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Phosphides | AMERICAN ELEMENTS 庐
<!DOCTYPE html> <html lang="en"> <head> <title>Phosphides | AMERICAN ELEMENTS 庐</title> <!--[if IE]><![endif]--> <meta charset="utf-8" /> <link rel="dns-prefetch" href="//www.americanelements.com" /> <link rel="dns-prefetch" href="//fonts.gstatic.com" /> <link rel="shortcut icon" href="https://www.americanelements.com/sites/all/themes/gratis_ae_subtheme/favicon.ico" type="image/vnd.microsoft.icon" /> <meta name="viewport" content="width=device-width, initial-scale=1, maximum-scale=1, user-scalable=no" /> <meta name="description" content="American Elements Phosphides online product catalog" /> <meta name="keywords" content="Phosphides product group" /> <link rel="canonical" href="https://www.americanelements.com/Phosphides.html" /> <meta http-equiv="content-language" content="en" /> <meta property="og:site_name" content="American Elements" /> <meta property="og:type" content="product.group" /> <meta property="og:description" content="Phosphides are compounds of phosphorus with one or more less electronegative elements. Most elements less-electronegative than phosphorus form at least one binary phosphide, and most form a number of binary phosphides with different stoichiometries. Notably, potassium is capable of forming nine different binary phosphides: K3P, K4P3, K5P4, KP, K4P6, K3P7, K3P11, KP10.3, KP15. Phosphides may be principally ionic compounds with P3- ions, ionic compounds with polymeric phosphorus ions such as P24- or P113-, or compounds with individual phosphorus atoms incorporated into a metal lattice which may exhibit metal-like or semiconductor-like properties. Although there are a number of ways to prepare phosphides, the most general method is to heat stoichiometric amounts of the metal and red phosphorus to high temperature in an inert atmosphere or a vacuum. Alkali and alkaline earth metals transition-metal phosphides are inert metallic-looking solids with high melting points and electrical conductivities. Some metal phosphides have been used as rodenticides, primarily calcium phosphide, zinc phosphide, and aluminum phosphide. Zinc phosphide baits have strong, pungent garlic-like odor characteristic for phosphine liberated by hydrolysis. The odor attracts rodents, but has a repulsive effect on other animals. Aluminum phosphide is also wide band gap semiconductor. Calcium phosphide has uses in incendiary bombs. On contact with acids or water, calcium phosphide releases phosphine, which ignites spontaneously. Calcium phosphide is also used in fireworks, torpedoes, self-igniting naval pyrotechnic flares, and various water-activated ammunition. Gallium phosphide is an important semiconducting phosphide used in the manufacture of low-cost red, orange, and green light-emitting diodes (LEDs) with low to medium brightness since the 1960s. It has a relatively short life at higher current and its lifetime is sensitive to temperature. Pure gallium phosphide LEDs emit green light at a wavelength of 555 nm. Nitrogen-doped gallium phosphide emits yellow-green (565 nm) light, zinc oxide doped gallium phosphide emits red (700 nm). Indium phosphide is a semiconductor and is used in high-power and high-frequency electronics because of its superior electron velocity with respect to the more common semiconductors such as gallium arsenide. Indium phosphide also has one of the longest-lived optical phonons of any compound with the zincblende crystal structure. Sodium phosphide is a source of the highly reactive phosphide anion, and is often employed commercially in conjunction with zinc phosphide and aluminum phosphide as a catalyst in polymer production. Sodium phosphide is highly dangerous, releasing toxic phosphine upon hydrolysis, a process that is so exothermic that it may result in fires." /> <meta name="twitter:card" content="summary" /> <meta name="twitter:url" content="https://www.americanelements.com/phosphides.html" /> <meta name="twitter:title" content="Phosphides" /> <meta name="twitter:description" content="Phosphides are compounds of phosphorus with one or more less electronegative elements. Most elements less-electronegative than phosphorus form at least one binary phosphide, and most form a number of" /> <meta itemprop="name" content="Phosphides" /> <meta itemprop="description" content="Phosphides are compounds of phosphorus with one or more less electronegative elements. Most elements less-electronegative than phosphorus form at least one binary phosphide, and most form a number of binary phosphides with different stoichiometries. Notably, potassium is capable of forming nine different binary phosphides: K3P, K4P3, K5P4, KP, K4P6, K3P7, K3P11, KP10.3, KP15. Phosphides may be principally ionic compounds with P3- ions, ionic compounds with polymeric phosphorus ions such as P24- or P113-, or compounds with individual phosphorus atoms incorporated into a metal lattice which may exhibit metal-like or semiconductor-like properties. Although there are a number of ways to prepare phosphides, the most general method is to heat stoichiometric amounts of the metal and red phosphorus to high temperature in an inert atmosphere or a vacuum. Alkali and alkaline earth metals transition-metal phosphides are inert metallic-looking solids with high melting points and electrical conductivities. Some metal phosphides have been used as rodenticides, primarily calcium phosphide, zinc phosphide, and aluminum phosphide. Zinc phosphide baits have strong, pungent garlic-like odor characteristic for phosphine liberated by hydrolysis. The odor attracts rodents, but has a repulsive effect on other animals. Aluminum phosphide is also wide band gap semiconductor. Calcium phosphide has uses in incendiary bombs. On contact with acids or water, calcium phosphide releases phosphine, which ignites spontaneously. Calcium phosphide is also used in fireworks, torpedoes, self-igniting naval pyrotechnic flares, and various water-activated ammunition. Gallium phosphide is an important semiconducting phosphide used in the manufacture of low-cost red, orange, and green light-emitting diodes (LEDs) with low to medium brightness since the 1960s. It has a relatively short life at higher current and its lifetime is sensitive to temperature. Pure gallium phosphide LEDs emit green light at a wavelength of 555 nm. Nitrogen-doped gallium phosphide emits yellow-green (565 nm) light, zinc oxide doped gallium phosphide emits red (700 nm). Indium phosphide is a semiconductor and is used in high-power and high-frequency electronics because of its superior electron velocity with respect to the more common semiconductors such as gallium arsenide. Indium phosphide also has one of the longest-lived optical phonons of any compound with the zincblende crystal structure. Sodium phosphide is a source of the highly reactive phosphide anion, and is often employed commercially in conjunction with zinc phosphide and aluminum phosphide as a catalyst in polymer production. Sodium phosphide is highly dangerous, releasing toxic phosphine upon hydrolysis, a process that is so exothermic that it may result in fires." /> <link rel="apple-touch-icon" href="/apple-touch-icon.png" /> <link rel="apple-touch-icon" sizes="57x57" href="/apple-touch-icon-57x57.png" /> <link rel="apple-touch-icon" sizes="72x72" href="/apple-touch-icon-72x72.png" /> <link rel="apple-touch-icon" sizes="76x76" href="/apple-touch-icon-76x76.png" /> <link rel="apple-touch-icon" sizes="114x114" href="/apple-touch-icon-114x114.png" /> <link rel="apple-touch-icon" sizes="120x120" href="/apple-touch-icon-120x120.png" /> <link rel="apple-touch-icon" sizes="144x144" href="/apple-touch-icon-144x144.png" /> <link rel="apple-touch-icon" sizes="152x152" href="/apple-touch-icon-152x152.png" /> <link rel="apple-touch-icon" sizes="180x180" href="/apple-touch-icon-180x180.png" /> <meta name="MobileOptimized" content="width"> <meta name="HandheldFriendly" content="true"> <meta 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pane-product-page-lists-panel-pane-9" ><div class="pane-content"><div class="view view-product-page-lists view-id-product_page_lists view-display-id-panel_pane_9 link-grids view-dom-id-bc3baa52062a17a08aa1f524de1e5d3a"><div class="view-content"><div class="view-grouping"><h3>A</h3><div> <a href="/aginp2se6-crystal">AgInP2Se6 Crystal</a></div><div> <a href="/aluminium-gallium-indium-phosphide-163207-18-9">Aluminium Gallium Indium Phosphide</a></div><div> <a href="/aluminum-gallium-phosphide">Aluminum Gallium Phosphide</a></div><div> <a href="/aluminum-phosphide-20859-73-8">Aluminum Phosphide</a></div><div> <a href="/aluminum-phosphide-sputtering-target-20859-73-8">Aluminum Phosphide Sputtering Target</a></div><div> <a href="/antimony-phosphide-53120-23-3">Antimony Phosphide</a></div><div> <a href="/antimony-phosphide-sputtering-target-53120-23-3">Antimony Phosphide Sputtering Target</a></div><div> <a href="/arsenic-monophosphide-12255-33-3">Arsenic Monophosphide</a></div><div> <a href="/arsenic-phosphide-12511-95-4">Arsenic Phosphide</a></div><div> <a href="/arsenic-phosphide-sputtering-target-12511-95-4">Arsenic Phosphide Sputtering Target</a></div></div><div class="view-grouping"><h3>B</h3><div> <a href="/barium-phosphide-12380-72-2">Barium Phosphide</a></div><div> <a href="/beryllium-phosphide-58127-61-0">Beryllium Phosphide</a></div><div> <a href="/bismuth-phosphide-12330-83-5">Bismuth Phosphide</a></div><div> <a href="/bismuth-phosphide-sputtering-target-12330-83-5">Bismuth Phosphide Sputtering Target</a></div><div> <a href="/boron-phosphide-20205-91-8">Boron Phosphide</a></div></div><div class="view-grouping"><h3>C</h3><div> <a href="/cadmium-phosphide-cd3p2-12014-28-7">Cadmium Phosphide Cd3P2</a></div><div> <a href="/cadmium-phosphide-cdp2-12133-44-7">Cadmium Phosphide CdP2</a></div><div> <a href="/cadmium-phosphide-sputtering-target-12014-28-7">Cadmium Phosphide Sputtering Target</a></div><div> <a href="/calcium-phosphide-1305-99-3">Calcium Phosphide</a></div><div> <a href="/calcium-phosphide-sputtering-target-1305-99-3">Calcium Phosphide Sputtering Target</a></div><div> <a href="/cdps3-crystal">CdPS3 Crystal</a></div><div> <a href="/cerium-phosphide-25275-75-6">Cerium Phosphide</a></div><div> <a href="/cesium-phosphide-113737-02-3">Cesium Phosphide</a></div><div> <a href="/cesium-phosphide-sputtering-target-113737-02-3">Cesium Phosphide Sputtering Target</a></div><div> <a href="/chromium-phosphide-26342-61-0">Chromium Phosphide</a></div><div> <a href="/cobalt-phosphide-12134-02-0">Cobalt Phosphide</a></div><div> <a href="/cobalt-phosphide-sputtering-target-12134-02-0">Cobalt Phosphide Sputtering Target</a></div><div> <a href="/copper-phosphide-12643-19-5">Copper Phosphide</a></div><div> <a href="/copper-phosphide-sputtering-target-12643-19-5">Copper Phosphide Sputtering Target</a></div><div> <a href="/copper-phosphorus-alloy-12517-41-8">Copper Phosphorus Alloy</a></div><div> <a href="/cops3-crystal">CoPS3 Crystal</a></div><div> <a href="/crps4-crystal">CrPS4 Crystal</a></div><div> <a href="/cucrp2s6-crystal">CuCrP2S6 Crystal</a></div><div> <a href="/cuinp2s6-crystal">CuInP2S6 Crystal</a></div><div> <a href="/cuinp2se6-crystal">CuInP2Se6 Crystal</a></div></div><div class="view-grouping"><h3>D</h3><div> <a href="/dysprosium-phosphide-12019-91-9">Dysprosium Phosphide</a></div><div> <a href="/dysprosium-phosphide-sputtering-target-12019-91-9">Dysprosium Phosphide Sputtering Target</a></div></div><div class="view-grouping"><h3>E</h3><div> <a href="/erbium-phosphide-12218-47-2">Erbium Phosphide</a></div><div> <a href="/erbium-phosphide-sputtering-target-12218-47-2">Erbium Phosphide Sputtering Target</a></div><div> <a href="/europium-phosphide-28866-07-1">Europium Phosphide</a></div><div> <a href="/europium-phosphide-sputtering-target-28866-07-1">Europium Phosphide Sputtering Target</a></div></div><div class="view-grouping"><h3>G</h3><div> <a href="/gadolinium-phosphide-12024-79-2">Gadolinium Phosphide</a></div><div> <a href="/gadolinium-phosphide-sputtering-target-12024-79-2">Gadolinium Phosphide Sputtering Target</a></div><div> <a href="/gallium-aluminum-phosphide-granule">Gallium Aluminum Phosphide Granule</a></div><div> <a href="/gallium-aluminum-phosphide-lump">Gallium Aluminum Phosphide Lump</a></div><div> <a href="/gallium-aluminum-phosphide-powder">Gallium Aluminum Phosphide Powder</a></div><div> <a href="/gallium-phosphide-12063-98-8">Gallium Phosphide</a></div><div> <a href="/gallium-phosphide-nanodispersion-12063-98-8">Gallium Phosphide Nanodispersion</a></div><div> <a href="/gallium-phosphide-single-crystal-substrate-12063-98-8">Gallium Phosphide Single Crystal Substrate</a></div><div> <a href="/gallium-phosphide-sputtering-target-12063-98-8">Gallium Phosphide Sputtering Target</a></div><div> <a href="/gaps4-crystal">GaPS4 Crystal</a></div><div> <a href="/germanium-phosphide">Germanium Phosphide</a></div><div> <a href="/germanium-phosphide-sputtering-target">Germanium Phosphide Sputtering Target</a></div><div> <a href="/gold-phosphide">Gold Phosphide</a></div><div> <a href="/gold-phosphide-sputtering-target">Gold Phosphide Sputtering Target</a></div></div><div class="view-grouping"><h3>H</h3><div> <a href="/hafnium-phosphide-12325-59-6">Hafnium Phosphide</a></div><div> <a href="/hafnium-phosphide-sputtering-target-12325-59-6">Hafnium Phosphide Sputtering Target</a></div><div> <a href="/hgpse3-crystal">HgPSe3 Crystal</a></div><div> <a href="/holmium-phosphide-12029-85-5">Holmium Phosphide</a></div><div> <a href="/holmium-phosphide-sputtering-target-12029-85-5">Holmium Phosphide Sputtering Target</a></div></div><div class="view-grouping"><h3>I</h3><div> <a href="/in2p3s9-crystal">In2P3S9 Crystal</a></div><div> <a href="/in2p3se9-crystal">In2P3Se9 Crystal</a></div><div> <a href="/inalp">InAlP</a></div><div> <a href="/indium-gallium-phosphide-ingap">Indium Gallium Phosphide InGaP</a></div><div> <a href="/indium-phosphide-22398-80-7">Indium Phosphide</a></div><div> <a href="/indium-phosphide-arsenide">Indium Phosphide Arsenide</a></div><div> <a href="/indium-phosphide-nanoparticles-22398-80-7">Indium Phosphide Nanoparticles</a></div><div> <a href="/indium-phosphide-sputtering-target-22398-80-7">Indium Phosphide Sputtering Target</a></div><div> <a href="/indium-phosphide-wafer-22398-80-7">Indium Phosphide Wafer</a></div><div> <a href="/indium-phosphide-zinc-sulfide-quantum-dots">Indium Phosphide/Zinc Sulfide Quantum Dots</a></div><div> <a href="/ingaasp">InGaAsP</a></div><div> <a href="/iodine-phosphide-12125-09-6">Iodine Phosphide</a></div><div> <a href="/iridium-phosphide">Iridium Phosphide</a></div><div> <a href="/iron-phosphide-12751-22-3">Iron Phosphide</a></div><div> <a href="/iron-phosphide-sputtering-target-12751-22-3">Iron Phosphide Sputtering Target</a></div><div> <a href="/iron-phosphide-fe2p-1310-43-6">Iron Phosphide, Fe2P</a></div><div> <a href="/iron-phosphide-fe3p-12023-53-9">Iron Phosphide, Fe3P</a></div></div><div class="view-grouping"><h3>L</h3><div> <a href="/lanthanum-phosphide-25275-74-5">Lanthanum Phosphide</a></div><div> <a href="/lanthanum-phosphide-sputtering-target-25275-74-5">Lanthanum Phosphide Sputtering Target</a></div><div> <a href="/lead-phosphide">Lead Phosphide</a></div><div> <a href="/lead-phosphide-sputtering-target">Lead Phosphide Sputtering Target</a></div><div> <a href="/lithium-phosphide-12057-29-3">Lithium Phosphide</a></div><div> <a href="/lithium-phosphide-sputtering-target">Lithium Phosphide Sputtering Target</a></div><div> <a href="/lithium-phosphorus-sulfide-chloride">Lithium Phosphorus Sulfide Chloride</a></div><div> <a href="/lutetium-phosphide-12032-05-2">Lutetium Phosphide</a></div><div> <a href="/lutetium-phosphide-sputtering-target-12032-05-2">Lutetium Phosphide Sputtering Target</a></div></div><div class="view-grouping"><h3>M</h3><div> <a href="/magnesium-phosphide-12057-74-8">Magnesium Phosphide</a></div><div> <a href="/magnesium-phosphide-sputtering-target-12057-74-8">Magnesium Phosphide Sputtering Target</a></div><div> <a href="/manganese-phosphide-12032-78-9">Manganese Phosphide</a></div><div> <a href="/manganese-phosphide-sputtering-target-12032-78-9">Manganese Phosphide Sputtering Target</a></div><div> <a href="/manganese-ii-phosphide-12263-33-1">Manganese(II) Phosphide</a></div><div> <a href="/mnps3-crystal">MnPS3 Crystal</a></div><div> <a href="/mnpse3-crystal">MnPSe3 Crystal</a></div><div> <a href="/molybdenum-phosphide-12163-69-8">Molybdenum Phosphide</a></div><div> <a href="/molybdenum-phosphide-sputtering-target-12163-69-8">Molybdenum Phosphide Sputtering Target</a></div></div><div class="view-grouping"><h3>N</h3><div> <a href="/neodymium-phosphide-30985-23-0">Neodymium Phosphide</a></div><div> <a href="/neodymium-phosphide-sputtering-target-30985-23-0">Neodymium Phosphide Sputtering Target</a></div><div> <a href="/nickel-phosphide-12035-64-2">Nickel Phosphide</a></div><div> <a href="/nickel-phosphide-sputtering-target-12035-64-2">Nickel Phosphide Sputtering Target</a></div><div> <a href="/niobium-phosphide-12034-66-1">Niobium Phosphide</a></div><div> <a href="/niobium-phosphide-sputtering-target-12034-66-1">Niobium Phosphide Sputtering Target</a></div><div> <a href="/nips3-crystal">NiPS3 Crystal</a></div></div><div class="view-grouping"><h3>O</h3><div> <a href="/osmium-phosphide">Osmium Phosphide</a></div><div> <a href="/osmium-phosphide-sputtering-target">Osmium Phosphide Sputtering Target</a></div></div><div class="view-grouping"><h3>P</h3><div> <a href="/palladium-phosphide">Palladium Phosphide</a></div><div> <a href="/palladium-phosphide-sputtering-target">Palladium Phosphide Sputtering Target</a></div><div> <a href="/platinum-phosphide">Platinum Phosphide</a></div><div> <a href="/platinum-phosphide-sputtering-target">Platinum Phosphide Sputtering Target</a></div><div> <a href="/potassium-phosphide-20770-41-6">Potassium Phosphide</a></div><div> <a href="/praseodymium-phosphide-12066-49-8">Praseodymium Phosphide</a></div><div> <a href="/praseodymium-phosphide-sputtering-target-12066-49-8">Praseodymium Phosphide Sputtering Target</a></div></div><div class="view-grouping"><h3>R</h3><div> <a href="/rhenium-phosphide">Rhenium Phosphide</a></div><div> <a href="/rhenium-phosphide-sputtering-target">Rhenium Phosphide Sputtering Target</a></div><div> <a href="/rhodium-phosphide">Rhodium Phosphide</a></div><div> <a href="/rhodium-phosphide-sputtering-target">Rhodium Phosphide Sputtering Target</a></div><div> <a href="/ruthenium-phosphide">Ruthenium Phosphide</a></div><div> <a href="/ruthenium-phosphide-sputtering-target">Ruthenium Phosphide Sputtering Target</a></div></div><div class="view-grouping"><h3>S</h3><div> <a href="/samarium-phosphide-12066-50-1">Samarium Phosphide</a></div><div> <a href="/samarium-phosphide-sputtering-target-12066-50-1">Samarium Phosphide Sputtering Target</a></div><div> <a href="/scandium-phosphide-12202-43-6">Scandium Phosphide</a></div><div> <a href="/scandium-phosphide-sputtering-target-12202-43-6">Scandium Phosphide Sputtering Target</a></div><div> <a href="/selenium-phosphide-12509-41-0">Selenium Phosphide</a></div><div> <a href="/selenium-phosphide-sputtering-target-12509-41-0">Selenium Phosphide Sputtering Target</a></div><div> <a href="/si2cup3-crystal">Si2CuP3 Crystal</a></div><div> <a href="/silicon-phosphide-60866-77-5">Silicon Phosphide</a></div><div> <a href="/silicon-phosphide-sputtering-target-60866-77-5">Silicon Phosphide Sputtering Target</a></div><div> <a href="/silver-phosphide-12002-82-3">Silver Phosphide</a></div><div> <a href="/silver-phosphide-sputtering-target-12002-82-3">Silver Phosphide Sputtering Target</a></div><div> <a href="/snps3-crystal">SnPS3 Crystal</a></div><div> <a href="/snpse3-crystal">SnPSe3 Crystal</a></div><div> <a href="/sodium-phosphide-12058-85-4">Sodium Phosphide</a></div><div> <a href="/strontium-phosphide-12504-16-4">Strontium Phosphide</a></div><div> <a href="/strontium-phosphide-sputtering-target-12504-16-4">Strontium Phosphide Sputtering Target</a></div><div> <a href="/sulfur-doped-gallium-phosphide-sputtering-target">Sulfur-doped Gallium Phosphide Sputtering Target</a></div></div><div class="view-grouping"><h3>T</h3><div> <a href="/tantalum-phosphide-12037-63-7">Tantalum Phosphide</a></div><div> <a href="/tantalum-phosphide-sputtering-target-12037-63-7">Tantalum Phosphide Sputtering Target</a></div><div> <a href="/tellurium-phosphide">Tellurium Phosphide</a></div><div> <a href="/terbium-phosphide-12037-64-8">Terbium Phosphide</a></div><div> <a href="/terbium-phosphide-sputtering-target-12037-64-8">Terbium Phosphide Sputtering Target</a></div><div> <a href="/thallium-phosphide">Thallium Phosphide</a></div><div> <a href="/thallium-phosphide-sputtering-target">Thallium Phosphide Sputtering Target</a></div><div> <a href="/thulium-phosphide-12037-68-2">Thulium Phosphide</a></div><div> <a href="/thulium-phosphide-sputtering-target-12037-68-2">Thulium Phosphide Sputtering Target</a></div><div> <a href="/tin-phosphide-25324-56-5">Tin Phosphide</a></div><div> <a href="/tin-phosphide-sputtering-target-25324-56-5">Tin Phosphide Sputtering Target</a></div><div> <a href="/titanium-phosphide-12037-65-9">Titanium Phosphide</a></div><div> <a href="/titanium-phosphide-sputtering-target-12037-65-9">Titanium Phosphide Sputtering Target</a></div><div> <a href="/tungsten-phosphide-12037-70-6">Tungsten Phosphide</a></div><div> <a href="/tungsten-phosphide-sputtering-target-12037-70-6">Tungsten Phosphide Sputtering Target</a></div></div><div class="view-grouping"><h3>V</h3><div> <a href="/vanadium-phosphide-12066-53-4">Vanadium Phosphide</a></div><div> <a href="/vanadium-phosphide-sputtering-target-12066-53-4">Vanadium Phosphide Sputtering Target</a></div></div><div class="view-grouping"><h3>Y</h3><div> <a href="/ytterbium-phosphide-12037-71-7">Ytterbium Phosphide</a></div><div> <a href="/ytterbium-phosphide-sputtering-target-12037-71-7">Ytterbium Phosphide Sputtering Target</a></div><div> <a href="/yttrium-phosphide-12294-01-8">Yttrium Phosphide</a></div><div> <a href="/yttrium-phosphide-sputtering-target-12294-01-8">Yttrium Phosphide Sputtering Target</a></div></div><div class="view-grouping"><h3>Z</h3><div> <a href="/zinc-diphosphide-12037-79-5">Zinc Diphosphide</a></div><div> <a href="/zinc-germanium-phosphide-granule">Zinc Germanium Phosphide Granule</a></div><div> <a href="/zinc-germanium-phosphide-lump">Zinc Germanium Phosphide Lump</a></div><div> <a href="/zinc-germanium-phosphide-powder">Zinc Germanium Phosphide Powder</a></div><div> <a href="/zinc-phosphide-1314-84-7">Zinc Phosphide</a></div><div> <a href="/zinc-phosphide-sputtering-target-1314-84-7">Zinc Phosphide Sputtering Target</a></div><div> <a href="/zinc-tin-phosphide-granule">Zinc Tin Phosphide Granule</a></div><div> <a href="/zinc-tin-phosphide-lump">Zinc Tin Phosphide Lump</a></div><div> <a href="/zinc-tin-phosphide-powder">Zinc Tin Phosphide Powder</a></div><div> <a href="/zinc-doped-gallium-phosphide-sputtering-target">Zinc-doped Gallium Phosphide Sputtering Target</a></div><div> <a href="/zirconium-phosphide-12037-72-8">Zirconium Phosphide</a></div><div> <a href="/zirconium-phosphide-sputtering-target-12037-72-8">Zirconium Phosphide Sputtering Target</a></div></div></div></div></div></div><div class="ctools-collapsible-container paneled paneled-padded anion-about"><h2 class="pane-title ctools-collapsible-handle">About Phosphides</h2><div class="ctools-collapsible-content"> <img src="https://www.americanelements.com/SOFC-SEM.jpg" alt="solid oxide fuel cell cathode and electrolyte cross section by SEM" width="130" height="101" border="0" class="image-left"><p><strong>Phosphides</strong> are compounds of phosphorus with one or more less electronegative elements. Most elements less-electronegative than phosphorus form at least one binary phosphide, and most form a number of binary phosphides with different stoichiometries. Notably, potassium is capable of forming nine different binary phosphides: K<sub>3</sub>P, K<sub>4</sub>P<sub>3</sub>, K<sub>5</sub>P<sub>4</sub>, KP, K<sub>4</sub>P<sub>6</sub>, K<sub>3</sub>P<sub>7</sub>, K<sub>3</sub>P<sub>11</sub>, KP<sub>10.3</sub>, KP<sub>15</sub>. Phosphides may be principally ionic compounds with P<sup>3-</sup> ions, ionic compounds with polymeric phosphorus ions such as P<sup>24-</sup> or P<sup>113-</sup>, or compounds with individual phosphorus atoms incorporated into a metal lattice which may exhibit metal-like or semiconductor-like properties.<p>Although there are a number of ways to prepare phosphides, the most general method is to heat stoichiometric amounts of the metal and red phosphorus to high temperature in an inert atmosphere or a vacuum. Alkali and alkaline earth metals transition-metal phosphides are inert metallic-looking solids with high melting points and electrical conductivities.</p><p>Some metal phosphides have been used as rodenticides, primarily calcium phosphide, zinc phosphide, and aluminum phosphide. Zinc phosphide baits have strong, pungent garlic-like odor characteristic for phosphine liberated by hydrolysis. The odor attracts rodents, but has a repulsive effect on other animals. Aluminum phosphide is also wide band gap <a href="https://www.americanelements.com/semiconductors.html">semiconductor</a>. Calcium phosphide has uses in incendiary bombs. On contact with acids or water, calcium phosphide releases phosphine, which ignites spontaneously. Calcium phosphide is also used in fireworks, torpedoes, self-igniting <a href="https://www.americanelements.com/defense.html">naval pyrotechnic flares</a>, and various water-activated ammunition.</p><p>Gallium phosphide is an important semiconducting phosphide used in the manufacture of low-cost red, orange, and green <a href="https://www.americanelements.com/lighting.html">light-emitting diodes</a> (LEDs) with low to medium brightness since the 1960s. It has a relatively short life at higher current and its lifetime is sensitive to temperature. Pure gallium phosphide LEDs emit green light at a wavelength of 555 nm. Nitrogen-doped gallium phosphide emits yellow-green (565 nm) light, zinc oxide doped gallium phosphide emits red (700 nm). Indium phosphide is a semiconductor and is used in high-power and high-frequency <a href="https://www.americanelements.com/electronics-materials.html">electronics</a> because of its superior electron velocity with respect to the more common semiconductors such as gallium arsenide. Indium phosphide also has one of the longest-lived optical phonons of any compound with the zincblende crystal structure.</p><p>Sodium phosphide is a source of the highly reactive phosphide anion, and is often employed commercially in conjunction with zinc phosphide and aluminum phosphide as a catalyst in polymer production. Sodium phosphide is highly dangerous, releasing toxic phosphine upon hydrolysis, a process that is so exothermic that it may result in fires.</p></div></div></div></div></div><div class="industry-apps-container industry-apps-footer clearfix panel-panel"><div class="industry-apps-container-inner industry-apps-footer-inner panel-panel-inner"></div></div></div></div></div></div></div></div> <footer id="footer" role="footer" class="l-footer-wrapper"><div class="l-setwidth l-footer" ><div class="footer"><div class="region region-footer-first"><div id="block-block-18" class="block block-block"><div class="cs-invented-box"><h5>We Invented It!</h5><div class="cs-link"><a href="https://www.americanelements.com/american-elements-case-studies">Case Studies of selected key technologies invented or co-invented by American Elements in just the 1st two decades of this century</a></div></div></div></div></div><div class="footer"><div class="region region-footer-second"><div id="block-views-56d84b070e9e67f34c1749909f8cdf92" class="block block-views"><div class="view view-aenotes-article-views view-id-aenotes_article_views view-display-id-block_aenotes aenotes-block aenotes-desktop centered view-dom-id-0a4e99e16589397e9592172a11aef290"><div class="view-header"><h2 class="pane-title" id="post">TODAY'S TOP DISCOVERY<span class="smaller">™</span>!</h2><div class="date-place">November 23, 2024<br />Los Angeles, CA</div><h6><em>Each business day American Elements' scientists & engineers post their choice for the most exciting materials science news of the day</em></h6></div><div class="view-content"><div class="view-grouping"><div class="views-row views-row-1 views-row-odd views-row-first views-row-last"><table class="aebox"><tr><td><span class="ampimg"><img typeof="foaf:Image" src="https://www.americanelements.com/sites/public/files/field/image/1_0.png" width="495" height="233" alt="CityUHK researchers discover method to reduce energy loss in metal nanostructures by altering their geometrical dimensions" /> </span></td><td class="tdtitle"><H2>CityUHK researchers discover method to reduce energy loss in metal nanostructures by altering their geometrical dimensions</H2></td></tr></table></div></div></div><div class="view-footer"><h4><a href="https://www.americanelements.com/aenotes.html"><u>Click here to see the primary source for this post and previous posts</u> > > > </a></h4></div></div></div><div id="block-block-1" class="block block-block"><div class="sponsored-conference"><a href="https://events.techconnect.org/DTCFall/" aria-label="logo" title="Defense TechConnect Innovation Summit"><div class="sponsored-conference-graphic"></div></a><div class="sponsored-conference-text">Please join us and our customers and co-sponsors Lockheed Martin & Northrop Grumman at the <a href="https://events.techconnect.org/DTCFall/">Defense TechConnect Innovation Summit</a> in Austin, Texas on December 3, 2024.</div></div></div><div id="block-block-2" class="block block-block"> Periodic table of the elements, materials science and academic information, elements and advanced materials data, scientific presentations and all pages, designs, concepts, logos, and color schemes herein are the copyrighted proprietary rights and intellectual property of American Elements. 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