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C60: Buckminsterfullerene | Nature

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Concerning the question of what kind of 60-carbon atom structure might give rise to a superstable species, we suggest a truncated icosahedron, a polygon with 60 vertices and 32 faces, 12 of which are pentagonal and 20 hexagonal. This object is commonly encountered as the football shown in Fig. 1. The C60 molecule which results when a carbon atom is placed at each vertex of this structure has all valences satisfied by two single bonds and one double bond, has many resonance structures, and appears to be aromatic. Before 1985, it was generally accepted that elemental carbon exists in two forms, or allotropes: diamond and graphite. Then, Kroto et al. identified the signature of a new, stable form of carbon that consisted of clusters of 60 atoms. They called this third allotrope of carbon 'buckminsterfullerene', and proposed that it consisted of polyhedral molecules in which the atoms were arrayed at the vertices of a truncated icosahedron. In 1990, the synthesis of large quantities of C60 [see Nature 347, 354–358 (1990)] confirmed this hypothesis.","datePublished":"","dateModified":"","pageStart":"162","pageEnd":"163","sameAs":"https://doi.org/10.1038/318162a0","keywords":["Science","Humanities and Social Sciences","multidisciplinary"],"image":[],"isPartOf":{"name":"Nature","issn":["1476-4687","0028-0836"],"volumeNumber":"318","@type":["Periodical","PublicationVolume"]},"publisher":{"name":"Nature Publishing Group UK","logo":{"url":"https://www.springernature.com/app-sn/public/images/logo-springernature.png","@type":"ImageObject"},"@type":"Organization"},"author":[{"name":"H. W. Kroto","affiliation":[{"name":"Rice Quantum Institute and Departments of Chemistry and Electrical Engineering, Rice University, Houston, Texas 77251, USA","address":{"name":"Rice Quantum Institute and Departments of Chemistry and Electrical Engineering, Rice University, Houston, Texas 77251, USA","@type":"PostalAddress"},"@type":"Organization"},{"name":"Permanent address: School of Chemistry and Molecular Sciences, University of Sussex, Brighton BN1 9QJ, UK.","address":{"name":"Permanent address: School of Chemistry and Molecular Sciences, University of Sussex, Brighton BN1 9QJ, UK.","@type":"PostalAddress"},"@type":"Organization"}],"@type":"Person"},{"name":"J. R. 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Curl","affiliation":[{"name":"Rice Quantum Institute and Departments of Chemistry and Electrical Engineering, Rice University, Houston, Texas 77251, USA","address":{"name":"Rice Quantum Institute and Departments of Chemistry and Electrical Engineering, Rice University, Houston, Texas 77251, USA","@type":"PostalAddress"},"@type":"Organization"}],"@type":"Person"},{"name":"R. E. Smalley","affiliation":[{"name":"Rice Quantum Institute and Departments of Chemistry and Electrical Engineering, Rice University, Houston, Texas 77251, USA","address":{"name":"Rice Quantum Institute and Departments of Chemistry and Electrical Engineering, Rice University, Houston, Texas 77251, USA","@type":"PostalAddress"},"@type":"Organization"}],"@type":"Person"}],"isAccessibleForFree":false,"hasPart":{"isAccessibleForFree":false,"cssSelector":".main-content","@type":"WebPageElement"},"@type":"ScholarlyArticle"},"@context":"https://schema.org","@type":"WebPage"}</script> <link rel="canonical" href="https://www.nature.com/articles/318162a0"> <meta name="journal_id" content="41586"/> <meta name="dc.title" content="C60: Buckminsterfullerene"/> <meta name="dc.source" content="Nature 1985 318:6042"/> <meta name="dc.format" content="text/html"/> <meta name="dc.publisher" content="Nature Publishing Group"/> <meta name="dc.type" content="OriginalPaper"/> <meta name="dc.language" content="En"/> <meta name="dc.copyright" content="1985 Springer Nature Limited"/> <meta name="dc.rights" content="1985 Springer Nature Limited"/> <meta name="dc.rightsAgent" content="journalpermissions@springernature.com"/> <meta name="dc.description" content="During experiments aimed at understanding the mechanisms by which long-chain carbon molecules are formed in interstellar space and circumstellar shells1, graphite has been vaporized by laser irradiation, producing a remarkably stable cluster consisting of 60 carbon atoms. 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itemscope itemtype="https://schema.org/ListItem"> <span itemprop="name">article</span><meta itemprop="position" content="3"></li> </ol> </div> </nav> </div> <div class="u-container u-mt-32 u-mb-32 u-clearfix" id="content" data-component="article-container" data-container-type="article"> <main class="c-article-main-column u-float-left js-main-column" data-track-component="article body"> <article lang="en"> <div class="c-article-header"> <header> <ul class="c-article-identifiers" data-test="article-identifier"> <li class="c-article-identifiers__item" data-test="article-category">Letter</li> <li class="c-article-identifiers__item">Published: <time datetime="1985-11-14">14 November 1985</time></li> </ul> <h1 class="c-article-title" data-test="article-title" data-article-title="">C<sub>60</sub>: Buckminsterfullerene</h1> <ul class="c-article-author-list c-article-author-list--short" data-test="authors-list" data-component-authors-activator="authors-list"><li class="c-article-author-list__item"><a data-test="author-name" data-track="click" data-track-action="open author" data-track-label="link" href="#auth-H__W_-Kroto-Aff1-Aff2" data-author-popup="auth-H__W_-Kroto-Aff1-Aff2" data-author-search="Kroto, H. W.">H. W. Kroto</a><sup class="u-js-hide"><a href="#Aff1">1</a>,<a href="#Aff2">2</a></sup>, </li><li class="c-article-author-list__item"><a data-test="author-name" data-track="click" data-track-action="open author" data-track-label="link" href="#auth-J__R_-Heath-Aff1" data-author-popup="auth-J__R_-Heath-Aff1" data-author-search="Heath, J. R.">J. R. Heath</a><sup class="u-js-hide"><a href="#Aff1">1</a></sup>, </li><li class="c-article-author-list__item c-article-author-list__item--hide-small-screen"><a data-test="author-name" data-track="click" data-track-action="open author" data-track-label="link" href="#auth-S__C_-O_Brien-Aff1" data-author-popup="auth-S__C_-O_Brien-Aff1" data-author-search="O’Brien, S. C.">S. C. 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Smalley</a><sup class="u-js-hide"><a href="#Aff1">1</a></sup> </li></ul><button aria-expanded="false" class="c-article-author-list__button"><svg width="16" height="16" focusable="false" role="img" aria-hidden="true" class="u-icon"><use xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="#icon-eds-i-chevron-down-medium"></use></svg><span>Show authors</span></button> <p class="c-article-info-details" data-container-section="info"> <a data-test="journal-link" href="/" data-track="click" data-track-action="journal homepage" data-track-category="article body" data-track-label="link"><i data-test="journal-title">Nature</i></a> <b data-test="journal-volume"><span class="u-visually-hidden">volume</span> 318</b>, <span class="u-visually-hidden">pages </span>162–163 (<span data-test="article-publication-year">1985</span>)<a href="#citeas" class="c-article-info-details__cite-as u-hide-print" data-track="click" data-track-action="cite this article" data-track-label="link">Cite this article</a> </p> <div class="c-article-metrics-bar__wrapper u-clear-both"> <ul class="c-article-metrics-bar u-list-reset"> <li class=" c-article-metrics-bar__item" data-test="access-count"> <p class="c-article-metrics-bar__count">62k <span class="c-article-metrics-bar__label">Accesses</span></p> </li> <li class="c-article-metrics-bar__item" data-test="citation-count"> <p class="c-article-metrics-bar__count">14k <span class="c-article-metrics-bar__label">Citations</span></p> </li> <li class="c-article-metrics-bar__item" data-test="altmetric-score"> <p class="c-article-metrics-bar__count">293 <span class="c-article-metrics-bar__label">Altmetric</span></p> </li> <li class="c-article-metrics-bar__item"> <p class="c-article-metrics-bar__details"><a href="/articles/318162a0/metrics" data-track="click" data-track-action="view metrics" data-track-label="link" rel="nofollow">Metrics <span class="u-visually-hidden">details</span></a></p> </li> </ul> </div> </header> </div> <div class="c-article-body"> <div class="c-article-section__content c-article-section__content--standfirst u-text-bold" lang="en"><p>During experiments aimed at understanding the mechanisms by which long-chain carbon molecules are formed in interstellar space and circumstellar shells<sup>1</sup>, graphite has been vaporized by laser irradiation, producing a remarkably stable cluster consisting of 60 carbon atoms. Concerning the question of what kind of 60-carbon atom structure might give rise to a superstable species, we suggest a truncated icosahedron, a polygon with 60 vertices and 32 faces, 12 of which are pentagonal and 20 hexagonal. This object is commonly encountered as the football shown in Fig. 1. The C<sub>60</sub> molecule which results when a carbon atom is placed at each vertex of this structure has all valences satisfied by two single bonds and one double bond, has many resonance structures, and appears to be aromatic.</p></div> <noscript> <div class="c-nature-box c-nature-box--side " data-component="entitlement-box"> <div class="js-access-button"> <a href="https://wayf.springernature.com?redirect_uri&#x3D;https%3A%2F%2Fwww.nature.com%2Farticles%2F318162a0" class="c-article__button" data-test="ra21"> <svg class="u-icon" width="18" height="18" aria-hidden="true" focusable="false"><use href="#icon-institution"></use></svg> <span class="c-article__button-text">Access through your institution</span> </a> </div> <div class="js-buy-button"> <a href="#access-options" class="c-article__button c-article__button--inverted" data-test="ra21"> <span>Buy or subscribe</span> </a> </div> </div> </noscript> <div class="js-context-bar-sticky-point-mobile" data-track-context="article body"> 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W. Kroto, J. R. Heath, S. C. O’Brien, R. F. Curl &amp; R. E. Smalley</p></li><li id="Aff2"><p class="c-article-author-affiliation__address">Permanent address: School of Chemistry and Molecular Sciences, University of Sussex, Brighton BN1 9QJ, UK. <a rel="nofollow" href="https://www.nature.com/nature">https://www.nature.com/nature</a></p><p class="c-article-author-affiliation__authors-list">H. W. Kroto</p></li></ol><div class="u-js-hide u-hide-print" data-test="author-info"><span class="c-article__sub-heading">Authors</span><ol class="c-article-authors-search u-list-reset"><li id="auth-H__W_-Kroto-Aff1-Aff2"><span class="c-article-authors-search__title u-h3 js-search-name">H. W. 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<i>Nature</i> <b>318</b>, 162–163 (1985). https://doi.org/10.1038/318162a0</p><p class="c-bibliographic-information__download-citation u-hide-print"><a data-test="citation-link" data-track="click" data-track-action="download article citation" data-track-label="link" data-track-external="" rel="nofollow" href="https://citation-needed.springer.com/v2/references/10.1038/318162a0?format=refman&amp;flavour=citation">Download citation<svg width="16" height="16" focusable="false" role="img" aria-hidden="true" class="u-icon"><use xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="#icon-eds-i-download-medium"></use></svg></a></p><ul class="c-bibliographic-information__list" data-test="publication-history"><li class="c-bibliographic-information__list-item"><p>Received<span class="u-hide">: </span><span class="c-bibliographic-information__value"><time datetime="1985-09-13">13 September 1985</time></span></p></li><li class="c-bibliographic-information__list-item"><p>Accepted<span 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