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class="firstHeading mw-first-heading"><span class="mw-page-title-main">Zirconyl chloride</span></h1> <div id="p-lang-btn" class="vector-dropdown mw-portlet mw-portlet-lang" > <input type="checkbox" id="p-lang-btn-checkbox" role="button" aria-haspopup="true" data-event-name="ui.dropdown-p-lang-btn" class="vector-dropdown-checkbox mw-interlanguage-selector" aria-label="Go to an article in another language. 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class="interlanguage-link interwiki-bn mw-list-item"><a href="https://bn.wikipedia.org/wiki/%E0%A6%9C%E0%A6%BF%E0%A6%B0%E0%A6%95%E0%A7%8B%E0%A6%A8%E0%A6%BE%E0%A6%87%E0%A6%B2_%E0%A6%95%E0%A7%8D%E0%A6%B2%E0%A7%8B%E0%A6%B0%E0%A6%BE%E0%A6%87%E0%A6%A1" title="জিরকোনাইল ক্লোরাইড – Bangla" lang="bn" hreflang="bn" data-title="জিরকোনাইল ক্লোরাইড" data-language-autonym="বাংলা" data-language-local-name="Bangla" class="interlanguage-link-target"><span>বাংলা</span></a></li><li class="interlanguage-link interwiki-de mw-list-item"><a href="https://de.wikipedia.org/wiki/Zirconylchlorid" title="Zirconylchlorid – German" lang="de" hreflang="de" data-title="Zirconylchlorid" data-language-autonym="Deutsch" data-language-local-name="German" class="interlanguage-link-target"><span>Deutsch</span></a></li><li class="interlanguage-link interwiki-fr mw-list-item"><a href="https://fr.wikipedia.org/wiki/Chlorure_de_zirconyle" title="Chlorure de zirconyle – French" lang="fr" hreflang="fr" data-title="Chlorure de 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<div class="mw-indicators"> </div> <div id="siteSub" class="noprint">From Wikipedia, the free encyclopedia</div> </div> <div id="contentSub"><div id="mw-content-subtitle"></div></div> <div id="mw-content-text" class="mw-body-content"><div class="mw-content-ltr mw-parser-output" lang="en" dir="ltr"><style data-mw-deduplicate="TemplateStyles:r1084375498">.mw-parser-output .ib-chembox{border-collapse:collapse;text-align:left}.mw-parser-output .ib-chembox td,.mw-parser-output .ib-chembox th{border:1px solid #a2a9b1;width:40%}.mw-parser-output .ib-chembox td+td{width:60%}</style> <table class="infobox ib-chembox"> <caption>Zirconyl chloride </caption> <tbody><tr> <td colspan="2" style="text-align:center; padding:2px;"><span typeof="mw:File"><a href="/wiki/File:ZrOCl2_(octahydrate).jpg" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/c/c2/ZrOCl2_%28octahydrate%29.jpg/220px-ZrOCl2_%28octahydrate%29.jpg" decoding="async" width="220" height="193" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/c/c2/ZrOCl2_%28octahydrate%29.jpg/330px-ZrOCl2_%28octahydrate%29.jpg 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/c/c2/ZrOCl2_%28octahydrate%29.jpg/440px-ZrOCl2_%28octahydrate%29.jpg 2x" data-file-width="1917" data-file-height="1679" /></a></span> </td></tr> <tr> <th colspan="2" style="background: #f8eaba; text-align: center;">Names </th></tr> <tr> <td colspan="2" style="text-align:left;"><a href="/wiki/Chemical_nomenclature" title="Chemical nomenclature">IUPAC name</a> <div style="max-width:22em; word-wrap:break-word; padding-left:1.7em;">Dichloro(oxo)zirconium</div> </td></tr> <tr> <td colspan="2" style="text-align:left;">Other names <div style="max-width:22em; word-wrap:break-word; padding-left:1.7em;"><style data-mw-deduplicate="TemplateStyles:r1126788409">.mw-parser-output .plainlist ol,.mw-parser-output .plainlist ul{line-height:inherit;list-style:none;margin:0;padding:0}.mw-parser-output .plainlist ol li,.mw-parser-output .plainlist ul li{margin-bottom:0}</style><div class="plainlist"><ul><li><i>basic zirconium chloride</i></li><li><i>dichlorooxozirconium</i></li><li><i>zirconium oxychloride</i></li><li><i>zirconium dichloride oxide</i></li><li><i>Zirconium chloride oxide</i></li><li><i>Chlorozirconyl</i></li></ul></div></div> </td></tr> <tr> <th colspan="2" style="background: #f8eaba; text-align: center;">Identifiers </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/CAS_Registry_Number" title="CAS Registry Number">CAS Number</a></div> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li>anhydrous: <span title="commonchemistry.cas.org"><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=7699-43-6">7699-43-6</a></span><sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></li><li>octahydrate: <span title="commonchemistry.cas.org"><a rel="nofollow" class="external text" href="https://commonchemistry.cas.org/detail?cas_rn=13520-92-8">13520-92-8</a></span><sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></li></ul></div> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">3D model (<a href="/wiki/JSmol" class="mw-redirect" title="JSmol">JSmol</a>)</div> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="chemapps.stolaf.edu (3D interactive model)"><a rel="nofollow" class="external text" href="https://chemapps.stolaf.edu/jmol/jmol.php?model=O%3D%5BZr%5D%28Cl%29Cl">Interactive image</a></span></li></ul></div> </td></tr> <tr> <td><a href="/wiki/ChemSpider" title="ChemSpider">ChemSpider</a> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="www.chemspider.com"><a rel="nofollow" class="external text" href="https://www.chemspider.com/Chemical-Structure.10606302.html">10606302</a></span><sup> <span typeof="mw:File"><span><img alt="☒" src="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/7px-X_mark.svg.png" decoding="async" width="7" height="8" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/11px-X_mark.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/14px-X_mark.svg.png 2x" data-file-width="525" data-file-height="600" /></span></span><span style="display:none">N</span></sup></li></ul></div> </td></tr> <tr> <td><a href="/wiki/ECHA_InfoCard" class="mw-redirect" title="ECHA InfoCard"><span title="echa.europa.eu">ECHA InfoCard</span></a> </td> <td><a rel="nofollow" class="external text" href="https://echa.europa.eu/substance-information/-/substanceinfo/100.028.835">100.028.835</a> <span class="mw-valign-text-top noprint" typeof="mw:File/Frameless"><a href="https://www.wikidata.org/wiki/Q128540#P2566" title="Edit this at Wikidata"><img alt="Edit this at Wikidata" src="//upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/10px-OOjs_UI_icon_edit-ltr-progressive.svg.png" decoding="async" width="10" height="10" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/15px-OOjs_UI_icon_edit-ltr-progressive.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/20px-OOjs_UI_icon_edit-ltr-progressive.svg.png 2x" data-file-width="20" data-file-height="20" /></a></span> </td></tr> <tr> <td><a href="/wiki/European_Community_number" title="European Community number"><span title="European Community number (chemical identifier)">EC Number</span></a> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li>603-909-6</li></ul></div> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/PubChem" title="PubChem">PubChem</a> <abbr title="Compound ID">CID</abbr></div> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="pubchem.ncbi.nlm.nih.gov"><a rel="nofollow" class="external text" href="https://pubchem.ncbi.nlm.nih.gov/compound/159678">159678</a></span></li></ul></div> </td></tr> <tr> <td><a href="/wiki/Unique_Ingredient_Identifier" title="Unique Ingredient Identifier">UNII</a> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li>anhydrous: <span title="precision.fda.gov"><a rel="nofollow" class="external text" href="https://precision.fda.gov/uniisearch/srs/unii/T4294601O7">T4294601O7</a></span><sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></li><li>octahydrate: <span title="precision.fda.gov"><a rel="nofollow" class="external text" href="https://precision.fda.gov/uniisearch/srs/unii/2R4A27N98K">2R4A27N98K</a></span><sup> <span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span></sup></li></ul></div> </td></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/CompTox_Chemicals_Dashboard" title="CompTox Chemicals Dashboard">CompTox Dashboard</a> <span style="font-weight:normal">(<abbr title="U.S. Environmental Protection Agency">EPA</abbr>)</span></div> </td> <td><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1126788409"><div class="plainlist"><ul><li><span title="comptox.epa.gov"><a rel="nofollow" class="external text" href="https://comptox.epa.gov/dashboard/chemical/details/DTXSID9049823">DTXSID9049823</a> <span class="mw-valign-text-top noprint" typeof="mw:File/Frameless"><a href="https://www.wikidata.org/wiki/Q128540#P3117" title="Edit this at Wikidata"><img alt="Edit this at Wikidata" src="//upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/10px-OOjs_UI_icon_edit-ltr-progressive.svg.png" decoding="async" width="10" height="10" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/15px-OOjs_UI_icon_edit-ltr-progressive.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/8/8a/OOjs_UI_icon_edit-ltr-progressive.svg/20px-OOjs_UI_icon_edit-ltr-progressive.svg.png 2x" data-file-width="20" data-file-height="20" /></a></span></span></li></ul></div> </td></tr> <tr> <td colspan="2"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold; text-align:left; font-weight:normal; background:transparent;"><div><a href="/wiki/International_Chemical_Identifier" title="International Chemical Identifier">InChI</a></div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0; word-break:break-all;"><li style="line-height: inherit; margin: 0"><div style="border-top:1px solid #ccc; padding:0.2em 0 0.2em 1.5em; text-align:left;"><div style="word-wrap:break-word; text-indent:-1.5em; font-size:97%; line-height:120%;">InChI=1S/2ClH.8H2O.O.Zr/h2*1H;8*1H2;;</div><div style="word-wrap:break-word; text-indent:-1.5em; font-size:97%; line-height:120%;">Key: FUBACIUATZGHAC-UHFFFAOYSA-N</div></div></li></ul> </div> </td></tr> <tr> <td colspan="2"><div class="collapsible-list mw-collapsible mw-collapsed" style="text-align: left;"> <div style="line-height: 1.6em; font-weight: bold; text-align:left; font-weight:normal; background:transparent;"><div><a href="/wiki/Simplified_molecular-input_line-entry_system" class="mw-redirect" title="Simplified molecular-input line-entry system">SMILES</a></div></div> <ul class="mw-collapsible-content" style="margin-top: 0; margin-bottom: 0; line-height: inherit; list-style: none; margin-left: 0; word-break:break-all;"><li style="line-height: inherit; margin: 0"><div style="border-top:1px solid #ccc; padding:0.2em 0 0.2em 1.6em; word-wrap:break-word; text-indent:-1.5em; text-align:left; font-size:97%; line-height:120%;">O=[Zr](Cl)Cl</div></li></ul> </div> </td></tr> <tr> <th colspan="2" style="background: #f8eaba; text-align: center;">Properties </th></tr> <tr> <td><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;"><a href="/wiki/Chemical_formula" title="Chemical formula">Chemical formula</a></div> </td> <td><span title="Chlorine">Cl</span><sub>2</sub><span title="Oxygen">O</span><span title="Zirconium">Zr</span> </td></tr> <tr> <td><a href="/wiki/Molar_mass" title="Molar mass">Molar mass</a> </td> <td><span class="nowrap"><span data-sort-value="7002178120000000000♠"></span>178.12</span> g·mol<sup>−1</sup>   </td></tr> <tr> <td>Appearance </td> <td>White crystals </td></tr> <tr> <th colspan="2" style="background: #f8eaba; text-align: center;">Hazards </th></tr> <tr> <td colspan="2" style="text-align:left; background-color:#eaeaea;"><b>Lethal dose</b> or concentration (LD, LC): </td></tr> <tr> <td style="padding-left:1em;"><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">LD<sub>50</sub> (<a href="/wiki/Lethal_dose#LD50" title="Lethal dose">median dose</a>)</div> </td> <td>400 mg kg<sup>−1</sup>, rat (intraperitioneal) </td></tr> <tr> <td colspan="2" style="text-align:left; background:#f8eaba; border:1px solid #a2a9b1;"><div style="display: inline-block; line-height: 1.2em; padding: .1em 0;">Except where otherwise noted, data are given for materials in their <a href="/wiki/Standard_state" title="Standard state">standard state</a> (at 25 °C [77 °F], 100 kPa).</div> <div style="margin-top: 0.3em;"><div style="text-align:center;"><span typeof="mw:File"><span><img alt="☒" src="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/12px-X_mark.svg.png" decoding="async" width="12" height="14" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/18px-X_mark.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/24px-X_mark.svg.png 2x" data-file-width="525" data-file-height="600" /></span></span><span style="display:none">N</span> <span class="reflink plainlinks nourlexpansion"><a class="external text" href="https://en.wikipedia.org/w/index.php?title=Special:ComparePages&rev1=417178510&page2=Zirconyl+chloride">verify</a></span> (<a href="/wiki/Wikipedia:WikiProject_Chemicals/Chembox_validation" title="Wikipedia:WikiProject Chemicals/Chembox validation">what is</a> <sup><span typeof="mw:File"><span><img alt="check" src="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/7px-Yes_check.svg.png" decoding="async" width="7" height="7" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/11px-Yes_check.svg.png 1.5x, //upload.wikimedia.org/wikipedia/en/thumb/f/fb/Yes_check.svg/14px-Yes_check.svg.png 2x" data-file-width="600" data-file-height="600" /></span></span><span style="display:none">Y</span><span typeof="mw:File"><span><img alt="☒" src="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/7px-X_mark.svg.png" decoding="async" width="7" height="8" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/11px-X_mark.svg.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/a/a2/X_mark.svg/14px-X_mark.svg.png 2x" data-file-width="525" data-file-height="600" /></span></span><span style="display:none">N</span></sup> ?) </div></div> <div style="margin-top: 0.3em; text-align: center;"><a href="/wiki/Wikipedia:Chemical_infobox#References" title="Wikipedia:Chemical infobox">Infobox references</a></div> </td></tr> </tbody></table><div class="shortdescription nomobile noexcerpt noprint searchaux" style="display:none">Chemical compound</div> <p><b>Zirconyl chloride</b> is the <a href="/wiki/Inorganic_compound" title="Inorganic compound">inorganic compound</a> with the formula of [Zr<sub>4</sub>(OH)<sub>8</sub>(H<sub>2</sub>O)<sub>16</sub>]Cl<sub>8</sub>(H<sub>2</sub>O)<sub>12</sub>, more commonly written ZrOCl<sub>2</sub>·8H<sub>2</sub>O, and referred to as zirconyl chloride octahydrate. It is a white solid and is the most common water-soluble derivative of <a href="/wiki/Zirconium" title="Zirconium">zirconium</a>. A compound with the formula ZrOCl<sub>2</sub> has not been characterized.<sup id="cite_ref-Greenwd_1-0" class="reference"><a href="#cite_note-Greenwd-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> </p> <meta property="mw:PageProp/toc" /> <div class="mw-heading mw-heading2"><h2 id="Production_and_structure">Production and structure</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zirconyl_chloride&action=edit&section=1" title="Edit section: Production and structure"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <figure class="mw-default-size mw-halign-left" typeof="mw:File/Thumb"><a href="/wiki/File:Zr8O8core(KAVRUX).png" class="mw-file-description"><img src="//upload.wikimedia.org/wikipedia/commons/thumb/5/53/Zr8O8core%28KAVRUX%29.png/220px-Zr8O8core%28KAVRUX%29.png" decoding="async" width="220" height="232" class="mw-file-element" srcset="//upload.wikimedia.org/wikipedia/commons/thumb/5/53/Zr8O8core%28KAVRUX%29.png/330px-Zr8O8core%28KAVRUX%29.png 1.5x, //upload.wikimedia.org/wikipedia/commons/thumb/5/53/Zr8O8core%28KAVRUX%29.png/440px-Zr8O8core%28KAVRUX%29.png 2x" data-file-width="1200" data-file-height="1264" /></a><figcaption>Structure of the Zr<sub>6</sub>O<sub>8</sub> core of <a href="/wiki/Zirconyl_acetate" title="Zirconyl acetate">zirconyl acetate</a>] and zirconyl chloride.</figcaption></figure> <p>The salt is produced by hydrolysis of <a href="/wiki/Zirconium_tetrachloride" class="mw-redirect" title="Zirconium tetrachloride">zirconium tetrachloride</a> or treating <a href="/wiki/Zirconium_oxide" class="mw-redirect" title="Zirconium oxide">zirconium oxide</a> with <a href="/wiki/Hydrochloric_acid" title="Hydrochloric acid">hydrochloric acid</a>.<sup id="cite_ref-Ullmann_2-0" class="reference"><a href="#cite_note-Ullmann-2"><span class="cite-bracket">[</span>2<span class="cite-bracket">]</span></a></sup> It adopts a tetrameric structure, consisting of the cation [Zr<sub>4</sub>(OH)<sub>8</sub>]<sup>8+</sup>. features four pairs of hydroxide <a href="/wiki/Bridging_ligand" title="Bridging ligand">bridging ligands</a> linking four Zr<sup>4+</sup> centers. The chloride <a href="/wiki/Anion" class="mw-redirect" title="Anion">anions</a> are not <a href="/wiki/Ligand" title="Ligand">ligands</a>, consistent with the high <a href="/wiki/Oxophilicity" title="Oxophilicity">oxophilicity</a> of Zr(IV).<sup id="cite_ref-Greenwd_1-1" class="reference"><a href="#cite_note-Greenwd-1"><span class="cite-bracket">[</span>1<span class="cite-bracket">]</span></a></sup> The salt crystallizes as <a href="/wiki/Tetragonal" class="mw-redirect" title="Tetragonal">tetragonal</a> crystals.<sup id="cite_ref-3" class="reference"><a href="#cite_note-3"><span class="cite-bracket">[</span>3<span class="cite-bracket">]</span></a></sup> </p> <div class="mw-heading mw-heading2"><h2 id="See_also">See also</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zirconyl_chloride&action=edit&section=2" title="Edit section: See also"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a href="/wiki/Zirconyl_acetate" title="Zirconyl acetate">Zirconyl acetate</a></li></ul> <div class="mw-heading mw-heading2"><h2 id="References">References</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zirconyl_chloride&action=edit&section=3" title="Edit section: References"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <style data-mw-deduplicate="TemplateStyles:r1239543626">.mw-parser-output .reflist{margin-bottom:0.5em;list-style-type:decimal}@media screen{.mw-parser-output .reflist{font-size:90%}}.mw-parser-output .reflist .references{font-size:100%;margin-bottom:0;list-style-type:inherit}.mw-parser-output .reflist-columns-2{column-width:30em}.mw-parser-output .reflist-columns-3{column-width:25em}.mw-parser-output .reflist-columns{margin-top:0.3em}.mw-parser-output .reflist-columns ol{margin-top:0}.mw-parser-output .reflist-columns li{page-break-inside:avoid;break-inside:avoid-column}.mw-parser-output .reflist-upper-alpha{list-style-type:upper-alpha}.mw-parser-output .reflist-upper-roman{list-style-type:upper-roman}.mw-parser-output .reflist-lower-alpha{list-style-type:lower-alpha}.mw-parser-output .reflist-lower-greek{list-style-type:lower-greek}.mw-parser-output .reflist-lower-roman{list-style-type:lower-roman}</style><div class="reflist"> <div class="mw-references-wrap"><ol class="references"> <li id="cite_note-Greenwd-1"><span class="mw-cite-backlink">^ <a href="#cite_ref-Greenwd_1-0"><sup><i><b>a</b></i></sup></a> <a href="#cite_ref-Greenwd_1-1"><sup><i><b>b</b></i></sup></a></span> <span class="reference-text"><style data-mw-deduplicate="TemplateStyles:r1238218222">.mw-parser-output cite.citation{font-style:inherit;word-wrap:break-word}.mw-parser-output .citation q{quotes:"\"""\"""'""'"}.mw-parser-output .citation:target{background-color:rgba(0,127,255,0.133)}.mw-parser-output .id-lock-free.id-lock-free a{background:url("//upload.wikimedia.org/wikipedia/commons/6/65/Lock-green.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-limited.id-lock-limited a,.mw-parser-output .id-lock-registration.id-lock-registration a{background:url("//upload.wikimedia.org/wikipedia/commons/d/d6/Lock-gray-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .id-lock-subscription.id-lock-subscription a{background:url("//upload.wikimedia.org/wikipedia/commons/a/aa/Lock-red-alt-2.svg")right 0.1em center/9px no-repeat}.mw-parser-output .cs1-ws-icon a{background:url("//upload.wikimedia.org/wikipedia/commons/4/4c/Wikisource-logo.svg")right 0.1em center/12px no-repeat}body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-free a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-limited a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-registration a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .id-lock-subscription a,body:not(.skin-timeless):not(.skin-minerva) .mw-parser-output .cs1-ws-icon a{background-size:contain;padding:0 1em 0 0}.mw-parser-output .cs1-code{color:inherit;background:inherit;border:none;padding:inherit}.mw-parser-output .cs1-hidden-error{display:none;color:var(--color-error,#d33)}.mw-parser-output .cs1-visible-error{color:var(--color-error,#d33)}.mw-parser-output .cs1-maint{display:none;color:#085;margin-left:0.3em}.mw-parser-output .cs1-kern-left{padding-left:0.2em}.mw-parser-output .cs1-kern-right{padding-right:0.2em}.mw-parser-output .citation .mw-selflink{font-weight:inherit}@media screen{.mw-parser-output .cs1-format{font-size:95%}html.skin-theme-clientpref-night .mw-parser-output .cs1-maint{color:#18911f}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .cs1-maint{color:#18911f}}</style><cite id="CITEREFGreenwoodEarnshaw1997" class="citation book cs1"><a href="/wiki/Norman_Greenwood" title="Norman Greenwood">Greenwood, Norman N.</a>; Earnshaw, Alan (1997). <i>Chemistry of the Elements</i> (2nd ed.). <a href="/wiki/Butterworth-Heinemann" title="Butterworth-Heinemann">Butterworth-Heinemann</a>. <a href="/wiki/ISBN_(identifier)" class="mw-redirect" title="ISBN (identifier)">ISBN</a> <a href="/wiki/Special:BookSources/978-0-08-037941-8" title="Special:BookSources/978-0-08-037941-8"><bdi>978-0-08-037941-8</bdi></a>.</cite><span title="ctx_ver=Z39.88-2004&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Abook&rft.genre=book&rft.btitle=Chemistry+of+the+Elements&rft.edition=2nd&rft.pub=Butterworth-Heinemann&rft.date=1997&rft.isbn=978-0-08-037941-8&rft.aulast=Greenwood&rft.aufirst=Norman+N.&rft.au=Earnshaw%2C+Alan&rfr_id=info%3Asid%2Fen.wikipedia.org%3AZirconyl+chloride" class="Z3988"></span></span> </li> <li id="cite_note-Ullmann-2"><span class="mw-cite-backlink"><b><a href="#cite_ref-Ullmann_2-0">^</a></b></span> <span class="reference-text">Ralph Nielsen "Zirconium and Zirconium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1002%2F14356007.a28_543">10.1002/14356007.a28_543</a></span> </li> <li id="cite_note-3"><span class="mw-cite-backlink"><b><a href="#cite_ref-3">^</a></b></span> <span class="reference-text">T. W. Mak "Refinement of the crystal structure of zirconyl chloride octahydrate" Canadian Journal of Chemistry, 46, 3491 (1968) <link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1238218222"><a href="/wiki/Doi_(identifier)" class="mw-redirect" title="Doi (identifier)">doi</a>:<a rel="nofollow" class="external text" href="https://doi.org/10.1139%2Fv68-579">10.1139/v68-579</a></span> </li> </ol></div></div> <div class="mw-heading mw-heading2"><h2 id="External_links">External links</h2><span class="mw-editsection"><span class="mw-editsection-bracket">[</span><a href="/w/index.php?title=Zirconyl_chloride&action=edit&section=4" title="Edit section: External links"><span>edit</span></a><span class="mw-editsection-bracket">]</span></span></div> <ul><li><a rel="nofollow" class="external text" href="http://ptcl.chem.ox.ac.uk/MSDS/ZI/zirconium_oxychloride.html">MSDS Data</a></li> <li><a rel="nofollow" class="external text" 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aria-labelledby="Zirconium_compounds" style="padding:3px"><table class="nowraplinks mw-collapsible mw-collapsed navbox-inner" style="border-spacing:0;background:transparent;color:inherit"><tbody><tr><th scope="col" class="navbox-title" colspan="2"><link rel="mw-deduplicated-inline-style" href="mw-data:TemplateStyles:r1129693374"><style data-mw-deduplicate="TemplateStyles:r1239400231">.mw-parser-output .navbar{display:inline;font-size:88%;font-weight:normal}.mw-parser-output .navbar-collapse{float:left;text-align:left}.mw-parser-output .navbar-boxtext{word-spacing:0}.mw-parser-output .navbar ul{display:inline-block;white-space:nowrap;line-height:inherit}.mw-parser-output .navbar-brackets::before{margin-right:-0.125em;content:"[ "}.mw-parser-output .navbar-brackets::after{margin-left:-0.125em;content:" ]"}.mw-parser-output .navbar li{word-spacing:-0.125em}.mw-parser-output .navbar a>span,.mw-parser-output .navbar a>abbr{text-decoration:inherit}.mw-parser-output .navbar-mini abbr{font-variant:small-caps;border-bottom:none;text-decoration:none;cursor:inherit}.mw-parser-output .navbar-ct-full{font-size:114%;margin:0 7em}.mw-parser-output .navbar-ct-mini{font-size:114%;margin:0 4em}html.skin-theme-clientpref-night .mw-parser-output .navbar li a abbr{color:var(--color-base)!important}@media(prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .navbar li a abbr{color:var(--color-base)!important}}@media print{.mw-parser-output .navbar{display:none!important}}</style><div class="navbar plainlinks hlist navbar-mini"><ul><li class="nv-view"><a href="/wiki/Template:Zirconium_compounds" title="Template:Zirconium compounds"><abbr title="View this template">v</abbr></a></li><li class="nv-talk"><a href="/wiki/Template_talk:Zirconium_compounds" title="Template talk:Zirconium compounds"><abbr title="Discuss this template">t</abbr></a></li><li class="nv-edit"><a href="/wiki/Special:EditPage/Template:Zirconium_compounds" title="Special:EditPage/Template:Zirconium compounds"><abbr title="Edit this template">e</abbr></a></li></ul></div><div id="Zirconium_compounds" style="font-size:114%;margin:0 4em"><a href="/wiki/Zirconium_compounds" class="mw-redirect" title="Zirconium compounds">Zirconium compounds</a></div></th></tr><tr><th scope="row" class="navbox-group" style="width:1%">Zr(II)</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Zirconium_diboride" title="Zirconium diboride">ZrB<sub>2</sub></a></li> <li><a href="/wiki/Zirconium_dibromide" title="Zirconium dibromide"><span class="chemf nowrap">ZrBr<sub class="template-chem2-sub">2</sub></span></a></li> <li><a href="/wiki/Zirconium_dichloride" title="Zirconium dichloride"><span class="chemf nowrap">ZrCl<sub class="template-chem2-sub">2</sub></span></a></li> <li><a href="/wiki/Zirconium_difluoride" title="Zirconium difluoride"><span class="chemf nowrap">ZrF<sub class="template-chem2-sub">2</sub></span></a></li> <li><a href="/wiki/Zirconium(II)_hydride" title="Zirconium(II) hydride">ZrH<sub>2</sub></a></li> <li><a href="/wiki/Zirconium_disilicide" title="Zirconium disilicide">ZrSi<sub>2</sub></a></li> <li><a href="/wiki/Zirconium(II)_iodide" title="Zirconium(II) iodide"><span class="chemf nowrap">ZrI<sub class="template-chem2-sub">2</sub></span></a></li> <li><a href="/wiki/Zirconium(II)_iodide" title="Zirconium(II) iodide"><span class="chemf nowrap">ZrI<sub class="template-chem2-sub">2</sub></span></a></li> <li><a href="/wiki/Zirconium_monoxide" class="mw-redirect" title="Zirconium monoxide">ZrO</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">Zr(III)</th><td class="navbox-list-with-group navbox-list navbox-even hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Zirconium_nitride" title="Zirconium nitride">ZrN</a></li> <li><a href="/wiki/Zirconium(III)_chloride" title="Zirconium(III) chloride">ZrCl<sub>3</sub></a></li> <li><a href="/wiki/Zirconium(III)_bromide" title="Zirconium(III) bromide">ZrBr<sub>3</sub></a></li> <li><a href="/wiki/Zirconium_trifluoride" title="Zirconium trifluoride"><span class="chemf nowrap">ZrF<sub class="template-chem2-sub">3</sub></span></a></li> <li><a href="/wiki/Zirconium(III)_iodide" title="Zirconium(III) iodide">ZrI<sub>3</sub></a></li> <li><a href="/wiki/Zirconium_phosphide" class="mw-redirect" title="Zirconium phosphide">ZrP</a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">Zr(IV)</th><td class="navbox-list-with-group navbox-list navbox-odd hlist" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Zirconium(IV)_acetate" title="Zirconium(IV) acetate">Zr<sub>6</sub>O<sub>4</sub>(OH)<sub>4</sub>(O<sub>2</sub>CCH<sub>3</sub>)<sub>12</sub></a></li> <li><a href="/wiki/Zirconium(IV)_bromide" title="Zirconium(IV) bromide">ZrBr<sub>4</sub></a></li> <li><a href="/wiki/Zirconium_carbide" title="Zirconium carbide">ZrC</a></li> <li><a href="/wiki/Zirconium(IV)_chloride" title="Zirconium(IV) chloride">ZrCl<sub>4</sub></a></li> <li><a href="/wiki/Zirconium_iodate" title="Zirconium iodate">Zr(IO<sub>3</sub>)<sub>4</sub></a></li> <li><a href="/wiki/Zirconium(IV)_iodide" title="Zirconium(IV) iodide">ZrI<sub>4</sub></a></li> <li><a href="/wiki/Zirconium(IV)_nitrate" class="mw-redirect" title="Zirconium(IV) nitrate">Zr(NO<sub>3</sub>)<sub>4</sub></a></li> <li><a class="mw-selflink selflink">ZrOCl<sub>2</sub></a></li> <li><a href="/wiki/Zirconium_perchlorate" title="Zirconium perchlorate">Zr(ClO<sub>4</sub>)<sub>4</sub></a></li> <li><a href="/wiki/Zirconium(IV)_hydroxide" title="Zirconium(IV) hydroxide">Zr(OH)<sub>4</sub></a></li> <li><a href="/wiki/Zirconium_diphosphide" title="Zirconium diphosphide"><span class="chemf nowrap">ZrP<sub class="template-chem2-sub">2</sub></span></a></li> <li><a href="/wiki/Zirconium_phosphate" title="Zirconium phosphate">Zr(HPO<sub>4</sub>)<sub>2</sub></a></li> <li><a href="/wiki/Zirconium(IV)_sulfide" class="mw-redirect" title="Zirconium(IV) sulfide">ZrS<sub>2</sub></a></li> <li><a href="/wiki/Zirconium(IV)_sulfate" title="Zirconium(IV) sulfate">Zr(SO<sub>4</sub>)<sub>2</sub></a></li> <li><a href="/wiki/Zirconium(IV)_selenate" class="mw-redirect" title="Zirconium(IV) selenate">Zr(SeO<sub>4</sub>)<sub>2</sub></a></li> <li><a href="/wiki/Zirconium(IV)_silicate" title="Zirconium(IV) silicate">ZrSiO<sub>4</sub></a></li> <li><a href="/wiki/Zirconium_tungstate" title="Zirconium tungstate">Zr(WO<sub>4</sub>)<sub>2</sub></a></li></ul> </div><table class="nowraplinks navbox-subgroup" style="border-spacing:0"><tbody><tr><th scope="row" class="navbox-group" style="width:1%">Acids and complexes</th><td class="navbox-list-with-group navbox-list navbox-even" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Zirconium(IV)_fluoride" class="mw-redirect" title="Zirconium(IV) fluoride">ZrF<sub>4</sub></a></li> <li><a href="/wiki/Lithium_hexafluorozirconate" title="Lithium hexafluorozirconate"><span class="chemf nowrap">Li<sub class="template-chem2-sub">2</sub>ZrF<sub class="template-chem2-sub">6</sub></span></a></li> <li><a href="/wiki/Potassium_hexafluorozirconate" title="Potassium hexafluorozirconate"><span class="chemf nowrap">K<sub class="template-chem2-sub">2</sub>ZrF<sub class="template-chem2-sub">6</sub></span></a></li> <li><a href="/wiki/Ammonium_hexafluorozirconate" title="Ammonium hexafluorozirconate"><span class="chemf nowrap">(NH<sub class="template-chem2-sub">4</sub>)<sub class="template-chem2-sub">2</sub>ZrF<sub class="template-chem2-sub">6</sub></span></a></li> <li><a href="/wiki/Zirconium_dioxide" title="Zirconium dioxide">ZrO<sub>2</sub></a></li> <li><a href="/wiki/Cesium_zirconate" class="mw-redirect" title="Cesium zirconate"><span class="chemf nowrap">Cs<sub class="template-chem2-sub">2</sub>ZrO<sub class="template-chem2-sub">3</sub></span></a></li></ul> </div></td></tr><tr><th scope="row" class="navbox-group" style="width:1%">Organozirconium(IV)</th><td class="navbox-list-with-group navbox-list navbox-odd" style="width:100%;padding:0"><div style="padding:0 0.25em"> <ul><li><a href="/wiki/Zirconium_acetylacetonate" title="Zirconium acetylacetonate">Zr(acac)<sub>4</sub></a></li> <li><a href="/wiki/(Cyclopentadienyl)zirconium_trichloride" title="(Cyclopentadienyl)zirconium trichloride">(C<sub>5</sub>H<sub>5</sub>)ZrCl<sub>3</sub></a></li> <li><a href="/wiki/Zirconocene_dichloride" title="Zirconocene dichloride">Cp<sub>2</sub>ZrCl<sub>2</sub></a></li> <li><a href="/wiki/Zirconium_stearate" title="Zirconium stearate"><span class="chemf nowrap">C<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">72</sub></span></span>H<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">140</sub></span></span>ZrO<span class="nowrap"><span style="display:inline-block;margin-bottom:-0.3em;vertical-align:-0.4em;line-height:1em;font-size:80%;text-align:left"><sup style="font-size:inherit;line-height:inherit;vertical-align:baseline"></sup><br /><sub style="font-size:inherit;line-height:inherit;vertical-align:baseline">8</sub></span></span></span></a></li></ul> </div></td></tr></tbody></table><div> </div></td></tr></tbody></table></div>    </div><noscript><img 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