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Available in 19 languages" > <label id="p-lang-btn-label" for="p-lang-btn-checkbox" class="vector-dropdown-label cdx-button cdx-button--fake-button cdx-button--fake-button--enabled cdx-button--weight-quiet cdx-button--action-progressive mw-portlet-lang-heading-19" aria-hidden="true" ><span class="vector-icon mw-ui-icon-language-progressive mw-ui-icon-wikimedia-language-progressive"></span> <span class="vector-dropdown-label-text">19 languages</span> </label> <div class="vector-dropdown-content"> <div class="vector-menu-content"> <ul class="vector-menu-content-list"> <li class="interlanguage-link interwiki-ar mw-list-item"><a href="https://ar.wikipedia.org/wiki/%D9%83%D9%84%D9%88%D8%B1%D9%8A%D8%AF_%D8%A7%D9%84%D8%B3%D9%8A%D8%B1%D9%8A%D9%88%D9%85_%D8%A7%D9%84%D8%AB%D9%84%D8%A7%D8%AB%D9%8A" title="كلوريد السيريوم الثلاثي – Arabic" lang="ar" hreflang="ar" data-title="كلوريد السيريوم الثلاثي" data-language-autonym="العربية" data-language-local-name="Arabic" class="interlanguage-link-target"><span>العربية</span></a></li><li class="interlanguage-link interwiki-azb mw-list-item"><a href="https://azb.wikipedia.org/wiki/%D8%B3%D8%B1%DB%8C%D9%88%D9%85_(III)_%DA%A9%D9%88%D9%84%D9%88%D8%B1%DB%8C%D8%AF" title="سریوم (III) کولورید – South Azerbaijani" lang="azb" hreflang="azb" data-title="سریوم (III) کولورید" data-language-autonym="تۆرکجه" data-language-local-name="South Azerbaijani" class="interlanguage-link-target"><span>تۆرکجه</span></a></li><li class="interlanguage-link interwiki-cs mw-list-item"><a href="https://cs.wikipedia.org/wiki/Chlorid_cerit%C3%BD" title="Chlorid ceritý – Czech" lang="cs" hreflang="cs" data-title="Chlorid ceritý" data-language-autonym="Čeština" data-language-local-name="Czech" class="interlanguage-link-target"><span>Čeština</span></a></li><li class="interlanguage-link interwiki-de mw-list-item"><a href="https://de.wikipedia.org/wiki/Cer(III)-chlorid" title="Cer(III)-chlorid – German" lang="de" hreflang="de" data-title="Cer(III)-chlorid" data-language-autonym="Deutsch" data-language-local-name="German" class="interlanguage-link-target"><span>Deutsch</span></a></li><li class="interlanguage-link interwiki-eo mw-list-item"><a href="https://eo.wikipedia.org/wiki/Ceria_(III)_klorido" title="Ceria (III) klorido – Esperanto" lang="eo" hreflang="eo" data-title="Ceria (III) klorido" data-language-autonym="Esperanto" data-language-local-name="Esperanto" class="interlanguage-link-target"><span>Esperanto</span></a></li><li class="interlanguage-link interwiki-fa mw-list-item"><a href="https://fa.wikipedia.org/wiki/%D8%B3%D8%B1%DB%8C%D9%85_(III)_%DA%A9%D9%84%D8%B1%DB%8C%D8%AF" title="سریم (III) کلرید – Persian" lang="fa" hreflang="fa" data-title="سریم (III) کلرید" data-language-autonym="فارسی" data-language-local-name="Persian" class="interlanguage-link-target"><span>فارسی</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/Chlorure_de_c%C3%A9rium(III)" title="Chlorure de cérium(III) – French" lang="fr" hreflang="fr" data-title="Chlorure de cérium(III)" data-language-autonym="Français" data-language-local-name="French" class="interlanguage-link-target"><span>Français</span></a></li><li class="interlanguage-link interwiki-hi mw-list-item"><a href="https://hi.wikipedia.org/wiki/%E0%A4%B8%E0%A5%87%E0%A4%B0%E0%A4%BF%E0%A4%AF%E0%A4%AE(III)_%E0%A4%95%E0%A5%8D%E0%A4%B2%E0%A5%8B%E0%A4%B0%E0%A4%BE%E0%A4%87%E0%A4%A1" title="सेरियम(III) क्लोराइड – Hindi" lang="hi" hreflang="hi" data-title="सेरियम(III) क्लोराइड" data-language-autonym="हिन्दी" data-language-local-name="Hindi" class="interlanguage-link-target"><span>हिन्दी</span></a></li><li class="interlanguage-link interwiki-id mw-list-item"><a href="https://id.wikipedia.org/wiki/Serium(III)_klorida" title="Serium(III) klorida – Indonesian" lang="id" hreflang="id" data-title="Serium(III) klorida" data-language-autonym="Bahasa Indonesia" data-language-local-name="Indonesian" class="interlanguage-link-target"><span>Bahasa Indonesia</span></a></li><li class="interlanguage-link interwiki-it mw-list-item"><a href="https://it.wikipedia.org/wiki/Cloruro_ceroso" title="Cloruro ceroso – Italian" lang="it" hreflang="it" data-title="Cloruro ceroso" data-language-autonym="Italiano" data-language-local-name="Italian" class="interlanguage-link-target"><span>Italiano</span></a></li><li class="interlanguage-link interwiki-nl mw-list-item"><a href="https://nl.wikipedia.org/wiki/Cerium(III)chloride" title="Cerium(III)chloride – Dutch" lang="nl" hreflang="nl" data-title="Cerium(III)chloride" data-language-autonym="Nederlands" data-language-local-name="Dutch" class="interlanguage-link-target"><span>Nederlands</span></a></li><li class="interlanguage-link interwiki-ja mw-list-item"><a href="https://ja.wikipedia.org/wiki/%E5%A1%A9%E5%8C%96%E3%82%BB%E3%83%AA%E3%82%A6%E3%83%A0(III)" title="塩化セリウム(III) – Japanese" lang="ja" hreflang="ja" data-title="塩化セリウム(III)" data-language-autonym="日本語" data-language-local-name="Japanese" class="interlanguage-link-target"><span>日本語</span></a></li><li class="interlanguage-link interwiki-ru mw-list-item"><a href="https://ru.wikipedia.org/wiki/%D0%A5%D0%BB%D0%BE%D1%80%D0%B8%D0%B4_%D1%86%D0%B5%D1%80%D0%B8%D1%8F(III)" title="Хлорид церия(III) – Russian" lang="ru" hreflang="ru" data-title="Хлорид церия(III)" data-language-autonym="Русский" data-language-local-name="Russian" class="interlanguage-link-target"><span>Русский</span></a></li><li class="interlanguage-link interwiki-sr mw-list-item"><a href="https://sr.wikipedia.org/wiki/Cerijum(III)_hlorid" title="Cerijum(III) hlorid – Serbian" lang="sr" hreflang="sr" data-title="Cerijum(III) hlorid" data-language-autonym="Српски / srpski" data-language-local-name="Serbian" class="interlanguage-link-target"><span>Српски / srpski</span></a></li><li class="interlanguage-link interwiki-sh mw-list-item"><a href="https://sh.wikipedia.org/wiki/Cerijum(III)_hlorid" title="Cerijum(III) hlorid – Serbo-Croatian" lang="sh" hreflang="sh" data-title="Cerijum(III) hlorid" data-language-autonym="Srpskohrvatski / српскохрватски" data-language-local-name="Serbo-Croatian" class="interlanguage-link-target"><span>Srpskohrvatski / српскохрватски</span></a></li><li class="interlanguage-link interwiki-fi mw-list-item"><a href="https://fi.wikipedia.org/wiki/Ceriumkloridi" title="Ceriumkloridi – Finnish" lang="fi" hreflang="fi" data-title="Ceriumkloridi" data-language-autonym="Suomi" data-language-local-name="Finnish" class="interlanguage-link-target"><span>Suomi</span></a></li><li class="interlanguage-link interwiki-ta mw-list-item"><a href="https://ta.wikipedia.org/wiki/%E0%AE%9A%E0%AF%80%E0%AE%B0%E0%AE%BF%E0%AE%AF%E0%AE%AE%E0%AF%8D(III)_%E0%AE%95%E0%AF%81%E0%AE%B3%E0%AF%8B%E0%AE%B0%E0%AF%88%E0%AE%9F%E0%AF%81" title="சீரியம்(III) குளோரைடு – Tamil" lang="ta" hreflang="ta" data-title="சீரியம்(III) குளோரைடு" data-language-autonym="தமிழ்" data-language-local-name="Tamil" class="interlanguage-link-target"><span>தமிழ்</span></a></li><li class="interlanguage-link interwiki-vi mw-list-item"><a href="https://vi.wikipedia.org/wiki/Ceri(III)_chloride" title="Ceri(III) chloride – Vietnamese" lang="vi" hreflang="vi" data-title="Ceri(III) chloride" data-language-autonym="Tiếng Việt" data-language-local-name="Vietnamese" class="interlanguage-link-target"><span>Tiếng Việt</span></a></li><li class="interlanguage-link interwiki-zh mw-list-item"><a href="https://zh.wikipedia.org/wiki/%E4%B8%89%E6%B0%AF%E5%8C%96%E9%93%88" title="三氯化铈 – Chinese" lang="zh" hreflang="zh" data-title="三氯化铈" data-language-autonym="中文" data-language-local-name="Chinese" class="interlanguage-link-target"><span>中文</span></a></li> </ul> <div class="after-portlet after-portlet-lang"><span class="wb-langlinks-edit wb-langlinks-link"><a href="https://www.wikidata.org/wiki/Special:EntityPage/Q419806#sitelinks-wikipedia" title="Edit 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dir="ltr"><style data-mw-deduplicate="TemplateStyles:r1268415487">.mw-parser-output .ib-chembox{border-collapse:collapse;text-align:left}.mw-parser-output .ib-chembox td,.mw-parser-output .ib-chembox th{border:1px solid #a2a9b1;width:40%}.mw-parser-output .ib-chembox td+td{width:60%}@media screen{html.skin-theme-clientpref-night .mw-parser-output .ib-chembox figure:not(.skin-invert-image):not(.skin-invert):not(.bg-transparent){background:var(--background-color-inverted,#f8f9fa)}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .ib-chembox figure:not(.skin-invert-image):not(.skin-invert):not(.bg-transparent){background:var(--background-color-inverted,#f8f9fa)}}</style> <table class="infobox ib-chembox"> <caption>Cerium(III) chloride </caption> <tbody><tr> <td colspan="2" style="text-align:center; padding:2px;"><figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:CeriumIIIchloride.jpg" class="mw-file-description" title="Cerium(III) chloride"><img alt="Cerium(III) chloride" src="//upload.wikimedia.org/wikipedia/commons/thumb/0/00/CeriumIIIchloride.jpg/220px-CeriumIIIchloride.jpg" decoding="async" width="220" height="266" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/0/00/CeriumIIIchloride.jpg 1.5x" data-file-width="300" data-file-height="363" /></a><figcaption>Cerium(III) chloride</figcaption></figure> </td></tr> <tr> <td colspan="2" class="borderless" style="text-align:center"> <table border="0" style="width:100%;display:inline-table;"> <tbody><tr> <td style="border-right:1px solid #aaa; width:50%;"><figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:UCl3_without_caption.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/2/24/UCl3_without_caption.png/110px-UCl3_without_caption.png" decoding="async" width="110" height="88" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/2/24/UCl3_without_caption.png/165px-UCl3_without_caption.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/2/24/UCl3_without_caption.png/220px-UCl3_without_caption.png 2x" data-file-width="2362" data-file-height="1890" /></a><figcaption></figcaption></figure> </td> <td style="width:50%;"><figure class="mw-halign-center" typeof="mw:File"><a href="/wiki/File:Cerium_bromide_(space_filling)_2.png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/9/93/Cerium_bromide_%28space_filling%29_2.png/110px-Cerium_bromide_%28space_filling%29_2.png" decoding="async" width="110" height="105" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/9/93/Cerium_bromide_%28space_filling%29_2.png/165px-Cerium_bromide_%28space_filling%29_2.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/9/93/Cerium_bromide_%28space_filling%29_2.png/220px-Cerium_bromide_%28space_filling%29_2.png 2x" data-file-width="2103" data-file-height="2000" /></a><figcaption></figcaption></figure> </td></tr></tbody></table> </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Names </th></tr> <tr> <td colspan="2" style="text-align:left;"><a href="/wiki/Chemical_nomenclature" title="Chemical nomenclature">IUPAC names</a> <div style="max-width:22em; word-wrap:break-word; padding-left:1.7em;">Cerium(III) chloride<br />Cerium trichloride</div> </td></tr> <tr> <td colspan="2" style="text-align:left;">Other names <div style="max-width:22em; word-wrap:break-word; padding-left:1.7em;">Cerous chloride</div> </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Identifiers </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/CAS_Registry_Number" title="CAS Registry Number">CAS Number</a></div> </td> <td><style data-mw-deduplicate="TemplateStyles:r1126788409">.mw-parser-output .plainlist ol,.mw-parser-output .plainlist ul{line-height:inherit;list-style:none;margin:0;padding:0}.mw-parser-output .plainlist ol li,.mw-parser-output .plainlist ul li{margin-bottom:0}</style><div class="plainlist"><ul><li><span title="commonchemistry.cas.org"><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=7790-86-5">7790-86-5</a></span><sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></li><li><span title="commonchemistry.cas.org"><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=18618-55-8">18618-55-8</a></span> (heptahydrate)<sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></li></ul></div> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">3D model (<a href="/wiki/JSmol" class="mw-redirect" title="JSmol">JSmol</a>)</div> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="chemapps.stolaf.edu (3D interactive model)"><a rel="nofollow" class="external text" href="https://chemapps.stolaf.edu/jmol/jmol.php?model=%5BCl-%5D.%5BCl-%5D.%5BCl-%5D.%5BCe%2B3%5D">Interactive image</a></span></li></ul></div> </td></tr> <tr> <td><a href="/wiki/ChEBI" title="ChEBI">ChEBI</a> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="www.ebi.ac.uk"><a rel="nofollow" class="external text" href="https://www.ebi.ac.uk/chebi/searchId.do?chebiId=35458">CHEBI:35458</a></span><sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></li></ul></div> </td></tr> <tr> <td><a href="/wiki/ChemSpider" title="ChemSpider">ChemSpider</a> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="www.chemspider.com"><a rel="nofollow" class="external text" href="https://www.chemspider.com/Chemical-Structure.23038.html">23038</a></span><sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></li></ul></div> </td></tr> <tr> <td><a href="/wiki/ECHA_InfoCard" class="mw-redirect" title="ECHA InfoCard"><span title="echa.europa.eu">ECHA InfoCard</span></a> </td> <td><a rel="nofollow" class="external text" href="https://echa.europa.eu/substance-information/-/substanceinfo/100.029.298">100.029.298</a> <span class="mw-valign-text-top noprint" typeof="mw:File/Frameless"><a href="https://www.wikidata.org/wiki/Q419806#P2566" title="Edit this at Wikidata"><img alt="Edit this at Wikidata" src="//upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/10px-OOjs_UI_icon_edit-ltr-progressive.svg.png" decoding="async" width="10" height="10" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/15px-OOjs_UI_icon_edit-ltr-progressive.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/20px-OOjs_UI_icon_edit-ltr-progressive.svg.png 2x" data-file-width="20" data-file-height="20" /></a></span> </td></tr> <tr> <td><a href="/wiki/European_Community_number" title="European Community number"><span title="European Community number (chemical identifier)">EC Number</span></a> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li>232-227-8</li></ul></div> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Gmelin_database" title="Gmelin database">Gmelin Reference</a></div> </td> <td>1828 </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/PubChem" title="PubChem">PubChem</a> <abbr title="Compound ID">CID</abbr></div> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="pubchem.ncbi.nlm.nih.gov"><a rel="nofollow" class="external text" href="https://pubchem.ncbi.nlm.nih.gov/compound/24636">24636</a></span></li></ul></div> </td></tr> <tr> <td><a href="/wiki/Unique_Ingredient_Identifier" title="Unique Ingredient Identifier">UNII</a> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="precision.fda.gov"><a rel="nofollow" class="external text" href="https://precision.fda.gov/uniisearch/srs/unii/TH8E3IE00V">TH8E3IE00V</a></span><sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></li><li><span title="precision.fda.gov"><a rel="nofollow" class="external text" href="https://precision.fda.gov/uniisearch/srs/unii/188BE3J495">188BE3J495</a></span> (heptahydrate)<sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></li></ul></div> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/CompTox_Chemicals_Dashboard" title="CompTox Chemicals Dashboard">CompTox Dashboard</a> <span style="font-weight:normal">(<abbr title="U.S. Environmental Protection Agency">EPA</abbr>)</span></div> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="comptox.epa.gov"><a rel="nofollow" class="external text" href="https://comptox.epa.gov/dashboard/chemical/details/DTXSID1037199">DTXSID1037199</a> <span class="mw-valign-text-top noprint" typeof="mw:File/Frameless"><a href="https://www.wikidata.org/wiki/Q419806#P3117" title="Edit this at Wikidata"><img alt="Edit this at Wikidata" src="//upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/10px-OOjs_UI_icon_edit-ltr-progressive.svg.png" decoding="async" width="10" height="10" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/15px-OOjs_UI_icon_edit-ltr-progressive.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/20px-OOjs_UI_icon_edit-ltr-progressive.svg.png 2x" data-file-width="20" data-file-height="20" /></a></span></span></li></ul></div> </td></tr> <tr> <td colspan="2"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold; text-align:left; font-weight:normal;"><div><a href="/wiki/International_Chemical_Identifier" title="International Chemical Identifier">InChI</a></div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0; word-break:break-all;"><li style="line-height: inherit; margin: 0"><div style="border-top:1px solid #ccc; padding:0.2em 0 0.2em 1.5em; text-align:left;"><div style="word-wrap:break-word; text-indent:-1.5em; font-size:97%; line-height:120%;">InChI=1S/Ce.3ClH/h;3*1H/q+3;;;/p-3<sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></div><div style="word-wrap:break-word; text-indent:-1.5em; font-size:97%; line-height:120%;">Key: VYLVYHXQOHJDJL-UHFFFAOYSA-K<sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></div></div></li><li style="line-height: inherit; margin: 0"><div style="border-top:1px solid #ccc; padding:0.2em 0 0.2em 1.5em; text-align:left;"><div style="word-wrap:break-word; text-indent:-1.5em; font-size:97%; line-height:120%;">InChI=1/Ce.3ClH/h;3*1H/q+3;;;/p-3</div><div style="word-wrap:break-word; text-indent:-1.5em; font-size:97%; line-height:120%;">Key: VYLVYHXQOHJDJL-DFZHHIFOAZ</div></div></li></ul> </div> </td></tr> <tr> <td colspan="2"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold; text-align:left; font-weight:normal;"><div><a href="/wiki/Simplified_molecular-input_line-entry_system" class="mw-redirect" title="Simplified molecular-input line-entry system">SMILES</a></div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0; word-break:break-all;"><li style="line-height: inherit; margin: 0"><div style="border-top:1px solid #ccc; padding:0.2em 0 0.2em 1.6em; word-wrap:break-word; text-indent:-1.5em; text-align:left; font-size:97%; line-height:120%;">[Cl-].[Cl-].[Cl-].[Ce+3]</div></li></ul> </div> </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Properties </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Chemical_formula" title="Chemical formula">Chemical formula</a></div> </td> <td>CeCl<sub>3</sub>  </td></tr> <tr> <td><a href="/wiki/Molar_mass" title="Molar mass">Molar mass</a> </td> <td>246.48 g/mol (anhydrous) <br /> 372.58 g/mol (heptahydrate)    </td></tr> <tr> <td>Appearance </td> <td>fine white powder </td></tr> <tr> <td><a href="/wiki/Density" title="Density">Density</a> </td> <td>3.97 g/cm<sup>3</sup> </td></tr> <tr> <td><a href="/wiki/Melting_point" title="Melting point">Melting point</a> </td> <td>817 °C (1,503 °F; 1,090 K) (anhydrous) <br /> 90 °C (heptahydrate, decomposes) </td></tr> <tr> <td><a href="/wiki/Boiling_point" title="Boiling point">Boiling point</a> </td> <td>1,727 °C (3,141 °F; 2,000 K) </td></tr> <tr> <td><a href="/wiki/Solubility" title="Solubility">Solubility</a> </td> <td>soluble in <a href="/wiki/Alcohol_(chemistry)" title="Alcohol (chemistry)">alcohol</a> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Magnetic_susceptibility" title="Magnetic susceptibility">Magnetic susceptibility</a> (χ)</div> </td> <td>+2490.0·10<sup>−6</sup> cm<sup>3</sup>/mol </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Structure </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Crystal_structure" title="Crystal structure">Crystal structure</a></div> </td> <td><a href="/wiki/Hexagonal_crystal_system" class="mw-redirect" title="Hexagonal crystal system">hexagonal</a> (<a href="/wiki/Uranium_trichloride#Structure" class="mw-redirect" title="Uranium trichloride">UCl<sub>3</sub> type</a>), <a href="/wiki/Pearson_symbol" title="Pearson symbol">hP8</a> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Space_group" title="Space group">Space group</a></div> </td> <td>P6<sub>3</sub>/m, No. 176 </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Coordination_geometry" title="Coordination geometry">Coordination geometry</a></div> </td> <td>Tricapped trigonal prismatic<br />(nine-coordinate) </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Hazards </th></tr> <tr> <td colspan="2" style="text-align:left; background-color:#eaeaea;color:inherit;"><a href="/wiki/Globally_Harmonized_System_of_Classification_and_Labelling_of_Chemicals" title="Globally Harmonized System of Classification and Labelling of Chemicals"><b>GHS</b> labelling</a>: </td></tr> <tr> <td style="padding-left:1em;"><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/GHS_hazard_pictograms" title="GHS hazard pictograms">Pictograms</a></div> </td> <td><span typeof="mw:File"><a href="/wiki/File:GHS-pictogram-acid.svg" class="mw-file-description" title="GHS05: Corrosive"><img alt="GHS05: Corrosive" src="//upload.wikimedia.org/wikipedia/commons/thumb/a/a1/GHS-pictogram-acid.svg/50px-GHS-pictogram-acid.svg.png" decoding="async" width="50" height="50" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/a/a1/GHS-pictogram-acid.svg/75px-GHS-pictogram-acid.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/a/a1/GHS-pictogram-acid.svg/100px-GHS-pictogram-acid.svg.png 2x" data-file-width="724" data-file-height="724" /></a></span><span typeof="mw:File"><a href="/wiki/File:GHS-pictogram-exclam.svg" class="mw-file-description" title="GHS07: Exclamation mark"><img alt="GHS07: Exclamation mark" src="//upload.wikimedia.org/wikipedia/commons/thumb/c/c3/GHS-pictogram-exclam.svg/50px-GHS-pictogram-exclam.svg.png" decoding="async" width="50" height="50" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/c/c3/GHS-pictogram-exclam.svg/75px-GHS-pictogram-exclam.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/c/c3/GHS-pictogram-exclam.svg/100px-GHS-pictogram-exclam.svg.png 2x" data-file-width="512" data-file-height="512" /></a></span><span typeof="mw:File"><a href="/wiki/File:GHS-pictogram-pollu.svg" class="mw-file-description" title="GHS09: Environmental hazard"><img alt="GHS09: Environmental hazard" src="//upload.wikimedia.org/wikipedia/commons/thumb/b/b9/GHS-pictogram-pollu.svg/50px-GHS-pictogram-pollu.svg.png" decoding="async" width="50" height="50" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/b/b9/GHS-pictogram-pollu.svg/75px-GHS-pictogram-pollu.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/b/b9/GHS-pictogram-pollu.svg/100px-GHS-pictogram-pollu.svg.png 2x" data-file-width="724" data-file-height="724" /></a></span> </td></tr> <tr> <td style="padding-left:1em;"><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Globally_Harmonized_System_of_Classification_and_Labelling_of_Chemicals#Signal_word" title="Globally Harmonized System of Classification and Labelling of Chemicals">Signal word</a></div> </td> <td><b>Danger</b> </td></tr> <tr> <td style="padding-left:1em;"><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/GHS_hazard_statements" title="GHS hazard statements">Hazard statements</a></div> </td> <td><abbr class="abbr" title="H315: Causes skin irritation">H315</abbr>, <abbr class="abbr" title="H318: Causes serious eye damage">H318</abbr>, <abbr class="abbr" title="H319: Causes serious eye irritation">H319</abbr>, <abbr class="abbr" title="H335: May cause respiratory irritation">H335</abbr>, <abbr class="abbr" title="H410: Very toxic to aquatic life with long lasting effects">H410</abbr> </td></tr> <tr> <td style="padding-left:1em;"><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/GHS_precautionary_statements" title="GHS precautionary statements">Precautionary statements</a></div> </td> <td><abbr class="abbr" title="P261: Avoid breathing dust/fume/gas/mist/vapours/spray.">P261</abbr>, <abbr class="abbr" title="P264: Wash ... thoroughly after handling.">P264</abbr>, <abbr class="abbr" title="P271: Use only outdoors or in a well-ventilated area.">P271</abbr>, <abbr class="abbr" title="P273: Avoid release to the environment.">P273</abbr>, <abbr class="abbr" title="P280: Wear protective gloves/protective clothing/eye protection/face protection.">P280</abbr>, <abbr class="abbr" title="P302+P352: IF ON SKIN: Wash with soap and water.">P302+P352</abbr>, <abbr class="abbr" title="P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.">P304+P340</abbr>, <abbr class="abbr" title="P305+P351+P338: IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.">P305+P351+P338</abbr>, <abbr class="abbr" title="P310: Immediately call a POISON CENTER or doctor/physician.">P310</abbr>, <abbr class="abbr" title="P312: Call a POISON CENTER or doctor/physician if you feel unwell.">P312</abbr>, <abbr class="abbr" title="P321: Specific treatment (see ... on this label).">P321</abbr>, <abbr class="abbr" title="P332+P313: If skin irritation occurs: Get medical advice/attention.">P332+P313</abbr>, <abbr class="abbr" title="P337+P313: If eye irritation persists: Get medical advice/attention.">P337+P313</abbr>, <abbr class="abbr" title="P362: Take off contaminated clothing.">P362</abbr>, <abbr class="abbr" title="P391: Collect spillage.">P391</abbr>, <abbr class="abbr" title="P403+P233: Store in a well ventilated place. Keep container tightly closed.">P403+P233</abbr>, <abbr class="abbr" title="P405: Store locked up.">P405</abbr>, <abbr class="abbr" title="P501: Dispose of contents/container to ...">P501</abbr> </td></tr> <tr> <td><a href="/wiki/Flash_point" title="Flash point">Flash point</a> </td> <td>Non-flammable </td></tr> <tr> <th colspan="2" style="background: #f8eaba;color:inherit; text-align: center;">Related compounds </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">Other <a href="/wiki/Ion" title="Ion">anions</a></div> </td> <td><a href="/wiki/Cerium(III)_oxide" title="Cerium(III) oxide">Cerium(III) oxide</a><br /><a href="/wiki/Cerium(III)_fluoride" title="Cerium(III) fluoride">Cerium(III) fluoride</a><br /><a href="/wiki/Cerium(III)_bromide" title="Cerium(III) bromide">Cerium(III) bromide</a><br /><a href="/wiki/Cerium(III)_iodide" title="Cerium(III) iodide">Cerium(III) iodide</a> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">Other <a href="/wiki/Ion" title="Ion">cations</a></div> </td> <td><a href="/wiki/Lanthanum(III)_chloride" title="Lanthanum(III) chloride">Lanthanum(III) chloride</a><br /><a href="/wiki/Praseodymium(III)_chloride" title="Praseodymium(III) chloride">Praseodymium(III) chloride</a> </td></tr> <tr> <td colspan="2" style="text-align:left; background:#f8eaba; color:inherit; border:1px solid #a2a9b1;"><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">Except where otherwise noted, data are given for materials in their <a href="/wiki/Standard_state" title="Standard state">standard state</a> (at 25 °C [77 °F], 100 kPa).</div> <div style="margin-top: 0.3em;"><div style="text-align:center;"><span typeof="mw:File"><span><img alt="☒" src="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/12px-X_mark.svg.png" decoding="async" width="12" height="14" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/18px-X_mark.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/24px-X_mark.svg.png 2x" data-file-width="525" data-file-height="600" /></span></span><span style="display:none">N</span> <span class="reflink plainlinks nourlexpansion"><a class="external text" href="https://en.wikipedia.org/w/index.php?title=Special:ComparePages&rev1=476998131&page2=Cerium%28III%29+chloride">verify</a></span> (<a href="/wiki/Wikipedia:WikiProject_Chemicals/Chembox_validation" title="Wikipedia:WikiProject Chemicals/Chembox validation">what is</a> <sup><span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span><span typeof="mw:File"><span><img alt="☒" src="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/7px-X_mark.svg.png" decoding="async" width="7" height="8" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/11px-X_mark.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/14px-X_mark.svg.png 2x" data-file-width="525" data-file-height="600" /></span></span><span style="display:none">N</span></sup> ?) </div></div> <div style="margin-top: 0.3em; text-align: center;"><a href="/wiki/Wikipedia:Chemical_infobox#References" title="Wikipedia:Chemical infobox">Infobox references</a></div> </td></tr> </tbody></table><div class="shortdescription nomobile noexcerpt noprint searchaux" style="display:none">Chemical compound</div> <p><b>Cerium(III) chloride</b> (CeCl<sub>3</sub>), also known as cerous chloride or cerium trichloride, is a compound of <a href="/wiki/Cerium" title="Cerium">cerium</a> and <a href="/wiki/Chlorine" title="Chlorine">chlorine</a>. It is a white <a href="/wiki/Hygroscopic" class="mw-redirect" title="Hygroscopic">hygroscopic</a> salt; it rapidly absorbs water on exposure to moist air to form a <a href="/wiki/Hydrate" title="Hydrate">hydrate</a>, which appears to be of variable composition,<sup id="cite_ref-1" class="reference"><a href="#cite_note-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> though the heptahydrate CeCl<sub>3</sub>·7H<sub>2</sub>O is known. It is highly soluble in <a href="/wiki/Water_(molecule)" class="mw-redirect" title="Water (molecule)">water</a>, and (when anhydrous) it is soluble in <a href="/wiki/Ethanol" title="Ethanol">ethanol</a> and <a href="/wiki/Acetone" title="Acetone">acetone</a>.<sup id="cite_ref-Paquette1999_2-0" class="reference"><a href="#cite_note-Paquette1999-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="Preparation_of_anhydrous_CeCl3">Preparation of anhydrous CeCl<sub>3</sub></h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Cerium(III)_chloride&action=edit&section=1" title="Edit section: Preparation of anhydrous CeCl3"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Simple rapid heating of the hydrate alone may cause small amounts of <a href="/wiki/Hydrolysis" title="Hydrolysis">hydrolysis</a>.<sup id="cite_ref-EdelmannPoremba1997_3-0" class="reference"><a href="#cite_note-EdelmannPoremba1997-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> </p><p>A useful form of <a href="/wiki/Anhydrous" title="Anhydrous">anhydrous</a> CeCl<sub>3</sub> can be prepared if care is taken to heat the heptahydrate gradually to 140 °C (284 °F) over many hours under vacuum.<sup id="cite_ref-Paquette1999_2-1" class="reference"><a href="#cite_note-Paquette1999-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-JohnsonTait1987_4-0" class="reference"><a href="#cite_note-JohnsonTait1987-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-Dimitrov1996_5-0" class="reference"><a href="#cite_note-Dimitrov1996-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup> This may or may not contain a little CeOCl from <a href="/wiki/Hydrolysis" title="Hydrolysis">hydrolysis</a>, but it is suitable for use with <a href="/wiki/Organolithium_reagent" title="Organolithium reagent">organolithium</a> and <a href="/wiki/Grignard_reagent" title="Grignard reagent">Grignard reagents</a>. Pure anhydrous CeCl<sub>3</sub> can be made by dehydration of the hydrate either by slowly heating to 400 °C (752 °F) with 4–6 equivalents of <a href="/wiki/Ammonium_chloride" title="Ammonium chloride">ammonium chloride</a> under high vacuum,<sup id="cite_ref-EdelmannPoremba1997_3-1" class="reference"><a href="#cite_note-EdelmannPoremba1997-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-Taylor1962_6-0" class="reference"><a href="#cite_note-Taylor1962-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-KutscherSchneider1971_7-0" class="reference"><a href="#cite_note-KutscherSchneider1971-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-Greenwood1984_8-0" class="reference"><a href="#cite_note-Greenwood1984-8"><span class="cite-bracket">[</span>8<span class="cite-bracket">]</span></a></sup> or by heating with an excess of <a href="/wiki/Thionyl_chloride" title="Thionyl chloride">thionyl chloride</a> for three hours.<sup id="cite_ref-EdelmannPoremba1997_3-2" class="reference"><a href="#cite_note-EdelmannPoremba1997-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-Freeman1958_9-0" class="reference"><a href="#cite_note-Freeman1958-9"><span class="cite-bracket">[</span>9<span class="cite-bracket">]</span></a></sup> The anhydrous <a href="/wiki/Halide" title="Halide">halide</a> may alternatively be prepared from <a href="/wiki/Cerium" title="Cerium">cerium</a> metal and <a href="/wiki/Hydrogen_chloride" title="Hydrogen chloride">hydrogen chloride</a>.<sup id="cite_ref-Druding1961_10-0" class="reference"><a href="#cite_note-Druding1961-10"><span class="cite-bracket">[</span>10<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-Corbett1973_11-0" class="reference"><a href="#cite_note-Corbett1973-11"><span class="cite-bracket">[</span>11<span class="cite-bracket">]</span></a></sup> It is usually purified by high temperature sublimation under high vacuum. Soxhlet extraction of <style data-mw-deduplicate="TemplateStyles:r1123817410">.mw-parser-output .template-chem2-su{display:inline-block;font-size:80%;line-height:1;vertical-align:-0.35em}.mw-parser-output .template-chem2-su>span{display:block;text-align:left}.mw-parser-output sub.template-chem2-sub{font-size:80%;vertical-align:-0.35em}.mw-parser-output sup.template-chem2-sup{font-size:80%;vertical-align:0.65em}</style><span class="chemf nowrap">CeCl<sub class="template-chem2-sub">3</sub></span> with thf gives <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">CeCl<sub class="template-chem2-sub">3</sub>(thf)<sub class="template-chem2-sub">1.04</sub></span>.<sup id="cite_ref-12" class="reference"><a href="#cite_note-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="Uses">Uses</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Cerium(III)_chloride&action=edit&section=2" title="Edit section: Uses"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Cerium(III) chloride can be used as a starting point for the preparation of other <a href="/wiki/Cerium" title="Cerium">cerium</a> <a href="/wiki/Salt_(chemistry)" title="Salt (chemistry)">salts</a>, such as the <a href="/wiki/Lewis_acid" class="mw-redirect" title="Lewis acid">Lewis acid</a> <a href="/wiki/Cerium(III)_trifluoromethanesulfonate" class="mw-redirect" title="Cerium(III) trifluoromethanesulfonate">cerium(III) trifluoromethanesulfonate</a>.<sup id="cite_ref-13" class="reference"><a href="#cite_note-13"><span class="cite-bracket">[</span>13<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading3"><h3 id="Organic_synthesis">Organic synthesis</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Cerium(III)_chloride&action=edit&section=3" title="Edit section: Organic synthesis"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Cerium(III) chloride is a reagent in several procedures used in organic synthesis.<sup id="cite_ref-14" class="reference"><a href="#cite_note-14"><span class="cite-bracket">[</span>14<span class="cite-bracket">]</span></a></sup> <a href="/wiki/Luche_reduction" title="Luche reduction">Luche reduction</a><sup id="cite_ref-Luche1978_15-0" class="reference"><a href="#cite_note-Luche1978-15"><span class="cite-bracket">[</span>15<span class="cite-bracket">]</span></a></sup> of alpha, beta-unsaturated carbonyl compounds has become a popular method in <a href="/wiki/Organic_synthesis" title="Organic synthesis">organic synthesis</a>, where CeCl<sub>3</sub>·7H<sub>2</sub>O is used in conjunction with <a href="/wiki/Sodium_borohydride" title="Sodium borohydride">sodium borohydride</a>. For example, <a href="/wiki/Carvone" title="Carvone">carvone</a> gives only the allylic <a href="/wiki/Alcohol_(chemistry)" title="Alcohol (chemistry)">alcohol</a> <b>1</b> and none of the <a href="/wiki/Saturated_and_unsaturated_compounds" title="Saturated and unsaturated compounds">saturated</a> <a href="/wiki/Alcohol_(chemistry)" title="Alcohol (chemistry)">alcohol</a> <b>2</b>. Without CeCl<sub>3</sub>, a mixture of <b>1</b> and <b>2</b> is formed. </p><p><span typeof="mw:File"><a href="/wiki/File:Luche_reduction.png" class="mw-file-description" title="Luche reduction"><img alt="Luche reduction" src="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/Luche_reduction.png/400px-Luche_reduction.png" decoding="async" width="400" height="152" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/a/a2/Luche_reduction.png 1.5x" data-file-width="551" data-file-height="210" /></a></span> </p><p>It can also deprotect <a href="/wiki/2-Methoxyethoxymethyl_chloride" title="2-Methoxyethoxymethyl chloride">MEM</a> group to alcohol in the presence of other acetal protecting groups (e.g. <a href="/wiki/Tetrahydropyran" title="Tetrahydropyran">THP</a>.) </p><p>Another important use in <a href="/wiki/Organic_synthesis" title="Organic synthesis">organic synthesis</a> is for alkylation of <a href="/wiki/Ketone" title="Ketone">ketones</a>, which would otherwise form <a href="/wiki/Enolate" title="Enolate">enolates</a> if simple <a href="/wiki/Organolithium_reagent" title="Organolithium reagent">organolithium reagents</a> were to be used. For example, compound <b>3</b> would be expected to simply form an enolate without CeCl<sub>3</sub> being present, but in the presence of CeCl<sub>3</sub> smooth alkylation occurs: <sup id="cite_ref-JohnsonTait1987_4-1" class="reference"><a href="#cite_note-JohnsonTait1987-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </p><p><span typeof="mw:File"><a href="/wiki/File:Cerium_alkylation.png" class="mw-file-description" title="CeCl3 directed alkylation reaction"><img alt="CeCl3 directed alkylation reaction" src="//upload.wikimedia.org/wikipedia/commons/thumb/4/4f/Cerium_alkylation.png/400px-Cerium_alkylation.png" decoding="async" width="400" height="111" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/4/4f/Cerium_alkylation.png 1.5x" data-file-width="545" data-file-height="151" /></a></span> </p><p>It is reported that organolithium reagents work more effectively in this reaction than do <a href="/wiki/Grignard_reagent" title="Grignard reagent">Grignard reagents</a>.<sup id="cite_ref-JohnsonTait1987_4-2" class="reference"><a href="#cite_note-JohnsonTait1987-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="References">References</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Cerium(III)_chloride&action=edit&section=4" title="Edit section: References"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <style data-mw-deduplicate="TemplateStyles:r1239543626">.mw-parser-output .reflist{margin-bottom:0.5em;list-style-type:decimal}@media screen{.mw-parser-output .reflist{font-size:90%}}.mw-parser-output .reflist .references{font-size:100%;margin-bottom:0;list-style-type:inherit}.mw-parser-output .reflist-columns-2{column-width:30em}.mw-parser-output .reflist-columns-3{column-width:25em}.mw-parser-output .reflist-columns{margin-top:0.3em}.mw-parser-output .reflist-columns ol{margin-top:0}.mw-parser-output .reflist-columns li{page-break-inside:avoid;break-inside:avoid-column}.mw-parser-output .reflist-upper-alpha{list-style-type:upper-alpha}.mw-parser-output .reflist-upper-roman{list-style-type:upper-roman}.mw-parser-output .reflist-lower-alpha{list-style-type:lower-alpha}.mw-parser-output .reflist-lower-greek{list-style-type:lower-greek}.mw-parser-output .reflist-lower-roman{list-style-type:lower-roman}</style><div class="reflist"> <div class="mw-references-wrap mw-references-columns"><ol class="references"> <li id="cite_note-1"><span class="mw-cite-backlink"><b><a href="#cite_ref-1">^</a></b></span> <span class="reference-text">Several great producers such as Alfa and Strem list their products simply as a "hydrate" with "<span class="texhtml mvar" style="font-style:italic;">x</span>H<sub>2</sub>O" in the formula, but Aldrich sells a heptahydrate.</span> </li> <li id="cite_note-Paquette1999-2"><span class="mw-cite-backlink">^ <a href="#cite_ref-Paquette1999_2-0"><sup><i><b>a</b></i></sup></a> <a href="#cite_ref-Paquette1999_2-1"><sup><i><b>b</b></i></sup></a></span> <span class="reference-text"><style data-mw-deduplicate="TemplateStyles:r1238218222">.mw-parser-output cite.citation{font-style:inherit;word-wrap:break-word}.mw-parser-output .citation q{quotes:"\"""\"""'""'"}.mw-parser-output .citation:target{background-color:rgba(0,127,255,0.133)}.mw-parser-output .id-lock-free.id-lock-free a{background:url("//upload.wikimedia.org/wikipedia/commons/6/65/Lock-green.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-limited.id-lock-limited a,.mw-parser-output .id-lock-registration.id-lock-registration a{background:url("//upload.wikimedia.org/wikipedia/commons/d/d6/Lock-gray-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-subscription.id-lock-subscription a{background:url("//upload.wikimedia.org/wikipedia/commons/a/aa/Lock-red-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .cs1-ws-icon a{background:url("//upload.wikimedia.org/wikipedia/commons/4/4c/Wikisource-logo.svg")right 0.1em center/12px no-repeat}body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-free a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-limited a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-registration a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-subscription a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .cs1-ws-icon a{background-size:contain;padding:0 1em 0 0}.mw-parser-output .cs1-code{color:inherit;background:inherit;border:none;padding:inherit}.mw-parser-output .cs1-hidden-error{display:none;color:var(--color-error,#d33)}.mw-parser-output .cs1-visible-error{color:var(--color-error,#d33)}.mw-parser-output .cs1-maint{display:none;color:#085;margin-left:0.3em}.mw-parser-output .cs1-kern-left{padding-left:0.2em}.mw-parser-output .cs1-kern-right{padding-right:0.2em}.mw-parser-output .citation .mw-selflink{font-weight:inherit}@media screen{.mw-parser-output .cs1-format{font-size:95%}html.skin-theme-clientpref-night .mw-parser-output .cs1-maint{color:#18911f}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .cs1-maint{color:#18911f}}</style><cite id="CITEREFPaquette1999" class="citation book cs1">Paquette, L. A. (1999). Coates, R. M.; Denmark, S. E. (eds.). <i>Handbook of Reagents for Organic Synthesis: Reagents, Auxiliaries and Catalysts for C-C Bond Formation</i>. New York: Wiley. <a href="/wiki/ISBN_(identifier)" class="mw-redirect" title="ISBN (identifier)">ISBN</a> <a href="/wiki/Special:BookSources/0-471-97924-4" title="Special:BookSources/0-471-97924-4"><bdi>0-471-97924-4</bdi></a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=book&rft.btitle=Handbook+of+Reagents+for+Organic+Synthesis%3A+Reagents%2C+Auxiliaries+and+Catalysts+for+C-C+Bond+Formation&rft.place=New+York&rft.pub=Wiley&rft.date=1999&rft.isbn=0-471-97924-4&rft.aulast=Paquette&rft.aufirst=L.+A.&rfr_id=info%3Asid%2Fen.wikipedia.org%3ACerium%28III%29+chloride" class="Z3988"></span></span> </li> <li id="cite_note-EdelmannPoremba1997-3"><span class="mw-cite-backlink">^ <a href="#cite_ref-EdelmannPoremba1997_3-0"><sup><i><b>a</b></i></sup></a> <a href="#cite_ref-EdelmannPoremba1997_3-1"><sup><i><b>b</b></i></sup></a> <a href="#cite_ref-EdelmannPoremba1997_3-2"><sup><i><b>c</b></i></sup></a></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFEdelmannPoremba,_P.1997" class="citation book cs1">Edelmann, F. T.; Poremba, P. (1997). Herrmann, W. A. (ed.). <i>Synthetic Methods of Organometallic and Inorganic Chemistry</i>. Vol. VI. 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R.; Tait, B. D. (1987). 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"Trichlorolanthanoid (LnCl<sub>3</sub>)-catalyzed Friedel-Crafts alkylation reactions". <i>Chemistry Letters</i>. <b>15</b> (3): <span class="nowrap">357–</span>360. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1246%2Fcl.1986.357">10.1246/cl.1986.357</a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.jtitle=Chemistry+Letters&rft.atitle=Trichlorolanthanoid+%28LnCl%3Csub%3E3%3C%2Fsub%3E%29-catalyzed+Friedel-Crafts+alkylation+reactions&rft.volume=15&rft.issue=3&rft.pages=%3Cspan+class%3D%22nowrap%22%3E357-%3C%2Fspan%3E360&rft.date=1986&rft_id=info%3Adoi%2F10.1246%2Fcl.1986.357&rft.aulast=Mine&rft.aufirst=Norioki&rft.au=Fujiwara%2C+Yuzo&rft.au=Taniguchi%2C+Hiroshi&rfr_id=info%3Asid%2Fen.wikipedia.org%3ACerium%28III%29+chloride" class="Z3988"></span></span> </li> <li id="cite_note-14"><span class="mw-cite-backlink"><b><a href="#cite_ref-14">^</a></b></span> <span class="reference-text"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFPaquetteSabithaYadavScheuermann2021" class="citation book cs1">Paquette, Leo A.; Sabitha, G.; Yadav, J. 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"Reduction of natural enones in the presence of cerium trichloride". <i>Journal of the Chemical Society, Chemical Communications</i> (14): <span class="nowrap">601–</span>602. <a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1039%2FC39780000601">10.1039/C39780000601</a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.jtitle=Journal+of+the+Chemical+Society%2C+Chemical+Communications&rft.atitle=Reduction+of+natural+enones+in+the+presence+of+cerium+trichloride&rft.issue=14&rft.pages=%3Cspan+class%3D%22nowrap%22%3E601-%3C%2Fspan%3E602&rft.date=1978&rft_id=info%3Adoi%2F10.1039%2FC39780000601&rft.aulast=Luche&rft.aufirst=Jean-Louis&rft.au=Rodriguez-Hahn%2C+Lydia&rft.au=Crabb%C3%A9%2C+Pierre&rfr_id=info%3Asid%2Fen.wikipedia.org%3ACerium%28III%29+chloride" class="Z3988"></span></span> </li> </ol></div></div> <div class="mw-heading mw-heading2"><h2 id="Further_reading">Further reading</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Cerium(III)_chloride&action=edit&section=5" title="Edit section: Further reading"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><i>CRC Handbook of Chemistry and Physics</i> (58th edition), CRC Press, West Palm Beach, Florida, 1977.</li> <li><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFAnwander1999" class="citation book cs1">Anwander, R. (1999). Kobayashi, S. (ed.). <a rel="nofollow" class="external text" href="https://archive.org/details/springer_10.1007-3-540-69801-9"><i>Lanthanides: Chemistry and Use in Organic Synthesis</i></a>. Berlin: Springer-Verlag. pp. <a rel="nofollow" class="external text" href="https://archive.org/details/springer_10.1007-3-540-69801-9/page/n17">10</a>–12. <a href="/wiki/ISBN_(identifier)" class="mw-redirect" title="ISBN (identifier)">ISBN</a> <a href="/wiki/Special:BookSources/9783540645269" title="Special:BookSources/9783540645269"><bdi>9783540645269</bdi></a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=book&rft.btitle=Lanthanides%3A+Chemistry+and+Use+in+Organic+Synthesis&rft.place=Berlin&rft.pages=10-12&rft.pub=Springer-Verlag&rft.date=1999&rft.isbn=9783540645269&rft.aulast=Anwander&rft.aufirst=R.&rft_id=https%3A%2F%2Farchive.org%2Fdetails%2Fspringer_10.1007-3-540-69801-9&rfr_id=info%3Asid%2Fen.wikipedia.org%3ACerium%28III%29+chloride" class="Z3988"></span></li></ul> <div class="navbox-styles"><style data-mw-deduplicate="TemplateStyles:r1129693374">.mw-parser-output .hlist dl,.mw-parser-output .hlist ol,.mw-parser-output .hlist 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.navbar{display:none!important}}</style><div class="navbar plainlinks hlist navbar-mini"><ul><li class="nv-view"><a href="/wiki/Template:Cerium_compounds" title="Template:Cerium compounds"><abbr title="View this template">v</abbr></a></li><li class="nv-talk"><a href="/wiki/Template_talk:Cerium_compounds" title="Template talk:Cerium compounds"><abbr title="Discuss this template">t</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:EditPage/Template:Cerium_compounds" title="Special:EditPage/Template:Cerium compounds"><abbr title="Edit this template">e</abbr></a></li></ul></div><div id="Cerium_compounds106" style="font-size:114%;margin:0 4em"><span style="vertical-align:1px;"><a href="/wiki/Cerium_compounds" title="Cerium compounds">Cerium compounds</a></span></div></th></tr><tr><th scope="row" class="navbox-group" style="width:1%">Cerium(II)</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Cerium_diiodide" title="Cerium diiodide">CeI<sub>2</sub></a></li> <li><a href="/wiki/Cerium_monoselenide" title="Cerium monoselenide">CeSe</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">Cerium(III)</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Cerium(III)_bromide" title="Cerium(III) bromide">CeBr<sub>3</sub></a></li> <li><a href="/wiki/Cerium(III)_carbonate" title="Cerium(III) carbonate">Ce<sub>2</sub>(CO<sub>3</sub>)<sub>3</sub></a></li> <li><a class="mw-selflink selflink">CeCl<sub>3</sub></a></li> <li><a href="/wiki/Cerium(III)_fluoride" title="Cerium(III) fluoride">CeF<sub>3</sub></a></li> <li><a href="/wiki/Cerium(III)_iodide" title="Cerium(III) iodide">CeI<sub>3</sub></a></li> <li><a href="/wiki/Cerium(III)_hydroxide" title="Cerium(III) hydroxide">Ce(OH)<sub>3</sub></a></li> <li><a href="/wiki/Cerium_nitride" title="Cerium nitride">CeN</a></li> <li><a href="/wiki/Cerium(III)_oxide" title="Cerium(III) oxide">Ce<sub>2</sub>O<sub>3</sub></a></li> <li><a href="/wiki/Cerium(III)_sulfate" title="Cerium(III) sulfate">Ce<sub>2</sub>(SO<sub>4</sub>)<sub>3</sub></a></li> <li><a href="/wiki/Cerium(III)_selenate" title="Cerium(III) selenate">Ce<sub>2</sub>(SeO<sub>4</sub>)<sub>3</sub></a></li> <li><a href="/wiki/Cerium(III)_sulfide" title="Cerium(III) sulfide">Ce<sub>2</sub>S<sub>3</sub></a></li> <li><a href="/wiki/Cerium_phosphide" title="Cerium phosphide">CeP</a></li> <li><a href="/wiki/Cerium_nitrate#Cerium(III)_nitrates" class="mw-redirect" title="Cerium nitrate">Ce(NO<sub>3</sub>)<sub>3</sub></a></li> <li><a href="/w/index.php?title=Cerium(III)_perchlorate&action=edit&redlink=1" class="new" title="Cerium(III) perchlorate (page does not exist)">Ce(ClO<sub>4</sub>)<sub>3</sub></a></li></ul> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th id="Organocerium(III)44" scope="row" class="navbox-group" style="width:1%"><a href="/wiki/Organocerium_chemistry" title="Organocerium chemistry">Organocerium(III)</a></th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Cerium(III)_acetylacetonate" title="Cerium(III) acetylacetonate">Ce(acac)<sub>3</sub></a></li> <li><a href="/wiki/Cerocene" title="Cerocene">Ce(C<sub>5</sub>H<sub>5</sub>)<sub>3</sub></a></li> <li><a href="/wiki/Cerium_oxalate" title="Cerium oxalate">Ce<sub>2</sub>(C<sub>2</sub>O<sub>4</sub>)<sub>3</sub></a></li> <li><a href="/wiki/Cerium(III)_methanesulfonate" title="Cerium(III) methanesulfonate">Ce(CH<sub>3</sub>SO<sub>3</sub>)<sub>3</sub></a></li> <li><a href="/wiki/Cerium_stearate" title="Cerium stearate"><span class="chemf nowrap">C<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">54</sub></span></span>H<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">105</sub></span></span>CeO<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">6</sub></span></span></span></a></li></ul> </div></td></tr></tbody></table><div> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">Cerium(III,IV)</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/w/index.php?title=Cerium(III,IV)_oxide&action=edit&redlink=1" class="new" title="Cerium(III,IV) oxide (page does not exist)">Ce<sub>3</sub>O<sub>4</sub></a></li> <li><a href="/wiki/Cerium_monosulfide" title="Cerium monosulfide">CeS</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">Cerium(IV)</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Ammonium_cerium(IV)_sulfate" title="Ammonium cerium(IV) sulfate">(NH<sub>4</sub>)<sub>4</sub>Ce(SO<sub>4</sub>)<sub>4</sub>·2H<sub>2</sub>O</a></li> <li><a href="/wiki/Ceric_ammonium_nitrate" title="Ceric ammonium nitrate">(NH<sub>4</sub>)<sub>2</sub>Ce(NO<sub>3</sub>)<sub>6</sub></a></li> <li><a href="/wiki/Cerium_hexaboride" title="Cerium hexaboride">CeB<sub>6</sub></a></li> <li><a href="/wiki/Cerium_nitrate#Cerium(IV)_nitrates" class="mw-redirect" title="Cerium nitrate">Ce(NO<sub>3</sub>)<sub>4</sub></a></li> <li><a href="/wiki/Cerium(IV)_hydroxide" title="Cerium(IV) hydroxide">Ce(OH)<sub>4</sub></a></li> <li><a href="/wiki/Cerium(IV)_oxide" title="Cerium(IV) oxide">CeO<sub>2</sub></a></li> <li><a href="/wiki/Cerium(IV)_sulfate" title="Cerium(IV) sulfate">Ce(SO<sub>4</sub>)<sub>2</sub></a></li> <li><a href="/wiki/Cerium(IV)_selenate" title="Cerium(IV) selenate">Ce(SeO<sub>4</sub>)<sub>2</sub></a></li> <li><a href="/wiki/Cerium(IV)_fluoride" title="Cerium(IV) fluoride">CeF<sub>4</sub></a></li> <li><a href="/wiki/Cerium(IV)_perchlorate" title="Cerium(IV) perchlorate">Ce(ClO<sub>4</sub>)<sub>4</sub></a></li></ul> </div></td></tr></tbody></table></div> <div class="navbox-styles"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1129693374"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1236075235"></div><div role="navigation" class="navbox" aria-labelledby="Salts_and_covalent_derivatives_of_the_chloride_ion136" style="display:table;;padding:3px"><table class="nowraplinks mw-collapsible autocollapse navbox-inner" style="border-spacing:0;background:transparent;color:inherit;table-layout:fixed;"><tbody><tr><th scope="col" class="navbox-title" colspan="2"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1129693374"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1239400231"><div class="navbar plainlinks hlist navbar-mini"><ul><li class="nv-view"><a href="/wiki/Template:Chlorides" title="Template:Chlorides"><abbr title="View this template">v</abbr></a></li><li class="nv-talk"><a href="/wiki/Template_talk:Chlorides" title="Template talk:Chlorides"><abbr title="Discuss this template">t</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:EditPage/Template:Chlorides" title="Special:EditPage/Template:Chlorides"><abbr title="Edit this template">e</abbr></a></li></ul></div><div id="Salts_and_covalent_derivatives_of_the_chloride_ion136" style="font-size:114%;margin:0 4em">Salts and covalent derivatives of the <a href="/wiki/Chloride" title="Chloride">chloride</a> ion</div></th></tr><tr><td colspan="2" class="navbox-list navbox-odd" style="width:100%;padding:0;border-width:0;"><div style="padding:0"><div class="mw-collapsible-content" style="overflow-x:auto"> <table class="center"> <tbody><tr style="background-color:mistyrose"> <td><a href="/wiki/Hydrogen_chloride" title="Hydrogen chloride">HCl</a> </td> <td style="background-color:white;color:inherit;border:none"> </td> <td style="background-color:white;color:inherit;border:none" colspan="11" rowspan="3"> </td> <td style="background-color:white;color:inherit;border:none" colspan="5"> </td> <td>He </td></tr> <tr style="background-color:mistyrose;color:black;"> <td><a href="/wiki/Lithium_chloride" title="Lithium chloride">LiCl</a> </td> <td><a href="/wiki/Beryllium_chloride" title="Beryllium chloride">BeCl<sub>2</sub></a> </td> <td><a href="/wiki/Boron_trichloride#Reduction" title="Boron trichloride">B<sub>4</sub>Cl<sub>4</sub></a><br /><a href="/w/index.php?title=Dodecaboron_dodecachloride&action=edit&redlink=1" class="new" title="Dodecaboron dodecachloride (page does not exist)">B<sub>12</sub>Cl<sub>12</sub></a><br /><a href="/wiki/Boron_trichloride" title="Boron trichloride">BCl<sub>3</sub></a><br /><a href="/wiki/Diboron_tetrachloride" title="Diboron tetrachloride">B<sub>2</sub>Cl<sub>4</sub></a><br /><a href="/wiki/Borate_chloride" title="Borate chloride">+BO<sub>3</sub></a> </td> <td><a href="/wiki/Dichloroacetylene" title="Dichloroacetylene">C<sub>2</sub>Cl<sub>2</sub></a><br /><a href="/wiki/Tetrachloroethylene" title="Tetrachloroethylene">C<sub>2</sub>Cl<sub>4</sub></a><br /><a href="/wiki/Hexachloroethane" title="Hexachloroethane">C<sub>2</sub>Cl<sub>6</sub></a><br /><a href="/wiki/Carbon_tetrachloride" title="Carbon tetrachloride">CCl<sub>4</sub></a><br /><a href="/wiki/Carbide_chloride" title="Carbide chloride">+C</a><br /><a href="/wiki/Carbonate_chloride" title="Carbonate chloride">+CO<sub>3</sub></a> </td> <td><a href="/wiki/Nitrogen_trichloride" title="Nitrogen trichloride">NCl<sub>3</sub></a><br /><a href="/wiki/Chlorine_azide" title="Chlorine azide">ClN<sub>3</sub></a><br /><a href="/wiki/Nitride_chloride" title="Nitride chloride">+N</a><br /><a href="/wiki/Nitrate_chlorides" title="Nitrate chlorides">+NO<sub>3</sub></a> </td> <td><a href="/wiki/Chlorine_oxide" title="Chlorine oxide">Cl<sub>x</sub>O<sub>y</sub></a><br /><a href="/wiki/Dichlorine_monoxide" title="Dichlorine monoxide">Cl<sub>2</sub>O</a><br /><a href="/wiki/Chlorine_peroxide" title="Chlorine peroxide">Cl<sub>2</sub>O<sub>2</sub></a><br /><a href="/wiki/Chlorine_monoxide" title="Chlorine monoxide">ClO</a><br /><a href="/wiki/Chlorine_dioxide" title="Chlorine dioxide">ClO<sub>2</sub></a><br /><a href="/wiki/Chlorine_perchlorate" title="Chlorine perchlorate">Cl<sub>2</sub>O<sub>4</sub></a><br /><a href="/wiki/Chloryl_perchlorate" class="mw-redirect" title="Chloryl perchlorate">Cl<sub>2</sub>O<sub>6</sub></a><br /><a href="/wiki/Dichlorine_heptoxide" title="Dichlorine heptoxide">Cl<sub>2</sub>O<sub>7</sub></a><br /><a href="/wiki/Chlorine_tetroxide" title="Chlorine tetroxide">ClO<sub>4</sub></a><br /><a href="/wiki/Oxychloride" class="mw-redirect" title="Oxychloride">+O</a> </td> <td><a href="/wiki/Chlorine_monofluoride" title="Chlorine monofluoride">ClF</a><br /><a href="/wiki/Chlorine_trifluoride" title="Chlorine trifluoride">ClF<sub>3</sub></a><br /><a href="/wiki/Chlorine_pentafluoride" title="Chlorine pentafluoride">ClF<sub>5</sub></a> </td> <td>Ne </td></tr> <tr style="background-color:mistyrose;color:black;"> <td><a href="/wiki/Sodium_chloride" title="Sodium chloride">NaCl</a> </td> <td><a href="/wiki/Magnesium_chloride" title="Magnesium chloride">MgCl<sub>2</sub></a> </td> <td><a href="/wiki/Aluminium_monochloride" title="Aluminium monochloride">AlCl</a><br /><a href="/wiki/Aluminium_chloride" title="Aluminium chloride">AlCl<sub>3</sub></a> </td> <td><a href="/w/index.php?title=Dodecachloroneopentasilane&action=edit&redlink=1" class="new" title="Dodecachloroneopentasilane (page does not exist)">Si<sub>5</sub>Cl<sub>12</sub></a><br /><a href="/wiki/Hexachlorodisilane" title="Hexachlorodisilane">Si<sub>2</sub>Cl<sub>6</sub></a><br /><a href="/wiki/Silicon_tetrachloride" title="Silicon tetrachloride">SiCl<sub>4</sub></a> </td> <td><a href="/wiki/Diphosphorus_tetrachloride" title="Diphosphorus tetrachloride">P<sub>2</sub>Cl<sub>4</sub></a><br /><a href="/wiki/Phosphorus_trichloride" title="Phosphorus trichloride">PCl<sub>3</sub></a><br /><a href="/wiki/Phosphorus_pentachloride" title="Phosphorus pentachloride">PCl<sub>5</sub></a><br /><a href="/wiki/Phosphide_chloride" title="Phosphide chloride">+P</a> </td> <td><a href="/wiki/Disulfur_dichloride" title="Disulfur dichloride">S<sub>2</sub>Cl<sub>2</sub></a><br /><a href="/wiki/Sulfur_dichloride" title="Sulfur dichloride">SCl<sub>2</sub></a><br /><a href="/wiki/Sulfur_tetrachloride" title="Sulfur tetrachloride">SCl<sub>4</sub></a><br /><a href="/wiki/Sulfate_chloride" title="Sulfate chloride">+SO<sub>4</sub></a> </td> <td><a href="/wiki/Chlorine" title="Chlorine">Cl<sub>2</sub></a> </td> <td>Ar </td></tr> <tr style="background-color:mistyrose;color:black;"> <td><a href="/wiki/Potassium_chloride" title="Potassium chloride">KCl</a> </td> <td><a href="/wiki/Calcium(I)_chloride" title="Calcium(I) chloride">CaCl</a><br /><a href="/wiki/Calcium_chloride" title="Calcium chloride">CaCl<sub>2</sub></a> </td> <td style="background-color:white;color:inherit;border:none"> </td> <td><a href="/wiki/Scandium_chloride" title="Scandium chloride">ScCl<sub>3</sub></a> </td> <td><a href="/wiki/Titanium(II)_chloride" title="Titanium(II) chloride">TiCl<sub>2</sub></a><br /><a href="/wiki/Titanium(III)_chloride" title="Titanium(III) chloride">TiCl<sub>3</sub></a><br /><a href="/wiki/Titanium_tetrachloride" title="Titanium tetrachloride">TiCl<sub>4</sub></a> </td> <td><a href="/wiki/Vanadium(II)_chloride" title="Vanadium(II) chloride">VCl<sub>2</sub></a><br /><a href="/wiki/Vanadium(III)_chloride" title="Vanadium(III) chloride">VCl<sub>3</sub></a><br /><a href="/wiki/Vanadium_tetrachloride" title="Vanadium tetrachloride">VCl<sub>4</sub></a><br /><a href="/wiki/Vanadium(V)_chloride" title="Vanadium(V) chloride">VCl<sub>5</sub></a> </td> <td><a href="/wiki/Chromium(II)_chloride" title="Chromium(II) chloride">CrCl<sub>2</sub></a><br /><a href="/wiki/Chromium(III)_chloride" title="Chromium(III) chloride">CrCl<sub>3</sub></a><br /><a href="/wiki/Chromium(IV)_chloride" title="Chromium(IV) chloride">CrCl<sub>4</sub></a> </td> <td><a href="/wiki/Manganese(II)_chloride" title="Manganese(II) chloride">MnCl<sub>2</sub></a><br /><a href="/wiki/Manganese(III)_chloride" title="Manganese(III) chloride">MnCl<sub>3</sub></a> </td> <td><a href="/wiki/Iron(II)_chloride" title="Iron(II) chloride">FeCl<sub>2</sub></a><br /><a href="/wiki/Iron(III)_chloride" title="Iron(III) chloride">FeCl<sub>3</sub></a> </td> <td><a href="/wiki/Cobalt(II)_chloride" title="Cobalt(II) chloride">CoCl<sub>2</sub></a><br /><a href="/wiki/Cobalt(III)_chloride" title="Cobalt(III) chloride">CoCl<sub>3</sub></a> </td> <td><a href="/wiki/Nickel(II)_chloride" title="Nickel(II) chloride">NiCl<sub>2</sub></a> </td> <td><a href="/wiki/Copper(I)_chloride" title="Copper(I) chloride">CuCl</a><br /><a href="/wiki/Copper(II)_chloride" title="Copper(II) chloride">CuCl<sub>2</sub></a> </td> <td><a href="/wiki/Zinc_chloride" title="Zinc chloride">ZnCl<sub>2</sub></a> </td> <td><a href="/w/index.php?title=Gallium_monochloride&action=edit&redlink=1" class="new" title="Gallium monochloride (page does not exist)">GaCl</a><br /><a href="/wiki/Gallium_trichloride" class="mw-redirect" title="Gallium trichloride">GaCl<sub>3</sub></a> </td> <td><a href="/wiki/Germanium_dichloride" title="Germanium dichloride">GeCl<sub>2</sub></a><br /><a href="/wiki/Germanium_tetrachloride" title="Germanium tetrachloride">GeCl<sub>4</sub></a> </td> <td><a href="/wiki/Arsenic_trichloride" title="Arsenic trichloride">AsCl<sub>3</sub></a><br /><a href="/wiki/Arsenic_pentachloride" title="Arsenic pentachloride">AsCl<sub>5</sub></a><br /><a href="/wiki/Arsenide_chloride" title="Arsenide chloride">+As</a> </td> <td><a href="/wiki/Selenium_monochloride" title="Selenium monochloride">Se<sub>2</sub>Cl<sub>2</sub></a><br /><a href="/wiki/Selenium_dichloride" title="Selenium dichloride">SeCl<sub>2</sub></a><br /><a href="/wiki/Selenium_tetrachloride" title="Selenium tetrachloride">SeCl<sub>4</sub></a> </td> <td><a href="/wiki/Bromine_monochloride" title="Bromine monochloride">BrCl</a> </td> <td>Kr </td></tr> <tr style="background-color:mistyrose;color:black;"> <td><a href="/wiki/Rubidium_chloride" title="Rubidium chloride">RbCl</a> </td> <td><a href="/wiki/Strontium_chloride" title="Strontium chloride">SrCl<sub>2</sub></a> </td> <td style="background-color:white;color:inherit;border:none"> </td> <td><a href="/wiki/Yttrium(III)_chloride" title="Yttrium(III) chloride">YCl<sub>3</sub></a> </td> <td><a href="/wiki/Zirconium(II)_chloride" class="mw-redirect" title="Zirconium(II) chloride">ZrCl<sub>2</sub></a><br /><a href="/wiki/Zirconium(III)_chloride" title="Zirconium(III) chloride">ZrCl<sub>3</sub></a><br /><a href="/wiki/Zirconium(IV)_chloride" title="Zirconium(IV) chloride">ZrCl<sub>4</sub></a> </td> <td><a href="/wiki/Niobium(III)_chloride" title="Niobium(III) chloride">NbCl<sub>3</sub></a><br /><a href="/wiki/Niobium(IV)_chloride" title="Niobium(IV) chloride">NbCl<sub>4</sub></a><br /><a href="/wiki/Niobium(V)_chloride" title="Niobium(V) chloride">NbCl<sub>5</sub></a> </td> <td><a href="/wiki/Molybdenum(II)_chloride" title="Molybdenum(II) chloride">MoCl<sub>2</sub></a><br /><a href="/wiki/Molybdenum(III)_chloride" title="Molybdenum(III) chloride">MoCl<sub>3</sub></a><br /><a href="/wiki/Molybdenum_tetrachloride" title="Molybdenum tetrachloride">MoCl<sub>4</sub></a><br /><a href="/wiki/Molybdenum(V)_chloride" title="Molybdenum(V) chloride">MoCl<sub>5</sub></a><br /><a href="/wiki/Molybdenum(VI)_chloride" title="Molybdenum(VI) chloride">MoCl<sub>6</sub></a> </td> <td><a href="/wiki/Technetium_trichloride" class="mw-redirect" title="Technetium trichloride">TcCl<sub>3</sub></a><br /><a href="/wiki/Technetium(IV)_chloride" title="Technetium(IV) chloride">TcCl<sub>4</sub></a> </td> <td><a href="/wiki/Ruthenium(II)_chloride" title="Ruthenium(II) chloride">RuCl<sub>2</sub></a><br /><a href="/wiki/Ruthenium(III)_chloride" title="Ruthenium(III) chloride">RuCl<sub>3</sub></a><br /><a href="/wiki/Ruthenium_tetrachloride" title="Ruthenium tetrachloride">RuCl<sub>4</sub></a> </td> <td><a href="/wiki/Rhodium(III)_chloride" title="Rhodium(III) chloride">RhCl<sub>3</sub></a> </td> <td><a href="/wiki/Palladium(II)_chloride" title="Palladium(II) chloride">PdCl<sub>2</sub></a> </td> <td><a href="/wiki/Silver_chloride" title="Silver chloride">AgCl</a> </td> <td><a href="/wiki/Cadmium_chloride" title="Cadmium chloride">CdCl<sub>2</sub></a> </td> <td><a href="/wiki/Indium(I)_chloride" title="Indium(I) chloride">InCl</a><br /><a href="/wiki/Indium(II)_chloride" title="Indium(II) chloride">InCl<sub>2</sub></a><br /><a href="/wiki/Indium(III)_chloride" title="Indium(III) chloride">InCl<sub>3</sub></a> </td> <td><a href="/wiki/Tin(II)_chloride" title="Tin(II) chloride">SnCl<sub>2</sub></a><br /><a href="/wiki/Tin(IV)_chloride" title="Tin(IV) chloride">SnCl<sub>4</sub></a> </td> <td><a href="/wiki/Antimony_trichloride" title="Antimony trichloride">SbCl<sub>3</sub></a><br /><a href="/wiki/Antimony_pentachloride" title="Antimony pentachloride">SbCl<sub>5</sub></a> </td> <td><a href="/wiki/Tritellurium_dichloride" title="Tritellurium dichloride">Te<sub>3</sub>Cl<sub>2</sub></a><br /><a href="/wiki/Tellurium_dichloride" title="Tellurium dichloride">TeCl<sub>2</sub></a><br /><a href="/wiki/Tellurium_tetrachloride" title="Tellurium tetrachloride">TeCl<sub>4</sub></a> </td> <td><a href="/wiki/Iodine_monochloride" title="Iodine monochloride">ICl</a><br /><a href="/wiki/Iodine_trichloride" title="Iodine trichloride">ICl<sub>3</sub></a> </td> <td><a href="/wiki/Xenon_monochloride" title="Xenon monochloride">XeCl</a><br /><a href="/wiki/Xenon_dichloride" title="Xenon dichloride">XeCl<sub>2</sub></a><br /><a href="/wiki/Xenon_tetrachloride" title="Xenon tetrachloride">XeCl<sub>4</sub></a> </td></tr> <tr style="background-color:mistyrose;color:black;"> <td><a href="/wiki/Caesium_chloride" title="Caesium chloride">CsCl</a> </td> <td><a href="/wiki/Barium_chloride" title="Barium chloride">BaCl<sub>2</sub></a> </td> <td style="background-color:white;color:inherit;border:none">* </td> <td><a href="/wiki/Lutetium(III)_chloride" title="Lutetium(III) chloride">LuCl<sub>3</sub></a> </td> <td><a href="/wiki/Hafnium_tetrachloride" title="Hafnium tetrachloride">HfCl<sub>4</sub></a> </td> <td><a href="/wiki/Tantalum(III)_chloride" title="Tantalum(III) chloride">TaCl<sub>3</sub></a><br /><a href="/w/index.php?title=Tantalum(IV)_chloride&action=edit&redlink=1" class="new" title="Tantalum(IV) chloride (page does not exist)">TaCl<sub>4</sub></a><br /><a href="/wiki/Tantalum(V)_chloride" title="Tantalum(V) chloride">TaCl<sub>5</sub></a> </td> <td><a href="/wiki/Tungsten(II)_chloride" title="Tungsten(II) chloride">WCl<sub>2</sub></a><br /><a href="/wiki/Tungsten(III)_chloride" title="Tungsten(III) chloride">WCl<sub>3</sub></a><br /><a href="/wiki/Tungsten(IV)_chloride" title="Tungsten(IV) chloride">WCl<sub>4</sub></a><br /><a href="/wiki/Tungsten(V)_chloride" title="Tungsten(V) chloride">WCl<sub>5</sub></a><br /><a href="/wiki/Tungsten_hexachloride" title="Tungsten hexachloride">WCl<sub>6</sub></a> </td> <td><a href="/wiki/Rhenium(III)_chloride" class="mw-redirect" title="Rhenium(III) chloride">ReCl<sub>3</sub></a><br /><a href="/wiki/Rhenium(IV)_chloride" title="Rhenium(IV) chloride">ReCl<sub>4</sub></a><br /><a href="/wiki/Rhenium_pentachloride" title="Rhenium pentachloride">ReCl<sub>5</sub></a><br /><a href="/wiki/Rhenium(VI)_chloride" title="Rhenium(VI) chloride">ReCl<sub>6</sub></a> </td> <td><a href="/wiki/Osmium(II)_chloride" title="Osmium(II) chloride">OsCl<sub>2</sub></a><br /><a href="/wiki/Osmium(III)_chloride" title="Osmium(III) chloride">OsCl<sub>3</sub></a><br /><a href="/wiki/Osmium(IV)_chloride" title="Osmium(IV) chloride">OsCl<sub>4</sub></a><br /><a href="/wiki/Osmium(V)_chloride" title="Osmium(V) chloride">OsCl<sub>5</sub></a> </td> <td><a href="/wiki/Iridium(II)_chloride" title="Iridium(II) chloride">IrCl<sub>2</sub></a><br /><a href="/wiki/Iridium(III)_chloride" title="Iridium(III) chloride">IrCl<sub>3</sub></a><br /><a href="/wiki/Iridium_tetrachloride" title="Iridium tetrachloride">IrCl<sub>4</sub></a> </td> <td><a href="/wiki/Platinum(II)_chloride" title="Platinum(II) chloride">PtCl<sub>2</sub></a><br /><a href="/wiki/Platinum(IV)_chloride" title="Platinum(IV) chloride">PtCl<sub>4</sub></a> </td> <td><a href="/wiki/Gold(I)_chloride" title="Gold(I) chloride">AuCl</a><br /><a href="/wiki/Gold(I,III)_chloride" title="Gold(I,III) chloride">(Au[AuCl<sub>4</sub>])<sub>2</sub></a><br /><a href="/wiki/Gold(III)_chloride" title="Gold(III) chloride">AuCl<sub>3</sub></a> </td> <td><a href="/wiki/Mercury(I)_chloride" title="Mercury(I) chloride">Hg<sub>2</sub>Cl<sub>2</sub></a><br /><a href="/wiki/Mercury(II)_chloride" title="Mercury(II) chloride">HgCl<sub>2</sub></a> </td> <td><a href="/wiki/Thallium(I)_chloride" title="Thallium(I) chloride">TlCl</a><br /><a href="/wiki/Thallium_trichloride" class="mw-redirect" title="Thallium trichloride">TlCl<sub>3</sub></a> </td> <td><a href="/wiki/Lead(II)_chloride" title="Lead(II) chloride">PbCl<sub>2</sub></a><br /><a href="/wiki/Lead(IV)_chloride" title="Lead(IV) chloride">PbCl<sub>4</sub></a> </td> <td><a href="/wiki/Bismuth_chloride" title="Bismuth chloride">BiCl<sub>3</sub></a> </td> <td><a href="/wiki/Polonium_dichloride" title="Polonium dichloride">PoCl<sub>2</sub></a><br /><a href="/wiki/Polonium_tetrachloride" title="Polonium tetrachloride">PoCl<sub>4</sub></a> </td> <td><a href="/wiki/Astatine_monochloride" class="mw-redirect" title="Astatine monochloride">AtCl</a> </td> <td>Rn </td></tr> <tr style="background-color:mistyrose;color:black;"> <td><a href="/wiki/Francium_chloride" title="Francium chloride">FrCl</a> </td> <td><a href="/wiki/Radium_chloride" title="Radium chloride">RaCl<sub>2</sub></a> </td> <td style="background-color:white;color:inherit;border:none">** </td> <td><a href="/wiki/Lawrencium#Chemical" title="Lawrencium">LrCl<sub>3</sub></a> </td> <td><a href="/wiki/Rutherfordium#Experimental_chemistry" title="Rutherfordium">RfCl<sub>4</sub></a> </td> <td><a href="/wiki/Dubnium#Experimental_chemistry" title="Dubnium">DbCl<sub>5</sub></a> </td> <td><a href="/wiki/Seaborgium#Experimental_chemistry" title="Seaborgium">SgO<sub>2</sub>Cl<sub>2</sub></a> </td> <td><a href="/wiki/Bohrium#Experimental_chemistry" title="Bohrium">BhO<sub>3</sub>Cl</a> </td> <td>Hs </td> <td>Mt </td> <td>Ds </td> <td>Rg </td> <td>Cn </td> <td>Nh </td> <td>Fl </td> <td>Mc </td> <td>Lv </td> <td>Ts </td> <td>Og </td></tr> <tr> <td style="background-color:white;color:inherit;border:none" colspan="2" rowspan="3"> </td> <td style="background-color:white;color:inherit;border:none" colspan="20">  </td></tr> <tr style="background-color:mistyrose;color:black;"> <td style="background-color:white;color:inherit;border:none">* </td> <td><a href="/wiki/Lanthanum(III)_chloride" title="Lanthanum(III) chloride">LaCl<sub>3</sub></a> </td> <td><a class="mw-selflink selflink">CeCl<sub>3</sub></a> </td> <td><a href="/wiki/Praseodymium(III)_chloride" title="Praseodymium(III) chloride">PrCl<sub>3</sub></a> </td> <td><a href="/wiki/Neodymium(II)_chloride" title="Neodymium(II) chloride">NdCl<sub>2</sub></a><br /><a href="/wiki/Neodymium(III)_chloride" title="Neodymium(III) chloride">NdCl<sub>3</sub></a> </td> <td><a href="/wiki/Promethium(III)_chloride" title="Promethium(III) chloride">PmCl<sub>3</sub></a> </td> <td><a href="/wiki/Samarium(II)_chloride" title="Samarium(II) chloride">SmCl<sub>2</sub></a><br /><a href="/wiki/Samarium(III)_chloride" title="Samarium(III) chloride">SmCl<sub>3</sub></a> </td> <td><a href="/wiki/Europium_dichloride" class="mw-redirect" title="Europium dichloride">EuCl<sub>2</sub></a><br /><a href="/wiki/Europium(III)_chloride" title="Europium(III) chloride">EuCl<sub>3</sub></a> </td> <td><a href="/wiki/Gadolinium(III)_chloride" title="Gadolinium(III) chloride">GdCl<sub>3</sub></a> </td> <td><a href="/wiki/Terbium(III)_chloride" title="Terbium(III) chloride">TbCl<sub>3</sub></a> </td> <td><a href="/wiki/Dysprosium(II)_chloride" title="Dysprosium(II) chloride">DyCl<sub>2</sub></a><br /><a href="/wiki/Dysprosium(III)_chloride" title="Dysprosium(III) chloride">DyCl<sub>3</sub></a> </td> <td><a href="/wiki/Holmium(III)_chloride" title="Holmium(III) chloride">HoCl<sub>3</sub></a> </td> <td><a href="/wiki/Erbium(III)_chloride" title="Erbium(III) chloride">ErCl<sub>3</sub></a> </td> <td><a href="/wiki/Thulium(II)_chloride" title="Thulium(II) chloride">TmCl<sub>2</sub></a><br /><a href="/wiki/Thulium(III)_chloride" title="Thulium(III) chloride">TmCl<sub>3</sub></a> </td> <td><a href="/wiki/Ytterbium(II)_chloride" title="Ytterbium(II) chloride">YbCl<sub>2</sub></a><br /><a href="/wiki/Ytterbium(III)_chloride" title="Ytterbium(III) chloride">YbCl<sub>3</sub></a> </td></tr> <tr style="background-color:mistyrose;color:black;"> <td style="background-color:white;color:inherit;border:none">** </td> <td><a href="/wiki/Actinium(III)_chloride" title="Actinium(III) chloride">AcCl<sub>3</sub></a> </td> <td><a href="/wiki/Thorium(III)_chloride" class="mw-redirect" title="Thorium(III) chloride">ThCl<sub>3</sub></a><br /><a href="/wiki/Thorium(IV)_chloride" title="Thorium(IV) chloride">ThCl<sub>4</sub></a> </td> <td><a href="/wiki/Protactinium(IV)_chloride" title="Protactinium(IV) chloride">PaCl<sub>4</sub></a><br /><a href="/wiki/Protactinium(V)_chloride" title="Protactinium(V) chloride">PaCl<sub>5</sub></a> </td> <td><a href="/wiki/Uranium(III)_chloride" title="Uranium(III) chloride">UCl<sub>3</sub></a><br /><a href="/wiki/Uranium_tetrachloride" title="Uranium tetrachloride">UCl<sub>4</sub></a><br /><a href="/wiki/Uranium_pentachloride" title="Uranium pentachloride">UCl<sub>5</sub></a><br /><a href="/wiki/Uranium_hexachloride" title="Uranium hexachloride">UCl<sub>6</sub></a> </td> <td><a href="/wiki/Neptunium(III)_chloride" title="Neptunium(III) chloride">NpCl<sub>3</sub></a> </td> <td><a href="/wiki/Plutonium(III)_chloride" title="Plutonium(III) chloride">PuCl<sub>3</sub></a> </td> <td><a href="/wiki/Americium(II)_chloride" title="Americium(II) chloride">AmCl<sub>2</sub></a><br /><a href="/wiki/Americium(III)_chloride" title="Americium(III) chloride">AmCl<sub>3</sub></a> </td> <td><a href="/wiki/Curium(III)_chloride" title="Curium(III) chloride">CmCl<sub>3</sub></a> </td> <td><a href="/wiki/Berkelium(III)_chloride" title="Berkelium(III) chloride">BkCl<sub>3</sub></a> </td> <td><a href="/wiki/Californium(III)_chloride" title="Californium(III) chloride">CfCl<sub>3</sub></a><br /><a href="/wiki/Californium_dichloride" title="Californium dichloride"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1123817410"><span class="chemf nowrap">CfCl<sub class="template-chem2-sub">2</sub></span></a> </td> <td><a href="/wiki/Einsteinium(II)_chloride" title="Einsteinium(II) chloride">EsCl<sub>2</sub></a><br /><a href="/wiki/Einsteinium(III)_chloride" title="Einsteinium(III) chloride">EsCl<sub>3</sub></a> </td> <td><a href="/wiki/Fermium#Chemistry" title="Fermium">FmCl<sub>2</sub></a> </td> <td><a href="/wiki/Mendelevium#Chemical" title="Mendelevium">MdCl<sub>2</sub></a> </td> <td><a href="/wiki/Nobelium#Chemical" title="Nobelium">NoCl<sub>2</sub></a> </td></tr></tbody></table></div> </div></td></tr></tbody></table></div> <div class="navbox-styles"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1129693374"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1236075235"></div><div role="navigation" class="navbox" aria-labelledby="Lanthanide_salts_of_halides131" style="display:table;;padding:3px"><table class="nowraplinks mw-collapsible mw-collapsed navbox-inner" style="border-spacing:0;background:transparent;color:inherit"><tbody><tr><th scope="col" class="navbox-title" colspan="2"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1129693374"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1239400231"><div class="navbar plainlinks hlist navbar-mini"><ul><li class="nv-view"><a href="/wiki/Template:Lanthanide_halides" title="Template:Lanthanide halides"><abbr title="View this template">v</abbr></a></li><li class="nv-talk"><a href="/wiki/Template_talk:Lanthanide_halides" title="Template talk:Lanthanide halides"><abbr title="Discuss this template">t</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:EditPage/Template:Lanthanide_halides" title="Special:EditPage/Template:Lanthanide halides"><abbr title="Edit this template">e</abbr></a></li></ul></div><div id="Lanthanide_salts_of_halides131" style="font-size:114%;margin:0 4em"><a href="/wiki/Lanthanide" title="Lanthanide">Lanthanide</a> <a href="/wiki/Salt_(chemistry)" title="Salt (chemistry)">salts</a> of <a href="/wiki/Halide" title="Halide">halides</a></div></th></tr><tr><td colspan="2" class="navbox-list navbox-odd" style="width:100%;padding:0;border-width:0;"><div style="padding:0"> <table style="width:100%"> <tbody><tr style="background-color:rose;"> <td> </td> <td><a href="/wiki/Lanthanum" title="Lanthanum">La</a> </td> <td><a href="/wiki/Cerium" title="Cerium">Ce</a> </td> <td><a href="/wiki/Praseodymium" title="Praseodymium">Pr</a> </td> <td><a href="/wiki/Neodymium" title="Neodymium">Nd</a> </td> <td><a href="/wiki/Promethium" title="Promethium">Pm</a> </td> <td><a href="/wiki/Samarium" title="Samarium">Sm</a> </td> <td><a href="/wiki/Europium" title="Europium">Eu</a> </td> <td><a href="/wiki/Gadolinium" title="Gadolinium">Gd</a> </td> <td><a href="/wiki/Terbium" title="Terbium">Tb</a> </td> <td><a href="/wiki/Dysprosium" title="Dysprosium">Dy</a> </td> <td><a href="/wiki/Holmium" title="Holmium">Ho</a> </td> <td><a href="/wiki/Erbium" title="Erbium">Er</a> </td> <td><a href="/wiki/Thulium" title="Thulium">Tm</a> </td> <td><a href="/wiki/Ytterbium" title="Ytterbium">Yb</a> </td> <td><a href="/wiki/Lutetium" title="Lutetium">Lu</a> </td></tr> <tr style="background-color:mistyrose;"> <td>+4 </td> <td> </td> <td><a href="/wiki/Cerium(IV)_fluoride" title="Cerium(IV) fluoride">CeF<sub>4</sub></a> </td> <td><a href="/wiki/Praseodymium(IV)_fluoride" title="Praseodymium(IV) fluoride">PrF<sub>4</sub></a> </td> <td><a href="/w/index.php?title=Neodymium(IV)_fluoride&action=edit&redlink=1" class="new" title="Neodymium(IV) fluoride (page does not exist)">NdF<sub>4</sub></a> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td><a href="/wiki/Terbium(IV)_fluoride" title="Terbium(IV) fluoride">TbF<sub>4</sub></a> </td> <td><a href="/w/index.php?title=Dysprosium(IV)_fluoride&action=edit&redlink=1" class="new" title="Dysprosium(IV) fluoride (page does not exist)">DyF<sub>4</sub></a> </td> <td> </td> <td> </td> <td> </td> <td> </td> <td> </td></tr> <tr style="background-color:mistyrose;"> <td>+3 </td> <td><a href="/wiki/Lanthanum_trifluoride" title="Lanthanum trifluoride">LaF<sub>3</sub></a><br /><a href="/wiki/Lanthanum(III)_chloride" title="Lanthanum(III) chloride">LaCl<sub>3</sub></a><br /><a href="/wiki/Lanthanum(III)_bromide" title="Lanthanum(III) bromide">LaBr<sub>3</sub></a><br /><a href="/wiki/Lanthanum(III)_iodide" title="Lanthanum(III) iodide">LaI<sub>3</sub></a> </td> <td><a href="/wiki/Cerium(III)_fluoride" title="Cerium(III) fluoride">CeF<sub>3</sub></a><br /><a class="mw-selflink selflink">CeCl<sub>3</sub></a><br /><a href="/wiki/Cerium(III)_bromide" title="Cerium(III) bromide">CeBr<sub>3</sub></a><br /><a href="/wiki/Cerium(III)_iodide" title="Cerium(III) iodide">CeI<sub>3</sub></a> </td> <td><a href="/wiki/Praseodymium(III)_fluoride" title="Praseodymium(III) fluoride">PrF<sub>3</sub></a><br /><a href="/wiki/Praseodymium(III)_chloride" title="Praseodymium(III) chloride">PrCl<sub>3</sub></a><br /><a href="/wiki/Praseodymium(III)_bromide" title="Praseodymium(III) bromide">PrBr<sub>3</sub></a><br /><a href="/wiki/Praseodymium(III)_iodide" title="Praseodymium(III) iodide">PrI<sub>3</sub></a> </td> <td><a href="/wiki/Neodymium(III)_fluoride" title="Neodymium(III) fluoride">NdF<sub>3</sub></a><br /><a href="/wiki/Neodymium(III)_chloride" title="Neodymium(III) chloride">NdCl<sub>3</sub></a><br /><a href="/wiki/Neodymium(III)_bromide" title="Neodymium(III) bromide">NdBr<sub>3</sub></a><br /><a href="/wiki/Neodymium(III)_iodide" title="Neodymium(III) iodide">NdI<sub>3</sub></a> </td> <td><a href="/wiki/Promethium(III)_fluoride" title="Promethium(III) fluoride">PmF<sub>3</sub></a><br /><a href="/wiki/Promethium(III)_chloride" title="Promethium(III) chloride">PmCl<sub>3</sub></a><br /><a href="/wiki/Promethium(III)_bromide" title="Promethium(III) bromide">PmBr<sub>3</sub></a><br /><a href="/wiki/Promethium(III)_iodide" title="Promethium(III) iodide">PmI<sub>3</sub></a> </td> <td><a href="/wiki/Samarium(III)_fluoride" title="Samarium(III) fluoride">SmF<sub>3</sub></a><br /><a href="/wiki/Samarium(III)_chloride" title="Samarium(III) chloride">SmCl<sub>3</sub></a><br /><a href="/wiki/Samarium(III)_bromide" title="Samarium(III) bromide">SmBr<sub>3</sub></a><br /><a href="/wiki/Samarium(III)_iodide" title="Samarium(III) iodide">SmI<sub>3</sub></a> </td> <td><a href="/wiki/Europium(III)_fluoride" title="Europium(III) fluoride">EuF<sub>3</sub></a><br /><a href="/wiki/Europium(III)_chloride" title="Europium(III) chloride">EuCl<sub>3</sub></a><br /><a href="/wiki/Europium(III)_bromide" title="Europium(III) bromide">EuBr<sub>3</sub></a><br /><a href="/wiki/Europium(III)_iodide" title="Europium(III) iodide">EuI<sub>3</sub></a> </td> <td><a href="/wiki/Gadolinium(III)_fluoride" title="Gadolinium(III) fluoride">GdF<sub>3</sub></a><br /><a href="/wiki/Gadolinium(III)_chloride" title="Gadolinium(III) chloride">GdCl<sub>3</sub></a><br /><a href="/wiki/Gadolinium(III)_bromide" title="Gadolinium(III) bromide">GdBr<sub>3</sub></a><br /><a href="/wiki/Gadolinium(III)_iodide" title="Gadolinium(III) iodide">GdI<sub>3</sub></a> </td> <td><a href="/wiki/Terbium(III)_fluoride" title="Terbium(III) fluoride">TbF<sub>3</sub></a><br /><a href="/wiki/Terbium(III)_chloride" title="Terbium(III) chloride">TbCl<sub>3</sub></a><br /><a href="/wiki/Terbium(III)_bromide" title="Terbium(III) bromide">TbBr<sub>3</sub></a><br /><a href="/wiki/Terbium(III)_iodide" title="Terbium(III) iodide">TbI<sub>3</sub></a> </td> <td><a href="/wiki/Dysprosium(III)_fluoride" title="Dysprosium(III) fluoride">DyF<sub>3</sub></a><br /><a href="/wiki/Dysprosium(III)_chloride" title="Dysprosium(III) chloride">DyCl<sub>3</sub></a><br /><a href="/wiki/Dysprosium(III)_bromide" title="Dysprosium(III) bromide">DyBr<sub>3</sub></a><br /><a href="/wiki/Dysprosium(III)_iodide" title="Dysprosium(III) iodide">DyI<sub>3</sub></a> </td> <td><a href="/wiki/Holmium(III)_fluoride" title="Holmium(III) fluoride">HoF<sub>3</sub></a><br /><a href="/wiki/Holmium(III)_chloride" title="Holmium(III) chloride">HoCl<sub>3</sub></a><br /><a href="/wiki/Holmium(III)_bromide" title="Holmium(III) bromide">HoBr<sub>3</sub></a><br /><a href="/wiki/Holmium(III)_iodide" title="Holmium(III) iodide">HoI<sub>3</sub></a> </td> <td><a href="/wiki/Erbium(III)_fluoride" title="Erbium(III) fluoride">ErF<sub>3</sub></a><br /><a href="/wiki/Erbium(III)_chloride" title="Erbium(III) chloride">ErCl<sub>3</sub></a><br /><a href="/wiki/Erbium(III)_bromide" title="Erbium(III) bromide">ErBr<sub>3</sub></a><br /><a href="/wiki/Erbium(III)_iodide" title="Erbium(III) iodide">ErI<sub>3</sub></a> </td> <td><a href="/wiki/Thulium(III)_fluoride" title="Thulium(III) fluoride">TmF<sub>3</sub></a><br /><a href="/wiki/Thulium(III)_chloride" title="Thulium(III) chloride">TmCl<sub>3</sub></a><br /><a href="/wiki/Thulium(III)_bromide" title="Thulium(III) bromide">TmBr<sub>3</sub></a><br /><a href="/wiki/Thulium(III)_iodide" title="Thulium(III) iodide">TmI<sub>3</sub></a> </td> <td><a href="/wiki/Ytterbium(III)_fluoride" title="Ytterbium(III) fluoride">YbF<sub>3</sub></a><br /><a href="/wiki/Ytterbium(III)_chloride" title="Ytterbium(III) chloride">YbCl<sub>3</sub></a><br /><a href="/wiki/Ytterbium(III)_bromide" title="Ytterbium(III) bromide">YbBr<sub>3</sub></a><br /><a href="/wiki/Ytterbium(III)_iodide" title="Ytterbium(III) iodide">YbI<sub>3</sub></a> </td> <td><a href="/wiki/Lutetium(III)_fluoride" title="Lutetium(III) fluoride">LuF<sub>3</sub></a><br /><a href="/wiki/Lutetium(III)_chloride" title="Lutetium(III) chloride">LuCl<sub>3</sub></a><br /><a href="/wiki/Lutetium(III)_bromide" title="Lutetium(III) bromide">LuBr<sub>3</sub></a><br /><a href="/wiki/Lutetium(III)_iodide" title="Lutetium(III) iodide">LuI<sub>3</sub></a> </td></tr> <tr style="background-color:mistyrose;"> <td>+2 </td> <td><a href="/wiki/Lanthanum_diiodide" title="Lanthanum diiodide">LaI<sub>2</sub></a> </td> <td><a href="/wiki/Cerium_diiodide" title="Cerium diiodide">CeI<sub>2</sub></a> </td> <td><a href="/wiki/Praseodymium_diiodide" title="Praseodymium diiodide">PrI<sub>2</sub></a> </td> <td><a href="/wiki/Neodymium(II)_fluoride" title="Neodymium(II) fluoride">NdF<sub>2</sub></a><br /><a href="/wiki/Neodymium(II)_chloride" title="Neodymium(II) chloride">NdCl<sub>2</sub></a><br /><a href="/wiki/Neodymium(II)_bromide" title="Neodymium(II) bromide">NdBr<sub>2</sub></a><br /><a href="/wiki/Neodymium(II)_iodide" title="Neodymium(II) iodide">NdI<sub>2</sub></a> </td> <td> </td> <td><a href="/wiki/Samarium(II)_fluoride" title="Samarium(II) fluoride">SmF<sub>2</sub></a><br /><a href="/wiki/Samarium(II)_chloride" title="Samarium(II) chloride">SmCl<sub>2</sub></a><br /><a href="/wiki/Samarium(II)_bromide" title="Samarium(II) bromide">SmBr<sub>2</sub></a><br /><a href="/wiki/Samarium(II)_iodide" title="Samarium(II) iodide">SmI<sub>2</sub></a> </td> <td><a href="/wiki/Europium(II)_fluoride" title="Europium(II) fluoride">EuF<sub>2</sub></a><br /><a href="/wiki/Europium_dichloride" class="mw-redirect" title="Europium dichloride">EuCl<sub>2</sub></a><br /><a href="/wiki/Europium(II)_bromide" title="Europium(II) bromide">EuBr<sub>2</sub></a><br /><a href="/wiki/Europium(II)_iodide" title="Europium(II) iodide">EuI<sub>2</sub></a> </td> <td><a href="/wiki/Gadolinium_diiodide" title="Gadolinium diiodide">GdI<sub>2</sub></a> </td> <td> </td> <td><a href="/w/index.php?title=Dysprosium(II)_fluoride&action=edit&redlink=1" class="new" title="Dysprosium(II) fluoride (page does not exist)">DyF<sub>2</sub></a><br /><a href="/wiki/Dysprosium(II)_chloride" title="Dysprosium(II) chloride">DyCl<sub>2</sub></a><br /><a href="/w/index.php?title=Dysprosium(II)_bromide&action=edit&redlink=1" class="new" title="Dysprosium(II) bromide (page does not exist)">DyBr<sub>2</sub></a><br /><a href="/wiki/Dysprosium(II)_iodide" title="Dysprosium(II) iodide">DyI<sub>2</sub></a> </td> <td> </td> <td> </td> <td><a href="/wiki/Thulium(II)_fluoride" title="Thulium(II) fluoride">TmF<sub>2</sub></a><br /><a href="/wiki/Thulium(II)_chloride" title="Thulium(II) chloride">TmCl<sub>2</sub></a><br /><a href="/wiki/Thulium(II)_bromide" class="mw-redirect" title="Thulium(II) bromide">TmBr<sub>2</sub></a><br /><a href="/wiki/Thulium(II)_iodide" title="Thulium(II) iodide">TmI<sub>2</sub></a> </td> <td><a href="/wiki/Ytterbium(II)_fluoride" title="Ytterbium(II) fluoride">YbF<sub>2</sub></a><br /><a href="/wiki/Ytterbium(II)_chloride" title="Ytterbium(II) chloride">YbCl<sub>2</sub></a><br /><a href="/wiki/Ytterbium(II)_bromide" title="Ytterbium(II) bromide">YbBr<sub>2</sub></a><br /><a href="/wiki/Ytterbium(II)_iodide" title="Ytterbium(II) iodide">YbI<sub>2</sub></a> </td> <td> </td></tr></tbody></table> </div></td></tr></tbody></table></div>    </div><noscript><img src="https://login.wikimedia.org/wiki/Special:CentralAutoLogin/start?useformat=desktop&type=1x1&usesul3=0" alt="" width="1" height="1" style="border: none; position: absolute;"></noscript> <div class="printfooter" data-nosnippet="">Retrieved from "<a dir="ltr" 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