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六羰基铬 - 维基百科,自由的百科全书
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id="firstHeading" class="firstHeading mw-first-heading"><span class="mw-page-title-main">六羰基铬</span></h1> <div id="p-lang-btn" class="vector-dropdown mw-portlet mw-portlet-lang" > <input type="checkbox" id="p-lang-btn-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-p-lang-btn" class="vector-dropdown-checkbox mw-interlanguage-selector" aria-label="前往另一种语言写成的文章。16种语言可用" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-16" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">16种语言</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D8%B3%D8%AF%D8%A7%D8%B3%D9%8A_%D9%83%D8%B1%D8%A8%D9%88%D9%86%D9%8A%D9%84_%D8%A7%D9%84%D9%83%D8%B1%D9%88%D9%85" title="سداسي كربونيل الكروم – 阿拉伯语" lang="ar" hreflang="ar" data-title="سداسي كربونيل الكروم" data-language-autonym="العربية" data-language-local-name="阿拉伯语" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-azb mw-list-item"><a href="https://azb.wikipedia.org/wiki/%DA%A9%D9%88%D8%B1%D9%88%D9%85_%D9%87%D9%82%D8%B2%D8%A7%DA%A9%D8%B1%D8%A8%D9%88%D9%86%DB%8C%D9%84" title="کوروم هقزاکربونیل – South Azerbaijani" lang="azb" hreflang="azb" data-title="کوروم هقزاکربونیل" data-language-autonym="تۆرکجه" data-language-local-name="South Azerbaijani" class="interlanguage-link-target"><span>تۆرکجه</span></a></li><li class="interlanguage-link interwiki-cs mw-list-item"><a href="https://cs.wikipedia.org/wiki/Hexakarbonyl_chromu" title="Hexakarbonyl chromu – 捷克语" lang="cs" hreflang="cs" data-title="Hexakarbonyl chromu" data-language-autonym="Čeština" data-language-local-name="捷克语" class="interlanguage-link-target"><span>Čeština</span></a></li><li class="interlanguage-link interwiki-de mw-list-item"><a href="https://de.wikipedia.org/wiki/Chromhexacarbonyl" title="Chromhexacarbonyl – 德语" lang="de" hreflang="de" data-title="Chromhexacarbonyl" data-language-autonym="Deutsch" data-language-local-name="德语" class="interlanguage-link-target"><span>Deutsch</span></a></li><li class="interlanguage-link interwiki-en mw-list-item"><a href="https://en.wikipedia.org/wiki/Chromium_hexacarbonyl" title="Chromium hexacarbonyl – 英语" lang="en" hreflang="en" data-title="Chromium hexacarbonyl" data-language-autonym="English" data-language-local-name="英语" class="interlanguage-link-target"><span>English</span></a></li><li class="interlanguage-link interwiki-es mw-list-item"><a href="https://es.wikipedia.org/wiki/Hexacarbonilo_de_cromo" title="Hexacarbonilo de cromo – 西班牙语" lang="es" hreflang="es" data-title="Hexacarbonilo de cromo" data-language-autonym="Español" data-language-local-name="西班牙语" class="interlanguage-link-target"><span>Español</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%DA%A9%D8%B1%D9%88%D9%85_%D9%87%DA%AF%D8%B2%D8%A7%DA%A9%D8%B1%D8%A8%D9%88%D9%86%DB%8C%D9%84" title="کروم هگزاکربونیل – 波斯语" lang="fa" hreflang="fa" data-title="کروم هگزاکربونیل" data-language-autonym="فارسی" data-language-local-name="波斯语" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fi mw-list-item"><a href="https://fi.wikipedia.org/wiki/Kromikarbonyyli" title="Kromikarbonyyli – 芬兰语" lang="fi" hreflang="fi" data-title="Kromikarbonyyli" data-language-autonym="Suomi" data-language-local-name="芬兰语" class="interlanguage-link-target"><span>Suomi</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/Hexacarbonyle_de_chrome" title="Hexacarbonyle de chrome – 法语" lang="fr" hreflang="fr" data-title="Hexacarbonyle de chrome" data-language-autonym="Français" data-language-local-name="法语" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-it mw-list-item"><a href="https://it.wikipedia.org/wiki/Esacarbonilcromo" title="Esacarbonilcromo – 意大利语" lang="it" hreflang="it" data-title="Esacarbonilcromo" data-language-autonym="Italiano" data-language-local-name="意大利语" class="interlanguage-link-target"><span>Italiano</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E3%83%98%E3%82%AD%E3%82%B5%E3%82%AB%E3%83%AB%E3%83%9C%E3%83%8B%E3%83%AB%E3%82%AF%E3%83%AD%E3%83%A0" title="ヘキサカルボニルクロム – 日语" lang="ja" hreflang="ja" data-title="ヘキサカルボニルクロム" data-language-autonym="日本語" data-language-local-name="日语" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-nl mw-list-item"><a href="https://nl.wikipedia.org/wiki/Chroomhexacarbonyl" title="Chroomhexacarbonyl – 荷兰语" lang="nl" hreflang="nl" data-title="Chroomhexacarbonyl" data-language-autonym="Nederlands" data-language-local-name="荷兰语" class="interlanguage-link-target"><span>Nederlands</span></a></li><li class="interlanguage-link interwiki-ru mw-list-item"><a href="https://ru.wikipedia.org/wiki/%D0%93%D0%B5%D0%BA%D1%81%D0%B0%D0%BA%D0%B0%D1%80%D0%B1%D0%BE%D0%BD%D0%B8%D0%BB_%D1%85%D1%80%D0%BE%D0%BC%D0%B0" title="Гексакарбонил хрома – 俄语" lang="ru" hreflang="ru" data-title="Гексакарбонил хрома" data-language-autonym="Русский" data-language-local-name="俄语" class="interlanguage-link-target"><span>Русский</span></a></li><li class="interlanguage-link interwiki-sh mw-list-item"><a href="https://sh.wikipedia.org/wiki/Hrom_heksakarbonil" title="Hrom heksakarbonil – 塞尔维亚-克罗地亚语" lang="sh" hreflang="sh" data-title="Hrom heksakarbonil" data-language-autonym="Srpskohrvatski / српскохрватски" data-language-local-name="塞尔维亚-克罗地亚语" class="interlanguage-link-target"><span>Srpskohrvatski / српскохрватски</span></a></li><li class="interlanguage-link interwiki-sr mw-list-item"><a href="https://sr.wikipedia.org/wiki/Hrom_heksakarbonil" title="Hrom heksakarbonil – 塞尔维亚语" lang="sr" hreflang="sr" data-title="Hrom heksakarbonil" data-language-autonym="Српски / srpski" data-language-local-name="塞尔维亚语" class="interlanguage-link-target"><span>Српски / srpski</span></a></li><li class="interlanguage-link interwiki-uk mw-list-item"><a href="https://uk.wikipedia.org/wiki/%D0%A5%D1%80%D0%BE%D0%BC_%D0%B3%D0%B5%D0%BA%D1%81%D0%B0%D0%BA%D0%B0%D1%80%D0%B1%D0%BE%D0%BD%D1%96%D0%BB" title="Хром гексакарбоніл – 乌克兰语" lang="uk" hreflang="uk" data-title="Хром гексакарбоніл" data-language-autonym="Українська" data-language-local-name="乌克兰语" class="interlanguage-link-target"><span>Українська</span></a></li> </ul> <div 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</div> </div> </div> </div> </nav> </div> </div> </div> <div class="vector-column-end"> <div class="vector-sticky-pinned-container"> <nav class="vector-page-tools-landmark" aria-label="页面工具"> <div id="vector-page-tools-pinned-container" class="vector-pinned-container"> </div> </nav> <nav class="vector-appearance-landmark" aria-label="外观"> <div id="vector-appearance-pinned-container" class="vector-pinned-container"> <div id="vector-appearance" class="vector-appearance vector-pinnable-element"> <div class="vector-pinnable-header vector-appearance-pinnable-header vector-pinnable-header-pinned" data-feature-name="appearance-pinned" data-pinnable-element-id="vector-appearance" data-pinned-container-id="vector-appearance-pinned-container" data-unpinned-container-id="vector-appearance-unpinned-container" > <div class="vector-pinnable-header-label">外观</div> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-pin-button" data-event-name="pinnable-header.vector-appearance.pin">移至侧栏</button> <button class="vector-pinnable-header-toggle-button vector-pinnable-header-unpin-button" data-event-name="pinnable-header.vector-appearance.unpin">隐藏</button> </div> </div> </div> </nav> </div> </div> <div id="bodyContent" class="vector-body" aria-labelledby="firstHeading" data-mw-ve-target-container> <div class="vector-body-before-content"> <div class="mw-indicators"> </div> <div id="siteSub" class="noprint">维基百科,自由的百科全书</div> </div> <div id="contentSub"><div id="mw-content-subtitle"></div></div> <div id="mw-content-text" class="mw-body-content"><div class="mw-content-ltr mw-parser-output" lang="zh" dir="ltr"><style data-mw-deduplicate="TemplateStyles:r84001320">.mw-parser-output .ib-chembox{border-collapse:collapse;text-align:left}.mw-parser-output .ib-chembox td,.mw-parser-output .ib-chembox th{border:1px solid #a2a9b1;width:40%}.mw-parser-output .ib-chembox td+td{width:60%}</style> <table class="infobox ib-chembox nounderlines" cellspacing="0" cellpadding="3" rules="all" style="background-color:#f0f0f0; float:right; margin: 0 0 1em 1em; border-color: #aaaaaa; border-style:solid; border:1px; border-collapse:collapse; empty-cells:show; width:305px; font-size:90%;"> <tbody><tr> <th colspan="2" style="font-size:120%; text-align:center; background:#d6e0dc;">六羰基铬 </th></tr> <tr> <td colspan="2" style="background:#ffffff; text-align:center;"><span typeof="mw:File"><a href="/wiki/File:Cr(CO)6.png" class="mw-file-description"><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/c/cf/Cr%28CO%296.png/150px-Cr%28CO%296.png" decoding="async" width="150" height="154" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/c/cf/Cr%28CO%296.png/225px-Cr%28CO%296.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/c/cf/Cr%28CO%296.png/300px-Cr%28CO%296.png 2x" data-file-width="675" data-file-height="692" /></a></span> </td></tr> <tr> <td colspan="2" style="background:#ffffff; text-align:center;"><span typeof="mw:File"><a href="/wiki/File:Chromium_hexacarbonyl.png" class="mw-file-description"><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/b/ba/Chromium_hexacarbonyl.png/200px-Chromium_hexacarbonyl.png" decoding="async" width="200" height="127" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/b/ba/Chromium_hexacarbonyl.png/300px-Chromium_hexacarbonyl.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/b/ba/Chromium_hexacarbonyl.png/400px-Chromium_hexacarbonyl.png 2x" data-file-width="1470" data-file-height="934" /></a></span> </td></tr> <tr> <td colspan="2" style="max-width:305px; word-wrap: break-word; text-align: center;"><a href="/wiki/IUPAC%E5%91%BD%E5%90%8D%E6%B3%95" title="IUPAC命名法">IUPAC名</a><br />六羰基铬(0) </td></tr> <tr> <td>别名 </td> <td>羰基铬 </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">识别 </th></tr> <tr> <td><a href="/wiki/CAS%E5%8F%B7" title="CAS号">CAS号</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=13007-92-6">13007-92-6</a></span> <sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup> </td></tr> <tr> <td><a href="/wiki/PubChem" title="PubChem">PubChem</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="https://pubchem.ncbi.nlm.nih.gov/compound/518677">518677</a></span> </td></tr> <tr> <td><a href="/wiki/ChemSpider" title="ChemSpider">ChemSpider</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="http://www.chemspider.com/23855">23855</a></span> </td></tr> <tr> <td><a href="/wiki/SMILES" class="mw-redirect" title="SMILES">SMILES</a> </td> <td><div style="word-break:break-all;"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold;"><div> </div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0;"><li style="line-height: inherit; margin: 0"><span lang="en">[Cr].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-]</span></li></ul> </div></div> </td></tr> <tr> <td><a href="/wiki/%E5%9B%BD%E9%99%85%E5%8C%96%E5%90%88%E7%89%A9%E6%A0%87%E8%AF%86" title="国际化合物标识">InChI</a> </td> <td><div style="word-break:break-all;"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold;"><div> </div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0;"><li style="line-height: inherit; margin: 0">1/6CO.Cr/c6*1-2;</li></ul> </div></div> </td></tr> <tr> <td><a href="/wiki/%E5%9B%BD%E9%99%85%E5%8C%96%E5%90%88%E7%89%A9%E6%A0%87%E8%AF%86" title="国际化合物标识">InChIKey</a> </td> <td><small>KOTQLLUQLXWWDK-UHFFFAOYAN</small> </td></tr> <tr> <td><a href="/wiki/ChEBI" title="ChEBI">ChEBI</a> </td> <td><span class="reflink plainlinks nourlexpansion"><a rel="nofollow" class="external text" href="http://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:33031">33031</a></span> </td></tr> <tr> <td><a href="/wiki/%E5%8C%96%E5%AD%A6%E7%89%A9%E8%B4%A8%E6%AF%92%E6%80%A7%E6%95%B0%E6%8D%AE%E5%BA%93" title="化学物质毒性数据库">RTECS</a> </td> <td>GB5075000 </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">性质 </th></tr> <tr> <td><a href="/wiki/%E5%8C%96%E5%AD%A6%E5%BC%8F" title="化学式">化学式</a> </td> <td><span lang="en">C<sub>6</sub>CrO<sub>6</sub></span> </td></tr> <tr> <td><a href="/wiki/%E6%91%A9%E5%B0%94%E8%B4%A8%E9%87%8F" title="摩尔质量">摩尔质量</a> </td> <td>220.057 g/mol g·mol⁻¹ </td></tr> <tr> <td>外观 </td> <td>无色晶体 </td></tr> <tr> <td><a href="/wiki/%E5%AF%86%E5%BA%A6" title="密度">密度</a> </td> <td>1.77 g/cm<sup>3</sup>(固体) </td></tr> <tr> <td><a href="/wiki/%E7%86%94%E7%82%B9" title="熔点">熔点</a> </td> <td>90 °C(363 K) </td></tr> <tr> <td><a href="/wiki/%E6%B2%B8%E7%82%B9" title="沸点">沸点</a> </td> <td>210 °C(483 K)((分解)) </td></tr> <tr> <td><a href="/wiki/%E6%BA%B6%E8%A7%A3%E6%80%A7" class="mw-redirect" title="溶解性">溶解性</a>(<a href="/wiki/%E6%B0%B4" title="水">水</a>) </td> <td>难溶 </td></tr> <tr> <td><a href="/wiki/%E6%BA%B6%E8%A7%A3%E6%80%A7" class="mw-redirect" title="溶解性">溶解性</a> </td> <td>可溶于<a href="/wiki/%E4%B9%99%E9%86%9A" title="乙醚">乙醚</a>, <a href="/wiki/%E6%B0%AF%E4%BB%BF" title="氯仿">氯仿</a>, <a href="/wiki/%E5%9B%9B%E6%B0%A2%E5%90%A1%E5%96%83" title="四氢吡喃">四氢吡喃</a> (THP), <a href="/wiki/%E4%BA%8C%E6%B0%AF%E7%94%B2%E7%83%B7" title="二氯甲烷">二氯甲烷</a> </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">结构 </th></tr> <tr> <td><a href="/wiki/%E6%99%B6%E4%BD%93%E7%BB%93%E6%9E%84" title="晶体结构">晶体结构</a> </td> <td>orthrhombic </td></tr> <tr> <td><a href="/wiki/%E9%85%8D%E5%90%88%E7%89%A9%E7%BB%93%E6%9E%84" title="配合物结构">配位几何</a> </td> <td>octahedral </td></tr> <tr> <td><a href="/wiki/%E5%81%B6%E6%A5%B5%E5%AD%90#分子的電偶極矩" title="偶極子">偶极矩</a> </td> <td>0 <a href="/wiki/Debye" class="mw-redirect" title="Debye">D</a> </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">危险性 </th></tr> <tr> <td><a href="/wiki/%E5%8C%96%E5%AD%A6%E5%93%81%E5%AE%89%E5%85%A8%E8%AF%B4%E6%98%8E%E4%B9%A6" class="mw-redirect" title="化学品安全说明书">MSDS</a> </td> <td><a rel="nofollow" class="external text" href="http://msds.chem.ox.ac.uk/HE/hexacarbonyl_chromium.html">Oxford MSDS</a> </td></tr> <tr> <td>欧盟编号 </td> <td>未列出 </td></tr> <tr> <td>主要危害 </td> <td>有毒 </td></tr> <tr> <td><a href="/wiki/NFPA_704" title="NFPA 704">NFPA 704</a> </td> <td> <div style="position: relative; height: 85px; width: 75px;"> <div style="position: absolute; height: 75px; width: 75px;"><span typeof="mw:File"><a href="/wiki/File:NFPA_704.svg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/6/6f/NFPA_704.svg/75px-NFPA_704.svg.png" decoding="async" width="75" height="75" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/6/6f/NFPA_704.svg/113px-NFPA_704.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/6/6f/NFPA_704.svg/150px-NFPA_704.svg.png 2x" data-file-width="512" data-file-height="512" /></a></span></div> <div title="可燃性" style="background: transparent; width: 75px; height: 2em; text-align: center; vertical-align: middle; position: absolute; top: 3px; font-size: large;"><span class="abbr" style="color: black;" title="可燃性1級。必須預熱才可能引燃(如菜籽油)。閃點高於93°C。"><b>1</b></span></div> <div title="健康" style="background: transparent; width: 37.5px; height: 2em; text-align: center; vertical-align: middle; position: absolute; top: 21px; font-size: large;"><span class="abbr" style="color: black;" title="健康危險2級。高濃度或持續性暴露可能導致暫時失去行為能力或可能造成持續性傷害(如氯仿)。"><b>2</b></span></div> <div title="反應性" style="background: transparent; width: 37.5px; height: 2em; text-align: center; vertical-align: middle; position: absolute; top: 21px; left: 37.5px; font-size: large;"><span class="abbr" style="color: black;" title="反應性0級。通常情況下穩定,即使暴露於明火中也不反應,並且不與水反應(如液氮)。"><b>0</b></span></div> <div title="其它危險" style="background: transparent; width: 75px; height: 2em; text-align: center; vertical-align: middle; position: absolute; top: 44px; font-size: small;"> </div> </div> </td></tr> <tr> <td colspan="2" style="text-align:left; background-color:#f1f1f1;">致死量或浓度: </td></tr> <tr class="skin-invert" style="background:#f1f1f1;"> <td style="padding-left:1em;"><div style="padding:0.1em 0;line-height:1.2em;">LD<sub>50</sub>(<a href="/wiki/%E5%8D%8A%E6%95%B8%E8%87%B4%E6%AD%BB%E9%87%8F" title="半數致死量">中位剂量</a>)</div> </td> <td>150 mg/kg (oral, mouse) <br /> 230 mg/kg (oral, rat) </td></tr> <tr> <th style="background:#D6E0DC; text-align:center;" colspan="2">相关物质 </th></tr> <tr> <td>其他<a href="/wiki/%E9%98%B3%E7%A6%BB%E5%AD%90" class="mw-redirect" title="阳离子">阳离子</a> </td> <td><a href="/wiki/%E5%85%AD%E7%BE%B0%E5%9F%BA%E9%92%BC" title="六羰基钼">六羰基钼</a><br /><a href="/wiki/%E5%85%AD%E7%BE%B0%E5%9F%BA%E9%92%A8" title="六羰基钨">六羰基钨</a> </td></tr> <tr> <td>相关化学品 </td> <td><a href="/wiki/%E5%85%AD%E7%BE%B0%E5%9F%BA%E9%92%92" title="六羰基钒">六羰基钒</a><br /><a href="/w/index.php?title=%E5%8D%81%E4%BA%8C%E7%BE%B0%E5%9F%BA%E4%BA%8C%E9%94%B0&action=edit&redlink=1" class="new" title="十二羰基二锰(页面不存在)">十二羰基二锰</a> </td></tr> <tr> <td style="background:#D6E0DC; text-align:center;" colspan="2">若非注明,所有数据均出自<a href="/wiki/%E6%A0%87%E5%87%86%E7%8A%B6%E6%80%81" title="标准状态">标准状态(25 ℃,100 kPa)</a>下。 </td></tr></tbody></table> <p><b>六羰基铬</b>是一种<a href="/wiki/%E9%85%8D%E4%BD%8D%E5%8C%96%E5%90%88%E7%89%A9" class="mw-redirect" title="配位化合物">配位化合物</a>,<a href="/wiki/%E5%8C%96%E5%AD%A6%E5%BC%8F" title="化学式">化学式</a>为 Cr(CO)<sub>6</sub>。它在室温是个固体,并且有着较高的<a href="/wiki/%E8%92%B8%E6%B1%BD%E5%8E%8B" class="mw-redirect" title="蒸汽压">蒸汽压</a>,易升华。六羰基铬中的铬原子的化合价为零。 它是一个均配物,所有羰基是等价的,其结构为八面体,Cr-C和C-O的键长分别是1.91和1.14 Å。.<sup id="cite_ref-1" class="reference"><a href="#cite_note-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="制备方法"><span id=".E5.88.B6.E5.A4.87.E6.96.B9.E6.B3.95"></span>制备方法</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%85%AD%E7%BE%B0%E5%9F%BA%E9%93%AC&action=edit&section=1" title="编辑章节:制备方法"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>利用<a href="/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%93%AC" class="mw-redirect" title="三氯化铬">三氯化铬</a>和溴化苯基镁在<a href="/wiki/%E4%B8%80%E6%B0%A7%E5%8C%96%E7%A2%B3" title="一氧化碳">一氧化碳</a>中制得六羰基铬是最早提出的一种方法:Cr(Cl)<sub>3</sub> + C<sub>6</sub>H<sub>5</sub>MgBr → <a href="/wiki/%E7%BB%9C%E5%90%88%E7%89%A9" class="mw-redirect" title="络合物">络合物</a> → Cr(CO)<sub>6</sub>。早期制备六羰基铬均采用这种方法。 </p><p>这个反应可以采用两种方法。一种是在<a href="/wiki/%E6%AD%A3%E5%8E%8B" title="正压">正压</a>一氧化碳气体中制备。一种是在常压一氧化碳中进行反应。<sup id="cite_ref-2" class="reference"><a href="#cite_note-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="化学性质"><span id=".E5.8C.96.E5.AD.A6.E6.80.A7.E8.B4.A8"></span>化学性质</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%85%AD%E7%BE%B0%E5%9F%BA%E9%93%AC&action=edit&section=2" title="编辑章节:化学性质"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>六羰基铬和同族的<a href="/wiki/%E5%85%AD%E7%BE%B0%E5%9F%BA%E9%92%BC" title="六羰基钼">六羰基钼</a>、<a href="/wiki/%E5%85%AD%E7%BE%B0%E5%9F%BA%E9%92%A8" title="六羰基钨">六羰基钨</a>一样,在光照下,其中的羰基可以被烯烃取代。<sup id="cite_ref-3" class="reference"><a href="#cite_note-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="参考资料"><span id=".E5.8F.82.E8.80.83.E8.B5.84.E6.96.99"></span>参考资料</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%85%AD%E7%BE%B0%E5%9F%BA%E9%93%AC&action=edit&section=3" title="编辑章节:参考资料"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="reflist" style="list-style-type: decimal;"> <ol class="references"> <li id="cite_note-1"><span class="mw-cite-backlink"><b><a href="#cite_ref-1">^</a></b></span> <span class="reference-text">Whitaker A.; Jeffery, J. W. “The Crystal Structure of Chromium Hexacarbonyl” Acta Crystallographica 1967, volume 23, pp. 977-984. <a href="/wiki/DOI" title="DOI">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1107%2FS0365110X67004153">10.1107/S0365110X67004153</a>.</span> </li> <li id="cite_note-2"><span class="mw-cite-backlink"><b><a href="#cite_ref-2">^</a></b></span> <span class="reference-text">黄枢等编. 有机合成试剂制备手册. 北京市:科学出版社, 2005.03. 第65页.</span> </li> <li id="cite_note-3"><span class="mw-cite-backlink"><b><a href="#cite_ref-3">^</a></b></span> <span class="reference-text">《高等配位化学》.朱龙观 主编. 华东理工大学出版社. 5.3.4 金属羰基化合物的反应. P<sub>151</sub>. <a href="/wiki/Special:%E7%BD%91%E7%BB%9C%E4%B9%A6%E6%BA%90/9787562824817" class="internal mw-magiclink-isbn">ISBN 978-7-5628-2481-7</a></span> </li> </ol></div> <div class="mw-heading mw-heading2"><h2 id="扩展链接"><span id=".E6.89.A9.E5.B1.95.E9.93.BE.E6.8E.A5"></span>扩展链接</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=%E5%85%AD%E7%BE%B0%E5%9F%BA%E9%93%AC&action=edit&section=4" title="编辑章节:扩展链接"><span>编辑</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a rel="nofollow" class="external text" href="https://web.archive.org/web/20040225045717/http://www.npi.gov.au/database/substance-info/profiles/24.html">National Pollutant Inventory - Chromium (III) and compounds fact sheet</a></li></ul> <div class="navbox-styles"><style data-mw-deduplicate="TemplateStyles:r84265675">.mw-parser-output .hlist dl,.mw-parser-output .hlist ol,.mw-parser-output .hlist ul{margin:0;padding:0}.mw-parser-output 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style="width:1%">有机铬(0)化合物</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <li><a href="/wiki/%E4%BA%8C%E8%8B%AF%E9%93%AC" title="二苯铬">Cr(C<sub>6</sub>H<sub>6</sub>)<sub>2</sub></a></li> <li><a href="/wiki/%E8%8B%AF%E4%B8%89%E7%BE%B0%E5%9F%BA%E9%93%AC" title="苯三羰基铬">CrC<sub>6</sub>H<sub>6</sub>(CO)<sub>3</sub></a></li> </div></td></tr></tbody></table><div> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">铬(II)</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E8%8D%89%E9%85%B8%E4%BA%9A%E9%93%AC" title="草酸亚铬">Cr(C<sub>2</sub>O<sub>4</sub>)</a></li> <li><a href="/wiki/%E4%B9%99%E9%85%B8%E4%BA%9A%E9%93%AC" title="乙酸亚铬">Cr(CH<sub>3</sub>COO)<sub>2</sub></a></li> <li><a href="/wiki/%E7%A2%98%E5%8C%96%E4%BA%9A%E9%93%AC" title="碘化亚铬">CrI<sub>2</sub></a></li> <li><a href="/wiki/%E4%BA%8C%E6%BA%B4%E5%8C%96%E9%93%AC" title="二溴化铬">CrBr<sub>2</sub></a></li> <li><a href="/wiki/%E6%B0%AF%E5%8C%96%E4%BA%9A%E9%93%AC" title="氯化亚铬">CrCl<sub>2</sub></a></li> <li><a href="/wiki/%E4%BA%8C%E6%B0%9F%E5%8C%96%E9%93%AC" title="二氟化铬">CrF<sub>2</sub></a></li> <li><a href="/wiki/%E4%B8%80%E6%B0%A7%E5%8C%96%E9%93%AC" title="一氧化铬">CrO</a></li> <li><a href="/wiki/%E7%A1%AB%E9%85%B8%E4%BA%9A%E9%93%AC" title="硫酸亚铬">CrSO<sub>4</sub></a></li> <li><a href="/wiki/%E4%B8%80%E7%A1%92%E5%8C%96%E9%93%AC" title="一硒化铬">CrSe</a></li> <li><a href="/wiki/%E4%BA%8C%E7%A1%85%E5%8C%96%E9%93%AC" title="二硅化铬">CrSi<sub>2</sub></a></li> <li><a href="/w/index.php?title=%E7%A2%B3%E5%8C%96%E9%93%AC&action=edit&redlink=1" class="new" title="碳化铬(页面不存在)">Cr<sub>3</sub>C<sub>2</sub></a></li></ul></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="有机铬(II)化合物" scope="row" class="navbox-group" style="width:1%">有机铬(II)化合物</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <li><a href="/wiki/%E4%BA%8C%E8%8C%82%E9%93%AC" title="二茂铬">Cr(C<sub>5</sub>H<sub>5</sub>)<sub>2</sub></a></li> </div></td></tr></tbody></table><div> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">铬(II,III)</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/w/index.php?title=%E7%A2%B3%E5%8C%96%E9%93%AC&action=edit&redlink=1" class="new" title="碳化铬(页面不存在)">Cr<sub>3</sub>C<sub>2</sub></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">铬(III)</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/w/index.php?title=%E7%A1%BC%E5%8C%96%E9%93%AC&action=edit&redlink=1" class="new" title="硼化铬(页面不存在)">CrB</a></li> <li><a href="/wiki/%E6%BA%B4%E5%8C%96%E9%93%AC" title="溴化铬">CrBr<sub>3</sub></a></li> <li><a href="/wiki/%E6%B0%AF%E5%8C%96%E9%93%AC" title="氯化铬">CrCl<sub>3</sub></a></li> <li><a href="/wiki/%E4%B8%89%E6%B0%9F%E5%8C%96%E9%93%AC" title="三氟化铬">CrF<sub>3</sub></a></li> <li><a href="/wiki/%E6%B0%AE%E5%8C%96%E9%93%AC" title="氮化铬">CrN</a></li> <li><a href="/wiki/%E7%A1%9D%E9%85%B8%E9%93%AC" title="硝酸铬">Cr(NO<sub>3</sub>)<sub>3</sub></a></li> <li><a href="/wiki/%E6%B0%A2%E6%B0%A7%E5%8C%96%E9%93%AC" title="氢氧化铬">Cr(OH)<sub>3</sub></a></li> <li><a href="/wiki/%E4%B8%89%E6%B0%A7%E5%8C%96%E4%BA%8C%E9%93%AC" title="三氧化二铬">Cr<sub>2</sub>O<sub>3</sub></a></li> <li><a href="/wiki/%E7%A1%AB%E5%8C%96%E9%93%AC" title="硫化铬">Cr<sub>2</sub>S<sub>3</sub></a></li> <li><a href="/wiki/%E7%A1%AB%E9%85%B8%E9%89%BB" title="硫酸鉻">Cr<sub>2</sub>(SO<sub>4</sub>)<sub>3</sub></a></li> <li><a href="/wiki/%E6%B0%AF%E9%85%B8%E9%93%AC" title="氯酸铬">Cr(ClO<sub>3</sub>)<sub>3</sub></a></li> <li><a href="/wiki/%E9%93%AC%E9%85%B8%E9%93%AC" title="铬酸铬">Cr<sub>2</sub>(CrO<sub>4</sub>)<sub>3</sub></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">铬(IV)</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E5%9B%9B%E6%B0%AF%E5%8C%96%E9%93%AC" title="四氯化铬">CrCl<sub>4</sub></a></li> <li><a href="/wiki/%E5%9B%9B%E6%B0%9F%E5%8C%96%E9%93%AC" title="四氟化铬">CrF<sub>4</sub></a></li> <li><a href="/wiki/%E4%BA%8C%E6%B0%A7%E5%8C%96%E9%93%AC" title="二氧化铬">CrO<sub>2</sub></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">铬(V)</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E4%BA%94%E6%B0%9F%E5%8C%96%E9%93%AC" title="五氟化铬">CrF<sub>5</sub></a></li> <li><a href="/wiki/%E5%9B%9B%E8%BF%87%E6%B0%A7%E9%93%AC(V)%E9%85%B8%E9%92%BE" title="四过氧铬(V)酸钾">K<sub>3</sub>Cr(O<sub>2</sub>)<sub>4</sub></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/%E5%85%AD%E4%BB%B7%E9%93%AC" title="六价铬">铬(VI)</a></th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <ul><li><a href="/wiki/%E4%B8%89%E6%B0%A7%E5%8C%96%E9%93%AC" title="三氧化铬">CrO<sub>3</sub></a></li> <li><a href="/wiki/%E8%BF%87%E6%B0%A7%E5%8C%96%E9%93%AC" title="过氧化铬">CrO(O<sub>2</sub>)<sub>2</sub></a></li> <li><a href="/wiki/%E9%93%AC%E9%85%B8" title="铬酸">H<sub>2</sub>CrO<sub>4</sub></a></li> <li><a href="/wiki/%E9%93%AC%E9%85%B8" title="铬酸">H<sub>2</sub>Cr<sub>2</sub>O<sub>7</sub></a></li> <li><a href="/wiki/%E9%93%AC%E9%85%B0%E6%B0%9F" title="铬酰氟">CrO<sub>2</sub>F<sub>2</sub></a></li> <li><a href="/wiki/%E9%93%AC%E9%85%B0%E6%B0%AF" title="铬酰氯">CrO<sub>2</sub>Cl<sub>2</sub></a></li> <li><a href="/wiki/%E6%B0%AF%E9%93%AC%E9%85%B8%E5%90%A1%E5%95%B6%E7%9B%90" class="mw-redirect" title="氯铬酸吡啶盐">C<sub>5</sub>H<sub>5</sub>NHCrO<sub>3</sub>Cl</a></li> <li><i><a href="/wiki/%E5%85%AD%E6%B0%9F%E5%8C%96%E9%93%AC" title="六氟化铬">CrF<sub>6</sub></a> (推测)</i></li></ul> </div></td></tr></tbody></table></div> <div class="navbox-styles"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84265675"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84261037"></div><div role="navigation" class="navbox" aria-labelledby="羰基配合物" style="padding:3px"><table class="nowraplinks mw-collapsible mw-collapsed navbox-inner" style="border-spacing:0;background:transparent;color:inherit"><tbody><tr><th scope="col" class="collapsible-title navbox-title" colspan="2"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84265675"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r84244141"><div class="navbar plainlinks hlist navbar-mini"><ul><li class="nv-view"><a href="/wiki/Template:%E7%BE%B0%E5%9F%BA%E9%85%8D%E5%90%88%E7%89%A9" title="Template:羰基配合物"><abbr title="查看该模板">查</abbr></a></li><li class="nv-talk"><a href="/w/index.php?title=Template_talk:%E7%BE%B0%E5%9F%BA%E9%85%8D%E5%90%88%E7%89%A9&action=edit&redlink=1" class="new" title="Template talk:羰基配合物(页面不存在)"><abbr title="讨论该模板">论</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:%E7%BC%96%E8%BE%91%E9%A1%B5%E9%9D%A2/Template:%E7%BE%B0%E5%9F%BA%E9%85%8D%E5%90%88%E7%89%A9" title="Special:编辑页面/Template:羰基配合物"><abbr title="编辑该模板">编</abbr></a></li></ul></div><div id="羰基配合物" style="font-size:110%;margin:0 5em"><b><a href="/wiki/%E7%BE%B0%E5%9F%BA%E9%85%8D%E5%90%88%E7%89%A9" class="mw-redirect" title="羰基配合物">羰基配合物</a></b></div></th></tr><tr><td colspan="2" class="navbox-list navbox-odd hlist" style="width:100%;padding:0px"><div style="padding:0em 0.25em"> <table style="width:100%;margin:0 auto;"> <tbody><tr style="background-color:mistyrose;vertical-align:top"> <td>H </td> <td style="background-color:white;border:none"> </td> <td style="background-color:white;border:none" colspan="10" rowspan="3"> </td> <td style="background-color:white;border:none" colspan="5"> </td> <td>He </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td>Li </td> <td>Be </td> <td>B </td> <td>C </td> <td>N </td> <td>O </td> <td>F </td> <td>Ne </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td>Na </td> <td>Mg </td> <td>Al </td> <td>Si </td> <td>P </td> <td>S </td> <td>Cl </td> <td>Ar </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td>K </td> <td>Ca </td> <td>Sc </td> <td>Ti </td> <td><a href="/wiki/%E5%85%AD%E7%BE%B0%E5%9F%BA%E9%92%92" title="六羰基钒">V(CO)<sub>6</sub></a> </td> <td><a class="mw-selflink selflink">Cr(CO)<sub>6</sub></a> </td> <td><a href="/wiki/%E5%8D%81%E7%BE%B0%E5%9F%BA%E4%BA%8C%E9%94%B0" title="十羰基二锰">Mn<sub>2</sub>(CO)<sub>10</sub></a> </td> <td><a href="/wiki/%E4%BA%94%E7%BE%B0%E5%9F%BA%E9%93%81" title="五羰基铁">Fe(CO)<sub>5</sub></a><br /><a href="/wiki/%E4%B9%9D%E7%BE%B0%E5%9F%BA%E4%BA%8C%E9%93%81" title="九羰基二铁">Fe<sub>2</sub>(CO)<sub>9</sub></a><br /><a href="/wiki/%E5%8D%81%E4%BA%8C%E7%BE%B0%E5%9F%BA%E4%B8%89%E9%93%81" title="十二羰基三铁">Fe<sub>3</sub>(CO)<sub>12</sub></a> </td> <td><a href="/wiki/%E5%85%AB%E7%BE%B0%E5%9F%BA%E4%BA%8C%E9%92%B4" title="八羰基二钴">Co<sub>2</sub>(CO)<sub>8</sub></a><br /><a href="/wiki/%E5%8D%81%E4%BA%8C%E7%BE%B0%E5%9F%BA%E5%9B%9B%E9%92%B4" title="十二羰基四钴">Co<sub>4</sub>(CO)<sub>12</sub></a> </td> <td><a href="/wiki/%E5%9B%9B%E7%BE%B0%E5%9F%BA%E9%95%8D" title="四羰基镍">Ni(CO)<sub>4</sub></a> </td> <td>Cu </td> <td>Zn </td> <td>Ga </td> <td>Ge </td> <td>As </td> <td>Se </td> <td>Br </td> <td>Kr </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td>Rb </td> <td>Sr </td> <td>Y </td> <td>Zr </td> <td>Nb </td> <td><a href="/wiki/%E5%85%AD%E7%BE%B0%E5%9F%BA%E9%92%BC" title="六羰基钼">Mo(CO)<sub>6</sub></a> </td> <td><a href="/wiki/%E5%8D%81%E7%BE%B0%E5%9F%BA%E4%BA%8C%E9%94%9D" title="十羰基二锝">Tc<sub>2</sub>(CO)<sub>10</sub></a> </td> <td><a href="/wiki/%E4%BA%94%E7%BE%B0%E5%9F%BA%E9%92%8C" title="五羰基钌">Ru(CO)<sub>5</sub></a><br /><a href="/wiki/%E5%8D%81%E4%BA%8C%E7%BE%B0%E5%9F%BA%E4%B8%89%E9%92%8C" title="十二羰基三钌">Ru<sub>3</sub>(CO)<sub>12</sub></a> </td> <td><a href="/wiki/%E5%8D%81%E4%BA%8C%E7%BE%B0%E5%9F%BA%E5%9B%9B%E9%93%91" title="十二羰基四铑">Rh<sub>4</sub>(CO)<sub>12</sub></a><br /><a href="/wiki/%E5%8D%81%E5%85%AD%E7%BE%B0%E5%9F%BA%E5%85%AD%E9%93%91" title="十六羰基六铑">Rh<sub>6</sub>(CO)<sub>16</sub></a> </td> <td>Pd </td> <td>Ag </td> <td>Cd </td> <td>In </td> <td>Sn </td> <td>Sb </td> <td>Te </td> <td>I </td> <td>Xe </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td>Cs </td> <td>Ba </td> <td style="background-color:white;border:none"><span title="镧系元素" style="font-family: Courier, monospace;">镧系</span> </td> <td>Hf </td> <td>Ta </td> <td><a href="/wiki/%E5%85%AD%E7%BE%B0%E5%9F%BA%E9%92%A8" title="六羰基钨">W(CO)<sub>6</sub></a> </td> <td><a href="/wiki/%E5%8D%81%E7%BE%B0%E5%9F%BA%E4%BA%8C%E9%8C%B8" title="十羰基二錸">Re<sub>2</sub>(CO)<sub>10</sub></a> </td> <td><a href="/wiki/%E4%BA%94%E7%BE%B0%E5%9F%BA%E9%94%87" title="五羰基锇">Os(CO)<sub>5</sub></a><br /><a href="/wiki/%E5%8D%81%E4%BA%8C%E7%BE%B0%E5%9F%BA%E4%B8%89%E9%94%87" title="十二羰基三锇">Os<sub>3</sub>(CO)<sub>12</sub></a> </td> <td><a href="/wiki/%E5%8D%81%E4%BA%8C%E7%BE%B0%E5%9F%BA%E5%9B%9B%E9%93%B1" title="十二羰基四铱">Ir<sub>4</sub>(CO)<sub>12</sub></a> </td> <td>Pt </td> <td>Au </td> <td>Hg </td> <td>Tl </td> <td>Pb </td> <td>Bi </td> <td>Po </td> <td>At </td> <td>Rn </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td>Fr </td> <td>Ra </td> <td style="background-color:white;border:none"><span title="锕系元素" style="font-family: Courier, monospace;">锕系</span> </td> <td>Rf </td> <td>Db </td> <td>Sg </td> <td>Bh </td> <td>Hs </td> <td>Mt </td> <td>Ds </td> <td>Rg </td> <td>Cn </td> <td>Nh </td> <td>Fl </td> <td>Mc </td> <td>Lv </td> <td>Ts </td> <td>Og </td></tr> <tr> <td style="background-color:white;border:none" rowspan="3"> </td> <td style="background-color:white;border:none" colspan="1"> </td> <td style="background-color:white;border:none">↓ </td> <td style="background-color:white;border:none" colspan="14"> </td> <td style="background-color:white;border:none" rowspan="3"> </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td style="background-color:white;border:none"><span title="镧系元素" style="font-family: Courier, monospace;">镧系</span> </td> <td>La </td> <td>Ce </td> <td>Pr </td> <td>Nd </td> <td>Pm </td> <td>Sm </td> <td>Eu </td> <td>Gd </td> <td>Tb </td> <td>Dy </td> <td>Ho </td> <td>Er </td> <td>Tm </td> <td>Yb </td> <td>Lu </td></tr> <tr style="background-color:mistyrose;vertical-align:top"> <td style="background-color:white;border:none"><span title="锕系元素" style="font-family: Courier, monospace;">锕系</span> </td> <td>Ac </td> <td>Th </td> <td>Pa </td> <td>U </td> <td>Np </td> <td>Pu </td> <td>Am </td> <td>Cm </td> <td>Bk </td> <td>Cf </td> <td>Es </td> <td>Fm </td> <td>Md </td> <td>No </td> <td>Lr </td></tr></tbody></table> </div></td></tr></tbody></table></div> <!-- NewPP limit report Parsed by mw‐web.codfw.main‐b4d578f7d‐4m6gc Cached time: 20241114204628 Cache expiry: 2592000 Reduced expiry: false Complications: [show‐toc] CPU time usage: 0.314 seconds Real time usage: 0.515 seconds Preprocessor visited node count: 4298/1000000 Post‐expand include size: 78399/2097152 bytes Template argument size: 12723/2097152 bytes Highest expansion depth: 16/100 Expensive parser function count: 6/500 Unstrip recursion depth: 0/20 Unstrip post‐expand size: 17795/5000000 bytes Lua time usage: 0.093/10.000 seconds Lua memory usage: 1508489/52428800 bytes Number of Wikibase entities loaded: 0/400 --> <!-- Transclusion expansion time report 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