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Tholin - Wikipedia

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</li> <li id="toc-Triton" class="vector-toc-list-item vector-toc-level-3"> <a class="vector-toc-link" href="#Triton"> <div class="vector-toc-text"> <span class="vector-toc-numb">4.1.4</span> <span>Triton</span> </div> </a> <ul id="toc-Triton-sublist" class="vector-toc-list"> </ul> </li> </ul> </li> <li id="toc-Dwarf_planets" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Dwarf_planets"> <div class="vector-toc-text"> <span class="vector-toc-numb">4.2</span> <span>Dwarf planets</span> </div> </a> <ul id="toc-Dwarf_planets-sublist" class="vector-toc-list"> <li id="toc-Pluto" class="vector-toc-list-item vector-toc-level-3"> <a class="vector-toc-link" href="#Pluto"> <div class="vector-toc-text"> <span class="vector-toc-numb">4.2.1</span> <span>Pluto</span> </div> </a> <ul id="toc-Pluto-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Ceres" class="vector-toc-list-item vector-toc-level-3"> <a class="vector-toc-link" href="#Ceres"> <div class="vector-toc-text"> <span class="vector-toc-numb">4.2.2</span> <span>Ceres</span> </div> </a> <ul id="toc-Ceres-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Makemake" class="vector-toc-list-item vector-toc-level-3"> <a class="vector-toc-link" href="#Makemake"> <div class="vector-toc-text"> <span class="vector-toc-numb">4.2.3</span> <span>Makemake</span> </div> </a> <ul id="toc-Makemake-sublist" class="vector-toc-list"> </ul> </li> </ul> </li> <li id="toc-Kuiper_belt_objects_and_Centaurs" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Kuiper_belt_objects_and_Centaurs"> <div class="vector-toc-text"> <span class="vector-toc-numb">4.3</span> <span>Kuiper belt objects and Centaurs</span> </div> </a> <ul id="toc-Kuiper_belt_objects_and_Centaurs-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Comets_and_asteroids" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Comets_and_asteroids"> <div class="vector-toc-text"> <span class="vector-toc-numb">4.4</span> <span>Comets and asteroids</span> </div> </a> <ul id="toc-Comets_and_asteroids-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-Tholins_beyond_the_Solar_System" class="vector-toc-list-item vector-toc-level-2"> <a class="vector-toc-link" href="#Tholins_beyond_the_Solar_System"> <div class="vector-toc-text"> <span class="vector-toc-numb">4.5</span> <span>Tholins beyond the Solar System</span> </div> </a> <ul id="toc-Tholins_beyond_the_Solar_System-sublist" class="vector-toc-list"> </ul> </li> </ul> </li> <li id="toc-See_also" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#See_also"> <div class="vector-toc-text"> <span class="vector-toc-numb">5</span> <span>See also</span> </div> </a> <ul id="toc-See_also-sublist" class="vector-toc-list"> </ul> </li> <li id="toc-References" class="vector-toc-list-item vector-toc-level-1 vector-toc-list-item-expanded"> <a class="vector-toc-link" href="#References"> <div class="vector-toc-text"> <span class="vector-toc-numb">6</span> <span>References</span> </div> </a> <ul id="toc-References-sublist" class="vector-toc-list"> </ul> </li> </ul> </div> </div> </nav> </div> </div> <div class="mw-content-container"> <main id="content" class="mw-body"> <header class="mw-body-header vector-page-titlebar"> <nav aria-label="Contents" class="vector-toc-landmark"> <div id="vector-page-titlebar-toc" class="vector-dropdown vector-page-titlebar-toc vector-button-flush-left" title="Table of Contents" > <input type="checkbox" id="vector-page-titlebar-toc-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-vector-page-titlebar-toc" class="vector-dropdown-checkbox " aria-label="Toggle the table of contents" > <label id="vector-page-titlebar-toc-label" for="vector-page-titlebar-toc-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button 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Available in 31 languages" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-31" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">31 languages</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-af mw-list-item"><a href="https://af.wikipedia.org/wiki/Tolien" title="Tolien – Afrikaans" lang="af" hreflang="af" data-title="Tolien" data-language-autonym="Afrikaans" data-language-local-name="Afrikaans" class="interlanguage-link-target"><span>Afrikaans</span></a></li><li class="interlanguage-link interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D8%AB%D9%88%D9%84%D9%8A%D9%86" title="ثولين – Arabic" lang="ar" hreflang="ar" data-title="ثولين" data-language-autonym="العربية" data-language-local-name="Arabic" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-bs mw-list-item"><a href="https://bs.wikipedia.org/wiki/Tolini" title="Tolini – Bosnian" lang="bs" hreflang="bs" data-title="Tolini" data-language-autonym="Bosanski" data-language-local-name="Bosnian" class="interlanguage-link-target"><span>Bosanski</span></a></li><li class="interlanguage-link interwiki-ca mw-list-item"><a href="https://ca.wikipedia.org/wiki/Tolins" title="Tolins – Catalan" lang="ca" hreflang="ca" data-title="Tolins" data-language-autonym="Català" data-language-local-name="Catalan" class="interlanguage-link-target"><span>Català</span></a></li><li class="interlanguage-link interwiki-cs mw-list-item"><a href="https://cs.wikipedia.org/wiki/Tholin" title="Tholin – Czech" lang="cs" hreflang="cs" data-title="Tholin" data-language-autonym="Čeština" data-language-local-name="Czech" class="interlanguage-link-target"><span>Čeština</span></a></li><li class="interlanguage-link interwiki-da mw-list-item"><a href="https://da.wikipedia.org/wiki/Tholin" title="Tholin – Danish" lang="da" hreflang="da" data-title="Tholin" data-language-autonym="Dansk" data-language-local-name="Danish" class="interlanguage-link-target"><span>Dansk</span></a></li><li class="interlanguage-link interwiki-de mw-list-item"><a href="https://de.wikipedia.org/wiki/Tholine" title="Tholine – German" lang="de" hreflang="de" data-title="Tholine" data-language-autonym="Deutsch" data-language-local-name="German" class="interlanguage-link-target"><span>Deutsch</span></a></li><li class="interlanguage-link interwiki-es mw-list-item"><a href="https://es.wikipedia.org/wiki/Tolina" title="Tolina – Spanish" lang="es" hreflang="es" data-title="Tolina" data-language-autonym="Español" data-language-local-name="Spanish" class="interlanguage-link-target"><span>Español</span></a></li><li class="interlanguage-link interwiki-eo mw-list-item"><a href="https://eo.wikipedia.org/wiki/Tolino_(kunpolimero)" title="Tolino (kunpolimero) – Esperanto" lang="eo" hreflang="eo" data-title="Tolino (kunpolimero)" data-language-autonym="Esperanto" data-language-local-name="Esperanto" class="interlanguage-link-target"><span>Esperanto</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%D8%AA%D9%88%D9%84%DB%8C%D9%86" title="تولین – Persian" lang="fa" hreflang="fa" data-title="تولین" data-language-autonym="فارسی" data-language-local-name="Persian" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/Tholin" title="Tholin – French" lang="fr" hreflang="fr" data-title="Tholin" data-language-autonym="Français" data-language-local-name="French" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-ko mw-list-item"><a href="https://ko.wikipedia.org/wiki/%ED%86%A8%EB%A6%B0" title="톨린 – Korean" lang="ko" hreflang="ko" data-title="톨린" data-language-autonym="한국어" data-language-local-name="Korean" class="interlanguage-link-target"><span>한국어</span></a></li><li class="interlanguage-link interwiki-hr mw-list-item"><a href="https://hr.wikipedia.org/wiki/Tolini" title="Tolini – Croatian" lang="hr" hreflang="hr" data-title="Tolini" data-language-autonym="Hrvatski" data-language-local-name="Croatian" class="interlanguage-link-target"><span>Hrvatski</span></a></li><li class="interlanguage-link interwiki-id mw-list-item"><a href="https://id.wikipedia.org/wiki/Tholin" title="Tholin – Indonesian" lang="id" hreflang="id" data-title="Tholin" data-language-autonym="Bahasa Indonesia" data-language-local-name="Indonesian" class="interlanguage-link-target"><span>Bahasa Indonesia</span></a></li><li class="interlanguage-link interwiki-it mw-list-item"><a href="https://it.wikipedia.org/wiki/Tolina" title="Tolina – Italian" lang="it" hreflang="it" data-title="Tolina" data-language-autonym="Italiano" data-language-local-name="Italian" class="interlanguage-link-target"><span>Italiano</span></a></li><li class="interlanguage-link interwiki-lb mw-list-item"><a href="https://lb.wikipedia.org/wiki/Tholin" title="Tholin – Luxembourgish" lang="lb" hreflang="lb" data-title="Tholin" data-language-autonym="Lëtzebuergesch" data-language-local-name="Luxembourgish" class="interlanguage-link-target"><span>Lëtzebuergesch</span></a></li><li class="interlanguage-link interwiki-hu mw-list-item"><a href="https://hu.wikipedia.org/wiki/Tholin" title="Tholin – Hungarian" lang="hu" hreflang="hu" data-title="Tholin" data-language-autonym="Magyar" data-language-local-name="Hungarian" class="interlanguage-link-target"><span>Magyar</span></a></li><li class="interlanguage-link interwiki-mn mw-list-item"><a href="https://mn.wikipedia.org/wiki/%D0%A2%D0%BE%D0%BB%D0%B8%D0%BD" title="Толин – Mongolian" lang="mn" hreflang="mn" data-title="Толин" data-language-autonym="Монгол" data-language-local-name="Mongolian" class="interlanguage-link-target"><span>Монгол</span></a></li><li class="interlanguage-link interwiki-nl mw-list-item"><a href="https://nl.wikipedia.org/wiki/Tholine" title="Tholine – Dutch" lang="nl" hreflang="nl" data-title="Tholine" data-language-autonym="Nederlands" data-language-local-name="Dutch" class="interlanguage-link-target"><span>Nederlands</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E3%82%BD%E3%83%AA%E3%83%B3_(%E7%89%A9%E8%B3%AA)" title="ソリン (物質) – Japanese" lang="ja" hreflang="ja" data-title="ソリン (物質)" data-language-autonym="日本語" data-language-local-name="Japanese" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-no mw-list-item"><a href="https://no.wikipedia.org/wiki/Tholin" title="Tholin – Norwegian Bokmål" lang="nb" hreflang="nb" data-title="Tholin" data-language-autonym="Norsk bokmål" data-language-local-name="Norwegian Bokmål" class="interlanguage-link-target"><span>Norsk bokmål</span></a></li><li class="interlanguage-link interwiki-pl mw-list-item"><a href="https://pl.wikipedia.org/wiki/Tholin" title="Tholin – Polish" lang="pl" hreflang="pl" data-title="Tholin" data-language-autonym="Polski" data-language-local-name="Polish" class="interlanguage-link-target"><span>Polski</span></a></li><li class="interlanguage-link interwiki-pt mw-list-item"><a href="https://pt.wikipedia.org/wiki/Tolina" title="Tolina – Portuguese" lang="pt" hreflang="pt" data-title="Tolina" data-language-autonym="Português" data-language-local-name="Portuguese" class="interlanguage-link-target"><span>Português</span></a></li><li class="interlanguage-link interwiki-ru mw-list-item"><a href="https://ru.wikipedia.org/wiki/%D0%A2%D0%BE%D0%BB%D0%B8%D0%BD%D1%8B" title="Толины – Russian" lang="ru" hreflang="ru" data-title="Толины" data-language-autonym="Русский" data-language-local-name="Russian" class="interlanguage-link-target"><span>Русский</span></a></li><li class="interlanguage-link interwiki-fi mw-list-item"><a href="https://fi.wikipedia.org/wiki/Toliinit" title="Toliinit – Finnish" lang="fi" hreflang="fi" data-title="Toliinit" data-language-autonym="Suomi" data-language-local-name="Finnish" class="interlanguage-link-target"><span>Suomi</span></a></li><li class="interlanguage-link interwiki-sv mw-list-item"><a href="https://sv.wikipedia.org/wiki/Tholiner" title="Tholiner – Swedish" lang="sv" hreflang="sv" data-title="Tholiner" data-language-autonym="Svenska" data-language-local-name="Swedish" class="interlanguage-link-target"><span>Svenska</span></a></li><li class="interlanguage-link interwiki-tr mw-list-item"><a href="https://tr.wikipedia.org/wiki/Tholin" title="Tholin – Turkish" lang="tr" hreflang="tr" data-title="Tholin" data-language-autonym="Türkçe" data-language-local-name="Turkish" class="interlanguage-link-target"><span>Türkçe</span></a></li><li class="interlanguage-link interwiki-uk mw-list-item"><a href="https://uk.wikipedia.org/wiki/%D0%A2%D0%BE%D0%BB%D1%96%D0%BD%D0%B8" title="Толіни – Ukrainian" lang="uk" hreflang="uk" data-title="Толіни" data-language-autonym="Українська" data-language-local-name="Ukrainian" class="interlanguage-link-target"><span>Українська</span></a></li><li class="interlanguage-link interwiki-vi mw-list-item"><a href="https://vi.wikipedia.org/wiki/Tholin" title="Tholin – Vietnamese" lang="vi" hreflang="vi" data-title="Tholin" data-language-autonym="Tiếng Việt" data-language-local-name="Vietnamese" class="interlanguage-link-target"><span>Tiếng Việt</span></a></li><li class="interlanguage-link interwiki-wuu mw-list-item"><a href="https://wuu.wikipedia.org/wiki/%E6%89%98%E6%9E%97%EF%BC%88%E5%A4%A9%E6%96%87%E5%AD%A6%EF%BC%89" title="托林(天文学) – Wu" lang="wuu" hreflang="wuu" data-title="托林(天文学)" data-language-autonym="吴语" data-language-local-name="Wu" class="interlanguage-link-target"><span>吴语</span></a></li><li class="interlanguage-link interwiki-zh mw-list-item"><a href="https://zh.wikipedia.org/wiki/%E6%89%98%E6%9E%97_(%E5%A4%A9%E6%96%87%E5%AD%A6)" title="托林 (天文学) – Chinese" lang="zh" hreflang="zh" data-title="托林 (天文学)" data-language-autonym="中文" data-language-local-name="Chinese" class="interlanguage-link-target"><span>中文</span></a></li> </ul> <div class="after-portlet after-portlet-lang"><span class="wb-langlinks-edit wb-langlinks-link"><a href="https://www.wikidata.org/wiki/Special:EntityPage/Q73017#sitelinks-wikipedia" title="Edit interlanguage links" class="wbc-editpage">Edit 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src="//upload.wikimedia.org/wikipedia/commons/thumb/d/d0/Mordor_Macula_Cropped.png/250px-Mordor_Macula_Cropped.png" decoding="async" width="220" height="122" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/d/d0/Mordor_Macula_Cropped.png/330px-Mordor_Macula_Cropped.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/d/d0/Mordor_Macula_Cropped.png/500px-Mordor_Macula_Cropped.png 2x" data-file-width="1107" data-file-height="612" /></a><figcaption><a href="/wiki/Mordor_Macula" title="Mordor Macula">Mordor Macula</a>, a dark region on <a href="/wiki/Charon_(moon)" title="Charon (moon)">Charon</a>'s north pole. The region is stained a dark brown by deposits of tholins</figcaption></figure> <p><b>Tholins</b> (after the Greek <span title="Ancient Greek (to 1453)-language text"><span lang="grc">θολός</span></span> (<i><span title="Ancient Greek (to 1453)-language text"><i lang="grc-Latn">tholós</i></span></i>) "hazy" or "muddy";<sup id="cite_ref-sagan1979_1-0" class="reference"><a href="#cite_note-sagan1979-1"><span class="cite-bracket">&#91;</span>1<span class="cite-bracket">&#93;</span></a></sup> from the <a href="/wiki/Ancient_Greek" title="Ancient Greek">ancient Greek</a> word meaning "sepia ink") are a wide variety of <a href="/wiki/Organic_compounds" class="mw-redirect" title="Organic compounds">organic compounds</a> formed by solar <a href="/wiki/Ultraviolet" title="Ultraviolet">ultraviolet</a> or <a href="/wiki/Cosmic_rays" class="mw-redirect" title="Cosmic rays">cosmic ray</a> irradiation of simple carbon-containing compounds such as <a href="/wiki/Carbon_dioxide" title="Carbon dioxide">carbon dioxide</a> (<span class="chemf nowrap">CO<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">2</sub></span></span></span>), <a href="/wiki/Methane" title="Methane">methane</a> (<span class="chemf nowrap">CH<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">4</sub></span></span></span>) or <a href="/wiki/Ethane" title="Ethane">ethane</a> (<span class="chemf nowrap">C<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">2</sub></span></span>H<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">6</sub></span></span></span>), often in combination with <a href="/wiki/Nitrogen" title="Nitrogen">nitrogen</a> (<span class="chemf nowrap">N<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">2</sub></span></span></span>) or <a href="/wiki/Water" title="Water">water</a> (<span class="chemf nowrap">H<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">2</sub></span></span>O</span>).<sup id="cite_ref-cometary_tholins_2-0" class="reference"><a href="#cite_note-cometary_tholins-2"><span class="cite-bracket">&#91;</span>2<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-Hörst_3-0" class="reference"><a href="#cite_note-Hörst-3"><span class="cite-bracket">&#91;</span>3<span class="cite-bracket">&#93;</span></a></sup> Tholins are disordered polymer-like materials made of repeating chains of linked subunits and complex combinations of functional groups, typically <a href="/wiki/Nitrile" title="Nitrile">nitriles</a> and <a href="/wiki/Hydrocarbon" title="Hydrocarbon">hydrocarbons</a>, and their degraded forms such as <a href="/wiki/Amine" title="Amine">amines</a> and <a href="/wiki/Phenyl_group" title="Phenyl group">phenyls</a>. Tholins do not form naturally on modern-day <a href="/wiki/Earth" title="Earth">Earth</a>, but they are found in great abundance on the surfaces of icy bodies in the outer <a href="/wiki/Solar_System" title="Solar System">Solar System</a>, and as reddish <a href="/wiki/Aerosol" title="Aerosol">aerosols</a> in the atmospheres of outer Solar System planets and moons. </p><p>In the presence of water, tholins could be raw materials for prebiotic chemistry (i.e., the non-living chemistry that forms the basic chemicals of which life is made). Their existence has implications for the <a href="/wiki/Abiogenesis" title="Abiogenesis">origins of life</a> on Earth and possibly on other planets. As particles in an atmosphere, tholins scatter light, and can affect <a href="/wiki/Planetary_habitability" title="Planetary habitability">habitability</a>. </p><p>Tholins may be produced in a laboratory, and are usually studied as a heterogeneous mixture of many chemicals with many different structures and properties. Using techniques like <a href="/wiki/Thermogravimetric_analysis" title="Thermogravimetric analysis">thermogravimetric analysis</a>, <a href="/wiki/Astrochemistry" title="Astrochemistry">astrochemists</a> analyze the composition of these tholin mixtures, and the exact character of the individual chemicals within them.<sup id="cite_ref-Planetary_and_Space_Science_pp._279–288_4-0" class="reference"><a href="#cite_note-Planetary_and_Space_Science_pp._279–288-4"><span class="cite-bracket">&#91;</span>4<span class="cite-bracket">&#93;</span></a></sup> </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="Overview">Overview</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Tholin&amp;action=edit&amp;section=1" title="Edit section: Overview"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <figure typeof="mw:File/Thumb"><a href="/wiki/File:Poly(acrylonitrile).png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/1/11/Poly%28acrylonitrile%29.png/250px-Poly%28acrylonitrile%29.png" decoding="async" width="150" height="185" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/1/11/Poly%28acrylonitrile%29.png 2x" data-file-width="286" data-file-height="352" /></a><figcaption><a href="/wiki/Polyacrylonitrile" title="Polyacrylonitrile">Polyacrylonitrile</a>, one hypothesized polymeric component of tholins, mostly in chemically degraded form as polymers containing <a href="/wiki/Cyanide" title="Cyanide">nitrile</a> and <a href="/wiki/Amine" title="Amine">amino</a> groups. It is used experimentally to create tholin mixtures.<sup id="cite_ref-Planetary_and_Space_Science_pp._279–288_4-1" class="reference"><a href="#cite_note-Planetary_and_Space_Science_pp._279–288-4"><span class="cite-bracket">&#91;</span>4<span class="cite-bracket">&#93;</span></a></sup></figcaption></figure> <p>The term "tholin" was coined by astronomer <a href="/wiki/Carl_Sagan" title="Carl Sagan">Carl Sagan</a> and his colleague <a href="/wiki/Bishun_Khare" title="Bishun Khare">Bishun Khare</a> to describe the difficult-to-characterize substances they obtained in his <a href="/wiki/Miller%E2%80%93Urey_experiment" title="Miller–Urey experiment">Miller–Urey-type experiments</a> on the methane-containing gas mixtures such as those found in <a href="/wiki/Titan_(moon)" title="Titan (moon)">Titan</a>'s atmosphere.<sup id="cite_ref-sagan1979_1-1" class="reference"><a href="#cite_note-sagan1979-1"><span class="cite-bracket">&#91;</span>1<span class="cite-bracket">&#93;</span></a></sup> Their paper proposing the name "tholin" said: </p> <blockquote><p>For the past decade we have been producing in our laboratory a variety of complex organic solids from mixtures of the cosmically abundant gases <span class="chemf nowrap">CH<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">4</sub></span></span></span>, <span class="chemf nowrap">C<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">2</sub></span></span>H<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">6</sub></span></span></span>, <span class="chemf nowrap">NH<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">3</sub></span></span></span>, <span class="chemf nowrap">H<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">2</sub></span></span>O</span>, HCHO, and <span class="chemf nowrap">H<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">2</sub></span></span>S</span>. The product, synthesized by ultraviolet (UV) light or spark discharge, is a brown, sometimes sticky, residue, which has been called, because of its resistance to conventional analytical chemistry, "intractable polymer". [...] We propose, as a model-free descriptive term, 'tholins' (Greek Θολός, muddy; but also Θόλος, vault or dome), although we were tempted by the phrase 'star-tar'.<sup id="cite_ref-Hörst_3-1" class="reference"><a href="#cite_note-Hörst-3"><span class="cite-bracket">&#91;</span>3<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-sagan1979_1-2" class="reference"><a href="#cite_note-sagan1979-1"><span class="cite-bracket">&#91;</span>1<span class="cite-bracket">&#93;</span></a></sup></p></blockquote> <p>Tholins are not one specific compound but rather are descriptive of a spectrum of molecules, including <a href="/wiki/Heteropolymer" class="mw-redirect" title="Heteropolymer">heteropolymers</a>,<sup id="cite_ref-5" class="reference"><a href="#cite_note-5"><span class="cite-bracket">&#91;</span>5<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-6" class="reference"><a href="#cite_note-6"><span class="cite-bracket">&#91;</span>6<span class="cite-bracket">&#93;</span></a></sup> that give a reddish, organic surface covering on certain planetary surfaces. Tholins are disordered polymer-like materials made of repeating chains of linked subunits and complex combinations of functional groups.<sup id="cite_ref-Colors_MU69_7-0" class="reference"><a href="#cite_note-Colors_MU69-7"><span class="cite-bracket">&#91;</span>7<span class="cite-bracket">&#93;</span></a></sup> Sagan and Khare note "The properties of tholins will depend on the energy source used and the initial abundances of precursors, but a general physical and chemical similarity among the various tholins is evident."<sup id="cite_ref-sagan1979_1-3" class="reference"><a href="#cite_note-sagan1979-1"><span class="cite-bracket">&#91;</span>1<span class="cite-bracket">&#93;</span></a></sup> </p><p>Some researchers in the field prefer a narrowed definition of tholins, for example S. Hörst wrote: "Personally, I try to use the word 'tholins' only when describing the laboratory-produced samples, in part because we do not really know yet how similar the material we produce in the lab is to the material found on places like Titan or Triton (or Pluto!)."<sup id="cite_ref-Hörst_3-2" class="reference"><a href="#cite_note-Hörst-3"><span class="cite-bracket">&#91;</span>3<span class="cite-bracket">&#93;</span></a></sup> French researchers also use the term tholins only when describing the laboratory-produced samples as analogues.<sup id="cite_ref-Dubois_2018_8-0" class="reference"><a href="#cite_note-Dubois_2018-8"><span class="cite-bracket">&#91;</span>8<span class="cite-bracket">&#93;</span></a></sup> NASA scientists also prefer the word 'tholin' for the products of laboratory simulations, and use the term 'refractory residues' for actual observations on astronomical bodies.<sup id="cite_ref-Colors_MU69_7-1" class="reference"><a href="#cite_note-Colors_MU69-7"><span class="cite-bracket">&#91;</span>7<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Formation">Formation</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Tholin&amp;action=edit&amp;section=2" title="Edit section: Formation"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <figure class="mw-default-size" typeof="mw:File/Thumb"><a href="/wiki/File:Formation_of_tholins_in_Titan%27s_upper_atmosphere.svg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/1/15/Formation_of_tholins_in_Titan%27s_upper_atmosphere.svg/330px-Formation_of_tholins_in_Titan%27s_upper_atmosphere.svg.png" decoding="async" width="310" height="413" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/1/15/Formation_of_tholins_in_Titan%27s_upper_atmosphere.svg/500px-Formation_of_tholins_in_Titan%27s_upper_atmosphere.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/1/15/Formation_of_tholins_in_Titan%27s_upper_atmosphere.svg/620px-Formation_of_tholins_in_Titan%27s_upper_atmosphere.svg.png 2x" data-file-width="600" data-file-height="800" /></a><figcaption>The formation of tholins in the <a href="/wiki/Atmosphere_of_Titan" title="Atmosphere of Titan">atmosphere of Titan</a></figcaption></figure> <div class="mw-heading mw-heading3"><h3 id="Artificially">Artificially</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Tholin&amp;action=edit&amp;section=3" title="Edit section: Artificially"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>The key elements of tholins are carbon, nitrogen, and hydrogen. Laboratory infrared spectroscopy analysis of experimentally synthesized tholins has confirmed earlier identifications of chemical groups present, including primary <a href="/wiki/Amine" title="Amine">amines</a>, <a href="/wiki/Nitrile" title="Nitrile">nitriles</a>, and <a href="/wiki/Alkyl" class="mw-redirect" title="Alkyl">alkyl</a> portions such as <span class="chemf nowrap">CH<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">2</sub></span></span></span>/<span class="chemf nowrap">CH<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">3</sub></span></span></span> forming complex disordered macromolecular solids. Laboratory tests generated complex solids formed from exposure of <span class="chemf nowrap">N<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">2</sub></span></span></span>:<span class="chemf nowrap">CH<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">4</sub></span></span></span> gaseous mixtures to electrical discharge in cold plasma conditions, reminiscent of the famous <a href="/wiki/Miller%E2%80%93Urey_experiment" title="Miller–Urey experiment">Miller–Urey experiment</a> conducted in 1952.<sup id="cite_ref-9" class="reference"><a href="#cite_note-9"><span class="cite-bracket">&#91;</span>9<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="Naturally">Naturally</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Tholin&amp;action=edit&amp;section=4" title="Edit section: Naturally"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>As illustrated to the right, tholins are thought to form in nature through a chain of chemical reactions known as <a href="/wiki/Pyrolysis" title="Pyrolysis">pyrolysis</a> and <a href="/wiki/Radiolysis" title="Radiolysis">radiolysis</a>. This begins with the <a href="/wiki/Dissociation_(chemistry)" title="Dissociation (chemistry)">dissociation</a> and <a href="/wiki/Ionization" title="Ionization">ionization</a> of molecular <a href="/wiki/Nitrogen" title="Nitrogen">nitrogen</a> (<span class="chemf nowrap">N<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">2</sub></span></span></span>) and <a href="/wiki/Methane" title="Methane">methane</a> (<span class="chemf nowrap">CH<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">4</sub></span></span></span>) by energetic particles and solar radiation. This is followed by the formation of <a href="/wiki/Ethylene" title="Ethylene">ethylene</a>, <a href="/wiki/Ethane" title="Ethane">ethane</a>, <a href="/wiki/Acetylene" title="Acetylene">acetylene</a>, <a href="/wiki/Hydrogen_cyanide" title="Hydrogen cyanide">hydrogen cyanide</a>, and other small simple molecules and small positive ions. Further reactions form <a href="/wiki/Benzene" title="Benzene">benzene</a> and other organic molecules, and their polymerization leads to the formation of an aerosol of heavier molecules, which then condense and precipitate on the planetary surface below.<sup id="cite_ref-Waite2007_10-0" class="reference"><a href="#cite_note-Waite2007-10"><span class="cite-bracket">&#91;</span>10<span class="cite-bracket">&#93;</span></a></sup> </p><p>Tholins formed at low pressure tend to contain nitrogen atoms in the interior of their molecules, while tholins formed at high pressure are more likely to have nitrogen atoms located in terminal positions.<sup id="cite_ref-11" class="reference"><a href="#cite_note-11"><span class="cite-bracket">&#91;</span>11<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-12" class="reference"><a href="#cite_note-12"><span class="cite-bracket">&#91;</span>12<span class="cite-bracket">&#93;</span></a></sup> </p><p>Tholins may be a major constituent of the <a href="/wiki/Interstellar_medium" title="Interstellar medium">interstellar medium</a>.<sup id="cite_ref-sagan1979_1-4" class="reference"><a href="#cite_note-sagan1979-1"><span class="cite-bracket">&#91;</span>1<span class="cite-bracket">&#93;</span></a></sup> On Titan, their chemistry is initiated at high altitudes and participates in the formation of solid organic particles.<sup id="cite_ref-Dubois_2018_8-1" class="reference"><a href="#cite_note-Dubois_2018-8"><span class="cite-bracket">&#91;</span>8<span class="cite-bracket">&#93;</span></a></sup> </p><p>These atmospherically-derived substances are distinct from <i>ice tholin II</i>, which are formed instead by irradiation (<a href="/wiki/Radiolysis" title="Radiolysis">radiolysis</a>) of <a href="/wiki/Clathrate" class="mw-redirect" title="Clathrate">clathrates</a> of <a href="/wiki/Water" title="Water">water</a> and organic compounds such as methane (<span class="chemf nowrap">CH<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">4</sub></span></span></span>) or ethane (<span class="chemf nowrap">C<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">2</sub></span></span>H<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">6</sub></span></span></span>).<sup id="cite_ref-cometary_tholins_2-1" class="reference"><a href="#cite_note-cometary_tholins-2"><span class="cite-bracket">&#91;</span>2<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-Cruikshank_2005_13-0" class="reference"><a href="#cite_note-Cruikshank_2005-13"><span class="cite-bracket">&#91;</span>13<span class="cite-bracket">&#93;</span></a></sup> The radiation-induced synthesis on ice are independent of temperature.<sup id="cite_ref-cometary_tholins_2-2" class="reference"><a href="#cite_note-cometary_tholins-2"><span class="cite-bracket">&#91;</span>2<span class="cite-bracket">&#93;</span></a></sup> </p><p>Models show that, even when far from UV radiation of a star, <a href="/wiki/Cosmic_ray" title="Cosmic ray">cosmic ray</a> doses may be fully sufficient to convert carbon-containing ice grains entirely to complex organics in less than the lifetime of the typical <a href="/wiki/Interstellar_cloud" title="Interstellar cloud">interstellar cloud</a>.<sup id="cite_ref-cometary_tholins_2-3" class="reference"><a href="#cite_note-cometary_tholins-2"><span class="cite-bracket">&#91;</span>2<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Biological_significance">Biological significance</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Tholin&amp;action=edit&amp;section=5" title="Edit section: Biological significance"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Some researchers have speculated that Earth may have been seeded by organic compounds early in its development by tholin-rich comets, providing the raw material necessary for life to develop.<sup id="cite_ref-sagan1979_1-5" class="reference"><a href="#cite_note-sagan1979-1"><span class="cite-bracket">&#91;</span>1<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-cometary_tholins_2-4" class="reference"><a href="#cite_note-cometary_tholins-2"><span class="cite-bracket">&#91;</span>2<span class="cite-bracket">&#93;</span></a></sup> (See <a href="/wiki/Miller%E2%80%93Urey_experiment" title="Miller–Urey experiment">Miller–Urey experiment</a> for discussion.) Tholins do not exist naturally on present-day Earth due to the oxidizing properties of the free oxygen component of its atmosphere ever since the <a href="/wiki/Great_Oxygenation_Event" class="mw-redirect" title="Great Oxygenation Event">Great Oxygenation Event</a> around 2.4 billion years ago.<sup id="cite_ref-prebiotic_chem_2013_14-0" class="reference"><a href="#cite_note-prebiotic_chem_2013-14"><span class="cite-bracket">&#91;</span>14<span class="cite-bracket">&#93;</span></a></sup> </p><p>Laboratory experiments<sup id="cite_ref-Coll_2010_15-0" class="reference"><a href="#cite_note-Coll_2010-15"><span class="cite-bracket">&#91;</span>15<span class="cite-bracket">&#93;</span></a></sup> suggest that tholins near large pools of liquid water that might persist for thousands of years could facilitate the formation of prebiotic chemistry to take place,<sup id="cite_ref-Tholins_Europa_16-0" class="reference"><a href="#cite_note-Tholins_Europa-16"><span class="cite-bracket">&#91;</span>16<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-Hörst_3-3" class="reference"><a href="#cite_note-Hörst-3"><span class="cite-bracket">&#91;</span>3<span class="cite-bracket">&#93;</span></a></sup> and has implications for the <a href="/wiki/Abiogenesis" title="Abiogenesis">origins of life</a> on Earth and possibly other planets.<sup id="cite_ref-Hörst_3-4" class="reference"><a href="#cite_note-Hörst-3"><span class="cite-bracket">&#91;</span>3<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-prebiotic_chem_2013_14-1" class="reference"><a href="#cite_note-prebiotic_chem_2013-14"><span class="cite-bracket">&#91;</span>14<span class="cite-bracket">&#93;</span></a></sup> Also, as particles in the atmosphere of an <a href="/wiki/Exoplanet" title="Exoplanet">exoplanet</a>, tholins affect the light scatter and act as a screen for protecting planetary surfaces from <a href="/wiki/Ultraviolet" title="Ultraviolet">ultraviolet</a> radiation, affecting <a href="/wiki/Planetary_habitability" title="Planetary habitability">habitability</a>.<sup id="cite_ref-Hörst_3-5" class="reference"><a href="#cite_note-Hörst-3"><span class="cite-bracket">&#91;</span>3<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-17" class="reference"><a href="#cite_note-17"><span class="cite-bracket">&#91;</span>17<span class="cite-bracket">&#93;</span></a></sup> Laboratory simulations found derived residues related to <a href="/wiki/Amino_acid" title="Amino acid">amino acids</a> as well as <a href="/wiki/Urea" title="Urea">urea</a>, with important <a href="/wiki/Astrobiology" title="Astrobiology">astrobiological</a> implications.<sup id="cite_ref-prebiotic_chem_2013_14-2" class="reference"><a href="#cite_note-prebiotic_chem_2013-14"><span class="cite-bracket">&#91;</span>14<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-Coll_2010_15-1" class="reference"><a href="#cite_note-Coll_2010-15"><span class="cite-bracket">&#91;</span>15<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-18" class="reference"><a href="#cite_note-18"><span class="cite-bracket">&#91;</span>18<span class="cite-bracket">&#93;</span></a></sup> </p><p>On Earth, a wide variety of <a href="/wiki/Soil_biology" title="Soil biology">soil bacteria</a> are able to use laboratory-produced tholins as their sole source of carbon. Tholins could have been the first microbial food for <a href="/wiki/Heterotroph" title="Heterotroph">heterotrophic</a> microorganisms before <a href="/wiki/Autotroph" title="Autotroph">autotrophy</a> evolved.<sup id="cite_ref-19" class="reference"><a href="#cite_note-19"><span class="cite-bracket">&#91;</span>19<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-20" class="reference"><a href="#cite_note-20"><span class="cite-bracket">&#91;</span>20<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Occurrence">Occurrence</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Tholin&amp;action=edit&amp;section=6" title="Edit section: Occurrence"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <figure class="mw-default-size mw-halign-left" typeof="mw:File/Thumb"><a href="/wiki/File:Huygens_surface_color.jpg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/b/bc/Huygens_surface_color.jpg/250px-Huygens_surface_color.jpg" decoding="async" width="170" height="339" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/b/bc/Huygens_surface_color.jpg/255px-Huygens_surface_color.jpg 1.5x, //upload.wikimedia.org/wikipedia/commons/b/bc/Huygens_surface_color.jpg 2x" data-file-width="316" data-file-height="630" /></a><figcaption>The surface of Titan as viewed from the <a href="/wiki/Huygens_(spacecraft)" title="Huygens (spacecraft)"><i>Huygens</i> lander</a>. Tholins are suspected to be the source of the reddish color of both the surface and the atmospheric haze.</figcaption></figure> <p>Sagan and Khare note the presence of tholins through multiple locations: "as a constituent of the Earth's primitive oceans and therefore relevant to the <a href="/wiki/Origin_of_life" class="mw-redirect" title="Origin of life">origin of life</a>; as a component of red aerosols in the atmospheres of the outer planets and Titan; present in <a href="/wiki/Comet" title="Comet">comets</a>, carbonaceous chondrites asteroids, and pre-planetary solar nebulae; and as a major constituent of the <a href="/wiki/Interstellar_medium" title="Interstellar medium">interstellar medium</a>."<sup id="cite_ref-sagan1979_1-6" class="reference"><a href="#cite_note-sagan1979-1"><span class="cite-bracket">&#91;</span>1<span class="cite-bracket">&#93;</span></a></sup> The surfaces of comets, <a href="/wiki/Centaur_(planetoid)" class="mw-redirect" title="Centaur (planetoid)">centaurs</a>, and many icy moons and <a href="/wiki/Kuiper_belt" title="Kuiper belt">Kuiper-belt</a> objects in the outer Solar System are rich in deposits of tholins.<sup id="cite_ref-21" class="reference"><a href="#cite_note-21"><span class="cite-bracket">&#91;</span>21<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="Moons">Moons</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Tholin&amp;action=edit&amp;section=7" title="Edit section: Moons"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="mw-heading mw-heading4"><h4 id="Titan">Titan</h4><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Tholin&amp;action=edit&amp;section=8" title="Edit section: Titan"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p><a href="/wiki/Titan_(moon)" title="Titan (moon)">Titan</a> tholins are nitrogen-rich<sup id="cite_ref-McDonald1994_22-0" class="reference"><a href="#cite_note-McDonald1994-22"><span class="cite-bracket">&#91;</span>22<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-23" class="reference"><a href="#cite_note-23"><span class="cite-bracket">&#91;</span>23<span class="cite-bracket">&#93;</span></a></sup> organic substances produced by the irradiation of the gaseous mixtures of nitrogen and methane found in the atmosphere and surface of Titan. Titan's atmosphere is about 97% nitrogen, 2.7±0.1% methane and the remaining trace amounts of other gases.<sup id="cite_ref-24" class="reference"><a href="#cite_note-24"><span class="cite-bracket">&#91;</span>24<span class="cite-bracket">&#93;</span></a></sup> In the case of Titan, the haze and orange-red color of its atmosphere are both thought to be caused by the presence of tholins.<sup id="cite_ref-Waite2007_10-1" class="reference"><a href="#cite_note-Waite2007-10"><span class="cite-bracket">&#91;</span>10<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-25" class="reference"><a href="#cite_note-25"><span class="cite-bracket">&#91;</span>25<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading4"><h4 id="Europa">Europa</h4><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Tholin&amp;action=edit&amp;section=9" title="Edit section: Europa"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <figure class="mw-default-size mw-halign-right" typeof="mw:File/Thumb"><a href="/wiki/File:PIA20028_-_Europa%27s_varied_surface_features_(rotated).jpg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/8/8c/PIA20028_-_Europa%27s_varied_surface_features_%28rotated%29.jpg/250px-PIA20028_-_Europa%27s_varied_surface_features_%28rotated%29.jpg" decoding="async" width="220" height="113" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/8/8c/PIA20028_-_Europa%27s_varied_surface_features_%28rotated%29.jpg/330px-PIA20028_-_Europa%27s_varied_surface_features_%28rotated%29.jpg 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/8/8c/PIA20028_-_Europa%27s_varied_surface_features_%28rotated%29.jpg/500px-PIA20028_-_Europa%27s_varied_surface_features_%28rotated%29.jpg 2x" data-file-width="2448" data-file-height="1252" /></a><figcaption>Linear fractures on Europa's surface, likely colored by tholins.</figcaption></figure> <p>Colored regions on Jupiter's satellite <a href="/wiki/Europa_(moon)" title="Europa (moon)">Europa</a> are thought to be tholins.<sup id="cite_ref-Tholins_Europa_16-1" class="reference"><a href="#cite_note-Tholins_Europa-16"><span class="cite-bracket">&#91;</span>16<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-amino_acids_26-0" class="reference"><a href="#cite_note-amino_acids-26"><span class="cite-bracket">&#91;</span>26<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-JPL2015_27-0" class="reference"><a href="#cite_note-JPL2015-27"><span class="cite-bracket">&#91;</span>27<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-28" class="reference"><a href="#cite_note-28"><span class="cite-bracket">&#91;</span>28<span class="cite-bracket">&#93;</span></a></sup> The morphology of Europa's impact craters and ridges is suggestive of fluidized material welling up from the fractures where <a href="/wiki/Pyrolysis" title="Pyrolysis">pyrolysis</a> and <a href="/wiki/Radiolysis" title="Radiolysis">radiolysis</a> take place. In order to generate colored tholins on Europa there must be a source of materials (carbon, nitrogen, and water), and a source of energy to drive the reactions. Impurities in the water ice crust of Europa are presumed both to emerge from the interior as <a href="/wiki/Cryovolcano" title="Cryovolcano">cryovolcanic</a> events that resurface the body, and to accumulate from space as interplanetary dust.<sup id="cite_ref-Tholins_Europa_16-2" class="reference"><a href="#cite_note-Tholins_Europa-16"><span class="cite-bracket">&#91;</span>16<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading4"><h4 id="Rhea">Rhea</h4><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Tholin&amp;action=edit&amp;section=10" title="Edit section: Rhea"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <figure class="mw-default-size" typeof="mw:File/Thumb"><a href="/wiki/File:PIA18438-SaturnMoon-Rhea-20141104-fig2.jpg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/f/f5/PIA18438-SaturnMoon-Rhea-20141104-fig2.jpg/250px-PIA18438-SaturnMoon-Rhea-20141104-fig2.jpg" decoding="async" width="220" height="149" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/f/f5/PIA18438-SaturnMoon-Rhea-20141104-fig2.jpg/330px-PIA18438-SaturnMoon-Rhea-20141104-fig2.jpg 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/f/f5/PIA18438-SaturnMoon-Rhea-20141104-fig2.jpg/500px-PIA18438-SaturnMoon-Rhea-20141104-fig2.jpg 2x" data-file-width="9336" data-file-height="6335" /></a><figcaption>The trailing hemisphere of Saturn's moon <a href="/wiki/Rhea_(moon)" title="Rhea (moon)">Rhea</a> is covered with tholins.</figcaption></figure> <figure class="mw-default-size" typeof="mw:File/Thumb"><a href="/wiki/File:Pluto%E2%80%99s_Heart_-_Like_a_Cosmic_Lava_Lamp.jpg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/2/23/Pluto%E2%80%99s_Heart_-_Like_a_Cosmic_Lava_Lamp.jpg/250px-Pluto%E2%80%99s_Heart_-_Like_a_Cosmic_Lava_Lamp.jpg" decoding="async" width="220" height="237" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/2/23/Pluto%E2%80%99s_Heart_-_Like_a_Cosmic_Lava_Lamp.jpg/330px-Pluto%E2%80%99s_Heart_-_Like_a_Cosmic_Lava_Lamp.jpg 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/2/23/Pluto%E2%80%99s_Heart_-_Like_a_Cosmic_Lava_Lamp.jpg/500px-Pluto%E2%80%99s_Heart_-_Like_a_Cosmic_Lava_Lamp.jpg 2x" data-file-width="2736" data-file-height="2944" /></a><figcaption>Close-up view of Sputnik Planitia on Pluto as viewed by the <i><a href="/wiki/New_Horizons" title="New Horizons">New Horizons</a></i> spacecraft, showing nitrogen ice glaciers and reddish-colored tholins.</figcaption></figure> <p>The extensive dark areas on the trailing hemisphere of Saturn's moon <a href="/wiki/Rhea_(moon)" title="Rhea (moon)">Rhea</a> are thought to be deposited tholins.<sup id="cite_ref-Cruikshank_2005_13-1" class="reference"><a href="#cite_note-Cruikshank_2005-13"><span class="cite-bracket">&#91;</span>13<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading4"><h4 id="Triton">Triton</h4><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Tholin&amp;action=edit&amp;section=11" title="Edit section: Triton"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Neptune's moon <a href="/wiki/Triton_(moon)" title="Triton (moon)">Triton</a> is observed to have the reddish color characteristic of tholins.<sup id="cite_ref-McDonald1994_22-1" class="reference"><a href="#cite_note-McDonald1994-22"><span class="cite-bracket">&#91;</span>22<span class="cite-bracket">&#93;</span></a></sup> Triton's atmosphere is mostly nitrogen, with trace amounts of methane and carbon monoxide.<sup id="cite_ref-29" class="reference"><a href="#cite_note-29"><span class="cite-bracket">&#91;</span>29<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-30" class="reference"><a href="#cite_note-30"><span class="cite-bracket">&#91;</span>30<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="Dwarf_planets">Dwarf planets</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Tholin&amp;action=edit&amp;section=12" title="Edit section: Dwarf planets"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="mw-heading mw-heading4"><h4 id="Pluto">Pluto</h4><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Tholin&amp;action=edit&amp;section=13" title="Edit section: Pluto"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Tholins occur on the <a href="/wiki/Dwarf_planet" title="Dwarf planet">dwarf planet</a> <a href="/wiki/Pluto" title="Pluto">Pluto</a><sup id="cite_ref-31" class="reference"><a href="#cite_note-31"><span class="cite-bracket">&#91;</span>31<span class="cite-bracket">&#93;</span></a></sup> and are responsible for red colors<sup id="cite_ref-32" class="reference"><a href="#cite_note-32"><span class="cite-bracket">&#91;</span>32<span class="cite-bracket">&#93;</span></a></sup> as well as the blue tint of the <a href="/wiki/Atmosphere_of_Pluto" title="Atmosphere of Pluto">atmosphere of Pluto</a>.<sup id="cite_ref-33" class="reference"><a href="#cite_note-33"><span class="cite-bracket">&#91;</span>33<span class="cite-bracket">&#93;</span></a></sup> The reddish-brown cap of the north pole of <a href="/wiki/Charon_(moon)" title="Charon (moon)">Charon</a>,<sup id="cite_ref-Hörst_3-6" class="reference"><a href="#cite_note-Hörst-3"><span class="cite-bracket">&#91;</span>3<span class="cite-bracket">&#93;</span></a></sup> the largest of five <a href="/wiki/Moons_of_Pluto" title="Moons of Pluto">moons of Pluto</a>, is thought to be composed of tholins, produced from methane, nitrogen and related gases released from the atmosphere of Pluto and transferred over about 19,000&#160;km (12,000&#160;mi) distance to the orbiting moon.<sup id="cite_ref-NASA-20150909_34-0" class="reference"><a href="#cite_note-NASA-20150909-34"><span class="cite-bracket">&#91;</span>34<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-NYT-20160914_35-0" class="reference"><a href="#cite_note-NYT-20160914-35"><span class="cite-bracket">&#91;</span>35<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-36" class="reference"><a href="#cite_note-36"><span class="cite-bracket">&#91;</span>36<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading4"><h4 id="Ceres">Ceres</h4><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Tholin&amp;action=edit&amp;section=14" title="Edit section: Ceres"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Tholins were detected on the dwarf planet <a href="/wiki/Ceres_(dwarf_planet)#Carbon" title="Ceres (dwarf planet)">Ceres</a> by the <a href="/wiki/Dawn_(spacecraft)" title="Dawn (spacecraft)"><i>Dawn</i> mission</a>.<sup id="cite_ref-PO-20170216_37-0" class="reference"><a href="#cite_note-PO-20170216-37"><span class="cite-bracket">&#91;</span>37<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-organics_2018_38-0" class="reference"><a href="#cite_note-organics_2018-38"><span class="cite-bracket">&#91;</span>38<span class="cite-bracket">&#93;</span></a></sup> Most of the planet's surface is extremely rich in carbon, with approximately 20% carbon by mass in its near surface.<sup id="cite_ref-PO_12_2018_39-0" class="reference"><a href="#cite_note-PO_12_2018-39"><span class="cite-bracket">&#91;</span>39<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-Nature_12_2018_40-0" class="reference"><a href="#cite_note-Nature_12_2018-40"><span class="cite-bracket">&#91;</span>40<span class="cite-bracket">&#93;</span></a></sup> The carbon content is more than five times higher than in <a href="/wiki/Carbonaceous_chondrite" title="Carbonaceous chondrite">carbonaceous chondrite</a> meteorites analyzed on Earth.<sup id="cite_ref-Nature_12_2018_40-1" class="reference"><a href="#cite_note-Nature_12_2018-40"><span class="cite-bracket">&#91;</span>40<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading4"><h4 id="Makemake">Makemake</h4><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Tholin&amp;action=edit&amp;section=15" title="Edit section: Makemake"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p><a href="/wiki/Makemake" title="Makemake">Makemake</a> exhibits <a href="/wiki/Methane" title="Methane">methane</a>, large amounts of <a href="/wiki/Ethane" title="Ethane">ethane</a> and tholins, as well as smaller amounts of <a href="/wiki/Ethylene" title="Ethylene">ethylene</a>, <a href="/wiki/Acetylene" title="Acetylene">acetylene</a> and high-mass <a href="/wiki/Alkane" title="Alkane">alkanes</a> may be present, most likely created by <a href="/wiki/Photolysis" class="mw-redirect" title="Photolysis">photolysis</a> of methane by solar radiation.<sup id="cite_ref-brown_41-0" class="reference"><a href="#cite_note-brown-41"><span class="cite-bracket">&#91;</span>41<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-brown2015_42-0" class="reference"><a href="#cite_note-brown2015-42"><span class="cite-bracket">&#91;</span>42<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-43" class="reference"><a href="#cite_note-43"><span class="cite-bracket">&#91;</span>43<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="Kuiper_belt_objects_and_Centaurs">Kuiper belt objects and Centaurs</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Tholin&amp;action=edit&amp;section=16" title="Edit section: Kuiper belt objects and Centaurs"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>The reddish color typical of tholins is characteristic of many <a href="/wiki/Trans-Neptunian_object" title="Trans-Neptunian object">Trans-Neptunian objects</a>, including <a href="/wiki/Plutino" title="Plutino">plutinos</a> in the outer Solar System such as <a href="/wiki/28978_Ixion" title="28978 Ixion">28978 Ixion</a>.<sup id="cite_ref-Boehnhardt2004_44-0" class="reference"><a href="#cite_note-Boehnhardt2004-44"><span class="cite-bracket">&#91;</span>44<span class="cite-bracket">&#93;</span></a></sup> Spectral reflectances of <a href="/wiki/Centaur_(minor_planet)" class="mw-redirect" title="Centaur (minor planet)">Centaurs</a> also suggest the presence of tholins on their surfaces.<sup id="cite_ref-45" class="reference"><a href="#cite_note-45"><span class="cite-bracket">&#91;</span>45<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-46" class="reference"><a href="#cite_note-46"><span class="cite-bracket">&#91;</span>46<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-47" class="reference"><a href="#cite_note-47"><span class="cite-bracket">&#91;</span>47<span class="cite-bracket">&#93;</span></a></sup> The <i>New Horizons</i> exploration of the <a href="/wiki/Classical_Kuiper_belt_object" title="Classical Kuiper belt object">classical Kuiper belt object</a> <a href="/wiki/486958_Arrokoth" title="486958 Arrokoth">486958 Arrokoth</a> revealed reddish color at its surface, suggestive of tholins.<sup id="cite_ref-Colors_MU69_7-2" class="reference"><a href="#cite_note-Colors_MU69-7"><span class="cite-bracket">&#91;</span>7<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-48" class="reference"><a href="#cite_note-48"><span class="cite-bracket">&#91;</span>48<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="Comets_and_asteroids">Comets and asteroids</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Tholin&amp;action=edit&amp;section=17" title="Edit section: Comets and asteroids"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Tholins were detected <i>in situ</i> by the <a href="/wiki/Rosetta_(spacecraft)" title="Rosetta (spacecraft)"><i>Rosetta</i></a> mission to comet <a href="/wiki/67P/Churyumov%E2%80%93Gerasimenko" title="67P/Churyumov–Gerasimenko">67P/Churyumov–Gerasimenko</a>.<sup id="cite_ref-49" class="reference"><a href="#cite_note-49"><span class="cite-bracket">&#91;</span>49<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-50" class="reference"><a href="#cite_note-50"><span class="cite-bracket">&#91;</span>50<span class="cite-bracket">&#93;</span></a></sup> Tholins are not typically characteristic of main-belt asteroids, but have been detected on the asteroid <a href="/wiki/24_Themis" title="24 Themis">24 Themis</a>.<sup id="cite_ref-Campins_51-0" class="reference"><a href="#cite_note-Campins-51"><span class="cite-bracket">&#91;</span>51<span class="cite-bracket">&#93;</span></a></sup><sup id="cite_ref-Rivkin2010_52-0" class="reference"><a href="#cite_note-Rivkin2010-52"><span class="cite-bracket">&#91;</span>52<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="Tholins_beyond_the_Solar_System">Tholins beyond the Solar System</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Tholin&amp;action=edit&amp;section=18" title="Edit section: Tholins beyond the Solar System"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Tholins might have also been detected in the stellar system of the young star <a href="/wiki/HR_4796" title="HR 4796">HR 4796A</a> using the <a href="/wiki/NICMOS" class="mw-redirect" title="NICMOS">Near-Infrared Camera and Multi-Object Spectrometer (NICMOS)</a> aboard the Hubble Space Telescope.<sup id="cite_ref-53" class="reference"><a href="#cite_note-53"><span class="cite-bracket">&#91;</span>53<span class="cite-bracket">&#93;</span></a></sup> The <a href="/wiki/HR_4796" title="HR 4796">HR 4796</a> system is approximately 220 light years from Earth.<sup id="cite_ref-54" class="reference"><a href="#cite_note-54"><span class="cite-bracket">&#91;</span>54<span class="cite-bracket">&#93;</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="See_also">See also</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Tholin&amp;action=edit&amp;section=19" title="Edit section: See also"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a href="/wiki/Abiogenesis" title="Abiogenesis">Abiogenesis</a>&#160;– Life arising from non-living matter</li> <li><a href="/wiki/Asphaltene" title="Asphaltene">Asphaltene</a>&#160;– Heavy organic molecular substances that are found in crude oil</li> <li><a href="/wiki/Hemolithin" title="Hemolithin">Hemolithin</a>&#160;– Protein claimed to be of extraterrestrial origin</li> <li><a href="/wiki/Kerogen" title="Kerogen">Kerogen</a>&#160;– Solid organic matter in sedimentary rocks</li> <li><a href="/wiki/PAH_world_hypothesis" title="PAH world hypothesis">PAH world hypothesis</a>&#160;– Hypothesis about the origin of life</li> <li><a href="/wiki/Pseudo-panspermia" title="Pseudo-panspermia">Pseudo-panspermia</a>&#160;– Supported hypothesis for the origin of life</li></ul> <div class="mw-heading mw-heading2"><h2 id="References">References</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Tholin&amp;action=edit&amp;section=20" title="Edit section: References"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <style data-mw-deduplicate="TemplateStyles:r1239543626">.mw-parser-output .reflist{margin-bottom:0.5em;list-style-type:decimal}@media screen{.mw-parser-output .reflist{font-size:90%}}.mw-parser-output .reflist .references{font-size:100%;margin-bottom:0;list-style-type:inherit}.mw-parser-output .reflist-columns-2{column-width:30em}.mw-parser-output .reflist-columns-3{column-width:25em}.mw-parser-output .reflist-columns{margin-top:0.3em}.mw-parser-output .reflist-columns ol{margin-top:0}.mw-parser-output .reflist-columns li{page-break-inside:avoid;break-inside:avoid-column}.mw-parser-output .reflist-upper-alpha{list-style-type:upper-alpha}.mw-parser-output .reflist-upper-roman{list-style-type:upper-roman}.mw-parser-output .reflist-lower-alpha{list-style-type:lower-alpha}.mw-parser-output .reflist-lower-greek{list-style-type:lower-greek}.mw-parser-output .reflist-lower-roman{list-style-type:lower-roman}</style><div class="reflist reflist-columns references-column-width" style="column-width: 36em;"> <ol class="references"> <li id="cite_note-sagan1979-1"><span class="mw-cite-backlink">^ <a href="#cite_ref-sagan1979_1-0"><sup><i><b>a</b></i></sup></a> <a href="#cite_ref-sagan1979_1-1"><sup><i><b>b</b></i></sup></a> <a href="#cite_ref-sagan1979_1-2"><sup><i><b>c</b></i></sup></a> <a href="#cite_ref-sagan1979_1-3"><sup><i><b>d</b></i></sup></a> <a href="#cite_ref-sagan1979_1-4"><sup><i><b>e</b></i></sup></a> <a href="#cite_ref-sagan1979_1-5"><sup><i><b>f</b></i></sup></a> <a href="#cite_ref-sagan1979_1-6"><sup><i><b>g</b></i></sup></a></span> <span class="reference-text"><style data-mw-deduplicate="TemplateStyles:r1238218222">.mw-parser-output cite.citation{font-style:inherit;word-wrap:break-word}.mw-parser-output .citation q{quotes:"\"""\"""'""'"}.mw-parser-output .citation:target{background-color:rgba(0,127,255,0.133)}.mw-parser-output .id-lock-free.id-lock-free a{background:url("//upload.wikimedia.org/wikipedia/commons/6/65/Lock-green.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-limited.id-lock-limited a,.mw-parser-output .id-lock-registration.id-lock-registration a{background:url("//upload.wikimedia.org/wikipedia/commons/d/d6/Lock-gray-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-subscription.id-lock-subscription a{background:url("//upload.wikimedia.org/wikipedia/commons/a/aa/Lock-red-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .cs1-ws-icon a{background:url("//upload.wikimedia.org/wikipedia/commons/4/4c/Wikisource-logo.svg")right 0.1em center/12px no-repeat}body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-free a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-limited a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-registration a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-subscription a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .cs1-ws-icon a{background-size:contain;padding:0 1em 0 0}.mw-parser-output .cs1-code{color:inherit;background:inherit;border:none;padding:inherit}.mw-parser-output .cs1-hidden-error{display:none;color:var(--color-error,#d33)}.mw-parser-output .cs1-visible-error{color:var(--color-error,#d33)}.mw-parser-output .cs1-maint{display:none;color:#085;margin-left:0.3em}.mw-parser-output .cs1-kern-left{padding-left:0.2em}.mw-parser-output .cs1-kern-right{padding-right:0.2em}.mw-parser-output .citation .mw-selflink{font-weight:inherit}@media screen{.mw-parser-output .cs1-format{font-size:95%}html.skin-theme-clientpref-night .mw-parser-output .cs1-maint{color:#18911f}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .cs1-maint{color:#18911f}}</style><cite id="CITEREFSaganKhare1979" class="citation journal cs1"><a href="/wiki/Carl_Sagan" title="Carl Sagan">Sagan, Carl</a>; <a href="/wiki/Bishun_Khare" title="Bishun Khare">Khare, Bishun</a> (11 January 1979). "Tholins: organic chemistry of interstellar grains and gas". <i>Nature</i>. <b>277</b> (5692): <span class="nowrap">102–</span>107. <a href="/wiki/Bibcode_(identifier)" class="mw-redirect" title="Bibcode (identifier)">Bibcode</a>:<a rel="nofollow" class="external text" href="https://ui.adsabs.harvard.edu/abs/1979Natur.277..102S">1979Natur.277..102S</a>. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1038%2F277102a0">10.1038/277102a0</a>. <a href="/wiki/S2CID_(identifier)" class="mw-redirect" title="S2CID (identifier)">S2CID</a>&#160;<a rel="nofollow" class="external text" href="https://api.semanticscholar.org/CorpusID:4261076">4261076</a>.</cite><span title="ctx_ver=Z39.88-2004&amp;rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&amp;rft.genre=article&amp;rft.jtitle=Nature&amp;rft.atitle=Tholins%3A+organic+chemistry+of+interstellar+grains+and+gas&amp;rft.volume=277&amp;rft.issue=5692&amp;rft.pages=%3Cspan+class%3D%22nowrap%22%3E102-%3C%2Fspan%3E107&amp;rft.date=1979-01-11&amp;rft_id=https%3A%2F%2Fapi.semanticscholar.org%2FCorpusID%3A4261076%23id-name%3DS2CID&amp;rft_id=info%3Adoi%2F10.1038%2F277102a0&amp;rft_id=info%3Abibcode%2F1979Natur.277..102S&amp;rft.aulast=Sagan&amp;rft.aufirst=Carl&amp;rft.au=Khare%2C+Bishun&amp;rfr_id=info%3Asid%2Fen.wikipedia.org%3ATholin" class="Z3988"></span></span> </li> <li id="cite_note-cometary_tholins-2"><span class="mw-cite-backlink">^ <a href="#cite_ref-cometary_tholins_2-0"><sup><i><b>a</b></i></sup></a> <a href="#cite_ref-cometary_tholins_2-1"><sup><i><b>b</b></i></sup></a> <a href="#cite_ref-cometary_tholins_2-2"><sup><i><b>c</b></i></sup></a> <a href="#cite_ref-cometary_tholins_2-3"><sup><i><b>d</b></i></sup></a> <a href="#cite_ref-cometary_tholins_2-4"><sup><i><b>e</b></i></sup></a></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222" /><cite id="CITEREFMcDonaldWhitedDeRuiterKhare1996" class="citation journal cs1">McDonald, G.D.; Whited, L.J.; DeRuiter, C.; Khare, B.N.; Patnaik, A.; Sagan, C. 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href="/wiki/Imidogen" title="Imidogen">Imidogen</a></li> <li><a href="/wiki/Iron(II)_oxide" title="Iron(II) oxide">Iron(II) oxide</a></li> <li><a href="/wiki/Magnesium_monohydride" title="Magnesium monohydride">Magnesium monohydride</a></li> <li><a href="/wiki/Methylidyne_radical" title="Methylidyne radical">Methylidyne radical</a></li> <li><a href="/wiki/Nitric_oxide" title="Nitric oxide">Nitric oxide</a></li> <li><a href="/wiki/Nitrogen" title="Nitrogen">Nitrogen</a> (molecular)</li> <li><a href="/wiki/Oxygen" title="Oxygen">Oxygen</a> (molecular)</li> <li><a href="/wiki/Phosphorus_monoxide" title="Phosphorus monoxide">Phosphorus monoxide</a></li> <li><a href="/wiki/Phosphorus_mononitride" title="Phosphorus mononitride">Phosphorus mononitride</a></li> <li><a href="/wiki/Potassium_chloride" title="Potassium chloride">Potassium chloride</a></li> <li><a href="/wiki/Silicon_carbide" title="Silicon carbide">Silicon carbide</a></li> <li><a href="/wiki/Silicon_monoxide" title="Silicon monoxide">Silicon monoxide</a></li> <li><a href="/wiki/Silicon_monosulfide" title="Silicon monosulfide">Silicon monosulfide</a></li> <li><a href="/wiki/Sodium_chloride" title="Sodium chloride">Sodium chloride</a></li> <li><a href="/wiki/Sodium_iodide" title="Sodium iodide">Sodium iodide</a></li> <li><a href="/wiki/Sulfanyl" title="Sulfanyl">Sulfanyl</a></li> <li><a href="/wiki/Sulfur_mononitride" title="Sulfur mononitride">Sulfur mononitride</a></li> <li><a href="/wiki/Sulfur_monoxide" title="Sulfur monoxide">Sulfur monoxide</a></li> <li><a href="/wiki/Titanium(II)_oxide" title="Titanium(II) oxide">Titanium(II) oxide</a></li></ul> </div></td><td class="noviewer navbox-image" rowspan="9" style="width:1px;padding:0 0 0 2px"><div><span typeof="mw:File"><a href="/wiki/Nitrous_oxide" title="Nitrous oxide"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/9/93/Nitrous-oxide-3D-balls.png/60px-Nitrous-oxide-3D-balls.png" decoding="async" width="60" height="24" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/9/93/Nitrous-oxide-3D-balls.png/90px-Nitrous-oxide-3D-balls.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/9/93/Nitrous-oxide-3D-balls.png/120px-Nitrous-oxide-3D-balls.png 2x" data-file-width="1100" data-file-height="441" /></a></span> <br /><br /><br /><br /> <span typeof="mw:File"><a href="/wiki/Ethanol" title="Ethanol"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/b/b0/Ethanol-3D-balls.png/60px-Ethanol-3D-balls.png" decoding="async" width="60" height="41" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/b/b0/Ethanol-3D-balls.png/120px-Ethanol-3D-balls.png 1.5x" data-file-width="1100" data-file-height="754" /></a></span> <br /><br /><br /><br /> <span typeof="mw:File"><a href="/wiki/Buckminsterfullerene" title="Buckminsterfullerene"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/0/0f/Buckminsterfullerene-perspective-3D-balls.png/60px-Buckminsterfullerene-perspective-3D-balls.png" decoding="async" width="60" height="63" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/0/0f/Buckminsterfullerene-perspective-3D-balls.png/120px-Buckminsterfullerene-perspective-3D-balls.png 1.5x" data-file-width="1056" data-file-height="1100" /></a></span></div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Triatomic_molecule" title="Triatomic molecule">Triatomic</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Aluminium(I)_hydroxide" class="mw-redirect" title="Aluminium(I) hydroxide">Aluminium(I) hydroxide</a></li> <li><a href="/w/index.php?title=Aluminium_isocyanide&amp;action=edit&amp;redlink=1" class="new" title="Aluminium isocyanide (page does not exist)">Aluminium isocyanide</a></li> <li><a href="/wiki/Amino_radical" title="Amino radical">Amino radical</a></li> <li><a href="/wiki/Carbon_dioxide" title="Carbon dioxide">Carbon dioxide</a></li> <li><a href="/wiki/Carbonyl_sulfide" title="Carbonyl sulfide">Carbonyl sulfide</a></li> <li><a href="/w/index.php?title=CCP_radical&amp;action=edit&amp;redlink=1" class="new" title="CCP radical (page does not exist)">CCP radical</a></li> <li><a href="/wiki/Halonium_ion" title="Halonium ion">Chloronium</a></li> <li><a href="/wiki/Diazenylium" title="Diazenylium">Diazenylium</a></li> <li><a href="/wiki/Dicarbon_monoxide" title="Dicarbon monoxide">Dicarbon monoxide</a></li> <li><a href="/w/index.php?title=Disilicon_carbide&amp;action=edit&amp;redlink=1" class="new" title="Disilicon carbide (page does not exist)">Disilicon carbide</a></li> <li><a href="/wiki/Ethynyl_radical" title="Ethynyl radical">Ethynyl radical</a></li> <li><a href="/w/index.php?title=Formyl_radical&amp;action=edit&amp;redlink=1" class="new" title="Formyl radical (page does not exist)">Formyl radical</a></li> <li><a href="/wiki/Hydrogen_cyanide" title="Hydrogen cyanide">Hydrogen cyanide</a> (HCN)</li> <li><a href="/wiki/Hydrogen_isocyanide" title="Hydrogen isocyanide">Hydrogen isocyanide</a> (HNC)</li> <li><a href="/wiki/Hydrogen_sulfide" title="Hydrogen sulfide">Hydrogen sulfide</a></li> <li><a href="/wiki/Hydroperoxyl" title="Hydroperoxyl">Hydroperoxyl</a></li> <li><a href="/wiki/Iron(II)_cyanide" title="Iron(II) cyanide">Iron cyanide</a></li> <li><a href="/w/index.php?title=Isoformyl&amp;action=edit&amp;redlink=1" class="new" title="Isoformyl (page does not exist)">Isoformyl</a></li> <li><a href="/wiki/Magnesium_cyanide" title="Magnesium cyanide">Magnesium cyanide</a></li> <li><a href="/w/index.php?title=Magnesium_isocyanide&amp;action=edit&amp;redlink=1" class="new" title="Magnesium isocyanide (page does not exist)">Magnesium isocyanide</a></li> <li><a href="/wiki/Methylene_(compound)" title="Methylene (compound)">Methylene</a></li> <li><a href="/wiki/Methylidynephosphane" title="Methylidynephosphane">Methylidynephosphane</a></li> <li><a href="/wiki/Diazenylium" title="Diazenylium">N<sub>2</sub>H<sup>+</sup></a></li> <li><a href="/wiki/Nitrous_oxide" title="Nitrous oxide">Nitrous oxide</a></li> <li><a href="/wiki/Nitroxyl" title="Nitroxyl">Nitroxyl</a></li> <li><a href="/wiki/Ozone" title="Ozone">Ozone</a></li> <li><a href="/wiki/Potassium_cyanide" title="Potassium cyanide">Potassium cyanide</a></li> <li><a href="/wiki/Sodium_cyanide" title="Sodium cyanide">Sodium cyanide</a></li> <li><a href="/wiki/Sodium_hydroxide" title="Sodium hydroxide">Sodium hydroxide</a></li> <li><a href="/w/index.php?title=Silicon_carbonitride&amp;action=edit&amp;redlink=1" class="new" title="Silicon carbonitride (page does not exist)">Silicon carbonitride</a></li> <li><a href="/w/index.php?title=C-Silicon_dicarbide&amp;action=edit&amp;redlink=1" class="new" title="C-Silicon dicarbide (page does not exist)">c-Silicon dicarbide</a></li> <li><a href="/w/index.php?title=SiNC&amp;action=edit&amp;redlink=1" class="new" title="SiNC (page does not exist)">SiNC</a></li> <li><a href="/wiki/Sulfur_dioxide" title="Sulfur dioxide">Sulfur dioxide</a></li> <li><a href="/w/index.php?title=Thioformyl&amp;action=edit&amp;redlink=1" class="new" title="Thioformyl (page does not exist)">Thioformyl</a></li> <li><a href="/wiki/Thioxoethenylidene" title="Thioxoethenylidene">Thioxoethenylidene</a></li> <li><a href="/wiki/Titanium_dioxide" title="Titanium dioxide">Titanium dioxide</a></li> <li><a href="/wiki/Tricarbon" title="Tricarbon">Tricarbon</a></li> <li><a href="/wiki/Trihydrogen_cation" title="Trihydrogen cation">Trihydrogen cation</a></li> <li><a href="/wiki/Water" title="Water">Water</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/List_of_interstellar_and_circumstellar_molecules#Molecules" title="List of interstellar and circumstellar molecules">Four<br />atoms</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Acetylene" title="Acetylene">Acetylene</a></li> <li><a href="/wiki/Ammonia" title="Ammonia">Ammonia</a></li> <li><a href="/wiki/Polyyne" title="Polyyne">Cyanoethynyl</a></li> <li><a href="/wiki/Interstellar_formaldehyde" title="Interstellar formaldehyde">Formaldehyde</a></li> <li><a href="/wiki/Fulminic_acid" title="Fulminic acid">Fulminic acid</a></li> <li><a href="/w/index.php?title=HCCN&amp;action=edit&amp;redlink=1" class="new" title="HCCN (page does not exist)">HCCN</a></li> <li><a href="/wiki/Hydrogen_peroxide" title="Hydrogen peroxide">Hydrogen peroxide</a></li> <li><a href="/w/index.php?title=Hydromagnesium_isocyanide&amp;action=edit&amp;redlink=1" class="new" title="Hydromagnesium isocyanide (page does not exist)">Hydromagnesium isocyanide</a></li> <li><a href="/wiki/Isocyanic_acid" title="Isocyanic acid">Isocyanic acid</a></li> <li><a href="/wiki/Thiocyanic_acid" title="Thiocyanic acid">Isothiocyanic acid</a></li> <li><a href="/w/index.php?title=Ketenyl&amp;action=edit&amp;redlink=1" class="new" title="Ketenyl (page does not exist)">Ketenyl</a></li> <li><a href="/wiki/Methyl_cation" class="mw-redirect" title="Methyl cation">Methyl cation</a></li> <li><a href="/wiki/Methyl_radical" title="Methyl radical">Methyl radical</a></li> <li><a href="/w/index.php?title=Methylene_amidogen&amp;action=edit&amp;redlink=1" class="new" title="Methylene amidogen (page does not exist)">Methylene amidogen</a></li> <li><a href="/wiki/Propynylidyne" title="Propynylidyne">Propynylidyne</a></li> <li><a href="/w/index.php?title=Protonated_carbon_dioxide&amp;action=edit&amp;redlink=1" class="new" title="Protonated carbon dioxide (page does not exist)">Protonated carbon dioxide</a></li> <li><a href="/wiki/Protonated_hydrogen_cyanide" title="Protonated hydrogen cyanide">Protonated hydrogen cyanide</a></li> <li><a href="/w/index.php?title=Silicon_tricarbide&amp;action=edit&amp;redlink=1" class="new" title="Silicon tricarbide (page does not exist)">Silicon tricarbide</a></li> <li><a href="/wiki/Thiocyanic_acid" title="Thiocyanic acid">Thiocyanic acid</a></li> <li><a href="/wiki/Thioformaldehyde" title="Thioformaldehyde">Thioformaldehyde</a></li> <li><a href="/wiki/Tricarbon_monosulfide" title="Tricarbon monosulfide">Tricarbon monosulfide</a></li> <li><a href="/wiki/Tricarbon_monoxide" title="Tricarbon monoxide">Tricarbon monoxide</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/List_of_interstellar_and_circumstellar_molecules#Molecules" title="List of interstellar and circumstellar molecules">Five<br />atoms</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Ammonium" title="Ammonium">Ammonium</a> ion</li> <li><a href="/wiki/Polyyne" title="Polyyne">Butadiynyl</a></li> <li><a href="/wiki/Carbodiimide" title="Carbodiimide">Carbodiimide</a></li> <li><a href="/wiki/Cyanamide" title="Cyanamide">Cyanamide</a></li> <li><a href="/wiki/Cyanoacetylene" title="Cyanoacetylene">Cyanoacetylene</a></li> <li><a href="/w/index.php?title=Cyanoformaldehyde&amp;action=edit&amp;redlink=1" class="new" title="Cyanoformaldehyde (page does not exist)">Cyanoformaldehyde</a></li> <li><a href="/wiki/Cyanomethyl" title="Cyanomethyl">Cyanomethyl</a></li> <li><a href="/wiki/Cyclopropenylidene" title="Cyclopropenylidene">Cyclopropenylidene</a></li> <li><a href="/wiki/Formic_acid" title="Formic acid">Formic acid</a></li> <li><a href="/w/index.php?title=Isocyanoacetylene&amp;action=edit&amp;redlink=1" class="new" title="Isocyanoacetylene (page does not exist)">Isocyanoacetylene</a></li> <li><a href="/wiki/Ketene" title="Ketene">Ketene</a></li> <li><a href="/wiki/Methane" title="Methane">Methane</a></li> <li><a href="/wiki/Methoxy" class="mw-redirect" title="Methoxy">Methoxy radical</a></li> <li><a href="/w/index.php?title=Methylenimine&amp;action=edit&amp;redlink=1" class="new" title="Methylenimine (page does not exist)">Methylenimine</a></li> <li><a href="/w/index.php?title=Propadienylidene&amp;action=edit&amp;redlink=1" class="new" title="Propadienylidene (page does not exist)">Propadienylidene</a></li> <li><a href="/w/index.php?title=Protonated_formaldehyde&amp;action=edit&amp;redlink=1" class="new" title="Protonated formaldehyde (page does not exist)">Protonated formaldehyde</a></li> <li><a href="/wiki/Silane" title="Silane">Silane</a></li> <li><a href="/w/index.php?title=Silicon-carbide_cluster&amp;action=edit&amp;redlink=1" class="new" title="Silicon-carbide cluster (page does not exist)">Silicon-carbide cluster</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/List_of_interstellar_and_circumstellar_molecules#Molecules" title="List of interstellar and circumstellar molecules">Six<br />atoms</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Acetonitrile" title="Acetonitrile">Acetonitrile</a></li> <li><a href="/w/index.php?title=Cyanobutadiynyl_radical&amp;action=edit&amp;redlink=1" class="new" title="Cyanobutadiynyl radical (page does not exist)">Cyanobutadiynyl radical</a></li> <li><a href="/wiki/Cyclopropenone" title="Cyclopropenone">Cyclopropenone</a></li> <li><a href="/wiki/Diacetylene" title="Diacetylene">Diacetylene</a></li> <li><a href="/w/index.php?title=E-Cyanomethanimine&amp;action=edit&amp;redlink=1" class="new" title="E-Cyanomethanimine (page does not exist)">E-Cyanomethanimine</a></li> <li><a href="/wiki/Ethylene" title="Ethylene">Ethylene</a></li> <li><a href="/wiki/Formamide" title="Formamide">Formamide</a></li> <li><a href="/w/index.php?title=HC4N&amp;action=edit&amp;redlink=1" class="new" title="HC4N (page does not exist)">HC<sub>4</sub>N</a></li> <li><a href="/wiki/Ketenimine" class="mw-redirect" title="Ketenimine">Ketenimine</a></li> <li><a href="/wiki/Methanethiol" title="Methanethiol">Methanethiol</a></li> <li><a href="/wiki/Methanol" title="Methanol">Methanol</a></li> <li><a href="/wiki/Methyl_isocyanide" title="Methyl isocyanide">Methyl isocyanide</a></li> <li><a href="/wiki/Polyyne" title="Polyyne">Pentynylidyne</a></li> <li><a href="/wiki/Propynal" class="mw-redirect" title="Propynal">Propynal</a></li> <li><a href="/w/index.php?title=Protonated_cyanoacetylene&amp;action=edit&amp;redlink=1" class="new" title="Protonated cyanoacetylene (page does not exist)">Protonated cyanoacetylene</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/List_of_interstellar_and_circumstellar_molecules#Molecules" title="List of interstellar and circumstellar molecules">Seven<br />atoms</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Acetaldehyde" title="Acetaldehyde">Acetaldehyde</a></li> <li><a href="/wiki/Acrylonitrile" title="Acrylonitrile">Acrylonitrile</a> <ul><li><a href="/wiki/Vinyl_cyanide" class="mw-redirect" title="Vinyl cyanide">Vinyl cyanide</a></li></ul></li> <li><a href="/wiki/Cyanopolyyne" title="Cyanopolyyne">Cyanodiacetylene</a></li> <li><a href="/wiki/Ethylene_oxide" title="Ethylene oxide">Ethylene oxide</a></li> <li><a href="/wiki/Glycolonitrile" title="Glycolonitrile">Glycolonitrile</a></li> <li><a href="/wiki/Hexatriynyl_radical" title="Hexatriynyl radical">Hexatriynyl radical</a></li> <li><a href="/wiki/Methyl_isocyanate" title="Methyl isocyanate">Methyl isocyanate</a></li> <li><a href="/wiki/Methylamine" title="Methylamine">Methylamine</a></li> <li><a href="/wiki/Propyne" title="Propyne">Propyne</a></li> <li><a href="/wiki/Vinyl_alcohol" title="Vinyl alcohol">Vinyl alcohol</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/List_of_interstellar_and_circumstellar_molecules#Molecules" title="List of interstellar and circumstellar molecules">Eight<br />atoms</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Acetic_acid" title="Acetic acid">Acetic acid</a></li> <li><a href="/wiki/Acrolein" title="Acrolein">Acrolein</a></li> <li><a href="/wiki/Aminoacetonitrile" title="Aminoacetonitrile">Aminoacetonitrile</a></li> <li><a href="/w/index.php?title=Cyanoallene&amp;action=edit&amp;redlink=1" class="new" title="Cyanoallene (page does not exist)">Cyanoallene</a></li> <li><a href="/wiki/Ethanimine" title="Ethanimine">Ethanimine</a></li> <li><a href="/wiki/Glycolaldehyde" title="Glycolaldehyde">Glycolaldehyde</a></li> <li><a href="/wiki/Polyyne" title="Polyyne">Hexapentaenylidene</a></li> <li><a href="/wiki/Methyl_formate" title="Methyl formate">Methyl formate</a></li> <li><a href="/wiki/Polyyne" title="Polyyne">Methylcyanoacetylene</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/List_of_interstellar_and_circumstellar_molecules#Molecules" title="List of interstellar and circumstellar molecules">Nine<br />atoms</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Acetamide" title="Acetamide">Acetamide</a></li> <li><a href="/wiki/Cyanopolyyne" title="Cyanopolyyne">Cyanohexatriyne</a></li> <li><a href="/wiki/Dimethyl_ether" title="Dimethyl ether">Dimethyl ether</a></li> <li><a href="/wiki/Ethanethiol" title="Ethanethiol">Ethanethiol</a></li> <li><a href="/wiki/Ethanol" title="Ethanol">Ethanol</a></li> <li><a href="/wiki/Polyyne" title="Polyyne">Methyldiacetylene</a></li> <li><a href="/wiki/N-Methylformamide" title="N-Methylformamide">N-Methylformamide</a></li> <li><a href="/wiki/Octatetraynyl_radical" title="Octatetraynyl radical">Octatetraynyl radical</a></li> <li><a href="/wiki/Propene" class="mw-redirect" title="Propene">Propene</a></li> <li><a href="/wiki/Propionitrile" title="Propionitrile">Propionitrile</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/List_of_interstellar_and_circumstellar_molecules#Molecules" title="List of interstellar and circumstellar molecules">Ten<br />atoms<br />or more</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Acetone" title="Acetone">Acetone</a></li> <li><a href="/wiki/Benzene" title="Benzene">Benzene</a></li> <li><a href="/wiki/Benzonitrile" title="Benzonitrile">Benzonitrile</a></li> <li><a href="/wiki/Buckminsterfullerene" title="Buckminsterfullerene">Buckminsterfullerene</a> (C<sub>60</sub>, C<sub>60</sub><sup>+</sup>, fullerene, buckyball)</li> <li><a href="/wiki/Butyronitrile" title="Butyronitrile">Butyronitrile</a></li> <li><a href="/wiki/C70_fullerene" title="C70 fullerene">C<sub>70</sub> fullerene</a></li> <li><a href="/wiki/Cyanopolyyne" title="Cyanopolyyne">Cyanodecapentayne</a></li> <li><a href="/wiki/Ethyl_formate" title="Ethyl formate">Ethyl formate</a></li> <li><a href="/wiki/Ethylene_glycol" title="Ethylene glycol">Ethylene glycol</a></li> <li><a href="/w/index.php?title=Heptatrienyl_radical&amp;action=edit&amp;redlink=1" class="new" title="Heptatrienyl radical (page does not exist)">Heptatrienyl radical</a></li> <li><a href="/wiki/Methyl_acetate" title="Methyl acetate">Methyl acetate</a></li> <li><a href="/wiki/Cyanopolyyne" title="Cyanopolyyne">Methyl-cyano-diacetylene</a></li> <li><a href="/wiki/Polyyne" title="Polyyne">Methyltriacetylene</a></li> <li><a href="/wiki/Propionaldehyde" title="Propionaldehyde">Propionaldehyde</a></li> <li><a href="/wiki/Pyrimidine" title="Pyrimidine">Pyrimidine</a></li></ul> </div></td></tr></tbody></table><div></div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Deuterium" title="Deuterium">Deuterated</a><br />molecules</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Ammonia" title="Ammonia">Ammonia</a></li> <li><a href="/wiki/Ammonium" title="Ammonium">Ammonium</a> ion</li> <li><a href="/wiki/Formaldehyde" title="Formaldehyde">Formaldehyde</a></li> <li><a href="/wiki/Interstellar_formaldehyde#Interstellar_reactions" title="Interstellar formaldehyde">Formyl radical</a></li> <li><a href="/wiki/Heavy_water" title="Heavy water">Heavy water</a></li> <li><a href="/wiki/Hydrogen_cyanide" title="Hydrogen cyanide">Hydrogen cyanide</a></li> <li><a href="/wiki/Hydrogen_deuteride" title="Hydrogen deuteride">Hydrogen deuteride</a></li> <li><a href="/wiki/Hydrogen_isocyanide" title="Hydrogen isocyanide">Hydrogen isocyanide</a></li> <li><a href="/wiki/Diazenylium" title="Diazenylium">N<sub>2</sub>D<sup>+</sup></a></li> <li><a href="/wiki/Propyne" title="Propyne">Propyne</a></li> <li><a href="/wiki/Trihydrogen_cation" title="Trihydrogen cation">Trihydrogen cation</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/List_of_interstellar_and_circumstellar_molecules#Molecules" title="List of interstellar and circumstellar molecules">Unconfirmed</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Anthracene" title="Anthracene">Anthracene</a></li> <li><a href="/wiki/Dihydroxyacetone" title="Dihydroxyacetone">Dihydroxyacetone</a></li> <li><a href="/wiki/Glycine" title="Glycine">Glycine</a></li> <li><a href="/wiki/Graphene" title="Graphene">Graphene</a></li> <li><a href="/w/index.php?title=H2NCO%2B&amp;action=edit&amp;redlink=1" class="new" title="H2NCO+ (page does not exist)">H<sub>2</sub>NCO<sup>+</sup></a></li> <li><a href="/wiki/Hemolithin" title="Hemolithin">Hemolithin</a></li> <li><a href="/wiki/Carbon" title="Carbon">Linear C<sub>5</sub></a></li> <li><a href="/wiki/Methoxyethane" title="Methoxyethane">Methoxyethane</a></li> <li><a href="/wiki/Naphthalene" title="Naphthalene">Naphthalene cation</a></li> <li><a href="/wiki/Phosphine" title="Phosphine">Phosphine</a></li> <li><a href="/wiki/Pyrene" title="Pyrene">Pyrene</a></li> <li><a href="/wiki/Silylidyne" title="Silylidyne">Silylidyne</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><a href="/wiki/List_of_interstellar_and_circumstellar_molecules#See_also" title="List of interstellar and circumstellar molecules">Related</a></th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Abiogenesis" title="Abiogenesis">Abiogenesis</a></li> <li><a href="/wiki/Astrobiology" title="Astrobiology">Astrobiology</a></li> <li><a href="/wiki/Astrochemistry" title="Astrochemistry">Astrochemistry</a></li> <li><a href="/wiki/Atomic_and_molecular_astrophysics" title="Atomic and molecular astrophysics">Atomic and molecular astrophysics</a></li> <li><a href="/wiki/Chemical_formula" title="Chemical formula">Chemical formula</a></li> <li><a href="/wiki/Circumstellar_dust" title="Circumstellar dust">Circumstellar dust</a></li> <li><a href="/wiki/Circumstellar_envelope" title="Circumstellar envelope">Circumstellar envelope</a></li> <li><a href="/wiki/Cosmic_dust" title="Cosmic dust">Cosmic dust</a></li> <li><a href="/wiki/Cosmic_ray" title="Cosmic ray">Cosmic ray</a></li> <li><a href="/wiki/Cosmochemistry" title="Cosmochemistry">Cosmochemistry</a></li> <li><a href="/wiki/Diffuse_interstellar_band" class="mw-redirect" title="Diffuse interstellar band">Diffuse interstellar band</a></li> <li><a href="/wiki/Earliest_known_life_forms" title="Earliest known life forms">Earliest known life forms</a></li> <li><a href="/wiki/Extraterrestrial_life" title="Extraterrestrial life">Extraterrestrial life</a></li> <li><a href="/wiki/Extraterrestrial_liquid_water" title="Extraterrestrial liquid water">Extraterrestrial liquid water</a></li> <li><a href="/wiki/Forbidden_mechanism" title="Forbidden mechanism">Forbidden mechanism</a></li> <li><a href="/wiki/Homochirality" title="Homochirality">Homochirality</a></li> <li><a href="/wiki/Intergalactic_dust" title="Intergalactic dust">Intergalactic dust</a></li> <li><a href="/wiki/Interplanetary_medium" title="Interplanetary medium">Interplanetary medium</a></li> <li><a href="/wiki/Interstellar_medium" title="Interstellar medium">Interstellar medium</a></li> <li><a href="/wiki/Iron%E2%80%93sulfur_world_theory" class="mw-redirect" title="Iron–sulfur world theory">Iron–sulfur world theory</a></li> <li><a href="/wiki/Kerogen" title="Kerogen">Kerogen</a></li> <li><a href="/wiki/Molecules_in_stars" title="Molecules in stars">Molecules in stars</a></li> <li><a href="/wiki/Nexus_for_Exoplanet_System_Science" title="Nexus for Exoplanet System Science">Nexus for Exoplanet System Science</a></li> <li><a href="/wiki/Organic_compound" title="Organic compound">Organic compound</a></li> <li><a href="/wiki/Outer_space" title="Outer space">Outer space</a></li> <li><a href="/wiki/PAH_world_hypothesis" title="PAH world hypothesis">PAH world hypothesis</a></li> <li><a href="/wiki/Photodissociation_region" title="Photodissociation region">Photodissociation region</a></li> <li><a href="/wiki/Polycyclic_aromatic_hydrocarbon" title="Polycyclic aromatic hydrocarbon">Polycyclic aromatic hydrocarbon</a> (PAH)</li> <li><a href="/wiki/Pseudo-panspermia" title="Pseudo-panspermia">Pseudo-panspermia</a></li> <li><a href="/wiki/RNA_world_hypothesis" class="mw-redirect" title="RNA world hypothesis">RNA world hypothesis</a></li> <li><a href="/wiki/Spectroscopy" title="Spectroscopy">Spectroscopy</a></li> <li><a class="mw-selflink selflink">Tholin</a></li></ul> </div></td></tr><tr><td class="navbox-abovebelow" colspan="2" style="font-weight: bold;"><div> <ul><li><b><span class="noviewer" typeof="mw:File"><span title="Category"><img alt="" src="//upload.wikimedia.org/wikipedia/en/thumb/9/96/Symbol_category_class.svg/20px-Symbol_category_class.svg.png" decoding="async" width="16" height="16" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/9/96/Symbol_category_class.svg/40px-Symbol_category_class.svg.png 1.5x" data-file-width="180" data-file-height="185" /></span></span> <a href="/wiki/Category:Astrochemistry" title="Category:Astrochemistry">Category:Astrochemistry</a></b></li> <li><span class="nowrap"><span class="noviewer" typeof="mw:File"><span><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/5/5c/Earth-moon.jpg/20px-Earth-moon.jpg" decoding="async" width="17" height="14" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/5/5c/Earth-moon.jpg/40px-Earth-moon.jpg 1.5x" data-file-width="3000" data-file-height="2400" /></span></span> </span><a href="/wiki/Portal:Outer_space" title="Portal:Outer space">Outer space&#32;portal</a></li> <li><span class="nowrap"><span class="noviewer" typeof="mw:File"><span><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/0/00/Crab_Nebula.jpg/20px-Crab_Nebula.jpg" decoding="async" width="15" height="15" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/0/00/Crab_Nebula.jpg/40px-Crab_Nebula.jpg 1.5x" data-file-width="3864" data-file-height="3864" /></span></span> </span><a href="/wiki/Portal:Astronomy" title="Portal:Astronomy">Astronomy&#32;portal</a></li> <li><span class="nowrap"><span class="noviewer" typeof="mw:File"><span><img alt="" src="//upload.wikimedia.org/wikipedia/commons/thumb/e/ed/Papapishu-Lab-icon-6.svg/15px-Papapishu-Lab-icon-6.svg.png" decoding="async" width="15" height="15" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/e/ed/Papapishu-Lab-icon-6.svg/23px-Papapishu-Lab-icon-6.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/e/ed/Papapishu-Lab-icon-6.svg/30px-Papapishu-Lab-icon-6.svg.png 2x" data-file-width="512" data-file-height="512" /></span></span> </span><a href="/wiki/Portal:Chemistry" title="Portal:Chemistry">Chemistry&#32;portal</a></li></ul> </div></td></tr></tbody></table></div> <div class="navbox-styles"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1129693374" /><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1236075235" /></div><div role="navigation" class="navbox" aria-labelledby="Astrobiology384" style="padding:3px"><table class="nowraplinks hlist mw-collapsible autocollapse navbox-inner" style="border-spacing:0;background:transparent;color:inherit"><tbody><tr><th scope="col" class="navbox-title" colspan="2" style="text-align: center;"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1129693374" /><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1239400231" /><div class="navbar plainlinks hlist navbar-mini"><ul><li class="nv-view"><a href="/wiki/Template:Astrobiology" title="Template:Astrobiology"><abbr title="View this template">v</abbr></a></li><li class="nv-talk"><a href="/wiki/Template_talk:Astrobiology" title="Template talk:Astrobiology"><abbr title="Discuss this template">t</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:EditPage/Template:Astrobiology" title="Special:EditPage/Template:Astrobiology"><abbr title="Edit this template">e</abbr></a></li></ul></div><div id="Astrobiology384" style="font-size:114%;margin:0 4em"><a href="/wiki/Astrobiology" title="Astrobiology">Astrobiology</a></div></th></tr><tr><th scope="row" class="navbox-group" style="text-align: center;;width:1%">Disciplines</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Astrochemistry" title="Astrochemistry">Astrochemistry</a></li> <li><a href="/wiki/Astrophysics" title="Astrophysics">Astrophysics</a></li> <li><a href="/wiki/Atmospheric_sciences" class="mw-redirect" title="Atmospheric sciences">Atmospheric sciences</a></li> <li><a href="/wiki/Biochemistry" title="Biochemistry">Biochemistry</a></li> <li><a href="/wiki/Evolutionary_biology" title="Evolutionary biology">Evolutionary biology</a></li> <li><a href="/wiki/Exoplanetology" class="mw-redirect" title="Exoplanetology">Exoplanetology</a></li> <li><a href="/wiki/Geomicrobiology" title="Geomicrobiology">Geomicrobiology</a></li> <li><a href="/wiki/Microbiology" title="Microbiology">Microbiology</a></li> <li><a href="/wiki/Paleontology" title="Paleontology">Paleontology</a></li> <li><a href="/wiki/Planetary_oceanography" title="Planetary oceanography">Planetary oceanography</a></li> <li><a href="/wiki/Planetary_science" title="Planetary science">Planetary science</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="text-align: center;;width:1%">Main topics</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Abiogenesis" title="Abiogenesis">Abiogenesis</a></li> <li><a href="/wiki/Allan_Hills_84001" title="Allan Hills 84001">Allan Hills 84001</a></li> <li><a href="/wiki/Biomolecule" title="Biomolecule">Biomolecule</a></li> <li><a href="/wiki/Biosignature" title="Biosignature">Biosignature</a></li> <li><a href="/wiki/Drake_equation" title="Drake equation">Drake equation</a></li> <li><a href="/wiki/Earliest_known_life_forms" title="Earliest known life forms">Earliest known life forms</a></li> <li><a href="/wiki/Earth_analog" title="Earth analog">Earth analog</a></li> <li><a href="/wiki/Extraterrestrial_life" title="Extraterrestrial life">Extraterrestrial life</a></li> <li><a href="/wiki/Extraterrestrial_sample_curation" title="Extraterrestrial sample curation">Extraterrestrial sample curation</a></li> <li><a href="/wiki/Extremophile" title="Extremophile">Extremophiles</a></li> <li><a href="/wiki/Hypothetical_types_of_biochemistry" title="Hypothetical types of biochemistry">Hypothetical types of biochemistry</a></li> <li><a href="/wiki/List_of_microorganisms_tested_in_outer_space" title="List of microorganisms tested in outer space">List of microorganisms tested in outer space</a></li> <li><a href="/wiki/Ocean_planet" class="mw-redirect" title="Ocean planet">Ocean planet</a></li> <li><a href="/wiki/Panspermia" title="Panspermia">Panspermia</a></li> <li><a href="/wiki/Planetary_protection" title="Planetary protection">Planetary protection</a></li> <li><a href="/wiki/Search_for_extraterrestrial_intelligence" title="Search for extraterrestrial intelligence">Search for extraterrestrial intelligence (SETI)</a></li> <li><a href="/wiki/Yamato_000593" title="Yamato 000593">Yamato meteorite</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="text-align: center;;width:1%"><a href="/wiki/Planetary_habitability" title="Planetary habitability">Planetary<br />habitability</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Circumstellar_habitable_zone" class="mw-redirect" title="Circumstellar habitable zone">Circumstellar habitable zone</a></li> <li><a href="/wiki/Earth_analog" title="Earth analog">Earth analog</a></li> <li><a href="/wiki/Extraterrestrial_liquid_water" title="Extraterrestrial liquid water">Extraterrestrial liquid water</a></li> <li><a href="/wiki/Galactic_habitable_zone" title="Galactic habitable zone">Galactic habitable zone</a></li> <li><a href="/wiki/Habitability_of_binary_star_systems" title="Habitability of binary star systems">Habitability of binary star systems</a></li> <li><a href="/wiki/Habitability_of_natural_satellites" title="Habitability of natural satellites">Habitability of natural satellites</a></li> <li><a href="/wiki/Habitability_of_neutron_star_systems" title="Habitability of neutron star systems">Habitability of neutron star systems</a></li> <li><a href="/wiki/Habitability_of_red_dwarf_systems" title="Habitability of red dwarf systems">Habitability of red dwarf systems</a></li> <li><a href="/wiki/Habitability_of_K-type_main-sequence_star_systems" title="Habitability of K-type main-sequence star systems">Habitability of K-type main-sequence star systems</a></li> <li><a href="/wiki/Habitability_of_yellow_dwarf_systems" title="Habitability of yellow dwarf systems">Habitability of yellow dwarf systems</a></li> <li><a href="/wiki/Habitability_of_F-type_main-sequence_star_systems" title="Habitability of F-type main-sequence star systems">Habitability of F-type main-sequence star systems</a></li> <li><a href="/wiki/Habitable_zone_for_complex_life" title="Habitable zone for complex life">Habitable zone for complex life</a></li> <li><a href="/wiki/List_of_potentially_habitable_exoplanets" title="List of potentially habitable exoplanets">List of potentially habitable exoplanets</a></li> <li><a class="mw-selflink selflink">Tholin</a></li> <li><a href="/wiki/Superhabitable_planet" class="mw-redirect" title="Superhabitable planet">Superhabitable planet</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="text-align: center;;width:1%">Space<br /> missions</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"></div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th scope="row" class="navbox-group" style="width:1%;text-align: center;">Earth orbit</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Space_Flyer_Unit#Experimentation_data" title="Space Flyer Unit">BIO</a></li> <li><a href="/wiki/Apollo_17#Biological_cosmic_ray_experiment" title="Apollo 17">BIOCORE</a></li> <li><a href="/wiki/Biolab" title="Biolab">Biolab</a></li> <li><a href="/wiki/Bion_(satellite)" title="Bion (satellite)">Bion</a></li> <li><a href="/wiki/BIOPAN" title="BIOPAN">BIOPAN</a></li> <li><a href="/wiki/Biosatellite_program" title="Biosatellite program">Biosatellite program</a></li> <li><a href="/wiki/Exposing_Microorganisms_in_the_Stratosphere" title="Exposing Microorganisms in the Stratosphere">E-MIST</a></li> <li><a href="/wiki/Exobiology_Radiation_Assembly" title="Exobiology Radiation Assembly">ERA</a></li> <li><a href="/wiki/EuCROPIS" title="EuCROPIS">Eu:CROPIS</a></li> <li><a href="/wiki/Long_Duration_Exposure_Facility#EXOSTACK" title="Long Duration Exposure Facility">EXOSTACK</a></li> <li><a href="/wiki/EXPOSE" title="EXPOSE">EXPOSE</a></li> <li><a href="/wiki/Chang%27e_4#Lunar_lander" title="Chang&#39;e 4">Lunar Micro Ecosystem</a></li> <li><a href="/wiki/O/OREOS" title="O/OREOS">O/OREOS</a></li> <li><a href="/wiki/OREOcube" title="OREOcube">OREOcube</a></li> <li><a href="/wiki/Tanpopo_(mission)" class="mw-redirect" title="Tanpopo (mission)">Tanpopo</a></li> <li><a href="/wiki/Vegetable_Production_System" title="Vegetable Production System">VEGGIE</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%;text-align: center;">Mars</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Beagle_2" title="Beagle 2">Beagle 2</a></li> <li><a href="/wiki/Fobos-Grunt" title="Fobos-Grunt">Fobos-Grunt</a></li> <li><a href="/wiki/Mars_Science_Laboratory" title="Mars Science Laboratory">Mars Science Laboratory</a> <ul><li><a href="/wiki/Curiosity_(rover)" title="Curiosity (rover)"><i>Curiosity</i> rover</a></li></ul></li> <li><a href="/wiki/Mars_2020" title="Mars 2020">Mars 2020</a> <ul><li><a href="/wiki/Perseverance_(rover)" title="Perseverance (rover)"><i>Perseverance</i> rover</a></li></ul></li> <li><i><a href="/wiki/Phoenix_(spacecraft)" title="Phoenix (spacecraft)">Phoenix</a></i></li> <li><a href="/wiki/Tianwen-1" title="Tianwen-1">Tianwen-1</a> <ul><li><a href="/wiki/Zhurong_(rover)" title="Zhurong (rover)"><i>Zhurong</i> rover</a></li></ul></li> <li><a href="/wiki/Trace_Gas_Orbiter" title="Trace Gas Orbiter">Trace Gas Orbiter</a></li> <li><a href="/wiki/Viking_lander_biological_experiments" title="Viking lander biological experiments">Viking</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%;text-align: center;">Comets and<br />asteroids</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><i><a href="/wiki/Hayabusa2" title="Hayabusa2">Hayabusa2</a></i></li> <li><a href="/wiki/OSIRIS-REx" title="OSIRIS-REx">OSIRIS-REx</a></li> <li><i><a href="/wiki/Rosetta_(spacecraft)" title="Rosetta (spacecraft)">Rosetta</a></i></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%;text-align: center;">Heliocentric</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/BioSentinel" title="BioSentinel">BioSentinel</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%;text-align: center;">Planned</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><i><a href="/wiki/Dragonfly_(Titan_space_probe)" title="Dragonfly (Titan space probe)">Dragonfly</a></i></li> <li><a href="/wiki/Europa_Clipper" title="Europa Clipper">Europa Clipper</a></li> <li><a href="/wiki/ExoMars" title="ExoMars">ExoMars</a> <ul><li><a href="/wiki/Rosalind_Franklin_(rover)" title="Rosalind Franklin (rover)"><i>Rosalind Franklin</i> rover</a></li></ul></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%;text-align: center;">Proposed</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Breakthrough_Enceladus_mission" title="Breakthrough Enceladus mission">Breakthrough Enceladus</a></li> <li><a href="/wiki/BRUIE" title="BRUIE">BRUIE</a></li> <li><a href="/wiki/CAESAR_(spacecraft)" title="CAESAR (spacecraft)">CAESAR</a></li> <li><a href="/wiki/Enceladus_Explorer" title="Enceladus Explorer">Enceladus Explorer</a></li> <li><a href="/wiki/Enceladus_Life_Finder" title="Enceladus Life Finder">Enceladus Life Finder‎</a></li> <li><a href="/wiki/Enceladus_Life_Signatures_and_Habitability" title="Enceladus Life Signatures and Habitability">Enceladus Life Signatures and Habitability</a></li> <li><a href="/wiki/Enceladus_Orbilander" title="Enceladus Orbilander">Enceladus Orbilander</a></li> <li><a href="/wiki/Europa_Lander_(NASA)" class="mw-redirect" title="Europa Lander (NASA)">Europa Lander</a></li> <li><a href="/wiki/ExoLance" title="ExoLance">ExoLance</a></li> <li><a href="/wiki/Explorer_of_Enceladus_and_Titan" title="Explorer of Enceladus and Titan">Explorer of Enceladus and Titan</a></li> <li><a href="/wiki/Icebreaker_Life" title="Icebreaker Life">Icebreaker Life</a></li> <li><a href="/wiki/Journey_to_Enceladus_and_Titan" title="Journey to Enceladus and Titan">Journey to Enceladus and Titan</a></li> <li><a href="/wiki/Laplace-P" title="Laplace-P">Laplace-P</a></li> <li><a href="/wiki/Life_Investigation_For_Enceladus" title="Life Investigation For Enceladus">Life Investigation For Enceladus</a></li> <li><a href="/wiki/Mars_sample_return_mission" class="mw-redirect" title="Mars sample return mission">Mars sample return mission</a></li> <li><a href="/wiki/Oceanus_(Titan_orbiter)" title="Oceanus (Titan orbiter)">Oceanus</a></li> <li><a href="/wiki/THEO" title="THEO">THEO</a></li> <li><a href="/wiki/Trident_(spacecraft)" title="Trident (spacecraft)">Trident</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%;text-align: center;">Cancelled and <br />undeveloped</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Astrobiology_Field_Laboratory" title="Astrobiology Field Laboratory">Astrobiology Field Laboratory</a></li> <li><a href="/wiki/Beagle_3" title="Beagle 3">Beagle 3</a></li> <li><a href="/wiki/Biological_Oxidant_and_Life_Detection" title="Biological Oxidant and Life Detection">Biological Oxidant and Life Detection</a></li> <li><a href="/wiki/Kazachok" 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data-event-name="ve-edit-sticky-header"><span class="vector-icon mw-ui-icon-wikimedia-edit mw-ui-icon-wikimedia-wikimedia-edit"></span> <span></span> </a> <a href="#" class="cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--icon-only" id="ca-viewsource-sticky-header" tabindex="-1" data-event-name="ve-edit-protected-sticky-header"><span class="vector-icon mw-ui-icon-wikimedia-editLock mw-ui-icon-wikimedia-wikimedia-editLock"></span> <span></span> </a> </div> <div class="vector-sticky-header-buttons"> <button class="cdx-button cdx-button--weight-quiet mw-interlanguage-selector" id="p-lang-btn-sticky-header" tabindex="-1" data-event-name="ui.dropdown-p-lang-btn-sticky-header"><span class="vector-icon mw-ui-icon-wikimedia-language mw-ui-icon-wikimedia-wikimedia-language"></span> <span>31 languages</span> </button> <a href="#" class="cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive" id="ca-addsection-sticky-header" tabindex="-1" data-event-name="addsection-sticky-header"><span class="vector-icon mw-ui-icon-speechBubbleAdd-progressive mw-ui-icon-wikimedia-speechBubbleAdd-progressive"></span> <span>Add topic</span> </a> </div> <div class="vector-sticky-header-icon-end"> <div class="vector-user-links"> </div> </div> </div> </div> </div> <div class="mw-portlet mw-portlet-dock-bottom emptyPortlet" id="p-dock-bottom"> <ul> </ul> </div> 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