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Vargas-Ceballos</title> <meta name="description" content="Search results for: Angie Dayana Vargas-Ceballos"> <meta name="keywords" content="Angie Dayana Vargas-Ceballos"> <meta name="viewport" content="width=device-width, initial-scale=1, minimum-scale=1, maximum-scale=1, user-scalable=no"> <meta charset="utf-8"> <link href="https://cdn.waset.org/favicon.ico" type="image/x-icon" rel="shortcut icon"> <link href="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/css/bootstrap.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/plugins/fontawesome/css/all.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/css/site.css?v=150220211555" rel="stylesheet"> </head> <body> <header> <div class="container"> <nav class="navbar navbar-expand-lg navbar-light"> <a class="navbar-brand" href="https://waset.org"> <img src="https://cdn.waset.org/static/images/wasetc.png" alt="Open Science Research Excellence" title="Open Science Research Excellence" /> </a> <button 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action="https://publications.waset.org/abstracts/search"> <div id="custom-search-input"> <div class="input-group"> <i class="fas fa-search"></i> <input type="text" class="search-query" name="q" placeholder="Author, Title, Abstract, Keywords" value="Angie Dayana Vargas-Ceballos"> <input type="submit" class="btn_search" value="Search"> </div> </div> </form> </div> </div> <div class="row mt-3"> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Commenced</strong> in January 2007</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Frequency:</strong> Monthly</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Edition:</strong> International</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Paper Count:</strong> 15</div> </div> </div> </div> <h1 class="mt-3 mb-3 text-center" style="font-size:1.6rem;">Search results for: Angie Dayana Vargas-Ceballos</h1> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">15</span> Cr (VI) Adsorption on Ce0.25Zr0.75O2.nH2O-Kinetics and Thermodynamics</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Carlos%20Alberto%20Rivera-corredor">Carlos Alberto Rivera-corredor</a>, <a href="https://publications.waset.org/abstracts/search?q=Angie%20Dayana%20Vargas-Ceballos"> Angie Dayana Vargas-Ceballos</a>, <a href="https://publications.waset.org/abstracts/search?q=Edison%20Gilpavas"> Edison Gilpavas</a>, <a href="https://publications.waset.org/abstracts/search?q=Izabela%20Dobrosz-G%C3%B3mez"> Izabela Dobrosz-Gómez</a>, <a href="https://publications.waset.org/abstracts/search?q=Miguel%20%C3%81ngel%20G%C3%B3mez-Garc%C3%ADa"> Miguel Ángel Gómez-García</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Hexavalent chromium, Cr (VI) is present in the effluents from different industries such as electroplating, mining, leather tanning, etc. This compound is of great academic and industrial concern because of its toxic and carcinogenic behavior. Its dumping to both environmental and public health for animals and humans causes serious problems in water sources. The amount of Cr (VI) in industrial wastewaters ranges from 0.5 to 270,000 mgL-1. According to the Colombian standard for water quality (NTC-813-2010), the maximum allowed concentration for the Cr (VI) in drinking water is 0.05 mg L-1. To comply with this limit, it is essential that industries treat their effluent to reduce the Cr (VI) to acceptable levels. Numerous methods have been reported for the treatment removing metal ions from aqueous solutions such as: reduction, ion exchange, electrodialysis, etc. Adsorption has become a promising method for the purification of metal ions in water, since its application corresponds with an economic and efficient technology. The absorbent selection and the kinetic and thermodynamic study of the adsorption conditions are key to the development of a suitable adsorption technology. The Ce0.25Zr0.75O2.nH2O presents higher adsorption capacity between a series of hydrated mixed oxides Ce1-xZrxO2 (x = 0, 0.25, 0.5, 0.75, 1). This work presents the kinetic and thermodynamic study of Cr (VI) adsorption on Ce0.25Zr0.75O2.nH2O. Experiments were performed under the following experimental conditions: initial Cr (VI) concentration = 25, 50 and 100 mgL-1, pH = 2, adsorbent charge = 4 gL-1, stirring time = 60 min, temperature=20, 28 and 40 °C. The Cr (VI) concentration was spectrophotometrically estimated by the method of difenilcarbazide with monitoring the absorbance at 540 nm. The Cr (VI) adsorption over hydrated Ce0.25Zr0.75O2.nH2O models was analyzed using pseudo-first and pseudo-second order kinetics. The Langmuir and Freundlich models were used to model the experimental data. The convergence between the experimental values and those predicted by the model, is expressed as a linear regression correlation coefficient (R2) and was employed as the model selection criterion. The adsorption process followed the pseudo-second order kinetic model and obeyed the Langmuir isotherm model. The thermodynamic parameters were calculated as: ΔH°=9.04 kJmol-1,ΔS°=0.03 kJmol-1 K-1, ΔG°=-0.35 kJmol-1 and indicated the endothermic and spontaneous nature of the adsorption process, governed by physisorption interactions. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=adsorption" title="adsorption">adsorption</a>, <a href="https://publications.waset.org/abstracts/search?q=hexavalent%20chromium" title=" hexavalent chromium"> hexavalent chromium</a>, <a href="https://publications.waset.org/abstracts/search?q=kinetics" title=" kinetics"> kinetics</a>, <a href="https://publications.waset.org/abstracts/search?q=thermodynamics" title=" thermodynamics"> thermodynamics</a> </p> <a href="https://publications.waset.org/abstracts/41080/cr-vi-adsorption-on-ce025zr075o2nh2o-kinetics-and-thermodynamics" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/41080.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">299</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">14</span> Non Immersive Virtual Laboratory Applied to Robotics Arms</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Luis%20F.%20Recalde">Luis F. Recalde</a>, <a href="https://publications.waset.org/abstracts/search?q=Daniela%20A.%20Bastidas"> Daniela A. Bastidas</a>, <a href="https://publications.waset.org/abstracts/search?q=Dayana%20E.%20Gallegos"> Dayana E. Gallegos</a>, <a href="https://publications.waset.org/abstracts/search?q=Patricia%20N.%20Constante"> Patricia N. Constante</a>, <a href="https://publications.waset.org/abstracts/search?q=Victor%20H.%20Andaluz"> Victor H. Andaluz</a> </p> <p class="card-text"><strong>Abstract:</strong></p> This article presents a non-immersive virtual lab-oratory to emulate the behavior of the Mitsubishi Melfa RV 2SDB robotic arm, allowing students and users to acquire skills and experience related to real robots, augmenting the access and learning of robotics in Universidad de las Fuerzas Armadas (ESPE). It was developed using the mathematical model of the robotic arm, thus defining the parameters for virtual recreation. The environment, interaction, and behavior of the robotic arm were developed in a graphic engine (Unity3D) to emulate learning tasks such as in a robotics laboratory. In the virtual system, four inputs were developed for the movement of the robot arm; further, to program the robot, a user interface was created where the user selects the trajectory such as point to point, line, arc, or circle. Finally, the hypothesis of the industrial robotic learning process is validated through the level of knowledge acquired after using the system. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=virtual%20learning" title="virtual learning">virtual learning</a>, <a href="https://publications.waset.org/abstracts/search?q=robot%20arm" title=" robot arm"> robot arm</a>, <a href="https://publications.waset.org/abstracts/search?q=non-immersive%20reality" title=" non-immersive reality"> non-immersive reality</a>, <a href="https://publications.waset.org/abstracts/search?q=mathematical%20model" title=" mathematical model"> mathematical model</a> </p> <a href="https://publications.waset.org/abstracts/145376/non-immersive-virtual-laboratory-applied-to-robotics-arms" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/145376.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">99</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">13</span> Voice Signal Processing and Coding in MATLAB Generating a Plasma Signal in a Tesla Coil for a Security System</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Juan%20Jimenez">Juan Jimenez</a>, <a href="https://publications.waset.org/abstracts/search?q=Erika%20Yambay"> Erika Yambay</a>, <a href="https://publications.waset.org/abstracts/search?q=Dayana%20Pilco"> Dayana Pilco</a>, <a href="https://publications.waset.org/abstracts/search?q=Brayan%20Parra"> Brayan Parra</a> </p> <p class="card-text"><strong>Abstract:</strong></p> This paper presents an investigation of voice signal processing and coding using MATLAB, with the objective of generating a plasma signal on a Tesla coil within a security system. The approach focuses on using advanced voice signal processing techniques to encode and modulate the audio signal, which is then amplified and applied to a Tesla coil. The result is the creation of a striking visual effect of voice-controlled plasma with specific applications in security systems. The article explores the technical aspects of voice signal processing, the generation of the plasma signal, and its relationship to security. The implications and creative potential of this technology are discussed, highlighting its relevance at the forefront of research in signal processing and visual effect generation in the field of security systems. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=voice%20signal%20processing" title="voice signal processing">voice signal processing</a>, <a href="https://publications.waset.org/abstracts/search?q=voice%20signal%20coding" title=" voice signal coding"> voice signal coding</a>, <a href="https://publications.waset.org/abstracts/search?q=MATLAB" title=" MATLAB"> MATLAB</a>, <a href="https://publications.waset.org/abstracts/search?q=plasma%20signal" title=" plasma signal"> plasma signal</a>, <a href="https://publications.waset.org/abstracts/search?q=Tesla%20coil" title=" Tesla coil"> Tesla coil</a>, <a href="https://publications.waset.org/abstracts/search?q=security%20system" title=" security system"> security system</a>, <a href="https://publications.waset.org/abstracts/search?q=visual%20effects" title=" visual effects"> visual effects</a>, <a href="https://publications.waset.org/abstracts/search?q=audiovisual%20interaction" title=" audiovisual interaction"> audiovisual interaction</a> </p> <a href="https://publications.waset.org/abstracts/170828/voice-signal-processing-and-coding-in-matlab-generating-a-plasma-signal-in-a-tesla-coil-for-a-security-system" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/170828.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">93</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">12</span> Measuring Government’s Performance (Services) Oman Service Maturity Model (OSMM)</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Angie%20Al%20Habib">Angie Al Habib</a>, <a href="https://publications.waset.org/abstracts/search?q=Khalid%20Al%20Siyabi"> Khalid Al Siyabi</a> </p> <p class="card-text"><strong>Abstract:</strong></p> To measure or asses any government’s efficiency we need to measure the performance of this government in regards to the quality of the service it provides. Using a technological platform in service provision became a trend and a public demand. It is also a public need to make sure these services are aligned to values and to the whole government’s strategy, vision and goals as well. Providing services using technology tools and channels can enhance the internal business process and also help establish many essential values to government services like transparency and excellence, since in order to establish e-services many standards and policies must be put in place to enable the handing over of decision making to a mature system oriented mechanism. There was no doubt that the Sultanate of Oman wanted to enhance its services and move it towards automation and establishes a smart government as well as links its services to life events. Measuring government efficiency is very essential in achieving social security and economic growth, since it can provide a clear dashboard of all projects and improvements. Based on this data we can improve the strategies and align the country goals to them. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=government" title="government">government</a>, <a href="https://publications.waset.org/abstracts/search?q=maturity" title=" maturity"> maturity</a>, <a href="https://publications.waset.org/abstracts/search?q=Oman" title=" Oman"> Oman</a>, <a href="https://publications.waset.org/abstracts/search?q=performance" title=" performance"> performance</a>, <a href="https://publications.waset.org/abstracts/search?q=service" title=" service"> service</a> </p> <a href="https://publications.waset.org/abstracts/11088/measuring-governments-performance-services-oman-service-maturity-model-osmm" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/11088.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">366</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">11</span> N Doped Multiwall Carbon Nanotubes Growth over a Ni Catalyst Substrate</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Angie%20Quevedo">Angie Quevedo</a>, <a href="https://publications.waset.org/abstracts/search?q=Juan%20Bussi"> Juan Bussi</a>, <a href="https://publications.waset.org/abstracts/search?q=Nestor%20Tancredi"> Nestor Tancredi</a>, <a href="https://publications.waset.org/abstracts/search?q=Juan%20Fajardo-D%C3%ADaz"> Juan Fajardo-Díaz</a>, <a href="https://publications.waset.org/abstracts/search?q=Florentino%20L%C3%B3pez-Ur%C3%ADas"> Florentino López-Urías</a>, <a href="https://publications.waset.org/abstracts/search?q=Emilio%20Mu%C3%B1%C3%B3z-Sandoval"> Emilio Muñóz-Sandoval</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In this work, we study the carbon nanotubes (CNTs) formation by catalytic chemical vapor deposition (CCVD) over a catalyst with 20 % of Ni supported over La₂Zr₂O₇ (Ni20LZO). The high C solubility of Ni made it one of the most used in CNTs synthesis. Nevertheless, Ni presents also sintering and coalescence at high temperature. These troubles can be reduced by choosing a suitable support. We propose La₂Zr₂O₇ as for this matter since the incorporation of Ni by co-precipitation and calcination at 900 °C allows a good dispersion and interaction of the active metal (in the oxidized form, NiO) with this support. The CCVD was performed using 1 g of Ni20LZO at 950 °C during 30 min in Ar:H₂ atmosphere (2.5 L/min). The precursor, benzylamine, was added by a nebulizer-sprayer. X ray diffraction study shows the phase separation of NiO and La₂Zr₂O₇ after the calcination and the reduction to Ni after the synthesis. Raman spectra show D and G bands with a ID/IG ratio of 0.75. Elemental study verifies the incorporation of 1% of N. Thermogravimetric analysis shows the oxidation process start at around 450 °C. Future studies will determine the application potential of the samples. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=N%20doped%20carbon%20nanotubes" title="N doped carbon nanotubes">N doped carbon nanotubes</a>, <a href="https://publications.waset.org/abstracts/search?q=catalytic%20chemical%20vapor%20deposition" title=" catalytic chemical vapor deposition"> catalytic chemical vapor deposition</a>, <a href="https://publications.waset.org/abstracts/search?q=nickel%20catalyst" title=" nickel catalyst"> nickel catalyst</a>, <a href="https://publications.waset.org/abstracts/search?q=bimetallic%20oxide" title=" bimetallic oxide"> bimetallic oxide</a> </p> <a href="https://publications.waset.org/abstracts/125152/n-doped-multiwall-carbon-nanotubes-growth-over-a-ni-catalyst-substrate" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/125152.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">162</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">10</span> Magnetohydrodynamics Flow and Heat Transfer in a Non-Newtonian Power-Law Fluid due to a Rotating Disk with Velocity Slip and Temperature Jump</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Nur%20Dayana%20Khairunnisa%20Rosli">Nur Dayana Khairunnisa Rosli</a>, <a href="https://publications.waset.org/abstracts/search?q=Seripah%20Awang%20Kechil"> Seripah Awang Kechil</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Swirling flows with velocity slip are important in nature and industrial processes. The present work considers the effects of velocity slip, temperature jump and suction/injection on the flow and heat transfer of power-law fluids due to a rotating disk in the presence of magnetic field. The system of the partial differential equations is highly non-linear. The number of independent variables is reduced by transforming the system into a system of coupled non-linear ordinary differential equations using similarity transformations. The effects of suction/injection, velocity slip and temperature jump on the flow rates are investigated for various cases of shear thinning and shear thickening power law fluids. The thermal and velocity jump strongly reduce the heat transfer rate and skin friction coefficient. Suction decreases the radial and tangential skin friction coefficient and the rate of heat transfer. It is also observed that the effects are more pronounced in the case of shear thinning fluids as compared to shear thickening fluids. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=heat%20transfer" title="heat transfer">heat transfer</a>, <a href="https://publications.waset.org/abstracts/search?q=power-law%20fluids" title=" power-law fluids"> power-law fluids</a>, <a href="https://publications.waset.org/abstracts/search?q=rotating%20disk" title=" rotating disk"> rotating disk</a>, <a href="https://publications.waset.org/abstracts/search?q=suction%20or%20injection" title=" suction or injection"> suction or injection</a>, <a href="https://publications.waset.org/abstracts/search?q=temperature%20jump" title=" temperature jump"> temperature jump</a>, <a href="https://publications.waset.org/abstracts/search?q=velocity%20slip" title=" velocity slip"> velocity slip</a> </p> <a href="https://publications.waset.org/abstracts/53534/magnetohydrodynamics-flow-and-heat-transfer-in-a-non-newtonian-power-law-fluid-due-to-a-rotating-disk-with-velocity-slip-and-temperature-jump" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/53534.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">267</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">9</span> Saving Lives: Alternative Approaches to Reducing Gun Violence</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Angie%20M.%20Wolf">Angie M. Wolf</a>, <a href="https://publications.waset.org/abstracts/search?q=DeVone%20Boggan"> DeVone Boggan</a> </p> <p class="card-text"><strong>Abstract:</strong></p> This paper highlights an innovative and nontraditional violence prevention program that is making a noticeable impact in what was once one of the country’s most violent communities. With unique and tailored strategies, the Operation Peacemaker Fellowship, established in Richmond, California, combines components of evidence-based practices with a community-oriented focus on relationships and mentoring to fill a gap in services and increase community safety. In an effort to highlight these unique strategies and provide a blueprint for other communities with violent crime problems, the authors of this paper hope to clearly delineate how one community is moving forward with vanguard approaches to invest in the lives of young men who once were labeled the communities’ most violent, even the most deadly, youth. The impact of this program is evidenced through the fellows’ own voices as they illuminate the experience of being in the Fellowship. In interviews, fellows’ describe how participating in this program has transformed their lives, and the lives of those they love. The authors of this article spent more than two years researching this Fellowship program in order to conduct an evaluation of it and, ultimately, to demonstrate how this program is a testament to the power of relationship and love combined with evidence-based practices, consequently enriching the lives of youth and the community that embraces them. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=gun%20violence%20prevention" title="gun violence prevention">gun violence prevention</a>, <a href="https://publications.waset.org/abstracts/search?q=high%20risk%20youth" title=" high risk youth"> high risk youth</a>, <a href="https://publications.waset.org/abstracts/search?q=law" title=" law"> law</a>, <a href="https://publications.waset.org/abstracts/search?q=policing%20justice" title=" policing justice"> policing justice</a> </p> <a href="https://publications.waset.org/abstracts/24452/saving-lives-alternative-approaches-to-reducing-gun-violence" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/24452.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">412</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">8</span> School Based Assessment Issues in Selected Malaysian Primary Schools</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Nur%20Amalina%20Dayana%20Abd%20Aziz">Nur Amalina Dayana Abd Aziz</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Assessment is an integral part of teaching and learning in any syllabus in the world. Recently, a new assessment system, School-Based Assessment (SBA) was introduced and implemented in the Malaysian education system to promote a more holistic, integrated and balanced assessment system. This effort is part of the reformation made in the Government Transformation Plan (GTP) to produce a world-class human capital as we are reaching and achieving the Vision 2020 in the near future. However, this new change has raised awareness and concerns from teachers, students, parents and non-profit organizations on how the new assessment is to be implemented and how it is affecting the students and teachers particularly. Therefore, this paper aims to investigate the issues that teachers face in implementing SBA in primary schools, the measures taken to address the issues and to propose ways of managing school-based assessment. Five national primary schools focusing in the urban areas in the Selangor state are chosen for this study to carry out. Data for the study will be gathered from interviews with teachers from each school, surveys and classrooms observation will be conducted in each school, and relevant documents are collected from the selected schools. The findings of this study will present the current issues that teachers from various types of national primary schools are facing and what actions they took to overcome the problems in carrying out SBA. Suggestions on how to better manage school-based assessment for teachers are also provided in this paper. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=community%20of%20practice" title="community of practice">community of practice</a>, <a href="https://publications.waset.org/abstracts/search?q=curriculum" title=" curriculum"> curriculum</a>, <a href="https://publications.waset.org/abstracts/search?q=managing%20change" title=" managing change"> managing change</a>, <a href="https://publications.waset.org/abstracts/search?q=school-based%20assessment" title=" school-based assessment "> school-based assessment </a> </p> <a href="https://publications.waset.org/abstracts/37883/school-based-assessment-issues-in-selected-malaysian-primary-schools" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/37883.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">426</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">7</span> Bioinformatic Screening of Metagenomic Fosmid Libraries for Identification of Biosynthetic Pathways Derived from the Colombian Soils</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Mar%C3%ADa%20Fernanda%20Quiceno%20Vallejo">María Fernanda Quiceno Vallejo</a>, <a href="https://publications.waset.org/abstracts/search?q=Patricia%20del%20Portillo"> Patricia del Portillo</a>, <a href="https://publications.waset.org/abstracts/search?q=Mar%C3%ADa%20Mercedes%20Zambrano"> María Mercedes Zambrano</a>, <a href="https://publications.waset.org/abstracts/search?q=Jeisson%20Alejandro%20Triana"> Jeisson Alejandro Triana</a>, <a href="https://publications.waset.org/abstracts/search?q=Dayana%20Calderon"> Dayana Calderon</a>, <a href="https://publications.waset.org/abstracts/search?q=Juan%20Manuel%20Anzola"> Juan Manuel Anzola</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Microorganisms from tropical ecosystems can be novel in terms of adaptations and conservation. Given the macrodiversity of Colombian ecosystems, it is possible that this diversity is also present in Colombian soils. Tropical soil bacteria could offer a potentially novel source of bioactive compounds. In this study we analyzed a metagenomic fosmid library constructed with tropical bacterial DNAs with the aim of understanding its underlying diversity and functional potential. 8640 clones from the fosmid library were sequenced by NANOPORE MiniOn technology, then analyzed with bioinformatic tools such as Prokka, AntiSMASH and Bagel4 in order to identify functional biosynthetic pathways in the sequences. The strains showed ample difference when it comes to biosynthetic pathways. In total we identified 4 pathways related to aryl polyene synthesis, 12 related to terpenes, 22 related to NRPs (Non ribosomal peptides), 11 related PKs (Polyketide synthases) and 7 related to RiPPs (bacteriocins). We designed primers for the metagenomic clones with the most BGCs (sample 6 and sample 2). Results show the biotechnological / pharmacological potential of tropical ecosystems. Overall, this work provides an overview of the genomic and functional potential of Colombian soil and sets the groundwork for additional exploration of tropical metagenomic sequencing. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=bioactives" title="bioactives">bioactives</a>, <a href="https://publications.waset.org/abstracts/search?q=biosyntethic%20pathways" title=" biosyntethic pathways"> biosyntethic pathways</a>, <a href="https://publications.waset.org/abstracts/search?q=bioinformatic" title=" bioinformatic"> bioinformatic</a>, <a href="https://publications.waset.org/abstracts/search?q=bacterial%20gene%20clusters" title=" bacterial gene clusters"> bacterial gene clusters</a>, <a href="https://publications.waset.org/abstracts/search?q=secondary%20metabolites" title=" secondary metabolites"> secondary metabolites</a> </p> <a href="https://publications.waset.org/abstracts/144224/bioinformatic-screening-of-metagenomic-fosmid-libraries-for-identification-of-biosynthetic-pathways-derived-from-the-colombian-soils" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/144224.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">165</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">6</span> Vocational Teaching Method: A Conceptual Model in Teaching Automotive Practical Work</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Adnan%20Ahmad">Adnan Ahmad</a>, <a href="https://publications.waset.org/abstracts/search?q=Yusri%20Kamin"> Yusri Kamin</a>, <a href="https://publications.waset.org/abstracts/search?q=Asnol%20Dahar%20Minghat"> Asnol Dahar Minghat</a>, <a href="https://publications.waset.org/abstracts/search?q=Mohd.%20Khir%20Nordin"> Mohd. Khir Nordin</a>, <a href="https://publications.waset.org/abstracts/search?q=Dayana%20Farzeha"> Dayana Farzeha</a>, <a href="https://publications.waset.org/abstracts/search?q=Ahmad%20Nabil"> Ahmad Nabil </a> </p> <p class="card-text"><strong>Abstract:</strong></p> The purpose of this study is to identify the teaching method practices of the practical work subject in Vocational Secondary School. This study examined the practice of Vocational Teaching Method in Automotive Practical Work. The quantitative method used the sets of the questionnaire. 283 students and 63 teachers involved from ten VSS involved in this research. Research finding showed in conducting the introduction session teachers prefer used the demonstration method and questioning technique. While in deliver the content of practical task, teachers applied group monitoring and problem-solving approach. To conclude the task of automotive practical work, teachers choose re-explain and report writing to make sure students really understand all the process of teaching. VTM-APW also involved the competency-based concept to embed in the model. Derived from factors investigated, research produced the combination of elements in teaching skills and vocational skills which could be used as the best teaching method in automotive practical work for school level. As conclusion this study has concluded that the VTM-APW model is able to apply in teaching to make an improvement with current practices in Vocational Secondary School. Hence, teachers are suggested to use this method to enhance student's knowledge in Automotive and teachers will deliver skills to the current and future workforce relevant with the required competency skilled in workplace. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=vocational%20teaching%20method" title="vocational teaching method">vocational teaching method</a>, <a href="https://publications.waset.org/abstracts/search?q=practical%20task" title=" practical task"> practical task</a>, <a href="https://publications.waset.org/abstracts/search?q=teacher%20preferences" title=" teacher preferences"> teacher preferences</a>, <a href="https://publications.waset.org/abstracts/search?q=student%20preferences" title=" student preferences"> student preferences</a> </p> <a href="https://publications.waset.org/abstracts/8306/vocational-teaching-method-a-conceptual-model-in-teaching-automotive-practical-work" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/8306.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">452</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">5</span> Clinical and Epidemiological Profile of Patients with Chronic Obstructive Pulmonary Disease in a Medical Institution from the City of Medellin, Colombia</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Camilo%20Andres%20Agudelo-Velez">Camilo Andres Agudelo-Velez</a>, <a href="https://publications.waset.org/abstracts/search?q=Lina%20Mar%C3%ADa%20Martinez-Sanchez"> Lina María Martinez-Sanchez</a>, <a href="https://publications.waset.org/abstracts/search?q=Natalia%20Perilla-Hernandez"> Natalia Perilla-Hernandez</a>, <a href="https://publications.waset.org/abstracts/search?q=Maria%20De%20Los%20Angeles%20Rodriguez-Gazquez"> Maria De Los Angeles Rodriguez-Gazquez</a>, <a href="https://publications.waset.org/abstracts/search?q=Felipe%20Hernandez-Restrepo"> Felipe Hernandez-Restrepo</a>, <a href="https://publications.waset.org/abstracts/search?q=Dayana%20Andrea%20Quintero-Moreno"> Dayana Andrea Quintero-Moreno</a>, <a href="https://publications.waset.org/abstracts/search?q=Camilo%20Ruiz-Mejia"> Camilo Ruiz-Mejia</a>, <a href="https://publications.waset.org/abstracts/search?q=Isabel%20Cristina%20Ortiz-Trujillo"> Isabel Cristina Ortiz-Trujillo</a>, <a href="https://publications.waset.org/abstracts/search?q=Monica%20Maria%20Zuluaga-Quintero"> Monica Maria Zuluaga-Quintero</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Chronic obstructive pulmonary disease is common condition, characterized by a persistent blockage of airflow, partially reversible and progressive, that represents 5% of total deaths around the world, and it is expected to become the third leading cause of death by 2030. Objective: To establish the clinical and epidemiological profile of patients with chronic obstructive pulmonary disease in a medical institution from the city of Medellin, Colombia. Methods: A cross-sectional study was performed, with a sample of 50 patients with a diagnosis of chronic obstructive pulmonary disease in a private institution in Medellin, during 2015. The software SPSS vr. 20 was used for the statistical analysis. For the quantitative variables, averages, standard deviations, and maximun and minimun values were calculated, while for ordinal and nominal qualitative variables, proportions were estimated. Results: The average age was 73.5±9.3 years, 52% of the patients were women, 50% of them had retired, 46% ere married and 80% lived in the city of Medellín. The mean time of diagnosis was 7.8±1.3 years and 100% of the patients were treated at the internal medicine service. The most common clinical features were: 36% were classified as class D for the disease, 34% had a FEV1 <30%, 88% had a history of smoking and 52% had oxygen therapy at home. Conclusion: It was found that class D was the most common, and the majority of the patients had a history of smoking, indicating the need to strengthen promotion and prevention strategies in this regard. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=pulmonary%20disease" title="pulmonary disease">pulmonary disease</a>, <a href="https://publications.waset.org/abstracts/search?q=chronic%20obstructive" title=" chronic obstructive"> chronic obstructive</a>, <a href="https://publications.waset.org/abstracts/search?q=pulmonary%20medicine" title=" pulmonary medicine"> pulmonary medicine</a>, <a href="https://publications.waset.org/abstracts/search?q=oxygen%20inhalation%20therapy" title=" oxygen inhalation therapy"> oxygen inhalation therapy</a> </p> <a href="https://publications.waset.org/abstracts/58057/clinical-and-epidemiological-profile-of-patients-with-chronic-obstructive-pulmonary-disease-in-a-medical-institution-from-the-city-of-medellin-colombia" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/58057.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">444</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">4</span> Clinical and Epidemiological Profile in Patients with Preeclampsia in a Private Institution in Medellin, Colombia 2015</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Camilo%20Andr%C3%A9s%20Agudelo%20V%C3%A9lez">Camilo Andrés Agudelo Vélez</a>, <a href="https://publications.waset.org/abstracts/search?q=Lina%20Mar%C3%ADa%20Mart%C3%ADnez%20S%C3%A1nchez"> Lina María Martínez Sánchez</a>, <a href="https://publications.waset.org/abstracts/search?q=Isabel%20Cristina%20Ortiz%20Trujillo"> Isabel Cristina Ortiz Trujillo</a>, <a href="https://publications.waset.org/abstracts/search?q=Evert%20Armando%20Jim%C3%A9nez%20Cotes"> Evert Armando Jiménez Cotes</a>, <a href="https://publications.waset.org/abstracts/search?q=Natalia%20Perilla%20Hern%C3%A1ndez"> Natalia Perilla Hernández</a>, <a href="https://publications.waset.org/abstracts/search?q=Mar%C3%ADa%20de%20los%20%C3%81ngeles%20Rodr%C3%ADguez%20G%C3%A1zquez"> María de los Ángeles Rodríguez Gázquez</a>, <a href="https://publications.waset.org/abstracts/search?q=Daniel%20Duque%20Restrepo"> Daniel Duque Restrepo</a>, <a href="https://publications.waset.org/abstracts/search?q=Felipe%20Hern%C3%A1ndez%20Restrepo"> Felipe Hernández Restrepo</a>, <a href="https://publications.waset.org/abstracts/search?q=Dayana%20Andrea%20Quintero%20Moreno"> Dayana Andrea Quintero Moreno</a>, <a href="https://publications.waset.org/abstracts/search?q=Juan%20Jos%C3%A9%20Builes%20G%C3%B3mez"> Juan José Builes Gómez</a>, <a href="https://publications.waset.org/abstracts/search?q=Camilo%20Ruiz%20Mej%C3%ADa"> Camilo Ruiz Mejía</a>, <a href="https://publications.waset.org/abstracts/search?q=Ana%20Lucia%20Arango%20G%C3%B3mez"> Ana Lucia Arango Gómez</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Preeclampsia is a clinical complication during pregnancy with high incidence in Colombia; therefore, it is important to evaluate the influence of external conditions and medical interventions, in order to promote measures that encourage improvements in the quality of life. Objective: Determine clinical and sociodemographic variables in women with preeclampsia. Methods: This cross-sectional study enrolled 50 patients with the diagnosis of preeclampsia, from a private institution in Medellin, during 2015. We used the software SPSS ver.20 for statistical analysis. For the qualitative variables, we calculated the mean and standard deviation, while, for ordinal and nominal levels of quantitative variables, ratios were estimated. Results: The average age was 26.8±5.9 years. The predominant characteristics were socioeconomic stratum 2 (48%), students (55%), mixed race (46%) and middle school as level of education (38%). As for clinical features, 72% of the cases were mild preeclampsia, and 22% were severe forms. The most common clinical manifestations were edema (46%), headache (62%), and proteinuria (55%). As for the Gyneco-obstetric history, 8% reported previous episodes of this disease and it was the first pregnancy for 60% of the patients. Conclusions: Preeclampsia is a frequent condition in young women; on the other hand, headache and edema were the most common reasons for consultation, therefore, doctors need to be aware of these symptoms in pregnant women. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=pre-eclampsia" title="pre-eclampsia">pre-eclampsia</a>, <a href="https://publications.waset.org/abstracts/search?q=hypertension" title=" hypertension"> hypertension</a>, <a href="https://publications.waset.org/abstracts/search?q=pregnancy%20complications" title=" pregnancy complications"> pregnancy complications</a>, <a href="https://publications.waset.org/abstracts/search?q=pregnancy" title=" pregnancy"> pregnancy</a>, <a href="https://publications.waset.org/abstracts/search?q=abdominal" title=" abdominal"> abdominal</a>, <a href="https://publications.waset.org/abstracts/search?q=edema" title=" edema"> edema</a> </p> <a href="https://publications.waset.org/abstracts/46372/clinical-and-epidemiological-profile-in-patients-with-preeclampsia-in-a-private-institution-in-medellin-colombia-2015" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/46372.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">363</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3</span> MAGNI Dynamics: A Vision-Based Kinematic and Dynamic Upper-Limb Model for Intelligent Robotic Rehabilitation</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Alexandros%20Lioulemes">Alexandros Lioulemes</a>, <a href="https://publications.waset.org/abstracts/search?q=Michail%20Theofanidis"> Michail Theofanidis</a>, <a href="https://publications.waset.org/abstracts/search?q=Varun%20Kanal"> Varun Kanal</a>, <a href="https://publications.waset.org/abstracts/search?q=Konstantinos%20Tsiakas"> Konstantinos Tsiakas</a>, <a href="https://publications.waset.org/abstracts/search?q=Maher%20Abujelala"> Maher Abujelala</a>, <a href="https://publications.waset.org/abstracts/search?q=Chris%20Collander"> Chris Collander</a>, <a href="https://publications.waset.org/abstracts/search?q=William%20B.%20Townsend"> William B. Townsend</a>, <a href="https://publications.waset.org/abstracts/search?q=Angie%20Boisselle"> Angie Boisselle</a>, <a href="https://publications.waset.org/abstracts/search?q=Fillia%20Makedon"> Fillia Makedon</a> </p> <p class="card-text"><strong>Abstract:</strong></p> This paper presents a home-based robot-rehabilitation instrument, called ”MAGNI Dynamics”, that utilized a vision-based kinematic/dynamic module and an adaptive haptic feedback controller. The system is expected to provide personalized rehabilitation by adjusting its resistive and supportive behavior according to a fuzzy intelligence controller that acts as an inference system, which correlates the user’s performance to different stiffness factors. The vision module uses the Kinect’s skeletal tracking to monitor the user’s effort in an unobtrusive and safe way, by estimating the torque that affects the user’s arm. The system’s torque estimations are justified by capturing electromyographic data from primitive hand motions (Shoulder Abduction and Shoulder Forward Flexion). Moreover, we present and analyze how the Barrett WAM generates a force-field with a haptic controller to support or challenge the users. Experiments show that by shifting the proportional value, that corresponds to different stiffness factors of the haptic path, can potentially help the user to improve his/her motor skills. Finally, potential areas for future research are discussed, that address how a rehabilitation robotic framework may include multisensing data, to improve the user’s recovery process. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=human-robot%20interaction" title="human-robot interaction">human-robot interaction</a>, <a href="https://publications.waset.org/abstracts/search?q=kinect" title=" kinect"> kinect</a>, <a href="https://publications.waset.org/abstracts/search?q=kinematics" title=" kinematics"> kinematics</a>, <a href="https://publications.waset.org/abstracts/search?q=dynamics" title=" dynamics"> dynamics</a>, <a href="https://publications.waset.org/abstracts/search?q=haptic%20control" title=" haptic control"> haptic control</a>, <a href="https://publications.waset.org/abstracts/search?q=rehabilitation%20robotics" title=" rehabilitation robotics"> rehabilitation robotics</a>, <a href="https://publications.waset.org/abstracts/search?q=artificial%20intelligence" title=" artificial intelligence"> artificial intelligence</a> </p> <a href="https://publications.waset.org/abstracts/58367/magni-dynamics-a-vision-based-kinematic-and-dynamic-upper-limb-model-for-intelligent-robotic-rehabilitation" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/58367.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">329</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">2</span> Design and Construction Demeanor of a Very High Embankment Using Geosynthetics</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Mariya%20Dayana">Mariya Dayana</a>, <a href="https://publications.waset.org/abstracts/search?q=Budhmal%20Jain"> Budhmal Jain</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Kannur International Airport Ltd. (KIAL) is a new Greenfield airport project with airside development on an undulating terrain with an average height of 90m above Mean Sea Level (MSL) and a maximum height of 142m. To accommodate the desired Runway length and Runway End Safety Area (RESA) at both the ends along the proposed alignment, it resulted in 45.5 million cubic meters in cutting and filling. The insufficient availability of land for the construction of free slope embankment at RESA 07 end resulted in the design and construction of Reinforced Soil Slope (RSS) with a maximum slope of 65 degrees. An embankment fill of average 70m height with steep slopes located in high rainfall area is a unique feature of this project. The design and construction was challenging being asymmetrical with curves and bends. The fill was reinforced with high strength Uniaxial geogrids laid perpendicular to the slope. Weld mesh wrapped with coir mat acted as the facia units to protect it against surface failure. Face anchorage were also provided by wrapping the geogrids along the facia units where the slope angle was steeper than 45 degrees. Considering high rainfall received on this table top airport site, extensive drainage system was designed for the high embankment fill. Gabion wall up to 10m height were also designed and constructed along the boundary to accommodate the toe of the RSS fill beside the jeepable track at the base level. The design of RSS fill was done using ReSSA software and verified in PLAXIS 2D modeling. Both slip surface failure and wedge failure cases were considered in static and seismic analysis for local and global failure cases. The site won excavated laterite soil was used as the fill material for the construction. Extensive field and laboratory tests were conducted during the construction of RSS system for quality assurance. This paper represents a case study detailing the design and construction of a very high embankment using geosynthetics for the provision of Runway length and RESA area. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=airport" title="airport">airport</a>, <a href="https://publications.waset.org/abstracts/search?q=embankment" title=" embankment"> embankment</a>, <a href="https://publications.waset.org/abstracts/search?q=gabion" title=" gabion"> gabion</a>, <a href="https://publications.waset.org/abstracts/search?q=high%20strength%20uniaxial%20geogrid" title=" high strength uniaxial geogrid"> high strength uniaxial geogrid</a>, <a href="https://publications.waset.org/abstracts/search?q=kial" title=" kial"> kial</a>, <a href="https://publications.waset.org/abstracts/search?q=laterite%20soil" title=" laterite soil"> laterite soil</a>, <a href="https://publications.waset.org/abstracts/search?q=plaxis%202d" title=" plaxis 2d"> plaxis 2d</a> </p> <a href="https://publications.waset.org/abstracts/104286/design-and-construction-demeanor-of-a-very-high-embankment-using-geosynthetics" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/104286.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">162</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">1</span> Geometric, Energetic and Topological Analysis of (Ethanol)₉-Water Heterodecamers</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Jennifer%20Cuellar">Jennifer Cuellar</a>, <a href="https://publications.waset.org/abstracts/search?q=Angie%20L.%20Parada"> Angie L. Parada</a>, <a href="https://publications.waset.org/abstracts/search?q=Kevin%20N.%20S.%20Chacon"> Kevin N. S. Chacon</a>, <a href="https://publications.waset.org/abstracts/search?q=Sol%20M.%20Mejia"> Sol M. Mejia</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The purification of bio-ethanol through distillation methods is an unresolved issue at the biofuel industry because of the ethanol-water azeotrope formation, which increases the steps of the purification process and subsequently increases the production costs. Therefore, understanding the mixture nature at the molecular level could provide new insights for improving the current methods and/or designing new and more efficient purification methods. For that reason, the present study focuses on the evaluation and analysis of (ethanol)₉-water heterodecamers, as the systems with the minimum molecular proportion that represents the azeotropic concentration (96 %m/m in ethanol). The computational modelling was carried out with B3LYP-D3/6-311++G(d,p) in Gaussian 09. Initial explorations of the potential energy surface were done through two methods: annealing simulated runs and molecular dynamics trajectories besides intuitive structures obtained from smaller (ethanol)n-water heteroclusters, n = 7, 8 and 9. The energetic order of the seven stable heterodecamers determines the most stable heterodecamer (Hdec-1) as a structure forming a bicyclic geometry with the O-H---O hydrogen bonds (HBs) where the water is a double proton donor molecule. Hdec-1 combines 1 water molecule and the same quantity of every ethanol conformer; this is, 3 trans, 3 gauche 1 and 3 gauche 2; its abundance is 89%, its decamerization energy is -80.4 kcal/mol, i.e. 13 kcal/mol most stable than the less stable heterodecamer. Besides, a way to understand why methanol does not form an azeotropic mixture with water, analogous systems ((ethanol)10, (methanol)10, and (methanol)9-water)) were optimized. Topologic analysis of the electron density reveals that Hec-1 forms 33 weak interactions in total: 11 O-H---O, 8 C-H---O, 2 C-H---C hydrogen bonds and 12 H---H interactions. The strength and abundance of the most unconventional interactions (H---H, C-H---O and C-H---O) seem to explain the preference of the ethanol for forming heteroclusters instead of clusters. Besides, O-H---O HBs present a significant covalent character according to topologic parameters as the Laplacian of electron density and the relationship between potential and kinetic energy densities evaluated at the bond critical points; obtaining negatives values and values between 1 and 2, for those two topological parameters, respectively. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=ADMP" title="ADMP">ADMP</a>, <a href="https://publications.waset.org/abstracts/search?q=DFT" title=" DFT"> DFT</a>, <a href="https://publications.waset.org/abstracts/search?q=ethanol-water%20azeotrope" title=" ethanol-water azeotrope"> ethanol-water azeotrope</a>, <a href="https://publications.waset.org/abstracts/search?q=Grimme%20dispersion%20correction" title=" Grimme dispersion correction"> Grimme dispersion correction</a>, <a href="https://publications.waset.org/abstracts/search?q=simulated%20annealing" title=" simulated annealing"> simulated annealing</a>, <a href="https://publications.waset.org/abstracts/search?q=weak%20interactions" title=" weak interactions"> weak interactions</a> </p> <a href="https://publications.waset.org/abstracts/114101/geometric-energetic-and-topological-analysis-of-ethanol9-water-heterodecamers" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/114101.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">103</span> </span> </div> </div> </div> </main> <footer> <div id="infolinks" class="pt-3 pb-2"> <div class="container"> <div style="background-color:#f5f5f5;" class="p-3"> <div class="row"> <div class="col-md-2"> <ul class="list-unstyled"> About <li><a href="https://waset.org/page/support">About Us</a></li> <li><a href="https://waset.org/page/support#legal-information">Legal</a></li> <li><a target="_blank" rel="nofollow" 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