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Zinc–bromine battery - Wikipedia
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data-mw-deduplicate="TemplateStyles:r1257001546">.mw-parser-output .infobox-subbox{padding:0;border:none;margin:-3px;width:auto;min-width:100%;font-size:100%;clear:none;float:none;background-color:transparent}.mw-parser-output .infobox-3cols-child{margin:auto}.mw-parser-output .infobox .navbar{font-size:100%}@media screen{html.skin-theme-clientpref-night .mw-parser-output .infobox-full-data:not(.notheme)>div:not(.notheme)[style]{background:#1f1f23!important;color:#f8f9fa}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .infobox-full-data:not(.notheme) div:not(.notheme){background:#1f1f23!important;color:#f8f9fa}}@media(min-width:640px){body.skin--responsive .mw-parser-output .infobox-table{display:table!important}body.skin--responsive .mw-parser-output .infobox-table>caption{display:table-caption!important}body.skin--responsive .mw-parser-output .infobox-table>tbody{display:table-row-group}body.skin--responsive .mw-parser-output .infobox-table tr{display:table-row!important}body.skin--responsive .mw-parser-output .infobox-table th,body.skin--responsive .mw-parser-output .infobox-table td{padding-left:inherit;padding-right:inherit}}</style><table class="infobox"><caption class="infobox-title">Zinc–bromine battery</caption><tbody><tr><th scope="row" class="infobox-label"><a href="/wiki/Specific_energy" title="Specific energy">Specific energy</a></th><td class="infobox-data">60–85 <a href="/wiki/Watt-hour" class="mw-redirect" title="Watt-hour">W·h</a>/<a href="/wiki/Kg" class="mw-redirect" title="Kg">kg</a></td></tr><tr><th scope="row" class="infobox-label"><a href="/wiki/Energy_density" title="Energy density">Energy density</a></th><td class="infobox-data">15–65 W·h/<a href="/wiki/Litre" title="Litre">L</a> (56–230 kJ/L)<sup id="cite_ref-Khor_et_al_2018_1-0" class="reference"><a href="#cite_note-Khor_et_al_2018-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup></td></tr><tr><th scope="row" class="infobox-label">Charge/discharge efficiency</th><td class="infobox-data">75.9%<sup id="cite_ref-2" class="reference"><a href="#cite_note-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup></td></tr><tr><th scope="row" class="infobox-label">Energy/consumer-price</th><td class="infobox-data">US$400/kW·h (US$0.11/kJ)<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">[<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (December 2010)">citation needed</span></a></i>]</sup></td></tr><tr><th scope="row" class="infobox-label">Cycle durability</th><td class="infobox-data">>6,000 <a href="/wiki/Charge_cycle" title="Charge cycle">cycles</a></td></tr><tr><th scope="row" class="infobox-label">Nominal cell voltage</th><td class="infobox-data">1.8 <a href="/wiki/Volt" title="Volt">V</a></td></tr></tbody></table> <p>A <b> zinc-bromine battery</b> is a <a href="/wiki/Rechargeable_battery" title="Rechargeable battery">rechargeable battery</a> system that uses the reaction between <a href="/wiki/Zinc" title="Zinc">zinc</a> metal and <a href="/wiki/Bromine" title="Bromine">bromine</a> to produce <a href="/wiki/Electric_current" title="Electric current">electric current</a>, with an <a href="/wiki/Electrolyte" title="Electrolyte">electrolyte</a> composed of an aqueous solution of <a href="/wiki/Zinc_bromide" title="Zinc bromide">zinc bromide</a>. Zinc has long been used as the negative electrode of <a href="/wiki/Primary_cell" class="mw-redirect" title="Primary cell">primary cells</a>. It is a widely available, relatively inexpensive metal. It is rather stable in contact with neutral and alkaline aqueous solutions. For this reason, it is used today in <a href="/wiki/Zinc%E2%80%93carbon_battery" title="Zinc–carbon battery">zinc–carbon</a> and <a href="/wiki/Alkaline_battery" title="Alkaline battery">alkaline</a> primaries. </p><p>The leading potential application is stationary energy storage, either for the <a href="/wiki/Grid_energy_storage" title="Grid energy storage">grid</a>, or for domestic or <a href="/wiki/Stand-alone_power_system" title="Stand-alone power system">stand-alone power systems</a>. The aqueous <a href="/wiki/Electrolyte" title="Electrolyte">electrolyte</a> makes the system less prone to <a href="/wiki/Lithium-ion_battery#Safety" title="Lithium-ion battery">overheating and fire</a> compared with lithium-ion battery systems. </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="Overview">Overview</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit&section=1" title="Edit section: Overview"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Zinc–bromine batteries can be split into two groups: <a href="/wiki/Flow_batteries" class="mw-redirect" title="Flow batteries">flow batteries</a> and non-flow batteries. </p><p>Primus Power (US) is active in commercializing flow batteries, while Gelion (Australia) and EOS Energy Enterprises (US) are <a href="/wiki/Rechargeable_battery#Other_experimental_types" title="Rechargeable battery">developing and commercializing</a> non-flow systems. </p> <div class="mw-heading mw-heading2"><h2 id="Features">Features</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit&section=2" title="Edit section: Features"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Zinc–bromine batteries share six advantages over lithium-ion storage systems: </p> <ul><li>100% depth of discharge capability on a daily basis.<sup id="cite_ref-FOOTNOTERoseFerreira4_3-0" class="reference"><a href="#cite_note-FOOTNOTERoseFerreira4-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup></li> <li>Little capacity degradation, enabling 5000+ cycles</li> <li>Low fire risk, since the electrolytes are non-flammable</li> <li>No need for cooling systems</li> <li>Low-cost and readily available battery materials</li> <li>Easy end-of-life recycling using existing processes</li></ul> <p>They share four disadvantages: </p> <ul><li>Lower energy density</li> <li>Lower round-trip efficiency (partially offset by the energy needed to run cooling systems).</li> <li>The need to be fully discharged every few days to prevent zinc dendrites, which can puncture the separator.<sup id="cite_ref-FOOTNOTERoseFerreira4_3-1" class="reference"><a href="#cite_note-FOOTNOTERoseFerreira4-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup></li> <li>Lower charge and discharge rates</li></ul> <p>These features make zinc-bromine batteries unsuitable for many mobile applications (that typically require high charge/discharge rates and low weight), but suitable for stationary energy storage applications such as daily cycling to support <a href="/wiki/Solar_power" title="Solar power">solar power</a> generation, <a href="/wiki/Off-the-grid" title="Off-the-grid">off-grid</a> systems, and <a href="/wiki/Load_management" title="Load management">load shifting</a>. </p> <div class="mw-heading mw-heading2"><h2 id="Types">Types</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit&section=3" title="Edit section: Types"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="mw-heading mw-heading3"><h3 id="Flow">Flow</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit&section=4" title="Edit section: Flow"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>The zinc–bromine <a href="/wiki/Flow_battery" title="Flow battery">flow battery</a> (ZBRFB) is a hybrid flow battery. A solution of <a href="/wiki/Zinc_bromide" title="Zinc bromide">zinc bromide</a> is stored in two tanks. When the battery is charged or discharged, the solutions (electrolytes) are pumped through a reactor stack from one tank to the other. One tank is used to store the electrolyte for positive electrode reactions, and the other stores the negative. <a href="/wiki/Energy_density" title="Energy density">Energy densities</a> range between 60 and 85 W·h/kg.<sup id="cite_ref-Khor_et_al_2018_1-1" class="reference"><a href="#cite_note-Khor_et_al_2018-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> </p><p>The aqueous electrolyte is composed of <a href="/wiki/Zinc_bromide" title="Zinc bromide">zinc bromide</a> salt dissolved in water. During charge, metallic zinc is plated from the electrolyte solution onto the negative electrode (carbon felt in older designs, titanium mesh in modern) surfaces in the cell stacks. <a href="/wiki/Bromide" title="Bromide">Bromide</a> is converted to <a href="/wiki/Bromine" title="Bromine">bromine</a> at the positive electrode surface and stored in a safe, <span class="clarify-content" style="padding-left:0.1em; padding-right:0.1em; color:var(--color-subtle, #54595d); border:1px solid var(--border-color-subtle, #c8ccd1);">chemically complexed organic phase</span><sup class="noprint Inline-Template Template-Clarify" style="margin-left:0.1em; white-space:nowrap;">[<i><a href="/wiki/Wikipedia:Please_clarify" title="Wikipedia:Please clarify"><span title="What "chemically complexed organic phase" is it stored in? (January 2024)">clarify</span></a></i>]</sup>. Older ZBRFB cells used <a href="/wiki/Synthetic_membrane" title="Synthetic membrane">polymer membranes</a> (microporous polymers, <a href="/wiki/Nafion" title="Nafion">Nafion</a>, etc.) More recent designs eliminate the membrane.<sup id="cite_ref-4" class="reference"><a href="#cite_note-4"><span class="cite-bracket">[</span>4<span class="cite-bracket">]</span></a></sup> The battery stack is typically made of carbon-filled plastic bipolar plates (e.g. 60 cells), and is enclosed into a <a href="/wiki/High-density_polyethylene" title="High-density polyethylene">high-density polyethylene</a> (HDPE) container. The battery can be regarded as an <a href="/wiki/Electroplating" title="Electroplating">electroplating</a> machine. During charging, zinc is electroplated onto conductive electrodes, while bromine is formed. On discharge, the process reverses: the metallic zinc plated on the negative electrodes dissolves in the electrolyte and is available to be plated again at the next <a href="/wiki/Charge_cycle" title="Charge cycle">charge cycle</a>. It can be left fully discharged indefinitely. Self-discharge does not occur in a fully charged state when the stack is kept dry. </p> <div class="mw-heading mw-heading4"><h4 id="Features_2">Features</h4><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit&section=5" title="Edit section: Features"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <figure class="mw-default-size" typeof="mw:File/Thumb"><a href="/wiki/File:Redflow_ZBM2_zinc-bromine_flow_batteries_in_a_performance_testing_lab.jpg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/3/31/Redflow_ZBM2_zinc-bromine_flow_batteries_in_a_performance_testing_lab.jpg/440px-Redflow_ZBM2_zinc-bromine_flow_batteries_in_a_performance_testing_lab.jpg" decoding="async" width="440" height="330" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/3/31/Redflow_ZBM2_zinc-bromine_flow_batteries_in_a_performance_testing_lab.jpg/660px-Redflow_ZBM2_zinc-bromine_flow_batteries_in_a_performance_testing_lab.jpg 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/3/31/Redflow_ZBM2_zinc-bromine_flow_batteries_in_a_performance_testing_lab.jpg/880px-Redflow_ZBM2_zinc-bromine_flow_batteries_in_a_performance_testing_lab.jpg 2x" data-file-width="4032" data-file-height="3024" /></a><figcaption>RedFlow ZBM2 10kWh flow batteries in a performance testing lab</figcaption></figure> <p>In addition to the general advantages of the chemistry, zinc–bromine flow batteries have two significant advantages: </p> <ul><li>They are scalable to large storage capacity through larger tanks and stacks.</li> <li>Individual parts can be serviced or replaced – for example the pump, tanks, or electrolyte.</li></ul> <p>Flow batteries also have specific disadvantages: </p> <ul><li>Reset: Every 1–4 cycles the terminals must be shorted across a low-impedance shunt while running the electrolyte pump, to fully remove zinc from battery plates.<sup id="cite_ref-FOOTNOTERoseFerreira4_3-2" class="reference"><a href="#cite_note-FOOTNOTERoseFerreira4-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup></li> <li>Low areal power: (<0.2 W/cm<sup>2</sup>) during both charge and discharge, which increases the cost of power.<sup id="cite_ref-5" class="reference"><a href="#cite_note-5"><span class="cite-bracket">[</span>5<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-Nakatsuji-MatherSaha2012_6-0" class="reference"><a href="#cite_note-Nakatsuji-MatherSaha2012-6"><span class="cite-bracket">[</span>6<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-SureshKesavan2014_7-0" class="reference"><a href="#cite_note-SureshKesavan2014-7"><span class="cite-bracket">[</span>7<span class="cite-bracket">]</span></a></sup></li> <li>Low Round Trip Efficiency: 70-80%, significantly lower than Li-ion batteries, which typically reach 90% or more.</li> <li>Low energy-density:</li> <li>Complex construction with moving parts</li></ul> <div class="mw-heading mw-heading4"><h4 id="Design">Design</h4><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit&section=6" title="Edit section: Design"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>The two electrode chambers of each cell are typically divided by a membrane (typically a microporous or <a href="/wiki/Ion-exchange_membrane" title="Ion-exchange membrane">ion-exchange</a> variety). This helps to prevent bromine from reaching the negative electrode, where it would react with the zinc, causing self-discharge. To further reduce self-discharge and to reduce bromine vapor pressure, complexing agents are added to the positive electrolyte. These react reversibly with the bromine to form an oily red liquid and reduce the <span class="chemf nowrap">Br<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">2</sub></span></span></span> concentration in the electrolyte.<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">[<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (November 2008)">citation needed</span></a></i>]</sup> </p> <div class="mw-heading mw-heading4"><h4 id="Developers">Developers</h4><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit&section=7" title="Edit section: Developers"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li>Primus Power – Hayward, California, is a privately held US company. However, as at May 2023, they had had no installations since 2015.<sup id="cite_ref-8" class="reference"><a href="#cite_note-8"><span class="cite-bracket">[</span>8<span class="cite-bracket">]</span></a></sup> Primus Power claim 70% efficiency for their 125 kWh unit.<sup id="cite_ref-9" class="reference"><a href="#cite_note-9"><span class="cite-bracket">[</span>9<span class="cite-bracket">]</span></a></sup></li> <li>RedFlow Limited – Brisbane, Australia, was a publicly listed company on the ASX until it went into voluntary administration on the 23rd of August, 2024,<sup id="cite_ref-10" class="reference"><a href="#cite_note-10"><span class="cite-bracket">[</span>10<span class="cite-bracket">]</span></a></sup> with an orderly wind down declared on the 18th of October.<sup id="cite_ref-11" class="reference"><a href="#cite_note-11"><span class="cite-bracket">[</span>11<span class="cite-bracket">]</span></a></sup> Their ZBM3 battery claimed to supply 12 hours of continuous power.<sup id="cite_ref-:3_12-0" class="reference"><a href="#cite_note-:3-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup> They claimed DC–DC "stack <a href="/wiki/Electrical_efficiency" title="Electrical efficiency">energy efficiency</a>" of up to 80% for their ZBM3 battery<sup id="cite_ref-:2_13-0" class="reference"><a href="#cite_note-:2-13"><span class="cite-bracket">[</span>13<span class="cite-bracket">]</span></a></sup> and 42 Wh/kg for the ZBM3,<sup id="cite_ref-:2_13-1" class="reference"><a href="#cite_note-:2-13"><span class="cite-bracket">[</span>13<span class="cite-bracket">]</span></a></sup> a 10 kWh unit.</li> <li>EnSync (Formerly ZBB)<sup id="cite_ref-14" class="reference"><a href="#cite_note-14"><span class="cite-bracket">[</span>14<span class="cite-bracket">]</span></a></sup> – Menomonee Falls, Wisconsin, US (defunct).<sup id="cite_ref-15" class="reference"><a href="#cite_note-15"><span class="cite-bracket">[</span>15<span class="cite-bracket">]</span></a></sup></li></ul> <div class="mw-heading mw-heading3"><h3 id="Non-flow">Non-flow</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit&section=8" title="Edit section: Non-flow"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Non-flow batteries do not pass battery materials between two tanks. </p> <div class="mw-heading mw-heading4"><h4 id="Developers_2">Developers</h4><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit&section=9" title="Edit section: Developers"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li>Gelion: <a href="/wiki/Thomas_Maschmeyer" title="Thomas Maschmeyer">Thomas Maschmeyer</a> at the <a href="/wiki/University_of_Sydney" title="University of Sydney">University of Sydney</a> replaced the liquid with a <a href="/wiki/Gel" title="Gel">gel</a>. Ions can move more quickly, decreasing charging time. The gel is fire-retardant.<sup id="cite_ref-16" class="reference"><a href="#cite_note-16"><span class="cite-bracket">[</span>16<span class="cite-bracket">]</span></a></sup> In April 2016 Gelion, launched. The company earned an A$11 million investment from UK renewables group <a href="/w/index.php?title=Armstrong_Energy&action=edit&redlink=1" class="new" title="Armstrong Energy (page does not exist)">Armstrong Energy</a>.<sup id="cite_ref-17" class="reference"><a href="#cite_note-17"><span class="cite-bracket">[</span>17<span class="cite-bracket">]</span></a></sup> Gelion raised further capital with an IPO and listed on the AIM London Stock Exchange 30 November 2021.</li></ul> <blockquote><p>Gelion plans to commercialise a 1.2 kWh monoblock battery for use in commercial and grid applications.<sup id="cite_ref-:0_18-0" class="reference"><a href="#cite_note-:0-18"><span class="cite-bracket">[</span>18<span class="cite-bracket">]</span></a></sup>  Gelion claimed its monoblocks will have<sup id="cite_ref-:0_18-1" class="reference"><a href="#cite_note-:0-18"><span class="cite-bracket">[</span>18<span class="cite-bracket">]</span></a></sup> higher energy density (120 Wh/kg), higher round-trip efficiency (>87%), no moving parts, and manufacturing scalability to gigawatt capacity by adapting existing lead–acid battery factories.</p></blockquote><blockquote><p>As of March 2023<sup class="plainlinks noexcerpt noprint asof-tag update" style="display:none;"><a class="external text" href="https://en.wikipedia.org/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit">[update]</a></sup>, Gelion planned to test-deploy a system for Acciona Energy in 2023.<sup id="cite_ref-19" class="reference"><a href="#cite_note-19"><span class="cite-bracket">[</span>19<span class="cite-bracket">]</span></a></sup> Gelion announced a fast discharge mode, lower cost electrodes (to replace titanium) and improvements for dendrite management and prevention.<sup id="cite_ref-20" class="reference"><a href="#cite_note-20"><span class="cite-bracket">[</span>20<span class="cite-bracket">]</span></a></sup></p></blockquote> <ul><li>EOS Energy Enterprise cathode: As of May 2023<sup class="plainlinks noexcerpt noprint asof-tag update" style="display:none;"><a class="external text" href="https://en.wikipedia.org/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit">[update]</a></sup> EOS had announced its Eos Z3 battery and claimed an order backlog of 347MWh and a total 2.2GWh of binding orders.<sup id="cite_ref-21" class="reference"><a href="#cite_note-21"><span class="cite-bracket">[</span>21<span class="cite-bracket">]</span></a></sup> EOS claimed its battery has an RTE "in the mid 80s" (with reduced depth of discharge) and a lifetime of 6,000 cycles/20 years.<sup id="cite_ref-22" class="reference"><a href="#cite_note-22"><span class="cite-bracket">[</span>22<span class="cite-bracket">]</span></a></sup></li></ul> <div class="mw-heading mw-heading2"><h2 id="Electrochemistry">Electrochemistry</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit&section=10" title="Edit section: Electrochemistry"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Flow and non-flow configuration share the same electrochemistry. </p><p>At the negative electrode <a href="/wiki/Zinc" title="Zinc">zinc</a> is the electroactive species. It is <a href="/wiki/Electropositive" class="mw-redirect" title="Electropositive">electropositive</a>, with a <a href="/wiki/Standard_reduction_potential" class="mw-redirect" title="Standard reduction potential">standard reduction potential</a> <i>E</i>° = −0.76 V vs <a href="/wiki/Standard_hydrogen_electrode" title="Standard hydrogen electrode">SHE</a>. </p><p>The negative electrode reaction is the reversible dissolution/plating of zinc: </p> <dl><dd><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle {\ce {Zn_{(s)}<=>{Zn^{2}+}_{(aq)}+2e^{-}}}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <msubsup> <mtext>Zn</mtext> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <mtext>s</mtext> <mo stretchy="false">)</mo> </mrow> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> <mrow class="MJX-TeXAtom-REL"> <mover> <mrow class="MJX-TeXAtom-OP MJX-fixedlimits"> <mrow class="MJX-TeXAtom-ORD"> <mpadded height="0" depth="0"> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">↽<!-- ↽ --></mo> </mrow> <mspace width="negativethinmathspace" /> <mspace width="negativethinmathspace" /> <mrow class="MJX-TeXAtom-ORD"> <mo>−<!-- − --></mo> </mrow> </mpadded> </mrow> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="false" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mo>−<!-- − --></mo> </mrow> <mspace width="negativethinmathspace" /> <mspace width="negativethinmathspace" /> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">⇀<!-- ⇀ --></mo> </mrow> </mrow> </mstyle> </mrow> </mover> </mrow> <msubsup> <mrow class="MJX-TeXAtom-ORD"> <msup> <mtext>Zn</mtext> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> <mo>+</mo> </mrow> </msup> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <mtext>aq</mtext> <mo stretchy="false">)</mo> </mrow> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> <mo>+</mo> <mn>2</mn> <mspace width="thinmathspace" /> <msup> <mtext>e</mtext> <mrow class="MJX-TeXAtom-ORD"> <mo>−<!-- − --></mo> </mrow> </msup> </mrow> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle {\ce {Zn_{(s)}<=>{Zn^{2}+}_{(aq)}+2e^{-}}}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/7316c16e4b1ec8d08e497153530be282bb850540" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -1.505ex; width:24.701ex; height:3.843ex;" alt="{\displaystyle {\ce {Zn_{(s)}<=>{Zn^{2}+}_{(aq)}+2e^{-}}}}"></span></dd></dl> <p>At the positive electrode <a href="/wiki/Bromine" title="Bromine">bromine</a> is reversibly <a href="/wiki/Redox" title="Redox">reduced</a> to <a href="/wiki/Bromide" title="Bromide">bromide</a> (with a standard reduction potential of +1.087 V vs SHE): </p> <dl><dd><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle {\ce {{Br2_{(aq)}}+2e^{-}<=>{2Br^{-}}_{(aq)}}}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <msubsup> <mtext>Br</mtext> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <mtext>aq</mtext> <mo stretchy="false">)</mo> </mrow> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> </mrow> <mo>+</mo> <mn>2</mn> <mspace width="thinmathspace" /> <msup> <mtext>e</mtext> <mrow class="MJX-TeXAtom-ORD"> <mo>−<!-- − --></mo> </mrow> </msup> <mrow class="MJX-TeXAtom-REL"> <mover> <mrow class="MJX-TeXAtom-OP MJX-fixedlimits"> <mrow class="MJX-TeXAtom-ORD"> <mpadded height="0" depth="0"> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">↽<!-- ↽ --></mo> </mrow> <mspace width="negativethinmathspace" /> <mspace width="negativethinmathspace" /> <mrow class="MJX-TeXAtom-ORD"> <mo>−<!-- − --></mo> </mrow> </mpadded> </mrow> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="false" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mo>−<!-- − --></mo> </mrow> <mspace width="negativethinmathspace" /> <mspace width="negativethinmathspace" /> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">⇀<!-- ⇀ --></mo> </mrow> </mrow> </mstyle> </mrow> </mover> </mrow> <msubsup> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> <mspace width="thinmathspace" /> <msup> <mtext>Br</mtext> <mrow class="MJX-TeXAtom-ORD"> <mo>−<!-- − --></mo> </mrow> </msup> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <mtext>aq</mtext> <mo stretchy="false">)</mo> </mrow> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> </mrow> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle {\ce {{Br2_{(aq)}}+2e^{-}<=>{2Br^{-}}_{(aq)}}}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/94a0c28db2789bc1ee7be5c6866c4e2c95e64155" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -1.505ex; width:26.981ex; height:3.843ex;" alt="{\displaystyle {\ce {{Br2_{(aq)}}+2e^{-}<=>{2Br^{-}}_{(aq)}}}}"></span></dd></dl> <p>So the overall cell reaction is </p> <dl><dd><span class="mwe-math-element"><span class="mwe-math-mathml-inline mwe-math-mathml-a11y" style="display: none;"><math xmlns="http://www.w3.org/1998/Math/MathML" alttext="{\displaystyle {\ce {{Zn_{(s)}}+Br2_{(aq)}<=>{2Br^{-}}_{(aq)}+{Zn^{2}+}_{(aq)}}}}"> <semantics> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="true" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <msubsup> <mtext>Zn</mtext> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <mtext>s</mtext> <mo stretchy="false">)</mo> </mrow> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> </mrow> <mo>+</mo> <msubsup> <mtext>Br</mtext> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <mtext>aq</mtext> <mo stretchy="false">)</mo> </mrow> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> <mrow class="MJX-TeXAtom-REL"> <mover> <mrow class="MJX-TeXAtom-OP MJX-fixedlimits"> <mrow class="MJX-TeXAtom-ORD"> <mpadded height="0" depth="0"> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">↽<!-- ↽ --></mo> </mrow> <mspace width="negativethinmathspace" /> <mspace width="negativethinmathspace" /> <mrow class="MJX-TeXAtom-ORD"> <mo>−<!-- − --></mo> </mrow> </mpadded> </mrow> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mstyle displaystyle="false" scriptlevel="0"> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mo>−<!-- − --></mo> </mrow> <mspace width="negativethinmathspace" /> <mspace width="negativethinmathspace" /> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">⇀<!-- ⇀ --></mo> </mrow> </mrow> </mstyle> </mrow> </mover> </mrow> <msubsup> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> <mspace width="thinmathspace" /> <msup> <mtext>Br</mtext> <mrow class="MJX-TeXAtom-ORD"> <mo>−<!-- − --></mo> </mrow> </msup> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <mtext>aq</mtext> <mo stretchy="false">)</mo> </mrow> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> <mo>+</mo> <msubsup> <mrow class="MJX-TeXAtom-ORD"> <msup> <mtext>Zn</mtext> <mrow class="MJX-TeXAtom-ORD"> <mn>2</mn> <mo>+</mo> </mrow> </msup> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mrow class="MJX-TeXAtom-ORD"> <mo stretchy="false">(</mo> <mtext>aq</mtext> <mo stretchy="false">)</mo> </mrow> </mrow> <mrow class="MJX-TeXAtom-ORD"> <mspace width="0pt" height="0pt" depth=".2em" /> </mrow> </msubsup> </mrow> </mstyle> </mrow> <annotation encoding="application/x-tex">{\displaystyle {\ce {{Zn_{(s)}}+Br2_{(aq)}<=>{2Br^{-}}_{(aq)}+{Zn^{2}+}_{(aq)}}}}</annotation> </semantics> </math></span><img src="https://wikimedia.org/api/rest_v1/media/math/render/svg/6f210647ed157392cc83fbb5d856ff08c6b8e480" class="mwe-math-fallback-image-inline mw-invert skin-invert" aria-hidden="true" style="vertical-align: -1.505ex; width:38.848ex; height:3.843ex;" alt="{\displaystyle {\ce {{Zn_{(s)}}+Br2_{(aq)}<=>{2Br^{-}}_{(aq)}+{Zn^{2}+}_{(aq)}}}}"></span></dd></dl> <p>The measured potential difference is around 1.67 V per cell (slightly less than that predicted from standard reduction potentials).<sup class="noprint Inline-Template Template-Fact" style="white-space:nowrap;">[<i><a href="/wiki/Wikipedia:Citation_needed" title="Wikipedia:Citation needed"><span title="This claim needs references to reliable sources. (November 2008)">citation needed</span></a></i>]</sup> </p> <div class="mw-heading mw-heading2"><h2 id="Applications">Applications</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit&section=11" title="Edit section: Applications"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <div class="mw-heading mw-heading3"><h3 id="Remote_telecom_sites">Remote telecom sites</h3><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit&section=12" title="Edit section: Remote telecom sites"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>Significant diesel-generator fuel savings are possible at remote telecom sites operating under conditions of low electrical load and large installed generation by using multiple systems in parallel to maximise the benefits and minimise the drawbacks of the technology.<sup id="cite_ref-FOOTNOTERoseFerreira10_23-0" class="reference"><a href="#cite_note-FOOTNOTERoseFerreira10-23"><span class="cite-bracket">[</span>23<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="History">History</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit&section=13" title="Edit section: History"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <p>In December 2021 Redflow completed a 2 MWh installation for Aneargia to support a 2.0 MW <a href="/wiki/Biogas" title="Biogas">biogas</a>-fuelled cogeneration unit, and a microgrid control system in California.<sup id="cite_ref-24" class="reference"><a href="#cite_note-24"><span class="cite-bracket">[</span>24<span class="cite-bracket">]</span></a></sup><sup id="cite_ref-25" class="reference"><a href="#cite_note-25"><span class="cite-bracket">[</span>25<span class="cite-bracket">]</span></a></sup> </p><p>As of November 2021<sup class="plainlinks noexcerpt noprint asof-tag update" style="display:none;"><a class="external text" href="https://en.wikipedia.org/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit">[update]</a></sup> EOS Energy Enterprises had secured a 300 MWh order from Pine Gate Renewables, with installation planned for 2022.<sup id="cite_ref-26" class="reference"><a href="#cite_note-26"><span class="cite-bracket">[</span>26<span class="cite-bracket">]</span></a></sup> </p><p>As of February 2022<sup class="plainlinks noexcerpt noprint asof-tag update" style="display:none;"><a class="external text" href="https://en.wikipedia.org/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit">[update]</a></sup>, Gelion announced an agreement with Acciona Energy to trial Endure batteries for grid-scale applications.<sup id="cite_ref-:1_27-0" class="reference"><a href="#cite_note-:1-27"><span class="cite-bracket">[</span>27<span class="cite-bracket">]</span></a></sup> </p><p>In June 2023, Redflow announced an agreement to supply a 20 MWh system to help power California's Rolling Hills Casino.<sup id="cite_ref-:3_12-1" class="reference"><a href="#cite_note-:3-12"><span class="cite-bracket">[</span>12<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="See_also">See also</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit&section=14" title="Edit section: See also"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a href="/wiki/Electrochemical_engineering" title="Electrochemical engineering">Electrochemical engineering</a></li> <li><a href="/wiki/List_of_battery_types" title="List of battery types">List of battery types</a></li></ul> <div class="mw-heading mw-heading2"><h2 id="References">References</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit&section=15" title="Edit section: References"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <style data-mw-deduplicate="TemplateStyles:r1239543626">.mw-parser-output .reflist{margin-bottom:0.5em;list-style-type:decimal}@media screen{.mw-parser-output .reflist{font-size:90%}}.mw-parser-output .reflist .references{font-size:100%;margin-bottom:0;list-style-type:inherit}.mw-parser-output .reflist-columns-2{column-width:30em}.mw-parser-output .reflist-columns-3{column-width:25em}.mw-parser-output .reflist-columns{margin-top:0.3em}.mw-parser-output .reflist-columns ol{margin-top:0}.mw-parser-output .reflist-columns li{page-break-inside:avoid;break-inside:avoid-column}.mw-parser-output .reflist-upper-alpha{list-style-type:upper-alpha}.mw-parser-output .reflist-upper-roman{list-style-type:upper-roman}.mw-parser-output .reflist-lower-alpha{list-style-type:lower-alpha}.mw-parser-output .reflist-lower-greek{list-style-type:lower-greek}.mw-parser-output .reflist-lower-roman{list-style-type:lower-roman}</style><div class="reflist reflist-columns references-column-width" style="column-width: 30em;"> <ol class="references"> <li id="cite_note-Khor_et_al_2018-1"><span class="mw-cite-backlink">^ <a href="#cite_ref-Khor_et_al_2018_1-0"><sup><i><b>a</b></i></sup></a> <a href="#cite_ref-Khor_et_al_2018_1-1"><sup><i><b>b</b></i></sup></a></span> <span class="reference-text"><style data-mw-deduplicate="TemplateStyles:r1238218222">.mw-parser-output cite.citation{font-style:inherit;word-wrap:break-word}.mw-parser-output .citation q{quotes:"\"""\"""'""'"}.mw-parser-output .citation:target{background-color:rgba(0,127,255,0.133)}.mw-parser-output .id-lock-free.id-lock-free a{background:url("//upload.wikimedia.org/wikipedia/commons/6/65/Lock-green.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-limited.id-lock-limited a,.mw-parser-output .id-lock-registration.id-lock-registration a{background:url("//upload.wikimedia.org/wikipedia/commons/d/d6/Lock-gray-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-subscription.id-lock-subscription a{background:url("//upload.wikimedia.org/wikipedia/commons/a/aa/Lock-red-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .cs1-ws-icon a{background:url("//upload.wikimedia.org/wikipedia/commons/4/4c/Wikisource-logo.svg")right 0.1em center/12px no-repeat}body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-free a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-limited a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-registration a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-subscription a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .cs1-ws-icon a{background-size:contain;padding:0 1em 0 0}.mw-parser-output .cs1-code{color:inherit;background:inherit;border:none;padding:inherit}.mw-parser-output .cs1-hidden-error{display:none;color:var(--color-error,#d33)}.mw-parser-output .cs1-visible-error{color:var(--color-error,#d33)}.mw-parser-output .cs1-maint{display:none;color:#085;margin-left:0.3em}.mw-parser-output .cs1-kern-left{padding-left:0.2em}.mw-parser-output .cs1-kern-right{padding-right:0.2em}.mw-parser-output .citation .mw-selflink{font-weight:inherit}@media screen{.mw-parser-output .cs1-format{font-size:95%}html.skin-theme-clientpref-night .mw-parser-output .cs1-maint{color:#18911f}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .cs1-maint{color:#18911f}}</style><cite id="CITEREFKhorLeungMohamedFlox2018" class="citation journal cs1">Khor, A.; Leung, P.; Mohamed, M.R.; Flox, C.; Xu, 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Retrieved <span class="nowrap">2022-02-08</span></span>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=unknown&rft.jtitle=RenewEconomy&rft.atitle=Gelion+to+trial+its+zinc+bromide+batteries+with+Spanish+solar+farm&rft.date=2022-02-02&rft.aulast=Vorrath&rft.aufirst=Sophie&rft_id=https%3A%2F%2Freneweconomy.com.au%2Fgelion-to-trial-its-zinc-bromide-batteries-with-spanish-solar-farm%2F&rfr_id=info%3Asid%2Fen.wikipedia.org%3AZinc%E2%80%93bromine+battery" class="Z3988"></span></span> </li> </ol></div> <div class="mw-heading mw-heading2"><h2 id="Further_reading">Further reading</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit&section=16" title="Edit section: Further reading"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li>Bromine complexation in zinc–bromine circulating batteries D. J. Eustace, J. Electrochem. Soc. 127(3), 528–32 (1980)</li> <li>Handbook of batteries, 3rd edition. D. Linden, T. B. Reddy. 39.1–39.8 (2002)</li> <li><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><cite id="CITEREFRoseFerreira" class="citation web cs1">Rose, David M.; Ferreira, Summer R. <a rel="nofollow" class="external text" href="http://www.sandia.gov/ess/publications/SAND2013-2818C.pdf">"Performance testing of zinc–bromine flow batteries for remote telecom sites"</a> <span class="cs1-format">(PDF)</span>. Sandia National Laboratory.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=unknown&rft.btitle=Performance+testing+of+zinc%E2%80%93bromine+flow+batteries+for+remote+telecom+sites&rft.pub=Sandia+National+Laboratory&rft.aulast=Rose&rft.aufirst=David+M.&rft.au=Ferreira%2C+Summer+R.&rft_id=http%3A%2F%2Fwww.sandia.gov%2Fess%2Fpublications%2FSAND2013-2818C.pdf&rfr_id=info%3Asid%2Fen.wikipedia.org%3AZinc%E2%80%93bromine+battery" class="Z3988"></span> <a rel="nofollow" class="external text" href="http://www.sandia.gov/ess/publications/SAND12-1352.pdf">Update</a></li> <li><a rel="nofollow" class="external text" href="http://redflow.com/">RedFlow.</a></li></ul> <div class="mw-heading mw-heading2"><h2 id="External_links">External links</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zinc%E2%80%93bromine_battery&action=edit&section=17" title="Edit section: External links"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a rel="nofollow" class="external text" href="http://www.electricitystorage.org/technology/storage_technologies/batteries/zinc_bromine_batteries/">ZnBr Batteries</a> at the Electricity Storage Association</li></ul> <div class="navbox-styles"><style data-mw-deduplicate="TemplateStyles:r1129693374">.mw-parser-output .hlist dl,.mw-parser-output .hlist ol,.mw-parser-output .hlist ul{margin:0;padding:0}.mw-parser-output .hlist dd,.mw-parser-output .hlist dt,.mw-parser-output .hlist li{margin:0;display:inline}.mw-parser-output .hlist.inline,.mw-parser-output .hlist.inline dl,.mw-parser-output .hlist.inline ol,.mw-parser-output .hlist.inline ul,.mw-parser-output .hlist dl dl,.mw-parser-output .hlist dl ol,.mw-parser-output .hlist dl ul,.mw-parser-output .hlist ol dl,.mw-parser-output .hlist ol ol,.mw-parser-output .hlist ol ul,.mw-parser-output .hlist ul dl,.mw-parser-output .hlist ul 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battery</a></li></ul></li> <li><a href="/wiki/Fuel_cell" title="Fuel cell">Fuel cell</a></li> <li><a href="/wiki/Thermogalvanic_cell" title="Thermogalvanic cell">Thermogalvanic cell</a></li> <li><a href="/wiki/Voltaic_pile" title="Voltaic pile">Voltaic pile</a></li></ul> </div></td><td class="noviewer navbox-image" rowspan="5" style="width:1px;padding:0 0 0 2px"><div><span typeof="mw:File"><a href="/wiki/File:Galvanic_Cell.svg" class="mw-file-description" title="Galvanic cell"><img alt="Galvanic cell" src="//upload.wikimedia.org/wikipedia/commons/thumb/8/8e/Galvanic_Cell.svg/150px-Galvanic_Cell.svg.png" decoding="async" width="150" height="159" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/8/8e/Galvanic_Cell.svg/225px-Galvanic_Cell.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/8/8e/Galvanic_Cell.svg/300px-Galvanic_Cell.svg.png 2x" data-file-width="376" data-file-height="399" /></a></span></div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Primary_battery" title="Primary battery">Primary cell</a><br /><span class="nobold">(non-rechargeable)</span></div></th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Alkaline_battery" title="Alkaline battery">Alkaline</a></li> <li><a href="/wiki/Aluminium%E2%80%93air_battery" title="Aluminium–air battery">Aluminium–air</a></li> <li><a href="/wiki/Bunsen_cell" title="Bunsen cell">Bunsen</a></li> <li><a href="/wiki/Chromic_acid_cell" title="Chromic acid cell">Chromic acid</a></li> <li><a href="/wiki/Clark_cell" title="Clark cell">Clark</a></li> <li><a href="/wiki/Daniell_cell" title="Daniell cell">Daniell</a></li> <li><a href="/wiki/Dry_cell" title="Dry cell">Dry</a></li> <li><a href="/wiki/Edison%E2%80%93Lalande_cell" title="Edison–Lalande cell">Edison–Lalande</a></li> <li><a href="/wiki/Grove_cell" title="Grove cell">Grove</a></li> <li><a href="/wiki/Leclanch%C3%A9_cell" title="Leclanché cell">Leclanché</a></li> <li><a href="/wiki/Lithium_metal_battery" title="Lithium metal battery">Lithium metal</a></li> <li><a href="/wiki/Lithium%E2%80%93air_battery" title="Lithium–air battery">Lithium–air</a></li> <li><a href="/wiki/Mercury_battery" title="Mercury battery">Mercury</a></li> <li><a href="/wiki/Metal%E2%80%93air_electrochemical_cell" title="Metal–air electrochemical cell">Metal–air electrochemical</a></li> <li><a href="/wiki/Nickel_oxyhydroxide_battery" title="Nickel oxyhydroxide battery">Nickel oxyhydroxide</a></li> <li><a href="/wiki/Silicon%E2%80%93air_battery" title="Silicon–air battery">Silicon–air</a></li> <li><a href="/wiki/Silver_oxide_battery" title="Silver oxide battery">Silver oxide</a></li> <li><a href="/wiki/Weston_cell" title="Weston cell">Weston</a></li> <li><a href="/wiki/Zamboni_pile" title="Zamboni pile">Zamboni</a></li> <li><a href="/wiki/Zinc%E2%80%93air_battery" title="Zinc–air battery">Zinc–air</a></li> <li><a href="/wiki/Zinc%E2%80%93carbon_battery" title="Zinc–carbon battery">Zinc–carbon</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Rechargeable_battery" title="Rechargeable battery">Secondary cell</a><br /><span class="nobold">(rechargeable)</span></div></th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Automotive_battery" title="Automotive battery">Automotive</a></li> <li><a href="/wiki/Lead%E2%80%93acid_battery" title="Lead–acid battery">Lead–acid</a> <ul><li><a href="/wiki/VRLA_battery" title="VRLA battery">gel–VRLA</a></li></ul></li> <li><a href="/wiki/Lithium%E2%80%93air_battery" title="Lithium–air battery">Lithium–air</a></li> <li><a href="/wiki/Lithium-ion_battery" title="Lithium-ion battery">Lithium ion</a> <ul><li><a href="/wiki/Dual_carbon_battery" title="Dual carbon battery">Dual carbon</a></li> <li><a href="/wiki/Lithium_iron_phosphate_battery" title="Lithium iron phosphate battery">Lithium–iron–phosphate</a></li> <li><a href="/wiki/Lithium_polymer_battery" title="Lithium polymer battery">Lithium–polymer</a></li> <li><a href="/wiki/Lithium%E2%80%93sulfur_battery" title="Lithium–sulfur battery">Lithium–sulfur</a></li> <li><a href="/wiki/Lithium-titanate_battery" title="Lithium-titanate battery">Lithium–titanate</a></li></ul></li> <li><a href="/wiki/Metal%E2%80%93air_electrochemical_cell" title="Metal–air electrochemical cell">Metal–air</a></li> <li><a href="/wiki/Molten-salt_battery" title="Molten-salt battery">Molten salt</a></li> <li><a href="/wiki/Nanopore_battery" title="Nanopore battery">Nanopore</a></li> <li><a href="/wiki/Nanowire_battery" title="Nanowire battery">Nanowire</a></li> <li><a href="/wiki/Nickel%E2%80%93cadmium_battery" title="Nickel–cadmium battery">Nickel–cadmium</a></li> <li><a href="/wiki/Nickel%E2%80%93hydrogen_battery" title="Nickel–hydrogen battery">Nickel–hydrogen</a></li> <li><a href="/wiki/Nickel%E2%80%93iron_battery" title="Nickel–iron battery">Nickel–iron</a></li> <li><a href="/wiki/Nickel%E2%80%93lithium_battery" title="Nickel–lithium battery">Nickel–lithium</a></li> <li><a href="/wiki/Nickel%E2%80%93metal_hydride_battery" title="Nickel–metal hydride battery">Nickel–metal hydride</a></li> <li><a href="/wiki/Nickel%E2%80%93zinc_battery" title="Nickel–zinc battery">Nickel–zinc</a></li> <li><a href="/wiki/Polysulfide%E2%80%93bromide_battery" title="Polysulfide–bromide battery">Polysulfide–bromide</a></li> <li><a href="/wiki/Potassium-ion_battery" title="Potassium-ion battery">Potassium ion</a></li> <li><a href="/wiki/Rechargeable_alkaline_battery" title="Rechargeable alkaline battery">Rechargeable alkaline</a></li> <li><a href="/wiki/Silver%E2%80%93cadmium_battery" title="Silver–cadmium battery">Silver–cadmium</a></li> <li><a href="/wiki/Silver_zinc_battery" title="Silver zinc battery">Silver–zinc</a></li> <li><a href="/wiki/Sodium-ion_battery" title="Sodium-ion battery">Sodium ion</a></li> <li><a href="/wiki/Sodium%E2%80%93sulfur_battery" title="Sodium–sulfur battery">Sodium–sulfur</a></li> <li><a href="/wiki/Solid-state_battery" title="Solid-state battery">Solid state</a></li> <li><a href="/wiki/Vanadium_redox_battery" title="Vanadium redox battery">Vanadium redox</a></li> <li><a class="mw-selflink selflink">Zinc–bromine</a></li> <li><a href="/wiki/Zinc%E2%80%93cerium_battery" title="Zinc–cerium battery">Zinc–cerium</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%"><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">Other cell</div></th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Atomic_battery" title="Atomic battery">Atomic battery</a></li> <li><a href="/wiki/Fuel_cell" title="Fuel cell">Fuel cell</a></li> <li><a href="/wiki/Solar_cell" title="Solar cell">Solar cell</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">Cell parts</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Anode" title="Anode">Anode</a></li> <li><a href="/wiki/Binder_(material)" title="Binder (material)">Binder</a></li> <li><a href="/wiki/Catalysis" title="Catalysis">Catalyst</a></li> <li><a href="/wiki/Cathode" title="Cathode">Cathode</a></li> <li><a href="/wiki/Electrode" title="Electrode">Electrode</a></li> <li><a href="/wiki/Electrolyte" title="Electrolyte">Electrolyte</a></li> <li><a href="/wiki/Half-cell" title="Half-cell">Half-cell</a></li> <li><a href="/wiki/Ion" title="Ion">Ions</a></li> <li><a href="/wiki/Salt_bridge" title="Salt bridge">Salt bridge</a></li> <li><a href="/wiki/Semipermeable_membrane" title="Semipermeable membrane">Semipermeable membrane</a></li></ul> </div></td></tr></tbody></table></div> <!-- NewPP limit report Parsed by mw‐web.codfw.main‐f69cdc8f6‐pdn6j Cached time: 20241122155709 Cache expiry: 2592000 Reduced expiry: false Complications: [vary‐revision‐sha1, show‐toc] CPU time usage: 0.714 seconds Real time usage: 0.971 seconds Preprocessor visited node count: 3910/1000000 Post‐expand include size: 84058/2097152 bytes Template argument size: 7937/2097152 bytes Highest expansion depth: 22/100 Expensive parser function count: 8/500 Unstrip recursion depth: 1/20 Unstrip post‐expand size: 97541/5000000 bytes Lua time usage: 0.434/10.000 seconds Lua memory usage: 7489424/52428800 bytes Number of Wikibase entities loaded: 0/400 --> <!-- Transclusion expansion time report (%,ms,calls,template) 100.00% 825.250 1 -total 28.65% 236.418 1 Template:Reflist 16.86% 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