Symmetric Polymerization with Dynamical Resolution

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Dynamical Resolution</title> <meta name="description" content="Symmetric Polymerization with Dynamical Resolution"> <meta name="keywords" content="stereo regularity, polymers, dynamical, symmetric"> <meta name="viewport" content="width=device-width, initial-scale=1, minimum-scale=1, maximum-scale=1, user-scalable=no"> <meta charset="utf-8"> <link href="https://cdn.waset.org/favicon.ico" type="image/x-icon" rel="shortcut icon"> <link href="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/css/bootstrap.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/plugins/fontawesome/css/all.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/css/site.css?v=150220211555" rel="stylesheet"> </head> <body> <header> <div class="container"> <nav class="navbar navbar-expand-lg navbar-light"> <a class="navbar-brand" href="https://waset.org"> <img src="https://cdn.waset.org/static/images/wasetc.png" alt="Open Science Research Excellence" title="Open Science Research 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Dynamical Resolution</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Muddser%20Ghaffar">Muddser Ghaffar</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In material science, synthetic chiral polymers are becoming increasingly significant due to their distinct properties that distinguish them from other polymer materials. One special technique for producing well-defined chiral polymers is asymmetric kinetic resolution polymerization (AKRP), which adds stereo regularity to a polymer chain by the kinetic resolution of a race mate preferentially polymerizing one enantiomer. Apart from making it possible to characterize chiral polymers enantioselective, AKRP can synthesize chiral polymers with high stereo selectivity. This review includes the literature on the use of enzymes, chiral metal complexes, and organ catalysts as AKRP promoters. One enantiomer reacts more quickly than the other in this kind of polymerisation, quickly entering the expanding polymer chain, while the kinetically less reactive enantiomer stays unreactive and is readily separated using straightforward purification techniques. The degree of chiral induction and overall chirality of the chiral polymers that are generated may be assessed using the enantiomeric excess (ee) of the initial monomer, which is frequently determined by chiral HPLC analysis, throughout the polymerisation process. <iframe src="https://publications.waset.org/abstracts/193168.pdf" style="width:100%; height:400px;" frameborder="0"></iframe> <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=stereo%20regularity" title="stereo regularity">stereo regularity</a>, <a href="https://publications.waset.org/abstracts/search?q=polymers" title=" polymers"> polymers</a>, <a href="https://publications.waset.org/abstracts/search?q=dynamical" title=" dynamical"> dynamical</a>, <a href="https://publications.waset.org/abstracts/search?q=symmetric" title=" symmetric"> symmetric</a> </p> <a href="https://publications.waset.org/abstracts/193168/symmetric-polymerization-with-dynamical-resolution" 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Symmetric Polymerization with Dynamical Resolution