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is-tooltip-top" data-tooltip="Quantum Physics">quant-ph</span> </div> <div class="is-inline-block" style="margin-left: 0.5rem"> <div class="tags has-addons"> <span class="tag is-dark is-size-7">doi</span> <span class="tag is-light is-size-7"><a class="" href="https://doi.org/10.1103/PhysRevX.11.031048">10.1103/PhysRevX.11.031048 <i class="fa fa-external-link" aria-hidden="true"></i></a></span> </div> </div> </div> <p class="title is-5 mathjax"> Correlation Driven Transient Hole Dynamics Resolved in Space and Time in the Isopropanol Molecule </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/quant-ph?searchtype=author&query=Barillot%2C+T">T. Barillot</a>, <a href="/search/quant-ph?searchtype=author&query=Alexander%2C+O">O. Alexander</a>, <a href="/search/quant-ph?searchtype=author&query=Cooper%2C+B">B. Cooper</a>, <a href="/search/quant-ph?searchtype=author&query=Driver%2C+T">T. Driver</a>, <a href="/search/quant-ph?searchtype=author&query=Garratt%2C+D">D. Garratt</a>, <a href="/search/quant-ph?searchtype=author&query=Li%2C+S">S. Li</a>, <a href="/search/quant-ph?searchtype=author&query=Haddad%2C+A+A">A. Al Haddad</a>, <a href="/search/quant-ph?searchtype=author&query=Sanchez-Gonzalez%2C+A">A. Sanchez-Gonzalez</a>, <a href="/search/quant-ph?searchtype=author&query=Ag%C3%A5ker%2C+M">M. Ag氓ker</a>, <a href="/search/quant-ph?searchtype=author&query=Arrell%2C+C">C. Arrell</a>, <a href="/search/quant-ph?searchtype=author&query=Bearpark%2C+M">M. Bearpark</a>, <a href="/search/quant-ph?searchtype=author&query=Berrah%2C+N">N. Berrah</a>, <a href="/search/quant-ph?searchtype=author&query=Bostedt%2C+C">C. Bostedt</a>, <a href="/search/quant-ph?searchtype=author&query=Bozek%2C+J">J. Bozek</a>, <a href="/search/quant-ph?searchtype=author&query=Brahms%2C+C">C. Brahms</a>, <a href="/search/quant-ph?searchtype=author&query=Bucksbaum%2C+P+H">P. H. Bucksbaum</a>, <a href="/search/quant-ph?searchtype=author&query=Clark%2C+A">A. Clark</a>, <a href="/search/quant-ph?searchtype=author&query=Doumy%2C+G">G. Doumy</a>, <a href="/search/quant-ph?searchtype=author&query=Feifel%2C+R">R. Feifel</a>, <a href="/search/quant-ph?searchtype=author&query=Frasinski%2C+L+J">L. J. Frasinski</a>, <a href="/search/quant-ph?searchtype=author&query=Jarosch%2C+S">S. Jarosch</a>, <a href="/search/quant-ph?searchtype=author&query=Johnson%2C+A+S">A. S. Johnson</a>, <a href="/search/quant-ph?searchtype=author&query=Kjellsson%2C+L">L. Kjellsson</a>, <a href="/search/quant-ph?searchtype=author&query=Koloren%C4%8D%2C+P">P. Koloren膷</a>, <a href="/search/quant-ph?searchtype=author&query=Kumagai%2C+Y">Y. Kumagai</a> , et al. (24 additional authors not shown) </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="2105.06507v1-abstract-short" style="display: inline;"> The possibility of suddenly ionized molecules undergoing extremely fast electron hole dynamics prior to significant structural change was first recognized more than 20 years ago and termed charge migration. The accurate probing of ultrafast electron hole dynamics requires measurements that have both sufficient temporal resolution and can detect the localization of a specific hole within the molecu… <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('2105.06507v1-abstract-full').style.display = 'inline'; document.getElementById('2105.06507v1-abstract-short').style.display = 'none';">▽ More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="2105.06507v1-abstract-full" style="display: none;"> The possibility of suddenly ionized molecules undergoing extremely fast electron hole dynamics prior to significant structural change was first recognized more than 20 years ago and termed charge migration. The accurate probing of ultrafast electron hole dynamics requires measurements that have both sufficient temporal resolution and can detect the localization of a specific hole within the molecule. We report an investigation of the dynamics of inner valence hole states in isopropanol where we use an x-ray pump/x-ray probe experiment, with site and state-specific probing of a transient hole state localized near the oxygen atom in the molecule, together with an ab initio theoretical treatment. We record the signature of transient hole dynamics and make the first observation of dynamics driven by frustrated Auger-Meitner transitions. We verify that the hole lifetime is consistent with our theoretical prediction. This state-specific measurement paves the way to widespread application for observations of transient hole dynamics localized in space and time in molecules and thus to charge transfer phenomena that are fundamental in chemical and material physics. <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('2105.06507v1-abstract-full').style.display = 'none'; document.getElementById('2105.06507v1-abstract-short').style.display = 'inline';">△ Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 13 May, 2021; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> May 2021. </p> <p class="comments is-size-7"> <span class="has-text-black-bis has-text-weight-semibold">Journal ref:</span> Phys. Rev. X 11, 031048 (2021) </p> </li> <li class="arxiv-result"> <div class="is-marginless"> <p class="list-title is-inline-block"><a href="https://arxiv.org/abs/1909.07441">arXiv:1909.07441</a> <span> [<a href="https://arxiv.org/pdf/1909.07441">pdf</a>, <a href="https://arxiv.org/format/1909.07441">other</a>] </span> </p> <div class="tags is-inline-block"> <span class="tag is-small is-link tooltip is-tooltip-top" data-tooltip="Chemical Physics">physics.chem-ph</span> <span class="tag is-small is-grey tooltip is-tooltip-top" data-tooltip="Optics">physics.optics</span> <span class="tag is-small is-grey tooltip is-tooltip-top" data-tooltip="Quantum Physics">quant-ph</span> </div> <div class="is-inline-block" style="margin-left: 0.5rem"> <div class="tags has-addons"> <span class="tag is-dark is-size-7">doi</span> <span class="tag is-light is-size-7"><a class="" href="https://doi.org/10.1039/C9CP03951A">10.1039/C9CP03951A <i class="fa fa-external-link" aria-hidden="true"></i></a></span> </div> </div> </div> <p class="title is-5 mathjax"> Attosecond Transient Absorption Spooktroscopy: a ghost imaging approach to ultrafast absorption spectroscopy </p> <p class="authors"> <span class="search-hit">Authors:</span> <a href="/search/quant-ph?searchtype=author&query=Driver%2C+T">Taran Driver</a>, <a href="/search/quant-ph?searchtype=author&query=Li%2C+S">Siqi Li</a>, <a href="/search/quant-ph?searchtype=author&query=Champenois%2C+E+G">Elio G. Champenois</a>, <a href="/search/quant-ph?searchtype=author&query=Duris%2C+J">Joseph Duris</a>, <a href="/search/quant-ph?searchtype=author&query=Ratner%2C+D">Daniel Ratner</a>, <a href="/search/quant-ph?searchtype=author&query=Lane%2C+T">TJ Lane</a>, <a href="/search/quant-ph?searchtype=author&query=Rosenberger%2C+P">Philipp Rosenberger</a>, <a href="/search/quant-ph?searchtype=author&query=Al-Haddad%2C+A">Andre Al-Haddad</a>, <a href="/search/quant-ph?searchtype=author&query=Averbukh%2C+V">Vitali Averbukh</a>, <a href="/search/quant-ph?searchtype=author&query=Barnard%2C+T">Toby Barnard</a>, <a href="/search/quant-ph?searchtype=author&query=Berrah%2C+N">Nora Berrah</a>, <a href="/search/quant-ph?searchtype=author&query=Bostedt%2C+C">Christoph Bostedt</a>, <a href="/search/quant-ph?searchtype=author&query=Bucksbaum%2C+P+H">Philip H. Bucksbaum</a>, <a href="/search/quant-ph?searchtype=author&query=Coffee%2C+R">Ryan Coffee</a>, <a href="/search/quant-ph?searchtype=author&query=DiMauro%2C+L+F">Louis F. DiMauro</a>, <a href="/search/quant-ph?searchtype=author&query=Fang%2C+L">Li Fang</a>, <a href="/search/quant-ph?searchtype=author&query=Garratt%2C+D">Douglas Garratt</a>, <a href="/search/quant-ph?searchtype=author&query=Gatton%2C+A">Averell Gatton</a>, <a href="/search/quant-ph?searchtype=author&query=Guo%2C+Z">Zhaoheng Guo</a>, <a href="/search/quant-ph?searchtype=author&query=Hartmann%2C+G">Gregor Hartmann</a>, <a href="/search/quant-ph?searchtype=author&query=Haxton%2C+D">Daniel Haxton</a>, <a href="/search/quant-ph?searchtype=author&query=Helml%2C+W">Wolfram Helml</a>, <a href="/search/quant-ph?searchtype=author&query=Huang%2C+Z">Zhirong Huang</a>, <a href="/search/quant-ph?searchtype=author&query=LaForge%2C+A">Aaron LaForge</a>, <a href="/search/quant-ph?searchtype=author&query=Kamalov%2C+A">Andrei Kamalov</a> , et al. (16 additional authors not shown) </p> <p class="abstract mathjax"> <span class="has-text-black-bis has-text-weight-semibold">Abstract</span>: <span class="abstract-short has-text-grey-dark mathjax" id="1909.07441v1-abstract-short" style="display: inline;"> The recent demonstration of isolated attosecond pulses from an X-ray free-electron laser (XFEL) opens the possibility for probing ultrafast electron dynamics at X-ray wavelengths. An established experimental method for probing ultrafast dynamics is X-ray transient absorption spectroscopy, where the X-ray absorption spectrum is measured by scanning the central photon energy and recording the result… <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1909.07441v1-abstract-full').style.display = 'inline'; document.getElementById('1909.07441v1-abstract-short').style.display = 'none';">▽ More</a> </span> <span class="abstract-full has-text-grey-dark mathjax" id="1909.07441v1-abstract-full" style="display: none;"> The recent demonstration of isolated attosecond pulses from an X-ray free-electron laser (XFEL) opens the possibility for probing ultrafast electron dynamics at X-ray wavelengths. An established experimental method for probing ultrafast dynamics is X-ray transient absorption spectroscopy, where the X-ray absorption spectrum is measured by scanning the central photon energy and recording the resultant photoproducts. The spectral bandwidth inherent to attosecond pulses is wide compared to the resonant features typically probed, which generally precludes the application of this technique in the attosecond regime. In this paper we propose and demonstrate a new technique to conduct transient absorption spectroscopy with broad bandwidth attosecond pulses with the aid of ghost imaging, recovering sub-bandwidth resolution in photoproduct-based absorption measurements. <a class="is-size-7" style="white-space: nowrap;" onclick="document.getElementById('1909.07441v1-abstract-full').style.display = 'none'; document.getElementById('1909.07441v1-abstract-short').style.display = 'inline';">△ Less</a> </span> </p> <p class="is-size-7"><span class="has-text-black-bis has-text-weight-semibold">Submitted</span> 16 September, 2019; <span class="has-text-black-bis has-text-weight-semibold">originally announced</span> September 2019. </p> <p class="comments is-size-7"> <span class="has-text-black-bis has-text-weight-semibold">Comments:</span> <span class="has-text-grey-dark mathjax">13 pages, 3 figures</span> </p> </li> </ol> <div class="is-hidden-tablet"> <!-- feedback for mobile only --> <span class="help" 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