Fertilizer security and safety

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href="/crop-nutrition/">Crop nutrition</a><span class="icon icon-carret-right"></span></p> </div> <div class="megamenu-subcolumn__wrap"> <div class="megamenu-subcolumn"> <div class="megamenu-subcolumn__item"> <p class="h3"><a href="/crop-nutrition/fertilizers/">Fertilizers</a></p> <ul> <li> <a href="/crop-nutrition/fertilizers/yaramila/">YaraMila Compound Fertilizers</a> </li> <li> <a href="/crop-nutrition/fertilizers/yaraliva/">YaraLiva Range - Calcium Nitrate Fertilizers</a> </li> <li> <a href="/crop-nutrition/fertilizers/yaratera/">YaraTera Range – Soluble Fertilizers for Fertigation</a> </li> <li> <a href="/crop-nutrition/fertilizers/yaravera/">YaraVera - Urea-based fertilizers</a> </li> <li> <a href="/crop-nutrition/fertilizers/yaravita/">YaraVita - Micronutrient foliar fertilizers</a> </li> </ul> </div> </div> <div class="megamenu-subcolumn"> <div class="megamenu-subcolumn__item"> <p class="h3"><a href="/crop-nutrition/fertilizer-handling-and-safety/">Fertilizer handling and safety</a></p> <ul> <li> <a href="/crop-nutrition/fertilizer-handling-and-safety/blended-fertilizer-quality/">Blended fertilizer quality</a> </li> <li> <a href="/crop-nutrition/fertilizer-handling-and-safety/fertilizer-labelling/">Fertilizer labelling</a> </li> <li> <a href="/crop-nutrition/fertilizer-handling-and-safety/fertilizer-security-and-safety/">Fertilizer security and safety</a> </li> <li> <a href="/crop-nutrition/fertilizer-handling-and-safety/fertilizer-spreading/">Fertilizer spreading</a> </li> <li> <a href="/crop-nutrition/fertilizer-handling-and-safety/fertilizer-stewardship/">Fertilizer stewardship</a> </li> <li> <a href="/crop-nutrition/fertilizer-handling-and-safety/fertilizer-storage/">Fertilizer storage</a> </li> <li> <a href="/crop-nutrition/fertilizer-handling-and-safety/fertilizer-technology/">Fertilizer technology</a> </li> <li> <a href="/crop-nutrition/fertilizer-handling-and-safety/handling-and-transport/">Handling and Transport</a> </li> <li> <a href="/crop-nutrition/fertilizer-handling-and-safety/physical-properties-of-fertilizers/">Physical properties of fertilizers</a> </li> <li> <a href="/crop-nutrition/fertilizer-handling-and-safety/safe-use-of-fertilizer/">Safe use of fertilizer</a> </li> </ul> </div> </div> <div class="megamenu-subcolumn"> <div class="megamenu-subcolumn__item"> <p class="h3"><a href="/crop-nutrition/crop-information/">Crop solutions</a></p> <ul> <li> <a href="/crop-nutrition/banana/">Banana</a> </li> <li> <a href="/crop-nutrition/broccoli/">Broccoli</a> </li> <li> <a href="/crop-nutrition/cabbage/">Cabbage</a> </li> <li> <a href="/crop-nutrition/cacao/">Cacao</a> </li> <li> <a href="/crop-nutrition/carrots/">Carrots</a> </li> <li> <a href="/crop-nutrition/chili/">Chili</a> </li> <li> <a href="/crop-nutrition/citrus/">Citrus</a> </li> <li> <a href="/crop-nutrition/corn/">Corn</a> </li> <li> <a href="/crop-nutrition/mango/">Mango</a> </li> <li> <a href="/crop-nutrition/oil-palm/">Oil Palm</a> </li> <li> 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class="common-block common--no-image"> <div class="common-body"> <div class="common-heading"> <h1 data-cy="article-page-heading">Fertilizer security and safety</h1> </div> </div> </div> </div> </div> <div class="col-md-8 mx-auto"> <div class="article"> <div class="common-block common--no-image mb-default"> <div class="common-body"> <div class="common-text common--text-intro"> New chemical knowledge and new chemical legislations can cause phosphate fertilizers containing ammonium nitrate and other ingredients to be classified. These types of product might be classified as hazardous to humans and also to the environment. </div> <br /> <div class="common-text popout-image-container" data-cy="article-page-main-body"> <h2>Fertilizer Safety</h2> <p>Over the years ammonium nitrate fertilizers have been involved in several accidents that have influenced the legislation of transport, storage and handling. Decompositions during transport and in storage have caused release of toxic gases and hazardous situations.</p> <p><img class="align-left lazyload " src="" alt="Talking about fertiliser safety next to a Yara tanker" width="312" height="207" data-src="/link/5cff3e0520cb4e11a488005b3e98c8bb.aspx" /></p> <p>United Nation has issued the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). The GHS is harmonized with the UN Recommendation on the Transport of Dangerous Goods – Model Regulation, regarding test methods and identifying hazards. Europe has adapted the European version of the GHS and issued the <a title="00 PAGE TITLE Fertiliser Product Labeling" href="http://www.yara.co.uk/crop-nutrition/fertiliser-information/fertiliser-labeling/default.aspx">Classification and Labelling of Products (CLP)</a>.</p> <p>The international UN ‘Recommendations on the Transport of Dangerous Goods’ (<a href="http://www.unece.org/trans/danger/danger.html">www.unece.org/trans/danger/danger.html</a>) is adopted in international fertilizer transport legislation by IMO (shipping), ADR (road), RID (rail), ADN(R) (barges) and IATA (air) regulations. National and local regulations apply for storage of fertilizers. The SEVESO-directive gives guidance on storage volumes /risk assessment for hazardous products within the EU.</p> <p>To ensure correct information about a product or raw materials used in the production or processing of fertilizers, the best thing to do is to request the new updated version of the safety data sheets (SDS) compiled according to legislations for the country where the products are used. A correct safety data sheet will have information about possible hazards and recommendation regarding handling and storage, unwanted situations and disposal. A correct safety data sheet will also contain transport classification information.</p> <h3>Straight Ammonium Nitrate (High nitrate fertilizer)</h3> <p>AN 33.5 is classified as an oxidizer (Class 5.1) by UN due to its high ammonium nitrate content. Special regulation for storage is given by national authorities. Yara ammonium nitrate based fertilizers pass the resistance to detonation test, and have very high resistance to detonation. When bagged fertilizers are involved in a fire, the bags may melt and break, but they will have insignificant effect on the fire.</p> <h3>Handling of spillage and reject material containing Ammonium Nitrate</h3> <p>Spillage from conveyor belts or from bags should be collected quickly, handled and sold as normal product if free from contamination and meeting the requirement of the fertilizer regulations.</p> <p><img class="align-right lazyload " src="" alt="Loading fertiliser bags" width="300" height="266" data-src="/link/c567568bf30e4716985f8304dbc2ea87.aspx" /></p> <p>If not, the material shall be dissolved or be made inert. If seriously contaminated, product should be treated as a waste material, and hazardous material should be handled according to local legislation.</p> <p>In addition to the CLP Regulation in Europe, storage of ammonium nitrate containing fertilizers are regulated under the COMAH (Seveso) directive. Some European countries like Germany and France have additional national regulations, TRGS in Germany, Code de l’environment in France, controlling the storage of these products. These types of national regulations are becoming more common and need to be checked locally.</p> <h3>Ammonium Nitrate in NPK</h3> <p>Ammonium nitrate in NPK fertilizers can decompose at high temperatures. Exothermic reactions cause evolution of heat and gases from the fertilizer after an initial period with decreasing pH. The rate of decomposition accelerates in the presence of chloride, organic substances and some metal ions – particularly copper (Cu2+). The decomposition is retarded in the presence of phosphate, carbonaceous material and high pH.</p> <p>Some ammonium nitrate based NPK fertilizers exhibit characteristics of self-sustaining decomposition (SSD). SSD can be initiated by accidental heating (> 120°C) over time for some fertilizers. Such decomposition will continue after the heat source has been eliminated, and can be very difficult to extinguish. The decomposition is normally not dangerous in itself, but the released gas contains toxic components (e.g. Cl2, HCl, NO</p> <div class="body-copy span-4-4 last"> <h3>Calcium Nitrate fertilizer</h3> <p>CN fertilizer contains approximately 15 % crystal water that minimises the oxidising properties of the material. fertilizers based on nitric acid ammonium calcium are classified in GHS/CLP as “Acute Tox, 4 H302., Eye Damage/Irritation, H318”. The product bags are labelled according to the appropriate chemical regulations. No severe accident has ever occurred with CN fertilizer.</p> <h3>Urea products</h3> <p>Urea products are not classified as hazardous material according to (<a title="00 PAGE TITLE Fertiliser Product Labeling" href="http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2008:353:0001:1355:en:PDF">EC No. 1272/2008) , CLP</a>) and the UN transport regulations, but are potentially dangerous because they can release ammonia if exposed to strong heat. Urea should not be mixed with other chemicals, mixing with Nitric acid may be particularly hazardous.</p> <h2 class="header-section">Preventing fertilizer Misuse</h2> <p>Buildings and areas for storage or handling of fertilizers should be secured properly to keep unauthorised people away. fertilizers containing ammonium nitrate or other nitrates can be used to manufacture explosives, which has occurred in several terror attacks worldwide.</p> <p><img class="align-left lazyload " src="" alt="Photo of a packlock securing fertiliser" width="252" height="168" data-src="/link/d82358c2b98c4622942d73790539d832.aspx" /> </p> <p>The availability of such products is therefore restricted by law. Mineral fertilizer containing 16% or more ammonium nitrate is not available to the public. Only farmers and other professional users are given access to such products. (<a href="http://eur-lex.europa.eu/legal-content/EN/TXT/?qid=1397640331163&uri=CELEX:32014R0317" target="_blank" rel="noopener">EU Regulation 1907/2006, REACH</a>)</p> <p>A simple rule of thumb is that if both the nitrate nitrogen (NO3-N) and the concentration of ammonium nitrogen (NH4-N) is 8% or higher, then the product contains more than 16% nitrogen in the form of ammonium nitrate.</p> <p>Simple advice for preventing crime: </p> <p>•   Store the mineral fertilizer in locked rooms <br />•   Cover the mineral fertilizer that must be kept outdoors <br />•   Check regularly if you lack the mineral, ie if something may have been stolen.</p> <p>Do not sell fertilizers on to someone if you are not sure whether it will be used professionally.</p> </div> </div> </div> </div> </div> </div> </div> <div class="row"> <div class="col-md-12"> </div> </div> </div> <script type="application/ld+json"> {"@context":"https://schema.org","@type":"Article","description":"New chemical knowledge and new chemical legislations can cause phosphate fertilizers containing ammonium nitrate and other ingredients to be classified. 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shadow-hover--sm text-center country-picker-link" href="https://www.yara.pt/" title="Portugal"> <img src="/Frontend/assets/images/flags/Portugal.svg" alt="Flag of Portugal" /> <div> Portugal </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.ro/" title="România"> <img src="/Frontend/assets/images/flags/Romania.svg" alt="Flag of Romania" /> <div> România </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.rs/" title="Serbia"> <img src="/Frontend/assets/images/flags/Serbia.svg" alt="Flag of Serbia" /> <div> Serbia </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.fi/" title="Suomi"> <img src="/Frontend/assets/images/flags/Finland.svg" alt="Flag of Finland" /> <div> Suomi </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.se/" title="Sverige"> <img src="/Frontend/assets/images/flags/Sweden.svg" alt="Flag of Sweden" /> <div> Sverige </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.co.uk/" title="United Kingdom"> <img src="/Frontend/assets/images/flags/UnitedKingdom.svg" alt="Flag of UnitedKingdom" /> <div> United Kingdom </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.gr/" title="Ελλάς"> <img src="/Frontend/assets/images/flags/Greece.svg" alt="Flag of Greece" /> <div> Ελλάς </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.bg/" title="България"> <img src="/Frontend/assets/images/flags/Bulgaria.svg" alt="Flag of Bulgaria" /> <div> България </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.ua/" title="Україна"> <img src="/Frontend/assets/images/flags/Ukraine.svg" alt="Flag of Ukraine" /> <div> Україна </div> </a> </div> </div> </div> </div> <div class="row section section--sm" id="Americas"> <div class="col-md-12"> <div class="common-heading mb-sm"> <p class="h2 color-light-blue"> Americas </p> </div> <div class="row"> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.com.ar/" title="Argentina"> <img src="/Frontend/assets/images/flags/Argentina.svg" alt="Flag of Argentina" /> <div> Argentina </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.bo/" title="Bolivia"> <img src="/Frontend/assets/images/flags/Bolivia.svg" alt="Flag of Bolivia" /> <div> Bolivia </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yarabrasil.com.br/" title="Brasil"> <img src="/Frontend/assets/images/flags/Brazil.svg" alt="Flag of Brazil" /> <div> Brasil </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yaracanada.ca/" title="Canada En"> <img src="/Frontend/assets/images/flags/Canada.svg" alt="Flag of Canada" /> <div> Canada En </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yaracanada.ca/fr-ca/" title="Canada Fr"> <img src="/Frontend/assets/images/flags/Canada.svg" alt="Flag of Canada" /> <div> Canada Fr </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.cl/" title="Chile"> <img src="/Frontend/assets/images/flags/Chile.svg" alt="Flag of Chile" /> <div> Chile </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.com.co/" title="Colombia"> <img src="/Frontend/assets/images/flags/Colombia.svg" alt="Flag of Colombia" /> <div> Colombia </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.cr/" title="Costa Rica"> <img src="/Frontend/assets/images/flags/CostaRica.svg" alt="Flag of CostaRica" /> <div> Costa Rica </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.com.ec/" title="Ecuador"> <img src="/Frontend/assets/images/flags/Ecuador.svg" alt="Flag of Ecuador" /> <div> Ecuador </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.com.gt/" title="Guatemala"> <img src="/Frontend/assets/images/flags/Guatemala.svg" alt="Flag of Guatemala" /> <div> Guatemala </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.com.mx/" title="México"> <img src="/Frontend/assets/images/flags/Mexico.svg" alt="Flag of Mexico" /> <div> México </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.com.pe/" title="Perú"> <img src="/Frontend/assets/images/flags/Peru.svg" alt="Flag of Peru" /> <div> Perú </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.us/" title="United States"> <img src="/Frontend/assets/images/flags/UnitedStates.svg" alt="Flag of UnitedStates" /> <div> United States </div> </a> </div> </div> </div> </div> <div class="row section section--sm" id="AsiaAndOceania"> <div class="col-md-12"> <div class="common-heading mb-sm"> <p class="h2 color-light-blue"> Asia and Oceania </p> </div> <div class="row"> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.com.au/" title="Australia"> <img src="/Frontend/assets/images/flags/Australia.svg" alt="Flag of Australia" /> <div> Australia </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.in/" title="India"> <img src="/Frontend/assets/images/flags/India.svg" alt="Flag of India" /> <div> India </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.id/" title="Indonesia"> <img src="/Frontend/assets/images/flags/Indonesia.svg" alt="Flag of Indonesia" /> <div> Indonesia </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.kz/" title="Kazakhstan"> <img src="/Frontend/assets/images/flags/Kazakhstan.svg" alt="Flag of Kazakhstan" /> <div> Kazakhstan </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.my/" title="Malaysia"> <img src="/Frontend/assets/images/flags/Malaysia.svg" alt="Flag of Malaysia" /> <div> Malaysia </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.com.mm/" title="Myanmar"> <img src="/Frontend/assets/images/flags/Myanmar.svg" alt="Flag of Myanmar" /> <div> Myanmar </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.co.nz/" title="New Zealand"> <img src="/Frontend/assets/images/flags/NewZealand.svg" alt="Flag of NewZealand" /> <div> New Zealand </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="/" title="Philippines"> <img src="/Frontend/assets/images/flags/Philippines.svg" alt="Flag of Philippines" /> <div> Philippines </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.vn/" title="Vietnam"> <img src="/Frontend/assets/images/flags/Vietnam.svg" alt="Flag of Vietnam" /> <div> Vietnam </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.co.th/" title="ไทย"> <img src="/Frontend/assets/images/flags/Thailand.svg" alt="Flag of Thailand" /> <div> ไทย </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.kr/" title="대한민국"> <img src="/Frontend/assets/images/flags/SouthKorea.svg" alt="Flag of SouthKorea" /> <div> 대한민국 </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.com.cn/" title="中国"> <img src="/Frontend/assets/images/flags/China.svg" alt="Flag of China" /> <div> 中国 </div> </a> </div> </div> </div> </div> <div class="row section section--sm" id="Africa"> <div class="col-md-12"> <div class="common-heading mb-sm"> <p class="h2 color-light-blue"> Africa </p> </div> <div class="row"> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.com.gh/" title="Ghana"> <img src="/Frontend/assets/images/flags/Ghana.svg" alt="Flag of Ghana" /> <div> Ghana </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.co.ke/" title="Kenya"> <img src="/Frontend/assets/images/flags/Kenya.svg" alt="Flag of Kenya" /> <div> Kenya </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.ma/" title="Maroc"> <img src="/Frontend/assets/images/flags/Morocco.svg" alt="Flag of Morocco" /> <div> Maroc </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.co.za/" title="South Africa"> <img src="/Frontend/assets/images/flags/SouthAfrica.svg" alt="Flag of SouthAfrica" /> <div> South Africa </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.co.tz/" title="Tanzania"> <img src="/Frontend/assets/images/flags/Tanzania.svg" alt="Flag of Tanzania" /> <div> Tanzania </div> </a> </div> <div class="col-md-2 mb-2"> <a class="flag-container shadow-hover shadow-hover--sm text-center country-picker-link" href="https://www.yara.co.zm/" title="Zambia"> <img src="/Frontend/assets/images/flags/Zambia.svg" alt="Flag of Zambia" /> <div> Zambia </div> </a> </div> </div> </div> </div> </div> </div> </div> </div> </div> <script defer="defer" src="/Util/Find/epi-util/find.js"></script> <script> document.addEventListener('DOMContentLoaded',function(){if(typeof FindApi === 'function'){var api = new 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