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pyrolysis</title> <meta name="description" content="Search results for: pyrolysis"> <meta name="keywords" content="pyrolysis"> <meta name="viewport" content="width=device-width, initial-scale=1, minimum-scale=1, maximum-scale=1, user-scalable=no"> <meta charset="utf-8"> <link href="https://cdn.waset.org/favicon.ico" type="image/x-icon" rel="shortcut icon"> <link href="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/css/bootstrap.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/plugins/fontawesome/css/all.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/css/site.css?v=150220211555" rel="stylesheet"> </head> <body> <header> <div class="container"> <nav class="navbar navbar-expand-lg navbar-light"> <a class="navbar-brand" href="https://waset.org"> <img src="https://cdn.waset.org/static/images/wasetc.png" alt="Open Science Research Excellence" title="Open Science Research Excellence" /> </a> <button class="d-block d-lg-none navbar-toggler ml-auto" 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id="custom-search-input"> <div class="input-group"> <i class="fas fa-search"></i> <input type="text" class="search-query" name="q" placeholder="Author, Title, Abstract, Keywords" value="pyrolysis"> <input type="submit" class="btn_search" value="Search"> </div> </div> </form> </div> </div> <div class="row mt-3"> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Commenced</strong> in January 2007</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Frequency:</strong> Monthly</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Edition:</strong> International</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Paper Count:</strong> 125</div> </div> </div> </div> <h1 class="mt-3 mb-3 text-center" style="font-size:1.6rem;">Search results for: pyrolysis</h1> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">125</span> Pyrolysis of Dursunbey Lignite and Pyrolysis Kinetics</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=H.%20S%C3%BCt%C3%A7%C3%BC">H. Sütçü</a>, <a href="https://publications.waset.org/abstracts/search?q=C.%20Efe"> C. Efe</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In this study, pyrolysis characteristics of Dursunbey-Balıkesir lignite and its pyrolysis kinetics are examined. The pyrolysis experiments carried out at three different heating rates are performed by using thermogravimetric method. Kinetic parameters are calculated by Coats & Redfern kinetic model and the degree of pyrolysis process is determined for each of the heating rate. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=lignite" title="lignite">lignite</a>, <a href="https://publications.waset.org/abstracts/search?q=thermogravimetric%20analysis" title=" thermogravimetric analysis"> thermogravimetric analysis</a>, <a href="https://publications.waset.org/abstracts/search?q=pyrolysis" title=" pyrolysis"> pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=kinetics" title=" kinetics"> kinetics</a> </p> <a href="https://publications.waset.org/abstracts/61724/pyrolysis-of-dursunbey-lignite-and-pyrolysis-kinetics" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/61724.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">367</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">124</span> Co-Pyrolysis of Olive Pomace with Plastic Wastes and Characterization of Pyrolysis Products</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Merve%20Sogancioglu">Merve Sogancioglu</a>, <a href="https://publications.waset.org/abstracts/search?q=Esra%20Yel"> Esra Yel</a>, <a href="https://publications.waset.org/abstracts/search?q=Ferda%20Tartar"> Ferda Tartar</a>, <a href="https://publications.waset.org/abstracts/search?q=Nihan%20Canan%20Iskender"> Nihan Canan Iskender</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Waste polyethylene (PE) is classified as waste low density polyethylene (LDPE) and waste high density polyethylene (HDPE) according to their densities. Pyrolysis of plastic waste may have an important role in dealing with the enormous amounts of plastic waste produced all over the world, by decreasing their negative impact on the environment. This waste may be converted into economically valuable hydrocarbons, which can be used both as fuels and as feed stock in the petrochemical industry. End product yields and properties depend on the plastic waste composition. Pyrolytic biochar is one of the most important products of waste plastics pyrolysis. In this study, HDPE and LDPE plastic wastes were co-pyrolyzed together with waste olive pomace. Pyrolysis runs were performed at temperature 700°C with heating rates of 5°C/min. Higher pyrolysis oil and gas yields were observed by the using waste olive pomace. The biochar yields of HDPE- olive pomace and LDPEolive pomace were 6.37% and 7.26% respectively for 50% olive pomace doses. The calorific value of HDPE-olive pomace and LDPE-olive pomace of pyrolysis oil were 8350 and 8495 kCal. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=biochar" title="biochar">biochar</a>, <a href="https://publications.waset.org/abstracts/search?q=co-pyrolysis" title=" co-pyrolysis"> co-pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=waste%20plastic" title=" waste plastic"> waste plastic</a>, <a href="https://publications.waset.org/abstracts/search?q=waste%20olive%20pomace" title=" waste olive pomace"> waste olive pomace</a> </p> <a href="https://publications.waset.org/abstracts/43077/co-pyrolysis-of-olive-pomace-with-plastic-wastes-and-characterization-of-pyrolysis-products" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/43077.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">317</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">123</span> Co-Pyrolysis of Bituminous Coal with Peat by Thermogravimetric Analysis</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ceren%20Efe">Ceren Efe</a>, <a href="https://publications.waset.org/abstracts/search?q=Hale%20S%C3%BCt%C3%A7%C3%BC"> Hale Sütçü</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In this study, the pyrolysis of bituminous coal, peat and their blends formed by mixing various ratios of them were examined by thermogravimetric analysis method. Thermogravimetric analyses of peat, bituminous coal and their blends in the proportions of 25 %, 50 % and 75 % were performed at heating rate of 10 °C/min and from the room temperature until to 800 °C temperature, in a nitrogen atmosphere of 100 ml/min. Kinetic parameters for the pyrolysis process were calculated using Coats&Redfern kinetic model. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=bituminous%20coal" title="bituminous coal">bituminous coal</a>, <a href="https://publications.waset.org/abstracts/search?q=peat" title=" peat"> peat</a>, <a href="https://publications.waset.org/abstracts/search?q=pyrolysis" title=" pyrolysis"> pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=thermogravimetric%20analysis" title=" thermogravimetric analysis"> thermogravimetric analysis</a>, <a href="https://publications.waset.org/abstracts/search?q=Coats%26Redfern" title=" Coats&Redfern"> Coats&Redfern</a> </p> <a href="https://publications.waset.org/abstracts/62239/co-pyrolysis-of-bituminous-coal-with-peat-by-thermogravimetric-analysis" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/62239.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">262</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">122</span> Co-Pyrolysis Characteristics of Waste Polyolefins</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Si%CC%87nem%20U%C4%9Fuz">Si̇nem Uğuz</a>, <a href="https://publications.waset.org/abstracts/search?q=Yuksel%20Ardali"> Yuksel Ardali</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Nowadays rapid population growth causes a mandatory increase in consumption. As a result of production activities which meet this consumption, energy sources decrease rapidly on our world. As well as with this production activities various waste occurs. At the end of the production and accumulation of this waste need a mandatory disposal. In this context, copyrolysis of waste polyolefins were investigated. In this study for pyrolysis process, polyethylene and polyprophylene are selected as polyolefins. The pyrolysis behavior (efficiency of solid, liquid and gas production) of selected materials were examined at the different temperatures and different mixtures. Pyrolysis process was carried out at 550 °C and 600 °C without air in a fixed bed pyrolysis oven solid under the nitrogen flow to provide inertness of medium. Elemental analyses (C, H, O, N, S) of this solid and liquid (bitumen) products were made and the calorific value was calculated. The availability of liquid product as a fuel was investigated. In addition different products’ amounts formed like solid, liquid and gas at different temperatures were evaluated. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=alternative%20energy" title="alternative energy">alternative energy</a>, <a href="https://publications.waset.org/abstracts/search?q=elemental%20analysis" title=" elemental analysis"> elemental analysis</a>, <a href="https://publications.waset.org/abstracts/search?q=pyrolysis" title=" pyrolysis"> pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=waste%20reduction" title=" waste reduction"> waste reduction</a> </p> <a href="https://publications.waset.org/abstracts/54584/co-pyrolysis-characteristics-of-waste-polyolefins" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/54584.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">314</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">121</span> A Novel Approach for Energy Utilisation in a Pyrolysis Plant</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=S.%20Murugan">S. Murugan</a>, <a href="https://publications.waset.org/abstracts/search?q=Bohumil%20Horak"> Bohumil Horak</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Pyrolysis is one of the possible technologies to derive energy from waste organic substances. In recent years, pilot level and demonstrated plants have been installed in few countries. The heat energy lost during the process is not effectively utilized resulting in less savings of energy and money. This paper proposes a novel approach to integrate a combined heat and power unit(CHP) and reduce the primary energy consumption in a tyre pyrolysis pilot plant. The proposal primarily uses the micro combined heat and power concept that will help to produce both heat and power in the process. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=pyrolysis" title="pyrolysis">pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=waste%20tyres" title=" waste tyres"> waste tyres</a>, <a href="https://publications.waset.org/abstracts/search?q=waste%20plastics" title=" waste plastics"> waste plastics</a>, <a href="https://publications.waset.org/abstracts/search?q=biomass" title=" biomass"> biomass</a>, <a href="https://publications.waset.org/abstracts/search?q=waste%20heat" title=" waste heat"> waste heat</a> </p> <a href="https://publications.waset.org/abstracts/28362/a-novel-approach-for-energy-utilisation-in-a-pyrolysis-plant" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/28362.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">328</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">120</span> A Comparative Study on Biochar from Slow Pyrolysis of Corn Cob and Cassava Wastes</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Adilah%20Shariff">Adilah Shariff</a>, <a href="https://publications.waset.org/abstracts/search?q=Nurhidayah%20Mohamed%20Noor"> Nurhidayah Mohamed Noor</a>, <a href="https://publications.waset.org/abstracts/search?q=Alexander%20Lau"> Alexander Lau</a>, <a href="https://publications.waset.org/abstracts/search?q=Muhammad%20Azwan%20Mohd%20Ali"> Muhammad Azwan Mohd Ali</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Biomass such as corn and cassava wastes if left to decay will release significant quantities of greenhouse gases (GHG) including carbon dioxide and methane. The biomass wastes can be converted into biochar via thermochemical process such as slow pyrolysis. This approach can reduce the biomass wastes as well as preserve its carbon content. Biochar has the potential to be used as a carbon sequester and soil amendment. The aim of this study is to investigate the characteristics of the corn cob, cassava stem, and cassava rhizome in order to identify their potential as pyrolysis feedstocks for biochar production. This was achieved by using the proximate and elemental analyses as well as calorific value and lignocellulosic determination. The second objective is to investigate the effect of pyrolysis temperature on the biochar produced. A fixed bed slow pyrolysis reactor was used to pyrolyze the corn cob, cassava stem, and cassava rhizome. The pyrolysis temperatures were varied between 400 °C and 600 °C, while the heating rate and the holding time were fixed at 5 °C/min and 1 hour, respectively. Corn cob, cassava stem, and cassava rhizome were found to be suitable feedstocks for pyrolysis process because they contained a high percentage of volatile matter more than 80 mf wt.%. All the three feedstocks contained low nitrogen and sulphur content less than 1 mf wt.%. Therefore, during the pyrolysis process, the feedstocks give off very low rate of GHG such as nitrogen oxides and sulphur oxides. Independent of the types of biomass, the percentage of biochar yield is inversely proportional to the pyrolysis temperature. The highest biochar yield for each studied temperature is from slow pyrolysis of cassava rhizome as the feedstock contained the highest percentage of ash compared to the other two feedstocks. The percentage of fixed carbon in all the biochars increased as the pyrolysis temperature increased. The increment of pyrolysis temperature from 400 °C to 600 °C increased the fixed carbon of corn cob biochar, cassava stem biochar and cassava rhizome biochar by 26.35%, 10.98%, and 6.20% respectively. Irrespective of the pyrolysis temperature, all the biochars produced were found to contain more than 60 mf wt.% fixed carbon content, much higher than its feedstocks. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=biochar" title="biochar">biochar</a>, <a href="https://publications.waset.org/abstracts/search?q=biomass" title=" biomass"> biomass</a>, <a href="https://publications.waset.org/abstracts/search?q=cassava%20wastes" title=" cassava wastes"> cassava wastes</a>, <a href="https://publications.waset.org/abstracts/search?q=corn%20cob" title=" corn cob"> corn cob</a>, <a href="https://publications.waset.org/abstracts/search?q=pyrolysis" title=" pyrolysis"> pyrolysis</a> </p> <a href="https://publications.waset.org/abstracts/53405/a-comparative-study-on-biochar-from-slow-pyrolysis-of-corn-cob-and-cassava-wastes" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/53405.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">299</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">119</span> A Numerical and Experimental Study on Fast Pyrolysis of Single Wood Particle</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Hamid%20Rezaei">Hamid Rezaei</a>, <a href="https://publications.waset.org/abstracts/search?q=Xiaotao%20Bi"> Xiaotao Bi</a>, <a href="https://publications.waset.org/abstracts/search?q=C.%20Jim%20Lim"> C. Jim Lim</a>, <a href="https://publications.waset.org/abstracts/search?q=Anthony%20Lau"> Anthony Lau</a>, <a href="https://publications.waset.org/abstracts/search?q=Shahab%20Sokhansanj"> Shahab Sokhansanj</a> </p> <p class="card-text"><strong>Abstract:</strong></p> A one-dimensional heat transfer model coupled with the kinetic information has been used to predict the overall pyrolysis mass loss of a single wood particle. The kinetic parameters were determined experimentally and the regime and characteristics of the conversion were evaluated in terms of the particle size and reactor temperature. The order of overall mass loss changed from n=1 at temperatures lower than 350 °C to n=0.5 at temperatures higher that 350 °C. Conversion time analysis showed that particles larger than 0.5 mm were controlled by internal thermal resistances. The valid range of particle size to use the simplified lumped model depends on the fluid temperature around the particles. The critical particle size was 0.6-0.7 mm for the fluid temperature of 500 °C and 0.9-1.0 mm for the fluid temperature of 100 °C. Experimental pyrolysis of moist particles did not show distinct drying and pyrolysis stages. The process was divided into two hypothetical drying and pyrolysis dominated zones and empirical correlations are developed to predict the rate of mass loss in each zone. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=pyrolysis" title="pyrolysis">pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=kinetics" title=" kinetics"> kinetics</a>, <a href="https://publications.waset.org/abstracts/search?q=model" title=" model"> model</a>, <a href="https://publications.waset.org/abstracts/search?q=single%20particle" title=" single particle"> single particle</a> </p> <a href="https://publications.waset.org/abstracts/57465/a-numerical-and-experimental-study-on-fast-pyrolysis-of-single-wood-particle" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/57465.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">320</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">118</span> Catalytic and Non-Catalytic Pyrolysis of Walnut Shell Waste to Biofuel: Characterisation of Catalytic Biochar and Biooil</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Saimatun%20Nisa">Saimatun Nisa</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Walnut is an important export product from the Union Territory of Jammy and Kashmir. After extraction of the kernel, the walnut shell forms a solid waste that needs to be managed. Pyrolysis is one interesting option for the utilization of this walnut waste. In this study microwave pyrolysis reactor is used to convert the walnut shell biomass into its value-added products. Catalytic and non-catalytic conversion of walnut shell waste to oil, gas and char was evaluated using a Co-based catalyst. The catalyst was characterized using XPS and SEM analysis. Pyrolysis temperature, reaction time, particle size and sweeping gas (N₂) flow rate were set in the ranges of 400–600 °C, 40 min, <0.6mm to < 4.75mm and 300 ml min−1, respectively. The heating rate was fixed at 40 °C min−1. Maximum gas yield was obtained at 600 °C, 40 min, particle size range 1.18-2.36, 0.5 molar catalytic as 45.2%. The liquid product catalytic and non-catalytic was characterized by GC–MS analyses. In addition, the solid product was analyzed by means of FTIR & SEM. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=walnut%20shell" title="walnut shell">walnut shell</a>, <a href="https://publications.waset.org/abstracts/search?q=biooil" title=" biooil"> biooil</a>, <a href="https://publications.waset.org/abstracts/search?q=biochar" title=" biochar"> biochar</a>, <a href="https://publications.waset.org/abstracts/search?q=microwave%20pyrolysis" title=" microwave pyrolysis"> microwave pyrolysis</a> </p> <a href="https://publications.waset.org/abstracts/185833/catalytic-and-non-catalytic-pyrolysis-of-walnut-shell-waste-to-biofuel-characterisation-of-catalytic-biochar-and-biooil" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/185833.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">52</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">117</span> Analysis of Bio-Oil Produced from Sugar Cane Bagasse Pyrolysis</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=D.%20S.%20Fardhyanti">D. S. Fardhyanti</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20Megawati"> M. Megawati</a>, <a href="https://publications.waset.org/abstracts/search?q=H.%20Prasetiawan"> H. Prasetiawan</a>, <a href="https://publications.waset.org/abstracts/search?q=U.%20Mediaty"> U. Mediaty</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Currently, fossil fuel is supplying most of world’s energy resources. However, fossil fuel resources are depleted rapidly and require an alternative energy to overcome the increasing of energy demands. Bio-oil is one of a promising alternative renewable energy resources which is converted from biomass through pyrolysis or fast pyrolysis process. Bio-oil is a dark liquid fuel, has a smelling smoke and usually obtained from sugar cane, wood, coconut shell and any other biomass. Sugar cane content analysis showed that the content of oligosaccharide, hemicellulose, cellulose and lignin was 16.69%, 25.66%, 51.27% and 6.38% respectively. Sugar cane is a potential sources for bio-oil production shown by its high content of cellulose. In this study, production of bio-oil from sugar cane bagasse was investigated via fast pyrolysis reactor. Fast pyrolysis was carried out at 500 °C with a heating rate of 10 °C and 1 hour holding time at pyrolysis temperature. Physical properties and chemical composition of bio-oil were analyzed. The viscosity, density, calorific value and molecular weight of produced bio-oil was 3.12 cp, 2.78 g/cm3, 11,048.44 cals/g, and 222.67 respectively. The Bio-oil chemical composition was investigated using GC-MS. Percentage value of furfural, phenol, 3-methyl 1,2-cyclopentanedione, 5-methyl-3-methylene 5-hexen-2-one, 4-methyl phenol, 4-ethyl phenol, 1,2-benzenediol, and 2,6-dimethoxy phenol was 20.76%, 16.42%, 10.86%, 7.54%, 7.05%, 7.72%, 5.27% and 6.79% respectively. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=bio-oil" title="bio-oil">bio-oil</a>, <a href="https://publications.waset.org/abstracts/search?q=pyrolysis" title=" pyrolysis"> pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=bagasse" title=" bagasse"> bagasse</a>, <a href="https://publications.waset.org/abstracts/search?q=sugar%20cane" title=" sugar cane"> sugar cane</a>, <a href="https://publications.waset.org/abstracts/search?q=gas%20chromatography-mass%20spectroscopy" title=" gas chromatography-mass spectroscopy"> gas chromatography-mass spectroscopy</a> </p> <a href="https://publications.waset.org/abstracts/93052/analysis-of-bio-oil-produced-from-sugar-cane-bagasse-pyrolysis" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/93052.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">142</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">116</span> A Study of Heavy Hydrocarbons Upgrading by Microwave Pyrolysis</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Thanida%20Sritangthong">Thanida Sritangthong</a>, <a href="https://publications.waset.org/abstracts/search?q=Suksun%20Amornraksa"> Suksun Amornraksa</a> </p> <p class="card-text"><strong>Abstract:</strong></p> By-product upgrading is crucial in hydrocarbon industries as it can increase overall profit margin of the business. Microwave-assisted pyrolysis is relatively new technique which induces heat directly to raw materials. This results in a more energy saving and more energy-efficient process. It is also a promising method to enhance and accelerate chemical reactions, thus reducing the pyrolysis reaction time and increasing the quality of value-added products from different kinds of feedstocks. In this study, upgrading opportunity of fuel oil by-product from an olefins plant is investigated by means of microwave pyrolysis. The experiment was conducted in a lab-scale quartz reactor placed inside a 1,100 watts household microwave oven. Operating temperature was varied from 500 to 900C to observe the consequence on the quality of pyrolysis products. Several microwave receptors i.e. activated carbon, silicon carbide (SiC) and copper oxide (CuO) were used as a material to enhance the heating and reaction in the reactor. The effect of residence time was determined by adjusting flow rate of N2 carrier gas. The chemical composition and product yield were analyzed by using gas chromatography (GC) and gas chromatography/mass spectrometry (GC/MS). The results showed that hydrogen, methane, ethylene, and ethane were obtained as the main gaseous products from all operating temperatures while the main liquid products were alkane, cycloalkane and polycyclic aromatic groups. The results indicated that microwave pyrolysis has a potential to upgrade low value hydrocarbons to high value products. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=fuel%20oil" title="fuel oil">fuel oil</a>, <a href="https://publications.waset.org/abstracts/search?q=heavy%20hydrocarbons" title=" heavy hydrocarbons"> heavy hydrocarbons</a>, <a href="https://publications.waset.org/abstracts/search?q=microwave%20pyrolysis" title=" microwave pyrolysis"> microwave pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=pyrolysis" title=" pyrolysis"> pyrolysis</a> </p> <a href="https://publications.waset.org/abstracts/35606/a-study-of-heavy-hydrocarbons-upgrading-by-microwave-pyrolysis" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/35606.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">319</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">115</span> Investigation of Biochar from Banana Peel</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Anurita%20Selvarajoo">Anurita Selvarajoo</a>, <a href="https://publications.waset.org/abstracts/search?q=Svenja%20Hanson"> Svenja Hanson</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Growing energy needs and increasing environmental issues are creating awareness for alternative energy which substitutes the non-renewable and polluting fossil fuels. Agricultural wastes are a good feedstock for biochar production through the pyrolysis process. There is potential to generate solid fuel from agricultural wastes, as there are large quantities of agricultural wastes available in Malaysia. This paper outlines the experimental study on the pyrolysis of banana peel. The effects of pyrolysis temperatures on the yield of biochar from the banana peel were investigated. Banana peel was pyrolysed in a horizontal tubular reactor under inert atmosphere by varying the temperatures between 300 and 700 0C. With increasing temperature, the total biochar yield decreased with increased heating value. It was found that the pyrolysis temperature had major effect on the yield of biochar product. It also exerted major influence on the heating value and C,H and O composition. The obtained biochar ranged between 31.9 to 56.7 %wt, at different pyrolysis temperatures. The optimum biochar yield was obtained at 325 0C. Biochar yield obtained at optimum temperature was 47 % wt with a heating value of 25.9 MJ kg-1. The study has been performed in order to demonstrate that agricultural wastes like banana peel are also important source of solid fuel. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=agricultural%20Wastes" title="agricultural Wastes">agricultural Wastes</a>, <a href="https://publications.waset.org/abstracts/search?q=banana%20peel" title=" banana peel"> banana peel</a>, <a href="https://publications.waset.org/abstracts/search?q=biochar" title=" biochar"> biochar</a>, <a href="https://publications.waset.org/abstracts/search?q=pyrolysis" title=" pyrolysis"> pyrolysis</a> </p> <a href="https://publications.waset.org/abstracts/23963/investigation-of-biochar-from-banana-peel" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/23963.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">297</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">114</span> The Pyrolysis of Leather and Textile Waste in Carbonised Materials as an Element of the Circular Economy Model</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Maciej%20%C5%BBycki">Maciej Życki</a>, <a href="https://publications.waset.org/abstracts/search?q=Anna%20Kowalik-klimczak"> Anna Kowalik-klimczak</a>, <a href="https://publications.waset.org/abstracts/search?q=Monika%20%C5%81o%C5%BCy%C5%84ska"> Monika Łożyńska</a>, <a href="https://publications.waset.org/abstracts/search?q=Wioletta%20Barszcz"> Wioletta Barszcz</a>, <a href="https://publications.waset.org/abstracts/search?q=Jolanta%20Drabik%20Anna%20Kowalik-klimczak"> Jolanta Drabik Anna Kowalik-klimczak</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The rapidly changing fashion trends generate huge amounts of leather and textile waste globally. The complexity of these types of waste makes recycling difficult in economic terms. Pyrolysis is suggested for this purpose, which transforms heterogeneous and complex waste into added-value products e.g. active carbons and soil fertilizer. The possibility of using pyrolysis for the valorization of leather and textile waste has been analyzed in this paper. In the first stage, leather and textile waste were subjected to TG/DTG thermogravimetric and DSC calorimetric analysis. These analyses provided basic information about thermochemical transformations and degradation rates during the pyrolysis of these types of waste and enabled the selection of the pyrolysis temperature. In the next stage, the effect of gas type using pyrolysis was investigated on the physicochemical properties, composition, structure, and formation of the specific surfaces of carbonized materials produced by means of a thermal treatment without oxygen access to the reaction chamber. These studies contribute some data about the thermal management and pyrolytic processing of leather and textile waste into useful carbonized materials, according to the circular economy model. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=pyrolysis" title="pyrolysis">pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=leather%20and%20textiles%20waste" title=" leather and textiles waste"> leather and textiles waste</a>, <a href="https://publications.waset.org/abstracts/search?q=composition%20and%20structure%20of%20carbonized%20materials" title=" composition and structure of carbonized materials"> composition and structure of carbonized materials</a>, <a href="https://publications.waset.org/abstracts/search?q=valorisation%20of%20waste" title=" valorisation of waste"> valorisation of waste</a>, <a href="https://publications.waset.org/abstracts/search?q=circular%20economy%20model" title=" circular economy model"> circular economy model</a> </p> <a href="https://publications.waset.org/abstracts/194644/the-pyrolysis-of-leather-and-textile-waste-in-carbonised-materials-as-an-element-of-the-circular-economy-model" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/194644.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">7</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">113</span> The Study of Tire Pyrolysis Fuel in CI Diesel Engine for Spray Combustion Character and Performance</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Chun%20Pao%20Kuo">Chun Pao Kuo</a>, <a href="https://publications.waset.org/abstracts/search?q=Chi%20Tong%20Lin"> Chi Tong Lin</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The study explored atomization characteristics of tire pyrolysis fuel and its impacts on using three types of fuel: diesel oil mixed with 10% of tire pyrolysis fuel (called T10), diesel oil mixed with 20% tire pyrolysis (called T20), and consumer-grade diesel oil (D100). The investigators used the fuel for simulation and tests at various fuel injection timing, engine speed, and fuel injection speed to inspect impacts from fuel type on oil droplet atomization speed and output power. Actual vehicle tests were conducted using a 5-ton sedan (Hino) with 3660 cc displacement and a front-end inline four-cylinder diesel engine, and this type of vehicle is easily available from the market. A dynamometer was used to set up three engine speeds for the dynamometer testing at different injection timing and pressure. Next, an exhaust analyzer was used to measure exhaust pollution at different conditions to explore the effect of fuel types and injection speeds on output power in order to establish the best operation conditions for tire pyrolysis fuel. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=diesel%20engine" title="diesel engine">diesel engine</a>, <a href="https://publications.waset.org/abstracts/search?q=exhaust%20pollution" title=" exhaust pollution"> exhaust pollution</a>, <a href="https://publications.waset.org/abstracts/search?q=fuel%20injection%20timing" title=" fuel injection timing"> fuel injection timing</a>, <a href="https://publications.waset.org/abstracts/search?q=tire%20pyrolysis%20oil" title=" tire pyrolysis oil"> tire pyrolysis oil</a> </p> <a href="https://publications.waset.org/abstracts/31810/the-study-of-tire-pyrolysis-fuel-in-ci-diesel-engine-for-spray-combustion-character-and-performance" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/31810.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">408</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">112</span> A Thermal Analysis Based Approach to Obtain High Carbonaceous Fibers from Chicken Feathers</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Y.%20Okumu%C5%9F">Y. Okumuş</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20Tuna"> A. Tuna</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20T.%20Seyhan"> A. T. Seyhan</a>, <a href="https://publications.waset.org/abstracts/search?q=H.%20%C3%87elebi"> H. Çelebi</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Useful carbon fibers were derived from chicken feathers (PCFs) based on a two-step pyrolysis method. The collected PCFs were cleaned and categorized as black, white and brown. Differential scanning calorimeter (DSC) and thermo-gravimetric analyzer (TGA) were systemically used to design the pyrolysis steps. Depending on colors, feathers exhibit different glass transition (Tg) temperatures. Long-time heat treatment applied to the feathers emerged influential on the surface quality of the resulting carbon fibers. Fourier Transformation Infrared (FTIR) examination revealed that the extent of disulﬁde bond cleavage is highly associated with the feather melting stability. Scanning electron microscopy (SEM) examinations were employed to evaluate the morphological changes of feathers after pyrolysis. Of all, brown feathers were found to be the most promising to turn into useful carbon fibers without any trace of melting and shape distortion when pyrolysis was carried out at 230°C for 24 hours and at 450°C for 1 hour. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=poultry%20chicken%20feather" title="poultry chicken feather">poultry chicken feather</a>, <a href="https://publications.waset.org/abstracts/search?q=keratin%20protein%20fiber" title=" keratin protein fiber"> keratin protein fiber</a>, <a href="https://publications.waset.org/abstracts/search?q=pyrolysis" title=" pyrolysis"> pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=high%20carbonaceous%20fibers" title=" high carbonaceous fibers"> high carbonaceous fibers</a> </p> <a href="https://publications.waset.org/abstracts/9790/a-thermal-analysis-based-approach-to-obtain-high-carbonaceous-fibers-from-chicken-feathers" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/9790.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">329</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">111</span> Analysis of Coal Tar Compositions Produced from Sub-Bituminous Kalimantan Coal Tar</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Dewi%20Selvia%20Fardhyanti">Dewi Selvia Fardhyanti</a>, <a href="https://publications.waset.org/abstracts/search?q=Astrilia%20Damayanti"> Astrilia Damayanti</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Coal tar is a liquid by-product of coal pyrolysis processes. This liquid oil mixture contains various kind of useful compounds such as benzoic aromatic compounds and phenolic compounds. These compounds are widely used as raw material for insecticides, dyes, medicines, perfumes, coloring matters, and many others. The coal tar was collected by pyrolysis process of coal obtained from PT Kaltim Prima Coal and Arutmin-Kalimantan. The experiments typically occurred at the atmospheric pressure in a laboratory furnace at temperatures ranging from 300 to 550oC with a heating rate of 10oC/min and a holding time of 1 hour at the pyrolysis temperature. Nitrogen gas has been used to obtain the inert condition and to carry the gaseous pyrolysis products. The pyrolysis transformed organic materials into gaseous components, small quantities of liquid, and a solid residue (coke) containing fixed amount of carbon and ash. The composition of gas which is produced from the pyrolysis is carbon monoxide, hydrogen, methane, and other hydrocarbon compounds. The gas was condensed and the liquid containing oil/tar and water was obtained. The Gas Chromatography-Mass Spectroscopy (GC-MS) was used to analyze the coal tar components. The obtained coal tar has the viscosity of 3.12 cp, the density of 2.78 g/cm3, the calorific value of 11,048.44 cal/g, and the molecular weight of 222.67. The analysis result showed that the coal tar contained more than 78 chemical compounds such as benzene, cresol, phenol, xylene, naphtalene, etc. The total phenolic compounds contained in coal tar is 33.25% (PT KPC) and 17.58% (Arutmin-Kalimantan). The total naphtalene compounds contained in coal tar is 14.15% (PT KPC) and 17.13% (Arutmin-Kalimantan). <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=coal%20tar" title="coal tar">coal tar</a>, <a href="https://publications.waset.org/abstracts/search?q=pyrolysis" title=" pyrolysis"> pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=gas%20chromatography-mass%20spectroscopy" title=" gas chromatography-mass spectroscopy"> gas chromatography-mass spectroscopy</a> </p> <a href="https://publications.waset.org/abstracts/28336/analysis-of-coal-tar-compositions-produced-from-sub-bituminous-kalimantan-coal-tar" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/28336.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">328</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">110</span> Catalytic Pyrolysis of Barley Straw for the Production of Fuels and Chemicals</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Funda%20Ates">Funda Ates</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Primary energy sources, such as petroleum, coal and natural gas are principle responsible of world’s energy consumption. However, the rapid worldwide increase in the depletion of these energy sources is remarkable. In addition to this, they have damaging environmentally effect. Renewable energy sources are capable of providing a considerable fraction of World energy demand in this century. Biomass is one of the most abundant and utilized sources of renewable energy in the world. It can be converted into commercial fuels, suitable to substitute for fossil fuels. A high number of biomass types can be converted through thermochemical processes into solid, liquid or gaseous fuels. Pyrolysis is the thermal decomposition of biomass in the absence of air or oxygen. In this study, barley straw has been investigated as an alternative feedstock to obtain fuels and chemicals via pyrolysis in fixed-bed reactor. The influence of pyrolysis temperature in the range 450–750 °C as well as the catalyst effects on the products was investigated and the obtained results were compared. The results indicated that a maximum oil yield of 20.4% was obtained at a moderate temperature of 550 °C. Oil yield decreased by using catalyst. Pyrolysis oils were examined by using instrumental analysis and GC/MS. Analyses revealed that the pyrolysis oils were chemically very heterogeneous at all temperatures. It was determined that the most abundant compounds composing the bio-oil were phenolics. Catalyst decreased the reaction temperature. Most of the components obtained using a catalyst at moderate temperatures was close to those obtained at high temperatures without using a catalyst. Moreover, the use of a catalyst also decreased the amount of oxygenated compounds produced. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=Barley%20straw" title="Barley straw">Barley straw</a>, <a href="https://publications.waset.org/abstracts/search?q=pyrolysis" title=" pyrolysis"> pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=catalyst" title=" catalyst"> catalyst</a>, <a href="https://publications.waset.org/abstracts/search?q=phenolics" title=" phenolics"> phenolics</a> </p> <a href="https://publications.waset.org/abstracts/72812/catalytic-pyrolysis-of-barley-straw-for-the-production-of-fuels-and-chemicals" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/72812.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">226</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">109</span> Thermodynamic Analysis and Experimental Study of Agricultural Waste Plasma Processing</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=V.%20E.%20Messerle">V. E. Messerle</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20B.%20Ustimenko"> A. B. Ustimenko</a>, <a href="https://publications.waset.org/abstracts/search?q=O.%20A.%20Lavrichshev"> O. A. Lavrichshev</a> </p> <p class="card-text"><strong>Abstract:</strong></p> A large amount of manure and its irrational use negatively affect the environment. As compared with biomass fermentation, plasma processing of manure enhances makes it possible to intensify the process of obtaining fuel gas, which consists mainly of synthesis gas (CO + H₂), and increase plant productivity by 150–200 times. This is achieved due to the high temperature in the plasma reactor and a multiple reduction in waste processing time. This paper examines the plasma processing of biomass using the example of dried mixed animal manure (dung with a moisture content of 30%). Characteristic composition of dung, wt.%: Н₂О – 30, С – 29.07, Н – 4.06, О – 32.08, S – 0.26, N – 1.22, P₂O₅ – 0.61, K₂O – 1.47, СаО – 0.86, MgO – 0.37. The thermodynamic code TERRA was used to numerically analyze dung plasma gasification and pyrolysis. Plasma gasification and pyrolysis of dung were analyzed in the temperature range 300–3,000 K and pressure 0.1 MPa for the following thermodynamic systems: 100% dung + 25% air (plasma gasification) and 100% dung + 25% nitrogen (plasma pyrolysis). Calculations were conducted to determine the composition of the gas phase, the degree of carbon gasification, and the specific energy consumption of the processes. At an optimum temperature of 1,500 K, which provides both complete gasification of dung carbon and the maximum yield of combustible components (99.4 vol.% during dung gasification and 99.5 vol.% during pyrolysis), and decomposition of toxic compounds of furan, dioxin, and benz(a)pyrene, the following composition of combustible gas was obtained, vol.%: СО – 29.6, Н₂ – 35.6, СО₂ – 5.7, N₂ – 10.6, H₂O – 17.9 (gasification) and СО – 30.2, Н₂ – 38.3, СО₂ – 4.1, N₂ – 13.3, H₂O – 13.6 (pyrolysis). The specific energy consumption of gasification and pyrolysis of dung at 1,500 K is 1.28 and 1.33 kWh/kg, respectively. An installation with a DC plasma torch with a rated power of 100 kW and a plasma reactor with a dung capacity of 50 kg/h was used for dung processing experiments. The dung was gasified in an air (or nitrogen during pyrolysis) plasma jet, which provided a mass-average temperature in the reactor volume of at least 1,600 K. The organic part of the dung was gasified, and the inorganic part of the waste was melted. For pyrolysis and gasification of dung, the specific energy consumption was 1.5 kWh/kg and 1.4 kWh/kg, respectively. The maximum temperature in the reactor reached 1,887 K. At the outlet of the reactor, a gas of the following composition was obtained, vol.%: СO – 25.9, H₂ – 32.9, СO₂ – 3.5, N₂ – 37.3 (pyrolysis in nitrogen plasma); СO – 32.6, H₂ – 24.1, СO₂ – 5.7, N₂ – 35.8 (air plasma gasification). The specific heat of combustion of the combustible gas formed during pyrolysis and plasma-air gasification of agricultural waste is 10,500 and 10,340 kJ/kg, respectively. Comparison of the integral indicators of dung plasma processing showed satisfactory agreement between the calculation and experiment. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=agricultural%20waste" title="agricultural waste">agricultural waste</a>, <a href="https://publications.waset.org/abstracts/search?q=experiment" title=" experiment"> experiment</a>, <a href="https://publications.waset.org/abstracts/search?q=plasma%20gasification" title=" plasma gasification"> plasma gasification</a>, <a href="https://publications.waset.org/abstracts/search?q=thermodynamic%20calculation" title=" thermodynamic calculation"> thermodynamic calculation</a> </p> <a href="https://publications.waset.org/abstracts/185728/thermodynamic-analysis-and-experimental-study-of-agricultural-waste-plasma-processing" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/185728.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">40</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">108</span> Production of Biocomposites Using Chars Obtained by Co-Pyrolysis of Olive Pomace with Plastic Wastes</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Esra%20Yel">Esra Yel</a>, <a href="https://publications.waset.org/abstracts/search?q=Tabriz%20Aslanov"> Tabriz Aslanov</a>, <a href="https://publications.waset.org/abstracts/search?q=Merve%20Sogancioglu"> Merve Sogancioglu</a>, <a href="https://publications.waset.org/abstracts/search?q=Suheyla%20Kocaman"> Suheyla Kocaman</a>, <a href="https://publications.waset.org/abstracts/search?q=Gulnare%20Ahmetli"> Gulnare Ahmetli</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The disposal of waste plastics has become a major worldwide environmental problem. Pyrolysis of waste plastics is one of the routes to waste minimization and recycling that has been gaining interest. In pyrolysis, the pyrolysed material is separated into gas, liquid (both are fuel) and solid (char) products. All fractions have utilities and economical value depending upon their characteristics. The first objective of this study is to determine the co-pyrolysis product fractions of waste HDPE- (high density polyethylene) and LDPE (low density polyethylene)-olive pomace (OP) and to determine the qualities of the solid product char. Chars obtained at 700 °C pyrolysis were used in biocomposite preparation as additive. As the second objective, the effects of char on biocomposite quality were investigated. Pyrolysis runs were performed at temperature 700 °C with heating rates of 5 °C/min. Biocomposites were prepared by mixing of chars with bisphenol-F type epoxy resin in various wt%. Biocomposite properties were determined by measuring electrical conductivity, surface hardness, Young’s modulus and tensile strength of the composites. The best electrical conductivity results were obtained with HDPE-OP char. For HDPE-OP char and LDPE-OP char, compared to neat epoxy, the tensile strength values of the composites increased by 102% and 78%, respectively, at 10% char dose. The hardness measurements showed similar results to the tensile tests, since there is a correlation between the hardness and the tensile strength. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=biocomposite" title="biocomposite">biocomposite</a>, <a href="https://publications.waset.org/abstracts/search?q=char" title=" char"> char</a>, <a href="https://publications.waset.org/abstracts/search?q=olive%20pomace" title=" olive pomace"> olive pomace</a>, <a href="https://publications.waset.org/abstracts/search?q=pyrolysis" title=" pyrolysis"> pyrolysis</a> </p> <a href="https://publications.waset.org/abstracts/43071/production-of-biocomposites-using-chars-obtained-by-co-pyrolysis-of-olive-pomace-with-plastic-wastes" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/43071.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">251</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">107</span> Thermochemical Conversion: Jatropha Curcus in Fixed Bed Reactor Using Slow Pyrolysis</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Vipan%20Kumar%20Sohpal">Vipan Kumar Sohpal</a>, <a href="https://publications.waset.org/abstracts/search?q=Rajesh%20Kumar%20Sharma"> Rajesh Kumar Sharma </a> </p> <p class="card-text"><strong>Abstract:</strong></p> Thermo-chemical conversion of non-edible biomass offers an efficient and economically process to provide valuable fuels and prepare chemicals derived from biomass in the context of developing countries. Pyrolysis has advantages over other thermochemical conversion techniques because it can convert biomass directly into solid, liquid and gaseous products by thermal decomposition of biomass in the absence of oxygen. The present paper aims to focus on the slow thermochemical conversion processes for non-edible Jatropha curcus seed cake. The present discussion focuses on the effect of nitrogen gas flow rate on products composition (wt %). In addition, comparative analysis has been performed for different mesh size for product composition. Result shows that, slow pyrolysis experiments of Jatropha curcus seed cake in fixed bed reactor yield the bio-oil 18.42 wt % at a pyrolysis temperature of 500°C, particle size of -6+8 mesh number and nitrogen gas flow rate of 150 ml/min. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=Jatropha%20curcus" title="Jatropha curcus">Jatropha curcus</a>, <a href="https://publications.waset.org/abstracts/search?q=thermo-chemical" title=" thermo-chemical"> thermo-chemical</a>, <a href="https://publications.waset.org/abstracts/search?q=pyrolysis" title=" pyrolysis"> pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=product%20composition" title=" product composition"> product composition</a>, <a href="https://publications.waset.org/abstracts/search?q=yield" title=" yield"> yield</a> </p> <a href="https://publications.waset.org/abstracts/2125/thermochemical-conversion-jatropha-curcus-in-fixed-bed-reactor-using-slow-pyrolysis" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/2125.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">433</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">106</span> Catalytic Pyrolysis of Sewage Sludge for Upgrading Bio-Oil Quality Using Sludge-Based Activated Char as an Alternative to HZSM5</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ali%20Zaker">Ali Zaker</a>, <a href="https://publications.waset.org/abstracts/search?q=Zhi%20Chen"> Zhi Chen</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Due to the concerns about the depletion of fossil fuel sources and the deteriorating environment, the attempt to investigate the production of renewable energy will play a crucial role as a potential to alleviate the dependency on mineral fuels. One particular area of interest is the generation of bio-oil through sewage sludge (SS) pyrolysis. SS can be a potential candidate in contrast to other types of biomasses due to its availability and low cost. However, the presence of high molecular weight hydrocarbons and oxygenated compounds in the SS bio-oil hinders some of its fuel applications. In this context, catalytic pyrolysis is another attainable route to upgrade bio-oil quality. Among different catalysts (i.e., zeolites) studied for SS pyrolysis, activated chars (AC) are eco-friendly alternatives. The beneficial features of AC derived from SS comprise the comparatively large surface area, porosity, enriched surface functional groups, and presence of a high amount of metal species that can improve the catalytic activity. Hence, a sludge-based AC catalyst was fabricated in a single-step pyrolysis reaction with NaOH as the activation agent and was compared with HZSM5 zeolite in this study. The thermal decomposition and kinetics were invested via thermogravimetric analysis (TGA) for guidance and control of pyrolysis and catalytic pyrolysis and the design of the pyrolysis setup. The results indicated that the pyrolysis and catalytic pyrolysis contains four obvious stages, and the main decomposition reaction occurred in the range of 200-600°C. The Coats-Redfern method was applied in the 2nd and 3rd devolatilization stages to estimate the reaction order and activation energy (E) from the mass loss data. The average activation energy (Em) values for the reaction orders n = 1, 2, and 3 were in the range of 6.67-20.37 kJ for SS; 1.51-6.87 kJ for HZSM5; and 2.29-9.17 kJ for AC, respectively. According to the results, AC and HZSM5 both were able to improve the reaction rate of SS pyrolysis by abridging the Em value. Moreover, to generate and examine the effect of the catalysts on the quality of bio-oil, a fixed-bed pyrolysis system was designed and implemented. The composition analysis of the produced bio-oil was carried out via gas chromatography/mass spectrometry (GC/MS). The selected SS to catalyst ratios were 1:1, 2:1, and 4:1. The optimum ratio in terms of cracking the long-chain hydrocarbons and removing oxygen-containing compounds was 1:1 for both catalysts. The upgraded bio-oils with AC and HZSM5 were in the total range of C4-C17, with around 72% in the range of C4-C9. The bio-oil from pyrolysis of SS contained 49.27% oxygenated compounds, while with the presence of AC and HZSM5 dropped to 13.02% and 7.3%, respectively. Meanwhile, the generation of benzene, toluene, and xylene (BTX) compounds was significantly improved in the catalytic process. Furthermore, the fabricated AC catalyst was characterized by BET, SEM-EDX, FT-IR, and TGA techniques. Overall, this research demonstrated AC is an efficient catalyst in the pyrolysis of SS and can be used as a cost-competitive catalyst in contrast to HZSM5. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=catalytic%20pyrolysis" title="catalytic pyrolysis">catalytic pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=sewage%20sludge" title=" sewage sludge"> sewage sludge</a>, <a href="https://publications.waset.org/abstracts/search?q=activated%20char" title=" activated char"> activated char</a>, <a href="https://publications.waset.org/abstracts/search?q=HZSM5" title=" HZSM5"> HZSM5</a>, <a href="https://publications.waset.org/abstracts/search?q=bio-oil" title=" bio-oil"> bio-oil</a> </p> <a href="https://publications.waset.org/abstracts/139358/catalytic-pyrolysis-of-sewage-sludge-for-upgrading-bio-oil-quality-using-sludge-based-activated-char-as-an-alternative-to-hzsm5" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/139358.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">179</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">105</span> Conversion of Tropical Wood to Bio-oil and Charcoal by Using the Process of Pyrolysis</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Kittiphop%20Promdee">Kittiphop Promdee</a>, <a href="https://publications.waset.org/abstracts/search?q=Somruedee%20Satitkune"> Somruedee Satitkune</a>, <a href="https://publications.waset.org/abstracts/search?q=Chakkrich%20Boonmee"> Chakkrich Boonmee</a>, <a href="https://publications.waset.org/abstracts/search?q=Tharapong%20Vitidsant"> Tharapong Vitidsant</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Conversion of tropical wood using the process of pyrolysis, which converts tropical wood into fuel products, i.e. bio-oil and charcoal. The results showed the high thermal in the reactor core was thermally controlled between 0-600°C within 60 minutes. The products yield calculation showed that the liquid yield obtained from tropical wood was at its highest at 39.42 %, at 600°C, indicating that the tropical wood had received good yields because of a low gas yield average and high solid and liquid yield average. This research is not only concerned with the controlled temperatures, but also with the controlled screw rotating and feeding rate of biomass. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=pyrolysis" title="pyrolysis">pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=tropical%20wood" title=" tropical wood"> tropical wood</a>, <a href="https://publications.waset.org/abstracts/search?q=bio-oil" title=" bio-oil"> bio-oil</a>, <a href="https://publications.waset.org/abstracts/search?q=charcoal" title=" charcoal"> charcoal</a>, <a href="https://publications.waset.org/abstracts/search?q=heating%20value" title=" heating value"> heating value</a>, <a href="https://publications.waset.org/abstracts/search?q=SEM" title=" SEM"> SEM</a> </p> <a href="https://publications.waset.org/abstracts/34906/conversion-of-tropical-wood-to-bio-oil-and-charcoal-by-using-the-process-of-pyrolysis" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/34906.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">480</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">104</span> The Prospect of Producing Hydrogen by Electrolysis of Idle Discharges of Water from Reservoirs and Recycling of Waste-Gas Condensates</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Inom%20Sh.%20Normatov">Inom Sh. Normatov</a>, <a href="https://publications.waset.org/abstracts/search?q=Nurmakhmad%20Shermatov"> Nurmakhmad Shermatov</a>, <a href="https://publications.waset.org/abstracts/search?q=Rajabali%20Barotov"> Rajabali Barotov</a>, <a href="https://publications.waset.org/abstracts/search?q=Rano%20Eshankulova"> Rano Eshankulova</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The results of the studies for the hydrogen production by the application of water electrolysis and plasma-chemical processing of gas condensate-waste of natural gas production methods are presented. Thin coating covers the electrode surfaces in the process of water electrolysis. Therefore, water for electrolysis was first exposed to electrosedimentation. The threshold voltage is shifted to a lower value compared with the use of electrodes made of stainless steel. At electrolysis of electrosedimented water by use of electrodes from stainless steel, a significant amount of hydrogen is formed. Pyrolysis of gas condensates in the atmosphere of a nitrogen was followed by the formation of acetylene (3-7 vol.%), ethylene (4-8 vol.%), and pyrolysis carbon (10-15 wt.%). <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=electrolyze" title="electrolyze">electrolyze</a>, <a href="https://publications.waset.org/abstracts/search?q=gascondensate" title=" gascondensate"> gascondensate</a>, <a href="https://publications.waset.org/abstracts/search?q=hydrogen" title=" hydrogen"> hydrogen</a>, <a href="https://publications.waset.org/abstracts/search?q=pyrolysis" title=" pyrolysis"> pyrolysis</a> </p> <a href="https://publications.waset.org/abstracts/57794/the-prospect-of-producing-hydrogen-by-electrolysis-of-idle-discharges-of-water-from-reservoirs-and-recycling-of-waste-gas-condensates" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/57794.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">310</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">103</span> Thermal Characteristics of Sewage Sludge to Develop an IDPG Technology</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Young%20Nam%20Chun">Young Nam Chun</a>, <a href="https://publications.waset.org/abstracts/search?q=Mun%20Sup%20Lim"> Mun Sup Lim</a>, <a href="https://publications.waset.org/abstracts/search?q=Byeo%20Ri%20Jeong"> Byeo Ri Jeong</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Sewage sludge is regarded as the residue produced by the waste water treatment process, during which liquids and solids are being separated. Thermal treatments are interesting techniques to stabilize the sewage sludge for disposal. Among the thermal treatments, pyrolysis and/or gasification has been being applied to the sewage sludge. The final goal of our NRF research is to develop a microwave In-line Drying-Pyrolysis-Gasification (IDPG) technology for the dewatered sewage sludge for the bio-waste to energy conversion. As a first step, the pyrolysis characteristics in a bench scale electric furnace was investigated at 800℃ for the dewatered sludge and dried sludge samples of which moisture contents are almost 80% and 0%, respectively. Main components of producer gas are hydrogen and carbon dioxide. Particularly, higher hydrogen for the dewatered sludge is shown as 75%. The hydrogen production for the dewatered sludge and dried sludge are 56% and 32%, respectively. However, the pyrolysis for the dried sludge produces higher carbon dioxide and other gases, while higher methane and carbon dioxide are given to 74% and 53%, respectively. Tar also generates during the pyrolysis process, showing lower value for case of the dewatered sludge. Gravimetric tar is 195 g/m3, and selected light tar like benzene, naphthalene, anthracene, pyrene are 9.4 g/m3, 2.1 g/m3, 0.5 g/m3, 0.3 g/m3, respectively. After the pyrolysis process, residual char for the dewatered sludge and dried sludge remain 1g and 1.3g, showing weight reduction rate of 93% and 57%, respectively. Through the results, this could be known that the dewatered sludge can be used to produce a clean hydrogen-rich gas fuel without the drying process. Therefore, the IDPG technology can be applied effectively to the energy conversion for dewater sludge waste without a drying pretreatment. Acknowledgment: This work was supported by the National Research Foundation of Korea(NRF) grant funded by the Korea government(MSIP) (No. 2015R1A2A2A03003044). <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=pyrolysis" title="pyrolysis">pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=gasification" title=" gasification"> gasification</a>, <a href="https://publications.waset.org/abstracts/search?q=sewage%20sludge" title=" sewage sludge"> sewage sludge</a>, <a href="https://publications.waset.org/abstracts/search?q=tar%20generation" title=" tar generation"> tar generation</a>, <a href="https://publications.waset.org/abstracts/search?q=producer%20gas" title=" producer gas"> producer gas</a>, <a href="https://publications.waset.org/abstracts/search?q=sludge%20char" title=" sludge char"> sludge char</a>, <a href="https://publications.waset.org/abstracts/search?q=biomass%20energy" title=" biomass energy"> biomass energy</a> </p> <a href="https://publications.waset.org/abstracts/38645/thermal-characteristics-of-sewage-sludge-to-develop-an-idpg-technology" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/38645.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">352</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">102</span> Stabilization of Pb, Cr, Cd, Cu and Zn in Solid Waste and Sludge Pyrolysis by Modified Vermiculite</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Yuxuan%20Yang">Yuxuan Yang</a>, <a href="https://publications.waset.org/abstracts/search?q=Zhaoping%20Zhong"> Zhaoping Zhong</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Municipal solid waste and sludge are important sources of waste energy and their proper disposal is of great importance. Pyrolysis can fully decompose solid wastes and sludge, and the pyrolysis products (charcoal, oil and gas) have important recovery values. Due to the complex composition of solid wastes and sludge, the pyrolysis process at high temperatures is prone to heavy metal emissions, which are harmful to humans and the environment and reduce the safety of pyrolysis products. In this paper, heavy metal emissions during pyrolysis of municipal sewage sludge, paper mill sludge, municipal domestic waste, and aged refuse at 450-650°C were investigated and the emissions and hazards of heavy metals (Pb, Cr, Cd, Cu and Zn) were effectively reduced by adding modified vermiculite as an additive. The vermiculite was modified by intercalation with cetyltrimethylammonium bromide, which resulted in more than twice the original layer spacing of the vermiculite. Afterward, the interpolated vermiculite was made into vermiculite flakes by exfoliation modification. After that, the expansion rate of vermiculite flakes was increased by Mg2+ modification and thermal activation. The expanded vermiculite flakes were acidified to improve the textural characteristics of the vermiculite. The modified vermiculite was analysed by XRD, FT-IR, BET and SEM to clarify the modification effect. The incorporation of modified vermiculite resulted in more than 80% retention of all heavy metals at 450°C. Cr, Cu and Zn were better retained than Pb and Cd. The incorporation of modified vermiculite effectively reduced the risk of heavy metals, and all risks were low for Pb, Cr, Cu and Zn. The toxicity of all heavy metals was greatly reduced by the incorporation of modified vermiculite and the morphology of heavy metals was transformed from Exchangeable and acid-soluble (F1) and Reducible (F2) to Oxidizable (F3) and Residual (F4). In addition, the increase in temperature favored the stabilization of heavy metal forms. This study provides a new insight into the cleaner use of energy and the safe management of solid waste. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=heavy%20metal" title="heavy metal">heavy metal</a>, <a href="https://publications.waset.org/abstracts/search?q=pyrolysis" title=" pyrolysis"> pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=vermiculite" title=" vermiculite"> vermiculite</a>, <a href="https://publications.waset.org/abstracts/search?q=solid%20waste" title=" solid waste"> solid waste</a> </p> <a href="https://publications.waset.org/abstracts/179601/stabilization-of-pb-cr-cd-cu-and-zn-in-solid-waste-and-sludge-pyrolysis-by-modified-vermiculite" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/179601.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">68</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">101</span> Effect of Boric Acid Content on the Structural and Optical Properties of In2O3 Films Prepared by Spray Pyrolysis Technique</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Mustafa%20%C3%96ztas">Mustafa Öztas</a>, <a href="https://publications.waset.org/abstracts/search?q=Metin%20Bedir"> Metin Bedir</a>, <a href="https://publications.waset.org/abstracts/search?q=Yahya%20%C3%96zdemir"> Yahya Özdemir</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Boron doped of In2O3 films were prepared by spray pyrolysis technique at 350 °C substrate temperature, which is a low cost and large area technique to be well-suited for the manufacture of solar cells, using boric acid (H3BO3) as dopant source, and their properties were investigated as a function of doping concentration. X-ray analysis showed that the films were polycrystalline fitting well with a hexagonal structure and have preferred orientation in (220) direction. The changes observed in the energy band gap and structural properties of the films related to the boric acid concentration are discussed in detail. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=spray%20pyrolysis" title="spray pyrolysis">spray pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=In2O3" title=" In2O3"> In2O3</a>, <a href="https://publications.waset.org/abstracts/search?q=boron" title=" boron"> boron</a>, <a href="https://publications.waset.org/abstracts/search?q=optical%20properties" title=" optical properties"> optical properties</a>, <a href="https://publications.waset.org/abstracts/search?q=boric%20acid" title=" boric acid"> boric acid</a> </p> <a href="https://publications.waset.org/abstracts/28202/effect-of-boric-acid-content-on-the-structural-and-optical-properties-of-in2o3-films-prepared-by-spray-pyrolysis-technique" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/28202.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">587</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">100</span> SO2 Sensing Performance of Nanostructured CdSnO3 Thin Films Prepared by Spray Pyrolysis Technique</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=R.%20H.%20Bari">R. H. Bari</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The nanostructured thin films of CdSnO3 are sensitive to change in their environment. CdSnO3 is successfully used as gas sensor due to the dependence of the electrical conductivity on the ambient gas composition. Nanostructured CdSnO3 thin films of different substrate temperature (300 0C, 350 0C, 400 0C and 450 0C) were deposited onto heated glass substrate by simple spray pyrolysis (SP) technique. Sensing elements of nanostructured CdSnO3 were annealed at 500 0C for 1 hrs. Characterization includes a different analytical technique such as, X-ray diffractogram (XRD), energy dispersive X-ray analysis (EDAX), and Field emission scanning electron microscope (FE-SEM). The average grain size observed from XRD and FF-SEM was found to be less than 18.36 and 23 nm respectively. The films sprayed at substrate temperature for 400 0C was observed to be most sensitive (S = 530) to SO2 for 500 ppm at 300 0C. The response and recovery time is 4 sec, 8 sec respectively. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=nanostructured%20CdSnO3" title="nanostructured CdSnO3">nanostructured CdSnO3</a>, <a href="https://publications.waset.org/abstracts/search?q=spray%20pyrolysis" title=" spray pyrolysis"> spray pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=SO2%20gas%20sensing" title=" SO2 gas sensing"> SO2 gas sensing</a>, <a href="https://publications.waset.org/abstracts/search?q=quick%20response" title=" quick response"> quick response</a> </p> <a href="https://publications.waset.org/abstracts/22298/so2-sensing-performance-of-nanostructured-cdsno3-thin-films-prepared-by-spray-pyrolysis-technique" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/22298.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">286</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">99</span> CuO Thin Films Deposition by Spray Pyrolysis: Influence of Precursor Solution Properties</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=M.%20Lamri%20Zeggar">M. Lamri Zeggar</a>, <a href="https://publications.waset.org/abstracts/search?q=F.%20Bourfaa"> F. Bourfaa</a>, <a href="https://publications.waset.org/abstracts/search?q=A.%20Adjimi"> A. Adjimi</a>, <a href="https://publications.waset.org/abstracts/search?q=F.%20Boutebakh"> F. Boutebakh</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20S.%20Aida"> M. S. Aida</a>, <a href="https://publications.waset.org/abstracts/search?q=N.%20Attaf"> N. Attaf</a> </p> <p class="card-text"><strong>Abstract:</strong></p> CuO thin films were deposited by spray ultrasonic pyrolysis with different precursor solution. Two staring solution slats were used namely: Copper acetate and copper chloride. The influence of these solutions on CuO thin films proprieties of is instigated. The X rays diffraction (XDR) analysis indicated that the films deposed with copper acetate are amorphous however the films elaborated with copper chloride have monoclinic structure. UV- Visible transmission spectra showed a strong absorbance of the deposited CuO thin films in the visible region. Electrical characterization has shown that CuO thin films prepared with copper acetate have a higher electrical conductivity. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=thin%20films" title="thin films">thin films</a>, <a href="https://publications.waset.org/abstracts/search?q=cuprous%20oxide" title=" cuprous oxide"> cuprous oxide</a>, <a href="https://publications.waset.org/abstracts/search?q=spray%20pyrolysis" title=" spray pyrolysis"> spray pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=precursor%20solution" title=" precursor solution"> precursor solution</a> </p> <a href="https://publications.waset.org/abstracts/36338/cuo-thin-films-deposition-by-spray-pyrolysis-influence-of-precursor-solution-properties" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/36338.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">311</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">98</span> Rubber Wood as a Potential Biomass Feedstock for Biochar via Slow Pyrolysis</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Adilah%20Shariff">Adilah Shariff</a>, <a href="https://publications.waset.org/abstracts/search?q=Radin%20Hakim"> Radin Hakim</a>, <a href="https://publications.waset.org/abstracts/search?q=Nurhayati%20Abdullah"> Nurhayati Abdullah</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Utilisation of biomass feedstock for biochar has received increasing attention because of their potential for carbon sequestration and soil amendment. The aim of this study is to investigate the characteristics of rubber wood as a biomass feedstock for biochar via slow pyrolysis process. This was achieved by using proximate, ultimate, and thermogravimetric analysis (TGA) as well as heating value, pH and lignocellulosic determination. Rubber wood contains 4.13 mf wt.% moisture, 86.30 mf wt.% volatile matter, 0.60 mf wt.% ash content, and 13.10 mf wt.% fixed carbon. The ultimate analysis shows that rubber wood consists of 44.33 mf wt.% carbon, 6.26 mf wt.% hydrogen, 19.31 mf wt.% nitrogen, 0.31 mf wt.% sulphur, and 29.79 mf wt.% oxygen. The higher heating value of rubber wood is 22.5 MJ/kg, and its lower heating value is 21.2 MJ/kg. At 27 °C, the pH value of rubber wood is 6.83 which is acidic. The lignocellulosic analysis revealed that rubber wood composition consists of 2.63 mf wt.% lignin, 20.13 mf wt.% cellulose, and 65.04 mf wt.% hemicellulose. The volatile matter to fixed carbon ratio is 6.58. This led to a biochar yield of 25.14 wt.% at 500 °C. Rubber wood is an environmental friendly feedstock due to its low sulphur content. Rubber wood therefore is a suitable and a potential feedstock for biochar production via slow pyrolysis. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=biochar" title="biochar">biochar</a>, <a href="https://publications.waset.org/abstracts/search?q=biomass" title=" biomass"> biomass</a>, <a href="https://publications.waset.org/abstracts/search?q=rubber%20wood" title=" rubber wood"> rubber wood</a>, <a href="https://publications.waset.org/abstracts/search?q=slow%20pyrolysis" title=" slow pyrolysis"> slow pyrolysis</a> </p> <a href="https://publications.waset.org/abstracts/53243/rubber-wood-as-a-potential-biomass-feedstock-for-biochar-via-slow-pyrolysis" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/53243.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">319</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">97</span> Energy Conversion for Sewage Sludge by Microwave Heating Pyrolysis and Gasification</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Young%20Nam%20Chun">Young Nam Chun</a>, <a href="https://publications.waset.org/abstracts/search?q=Soo%20Hyuk%20Yun"> Soo Hyuk Yun</a>, <a href="https://publications.waset.org/abstracts/search?q=Byeo%20Ri%20Jeong"> Byeo Ri Jeong</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The recent gradual increase in the energy demand is mostly met by fossil fuel, but the research on and development of new alternative energy sources is drawing much attention due to the limited fossil fuel supply and the greenhouse gas problem. Biomass is an eco-friendly renewable energy that can achieve carbon neutrality. The conversion of the biomass sludge wastes discharged from a wastewater treatment plant to clean energy is an important green energy technology in an eco-friendly way. In this NRF study, a new type of microwave thermal treatment was developed to apply the biomass-CCS technology to sludge wastes. For this, the microwave dielectric heating characteristics were examined to investigate the energy conversion mechanism for the combined drying-pyrolysis/gasification of the dewatered wet sludge. The carbon dioxide gasification was tested using the CO2 captured from the pre-combustion capture process. In addition, the results of the pyrolysis and gasification test with the wet sludge were analyzed to compare the microwave energy conversion results with the results of the use of the conventional heating method. Gas was the largest component of the product of both pyrolysis and gasification, followed by sludge char and tar. In pyrolysis, the main components of the producer gas were hydrogen and carbon monoxide, and there were some methane and hydrocarbons. In gasification, however, the amount of carbon monoxide was greater than that of hydrogen. In microwave gasification, a large amount of heavy tar was produced. The largest amount of benzene among light tar was produced in both pyrolysis and gasification. NH3 and HCN which are the precursors of NOx, generated as well. In microwave heating, the sludge char had a smooth surface, like that of glass, and in the conventional heating method with an electric furnace, deep cracks were observed in the sludge char. This indicates that the gas obtained from the microwave pyrolysis and gasification of wet sewage sludge can be used as fuel, but the heavy tar and NOx precursors in the gas must be treated. Sludge char can be used as solid fuel or as a tar reduction adsorbent in the process if necessary. This work supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIP) (No. 2015R1R1A2A2A03003044). <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=microwave%20heating" title="microwave heating">microwave heating</a>, <a href="https://publications.waset.org/abstracts/search?q=pyrolysis%20gasification" title=" pyrolysis gasification"> pyrolysis gasification</a>, <a href="https://publications.waset.org/abstracts/search?q=precombustion%20CCS" title=" precombustion CCS"> precombustion CCS</a>, <a href="https://publications.waset.org/abstracts/search?q=sewage%20sludge" title=" sewage sludge"> sewage sludge</a>, <a href="https://publications.waset.org/abstracts/search?q=biomass%20energy" title=" biomass energy"> biomass energy</a> </p> <a href="https://publications.waset.org/abstracts/56659/energy-conversion-for-sewage-sludge-by-microwave-heating-pyrolysis-and-gasification" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/56659.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">322</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">96</span> The Reducing Agent of Glycerol for the Reduction of Metal Oxides under Microwave Heating</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Kianoosh%20Shojae">Kianoosh Shojae</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In recent years, the environmental challenges due to the excessive use of fossil fuels have led to heightened greenhouse gas production. In response, biodiesel has emerged as a cleaner alternative, offering reduced pollutant emissions compared to traditional fuels. The large-scale production of biodiesel, involving ester exchange of animal fats or vegetable oils, results in a surplus of crude glycerin. With environmental regulations on the rise and an increasing demand for biodiesel, glycerin production has seen a significant upswing. This paper focuses on the economic significance of glycerin through its pyrolysis as a raw material, particularly in the synthesis of metals. As industries pivoted towards cleaner fuels, glycerin, as a byproduct of biodiesel production, is poised to remain a cost-effective and surplus product. In this work, for evaluating the possible performance of using the gaseous products from the pyrolysis reaction of glycerol, we concerned the glycerin pyrolysis reactions, emphasizing the catalytic role of activated carbon, various reaction pathways and the impact of carrier gas flow rate on hydrogen production, providing valuable insights into the evolving landscape of sustainable fuel alternatives. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=biodiesel" title="biodiesel">biodiesel</a>, <a href="https://publications.waset.org/abstracts/search?q=glycerin%20pyrolysis" title=" glycerin pyrolysis"> glycerin pyrolysis</a>, <a href="https://publications.waset.org/abstracts/search?q=activated%20carbon%20catalysis" title=" activated carbon catalysis"> activated carbon catalysis</a>, <a href="https://publications.waset.org/abstracts/search?q=syngas" title=" syngas"> syngas</a> </p> <a href="https://publications.waset.org/abstracts/181958/the-reducing-agent-of-glycerol-for-the-reduction-of-metal-oxides-under-microwave-heating" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/181958.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">54</span> </span> </div> </div> <ul class="pagination"> <li class="page-item disabled"><span class="page-link">&lsaquo;</span></li> <li class="page-item active"><span class="page-link">1</span></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=pyrolysis&page=2">2</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=pyrolysis&page=3">3</a></li> <li class="page-item"><a class="page-link" href="https://publications.waset.org/abstracts/search?q=pyrolysis&page=4">4</a></li> <li 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