wiki/Hydrogen_peroxide" title="Hydrogen peroxide">H<sub>2</sub>O<sub>2</sub></a></li> <li><a href="/wiki/Trioxidane" title="Trioxidane">H<sub>2</sub>O<sub>3</sub></a></li> <li><a href="/wiki/Tetraoxidane" title="Tetraoxidane">H<sub>2</sub>O<sub>4</sub></a></li> <li><a href="/wiki/Pentaoxidane" title="Pentaoxidane">H<sub>2</sub>O<sub>5</sub></a></li> <li><a href="/wiki/Hydrogen_polyoxide" title="Hydrogen polyoxide">more...</a></li> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Polysulfanes" scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Polysulfane" title="Polysulfane">Polysulfanes</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Hydrogen_sulfide" title="Hydrogen sulfide">H<sub>2</sub>S</a></li> <li><a href="/wiki/Hydrogen_disulfide" title="Hydrogen disulfide">H<sub>2</sub>S<sub>2</sub></a></li> <li><a href="/wiki/Trisulfane" title="Trisulfane">H<sub>2</sub>S<sub>3</sub></a></li> <li><a href="/w/index.php?title=Hydrogen_tetrasulfide&action=edit&redlink=1" class="new" title="Hydrogen tetrasulfide (page does not exist)">H<sub>2</sub>S<sub>4</sub></a></li> <li><a href="/w/index.php?title=Hydrogen_pentasulfide&action=edit&redlink=1" class="new" title="Hydrogen pentasulfide (page does not exist)">H<sub>2</sub>S<sub>5</sub></a></li> <li><a href="/w/index.php?title=Hydrogen_hexasulfide&action=edit&redlink=1" class="new" title="Hydrogen hexasulfide (page does not exist)">H<sub>2</sub>S<sub>6</sub></a></li> <li><a href="/w/index.php?title=Hydrogen_heptasulfide&action=edit&redlink=1" class="new" title="Hydrogen heptasulfide (page does not exist)">H<sub>2</sub>S<sub>7</sub></a></li> <li><a href="/w/index.php?title=Hydrogen_octasulfide&action=edit&redlink=1" class="new" title="Hydrogen octasulfide (page does not exist)">H<sub>2</sub>S<sub>8</sub></a></li> <li><a href="/w/index.php?title=Hydrogen_nonasulfide&action=edit&redlink=1" class="new" title="Hydrogen nonasulfide (page does not exist)">H<sub>2</sub>S<sub>9</sub></a></li> <li><a href="/w/index.php?title=Hydrogen_decasulfide&action=edit&redlink=1" class="new" title="Hydrogen decasulfide (page does not exist)">H<sub>2</sub>S<sub>10</sub></a></li> <li><a href="/wiki/Polysulfane" title="Polysulfane">more...</a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Selanes" scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Selanes" class="mw-redirect" title="Selanes">Selanes</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Hydrogen_selenide" title="Hydrogen selenide">H<sub>2</sub>Se</a></li> <li><a href="/wiki/Hydrogen_diselenide" title="Hydrogen diselenide">H<sub>2</sub>Se<sub>2</sub></a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Tellanes" scope="row" class="navbox-group" style="width:1%">Tellanes</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Hydrogen_telluride" title="Hydrogen telluride">H<sub>2</sub>Te</a></li> <li><a href="/wiki/Hydrogen_ditelluride" title="Hydrogen ditelluride">H<sub>2</sub>Te<sub>2</sub></a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Polanes" scope="row" class="navbox-group" style="width:1%">Polanes</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Polonium_hydride" title="Polonium hydride">PoH<sub>2</sub></a></li></ul> </div></td></tr></tbody></table><div> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Livermoranes" scope="row" class="navbox-group" style="width:1%">Livermoranes</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><i><a href="/wiki/Livermorium" title="Livermorium">LvH<sub>2</sub></a></i> (<i>predicted</i>)</li></ul> </div></td></tr></tbody></table><div> <ul><li><a href="/wiki/Hydroxyl_radical" title="Hydroxyl radical">HO</a></li> <li><a href="/wiki/Hydroperoxyl" title="Hydroperoxyl">HO<sub>2</sub></a></li> <li><a href="/wiki/Hydrogen_ozonide" title="Hydrogen ozonide">HO<sub>3</sub></a></li> <li><a href="/w/index.php?title=Oxywater&action=edit&redlink=1" class="new" title="Oxywater (page does not exist)">H<sub>2</sub>O<sup>+</sup>–O<sup>–</sup></a> <i>(hypothetical)</i></li> <li><a href="/wiki/Sulfanyl" title="Sulfanyl">HS</a></li> <li><a href="/wiki/Semiheavy_water" title="Semiheavy water">HDO</a></li> <li><a href="/wiki/Heavy_water" title="Heavy water">D<sub>2</sub>O</a></li> <li><a href="/wiki/Tritiated_water" title="Tritiated water">T<sub>2</sub>O</a></li></ul></div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Hydrogen_halide" title="Hydrogen halide">Hydrogen halides <br />(Group 17 hydrides)</a></th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <li><a href="/wiki/Hydrogen_fluoride" title="Hydrogen fluoride">HF</a></li> <li><a href="/wiki/Hydrogen_chloride" title="Hydrogen chloride">HCl</a></li> <li><a href="/wiki/Hydrogen_bromide" title="Hydrogen bromide">HBr</a></li> <li><a href="/wiki/Hydrogen_iodide" title="Hydrogen iodide">HI</a></li> <li><a href="/wiki/Hydrogen_astatide" title="Hydrogen astatide">HAt</a></li> <li><i><a href="/wiki/Tennessine" title="Tennessine">HTs</a></i> (<i>predicted</i>)</li> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Transition_metal_hydrides" class="mw-redirect" title="Transition metal hydrides">Transition metal hydrides</a></th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Scandium_hydride" title="Scandium hydride">ScH<sub>2</sub></a></li> <li><a href="/wiki/Yttrium_hydride" title="Yttrium hydride">YH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Yttrium_trihydride&action=edit&redlink=1" class="new" title="Yttrium trihydride (page does not exist)">YH<sub>3</sub></a></li> <li><a href="/w/index.php?title=Yttrium_hexahydride&action=edit&redlink=1" class="new" title="Yttrium hexahydride (page does not exist)">YH<sub>6</sub></a></li> <li><a href="/w/index.php?title=Yttrium_nonahydride&action=edit&redlink=1" class="new" title="Yttrium nonahydride (page does not exist)">YH<sub>9</sub></a></li> <li><a href="/w/index.php?title=Lutetium_dihydride&action=edit&redlink=1" class="new" title="Lutetium dihydride (page does not exist)">LuH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Lutetium_trihydride&action=edit&redlink=1" class="new" title="Lutetium trihydride (page does not exist)">LuH<sub>3</sub></a></li> <li><a href="/wiki/Titanium_hydride" title="Titanium hydride">TiH<sub>2</sub></a></li> <li><a href="/wiki/Titanium(IV)_hydride" title="Titanium(IV) hydride">TiH<sub>4</sub></a></li> <li><a href="/wiki/Zirconium(II)_hydride" title="Zirconium(II) hydride">ZrH<sub>2</sub></a></li> <li><a href="/wiki/Zirconium_hydride" title="Zirconium hydride">ZrH<sub>4</sub></a></li> <li><a href="/w/index.php?title=Hafnium(II)_hydride&action=edit&redlink=1" class="new" title="Hafnium(II) hydride (page does not exist)">HfH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Hafnium_hydride&action=edit&redlink=1" class="new" title="Hafnium hydride (page does not exist)">HfH<sub>4</sub></a></li> <li><a href="/w/index.php?title=Vanadium(I)_hydride&action=edit&redlink=1" class="new" title="Vanadium(I) hydride (page does not exist)">VH</a></li> <li><a href="/w/index.php?title=Vanadium(II)_hydride&action=edit&redlink=1" class="new" title="Vanadium(II) hydride (page does not exist)">VH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Niobium_monohydride&action=edit&redlink=1" class="new" title="Niobium monohydride (page does not exist)">NbH</a></li> <li><a href="/w/index.php?title=Niobium_dihydride&action=edit&redlink=1" class="new" title="Niobium dihydride (page does not exist)">NbH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Tantalum_monohydride&action=edit&redlink=1" class="new" title="Tantalum monohydride (page does not exist)">TaH</a></li> <li><a href="/w/index.php?title=Tantalum_dihydride&action=edit&redlink=1" class="new" title="Tantalum dihydride (page does not exist)">TaH<sub>2</sub></a></li> <li><a href="/wiki/Chromium(I)_hydride" title="Chromium(I) hydride">CrH</a></li> <li><a href="/wiki/Chromium(II)_hydride" title="Chromium(II) hydride">CrH<sub>2</sub></a></li> <li><a href="/wiki/Chromium_hydride" title="Chromium hydride">CrH<sub>x</sub></a></li> <li><a href="/wiki/Iron(I)_hydride" title="Iron(I) hydride">FeH</a></li> <li><a href="/wiki/Iron(II)_hydride" title="Iron(II) hydride">FeH<sub>2</sub></a></li> <li><a href="/wiki/Iron_pentahydride" title="Iron pentahydride">FeH<sub>5</sub></a></li> <li><a href="/wiki/Cobalt(II)_hydride" title="Cobalt(II) hydride">CoH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Rhodium_hydride&action=edit&redlink=1" class="new" title="Rhodium hydride (page does not exist)">RhH<sub>2</sub></a></li> <li><a href="/wiki/Iridium_trihydride" title="Iridium trihydride">IrH<sub>3</sub></a></li> <li><a href="/wiki/Nickel_hydride" title="Nickel hydride">NiH</a></li> <li><a href="/wiki/Palladium_hydride" title="Palladium hydride">PdH<sub><i>x</i></sub> (<i>x</i> < 1)</a></li> <li><a href="/w/index.php?title=Platinum_hydride&action=edit&redlink=1" class="new" title="Platinum hydride (page does not exist)">PtH<sub><i>x</i></sub> (<i>x</i>< 1) </a></li> <li><i><a href="/wiki/Darmstadtium" title="Darmstadtium">DsH<sub>2</sub></a></i> (<i>predicted</i>)</li> <li><a href="/wiki/Copper_hydride" title="Copper hydride">CuH</a></li> <li><i><a href="/wiki/Roentgenium" title="Roentgenium">RgH</a></i> (<i>predicted</i>)</li> <li><a href="/wiki/Zinc_hydride" title="Zinc hydride">ZnH<sub>2</sub></a></li> <li><a href="/wiki/Cadmium_hydride" title="Cadmium hydride">CdH<sub>2</sub></a></li> <li><a href="/wiki/Mercury(I)_hydride" title="Mercury(I) hydride">HgH</a></li> <li><a href="/wiki/Mercury(I)_hydride" title="Mercury(I) hydride">Hg<sub>2</sub>H<sub>2</sub></a></li> <li><a href="/wiki/Mercury(II)_hydride" title="Mercury(II) hydride">HgH<sub>2</sub></a></li> <li><i><a href="/wiki/Copernicium" title="Copernicium">CnH<sub>2</sub></a></i> (<i>predicted</i>)</li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/w/index.php?title=Lanthanide_hydrides&action=edit&redlink=1" class="new" title="Lanthanide hydrides (page does not exist)">Lanthanide hydrides</a></th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/w/index.php?title=Lanthanum_dihydride&action=edit&redlink=1" class="new" title="Lanthanum dihydride (page does not exist)">LaH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Lanthanum_trihydride&action=edit&redlink=1" class="new" title="Lanthanum trihydride (page does not exist)">LaH<sub>3</sub></a></li> <li><a href="/wiki/Lanthanum_decahydride" title="Lanthanum decahydride">LaH<sub>10</sub></a></li> <li><a href="/w/index.php?title=Cerium_dihydride&action=edit&redlink=1" class="new" title="Cerium dihydride (page does not exist)">CeH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Cerium_trihydride&action=edit&redlink=1" class="new" title="Cerium trihydride (page does not exist)">CeH<sub>3</sub></a></li> <li><a href="/w/index.php?title=Praseodymium_dihydride&action=edit&redlink=1" class="new" title="Praseodymium dihydride (page does not exist)">PrH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Praseodymium_hydride&action=edit&redlink=1" class="new" title="Praseodymium hydride (page does not exist)">PrH<sub>3</sub></a></li> <li><a href="/wiki/Neodymium(II)_hydride" title="Neodymium(II) hydride">NdH<sub>2</sub></a></li> <li><a href="/wiki/Neodymium(III)_hydride" title="Neodymium(III) hydride">NdH<sub>3</sub></a></li> <li><a href="/w/index.php?title=Samarium_dihydride&action=edit&redlink=1" class="new" title="Samarium dihydride (page does not exist)">SmH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Samarium_trihydride&action=edit&redlink=1" class="new" title="Samarium trihydride (page does not exist)">SmH<sub>3</sub></a></li> <li><a href="/wiki/Europium_hydride" title="Europium hydride">EuH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Gadolinium_dihydride&action=edit&redlink=1" class="new" title="Gadolinium dihydride (page does not exist)">GdH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Gadolinium_trihydride&action=edit&redlink=1" class="new" title="Gadolinium trihydride (page does not exist)">GdH<sub>3</sub></a></li> <li><a href="/w/index.php?title=Terbium_dihydride&action=edit&redlink=1" class="new" title="Terbium dihydride (page does not exist)">TbH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Terbium_trihydride&action=edit&redlink=1" class="new" title="Terbium trihydride (page does not exist)">TbH<sub>3</sub></a></li> <li><a href="/w/index.php?title=Dysprosium_dihydride&action=edit&redlink=1" class="new" title="Dysprosium dihydride (page does not exist)">DyH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Dysprosium_trihydride&action=edit&redlink=1" class="new" title="Dysprosium trihydride (page does not exist)">DyH<sub>3</sub></a></li> <li><a href="/w/index.php?title=Holmium_dihydride&action=edit&redlink=1" class="new" title="Holmium dihydride (page does not exist)">HoH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Holmium_trihydride&action=edit&redlink=1" class="new" title="Holmium trihydride (page does not exist)">HoH<sub>3</sub></a></li> <li><a href="/w/index.php?title=Erbium_dihydride&action=edit&redlink=1" class="new" title="Erbium dihydride (page does not exist)">ErH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Erbium_trihydride&action=edit&redlink=1" class="new" title="Erbium trihydride (page does not exist)">ErH<sub>3</sub></a></li> <li><a href="/w/index.php?title=Thulium_dihydride&action=edit&redlink=1" class="new" title="Thulium dihydride (page does not exist)">TmH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Thulium_trihydride&action=edit&redlink=1" class="new" title="Thulium trihydride (page does not exist)">TmH<sub>3</sub></a></li> <li><a href="/wiki/Ytterbium(II)_hydride" title="Ytterbium(II) hydride">YbH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Lutetium_dihydride&action=edit&redlink=1" class="new" title="Lutetium dihydride (page does not exist)">LuH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Lutetium_trihydride&action=edit&redlink=1" class="new" title="Lutetium trihydride (page does not exist)">LuH<sub>3</sub></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/w/index.php?title=Actinide_hydrides&action=edit&redlink=1" class="new" title="Actinide hydrides (page does not exist)">Actinide hydrides</a></th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/w/index.php?title=Actinium_dihydride&action=edit&redlink=1" class="new" title="Actinium dihydride (page does not exist)">AcH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Thorium_hydride&action=edit&redlink=1" class="new" title="Thorium hydride (page does not exist)">ThH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Thorium(IV)_hydride&action=edit&redlink=1" class="new" title="Thorium(IV) hydride (page does not exist)">ThH<sub>4</sub></a></li> <li>Th<sub>4</sub>H<sub>15</sub></li> <li><a href="/wiki/Protactinium_trihydride" title="Protactinium trihydride">PaH<sub>3</sub></a></li> <li><a href="/wiki/Uranium(III)_hydride" title="Uranium(III) hydride">UH<sub>3</sub></a></li> <li><a href="/wiki/Uranium(IV)_hydride" title="Uranium(IV) hydride">UH<sub>4</sub></a></li> <li><a href="/w/index.php?title=Neptunium_dihydride&action=edit&redlink=1" class="new" title="Neptunium dihydride (page does not exist)">NpH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Neptunium_trihydride&action=edit&redlink=1" class="new" title="Neptunium trihydride (page does not exist)">NpH<sub>3</sub></a></li> <li><a href="/wiki/Plutonium_hydride" title="Plutonium hydride">PuH<sub>2</sub></a></li> <li><a href="/wiki/Plutonium_hydride" title="Plutonium hydride">PuH<sub>3</sub></a></li> <li><a href="/w/index.php?title=Americium_dihydride&action=edit&redlink=1" class="new" title="Americium dihydride (page does not exist)">AmH<sub>2</sub></a></li> <li><a href="/wiki/Americium_trihydride" title="Americium trihydride">AmH<sub>3</sub></a></li> <li><a href="/w/index.php?title=Curium_hydride&action=edit&redlink=1" class="new" title="Curium hydride (page does not exist)">CmH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Berkelium_dihydride&action=edit&redlink=1" class="new" title="Berkelium dihydride (page does not exist)">BkH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Berkelium_trihydride&action=edit&redlink=1" class="new" title="Berkelium trihydride (page does not exist)">BkH<sub>3</sub></a></li> <li><a href="/w/index.php?title=Californium_dihydride&action=edit&redlink=1" class="new" title="Californium dihydride (page does not exist)">CfH<sub>2</sub></a></li> <li><a href="/w/index.php?title=Californium_trihydride&action=edit&redlink=1" class="new" title="Californium trihydride (page does not exist)">CfH<sub>3</sub></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Exotic_atoms" class="mw-redirect" title="Exotic atoms">Exotic matter hydrides</a></th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Positronium_hydride" title="Positronium hydride">PsH</a></li></ul> </div></td></tr></tbody></table></div> <div class="navbox-styles"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1129693374"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1236075235"><style data-mw-deduplicate="TemplateStyles:r1038841319">.mw-parser-output .tooltip-dotted{border-bottom:1px dotted;cursor:help}</style></div><div role="navigation" class="navbox authority-control" aria-label="Navbox" style="padding:3px"><table class="nowraplinks hlist navbox-inner" style="border-spacing:0;background:transparent;color:inherit"><tbody><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Help:Authority_control" title="Help:Authority control">Authority control databases</a>: National <span class="mw-valign-text-top noprint" typeof="mw:File/Frameless"><a href="https://www.wikidata.org/wiki/Q412361#identifiers" title="Edit this at Wikidata"><img alt="Edit this at Wikidata" src="//upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/10px-OOjs_UI_icon_edit-ltr-progressive.svg.png" decoding="async" width="10" height="10" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/15px-OOjs_UI_icon_edit-ltr-progressive.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/20px-OOjs_UI_icon_edit-ltr-progressive.svg.png 2x" data-file-width="20" data-file-height="20" /></a></span></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"><ul><li><span class="uid"><a rel="nofollow" class="external text" href="https://d-nb.info/gnd/4142120-6">Germany</a></span></li><li><span class="uid"><span class="rt-commentedText tooltip tooltip-dotted" title="hydrid hliníku"><a rel="nofollow" class="external text" href="https://aleph.nkp.cz/F/?func=find-c&local_base=aut&ccl_term=ica=ph120964&CON_LNG=ENG">Czech Republic</a></span></span></li></ul></div></td></tr></tbody></table></div>    </div><noscript><img src="https://login.wikimedia.org/wiki/Special:CentralAutoLogin/start?type=1x1" alt="" width="1" height="1" style="border: none; position: absolute;"></noscript> <div class="printfooter" data-nosnippet="">Retrieved from "<a dir="ltr" href="https://en.wikipedia.org/w/index.php?title=Aluminium_hydride&oldid=1250227833">https://en.wikipedia.org/w/index.php?title=Aluminium_hydride&oldid=1250227833</a>"</div></div> <div id="catlinks" class="catlinks" data-mw="interface"><div id="mw-normal-catlinks" class="mw-normal-catlinks"><a href="/wiki/Help:Category" 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185.505 16 Template:Trim"," 11.18% 157.333 35 Template:Navbox"," 8.83% 124.178 1 Template:Chembox_Properties"," 7.98% 112.232 16 Template:Fix"," 6.80% 95.710 64 Template:Main_other"]},"scribunto":{"limitreport-timeusage":{"value":"0.665","limit":"10.000"},"limitreport-memusage":{"value":13079846,"limit":52428800},"limitreport-logs":"anchor_id_list = table#1 {\n [\"CITEREFAlpatova,_N._M.Dymova,_T._N.Kessler,_Yu._M.Osipov,_O._R.1968\"] = 1,\n [\"CITEREFAndrewsWang2003\"] = 1,\n [\"CITEREFAtwood,_J._L.Bennett,_F._R.Elms,_F._M.Jones,_C.1991\"] = 1,\n [\"CITEREFAyres,_D._C.Sawdaye,_R.1967\"] = 1,\n [\"CITEREFBrower,_F._M.Matzek,_N._E.Reigler,_P._F.Rinn,_H._W.1976\"] = 1,\n [\"CITEREFBrown,_H._C.Krishnamurthy,_S.1979\"] = 1,\n [\"CITEREFCalabro2011\"] = 1,\n [\"CITEREFClaesson,_A.Olsson,_L.-I.1979\"] = 1,\n [\"CITEREFClasen,_H.1962\"] = 1,\n [\"CITEREFCorey,_E._J.Cane,_D._E.1971\"] = 1,\n [\"CITEREFCorey,_E._J.Katzenellenbogen,_J._A.Posner,_G._H.1967\"] = 1,\n [\"CITEREFFinholt,_A._E.Bond,_A._C._Jr.Schlesinger,_H._I.1947\"] = 1,\n [\"CITEREFGalatsis,_P.2001\"] = 1,\n [\"CITEREFGalatsisSintimWang2008\"] = 1,\n [\"CITEREFGraetz,_J..Reilly,_J..Sandrock,_G..Johnson,_J..2006\"] = 1,\n [\"CITEREFHousecroft2018\"] = 1,\n [\"CITEREFHousecroftSharpe2018\"] = 1,\n [\"CITEREFJorgenson1962\"] = 1,\n [\"CITEREFKurth,_F._A.Eberlein,_R._A.Schnöckel,_H.-G.Downs,_A._J.1993\"] = 1,\n [\"CITEREFLin-Lin_WangAditi_HerwadkarJason_M._ReichDuane_D._Johnson2016\"] = 1,\n [\"CITEREFLiuYangZhangWu2024\"] = 1,\n [\"CITEREFLund,_G._K.;_Hanks,_J._M.;_Johnston,_H._E.\"] = 1,\n [\"CITEREFMartinez-Rodriguez,_M._J.Garcia-Diaz,_B._L.Teprovich,_J._A.Knight,_D._A.2012\"] = 1,\n [\"CITEREFMaruoka,_K.Saito,_S.Ooi,_T.Yamamoto,_H.1991\"] = 1,\n [\"CITEREFOsipov,_O._R.Alpatova,_N._M.Kessler,_Yu._M.1966\"] = 1,\n [\"CITEREFPaquetteOllevierDesyroy2004\"] = 1,\n [\"CITEREFPetrie,_M._A.;_Bottaro,_J._C.;_Schmitt,_R._J.;_Penwell,_P._E.;_Bomberger,_D._C.2001\"] = 1,\n [\"CITEREFPulham,_C._R.Downs,_A._J.Goode,_M._J.Rankin_D._W._H.1991\"] = 1,\n [\"CITEREFRichter,_W._J.1981\"] = 1,\n [\"CITEREFSaitohSakuraiMachidaKatayama2010\"] = 1,\n [\"CITEREFSato,_F.Sato,_S.Kodama,_H.Sato,_M.1977\"] = 1,\n [\"CITEREFSchmidt,_D._L.Roberts,_C._B.Reigler,_P._F.Lemanski,_M._F._Jr.1973\"] = 1,\n [\"CITEREFSemenenko,_K._N.Bulychev,_B._M.Shevlyagina,_E._A.1966\"] = 1,\n [\"CITEREFSuárez-Alcántara,_KarinaTena-Garcia,_Juan_RogelioGuerrero-Ortiz,_Ricardo2019\"] = 1,\n [\"CITEREFTakano,_S.Akiyama,_M.Sato,_S.Ogasawara,_K.1983\"] = 1,\n [\"CITEREFTaydakov2020\"] = 1,\n [\"CITEREFTurleyRinn1969\"] = 1,\n [\"CITEREFYun,_J.-H.Kim,_B.-Y.Rhee,_S.-W.1998\"] = 1,\n [\"CITEREFZidan,_R.2013\"] = 1,\n [\"CITEREFZidan,_R.Garcia-Diaz,_B._L.Fewox,_C._S.Stowe,_A._C.2009\"] = 1,\n}\ntemplate_list = table#1 {\n [\"Aluminium compounds\"] = 1,\n [\"Authority control\"] = 1,\n [\"Better source\"] = 1,\n [\"Cascite\"] = 1,\n [\"Chem\"] = 4,\n [\"Chem2\"] = 35,\n [\"Chembox\"] = 1,\n [\"Chembox Identifiers\"] = 1,\n [\"Chembox Properties\"] = 1,\n [\"Chembox Related\"] = 1,\n [\"Chembox Thermochemistry\"] = 1,\n [\"Chemspidercite\"] = 2,\n [\"Citation needed lead\"] = 2,\n [\"Cite book\"] = 5,\n [\"Cite encyclopedia\"] = 1,\n [\"Cite journal\"] = 29,\n [\"Cite patent\"] = 4,\n [\"Cite report\"] = 1,\n [\"Cn\"] = 9,\n [\"Convert\"] = 2,\n [\"Dead link\"] = 1,\n [\"Doi\"] = 1,\n [\"Ebicite\"] = 1,\n [\"Expand section\"] = 1,\n [\"Fdacite\"] = 1,\n [\"Greenwood\u0026Earnshaw\"] = 1,\n [\"Harvid\"] = 2,\n [\"Harvnb\"] = 3,\n [\"Hydrides by group\"] = 1,\n [\"Needs expansion\"] = 1,\n [\"Primary source inline\"] = 1,\n [\"Primary src inline\"] = 1,\n [\"Refimprove section\"] = 1,\n [\"See also\"] = 1,\n [\"Stdinchicite\"] = 2,\n [\"Ubl\"] = 1,\n [\"Update\"] = 1,\n [\"Update after\"] = 1,\n [\"Use British English\"] = 1,\n [\"What\"] = 1,\n [\"Why\"] = 1,\n}\narticle_whitelist = table#1 {\n}\n"},"cachereport":{"origin":"mw-web.codfw.main-f69cdc8f6-g2dn4","timestamp":"20241124164113","ttl":26341,"transientcontent":true}}});});</script> <script type="application/ld+json">{"@context":"https:\/\/schema.org","@type":"Article","name":"Aluminium hydride","url":"https:\/\/en.wikipedia.org\/wiki\/Aluminium_hydride","sameAs":"http:\/\/www.wikidata.org\/entity\/Q412361","mainEntity":"http:\/\/www.wikidata.org\/entity\/Q412361","author":{"@type":"Organization","name":"Contributors to Wikimedia projects"},"publisher":{"@type":"Organization","name":"Wikimedia Foundation, Inc.","logo":{"@type":"ImageObject","url":"https:\/\/www.wikimedia.org\/static\/images\/wmf-hor-googpub.png"}},"datePublished":"2006-07-20T14:04:11Z","dateModified":"2024-10-09T05:12:14Z","image":"https:\/\/upload.wikimedia.org\/wikipedia\/commons\/4\/46\/Aluminium-hydride-unit-cell-3D-vdW.png","headline":"chemical compound"}</script> </body> </html>