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src="../_media/icons/logo_60.png" alt="WebElements logo"></a> <a class="white" href="./">Titanium - <sub>22</sub>Ti</a>&nbsp;&nbsp;<audio id="myAudio_f"> <source src="../_media/elements/snds_f/Ti.mp3" type="audio/mpeg">Your user agent does not support the HTML5 Audio element. </audio> <button class="pure-button d_button" style=" display: inline;" type="button" onclick="audf_play_pause()"> 🔊&nbsp; </button> <script> function audf_play_pause() { var myAudiof = document.getElementById("myAudio_f"); if (myAudiof.paused) { myAudiof.play(); } else { myAudiof.pause(); }} </script></span> </div> </div> </div> <div id="main"> <!-- element specific content--> <div class="pure-u-1 pure-u-sm-1-1"> <div class="pure-menu pure-menu-horizontal pure-menu-scrollable"> <a href="#" class="pure-menu-link pure-menu-heading">▸▸</a> <ul class="pure-menu-list"> <li class="pure-menu-item">🇬🇧&nbsp;Titanium</li> <li class="pure-menu-item">🇺🇦&nbsp;Титан</li> <li class="pure-menu-item">🇨🇳&nbsp;鈦</li> <li class="pure-menu-item">🇳🇱&nbsp;Titaan</li> <li class="pure-menu-item">🇫🇷&nbsp;Titane</li> <li class="pure-menu-item">🇩🇪&nbsp;Titan</li> <li class="pure-menu-item">🇮🇱&nbsp;טיטניום</li> <li class="pure-menu-item">🇮🇹&nbsp;Titanio</li> <li class="pure-menu-item">🇯🇵&nbsp;チタン</li> <li class="pure-menu-item">🇵🇹&nbsp;Tit&acirc;nio</li> <li class="pure-menu-item">🇪🇸&nbsp;Titanio</li> <li class="pure-menu-item">🇸🇪&nbsp;Titan</li> <li class="pure-menu-item">🇷🇺&nbsp;Титан</li> </ul> </div> </div> <div class="pure-g"> <div class="pure-u-1 pure-u-sm-1-1"> <div class="google_navbar_positioning"> <form action="https://www.google.com" id="cse-search-box"> <div> <input type="hidden" name="cx" value="partner-pub-9334432533380510:6223510783"> <input type="hidden" name="ie" value="UTF-8"> <input type="text" name="q" size="28"> <input type="submit" name="sa" value="Search"> </div> </form> <script> </script> </div> </div> </div> <main> <div class="pure-g"> <div class="pure-u-1 pure-u-sm-1-1"> <h1 class="d">Titanium - <sub><small>22</small></sub>Ti: isotope data</h1> <div class="pure-menu pure-menu-horizontal pure-menu-scrollable"> <ul class="pure-menu-list z_menu"> <li class="pure-menu-item d"><a href="../titanium/" class="pure-menu-link">▸▸ Ti Essentials</a></li> <li class="pure-menu-item d"><a class="pure-menu-link" href="../titanium/physics.html">Physical properties</a></li> <li class="pure-menu-item d"><a class="pure-menu-link" href="../titanium/atoms.html">Electron shell data</a></li> <li class="pure-menu-item d"><a class="pure-menu-link" href="../titanium/atom_sizes.html">Atom sizes</a></li> <li class="pure-menu-item d"><a class="pure-menu-link" href="../titanium/electronegativity.html">Electronegativity</a></li> <li class="pure-menu-item d"><a class="pure-menu-link" href="../titanium/isotopes.html" >Isotopes and NMR</a></li> <li class="pure-menu-item d"><a class="pure-menu-link" href="../titanium/crystal_structure.html">Crystal structure</a></li> <li class="pure-menu-item d"><a class="pure-menu-link" href="../titanium/thermochemistry.html">Thermochemistry</a></li> <li class="pure-menu-item d"><a class="pure-menu-link" href="../titanium/history.html">History</a></li> <li class="pure-menu-item d"><a class="pure-menu-link" href="../titanium/uses.html">Uses</a></li> <li class="pure-menu-item d"><a class="pure-menu-link" href="../titanium/geology.html">Geology</a></li> <li class="pure-menu-item d"><a class="pure-menu-link" href="../titanium/biology.html">Biology</a></li> <li class="pure-menu-item d"><a class="pure-menu-link" href="../titanium/compounds.html">Binary compounds</a></li> <li class="pure-menu-item d"><a class="pure-menu-link" href="../titanium/compound_properties.html" >Compound properties</a></li> <li class="pure-menu-item d"><a class="pure-menu-link" href="../titanium/chemistry.html">Element reactions</a></li> <li class="pure-menu-item d"><a class="pure-menu-link" href="../titanium/contents.html">List all Ti properties</a></li> </ul> </div> </div> </div> <p class="p_first">The five stable Titanium isotopes are used for a wide range of studies and applications. Ti-48 is used for the production of the radioisotope V-48 which is used in nutritional studies and for calibrating PET instrumentation. Ti-47 is occasionally used as an alternative precursor for the production of V-48. Ti-50 is used in the production of super heavy elements whereby Lead or Bismuth targets are bombarded with Ti-50. Finally, Ti-49 is used in the production of the radioisotope V-49.</p> <h2 class="d">Naturally occurring isotopes</h2> <div class="table-responsive"> <table class="pure-table"> <caption>This table shows information about <a href="../periodicity/isotopes/">naturally occuring isotopes</a>, their <a href="../periodicity/isotopes/">atomic masses</a>, their <a href="../periodicity/isotopes/">natural abundances</a>, their <a href="../periodicity/isotopes_nuclear_spin/">nuclear spins</a>, and their <a href="../periodicity/isotopes_nuc_magnetic_moment/">magnetic moments</a>. Further data for radioisotopes (radioactive isotopes) of titanium are listed (including any which occur naturally) below. </caption> <thead> <tr> <th>Isotope</th> <th>Mass&nbsp;/&nbsp;Da</th> <th>Natural abundance (atom %)</th> <th>Nuclear spin (I)</th> <th>Magnetic moment (&mu;/&mu;<sub>N</sub>)</th> </tr> </thead> <tbody> <tr> <td><sup>46</sup>Ti</td> <td>45.9526294 (14)</td> <td>8.25 (3)</td> <td>0</td> <td></td> </tr><tr> <td><sup>47</sup>Ti</td> <td>46.9517640 (11)</td> <td>7.44 (2)</td> <td><sup>5</sup>/<sub>2</sub></td> <td>-0.78848</td> </tr><tr> <td><sup>48</sup>Ti</td> <td>47.9479473 (11)</td> <td>73.72 (3)</td> <td>0</td> <td></td> </tr><tr> <td><sup>49</sup>Ti</td> <td>48.9478711 (11)</td> <td>5.41 (2)</td> <td><sup>7</sup>/<sub>2</sub></td> <td>-1.10417</td> </tr><tr> <td><sup>50</sup>Ti</td> <td>49.9447921 (12)</td> <td>5.18 (2)</td> <td>0</td> <td></td> </tr></tbody></table> </div> <div><figure><img class="pure-img" src="../_media/elements/isotopes/isotope_abundance_Ti.png" alt="Isotope abundances of titanium" /><figcaption><strong>Isotope abundances of titanium.</strong> In the above, the most intense ion is set to 100% since this corresponds best to the output from a mass spectrometer. This is not to be confused with the relative percentage isotope abundances which <strong>totals</strong> 100% for all the naturally occurring isotopes.</figcaption> </figure> </div> <div class="pure-g"> <div class="pure-u-1 pure-u-sm-1-1"> <script async src="//pagead2.googlesyndication.com/pagead/js/adsbygoogle.js"></script> <!-- elements_responsive_centre --> <ins class="adsbygoogle" style="display:block" data-ad-client="ca-pub-9334432533380510" data-ad-slot="4479092381" data-ad-format="auto"></ins> <script> (adsbygoogle = window.adsbygoogle || []).push({}); </script> </div> </div> <h2 class="d">Radiosotope data</h2> <div class="table-responsive"> <table class="pure-table"> <caption>Further data for naturally occuring isotopes of titanium are listed above. This table gives information about some <a href="../periodicity/isotopes_radioactive/">radiosotopes</a> of titanium, their <a href="../periodicity/isotopes_radioactive/">masses</a>, their <a href="../periodicity/isotopes_radioactive/">half-lives</a>, their <a href="../periodicity/isotopes_radioactive/">modes of decay</a>, their <a href="../periodicity/isotopes_radioactive/">nuclear spins</a>, and their <a href="../periodicity/isotopes_radioactive/">nuclear magnetic moments</a>.</caption> <thead> <tr> <th>Isotope</th> <th>Mass&nbsp;/&nbsp;Da</th> <th>Half-life</th> <th>Mode of decay</th> <th>Nuclear spin</th> <th>Nuclear magnetic moment</th> </tr> </thead> <tbody> <tr> <td><sup>44</sup>Ti </td> <td>43.959690</td> <td>67 y </td> <td>EC to <sup>44</sup>Sc</td> <td>0</td> <td></td> </tr><tr> <td><sup>45</sup>Ti</td> <td>44.958124</td> <td>3.078 h</td> <td>EC to <sup>45</sup>Sc</td> <td><sup>7</sup>/<sub>2</sub></td> <td>0.095</td> </tr><tr> <td><sup>51</sup>Ti</td> <td>50.946616</td> <td>5.76 m</td> <td>&beta;<sup>-</sup> to <sup>51</sup>V</td> <td>0</td> <td></td> </tr><tr> <td><sup>52</sup>Ti</td> <td>51.94690</td> <td>1.7 m</td> <td>&beta;<sup>-</sup> to <sup>52</sup>V</td> <td><sup>3</sup>/<sub>2</sub></td> <td></td> </tr><tr> <td> </td> <td></td> <td></td> <td></td> <td></td> <td></td> </tr><tr> <td></td> <td></td> <td></td> <td></td> <td></td> <td></td> </tr></tbody></table> </div> <h2 class="d">References</h2> <ol> <li>Naturally occurring isotope abundances: Commission on Atomic Weights and Isotopic Abundances report for the International Union of Pure and Applied Chemistry in <em>Isotopic Compositions of the Elements 1989</em>, Pure and Applied Chemistry, 1998, <strong>70</strong>, 217. [Copyright 1998 IUPAC]</li> <li>For further information about radioisotopes see Jonghwa Chang's (Korea Atomic Energy Research Institute) <a href="http://atom.kaeri.re.kr/">Table of the Nuclides</a></li> <li>Masses, nuclear spins, and magnetic moments: I. Mills, T. Cvitas, K. Homann, N. Kallay, and K. Kuchitsu in <em>Quantities, Units and Symbols in Physical Chemistry</em>, Blackwell Scientific Publications, Oxford, UK, 1988. [Copyright 1988 IUPAC]</li> </ol> <h2 class="d"><a id="essentials"></a>NMR Properties of titanium</h2> <p class="p_first"><strong>Common reference compound:</strong> TiCl<sub>4</sub>, neat.</p> <div class="table-responsive"> <table class="pure-table pure-table-striped"> <caption>Table of NMR-active nucleus propeties of titanium</caption> <thead> <tr> <td>&nbsp;</td> <th>Isotope 1</th> <th>Isotope 2</th> <th>Isotope 3</th> </tr> </thead> <tbody> <tr> <td><a href="../periodicity/nmr/">Isotope</a></td> <td><sup>47</sup>Ti</td> <td><sup>49</sup>Ti</td> <td></td> </tr> <tr> <td><a href="../periodicity/nmr/">Natural abundance </a>/%</td> <td>7.44</td> <td>5.41</td> <td></td> </tr> <tr> <td><a href="../periodicity/nmr/">Spin</a> (I)</td> <td><sup>5</sup>/<sub>2</sub></td> <td><sup>7</sup>/<sub>2</sub></td> <td></td> </tr> <tr> <td><a href="../periodicity/nmr/">Frequency</a> relative to <sup>1</sup>H = 100 (MHz)</td> <td>5.637534</td> <td>5.639037</td> <td></td> </tr> <tr> <td><a href="../periodicity/nmr/">Receptivity</a>, D<sup>P</sup>, relative to <sup>1</sup>H = 1.00</td> <td>0.000156</td> <td>0.000205</td> <td></td> </tr> <tr> <td><a href="../periodicity/nmr/">Receptivity</a>, D<sup>C</sup>, relative to <sup>13</sup>C = 1.00</td> <td>0.918</td> <td>1.20</td> <td></td> </tr> <tr> <td><a href="../periodicity/nmr/">Magnetogyric ratio</a>, &gamma; (10<sup>7</sup> rad&nbsp;T<sup>&#8209;1</sup>&nbsp;s<sup>-1</sup>)</td> <td>-1.5105</td> <td>-1.51095</td> <td></td> </tr> <tr> <td><a href="../periodicity/nmr/">Magnetic moment</a>, &mu; (&mu;<sub>N</sub>)</td> <td>-0.93294</td> <td>-1.25201</td> <td></td> </tr> <tr> <td><a href="../periodicity/nmr/">Nuclear quadrupole moment</a>, Q/millibarn</td> <td>302(10)</td> <td>247(11)</td> <td></td> </tr> <tr> <td><a href="../periodicity/nmr/">Line width factor</a>, 10<sup>56</sup> l (m<sup>4</sup>)</td> <td>290</td> <td>83</td> <td></td> </tr> </tbody> </table> </div> <h2 class="d">References</h2> <ol> <li>R.K. Harris in <em>Encyclopedia of Nuclear Magnetic Resonance</em>, D.M. Granty and R.K. Harris, (eds.), vol. 5, John Wiley &amp; Sons, Chichester, UK, 1996. I am grateful to <a href="http://www.dur.ac.uk/chemistry/staff/profile/?id=184">Professor Robin Harris</a> (University of Durham, UK) who provided much of the NMR data, which are copyright 1996 IUPAC, adapted from his contribution contained within this reference.</li> <li>J. Mason in <em>Multinuclear NMR</em>, Plenum Press, New York, USA, 1987. Where given, data for certain radioactive nuclei are from this reference.</li> <li>P. Pyykk&ouml;, <em>Mol. Phys.</em>, 2008, <strong>106</strong>, 1965-1974.</li> <li>P. Pyykk&ouml;, <em>Mol. Phys.</em>, 2001, <strong>99</strong>, 1617-1629.</li> <li>P. Pyykk&ouml;, <em>Z. Naturforsch.</em>, 1992, <strong>47a</strong>, 189. I am grateful to <a href="http://www.chem.helsinki.fi/~pyykko/">Professor Pekka Pyykk&ouml;</a> (University of Helsinki, Finland) who provided the nuclear quadrupole moment data in this and the following two references.</li> <li>D.R. Lide, (ed.), <em><a href="http://www.amazon.com/exec/obidos/ASIN/0849304814/webelements">CRC Handbook of Chemistry and Physics 1999-2000 : A Ready-Reference Book of Chemical and Physical Data (CRC Handbook of Chemistry and Physics</a></em>, CRC Press, Boca Raton, Florida, USA, 79th edition, 1998.</li> <li>P. 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