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Mystery tap water substance finally discovered, concerning scientists
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class="entry-content cols-6 md-cols-1 cols-gap-1 margin-top-1"> <div class="content-left-sidebar cols-1 col"> <section class="contributors md-cols-1 rows-gap"> <div class="row post-date"> <span class="published-date">November 22, 2024</span> </div> <a href="https://cosmosmagazine.com/contributor/ellen-phiddian/" class="author row md-hide"> <img src="data:image/svg+xml;base64,PHN2ZyB4bWxucz0iaHR0cDovL3d3dy53My5vcmcvMjAwMC9zdmciIHZpZXdCb3g9IjAgMCA0NTAgNDM2IiB3aWR0aD0iNDUwIiBoZWlnaHQ9IjQzNiIgZGF0YS11PSIlMkZ3cC1jb250ZW50JTJGdXBsb2FkcyUyRjIwMjElMkYwMiUyRkVsbGVuLXNtYWxsLmpwZyIgZGF0YS13PSI0NTAiIGRhdGEtaD0iNDM2IiBkYXRhLWJpcD0iIj48L3N2Zz4=" data-spai="1" alt="Ellen Phiddian" width="200" /><noscript data-spai="1"><img src="https://cdn.shortpixel.ai/spai/q_lossy+ret_img+to_auto/cosmosmagazine.com/wp-content/uploads/2021/02/Ellen-small.jpg" data-spai-egr="1" alt="Ellen Phiddian" width="200" /></noscript> <div class="bio"> <h3>Ellen Phiddian</h3> <p>Cosmos science journalist</p> </div> </a> <div id="author-name" class="hide"> <a href="https://cosmosmagazine.com/contributor/ellen-phiddian/" class="bio"> By Ellen Phiddian </a> </div> <div class="favourite__wrapper row cols"> <button class="showDialog simplefavorite-button" aria-label="Favourite button"> </button> </div> </section> </div> <div class="primary-content cols-1 col-span-5 col"> <div class="flexible-content "> <div class="copy"> <figure class="wp-block-image size-full"><img decoding="async" fetchpriority="high" width="850" height="478" src="data:image/svg+xml;base64,PHN2ZyB4bWxucz0iaHR0cDovL3d3dy53My5vcmcvMjAwMC9zdmciIHZpZXdCb3g9IjAgMCA4NTAgNDc4IiB3aWR0aD0iODUwIiBoZWlnaHQ9IjQ3OCIgZGF0YS11PSIlMkZ3cC1jb250ZW50JTJGdXBsb2FkcyUyRjIwMjMlMkYwNyUyRjg1MC0xNi1HZXR0eUltYWdlcy0xNDQ1MzgxODY1LmpwZyIgZGF0YS13PSI4NTAiIGRhdGEtaD0iNDc4IiBkYXRhLWJpcD0iIj48L3N2Zz4=" data-spai="1" alt="Hand filling glass with tap water" class="wp-image-316639" title="substance unknown to science identified in tap water 1"><noscript data-spai="1"><img decoding="async" fetchpriority="high" width="850" height="478" src="https://cdn.shortpixel.ai/spai/q_lossy+ret_img+to_auto/cosmosmagazine.com/wp-content/uploads/2023/07/850-16-GettyImages-1445381865.jpg" data-spai-egr="1" alt="Hand filling glass with tap water" class="wp-image-316639" srcset="https://cdn.shortpixel.ai/spai/q_lossy+ret_img+to_auto/cosmosmagazine.com/wp-content/uploads/2023/07/850-16-GettyImages-1445381865.jpg 850w, https://cdn.shortpixel.ai/spai/q_lossy+ret_img+to_auto/cosmosmagazine.com/wp-content/uploads/2023/07/850-16-GettyImages-1445381865-600x337.jpg 600w, https://cdn.shortpixel.ai/spai/q_lossy+ret_img+to_auto/cosmosmagazine.com/wp-content/uploads/2023/07/850-16-GettyImages-1445381865-768x432.jpg 768w, https://cdn.shortpixel.ai/spai/q_lossy+ret_img+to_auto/cosmosmagazine.com/wp-content/uploads/2023/07/850-16-GettyImages-1445381865-300x169.jpg 300w" sizes="(max-width: 850px) 100vw, 850px" title="substance unknown to science identified in tap water 1"></noscript><figcaption class="wp-element-caption">Credit: d3sign / Getty Images</figcaption></figure> <p>After eluding chemists for 40 years, a mystery compound found in drinking water has finally been identified.</p> <p>The compound – called chloronitramide anion – is previously unknown to science.</p> <p>While it’s important to research the toxicity of the compound, independent experts say it’s no reason to avoid your <a href="https://cosmosmagazine.com/earth/tapwater-explainer/" target="_blank" rel="noreferrer noopener">tap water</a>.</p> <p>The compound forms, according to a <a href="https://doi.org/10.1126/science.adk6749" target="_blank" rel="noreferrer noopener">paper</a> in <em>Science,</em> as a by-product of common disinfectants called chloramines.</p> <p>The mystery molecule has a very simple structure, by chemical standards: Cl-N-NO<sub>2</sub><sup>–</sup>.</p> <p>The researchers identified it in 40 samples of tap water from the USA, at an average concentration of 23 micrograms, or 0.00023 grams, per litre.</p> <div class="advert ad-in-content ad-mobile auh-250"><div id="adn-00000000001fc2ca-i0p0" style="display: none"></div></div> <p>“This compound will be present in any chloramine system,” lead author Associate Professor Julian Fairey, a civil engineer at the University of Arkansas, USA, tells <em>Cosmos.</em></p> <p>“However, it could also form in systems that use chlorine or chlorine dioxide in which ammonia-nitrogen or other nitrogen-containing compounds are present.”</p> <p>The compound was first detected more than 40 years ago, as an unidentified signal from an analysis using UV light.</p> <p>Fairey began trying to unmask it 10 years ago. The tiny molecular size of the compound made it hard to pin down.</p> <p>“It does seem like a long time coming!” he says.</p> <div class="advert ad-in-content ad-mobile auh-250"><div id="adn-00000000001fc2ca-i1p0" style="display: none"></div></div> <p>“However, chloramine chemistry is complicated and until our <a href="https://doi.org/10.1021/acs.est.0c06456" target="_blank" rel="noreferrer noopener">recent</a> <a href="https://pubs.acs.org/doi/10.1021/acs.est.3c08088" target="_blank" rel="noreferrer noopener">work</a>, the formation pathway of this mysterious compound was not well understood.”</p> <figure class="wp-block-image size-full"><img decoding="async" width="850" height="567" src="data:image/svg+xml;base64,PHN2ZyB4bWxucz0iaHR0cDovL3d3dy53My5vcmcvMjAwMC9zdmciIHZpZXdCb3g9IjAgMCA4NTAgNTY3IiB3aWR0aD0iODUwIiBoZWlnaHQ9IjU2NyIgZGF0YS11PSIlMkZ3cC1jb250ZW50JTJGdXBsb2FkcyUyRjIwMjMlMkYwNyUyRjg1MC0xMDgwM19KdWxpYW5fRmFpcmV5X0FSTmV3c19SZXNlYXJjaC0yNC01MC5qcGciIGRhdGEtdz0iODUwIiBkYXRhLWg9IjU2NyIgZGF0YS1iaXA9IiI+PC9zdmc+" data-spai="1" alt="Person in lab" class="wp-image-316638" title="substance unknown to science identified in tap water 2"><noscript data-spai="1"><img decoding="async" width="850" height="567" src="https://cdn.shortpixel.ai/spai/q_lossy+ret_img+to_auto/cosmosmagazine.com/wp-content/uploads/2023/07/850-10803_Julian_Fairey_ARNews_Research-24-50.jpg" data-spai-egr="1" alt="Person in lab" class="wp-image-316638" srcset="https://cdn.shortpixel.ai/spai/q_lossy+ret_img+to_auto/cosmosmagazine.com/wp-content/uploads/2023/07/850-10803_Julian_Fairey_ARNews_Research-24-50.jpg 850w, https://cdn.shortpixel.ai/spai/q_lossy+ret_img+to_auto/cosmosmagazine.com/wp-content/uploads/2023/07/850-10803_Julian_Fairey_ARNews_Research-24-50-600x400.jpg 600w, https://cdn.shortpixel.ai/spai/q_lossy+ret_img+to_auto/cosmosmagazine.com/wp-content/uploads/2023/07/850-10803_Julian_Fairey_ARNews_Research-24-50-768x512.jpg 768w, https://cdn.shortpixel.ai/spai/q_lossy+ret_img+to_auto/cosmosmagazine.com/wp-content/uploads/2023/07/850-10803_Julian_Fairey_ARNews_Research-24-50-300x200.jpg 300w" sizes="(max-width: 850px) 100vw, 850px" title="substance unknown to science identified in tap water 2"></noscript><figcaption class="wp-element-caption">Julian Fairey. Credit: University Relations</figcaption></figure> <p>The researchers were able to identify it by making it from compounds used to disinfect water, and performing a number of analytical techniques to show it was the same thing as the mystery water feature.</p> <p>Because no-one knew the compound’s identity, it’s not yet clear if it’s dangerous to human health. But computer modelling suggests it could be problematic.</p> <a href="https://link.cosmosmagazine.com/OP59" class="newsletter-cta" data-device="mobile"> <img decoding="async" src="data:image/svg+xml;base64,PHN2ZyB4bWxucz0iaHR0cDovL3d3dy53My5vcmcvMjAwMC9zdmciIHZpZXdCb3g9IjAgMCAzMDAgMjUwIiB3aWR0aD0iMzAwIiBoZWlnaHQ9IjI1MCIgZGF0YS11PSIlMkZ3cC1jb250ZW50JTJGdXBsb2FkcyUyRjIwMjQlMkYwMyUyRldlZWtseS1DYXRjaHVwLTMwMHgyNTAtMS5wbmciIGRhdGEtdz0iMzAwIiBkYXRhLWg9IjI1MCIgZGF0YS1iaXA9IiI+PC9zdmc+" data-spai="1" alt="Newsletter" title="substance unknown to science identified in tap water 3"><noscript data-spai="1"><img decoding="async" src="https://cdn.shortpixel.ai/spai/q_lossy+ret_img+to_auto/cosmosmagazine.com/wp-content/uploads/2024/03/Weekly-Catchup-300x250-1.png" data-spai-egr="1" alt="Newsletter" title="substance unknown to science identified in tap water 3"></noscript> </a> <p>“We plan to collaborate with toxicity experts to help assess the public health relevance of this compound,” says Fairey.</p> <p>“It’s widely acknowledged that we don’t know the precise chemical identity of all the substances that form as byproducts from drinking water disinfection,” Professor Stuart Khan, a civil engineer at the University of Sydney, tells <em>Cosmos.</em></p> <div class="advert ad-in-content ad-mobile auh-250"><div id="adn-00000000001fc2ca-i2p0" style="display: none"></div></div> <p>Khan, who was not involved with the study, says that it would be useful to have occurrence and toxicity data for the compound.</p> <p>“It’s not surprising – and it’s potentially very helpful – to see the science chugging away at gradually identifying more and more of the components,” he says.</p> <div class="in-content-area related-box-wrapper content-third content-right margin-bottom-1"> <div class="gradient-title">Read More</div> <ul class="related-box article-listing"> <li class="cols"> <div class="article article-post"> <a href="https://cosmosmagazine.com/earth/tapwater-explainer/" class="thumbnail ar-16-9" aria-label="Article link"> <span data-spai-bg-on="1" class="image" style="background-image: url(data:image/svg+xml;base64,PHN2ZyB4bWxucz0iaHR0cDovL3d3dy53My5vcmcvMjAwMC9zdmciIHZpZXdCb3g9IjAgMCAxMjAwIDY3NSIgd2lkdGg9IjEyMDAiIGhlaWdodD0iNjc1IiBkYXRhLXU9Imh0dHBzJTNBJTJGJTJGY29zbW9zbWFnYXppbmUuY29tJTJGd3AtY29udGVudCUyRnVwbG9hZHMlMkYyMDIyJTJGMDclMkYxMjAwLUdldHR5SW1hZ2VzLTEwMDIwMTA3NjIuanBnIiBkYXRhLXc9IjEyMDAiIGRhdGEtaD0iNjc1IiBkYXRhLWJpcD0iIj48L3N2Zz4=)"></span> </a> <div class="article-content has-very-light-grey-background-color"> <a href="/earth/"> <span class="category earth-color"> Earth </span> </a> <a href="https://cosmosmagazine.com/earth/tapwater-explainer/"> <h3>Explainer: what’s in my tapwater, and why isn’t it pure?</h3> </a> </div> </div> </li> </ul> </div> <p>“I agree that a toxicological investigation of this would be useful now that we know its identity, but I am not overly worried about my tap water,” says Professor Oliver Jones, a chemist at RMIT University, who also wasn’t involved with the research.</p> <p>“The compound in question is not newly discovered, just newly defined.”</p> <p>Fairey says that agencies need to develop analytical techniques for finding Cl-N-NO<sub>2</sub><sup>–</sup> in drinking water, so it can be monitored.</p> <div class="advert ad-in-content ad-mobile auh-250"><div id="adn-00000000001fc2ca-i3p0" style="display: none"></div></div> <p>“We also need to advance formation methods for this compound to generate sufficient quantities for health effects studies,” he says.</p> <p>Khan adds that disinfecting drinking water “saves millions of illnesses and deaths”.</p> <p>“The very low levels of toxicity that have been reported for disinfected drinking water are many orders of magnitude safer than a situation we would have without disinfection,” he says.</p> <p>“I used to work in a lab in the US that had a sign on the wall that read ‘drinking water disinfection has allowed millions of people to live long enough 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