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New and Future Developments in Catalysis - 1st Edition | Elsevier Shop

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Both homogeneous and heterogeneous catalysts and catalytic processes will be discussed in a unified and comprehensive approach. There will be extensive cross-referencing within all volumes.<br /><br />The use of catalysts in the nanoscale offers various advantages (increased efficiency and less byproducts), and these are discussed in this volume along with the various catalytic processes using nanoparticles. However, this is not without any risks and the safety aspects and effects on humans and the environment are still unknown. The present data as well as future needs are all part of this volume along with the economics involved. </p></div></span></div></div></div></div><div class="_16jmeqbik _16jmeqbkg _16jmeqb1s _16jmeqb18 _16jmeqb0 _16jmeqb70 _16jmeqb1ii"><button class="_16jmeqbwo _16jmeqb17y" aria-expanded="false" aria-controls="keyFeatures-accordion"><div class="_16jmeqbis _16jmeqbko _16jmeqb1s _16jmeqb10 _16jmeqb4 _16jmeqbw"><span class="ou5ptd0 gv4p8b0 _16jmeqb166 _16jmeqb167 _16jmeqbsi _16jmeqbsc _16jmeqb16m" data-text-size="md"><div class="" id="keyFeatures">Key features</div></span><svg viewBox="0 0 24 24" class=" nddnvd4 nddnvd5 nddnvd8"><path fill="currentColor" fill-rule="evenodd" d="M12.938 10.875V3.75h-1.876v7.125H3.939v1.875h7.124v7.125h1.876V12.75h7.124v-1.875h-7.125Z" clip-rule="evenodd"></path></svg></div></button><div class="" hidden="" id="keyFeatures-accordion"><div class="_16jmeqbik _16jmeqbkg _16jmeqb1s _16jmeqb18 _16jmeqb0"><div class="gv4p8b0 _16jmeqb166 _16jmeqb167 _16jmeqbsi _16jmeqbsc _16jmeqb16m" data-text-size="md"><span><span class="_12fsmvo0 _16jmeqbsc"><ul> <li>Offers in-depth coverage of all catalytic topics of current interest and outlines future challenges and research areas</li> <li>A clear and visual description of all parameters and conditions, enabling the reader to draw conclusions for a particular case</li> <li>Outlines the catalytic processes applicable to energy generation and design of green processes</li></ul></span></span></div></div></div></div><div class="_16jmeqbik _16jmeqbkg _16jmeqb1s _16jmeqb18 _16jmeqb0 _16jmeqb70 _16jmeqb1ii"><button class="_16jmeqbwo _16jmeqb17y" aria-expanded="false" aria-controls="readership-accordion"><div class="_16jmeqbis _16jmeqbko _16jmeqb1s _16jmeqb10 _16jmeqb4 _16jmeqbw"><span class="ou5ptd0 gv4p8b0 _16jmeqb166 _16jmeqb167 _16jmeqbsi _16jmeqbsc _16jmeqb16m" data-text-size="md"><div class="" id="readership">Readership</div></span><svg viewBox="0 0 24 24" class=" nddnvd4 nddnvd5 nddnvd8"><path fill="currentColor" fill-rule="evenodd" d="M12.938 10.875V3.75h-1.876v7.125H3.939v1.875h7.124v7.125h1.876V12.75h7.124v-1.875h-7.125Z" clip-rule="evenodd"></path></svg></div></button><div class="" hidden="" id="readership-accordion"><div class="_16jmeqbik _16jmeqbkg _16jmeqb1s _16jmeqb18 _16jmeqb0"><div class="gv4p8b0 _16jmeqb166 _16jmeqb167 _16jmeqbsi _16jmeqbsc _16jmeqb16m" data-text-size="md"><span><span class="_12fsmvo0 _16jmeqbsc"><p>Chemists, chemical engineers, and biochemical engineers working in academic and government research; academics, research students, post graduate and graduate students in these areas of study; materials scientists, environmental engineers, biochemists, petroleum engineers, post graduate and research students in these areas</p></span></span></div></div></div></div><div class="_16jmeqbik _16jmeqbkg _16jmeqb1s _16jmeqb18 _16jmeqb0 _16jmeqb70 _16jmeqb1ii"><button class="_16jmeqbwo _16jmeqb17y" aria-expanded="false" aria-controls="tableOfContents-accordion"><div class="_16jmeqbis _16jmeqbko _16jmeqb1s _16jmeqb10 _16jmeqb4 _16jmeqbw"><span class="ou5ptd0 gv4p8b0 _16jmeqb166 _16jmeqb167 _16jmeqbsi _16jmeqbsc _16jmeqb16m" data-text-size="md"><div class="" id="tableOfContents">Table of contents</div></span><svg viewBox="0 0 24 24" class=" nddnvd4 nddnvd5 nddnvd8"><path fill="currentColor" fill-rule="evenodd" d="M12.938 10.875V3.75h-1.876v7.125H3.939v1.875h7.124v7.125h1.876V12.75h7.124v-1.875h-7.125Z" clip-rule="evenodd"></path></svg></div></button><div class="" hidden="" id="tableOfContents-accordion"><div class="_16jmeqbik _16jmeqbkg _16jmeqb1s _16jmeqb18 _16jmeqb0"><div class="gv4p8b0 _16jmeqb166 _16jmeqb167 _16jmeqbsi _16jmeqbsc _16jmeqb16m" data-text-size="md"><span><div class="_12fsmvo0 hprf9u0 _16jmeqbsc"><p>Introduction</p> <p>Contributors</p> <p>Chapter 1. Gold-Based Catalysts for CO Oxidation, the Water-Gas Shift, and Desulfurization Processes</p> <p>Acknowledgments</p> <p>1.1 Introduction</p> <p>1.2 Bonding Interactions Between Gold and Metal Oxide or Carbide Surfaces</p> <p>1.3 Oxidation of Carbon Monoxide on Au-Oxide and Au-Carbide Surfaces</p> <p>1.4 Water-Gas Shift Reaction on Au-Oxide Surfaces</p> <p>1.5 Decomposition of Sulfur Dioxide on Au-Oxide and Au-Carbide Surfaces</p> <p>1.6 Conclusions</p> <p>References</p> <p>Chapter 2. Structural and Electronic Properties of Group 6 Transition Metal Oxide Clusters</p> <p>Acknowledgments</p> <p>2.1 Introduction</p> <p>2.2 Accurate Thermochemistry for Transition Metal Oxide Clusters</p> <p>2.3 Group 6 Transition Metal Oxides</p> <p>2.4 Group 6 Transition Metal Hydroxides: Hydrolysis of Metal Oxide Clusters</p> <p>Conclusions</p> <p>References</p> <p>Chapter 3. Nanoparticle Catalysis for Reforming of Biomass-Derived Fuels</p> <p>Acknowledgment</p> <p>3.1 Introduction</p> <p>3.2 Biogas Reforming</p> <p>3.3 Oxygenates Reforming</p> <p>3.4 Conclusions</p> <p>References</p> <p>Chapter 4. Nanoparticles in Biocatalysis</p> <p>4.1 What is Biocatalysis?</p> <p>4.2 Nanomaterials as Enzyme Supports</p> <p>4.3 Bionanocatalysis</p> <p>4.4 Conclusion</p> <p>References</p> <p>Chapter 5. Thin Iron Heme Enzyme Films on Electrodes and Nanoparticles for Biocatalysis</p> <p>Acknowledgments</p> <p>5.1 Why Enzyme Biocatalysis on Electrodes and Nanoparticles?</p> <p>5.2 Cyt P450 Electrocatalysis on Electrodes</p> <p>5.3 Cyt P450 Biocatalysis on Nanoparticles</p> <p>5.4 Summary and Prospects for the Future</p> <p>References</p> <p>Chapter 6. Nanoparticles as Enzyme Mimics</p> <p>6.1 Introduction</p> <p>6.2 Nanoparticles and Their Properties in Solution, Uptake in Cells, and Clearance</p> <p>6.3 Chemically Active Nanoparticles</p> <p>6.4 Other Oxidoreductase Mimics—Superoxide Dismutases and Oxidases</p> <p>6.5 Conclusions/Outlook</p> <p>References</p> <p>Chapter 7. A Physical Approach to Monitoring Biological Activity of Nanoparticulates</p> <p>Acknowledgments</p> <p>7.1 Fibrous Character of Carbon Nanotubes (CNT)</p> <p>7.2 Biological Activity of Nano-Sized Particulates of Some Oxides</p> <p>7.3 <i>In Vitro</i> versus <i>In Vivo</i> Testing for Biotoxicity of Nanomaterials</p> <p>7.4 Fundamental Approach to the Problem of Health Hazards Posed by Inhalation of Nanoparticulates of Diverse Chemicals</p> <p>7.5 Experimental Evidence Forming the Basis of the Proposed Model</p> <p>7.6 Physico-Chemical Approach to Monitoring Bioactivity</p> <p>7.7 Thermally Stimulated Luminescence, Conductivity, and Exoelectron Emission [51–59]</p> <p>7.8 How Can Emission Mössbauer Spectroscopy (EMS) Help in Identification and Estimation of Bioactive Defects?</p> <p>7.9 Remedial Measures: Procedures Adopted for Preparation and Passivation of Defect Sites</p> <p>7.10 Summary</p> <p>References</p> <p>Chapter 8. Morphology-Tailored Titania Nanoparticles</p> <p>Acknowledgment</p> <p>8.1 Introduction</p> <p>8.2 Ionic Liquids</p> <p>8.3 Combustion-Assisted Methods</p> <p>8.4 Gas Flame Combustion</p> <p>8.5 Sonochemical Methods</p> <p>8.6 Reverse Microemulsion</p> <p>8.7 Methods Starting from Metallic Titanium</p> <p>8.8 Anodization</p> <p>8.9 Modification of Commercial Titania</p> <p>8.10 Miscellaneous Methods</p> <p>8.11 Conclusions</p> <p>References</p> <p>Chapter 9. Metal Oxide Nanotube, Nanorod, and Quantum Dot Photocatalysis</p> <p>Acknowledgments</p> <p>9.1 Introduction</p> <p>9.2 Semiconductor Photocatalysts</p> <p>9.3 Advantages of Nanoparticles</p> <p>9.4 Nanoparticle Synthesis</p> <p>9.5 Doping</p> <p>9.6 Metal Nanoparticles</p> <p>9.7 Quantum Dots</p> <p>9.8 Carbon Heterojunctions</p> <p>9.9 Water Splitting</p> <p>9.10 CO<sub>2</sub> Reduction</p> <p>9.11 Solar Photocatalysis</p> <p>9.12 Photodynamic Therapy PDT</p> <p>9.13 Future Directions</p> <p>References</p> <p>Chapter 10. Photocatalytic Nanooxides: The Case of TiO<sub>2</sub> and ZnO</p> <p>Acknowledgments</p> <p>10.1 Introduction</p> <p>10.2 The Case of Bare Oxides</p> <p>10.3 Doping and Composite Systems Based in Titania and Zinc Oxides</p> <p>References</p> <p>Chapter 11. Recent Advances in Photocatalytic Processes by Nanomaterials</p> <p>Acknowledgment</p> <p>11.1 Photocatalysts and Mechanisms of Photocatalysis Processes</p> <p>11.2 Applications of Photocatalysts</p> <p>11.3 Challenges and Issues with Possible Solutions in Photocatalytic Processes</p> <p>11.4 Conclusions</p> <p>References</p> <p>Chapter 12. Insights into Heterogeneous Catalysis through Surface Science Techniques</p> <p>Acknowledgments</p> <p>12.1 Introduction</p> <p>12.2 X-ray Photoelectron Spectroscopy Under Near Ambient Conditions (APXPS)</p> <p>12.3 Vibrational Spectroscopy at High Pressures</p> <p>12.3.1 Polarization Modulation Infrared Reflection Absorption Spectroscopy (PM-IRRAS)</p> <p>12.3.2 Sum Frequency Generation Spectroscopy</p> <p>12.4 Surface Science Studies Using High Pressure Techniques</p> <p>12.5 Conclusion and Outlook</p> <p>References</p> <p>Chapter 13. Block Copolymer Lithography</p> <p>13.1 Introduction</p> <p>13.2 Introduction to Block copolymers</p> <p>13.3 Catalysis</p> <p>13.4 New Frontiers: Plasmonics</p> <p>13.5 Outlook</p> <p>References</p> <p>Chapter 14. Multi-Metallic Nanoparticles as More Efficient Catalysts for Fuel Cell Reactions</p> <p>14.1 Introduction</p> <p>14.2 Multi-Metallic Alloy NPs</p> <p>14.3 Dumbbell NPs</p> <p>14.4 Core/Shell NPs</p> <p>14.5 Conclusions and Perspectives</p> <p>References</p> <p>Chapter 15. Hydrogenation by Nanoparticle Catalysts</p> <p>Acknowledgment</p> <p>15.1 Introduction</p> <p>15.2 Hydrogenation Catalysts</p> <p>15.3 Hydrogenation by Monometallic Nanoparticles</p> <p>15.4 Hydrogenation by Bimetallic Nanoparticles</p> <p>15.5 Hydrogenation by Multimetallic Nanoparticles</p> <p>15.6 Future Outlook: Nanoparticle-Catalyzed Hydrodeoxygenation</p> <p>15.7 Summary</p> <p>References</p> <p>Chapter 16. Silicone Stabilized Nanoparticles as Hybrid Phase Catalysts for Selective Hydrolytic Oxidation of Hydrosilanes</p> <p>Acknowledgments</p> <p>16.1 Introduction</p> <p>16.2 What are Silanols?</p> <p>16.3 Pt-nanoparticle Catalyzed Hydrolytic Oxidation of Organosilanes</p> <p>16.4 Investigation of the Nature of Catalysts</p> <p>16.5 Mechanistic Proposal</p> <p>16.6 Polymerization of Bis-silanols via Dehydrocoupling Reaction</p> <p>16.7 Conclusion</p> <p>16.8 Experimental Section</p> <p>16.8.1 Preparation and Characterization of Functional Silanes (1j-1n and 1p-1s)</p> <p>References</p> <p>Chapter 17. Basics of PEMFC Including the Use of Carbon-Supported Nanoparticles</p> <p>Acknowledgments</p> <p>17.1 Introduction</p> <p>17.2 Basics of PEFMC Operation</p> <p>17.3 Durability Issues in Fuel Cells</p> <p>17.4 Beyond Classical Carbon-Supported Pt-Based Nanoparticles</p> <p>17.5 Conclusion</p> <p>References</p> <p>Chapter 18. Supported Gold Nanoparticles as Heterogeneous Catalysts</p> <p>18.1 Introduction and Historical Perspective of Recent Gold Catalysis Developments</p> <p>18.2 Methodologies to Obtain Gold Nanoparticles Supported on Insoluble Solids</p> <p>18.3 Role of Support</p> <p>18.4 Role of Metal Oxides in Gold Catalysis</p> <p>18.5 Gold Nanoparticles as Catalysts in Organic Reactions</p> <p>18.6 Aerobic Oxidation of Alcohols</p> <p>18.7 Selective Nitro Group Hydrogenation</p> <p>18.8 Concluding Remarks and Future Prospects</p> <p>References</p> <p>Chapter 19. Developing Semiconductive Catalysts with Three-Dimensional Nanobranches via Solution Routes</p> <p>19.1 Advantages of Morphological Branching-out for Semiconductive Heterogeneous Catalysts from Solution Syntheses</p> <p>19.2 Simple Multi-pods</p> <p>19.3 Nanobranched Multi-pods</p> <p>19.4 From Complex Multi-pods to Koosh Balls</p> <p>19.5 Nanotetrapod in a Hollow Nanotetrapod: the Power of Selective Dissolution</p> <p>19.6 Secondary Nanobranches On 1D Primary Structures</p> <p>19.7 Secondary Nanobranches on 2D and 3D Primary Structures</p> <p>19.8 Tertiary and Quaternary Structures from Hierarchical Nanobranch Growths</p> <p>19.9 Micropatterned Arrays of Tertiary Cactus Structures</p> <p>19.10 3D Self-Assembled Nanobranches</p> <p>19.11 3D Networks of Interconnecting Nanowires</p> <p>19.12 What Next?</p> <p>References</p> <p>Chapter 20. Nanoparticle Catalysis by Surface Plasmon</p> <p>Acknowledgments</p> <p>20.1 Introduction</p> <p>20.2 Plasmon-Driven Surface Catalyzed Reaction</p> <p>20.3 Conclusions</p> <p>References</p> <p>Index</p></div></span></div></div></div></div><div class="_16jmeqbik _16jmeqbkg _16jmeqb1s _16jmeqb18 _16jmeqb0 _16jmeqb70 _16jmeqb1ii"><button class="_16jmeqbwo _16jmeqb17y" aria-expanded="false" aria-controls="product-details-accordion"><div class="_16jmeqbis _16jmeqbko _16jmeqb1s _16jmeqb10 _16jmeqb4 _16jmeqbw"><span class="ou5ptd0 gv4p8b0 _16jmeqb166 _16jmeqb167 _16jmeqbsi _16jmeqbsc _16jmeqb16m" data-text-size="md"><div class="" id="full-product-details">Product details</div></span><svg viewBox="0 0 24 24" class=" nddnvd4 nddnvd5 nddnvd8"><path fill="currentColor" fill-rule="evenodd" d="M12.938 10.875V3.75h-1.876v7.125H3.939v1.875h7.124v7.125h1.876V12.75h7.124v-1.875h-7.125Z" clip-rule="evenodd"></path></svg></div></button><div class="" hidden="" id="product-details-accordion"><div class="_16jmeqbik _16jmeqbkg _16jmeqb1s _16jmeqb18 _16jmeqb0"><div class="gv4p8b0 _16jmeqb166 _16jmeqb167 _16jmeqbsi _16jmeqbsc _16jmeqb16m" data-text-size="md"><div aria-live="polite"><ul class="_1w1hhao0 _1k5vt000 _16jmeqb18 _16jmeqb1s _16jmeqbic _16jmeqbsc"><li class="_1k5vt001"><div class="_16jmeqbi8 _16jmeqbk4 _16jmeqb1s _16jmeqb10 _16jmeqb4"><div class="_16jmeqbs4">No. of pages<!-- -->: <!-- -->512</div></div></li><li class="_1k5vt001"><div class="_16jmeqbi8 _16jmeqbk4 _16jmeqb1s _16jmeqb10 _16jmeqb4"><div class="_16jmeqbs4">Language<!-- -->: <!-- -->English</div></div></li><li class="_1k5vt001"><div class="_16jmeqbi8 _16jmeqbk4 _16jmeqb1s _16jmeqb10 _16jmeqb4"><div class="_16jmeqbs4">Edition<!-- -->: <!-- -->1</div></div></li><li class="_1k5vt001"><div class="_16jmeqbi8 _16jmeqbk4 _16jmeqb1s _16jmeqb10 _16jmeqb4"><div class="_16jmeqbs4">Published<!-- -->: <!-- -->July 13, 2013</div></div></li><li class="_1k5vt001"><div class="_16jmeqbi8 _16jmeqbk4 _16jmeqb1s _16jmeqb10 _16jmeqb4"><div class="_16jmeqbs4">Imprint<!-- -->: <!-- -->Elsevier</div></div></li><li class="_1k5vt001"><div class="_16jmeqbi8 _16jmeqbk4 _16jmeqb1s _16jmeqb10 _16jmeqb4"><div class="_16jmeqbs4">Hardback ISBN<!-- -->: <!-- -->9780444538741</div></div></li><li class="_1k5vt001"><div class="_16jmeqbi8 _16jmeqbk4 _16jmeqb1s _16jmeqb10 _16jmeqb4"><div class="_16jmeqbs4">eBook ISBN<!-- -->: <!-- -->9780444538758</div></div></li></ul></div></div></div></div></div><div class="_16jmeqbik _16jmeqbkg _16jmeqb1s _16jmeqb18 _16jmeqb0 _16jmeqb70 _16jmeqb1ii"><button class="_16jmeqbwo _16jmeqb17y" aria-expanded="false" aria-controls="about-the-editor-accordion"><div class="_16jmeqbis _16jmeqbko _16jmeqb1s _16jmeqb10 _16jmeqb4 _16jmeqbw"><span class="ou5ptd0 gv4p8b0 _16jmeqb166 _16jmeqb167 _16jmeqbsi _16jmeqbsc _16jmeqb16m" data-text-size="md"><div class="" id="about-the-editor">About the editor</div></span><svg viewBox="0 0 24 24" class=" nddnvd4 nddnvd5 nddnvd8"><path fill="currentColor" fill-rule="evenodd" d="M12.938 10.875V3.75h-1.876v7.125H3.939v1.875h7.124v7.125h1.876V12.75h7.124v-1.875h-7.125Z" clip-rule="evenodd"></path></svg></div></button><div class="" hidden="" id="about-the-editor-accordion"><div class="_16jmeqbik _16jmeqbkg _16jmeqb1s _16jmeqb18 _16jmeqb0"><div class="gv4p8b0 _16jmeqb166 _16jmeqb167 _16jmeqbsi _16jmeqbsc _16jmeqb16m" data-text-size="md"><div class="" data-testid="about-the-contributor"><div class="_16jmeqb3c _16jmeqb74" data-testid="contributor"><div class="_1u13v720 _16jmeqbic _16jmeqbk8" style="grid-template-columns:repeat(12, 1fr)"><div class="_16jmeqbn4 _16jmeqbn8 _16jmeqbn9 _16jmeqbq0 _16jmeqbox _16jmeqb1s _16jmeqbk _16jmeqbp"><div class="_1ldxxay0"><p class="gv4p8b0 _16jmeqb166 _16jmeqb167 _16jmeqb1s _16jmeqb8 _16jmeqbo _16jmeqb2c _16jmeqb24">SS</p></div></div><div class="_16jmeqbn4 _16jmeqbn8 _16jmeqbnh _16jmeqbq0 _16jmeqbq1 _16jmeqbgc"><h3 class="m0fuh0 _16jmeqba4 _16jmeqbc4 _16jmeqbew _16jmeqbg4 _16jmeqb15t _16jmeqb15u _16jmeqb167 _16jmeqb176 _16jmeqbsk _16jmeqb16k _16jmeqb164" data-heading-level="3">Steven L Suib</h3><div class="_16jmeqbew"><span><span class="_12fsmvo0 _16jmeqbsc">Steve Suib is one of the leading figures in solid-state catalysis and renewable systems in the US. His 450 publications, 40 patents, and authorship on multiple books on the topic of catalysis is proof of this, as is his distinguished Professor status. He is also editor for Microporous and Mesoporous Materials, which puts him in a perfect position to keep abreast with current developments in the area. <p></p><p>He has been a prominent and prolific catalysis researcher for many years encompassing all aspects of the fields from synthesis, characterization, catalysis, to applications. He easily works in both basic fundamental academic research as well as applied industrial research.</p></span></span></div><div class=""><div class="_16jmeqbsg">Affiliations and expertise</div><span><span class="_12fsmvo0 _16jmeqbsc">Board of Trustees Distinguished Professor, Director, Institute of Materials Science, University of Connecticut, USA</span></span></div></div></div></div></div></div></div></div></div><div class="_16jmeqbik _16jmeqbkg _16jmeqb1s _16jmeqb18 _16jmeqb0 _16jmeqb70 _16jmeqb1ii"><button class="_16jmeqbwo _16jmeqb17y" aria-expanded="false" aria-controls="science-direct-accordion"><div class="_16jmeqbis _16jmeqbko _16jmeqb1s _16jmeqb10 _16jmeqb4 _16jmeqbw"><span class="ou5ptd0 gv4p8b0 _16jmeqb166 _16jmeqb167 _16jmeqbsi _16jmeqbsc _16jmeqb16m" data-text-size="md"><div class="">View book on ScienceDirect</div></span><svg viewBox="0 0 24 24" class=" nddnvd4 nddnvd5 nddnvd8"><path fill="currentColor" fill-rule="evenodd" d="M12.938 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He easily works in both basic fundamental academic research as well as applied industrial research.","affiliation":"Board of Trustees Distinguished Professor, Director, Institute of Materials Science, University of Connecticut, USA","avatarURL":null}],"authors":[]},"keyFeatures":"\u003cul\u003e \u003cli\u003eOffers in-depth coverage of all catalytic topics of current interest and outlines future challenges and research areas\u003c/li\u003e \u003cli\u003eA clear and visual description of all parameters and conditions, enabling the reader to draw conclusions for a particular case\u003c/li\u003e \u003cli\u003eOutlines the catalytic processes applicable to energy generation and design of green processes\u003c/li\u003e\u003c/ul\u003e","readership":"\u003cp\u003eChemists, chemical engineers, and biochemical engineers working in academic and government research; academics, research students, post graduate and graduate students in these areas of study; materials scientists, environmental engineers, biochemists, petroleum engineers, post graduate and research students in these areas\u003c/p\u003e","identifiersAndFormats":[{"isbn":{"formatted":"978-0-444-53874-1","stripped":"9780444538741"},"format":"Hardback"},{"isbn":{"formatted":"978-0-444-53875-8","stripped":"9780444538758"},"format":"eBook"}],"divisionCode":"S\u0026T","tableOfContents":"\u003cp\u003eIntroduction\u003c/p\u003e \u003cp\u003eContributors\u003c/p\u003e \u003cp\u003eChapter 1. Gold-Based Catalysts for CO Oxidation, the Water-Gas Shift, and Desulfurization Processes\u003c/p\u003e \u003cp\u003eAcknowledgments\u003c/p\u003e \u003cp\u003e1.1 Introduction\u003c/p\u003e \u003cp\u003e1.2 Bonding Interactions Between Gold and Metal Oxide or Carbide Surfaces\u003c/p\u003e \u003cp\u003e1.3 Oxidation of Carbon Monoxide on Au-Oxide and Au-Carbide Surfaces\u003c/p\u003e \u003cp\u003e1.4 Water-Gas Shift Reaction on Au-Oxide Surfaces\u003c/p\u003e \u003cp\u003e1.5 Decomposition of Sulfur Dioxide on Au-Oxide and Au-Carbide Surfaces\u003c/p\u003e \u003cp\u003e1.6 Conclusions\u003c/p\u003e \u003cp\u003eReferences\u003c/p\u003e \u003cp\u003eChapter 2. Structural and Electronic Properties of Group 6 Transition Metal Oxide Clusters\u003c/p\u003e \u003cp\u003eAcknowledgments\u003c/p\u003e \u003cp\u003e2.1 Introduction\u003c/p\u003e \u003cp\u003e2.2 Accurate Thermochemistry for Transition Metal Oxide Clusters\u003c/p\u003e \u003cp\u003e2.3 Group 6 Transition Metal Oxides\u003c/p\u003e \u003cp\u003e2.4 Group 6 Transition Metal Hydroxides: Hydrolysis of Metal Oxide Clusters\u003c/p\u003e \u003cp\u003eConclusions\u003c/p\u003e \u003cp\u003eReferences\u003c/p\u003e \u003cp\u003eChapter 3. Nanoparticle Catalysis for Reforming of Biomass-Derived Fuels\u003c/p\u003e \u003cp\u003eAcknowledgment\u003c/p\u003e \u003cp\u003e3.1 Introduction\u003c/p\u003e \u003cp\u003e3.2 Biogas Reforming\u003c/p\u003e \u003cp\u003e3.3 Oxygenates Reforming\u003c/p\u003e \u003cp\u003e3.4 Conclusions\u003c/p\u003e \u003cp\u003eReferences\u003c/p\u003e \u003cp\u003eChapter 4. Nanoparticles in Biocatalysis\u003c/p\u003e \u003cp\u003e4.1 What is Biocatalysis?\u003c/p\u003e \u003cp\u003e4.2 Nanomaterials as Enzyme Supports\u003c/p\u003e \u003cp\u003e4.3 Bionanocatalysis\u003c/p\u003e \u003cp\u003e4.4 Conclusion\u003c/p\u003e \u003cp\u003eReferences\u003c/p\u003e \u003cp\u003eChapter 5. Thin Iron Heme Enzyme Films on Electrodes and Nanoparticles for Biocatalysis\u003c/p\u003e \u003cp\u003eAcknowledgments\u003c/p\u003e \u003cp\u003e5.1 Why Enzyme Biocatalysis on Electrodes and Nanoparticles?\u003c/p\u003e \u003cp\u003e5.2 Cyt P450 Electrocatalysis on Electrodes\u003c/p\u003e \u003cp\u003e5.3 Cyt P450 Biocatalysis on Nanoparticles\u003c/p\u003e \u003cp\u003e5.4 Summary and Prospects for the Future\u003c/p\u003e \u003cp\u003eReferences\u003c/p\u003e \u003cp\u003eChapter 6. Nanoparticles as Enzyme Mimics\u003c/p\u003e \u003cp\u003e6.1 Introduction\u003c/p\u003e \u003cp\u003e6.2 Nanoparticles and Their Properties in Solution, Uptake in Cells, and Clearance\u003c/p\u003e \u003cp\u003e6.3 Chemically Active Nanoparticles\u003c/p\u003e \u003cp\u003e6.4 Other Oxidoreductase Mimics\u0026#8212;Superoxide Dismutases and Oxidases\u003c/p\u003e \u003cp\u003e6.5 Conclusions/Outlook\u003c/p\u003e \u003cp\u003eReferences\u003c/p\u003e \u003cp\u003eChapter 7. A Physical Approach to Monitoring Biological Activity of Nanoparticulates\u003c/p\u003e \u003cp\u003eAcknowledgments\u003c/p\u003e \u003cp\u003e7.1 Fibrous Character of Carbon Nanotubes (CNT)\u003c/p\u003e \u003cp\u003e7.2 Biological Activity of Nano-Sized Particulates of Some Oxides\u003c/p\u003e \u003cp\u003e7.3 \u003ci\u003eIn Vitro\u003c/i\u003e versus \u003ci\u003eIn Vivo\u003c/i\u003e Testing for Biotoxicity of Nanomaterials\u003c/p\u003e \u003cp\u003e7.4 Fundamental Approach to the Problem of Health Hazards Posed by Inhalation of Nanoparticulates of Diverse Chemicals\u003c/p\u003e \u003cp\u003e7.5 Experimental Evidence Forming the Basis of the Proposed Model\u003c/p\u003e \u003cp\u003e7.6 Physico-Chemical Approach to Monitoring Bioactivity\u003c/p\u003e \u003cp\u003e7.7 Thermally Stimulated Luminescence, Conductivity, and Exoelectron Emission [51\u0026#8211;59]\u003c/p\u003e \u003cp\u003e7.8 How Can Emission M\u0026#246;ssbauer Spectroscopy (EMS) Help in Identification and Estimation of Bioactive Defects?\u003c/p\u003e \u003cp\u003e7.9 Remedial Measures: Procedures Adopted for Preparation and Passivation of Defect Sites\u003c/p\u003e \u003cp\u003e7.10 Summary\u003c/p\u003e \u003cp\u003eReferences\u003c/p\u003e \u003cp\u003eChapter 8. Morphology-Tailored Titania Nanoparticles\u003c/p\u003e \u003cp\u003eAcknowledgment\u003c/p\u003e \u003cp\u003e8.1 Introduction\u003c/p\u003e \u003cp\u003e8.2 Ionic Liquids\u003c/p\u003e \u003cp\u003e8.3 Combustion-Assisted Methods\u003c/p\u003e \u003cp\u003e8.4 Gas Flame Combustion\u003c/p\u003e \u003cp\u003e8.5 Sonochemical Methods\u003c/p\u003e \u003cp\u003e8.6 Reverse Microemulsion\u003c/p\u003e \u003cp\u003e8.7 Methods Starting from Metallic Titanium\u003c/p\u003e \u003cp\u003e8.8 Anodization\u003c/p\u003e \u003cp\u003e8.9 Modification of Commercial Titania\u003c/p\u003e \u003cp\u003e8.10 Miscellaneous Methods\u003c/p\u003e \u003cp\u003e8.11 Conclusions\u003c/p\u003e \u003cp\u003eReferences\u003c/p\u003e \u003cp\u003eChapter 9. Metal Oxide Nanotube, Nanorod, and Quantum Dot Photocatalysis\u003c/p\u003e \u003cp\u003eAcknowledgments\u003c/p\u003e \u003cp\u003e9.1 Introduction\u003c/p\u003e \u003cp\u003e9.2 Semiconductor Photocatalysts\u003c/p\u003e \u003cp\u003e9.3 Advantages of Nanoparticles\u003c/p\u003e \u003cp\u003e9.4 Nanoparticle Synthesis\u003c/p\u003e \u003cp\u003e9.5 Doping\u003c/p\u003e \u003cp\u003e9.6 Metal Nanoparticles\u003c/p\u003e \u003cp\u003e9.7 Quantum Dots\u003c/p\u003e \u003cp\u003e9.8 Carbon Heterojunctions\u003c/p\u003e \u003cp\u003e9.9 Water Splitting\u003c/p\u003e \u003cp\u003e9.10 CO\u003csub\u003e2\u003c/sub\u003e Reduction\u003c/p\u003e \u003cp\u003e9.11 Solar Photocatalysis\u003c/p\u003e \u003cp\u003e9.12 Photodynamic Therapy PDT\u003c/p\u003e \u003cp\u003e9.13 Future Directions\u003c/p\u003e \u003cp\u003eReferences\u003c/p\u003e \u003cp\u003eChapter 10. Photocatalytic Nanooxides: The Case of TiO\u003csub\u003e2\u003c/sub\u003e and ZnO\u003c/p\u003e \u003cp\u003eAcknowledgments\u003c/p\u003e \u003cp\u003e10.1 Introduction\u003c/p\u003e \u003cp\u003e10.2 The Case of Bare Oxides\u003c/p\u003e \u003cp\u003e10.3 Doping and Composite Systems Based in Titania and Zinc Oxides\u003c/p\u003e \u003cp\u003eReferences\u003c/p\u003e \u003cp\u003eChapter 11. Recent Advances in Photocatalytic Processes by Nanomaterials\u003c/p\u003e \u003cp\u003eAcknowledgment\u003c/p\u003e \u003cp\u003e11.1 Photocatalysts and Mechanisms of Photocatalysis Processes\u003c/p\u003e \u003cp\u003e11.2 Applications of Photocatalysts\u003c/p\u003e \u003cp\u003e11.3 Challenges and Issues with Possible Solutions in Photocatalytic Processes\u003c/p\u003e \u003cp\u003e11.4 Conclusions\u003c/p\u003e \u003cp\u003eReferences\u003c/p\u003e \u003cp\u003eChapter 12. Insights into Heterogeneous Catalysis through Surface Science Techniques\u003c/p\u003e \u003cp\u003eAcknowledgments\u003c/p\u003e \u003cp\u003e12.1 Introduction\u003c/p\u003e \u003cp\u003e12.2 X-ray Photoelectron Spectroscopy Under Near Ambient Conditions (APXPS)\u003c/p\u003e \u003cp\u003e12.3 Vibrational Spectroscopy at High Pressures\u003c/p\u003e \u003cp\u003e12.3.1 Polarization Modulation Infrared Reflection Absorption Spectroscopy (PM-IRRAS)\u003c/p\u003e \u003cp\u003e12.3.2 Sum Frequency Generation Spectroscopy\u003c/p\u003e \u003cp\u003e12.4 Surface Science Studies Using High Pressure Techniques\u003c/p\u003e \u003cp\u003e12.5 Conclusion and Outlook\u003c/p\u003e \u003cp\u003eReferences\u003c/p\u003e \u003cp\u003eChapter 13. Block Copolymer Lithography\u003c/p\u003e \u003cp\u003e13.1 Introduction\u003c/p\u003e \u003cp\u003e13.2 Introduction to Block copolymers\u003c/p\u003e \u003cp\u003e13.3 Catalysis\u003c/p\u003e \u003cp\u003e13.4 New Frontiers: Plasmonics\u003c/p\u003e \u003cp\u003e13.5 Outlook\u003c/p\u003e \u003cp\u003eReferences\u003c/p\u003e \u003cp\u003eChapter 14. Multi-Metallic Nanoparticles as More Efficient Catalysts for Fuel Cell Reactions\u003c/p\u003e \u003cp\u003e14.1 Introduction\u003c/p\u003e \u003cp\u003e14.2 Multi-Metallic Alloy NPs\u003c/p\u003e \u003cp\u003e14.3 Dumbbell NPs\u003c/p\u003e \u003cp\u003e14.4 Core/Shell NPs\u003c/p\u003e \u003cp\u003e14.5 Conclusions and Perspectives\u003c/p\u003e \u003cp\u003eReferences\u003c/p\u003e \u003cp\u003eChapter 15. Hydrogenation by Nanoparticle Catalysts\u003c/p\u003e \u003cp\u003eAcknowledgment\u003c/p\u003e \u003cp\u003e15.1 Introduction\u003c/p\u003e \u003cp\u003e15.2 Hydrogenation Catalysts\u003c/p\u003e \u003cp\u003e15.3 Hydrogenation by Monometallic Nanoparticles\u003c/p\u003e \u003cp\u003e15.4 Hydrogenation by Bimetallic Nanoparticles\u003c/p\u003e \u003cp\u003e15.5 Hydrogenation by Multimetallic Nanoparticles\u003c/p\u003e \u003cp\u003e15.6 Future Outlook: Nanoparticle-Catalyzed Hydrodeoxygenation\u003c/p\u003e \u003cp\u003e15.7 Summary\u003c/p\u003e \u003cp\u003eReferences\u003c/p\u003e \u003cp\u003eChapter 16. Silicone Stabilized Nanoparticles as Hybrid Phase Catalysts for Selective Hydrolytic Oxidation of Hydrosilanes\u003c/p\u003e \u003cp\u003eAcknowledgments\u003c/p\u003e \u003cp\u003e16.1 Introduction\u003c/p\u003e \u003cp\u003e16.2 What are Silanols?\u003c/p\u003e \u003cp\u003e16.3 Pt-nanoparticle Catalyzed Hydrolytic Oxidation of Organosilanes\u003c/p\u003e \u003cp\u003e16.4 Investigation of the Nature of Catalysts\u003c/p\u003e \u003cp\u003e16.5 Mechanistic Proposal\u003c/p\u003e \u003cp\u003e16.6 Polymerization of Bis-silanols via Dehydrocoupling Reaction\u003c/p\u003e \u003cp\u003e16.7 Conclusion\u003c/p\u003e \u003cp\u003e16.8 Experimental Section\u003c/p\u003e \u003cp\u003e16.8.1 Preparation and Characterization of Functional Silanes (1j-1n and 1p-1s)\u003c/p\u003e \u003cp\u003eReferences\u003c/p\u003e \u003cp\u003eChapter 17. Basics of PEMFC Including the Use of Carbon-Supported Nanoparticles\u003c/p\u003e \u003cp\u003eAcknowledgments\u003c/p\u003e \u003cp\u003e17.1 Introduction\u003c/p\u003e \u003cp\u003e17.2 Basics of PEFMC Operation\u003c/p\u003e \u003cp\u003e17.3 Durability Issues in Fuel Cells\u003c/p\u003e \u003cp\u003e17.4 Beyond Classical Carbon-Supported Pt-Based Nanoparticles\u003c/p\u003e \u003cp\u003e17.5 Conclusion\u003c/p\u003e \u003cp\u003eReferences\u003c/p\u003e \u003cp\u003eChapter 18. Supported Gold Nanoparticles as Heterogeneous Catalysts\u003c/p\u003e \u003cp\u003e18.1 Introduction and Historical Perspective of Recent Gold Catalysis Developments\u003c/p\u003e \u003cp\u003e18.2 Methodologies to Obtain Gold Nanoparticles Supported on Insoluble Solids\u003c/p\u003e \u003cp\u003e18.3 Role of Support\u003c/p\u003e \u003cp\u003e18.4 Role of Metal Oxides in Gold Catalysis\u003c/p\u003e \u003cp\u003e18.5 Gold Nanoparticles as Catalysts in Organic Reactions\u003c/p\u003e \u003cp\u003e18.6 Aerobic Oxidation of Alcohols\u003c/p\u003e \u003cp\u003e18.7 Selective Nitro Group Hydrogenation\u003c/p\u003e \u003cp\u003e18.8 Concluding Remarks and Future Prospects\u003c/p\u003e \u003cp\u003eReferences\u003c/p\u003e \u003cp\u003eChapter 19. Developing Semiconductive Catalysts with Three-Dimensional Nanobranches via Solution Routes\u003c/p\u003e \u003cp\u003e19.1 Advantages of Morphological Branching-out for Semiconductive Heterogeneous Catalysts from Solution Syntheses\u003c/p\u003e \u003cp\u003e19.2 Simple Multi-pods\u003c/p\u003e \u003cp\u003e19.3 Nanobranched Multi-pods\u003c/p\u003e \u003cp\u003e19.4 From Complex Multi-pods to Koosh Balls\u003c/p\u003e \u003cp\u003e19.5 Nanotetrapod in a Hollow Nanotetrapod: the Power of Selective Dissolution\u003c/p\u003e \u003cp\u003e19.6 Secondary Nanobranches On 1D Primary Structures\u003c/p\u003e \u003cp\u003e19.7 Secondary Nanobranches on 2D and 3D Primary Structures\u003c/p\u003e \u003cp\u003e19.8 Tertiary and Quaternary Structures from Hierarchical Nanobranch Growths\u003c/p\u003e \u003cp\u003e19.9 Micropatterned Arrays of Tertiary Cactus Structures\u003c/p\u003e \u003cp\u003e19.10 3D Self-Assembled Nanobranches\u003c/p\u003e \u003cp\u003e19.11 3D Networks of Interconnecting Nanowires\u003c/p\u003e \u003cp\u003e19.12 What Next?\u003c/p\u003e \u003cp\u003eReferences\u003c/p\u003e \u003cp\u003eChapter 20. Nanoparticle Catalysis by Surface Plasmon\u003c/p\u003e \u003cp\u003eAcknowledgments\u003c/p\u003e \u003cp\u003e20.1 Introduction\u003c/p\u003e \u003cp\u003e20.2 Plasmon-Driven Surface Catalyzed Reaction\u003c/p\u003e \u003cp\u003e20.3 Conclusions\u003c/p\u003e \u003cp\u003eReferences\u003c/p\u003e \u003cp\u003eIndex\u003c/p\u003e","identifier":{"formatted":"978-0-444-53874-1","stripped":"9780444538741"},"regionalHealthStoreURL":null,"companionSiteURL":null,"textbookSupportURL":null,"scienceDirectURL":"https://www.sciencedirect.com/science/book/9780444538741","productDetailPageURL":"https://shop.elsevier.com/books/new-and-future-developments-in-catalysis/suib/978-0-444-53874-1","volume":null,"subjects":["physical-sciences-and-engineering","physical-sciences-and-engineering/chemical-engineering","physical-sciences-and-engineering/chemical-engineering/catalysis","physical-sciences-and-engineering/chemical-engineering/catalysis/catalysis","physical-sciences-and-engineering/chemical-engineering/chemical-engineering-general","physical-sciences-and-engineering/chemical-engineering/chemical-engineering-general/chemical-engineering"]},"bookBanners":[{"__typename":"Banner","title":"Save 50% on book bundles","image":{"src":"https://images.ctfassets.net/ahaoy9whsr8a/3hh8459sY2nXIBbSiKJFQm/ed36678e72516d39f8a78ab741be67ec/book-promo-banner3.png","alt":"Image of books","width":400,"height":400},"subTitle":"Immediately download your ebook while waiting for your print delivery. 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