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amines</title> <meta name="description" content="Search results for: borylated amines"> <meta name="keywords" content="borylated amines"> <meta name="viewport" content="width=device-width, initial-scale=1, minimum-scale=1, maximum-scale=1, user-scalable=no"> <meta charset="utf-8"> <link href="https://cdn.waset.org/favicon.ico" type="image/x-icon" rel="shortcut icon"> <link href="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/css/bootstrap.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/plugins/fontawesome/css/all.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/css/site.css?v=150220211555" rel="stylesheet"> </head> <body> <header> <div class="container"> <nav class="navbar navbar-expand-lg navbar-light"> <a class="navbar-brand" href="https://waset.org"> <img src="https://cdn.waset.org/static/images/wasetc.png" alt="Open Science Research Excellence" title="Open Science Research Excellence" /> </a> <button class="d-block d-lg-none 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action="https://publications.waset.org/abstracts/search"> <div id="custom-search-input"> <div class="input-group"> <i class="fas fa-search"></i> <input type="text" class="search-query" name="q" placeholder="Author, Title, Abstract, Keywords" value="borylated amines"> <input type="submit" class="btn_search" value="Search"> </div> </div> </form> </div> </div> <div class="row mt-3"> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Commenced</strong> in January 2007</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Frequency:</strong> Monthly</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Edition:</strong> International</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Paper Count:</strong> 57</div> </div> </div> </div> <h1 class="mt-3 mb-3 text-center" style="font-size:1.6rem;">Search results for: borylated amines</h1> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">57</span> Asymmetric Synthesis of β- and γ-Borylated Amines via Rh-Catalyzed Hydroboration of Allylamine Derivatives</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Rukshani%20Wickrama-Arachchi">Rukshani Wickrama-Arachchi</a>, <a href="https://publications.waset.org/abstracts/search?q=Tanner%20Metz"> Tanner Metz</a>, <a href="https://publications.waset.org/abstracts/search?q=James%20M.%20Takacs"> James M. Takacs </a> </p> <p class="card-text"><strong>Abstract:</strong></p> Amines bearing γ-stereocenters are important structural motifs found in many biologically active compounds. Regioselective Rh-catalyzed asymmetric hydroboration of acyclic allylamines is used to synthesize amines bearing chiral β- and γ-boronic esters yields up to 70% with 98:2 enantioselectivity. The major enantiomeric outcome can be independent of starting alkene geometry, revealing that cis/trans-isomerization of alkene can occur before hydroboration. Stereospecific transformations of the newly generated C-B bond illustrates the utility of these chiral synthons. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=allylamines" title="allylamines">allylamines</a>, <a href="https://publications.waset.org/abstracts/search?q=borylated%20amines" title=" borylated amines"> borylated amines</a>, <a href="https://publications.waset.org/abstracts/search?q=chiral%20amines" title=" chiral amines"> chiral amines</a>, <a href="https://publications.waset.org/abstracts/search?q=hydroboration" title=" hydroboration"> hydroboration</a>, <a href="https://publications.waset.org/abstracts/search?q=rhodium-catalysis" title=" rhodium-catalysis"> rhodium-catalysis</a> </p> <a href="https://publications.waset.org/abstracts/111277/asymmetric-synthesis-of-v-and-gh-borylated-amines-via-rh-catalyzed-hydroboration-of-allylamine-derivatives" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/111277.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">190</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">56</span> Biogenic Amines Production during RAS Cheese Ripening</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Amr%20Amer">Amr Amer</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Cheeses are among those high-protein-containing foodstuffs in which enzymatic and microbial activities cause the formation of biogenic amines from amino acids decarboxylation. The amount of biogenic amines in cheese may act as a useful indicator of the hygienic quality of the product. In other words, their presence in cheese is related to its spoilage and safety. Formation of biogenic amines during Ras cheese (Egyptian hard cheese) ripening was investigated for 4 months. Three batches of Ras cheese were manufactured using Egyptian traditional method. From each batch, Samples were collected at 1, 7, 15, 30, 60, 90 and 120 days after cheese manufacture. The concentrations of biogenic amines (Tyramine, Histamine, Cadaverine and Tryptamine) were analyzed by high performance liquid chromatography (HPLC). There was a significant increased (P<0.05) in Tyramine levels from 4.34± 0.07 mg|100g in the first day of storage till reached 88.77± 0.14 mg|100g at a 120-day of storage. Also, Histamine and Cadaverine levels had the same increased pattern of Tyramine reaching 64.94± 0.10 and 28.28± 0.08 mg|100g in a 120- day of storage, respectively. While, there was a fluctuation in the concentration of Tryptamine level during ripening period as it decreased from 3.24± 0.06 to 2.66± 0.11 mg|100g at 60-day of storage then reached 5.38±0.08 mg|100g in a 120- day of storage. Biogenic amines can be formed in cheese during production and storage: many variables, as pH, salt concentration, bacterial activity as well as moisture, storage temperature and ripening time, play a relevant role in their formation. Comparing the obtained results with the recommended standard by Food and Drug Administration "FDA" (2001), High levels of biogenic amines in various Ras cheeses consumed in Egypt exceeded the permissible value (10 mg%) which seemed to pose a threat to public health. In this study, presence of high concentrations of biogenic amines (Tyramine, Histamine, cadaverine and Tryptamine) in Egyptian Ras cheeses reflects the bad hygienic conditions under which they produced and stored. Accordingly, the levels of biogenic amines in different cheeses should be come in accordance with the safe permissible limit recommended by FDA to ensure human safety. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ras%20cheese" title="Ras cheese">Ras cheese</a>, <a href="https://publications.waset.org/abstracts/search?q=biogenic%20amines" title=" biogenic amines"> biogenic amines</a>, <a href="https://publications.waset.org/abstracts/search?q=tyramine" title=" tyramine"> tyramine</a>, <a href="https://publications.waset.org/abstracts/search?q=histamine" title=" histamine"> histamine</a>, <a href="https://publications.waset.org/abstracts/search?q=cadaverine" title=" cadaverine "> cadaverine </a> </p> <a href="https://publications.waset.org/abstracts/25970/biogenic-amines-production-during-ras-cheese-ripening" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/25970.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">436</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">55</span> Inhibitory Activity of Lactic Acid Bacteria on the Growth and Biogenic Amines Production by Foodborne Pathogens and Food Spoilage Bacteria</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Abderrezzak%C2%A0khatib">Abderrezzak khatib</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Biogenic amines are low molecular weight nitrogenous compounds that have the potential to accumulate in food, posing a significant risk to food safety and human health. In this study, we investigated the inhibitory activity of three strains of lactic acid bacteria (LAB), against the growth and production of biogenic amines by both foodborne pathogens and food spoilage bacteria. The foodborne pathogens studied included Staphylococcus aureus, Pseudomonas aeruginosa, and Salmonella Paratyphi, while the food spoilage bacteria comprised Enterobacter cloacae and Proteus mirabilis. The methodology involved bacterial growth determination in petri dishes, bacterial culture extraction and derivatization, and biogenic amine analysis using HPLC. Our findings revealed that the inhibitory effects of LAB on these pathogens varied, with all three LAB strains demonstrating a remarkable reduction in the total bacterial count when combined with most pathogens, compared to the individual cultures of the pathogens. Furthermore, the presence of LAB in co-cultures with the pathogens resulted in a significant decrease in the production of tyramine and other biogenic amines by the pathogens themselves. These results suggest that LAB strains hold considerable promise in preventing the accumulation of biogenic amines in food products, thereby enhancing food safety. This study provides insights into the potential utilization of LAB in the context of preserving and ensuring the safety of food products. It highlights the significance of conducting additional research endeavors to elucidate the underlying mechanisms involved and to identify the precise bioactive compounds that are responsible for the observed inhibitory effects. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=food%20safety" title="food safety">food safety</a>, <a href="https://publications.waset.org/abstracts/search?q=lactic%20acid%20bacteria" title=" lactic acid bacteria"> lactic acid bacteria</a>, <a href="https://publications.waset.org/abstracts/search?q=foodborne%20pathogens" title=" foodborne pathogens"> foodborne pathogens</a>, <a href="https://publications.waset.org/abstracts/search?q=food%20spoilage%20bacteria" title=" food spoilage bacteria"> food spoilage bacteria</a>, <a href="https://publications.waset.org/abstracts/search?q=biogenic%20amines" title=" biogenic amines"> biogenic amines</a>, <a href="https://publications.waset.org/abstracts/search?q=tyrosine" title=" tyrosine"> tyrosine</a> </p> <a href="https://publications.waset.org/abstracts/180647/inhibitory-activity-of-lactic-acid-bacteria-on-the-growth-and-biogenic-amines-production-by-foodborne-pathogens-and-food-spoilage-bacteria" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/180647.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">55</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">54</span> Synthesis and Characterization of Model Amines for Corrosion Applications</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=John%20Vergara">John Vergara</a>, <a href="https://publications.waset.org/abstracts/search?q=Giuseppe%20Palmese"> Giuseppe Palmese</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Fundamental studies aimed at elucidating the key contributions to corrosion performance are needed to make progress toward effective and environmentally compliant corrosion control. Epoxy/amine systems are typically employed as barrier coatings for corrosion control. However, the hardening agents used for coating applications can be very complex, making fundamental studies of water and oxygen permeability challenging to carry out. Creating model building blocks for epoxy/amine coatings is the first step in carrying out these studies. We will demonstrate the synthesis and characterization of model amine building blocks from saturated fatty acids and simple amines such as diethylenetriamine (DETA) and Bis(3-aminopropyl)amine. The structure-property relationship of thermosets made from these model amines and Diglycidyl ether of bisphenol A (DGBEA) will be discussed. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=building%20block" title="building block">building block</a>, <a href="https://publications.waset.org/abstracts/search?q=amine" title=" amine"> amine</a>, <a href="https://publications.waset.org/abstracts/search?q=synthesis" title=" synthesis"> synthesis</a>, <a href="https://publications.waset.org/abstracts/search?q=characterization" title=" characterization"> characterization</a> </p> <a href="https://publications.waset.org/abstracts/19436/synthesis-and-characterization-of-model-amines-for-corrosion-applications" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/19436.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">539</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">53</span> Corrosion Behvaior of CS1018 in Various CO2 Capture Solvents</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Aida%20Rafat">Aida Rafat</a>, <a href="https://publications.waset.org/abstracts/search?q=Ramazan%20Kahraman"> Ramazan Kahraman</a>, <a href="https://publications.waset.org/abstracts/search?q=Mert%20Atilhan"> Mert Atilhan</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The aggressive corrosion behavior of conventional amine solvents is one of main barriers against large scale commerizaliation of amine absorption process for carbon capture application. Novel CO2 absorbents that exhibit minimal corrosivity against operation conditions are essential to lower corrosion damage and control and ensure more robustness in the capture plant. This work investigated corrosion behavior of carbon steel CS1018 in various CO2 absrobent solvents. The tested solvents included the classical amines MEA, DEA and MDEA, piperazine activated solvents MEA/PZ, MDEA/PZ and MEA/MDEA/PZ as well as mixtures of MEA and Room Temperature Ionic Liquids RTIL, namely MEA/[C4MIM][BF4] and MEA/[C4MIM][Otf]. Electrochemical polarization technique was used to determine the system corrosiveness in terms of corrosion rate and polarization behavior. The process parameters of interest were CO2 loading and solution temperature. Electrochemical resulted showed corrosivity order of classical amines at 40°C is MDEA> MEA > DEA wherase at 80°C corrosivity ranking changes to MEA > DEA > MDEA. Corrosivity rankings were mainly governed by CO2 absorption capacity at the test temperature. Corrosivity ranking for activated amines at 80°C was MEA/PZ > MDEA/PZ > MEA/MDEA/PZ. Piperazine addition seemed to have a dual advanatge in terms of enhancing CO2 absorption capacity as well as nullifying corrosion. For MEA/RTIL mixtures, the preliminary results showed that the partial repalcement of aqueous phase in MEA solution by the more stable nonvolatile RTIL solvents reduced corrosion rates considerably. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=corrosion" title="corrosion">corrosion</a>, <a href="https://publications.waset.org/abstracts/search?q=amines" title=" amines"> amines</a>, <a href="https://publications.waset.org/abstracts/search?q=CO2%20capture" title=" CO2 capture"> CO2 capture</a>, <a href="https://publications.waset.org/abstracts/search?q=piperazine" title=" piperazine"> piperazine</a>, <a href="https://publications.waset.org/abstracts/search?q=ionic%20liquids" title=" ionic liquids"> ionic liquids</a> </p> <a href="https://publications.waset.org/abstracts/18686/corrosion-behvaior-of-cs1018-in-various-co2-capture-solvents" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/18686.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">460</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">52</span> Vapour Liquid Equilibrium Measurement of CO₂ Absorption in Aqueous 2-Aminoethylpiperazine (AEP)</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Anirban%20Dey">Anirban Dey</a>, <a href="https://publications.waset.org/abstracts/search?q=Sukanta%20Kumar%20Dash"> Sukanta Kumar Dash</a>, <a href="https://publications.waset.org/abstracts/search?q=Bishnupada%20Mandal"> Bishnupada Mandal</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Carbondioxide (CO2) is a major greenhouse gas responsible for global warming and fossil fuel power plants are the main emitting sources. Therefore the capture of CO2 is essential to maintain the emission levels according to the standards. Carbon capture and storage (CCS) is considered as an important option for stabilization of atmospheric greenhouse gases and minimizing global warming effects. There are three approaches towards CCS: Pre combustion capture where carbon is removed from the fuel prior to combustion, Oxy-fuel combustion, where coal is combusted with oxygen instead of air and Post combustion capture where the fossil fuel is combusted to produce energy and CO2 is removed from the flue gases left after the combustion process. Post combustion technology offers some advantage as existing combustion technologies can still be used without adopting major changes on them. A number of separation processes could be utilized part of post –combustion capture technology. These include (a) Physical absorption (b) Chemical absorption (c) Membrane separation (d) Adsorption. Chemical absorption is one of the most extensively used technologies for large scale CO2 capture systems. The industrially important solvents used are primary amines like Monoethanolamine (MEA) and Diglycolamine (DGA), secondary amines like diethanolamine (DEA) and Diisopropanolamine (DIPA) and tertiary amines like methyldiethanolamine (MDEA) and Triethanolamine (TEA). Primary and secondary amines react fast and directly with CO2 to form stable carbamates while Tertiary amines do not react directly with CO2 as in aqueous solution they catalyzes the hydrolysis of CO2 to form a bicarbonate ion and a protonated amine. Concentrated Piperazine (PZ) has been proposed as a better solvent as well as activator for CO2 capture from flue gas with a 10 % energy benefit compared to conventional amines such as MEA. However, the application of concentrated PZ is limited due to its low solubility in water at low temperature and lean CO2 loading. So following the performance of PZ its derivative 2-Aminoethyl piperazine (AEP) which is a cyclic amine can be explored as an activator towards the absorption of CO2. Vapour liquid equilibrium (VLE) in CO2 capture systems is an important factor for the design of separation equipment and gas treating processes. For proper thermodynamic modeling accurate equilibrium data for the solvent system over a wide range of temperatures, pressure and composition is essential. The present work focuses on the determination of VLE data for (AEP + H2O) system at 40 °C for various composition range. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=absorption" title="absorption">absorption</a>, <a href="https://publications.waset.org/abstracts/search?q=aminoethyl%20piperazine" title=" aminoethyl piperazine"> aminoethyl piperazine</a>, <a href="https://publications.waset.org/abstracts/search?q=carbondioxide" title=" carbondioxide"> carbondioxide</a>, <a href="https://publications.waset.org/abstracts/search?q=vapour%20liquid%20equilibrium" title=" vapour liquid equilibrium"> vapour liquid equilibrium</a> </p> <a href="https://publications.waset.org/abstracts/59396/vapour-liquid-equilibrium-measurement-of-co2-absorption-in-aqueous-2-aminoethylpiperazine-aep" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/59396.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">267</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">51</span> Gas-Phase Nondestructive and Environmentally Friendly Covalent Functionalization of Graphene Oxide Paper with Amines</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Natalia%20Alzate-Carvajal">Natalia Alzate-Carvajal</a>, <a href="https://publications.waset.org/abstracts/search?q=Diego%20A.%20Acevedo-Guzman"> Diego A. Acevedo-Guzman</a>, <a href="https://publications.waset.org/abstracts/search?q=Victor%20Meza-Laguna"> Victor Meza-Laguna</a>, <a href="https://publications.waset.org/abstracts/search?q=Mario%20H.%20Farias"> Mario H. Farias</a>, <a href="https://publications.waset.org/abstracts/search?q=Luis%20A.%20Perez-Rey"> Luis A. Perez-Rey</a>, <a href="https://publications.waset.org/abstracts/search?q=Edgar%20Abarca-Morales"> Edgar Abarca-Morales</a>, <a href="https://publications.waset.org/abstracts/search?q=Victor%20A.%20Garcia-Ramirez"> Victor A. Garcia-Ramirez</a>, <a href="https://publications.waset.org/abstracts/search?q=Vladimir%20A.%20Basiuk"> Vladimir A. Basiuk</a>, <a href="https://publications.waset.org/abstracts/search?q=Elena%20V.%20Basiuk"> Elena V. Basiuk</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Direct covalent functionalization of prefabricated free-standing graphene oxide paper (GOP) is considered as the only approach suitable for systematic tuning of thermal, mechanical and electronic characteristics of this important class of carbon nanomaterials. At the same time, the traditional liquid-phase functionalization protocols can compromise physical integrity of the paper-like material up to its total disintegration. To avoid such undesirable effects, we explored the possibility of employing an alternative, solvent-free strategy for facile and nondestructive functionalization of GOP with two representative aliphatic amines, 1-octadecylamine (ODA) and 1,12-diaminododecane (DAD), as well as with two aromatic amines, 1-aminopyrene (AP) and 1,5-diaminonaphthalene (DAN). The functionalization was performed under moderate heating at 150-180 °C in vacuum. Under such conditions, it proceeds through both amidation and epoxy ring opening reactions. Comparative characterization of pristine and amine-functionalized GOP mats was carried out by using Fourier-transform infrared, Raman, and X-ray photoelectron spectroscopy (XPS), thermogravimetric (TGA) and differential thermal analysis, scanning electron and atomic force microscopy (SEM and AFM, respectively). Besides that, we compared the stability in water, wettability, electrical conductivity and elastic (Young's) modulus of GOP mats before and after amine functionalization. The highest content of organic species was obtained in the case of GOP-ODA, followed by GOP-DAD, GOP-AP and GOP-DAN samples. The covalent functionalization increased mechanical and thermal stability of GOP, as well as its electrical conductivity. The magnitude of each effect depends on the particular chemical structure of amine employed, which allows for tuning a given GOP property. Morphological characterization by using SEM showed that, compared to pristine graphene oxide paper, amine-modified GOP mats become relatively ordered layered assemblies, in which individual GO sheets are organized in a near-parallel pattern. Financial support from the National Autonomous University of Mexico (grants DGAPA-IN101118 and IN200516) and from the National Council of Science and Technology of Mexico (CONACYT, grant 250655) is greatly appreciated. The authors also thank David A. Domínguez (CNyN of UNAM) for XPS measurements and Dr. Edgar Alvarez-Zauco (Faculty of Science of UNAM) for the opportunity to use TGA equipment. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=amines" title="amines">amines</a>, <a href="https://publications.waset.org/abstracts/search?q=covalent%20functionalization" title=" covalent functionalization"> covalent functionalization</a>, <a href="https://publications.waset.org/abstracts/search?q=gas-phase" title=" gas-phase"> gas-phase</a>, <a href="https://publications.waset.org/abstracts/search?q=graphene%20oxide%20paper" title=" graphene oxide paper"> graphene oxide paper</a> </p> <a href="https://publications.waset.org/abstracts/91820/gas-phase-nondestructive-and-environmentally-friendly-covalent-functionalization-of-graphene-oxide-paper-with-amines" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/91820.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">181</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">50</span> Theoretical Study of Acetylation of P-Methylaniline Catalyzed by Cu²⁺ Ions</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Silvana%20Caglieri">Silvana Caglieri</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Theoretical study of acetylation of p-methylaniline catalyzed by Cu2+ ions from the analysis of intermediate of the reaction was carried out. The study of acetylation of amines is of great interest by the utility of its products of reaction and is one of the most frequently used transformations in organic synthesis as it provides an efficient and inexpensive means for protecting amino groups in a multistep synthetic process. Acetylation of amine is a nucleophilic substitution reaction. This reaction can be catalyzed by Lewis acid, metallic ion. In reaction mechanism, the metallic ion formed a complex with the oxygen of the acetic anhydride carbonyl, facilitating the polarization of the same and the successive addition of amine at the position to form a tetrahedral intermediate, determining step of the rate of the reaction. Experimental work agreed that this reaction takes place with the formation of a tetrahedral intermediate. In the present theoretical work were investigated the structure and energy of the tetrahedral intermediate of the reaction catalyzed by Cu2+ ions. Geometries of all species involved in the acetylation were made and identified. All of the geometry optimizations were performed by the method at the DFT/B3LYP level of theory and the method MP2. Were adopted the 6-31+G* basis sets. Energies were calculated using the Mechanics-UFF method. Following the same procedure it was identified the geometric parameters and energy of reaction intermediate. The calculations show 61.35 kcal/mol of energy for the tetrahedral intermediate and the energy of activation for the reaction was 15.55 kcal/mol. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=amides" title="amides">amides</a>, <a href="https://publications.waset.org/abstracts/search?q=amines" title=" amines"> amines</a>, <a href="https://publications.waset.org/abstracts/search?q=DFT" title=" DFT"> DFT</a>, <a href="https://publications.waset.org/abstracts/search?q=MP2" title=" MP2"> MP2</a> </p> <a href="https://publications.waset.org/abstracts/56510/theoretical-study-of-acetylation-of-p-methylaniline-catalyzed-by-cu2-ions" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/56510.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">282</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">49</span> Structural Insights into the Bypass of the Major Deaminated Purines by Translesion Synthesis DNA Polymerase</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Hunmin%20Jung">Hunmin Jung</a>, <a href="https://publications.waset.org/abstracts/search?q=Michael%20Hawkins"> Michael Hawkins</a>, <a href="https://publications.waset.org/abstracts/search?q=Seongmin%20Lee"> Seongmin Lee</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The exocyclic amines of nucleobases can undergo deamination by various DNA damaging agents such as reactive oxygen species, nitric oxide, and water. The deamination of guanine and adenine generates the promutagenic xanthine and hypoxanthine, respectively. The exocyclic amines of bases in DNA are hydrogen bond donors, while the carbonyl moiety generated by the base deamination acts as hydrogen bond acceptors, which can alter base pairing properties of the purines. Xanthine is known to base pair with both cytosine and thymine, while hypoxanthine predominantly pairs with cytosine to promote A to G mutations. Despite the known promutagenicity of the major deaminated purines, structures of DNA polymerase bypassing these lesions have not been reported. To gain insights into the deaminated-induced mutagenesis, we solved crystal structures of human DNA polymerase η (polη) catalyzing across xanthine and hypoxanthine. In the catalytic site of polη, the deaminated guanine (i.e., xanthine) forms three Watson-Crick-like hydrogen bonds with an incoming dCTP, indicating the O2-enol tautomer of xanthine involves in the base pairing. The formation of the enol tautomer appears to be promoted by the minor groove contact by Gln38 of polη. When hypoxanthine is at the templating position, the deaminated adenine uses its O6-keto tautomer to form two Watson-Crick hydrogen bonds with an incoming dCTP, providing the structural basis for the high promutagenicity of hypoxanthine. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=DNA%20damage" title="DNA damage">DNA damage</a>, <a href="https://publications.waset.org/abstracts/search?q=DNA%20polymerase" title="DNA polymerase">DNA polymerase</a>, <a href="https://publications.waset.org/abstracts/search?q=deamination" title="deamination">deamination</a>, <a href="https://publications.waset.org/abstracts/search?q=mutagenesis" title="mutagenesis">mutagenesis</a>, <a href="https://publications.waset.org/abstracts/search?q=tautomerization" title="tautomerization">tautomerization</a>, <a href="https://publications.waset.org/abstracts/search?q=translesion%20synthesis" title="translesion synthesis">translesion synthesis</a> </p> <a href="https://publications.waset.org/abstracts/149816/structural-insights-into-the-bypass-of-the-major-deaminated-purines-by-translesion-synthesis-dna-polymerase" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/149816.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">134</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">48</span> Antimicrobial Functions of Some Spice Extracts Such as Sumac, Cumin, Black Pepper and Red Pepper on the Growth of Common Food-Borne Pathogens and Their Biogenic Amine Formation</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Fatih%20%C3%96zogul">Fatih Özogul</a>, <a href="https://publications.waset.org/abstracts/search?q=Esmeray%20Kuley%20Boga"> Esmeray Kuley Boga</a>, <a href="https://publications.waset.org/abstracts/search?q=Ferhat%20Kuley"> Ferhat Kuley</a>, <a href="https://publications.waset.org/abstracts/search?q=Yesim%20%C3%96zogul"> Yesim Özogul</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The impact of diethyl ether extract of spices (sumac, cumin, black pepper and red pepper) on growth of Staphylococcus aureus, Salmonella Paratyphi A, Klebsiella pneumoniae, Enterococcus faecalis, Camplylobacter jejuni, Aeromonas hydrophila, Pseudomonas aeruginosa and Yersinia enterocolitica and their biogenic amine production were investigated in tyrosine decarboxylase broth. Sumac extract generally had the highest activity to inhibit bacterial growth compared to other extracts, although antimicrobial effect of extracts used varied depending on bacterial strains. Sumac extract resulted in 3.34 and 2.54 log reduction for Y. enterocolitica and Camp. jejuni growth, whilst red pepper extract induced 0.65, 0.41 and 0.34 log reduction for growth of Y. enterocolitica, S. Paratyphi A and Staph. aureus, respectively. Spice extracts significantly inhibited ammonia production by bacteria (P < 0.05). Eleven and nine fold reduction on ammonia production by S. Paratyphi A and Staph. aureus were observed in the presence of sumac extract. Dopamine, agmatine, tyramine, serotonin and TMA were main amines produced by bacteria. Tyramine production by food-borne-pathogens was more than 10 mg/L, whereas histamine accumulated below 52 mg/L. The effect of spice extracts on biogenic amine production varied depending on amino acid decarboxylase broth, spice type, bacterial strains and specific amine, although cumin extract generally increased biogenic amine production by bacteria. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=antimicrobials" title="antimicrobials">antimicrobials</a>, <a href="https://publications.waset.org/abstracts/search?q=biogenic%20amines" title=" biogenic amines"> biogenic amines</a>, <a href="https://publications.waset.org/abstracts/search?q=food-borne%20pathogens" title=" food-borne pathogens"> food-borne pathogens</a>, <a href="https://publications.waset.org/abstracts/search?q=spice%20extracts" title=" spice extracts"> spice extracts</a> </p> <a href="https://publications.waset.org/abstracts/72668/antimicrobial-functions-of-some-spice-extracts-such-as-sumac-cumin-black-pepper-and-red-pepper-on-the-growth-of-common-food-borne-pathogens-and-their-biogenic-amine-formation" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/72668.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">312</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">47</span> Chiral Amine Synthesis and Recovery by Using High Molecular Weight Amine Donors</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Claudia%20Matassa">Claudia Matassa</a>, <a href="https://publications.waset.org/abstracts/search?q=Matthias%20Hohne"> Matthias Hohne</a>, <a href="https://publications.waset.org/abstracts/search?q=Dominic%20Ormerod"> Dominic Ormerod</a>, <a href="https://publications.waset.org/abstracts/search?q=Yamini%20Satyawali"> Yamini Satyawali</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Chiral amines integrate the backbone of several active pharmaceutical ingredients (APIs) used in modern medicine for the treatment of a vast range of diseases. Despite the demand, their synthesis remains challenging. Besides a range of chemicals and enzymatical methods, chiral amine synthesis using transaminases (EC 2.6.1.W) represents a useful alternative to access this important class of compounds. Even though transaminases exhibit excellent stereo and regioselectivity and the potential for high yield, the reaction suffers from a number of challenges, including the thermodynamic equilibrium, product inhibition, and low substrate solubility. In this work, we demonstrate a membrane assisted strategy for addressing these challenges. It involves the use of high molecular weight (HMW) amine donors for the transaminase-catalyzed synthesis of 4-phenyl-2-butylamine in both aqueous and organic solvent media. In contrast to common amine donors such as alanine or isopropylamine, these large molecules, provided in excess for thermodynamic equilibrium shifting, are easily retained by commercial nanofiltration membranes; thus a selective permeation of the desired smaller product amine is possible. The enzymatic transamination in aqueous media, combined with selective product removal shifted the equilibrium enhancing substrate conversion by an additional 25% compared to the control reaction. Along with very efficient amine product removal, there was undesirable loss of ketone substrate and low product concentration was achieved. The system was therefore further improved by performing the reaction in organic solvent (n-heptane). Coupling the reaction system with membrane-assisted product removal resulted in a highly concentrated and relatively pure ( > 97%) product solution. Moreover, a product yield of 60% was reached, compared to 15% without product removal. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=amine%20donor" title="amine donor">amine donor</a>, <a href="https://publications.waset.org/abstracts/search?q=chiral%20amines" title=" chiral amines"> chiral amines</a>, <a href="https://publications.waset.org/abstracts/search?q=in%20situ%20product%20removal" title=" in situ product removal"> in situ product removal</a>, <a href="https://publications.waset.org/abstracts/search?q=transamination" title=" transamination"> transamination</a> </p> <a href="https://publications.waset.org/abstracts/110355/chiral-amine-synthesis-and-recovery-by-using-high-molecular-weight-amine-donors" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/110355.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">154</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">46</span> Comparison of Catalyst Support for High Pressure Reductive Amination</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Tz-Bang%20Du">Tz-Bang Du</a>, <a href="https://publications.waset.org/abstracts/search?q=Cheng-Han%20Hsieh"> Cheng-Han Hsieh</a>, <a href="https://publications.waset.org/abstracts/search?q=Li-Ping%20Ju"> Li-Ping Ju</a>, <a href="https://publications.waset.org/abstracts/search?q=Hung-Jie%20Liou"> Hung-Jie Liou</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Polyether amines synthesize by secondary hydroxyl polyether diol play an important role in epoxy hardener. The low molecular weight product is used in low viscosity and high transparent polyamine product for the logo, ground cover, especially for wind turbine blade, while the high molecular weight products are used in advanced agricultures such as a high-speed railway. High-pressure reductive amination process is required for producing these amines. In the condition of higher than 150 atm pressure and 200 degrees Celsius temperature, supercritical ammonia is used as a reactant and also a solvent. It would be a great challenge to select a catalyst support for such high-temperature alkaline circumstance. In this study, we have established a six-autoclave-type (SAT) high-pressure reactor for amination catalyst screening, which six experiment conditions with different temperature and pressure could be examined at the same time. We synthesized copper-nickel catalyst on different shaped alumina catalyst support and evaluated the catalyst activity for high-pressure reductive amination of polypropylene glycol (PPG) by SAT reactor. Ball type gamma alumina, ball type activated alumina and pellet type gamma alumina catalyst supports are evaluated in this study. Gamma alumina supports have shown better activity on PPG reductive amination than activated alumina support. In addition, the catalysts are evaluated in fixed bed reactor. The diamine product was successfully synthesized via this catalyst and the strength of the catalysts is measured. The crush strength of blank supports is about 13.5 lb for both gamma alumina and activated alumina. The strength increases to 20.3 lb after synthesized to be copper-nickel catalyst. After test in the fixed bed high-pressure reductive amination process for 100 hours, the crush strength of the used catalyst is 3.7 lb for activated alumina support, 12.0 lb for gamma alumina support. The gamma alumina is better than activated alumina to use as catalyst support in high-pressure reductive amination process. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=high%20pressure%20reductive%20amination" title="high pressure reductive amination">high pressure reductive amination</a>, <a href="https://publications.waset.org/abstracts/search?q=copper%20nickel%20catalyst" title=" copper nickel catalyst"> copper nickel catalyst</a>, <a href="https://publications.waset.org/abstracts/search?q=polyether%20amine" title=" polyether amine"> polyether amine</a>, <a href="https://publications.waset.org/abstracts/search?q=alumina" title=" alumina"> alumina</a> </p> <a href="https://publications.waset.org/abstracts/47166/comparison-of-catalyst-support-for-high-pressure-reductive-amination" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/47166.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">229</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">45</span> Kinetic Evaluation of Sterically Hindered Amines under Partial Oxy-Combustion Conditions</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Sara%20Camino">Sara Camino</a>, <a href="https://publications.waset.org/abstracts/search?q=Fernando%20Vega"> Fernando Vega</a>, <a href="https://publications.waset.org/abstracts/search?q=Mercedes%20Cano"> Mercedes Cano</a>, <a href="https://publications.waset.org/abstracts/search?q=Benito%20Navarrete"> Benito Navarrete</a>, <a href="https://publications.waset.org/abstracts/search?q=Jos%C3%A9%20A.%20Camino"> José A. Camino</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Carbon capture and storage (CCS) technologies should play a relevant role towards low-carbon systems in the European Union by 2030. Partial oxy-combustion emerges as a promising CCS approach to mitigate anthropogenic CO₂ emissions. Its advantages respect to other CCS technologies rely on the production of a higher CO₂ concentrated flue gas than these provided by conventional air-firing processes. The presence of more CO₂ in the flue gas increases the driving force in the separation process and hence it might lead to further reductions of the energy requirements of the overall CO₂ capture process. A higher CO₂ concentrated flue gas should enhance the CO₂ capture by chemical absorption in solvent kinetic and CO₂ cyclic capacity. They have impact on the performance of the overall CO₂ absorption process by reducing the solvent flow-rate required for a specific CO₂ removal efficiency. Lower solvent flow-rates decreases the reboiler duty during the regeneration stage and also reduces the equipment size and pumping costs. Moreover, R&D activities in this field are focused on novel solvents and blends that provide lower CO₂ absorption enthalpies and therefore lower energy penalties associated to the solvent regeneration. In this respect, sterically hindered amines are considered potential solvents for CO₂ capture. They provide a low energy requirement during the regeneration process due to its molecular structure. However, its absorption kinetics are slow and they must be promoted by blending with faster solvents such as monoethanolamine (MEA) and piperazine (PZ). In this work, the kinetic behavior of two sterically hindered amines were studied under partial oxy-combustion conditions and compared with MEA. A lab-scale semi-batch reactor was used. The CO₂ composition of the synthetic flue gas varied from 15%v/v – conventional coal combustion – to 60%v/v – maximum CO₂ concentration allowable for an optimal partial oxy-combustion operation. Firstly, 2-amino-2-methyl-1-propanol (AMP) showed a hybrid behavior with fast kinetics and a low enthalpy of CO₂ absorption. The second solvent was Isophrondiamine (IF), which has a steric hindrance in one of the amino groups. Its free amino group increases its cyclic capacity. In general, the presence of higher CO₂ concentration in the flue gas accelerated the CO₂ absorption phenomena, producing higher CO₂ absorption rates. In addition, the evolution of the CO2 loading also exhibited higher values in the experiments using higher CO₂ concentrated flue gas. The steric hindrance causes a hybrid behavior in this solvent, between both fast and slow kinetic solvents. The kinetics rates observed in all the experiments carried out using AMP were higher than MEA, but lower than the IF. The kinetic enhancement experienced by AMP at a high CO2 concentration is slightly over 60%, instead of 70% – 80% for IF. AMP also improved its CO₂ absorption capacity by 24.7%, from 15%v/v to 60%v/v, almost double the improvements achieved by MEA. In IF experiments, the CO₂ loading increased around 10% from 15%v/v to 60%v/v CO₂ and it changed from 1.10 to 1.34 mole CO₂ per mole solvent, more than 20% of increase. This hybrid kinetic behavior makes AMP and IF promising solvents for partial oxy–combustion applications. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=absorption" title="absorption">absorption</a>, <a href="https://publications.waset.org/abstracts/search?q=carbon%20capture" title=" carbon capture"> carbon capture</a>, <a href="https://publications.waset.org/abstracts/search?q=partial%20oxy-combustion" title=" partial oxy-combustion"> partial oxy-combustion</a>, <a href="https://publications.waset.org/abstracts/search?q=solvent" title=" solvent"> solvent</a> </p> <a href="https://publications.waset.org/abstracts/86708/kinetic-evaluation-of-sterically-hindered-amines-under-partial-oxy-combustion-conditions" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/86708.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">190</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">44</span> Effect of Chemical Modification of Functional Groups on Copper(II) Biosorption by Brown Marine Macroalgae Ascophyllum nodosum</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Luciana%20P.%20Mazur">Luciana P. Mazur</a>, <a href="https://publications.waset.org/abstracts/search?q=Tatiana%20A.%20Pozdniakova"> Tatiana A. Pozdniakova</a>, <a href="https://publications.waset.org/abstracts/search?q=Rui%20A.%20R.%20Boaventura"> Rui A. R. Boaventura</a>, <a href="https://publications.waset.org/abstracts/search?q=Vitor%20J.%20P.%20Vilar"> Vitor J. P. Vilar</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The principal mechanism of metal ions sequestration by brown algae involves the formation of complexes between the metal ion and functional groups present on the cell wall of the biological material. To understand the role of functional groups on copper(II) uptake by Ascophyllum nodosum, some functional groups were chemically modified. The esterification of carboxylic groups was carried out by suspending the biomass in a methanol/HCl solution under stirring for 48 h and the blocking of the sulfonic groups was performed by repeating the same procedure for 4 cycles of 48 h. The methylation of amines was conducted by suspending the biomass in a formaldehyde/formic acid solution under shaking for 6 h and the chemical modification of sulfhydryl groups on the biomass surface was achieved using dithiodipyridine for 1 h. Equilibrium sorption studies for Cu2+ using the raw and esterified algae were performed at pH 2.0 and 4.0. The experiments were performed using an initial copper concentration of 300 mg/L and algae dose of 1.0 g/L. After reaching the equilibrium, the metal in solution was quantified by atomic absorption spectrometry. The biological material was analyzed by Fourier Transform Infrared Spectroscopy and Potentiometric Titration techniques for functional groups identification and quantification, respectively. The results using unmodified algae showed that the maximum copper uptake capacity at pH 4.0 and 2.0 was 1.17 and 0.52 mmol/g, respectively. At acidic pH values most carboxyl groups are protonated and copper sorption suffered a significant reduction of 56%. Blocking the carboxylic, sulfonic, amines and sulfhydryl functional groups, copper uptake decreased by 24/26%, 69/81%, 1/23% and 40/27% at pH 2.0/4.0, respectively, when compared to the unmodified biomass. It was possible to conclude that the carboxylic and sulfonic groups are the main functional groups responsible for copper binding (>80%). This result is supported by the fact that the adsorption capacity is directly related to the presence of carboxylic groups of the alginate polymer, and the second most abundant acidic functional group in brown algae is the sulfonic acid of fucoidan that contributes, to a lower extent, to heavy metal binding, particularly at low pH. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=biosorption" title="biosorption">biosorption</a>, <a href="https://publications.waset.org/abstracts/search?q=brown%20marine%20macroalgae" title=" brown marine macroalgae"> brown marine macroalgae</a>, <a href="https://publications.waset.org/abstracts/search?q=copper" title=" copper"> copper</a>, <a href="https://publications.waset.org/abstracts/search?q=ion-exchange" title=" ion-exchange"> ion-exchange</a> </p> <a href="https://publications.waset.org/abstracts/21834/effect-of-chemical-modification-of-functional-groups-on-copperii-biosorption-by-brown-marine-macroalgae-ascophyllum-nodosum" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/21834.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">326</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">43</span> Khaya Cellulose Supported Copper Nanoparticles for Chemo Selective Aza-Michael Reactions</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=M.%20Shaheen%20Sarkar">M. Shaheen Sarkar</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20Lutfor%20Rahman"> M. Lutfor Rahman</a>, <a href="https://publications.waset.org/abstracts/search?q=Mashitah%20Mohd%20Yusoff"> Mashitah Mohd Yusoff</a> </p> <p class="card-text"><strong>Abstract:</strong></p> We prepared a highly active Khaya cellulose supported poly(hydroxamic acid) copper nanoparticles by the surface modification of Khaya cellulose through graft co-polymerization and subsequently amidoximation. The Cu-nanoparticle (0.05 mol% to 50 mol ppm) was selectively promoted Aza-Michael reaction of aliphatic amines to give the corresponding alkylated products at room temperature in methanol. The supported nanoparticle was easy to recover and reused seven times without significance loss of its activity. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=Aza-Michael" title="Aza-Michael">Aza-Michael</a>, <a href="https://publications.waset.org/abstracts/search?q=copper" title=" copper"> copper</a>, <a href="https://publications.waset.org/abstracts/search?q=cellulose" title=" cellulose"> cellulose</a>, <a href="https://publications.waset.org/abstracts/search?q=nanoparticles" title=" nanoparticles"> nanoparticles</a>, <a href="https://publications.waset.org/abstracts/search?q=poly%28hydroxamic%20acid%29" title=" poly(hydroxamic acid)"> poly(hydroxamic acid)</a> </p> <a href="https://publications.waset.org/abstracts/48532/khaya-cellulose-supported-copper-nanoparticles-for-chemo-selective-aza-michael-reactions" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/48532.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">343</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">42</span> Synthesis of Antifungal by the Use of Green Catalyst</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Elmeliani%20M%E2%80%99Hammed">Elmeliani M’Hammed</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The work is carried out for the synthesis of antifungal effective against the fungus Fusarium oxysporum, Albedinis (Foa), the causative agent of bayoud, dates palm disease, through the use of raw clay as a green catalyst. The Aza-Michael reaction of amine addition to α, β-unsaturated alkene was carried out using the crude clay as a green catalyst to synthesize the antifungal agent bayoud. The reaction was carried out under favorable conditions, ambient temperature, without solvent, and a green catalyst "loves the environment" that the product that was synthesized gave us a high yield and excellent chemo selectivity. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=raw%20clay" title="raw clay">raw clay</a>, <a href="https://publications.waset.org/abstracts/search?q=amines" title=" amines"> amines</a>, <a href="https://publications.waset.org/abstracts/search?q=alkenes" title=" alkenes"> alkenes</a>, <a href="https://publications.waset.org/abstracts/search?q=environment" title=" environment"> environment</a>, <a href="https://publications.waset.org/abstracts/search?q=antifungal" title=" antifungal"> antifungal</a>, <a href="https://publications.waset.org/abstracts/search?q=bayoud" title=" bayoud"> bayoud</a>, <a href="https://publications.waset.org/abstracts/search?q=date%20palms" title=" date palms"> date palms</a> </p> <a href="https://publications.waset.org/abstracts/171504/synthesis-of-antifungal-by-the-use-of-green-catalyst" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/171504.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">98</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">41</span> In silico Model of Transamination Reaction Mechanism</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Sang-Woo%20Han">Sang-Woo Han</a>, <a href="https://publications.waset.org/abstracts/search?q=Jong-Shik%20Shin"> Jong-Shik Shin</a> </p> <p class="card-text"><strong>Abstract:</strong></p> w-Transaminase (w-TA) is broadly used for synthesizing chiral amines with a high enantiopurity. However, the reaction mechanism of w-TA has been not well studied, contrary to a-transaminase (a-TA) such as AspTA. Here, we propose in silico model on the reaction mechanism of w-TA. Based on the modeling results which showed large free energy gaps between external aldimine and quinonoid on deamination (or ketimine and quinonoid on amination), withdrawal of Ca-H seemed as a critical step which determines the reaction rate on both amination and deamination reactions, which is consistent with previous researches. Hyperconjugation was also observed in both external aldimine and ketimine which weakens Ca-H bond to elevate Ca-H abstraction. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=computational%20modeling" title="computational modeling">computational modeling</a>, <a href="https://publications.waset.org/abstracts/search?q=reaction%20intermediates" title=" reaction intermediates"> reaction intermediates</a>, <a href="https://publications.waset.org/abstracts/search?q=w-transaminase" title=" w-transaminase"> w-transaminase</a>, <a href="https://publications.waset.org/abstracts/search?q=in%20silico%20model" title=" in silico model"> in silico model</a> </p> <a href="https://publications.waset.org/abstracts/23667/in-silico-model-of-transamination-reaction-mechanism" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/23667.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">544</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">40</span> Antioxidant Activity Studies of Novel Schiff and Mannich Bases</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=D.%20J.%20Madhu%20Kumar">D. J. Madhu Kumar</a>, <a href="https://publications.waset.org/abstracts/search?q=D.%20Jagadeesh%20Prasad"> D. Jagadeesh Prasad</a>, <a href="https://publications.waset.org/abstracts/search?q=Sana%20Sheik"> Sana Sheik</a>, <a href="https://publications.waset.org/abstracts/search?q=E.%20P.%20Rejeesh"> E. P. Rejeesh </a> </p> <p class="card-text"><strong>Abstract:</strong></p> A series of Mannich bases derived from 1,2,4-triazole(3a-k and 4a-k) are synthesized by treating a Schiff base with various substituted primary/secondary amines and formaldehyde. The Schiff base is prepared by treating 3-methyl-4-amino-5-mercapto-1,2,4-triazole with 3,4-dimethoxybenzaldehyde in the presence of acid catalyst. The triazole is prepared by treating acetic acid with thiocarbohydrazide at reflux temperature. All the synthesized samples are characterised by FT-IR, 1H-NMR, and LC-MASS spectral studies and screened for their anti-oxidant activity. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=mannich%20bases" title="mannich bases">mannich bases</a>, <a href="https://publications.waset.org/abstracts/search?q=anti-oxidant%20activity" title=" anti-oxidant activity"> anti-oxidant activity</a>, <a href="https://publications.waset.org/abstracts/search?q=schiff%20base" title=" schiff base"> schiff base</a>, <a href="https://publications.waset.org/abstracts/search?q=triazole" title=" triazole"> triazole</a> </p> <a href="https://publications.waset.org/abstracts/1711/antioxidant-activity-studies-of-novel-schiff-and-mannich-bases" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/1711.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">516</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">39</span> Eco-Benign and Highly Efficient Procedures for the Synthesis of Amides Catalyzed by Heteropolyanion-Based Ionic Liquids under Solvent-Free Conditions</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Zhikai%20Chena">Zhikai Chena</a>, <a href="https://publications.waset.org/abstracts/search?q=Renzhong%20Fu"> Renzhong Fu</a>, <a href="https://publications.waset.org/abstracts/search?q=Wen%20Chaib"> Wen Chaib</a>, <a href="https://publications.waset.org/abstracts/search?q=Rongxin%20Yuanb"> Rongxin Yuanb</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Two eco-benign and highly efficient routes for the synthesis of amides have been developed by treating amines with corresponding carboxylic acids or carboxamides in the presence of heteropolyanion-based ionic liquids (HPAILs) as catalysts. These practical reactions can tolerate a wide range of substrates. Thus, various amides were obtained in good to excellent yields under solvent-free conditions at heating. Moreover, recycling studies revealed that HPAILs are easily reusable for this two procedures. These methods provide green and much improved protocols over the existing methods. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=synthesis" title="synthesis">synthesis</a>, <a href="https://publications.waset.org/abstracts/search?q=amide" title=" amide"> amide</a>, <a href="https://publications.waset.org/abstracts/search?q=%C4%B1onic%20liquid" title=" ıonic liquid"> ıonic liquid</a>, <a href="https://publications.waset.org/abstracts/search?q=catalyst" title=" catalyst"> catalyst</a> </p> <a href="https://publications.waset.org/abstracts/1964/eco-benign-and-highly-efficient-procedures-for-the-synthesis-of-amides-catalyzed-by-heteropolyanion-based-ionic-liquids-under-solvent-free-conditions" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/1964.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">259</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">38</span> Experimental Investigation of Absorbent Regeneration Techniques to Lower the Cost of Combined CO₂ and SO₂ Capture Process</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Bharti%20Garg">Bharti Garg</a>, <a href="https://publications.waset.org/abstracts/search?q=Ashleigh%20Cousins"> Ashleigh Cousins</a>, <a href="https://publications.waset.org/abstracts/search?q=Pauline%20Pearson"> Pauline Pearson</a>, <a href="https://publications.waset.org/abstracts/search?q=Vincent%20Verheyen"> Vincent Verheyen</a>, <a href="https://publications.waset.org/abstracts/search?q=Paul%20Feron"> Paul Feron</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The presence of SO₂ in power plant flue gases makes flue gas desulfurization (FGD) an essential requirement prior to post combustion CO₂ (PCC) removal facilities. Although most of the power plants worldwide deploy FGD in order to comply with environmental regulations, generally the achieved SO₂ levels are not sufficiently low for the flue gases to enter the PCC unit. The SO₂ level in the flue gases needs to be less than 10 ppm to effectively operate the PCC installation. The existing FGD units alone cannot bring down the SO₂ levels to or below 10 ppm as required for CO₂ capture. It might require an additional scrubber along with the existing FGD unit to bring the SO₂ to the desired levels. The absence of FGD units in Australian power plants brings an additional challenge. SO₂ concentrations in Australian power station flue gas emissions are in the range of 100-600 ppm. This imposes a serious barrier on the implementation of standard PCC technologies in Australia. CSIRO’s developed CS-Cap process is a unique solution to capture SO₂ and CO₂ in a single column with single absorbent which can potentially bring cost-effectiveness to the commercial deployment of carbon capture in Australia, by removing the need for FGD. Estimated savings of removing SO₂ through a similar process as CS-Cap is around 200 MMUSD for a 500 MW Australian power plant. Pilot plant trials conducted to generate the proof of concept resulted in 100% removal of SO₂ from flue gas without utilising standard limestone-based FGD. In this work, removal of absorbed sulfur from aqueous amine absorbents generated in the pilot plant trials has been investigated by reactive crystallisation and thermal reclamation. More than 95% of the aqueous amines can be reclaimed back from the sulfur loaded absorbent via reactive crystallisation. However, the recovery of amines through thermal reclamation is limited and depends on the sulfur loading on the spent absorbent. The initial experimental work revealed that reactive crystallisation is a better fit for CS-Cap’s sulfur-rich absorbent especially when it is also capable of generating K₂SO₄ crystals of highly saleable quality ~ 99%. Initial cost estimation carried on both the technologies resulted in almost similar capital expenditure; however, the operating cost is considerably higher in thermal reclaimer than that in crystalliser. The experimental data generated in the laboratory from both the regeneration techniques have been used to generate the simulation model in Aspen Plus. The simulation model illustrates the economic benefits which could be gained by removing flue gas desulfurization prior to standard PCC unit and replacing it with a CS-Cap absorber column co-capturing CO₂ and SO₂, and it's absorbent regeneration system which would be either reactive crystallisation or thermal reclamation. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=combined%20capture" title="combined capture">combined capture</a>, <a href="https://publications.waset.org/abstracts/search?q=cost%20analysis" title=" cost analysis"> cost analysis</a>, <a href="https://publications.waset.org/abstracts/search?q=crystallisation" title=" crystallisation"> crystallisation</a>, <a href="https://publications.waset.org/abstracts/search?q=CS-Cap" title=" CS-Cap"> CS-Cap</a>, <a href="https://publications.waset.org/abstracts/search?q=flue%20gas%20desulfurisation" title=" flue gas desulfurisation"> flue gas desulfurisation</a>, <a href="https://publications.waset.org/abstracts/search?q=regeneration" title=" regeneration"> regeneration</a>, <a href="https://publications.waset.org/abstracts/search?q=sulfur" title=" sulfur"> sulfur</a>, <a href="https://publications.waset.org/abstracts/search?q=thermal%20reclamation" title=" thermal reclamation "> thermal reclamation </a> </p> <a href="https://publications.waset.org/abstracts/100335/experimental-investigation-of-absorbent-regeneration-techniques-to-lower-the-cost-of-combined-co2-and-so2-capture-process" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/100335.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">127</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">37</span> Biogas Separation, Alcohol Amine Solutions</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Jingxiao%20Liang">Jingxiao Liang</a>, <a href="https://publications.waset.org/abstracts/search?q=David%20Rooneyman"> David Rooneyman</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Biogas, which is a valuable renewable energy source, can be produced by anaerobic fermentation of agricultural waste, manure, municipal waste, plant material, sewage, green waste, or food waste. It is composed of methane (CH4) and carbon dioxide (CO2) but also contains significant quantities of undesirable compounds such as hydrogen sulfide (H2S), ammonia (NH3), and siloxanes. Since typical raw biogas contains 25–45% CO2, The requirements for biogas quality depend on its further application. Before biogas is being used more efficiently, CO2 should be removed. One of the existing options for biogas separation technologies is based on chemical absorbents, in particular, mono-, di- and tri-alcohol amine solutions. Such amine solutions have been applied as highly efficient CO2 capturing agents. The benchmark in this experiment is N-methyldiethanolamine (MDEA) with piperazine (PZ) as an activator, from CO2 absorption Isotherm curve, optimization conditions are collected, such as activator percentage, temperature etc. This experiment makes new alcohol amines, which could have the same CO2 absorbing ability as activated MDEA, using glycidol as one of reactant, the result is quite satisfying. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=biogas" title="biogas">biogas</a>, <a href="https://publications.waset.org/abstracts/search?q=CO2" title=" CO2"> CO2</a>, <a href="https://publications.waset.org/abstracts/search?q=MDEA" title=" MDEA"> MDEA</a>, <a href="https://publications.waset.org/abstracts/search?q=separation" title=" separation"> separation</a> </p> <a href="https://publications.waset.org/abstracts/34283/biogas-separation-alcohol-amine-solutions" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/34283.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">634</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">36</span> Highly Selective Phosgene Free Synthesis of Methylphenylcarbamate from Aniline and Dimethyl Carbonate over Heterogeneous Catalyst</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Nayana%20T.%20Nivangune">Nayana T. Nivangune</a>, <a href="https://publications.waset.org/abstracts/search?q=Vivek%20V.%20Ranade"> Vivek V. Ranade</a>, <a href="https://publications.waset.org/abstracts/search?q=Ashutosh%20A.%20Kelkar"> Ashutosh A. Kelkar</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Organic carbamates are versatile compounds widely employed as pesticides, fungicides, herbicides, dyes, pharmaceuticals, cosmetics and in the synthesis of polyurethanes. Carbamates can be easily transformed into isocyanates by thermal cracking. Isocyantes are used as precursors for manufacturing agrochemicals, adhesives and polyurethane elastomers. Manufacture of polyurethane foams is a major application of aromatic ioscyanates and in 2007 the global consumption of polyurethane was about 12 million metric tons/year and the average annual growth rate was about 5%. Presently Isocyanates/carbamates are manufactured by phosgene based process. However, because of high toxicity of phoegene and formation of waste products in large quantity; there is a need to develop alternative and safer process for the synthesis of isocyanates/carbamates. Recently many alternative processes have been investigated and carbamate synthesis by methoxycarbonylation of aromatic amines using dimethyl carbonate (DMC) as a green reagent has emerged as promising alternative route. In this reaction methanol is formed as a by-product, which can be converted to DMC either by oxidative carbonylation of methanol or by reacting with urea. Thus, the route based on DMC has a potential to provide atom efficient and safer route for the synthesis of carbamates from DMC and amines. Lot of work is being carried out on the development of catalysts for this reaction and homogeneous zinc salts were found to be good catalysts for the reaction. However, catalyst/product separation is challenging with these catalysts. There are few reports on the use of supported Zn catalysts; however, deactivation of the catalyst is the major problem with these catalysts. We wish to report here methoxycarbonylation of aniline to methylphenylcarbamate (MPC) using amino acid complexes of Zn as highly active and selective catalysts. The catalysts were characterized by XRD, IR, solid state NMR and XPS analysis. Methoxycarbonylation of aniline was carried out at 170 °C using 2.5 wt% of the catalyst to achieve >98% conversion of aniline with 97-99% selectivity to MPC as the product. Formation of N-methylated products in small quantity (1-2%) was also observed. Optimization of the reaction conditions was carried out using zinc-proline complex as the catalyst. Selectivity was strongly dependent on the temperature and aniline:DMC ratio used. At lower aniline:DMC ratio and at higher temperature, selectivity to MPC decreased (85-89% respectively) with the formation of N-methylaniline (NMA), N-methyl methylphenylcarbamate (MMPC) and N,N-dimethyl aniline (NNDMA) as by-products. Best results (98% aniline conversion with 99% selectivity to MPC in 4 h) were observed at 170oC and aniline:DMC ratio of 1:20. Catalyst stability was verified by carrying out recycle experiment. Methoxycarbonylation preceded smoothly with various amine derivatives indicating versatility of the catalyst. The catalyst is inexpensive and can be easily prepared from zinc salt and naturally occurring amino acids. The results are important and provide environmentally benign route for MPC synthesis with high activity and selectivity. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=aniline" title="aniline">aniline</a>, <a href="https://publications.waset.org/abstracts/search?q=heterogeneous%20catalyst" title=" heterogeneous catalyst"> heterogeneous catalyst</a>, <a href="https://publications.waset.org/abstracts/search?q=methoxycarbonylation" title=" methoxycarbonylation"> methoxycarbonylation</a>, <a href="https://publications.waset.org/abstracts/search?q=methylphenyl%20carbamate" title=" methylphenyl carbamate"> methylphenyl carbamate</a> </p> <a href="https://publications.waset.org/abstracts/52921/highly-selective-phosgene-free-synthesis-of-methylphenylcarbamate-from-aniline-and-dimethyl-carbonate-over-heterogeneous-catalyst" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/52921.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">274</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">35</span> Experimental Study of CO2 Absorption in Different Blend Solutions as Solvent for CO2 Capture</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Rouzbeh%20Ramezani">Rouzbeh Ramezani</a>, <a href="https://publications.waset.org/abstracts/search?q=Renzo%20Di%20Felice"> Renzo Di Felice</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Nowadays, removal of CO<sub>2</sub> as one of the major contributors to global warming using alternative solvents with high CO<sub>2</sub> absorption efficiency, is an important industrial operation. In this study, three amines, including 2-methylpiperazine, potassium sarcosinate and potassium lysinate as potential additives, were added to the potassium carbonate solution as a base solvent for CO<sub>2</sub> capture. In order to study the absorption performance of CO<sub>2</sub> in terms of loading capacity of CO<sub>2</sub> and absorption rate, the absorption experiments in a blend of additives with potassium carbonate were carried out using the vapor-liquid equilibrium apparatus at a temperature of 313.15 K, CO<sub>2</sub> partial pressures ranging from 0 to 50 kPa and at mole fractions 0.2, 0.3, and 0.4. Furthermore, the performance of CO<sub>2</sub> absorption in these blend solutions was compared with pure monoethanolamine and with pure potassium carbonate. Finally, a correlation with good accuracy was developed using the nonlinear regression analysis in order to predict CO<sub>2</sub> loading capacity. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=absorption%20rate" title="absorption rate">absorption rate</a>, <a href="https://publications.waset.org/abstracts/search?q=carbon%20dioxide" title=" carbon dioxide"> carbon dioxide</a>, <a href="https://publications.waset.org/abstracts/search?q=CO2%20capture" title=" CO2 capture"> CO2 capture</a>, <a href="https://publications.waset.org/abstracts/search?q=global%20warming" title=" global warming"> global warming</a>, <a href="https://publications.waset.org/abstracts/search?q=loading%20capacity" title=" loading capacity"> loading capacity</a> </p> <a href="https://publications.waset.org/abstracts/68900/experimental-study-of-co2-absorption-in-different-blend-solutions-as-solvent-for-co2-capture" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/68900.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">284</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">34</span> An Investigation on the Removal of Synthetic Dyes from Aqueous Solution by a Functional Polymer</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ali%20Kara">Ali Kara</a>, <a href="https://publications.waset.org/abstracts/search?q=Asim%20Olgun"> Asim Olgun</a>, <a href="https://publications.waset.org/abstracts/search?q=Sevgi%20Sozugecer"> Sevgi Sozugecer</a>, <a href="https://publications.waset.org/abstracts/search?q=Sahin%20Ozel"> Sahin Ozel</a>, <a href="https://publications.waset.org/abstracts/search?q=Kubra%20Nur%20Yildiz"> Kubra Nur Yildiz</a>, <a href="https://publications.waset.org/abstracts/search?q=P.%20Sevin%C3%A7"> P. Sevinç</a>, <a href="https://publications.waset.org/abstracts/search?q=Abdurrahman%20Kuresh"> Abdurrahman Kuresh</a>, <a href="https://publications.waset.org/abstracts/search?q=Guliz%20Turhan"> Guliz Turhan</a>, <a href="https://publications.waset.org/abstracts/search?q=Duygu%20Gulgun"> Duygu Gulgun</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The synthetic dyes, one of the most hazardous chemical compound classes, are important potential water pollutions since their presence in water bodies reduces light penetration, precluding the photosynthesis of aqueous flora and causing various diseases. Some the synthetic dyes are highly toxic and/or carcinogenic, and their biodegradation can produce even more toxic aromatic amines. The adsorption procedure is one of the most effective means of removing synthetic dye pollutants, and has been described in a number of previous studies by using the functional polymers. In this study, we investigated the removal of synthetic dyes from aqueous solution by using a functional polymer as an adsorbent material. The effect of initial solution concentration, pH, and contact time on the adsorption capacity of the adsorbent were studied in details. The results showed that functional polymer has a potential to be used as cost-effective and efficient adsorbent for the treatment of aqueous solutions from textile industries. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=functional%20polymers" title="functional polymers">functional polymers</a>, <a href="https://publications.waset.org/abstracts/search?q=synhetic%20dyes" title=" synhetic dyes"> synhetic dyes</a>, <a href="https://publications.waset.org/abstracts/search?q=adsorption" title=" adsorption"> adsorption</a>, <a href="https://publications.waset.org/abstracts/search?q=physicochemical%20parameters" title=" physicochemical parameters"> physicochemical parameters</a> </p> <a href="https://publications.waset.org/abstracts/94325/an-investigation-on-the-removal-of-synthetic-dyes-from-aqueous-solution-by-a-functional-polymer" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/94325.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">182</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">33</span> Determination of Verapamil Hydrochloride in the Tablet and Injection Solution by the Verapamil-Sensitive Electrode and Possibilities of Application in Pharmaceutical Analysis</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Faisal%20A.%20Salih">Faisal A. Salih</a>, <a href="https://publications.waset.org/abstracts/search?q=V.%20V.%20Egorov"> V. V. Egorov</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Verapamil is a drug used in medicine for arrhythmia, angina, and hypertension as a calcium channel blocker. In this study, a Verapamil-selective electrode was prepared, and the concentrations of the components in the membrane were as follows: PVC (32.8 wt %), O-NPhOE (66.6 wt %), and KTPClPB (0.6 wt % or approximately 0.01 M). The inner solution containing verapamil hydrochloride 1 x 10⁻³ M was introduced, and the electrodes were conditioned overnight in 1 x 10⁻³ M verapamil hydrochloride solution in 1 x 10⁻³ M orthophosphoric acid. These studies have demonstrated that O-NPhOE and KTPClPB are the best plasticizers and ion exchangers, while both direct potentiometry and potentiometric titration methods can be used for the determination of verapamil hydrochloride in tablets and injection solutions. Normalized weights of verapamil per tablet (80.4±0.2, 80.7±0.2, 81.0±0.4 mg) were determined by direct potentiometry and potentiometric titration, respectively. Weights of verapamil per average tablet weight determined by the methods of direct potentiometry and potentiometric titration were" 80.4±0.2, 80.7±0.2 mg determined for the same set of tablets, respectively. The masses of verapamil in solutions for injection, determined by direct potentiometry for two ampoules from one set, were (5.00±0.015, 5.004±0.006) mg. In all cases, good reproducibility and excellent correspondence with the declared quantities were observed. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=verapamil" title="verapamil">verapamil</a>, <a href="https://publications.waset.org/abstracts/search?q=potentiometry" title=" potentiometry"> potentiometry</a>, <a href="https://publications.waset.org/abstracts/search?q=ion-selective%20electrode" title=" ion-selective electrode"> ion-selective electrode</a>, <a href="https://publications.waset.org/abstracts/search?q=lipophilic%20physiologically%20active%20amines" title=" lipophilic physiologically active amines"> lipophilic physiologically active amines</a> </p> <a href="https://publications.waset.org/abstracts/154452/determination-of-verapamil-hydrochloride-in-the-tablet-and-injection-solution-by-the-verapamil-sensitive-electrode-and-possibilities-of-application-in-pharmaceutical-analysis" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/154452.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">86</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">32</span> Assessment of Carbon Dioxide Separation by Amine Solutions Using Electrolyte Non-Random Two-Liquid and Peng-Robinson Models: Carbon Dioxide Absorption Efficiency </h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Arash%20Esmaeili">Arash Esmaeili</a>, <a href="https://publications.waset.org/abstracts/search?q=Zhibang%20Liu"> Zhibang Liu</a>, <a href="https://publications.waset.org/abstracts/search?q=Yang%20Xiang"> Yang Xiang</a>, <a href="https://publications.waset.org/abstracts/search?q=Jimmy%20Yun"> Jimmy Yun</a>, <a href="https://publications.waset.org/abstracts/search?q=Lei%20Shao"> Lei Shao</a> </p> <p class="card-text"><strong>Abstract:</strong></p> A high pressure carbon dioxide (CO<sub>2</sub>) absorption from a specific gas in a conventional column has been evaluated by the Aspen HYSYS simulator using a wide range of single absorbents and blended solutions to estimate the outlet CO<sub>2</sub> concentration, absorption efficiency and CO<sub>2</sub> loading to choose the most proper solution in terms of CO<sub>2 </sub>capture for environmental concerns. The property package (Acid Gas-Chemical Solvent) which is compatible with all applied solutions for the simulation in this study, estimates the properties based on an electrolyte non-random two-liquid (E-NRTL) model for electrolyte thermodynamics and Peng-Robinson equation of state for the vapor and liquid hydrocarbon phases. Among all the investigated single amines as well as blended solutions, piperazine (PZ) and the mixture of piperazine and monoethanolamine (MEA) have been found as the most effective absorbents respectively for CO<sub>2</sub> absorption with high reactivity based on the simulated operational conditions. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=absorption" title="absorption">absorption</a>, <a href="https://publications.waset.org/abstracts/search?q=amine%20solutions" title=" amine solutions"> amine solutions</a>, <a href="https://publications.waset.org/abstracts/search?q=Aspen%20HYSYS" title=" Aspen HYSYS"> Aspen HYSYS</a>, <a href="https://publications.waset.org/abstracts/search?q=carbon%20dioxide" title=" carbon dioxide"> carbon dioxide</a>, <a href="https://publications.waset.org/abstracts/search?q=simulation" title=" simulation"> simulation</a> </p> <a href="https://publications.waset.org/abstracts/127187/assessment-of-carbon-dioxide-separation-by-amine-solutions-using-electrolyte-non-random-two-liquid-and-peng-robinson-models-carbon-dioxide-absorption-efficiency" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/127187.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">185</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">31</span> Synthesis of Cardanol Oil Building Blocks for Polymer Synthesis</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Sylvain%20Caillol">Sylvain Caillol</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Uncertainty in terms of price and availability of petroleum, in addition to global political and institutional tendencies toward the principles of sustainable development, urge chemical industry to a sustainable chemistry and particularly the use of renewable resources in order to synthesize biobased chemicals and products. We propose a platform approach for the synthesis of various building blocks from cardanol in one or two-steps syntheses. Cardanol, which is a natural phenol, is issued from Cashew Nutshell Liquid (CNSL), a non-edible renewable resource, co-produced from cashew industry in large commercial volumes. Cardanol is particularly interesting to replace fossil aromatic groups in polymers and materials. Our team studied various routes for the synthesis of cardanol-derived biobased building blocks used after that in polymer syntheses. For example, we used phenolation to dimerize/oligomerize cardanol to propose increase functionality of cardanol. Thio-ene was used to synthesize new reactive amines. Epoxidation and (meth)acrylation were also used to insert oxirane or (meth)acrylate groups in order to synthesize polymers and materials. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=cardanol" title="cardanol">cardanol</a>, <a href="https://publications.waset.org/abstracts/search?q=cashew%20nutshell%20liquid" title=" cashew nutshell liquid"> cashew nutshell liquid</a>, <a href="https://publications.waset.org/abstracts/search?q=epoxy" title=" epoxy"> epoxy</a>, <a href="https://publications.waset.org/abstracts/search?q=vinyl%20ester" title=" vinyl ester"> vinyl ester</a>, <a href="https://publications.waset.org/abstracts/search?q=latex" title=" latex"> latex</a>, <a href="https://publications.waset.org/abstracts/search?q=emulsion" title=" emulsion"> emulsion</a> </p> <a href="https://publications.waset.org/abstracts/40491/synthesis-of-cardanol-oil-building-blocks-for-polymer-synthesis" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/40491.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">176</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">30</span> Solid-State Luminescence of Fluorenone Grafted onto Cellulose Aldehyde Backbone Using Different Organic Amine Spacers</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Isam%20M.%20Arafa">Isam M. Arafa</a>, <a href="https://publications.waset.org/abstracts/search?q=Mazin%20Y.%20Shatnawi"> Mazin Y. Shatnawi</a>, <a href="https://publications.waset.org/abstracts/search?q=Yaser%20A.%20Yousef"> Yaser A. Yousef</a>, <a href="https://publications.waset.org/abstracts/search?q=Batool%20Zaid%20Al-Momani"> Batool Zaid Al-Momani</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The present work describes the preparation, characterization, and luminescence of a series of fluorenone (FL) based luminophores grafted onto modified cellulose microfibers. The FL is condensed onto cellulose aldehyde using three diamine spacers (H₂N-NH₂, H₂N(CH₂)₂NH₂ and H₂N(CH₂)₃NH₂) to afford Cell=Spacer=FL. The obtained products were characterized by spectroscopic (FT-IR, UV–Vis), thermal gravimetric analysis (TGA), and microscopic (Optical, SEM) techniques. The UV-Vis spectra of the FL=N(CH₂)ₓNH₂ (x = 0, 2, 3) moieties show that they are transparent in the 375- 800 nm region while they exhibit intense absorption band below 350 nm attributed to n-π* and π-π* transitions. The solid-state photoluminescence (PLs-s) of the cold-pressed pellets of the FL=N(CH₂)ₓNH₂ and Cell=Spacer=FL placed in a quartz cuvette show strong emission in the 500-550 nm region upon irradiation with Xe lamp light (λex = 320 nm). The PLs-s green emission of the grafted Cell=Spacer=FL was evaluated relative to that of the FL-based precursor. These grafted conjugated products have the potential to be used as analyte sensors for typical nitroaromatics/aromatic amines and be further extended to immunoassay studies for aromatic amino acids such as phenylalanine and histidine. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=luminescence" title="luminescence">luminescence</a>, <a href="https://publications.waset.org/abstracts/search?q=cellulose" title=" cellulose"> cellulose</a>, <a href="https://publications.waset.org/abstracts/search?q=fluorenone" title=" fluorenone"> fluorenone</a>, <a href="https://publications.waset.org/abstracts/search?q=grafting" title=" grafting"> grafting</a>, <a href="https://publications.waset.org/abstracts/search?q=solid%20state" title=" solid state"> solid state</a> </p> <a href="https://publications.waset.org/abstracts/176946/solid-state-luminescence-of-fluorenone-grafted-onto-cellulose-aldehyde-backbone-using-different-organic-amine-spacers" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/176946.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">72</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">29</span> Amine Hardeners with Carbon Nanotubes Dispersing Ability for Epoxy Coating Systems</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Szymon%20Kugler">Szymon Kugler</a>, <a href="https://publications.waset.org/abstracts/search?q=Krzysztof%20Kowalczyk"> Krzysztof Kowalczyk</a>, <a href="https://publications.waset.org/abstracts/search?q=Tadeusz%20Spychaj"> Tadeusz Spychaj</a> </p> <p class="card-text"><strong>Abstract:</strong></p> An addition of carbon nanotubes (CNT) can simultaneously improve many features of epoxy coatings, i.e. electrical, mechanical, functional and thermal. Unfortunately, this nanofiller negatively affects visual properties of the coatings, such as transparency and gloss. The main reason for the low visual performance of CNT-modified epoxy coatings is the lack of compatibility between CNT and popular amine curing agents, although epoxy resins based on bisphenol A are indisputable good CNT dispersants. This is a serious obstacle in utilization of the coatings in advanced applications, demanding both high transparency and electrical conductivity. The aim of performed investigations was to find amine curing agents exhibiting affinity for CNT, and ensuring good performance of epoxy coatings with them. Commercially available CNT was dispersed in epoxy resin, as well as in different aliphatic, cycloaliphatic and aromatic amines, using one of two dispergation methods: ultrasonic or mechanical. The CNT dispersions were subsequently used in the preparation of epoxy coating compositions and coatings on a transparent substrate. It was found that amine derivative of bio-based cardanol, as well as modified o-tolylbiguanide exhibit significant CNT, dispersing properties, resulting in improved transparent/electroconductive performance of epoxy coatings. In one of prepared coating systems just 0.025 wt.% (250 ppm) of CNT was enough to obtain coatings with semi conductive properties, 83% of transparency as well as perfect chemical resistance to methyl-ethyl ketone and improved thermal stability. Additionally, a theory of the influence of amine chemical structure on CNT dispersing properties was proposed. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=bio-based%20cardanol" title="bio-based cardanol">bio-based cardanol</a>, <a href="https://publications.waset.org/abstracts/search?q=carbon%20nanotubes" title=" carbon nanotubes"> carbon nanotubes</a>, <a href="https://publications.waset.org/abstracts/search?q=epoxy%20coatings" title=" epoxy coatings"> epoxy coatings</a>, <a href="https://publications.waset.org/abstracts/search?q=tolylbiguanide" title=" tolylbiguanide"> tolylbiguanide</a> </p> <a href="https://publications.waset.org/abstracts/74761/amine-hardeners-with-carbon-nanotubes-dispersing-ability-for-epoxy-coating-systems" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/74761.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">211</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">28</span> Synthesis and Characterization of Some Novel Carbazole Schiff Bases (OLED)</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Baki%20Cicek">Baki Cicek</a>, <a href="https://publications.waset.org/abstracts/search?q=Umit%20Calisir"> Umit Calisir</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Carbazoles have been replaced lots of studies from 1960's to present and also still continues. In 1987, the first diode device had been developed. Thanks to that study, light emitting devices have been investigated and developed and also have been used on commercial applications. Nowadays, OLED (Organic Light Emitting Diodes) technology is using on lots of electronic screen such as (mobile phone, computer monitors, televisions, etc.) Carbazoles were subject a lot of study as a semiconductor material. Although this technology is used commen and widely, it is still development stage. Metal complexes of these compounds are using at pigment dyes because of colored substances, polymer technology, medicine industry, agriculture area, preparing rocket fuel-oil, determine some of biological events, etc. Becides all of these to preparing of schiff base synthesis is going on intensely. In this study, some of novel carbazole schiff bases were synthesized starting from carbazole. For that purpose, firstly, carbazole was alkylated. After purification of N-substituted-carbazole was nitrated to sythesized 3-nitro-N-substituted and 3,6-dinitro-N-substituted carbazoles. At next step, nitro group/groups were reduced to amines. Purified with using a type of silica gel-column chromatography. At the last step of our study, with sythesized 3,6-diamino-N-substituted carbazoles and 3-amino-N-substituted carbazoles were reacted with aldehydes to condensation reactions. 3-(imino-p-hydroxybenzyl)-N-isobutyl -carbazole, 3-(imino-2,3,4-trimethoxybenzene)-N-butylcarbazole, 3-(imino-3,4-dihydroxybenzene)-N-octylcarbazole, 3-(imino-2,3-dihydroxybenzene)-N-octylkarbazole and 3,6-di(α-imino-β-naphthol) -N-hexylcarbazole compounds were synthesized. All of synthesized compounds were characterized with FT-IR, 1H-NMR, 13C-NMR, and LC-MS. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=carbazole" title="carbazole">carbazole</a>, <a href="https://publications.waset.org/abstracts/search?q=carbazol%20schiff%20base" title=" carbazol schiff base"> carbazol schiff base</a>, <a href="https://publications.waset.org/abstracts/search?q=condensation%20reactions" title=" condensation reactions"> condensation reactions</a>, <a href="https://publications.waset.org/abstracts/search?q=OLED" title=" OLED"> OLED</a> </p> <a href="https://publications.waset.org/abstracts/23146/synthesis-and-characterization-of-some-novel-carbazole-schiff-bases-oled" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/23146.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span 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