A comprehensive review on the analytical method, occurrence, transformation and toxicity of a reactive pollutant: BADGE

<!DOCTYPE html> <html> <head> <title>A comprehensive review on the analytical method, occurrence, transformation and toxicity of a reactive pollutant: BADGE | NTU Singapore</title> <meta http-equiv="Content-Type" content="text/html; charset=UTF-8" /> <meta http-equiv="X-UA-Compatible" content="IE=edge"/> <meta name="Generator" content="DSpace CRIS-6.3.0-SNAPSHOT" /> <meta name="viewport" content="width=device-width, initial-scale=1.0"> <link rel="resourcesync sitemap" href="https://dr.ntu.edu.sg/rs/resourcesync.xml" type="application/xml"/> <link rel="shortcut icon" href="/favicon.ico" type="image/x-icon"/> <link rel="stylesheet" href="/static/css/jquery-ui/redmond/jquery-ui-1.13.1.css" type="text/css" /> <link href="/css/researcher.css" type="text/css" rel="stylesheet" /> <link href="/css/jdyna.css" type="text/css" rel="stylesheet" /> <link rel="stylesheet" href="/static/css/bootstrap/bootstrap.min.css" type="text/css" /> <link rel="stylesheet" href="/static/css/bootstrap/bootstrap-theme.css" type="text/css" /> <link href="/static/css/font-awesome/css/font-awesome.min.css" rel="stylesheet"> <link href="/static/css/jstree/themes/default/style.min.css" rel="stylesheet"/> <link rel="stylesheet" href="/static/css/bootstrap/dspace-theme.css" type="text/css" /> <link rel="stylesheet" href="/css/orcid.css" type="text/css" /> <link rel="stylesheet" type="text/css" href="/static/css/dataTables.bootstrap.min.css"/> <link rel="stylesheet" type="text/css" href="/static/css/buttons.bootstrap.min.css"/> <link rel="stylesheet" type="text/css" href="/static/css/responsive.bootstrap.min.css"/> <link rel="stylesheet" type="text/css" href="/css/bootstrap-datetimepicker.min.css" /> <link rel="stylesheet" type="text/css" href="/static/css/select.dataTables.min.css" /> <link rel="search" type="application/opensearchdescription+xml" href="/open-search/description.xml" title="DSpace"/> <link rel="schema.DCTERMS" href="http://purl.org/dc/terms/" /> <link rel="schema.DC" href="http://purl.org/dc/elements/1.1/" /> <meta name="DC.creator" content="Wang, Dongqi" xml:lang="en_US" /> <meta name="DC.creator" content="Zhao, Haoduo" xml:lang="en_US" /> <meta name="DC.creator" content="Fei, Xunchang" xml:lang="en_US" /> <meta name="DC.creator" content="Synder, Shane Allen" xml:lang="en_US" /> <meta name="DC.creator" content="Fang, Mingliang" xml:lang="en_US" /> <meta name="DC.creator" content="Liu, Min" xml:lang="en_US" /> <meta name="DCTERMS.dateAccepted" content="2022-09-02T07:59:29Z" scheme="DCTERMS.W3CDTF" /> <meta name="DCTERMS.available" content="2022-09-02T07:59:29Z" scheme="DCTERMS.W3CDTF" /> <meta name="DCTERMS.issued" content="2021" scheme="DCTERMS.W3CDTF" /> <meta name="DCTERMS.bibliographicCitation" content="Wang, D., Zhao, H., Fei, X., Synder, S. A., Fang, M. & Liu, M. (2021). A comprehensive review on the analytical method, occurrence, transformation and toxicity of a reactive pollutant: BADGE. Environment International, 155, 106701-. https://dx.doi.org/10.1016/j.envint.2021.106701" xml:lang="en_US" /> <meta name="DC.identifier" content="0160-4120" xml:lang="en_US" /> <meta name="DC.identifier" content="https://hdl.handle.net/10356/161451" scheme="DCTERMS.URI" /> <meta name="DCTERMS.abstract" content="Bisphenol A diglycidyl ether (BADGE)-based epoxy resin is one of the most widely used epoxy resins with an annual production amount of several million tons. Compared with all other legacy or emerging organic compounds, BADGE is special due to its toxicity and high reactivity in the environment. More and more studies are available on its analytical methods, occurrence, transformation and toxicity. Here, we provided a comprehensive review of the current BADGE-related studies, with focus on its production, application, available analytical methods, occurrences in the environment and human specimen, abiotic and biotic transformation, as well as the in vitro and in vivo toxicities. The available data show that BADGE and its derivatives are ubiquitous environmental chemicals and often well detected in human specimens. For their analysis, a water-free sample pretreatment should be considered to avoid hydrolysis. Additionally, their complex reactions with endogenous metabolites are areas of great interest. To date, the monitoring and further understanding of their transport and fate in the environment are still quite lacking, comparing with its analogues bisphenol A (BPA) and bisphenol S (BPS). In terms of toxicity, the summary of its current studies and Environmental Protection Agency (EPA) ToxCast toxicity database suggests BADGE might be an endocrine disruptor, though more detailed evidence is still needed to confirm this hypothesis in in vivo animal models. Future study of BADGE should focus on its metabolic transformation, reaction with protein and validation of its role as an endocrine disruptor. We believe that the elucidation of BADGEs can greatly enhance our understandings of those reactive compounds in the environment and human." xml:lang="en_US" /> <meta name="DC.description" content="National Environmental Agency (NEA)" xml:lang="en_US" /> <meta name="DC.language" content="en" xml:lang="en_US" scheme="DCTERMS.RFC1766" /> <meta name="DC.relation" content="04SBS000714N025" xml:lang="en_US" /> <meta name="DCTERMS.isPartOf" content="Environment International" xml:lang="en_US" /> <meta name="DC.rights" content="© 2021 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/)." xml:lang="en_US" /> <meta name="DC.subject" content="Engineering::Civil engineering" xml:lang="en_US" /> <meta name="DC.title" content="A comprehensive review on the analytical method, occurrence, transformation and toxicity of a reactive pollutant: BADGE" xml:lang="en_US" /> <meta name="DC.type" content="Journal Article" xml:lang="en" /> <meta name="DC.contributor" content="School of Civil and Environmental Engineering" xml:lang="en_US" /> <meta name="DC.contributor" content="Nanyang Environment and Water Research Institute" xml:lang="en_US" /> <meta name="DC.identifier" content="10.1016/j.envint.2021.106701" /> <meta name="DC.description" content="Published version" xml:lang="en_US" /> <meta name="DC.identifier" content="34146765" /> <meta name="DC.identifier" content="2-s2.0-85108018100" /> <meta name="DC.identifier" content="155" xml:lang="en_US" /> <meta 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record</a> </li> <li class="nav-item"> <a class="nav-link" href="/handle/10356/161451?mode=full">Show full item record</a> </li> <li class="nav-item"> <a class="nav-link" href="/handle/10356/161451?mode=export" >Export item record </a> </li> </ul> <div class="row"> <div class="col-sm-12 col-md-12 col-lg-12"> <div class="well">Please use this identifier to cite or link to this item: <code>https://hdl.handle.net/10356/161451</code></div> </div> </div> <div class="row"> <div id="wrapperDisplayItem" class="col-lg-12"> <div class="col-lg-9"> <table class="table itemDisplayTable"> <td class="metadataFieldLabel">Title: </td><td class="metadataFieldValue">A comprehensive review on the analytical method, occurrence, transformation and toxicity of a reactive pollutant: BADGE</td></tr> <td class="metadataFieldLabel">Authors: </td><td class="metadataFieldValue"><a href="/browse?type=publicationauthor&value=Wang%2C+Dongqi&value_lang=en_US">Wang, Dongqi</a><br /><a href="/browse?type=publicationauthor&value=Zhao%2C+Haoduo&value_lang=en_US">Zhao, Haoduo</a><br /><a href="/browse?type=publicationauthor&value=Fei%2C+Xunchang&value_lang=en_US">Fei, Xunchang</a><br /><a href="/browse?type=publicationauthor&value=Synder%2C+Shane+Allen&value_lang=en_US">Synder, Shane Allen</a><br /><a href="/browse?type=publicationauthor&value=Fang%2C+Mingliang&value_lang=en_US">Fang, Mingliang</a><br /><a href="/browse?type=publicationauthor&value=Liu%2C+Min&value_lang=en_US">Liu, Min</a></td></tr> <td class="metadataFieldLabel">Keywords: </td><td class="metadataFieldValue"><a href="/browse?type=subject&value=Engineering%3A%3ACivil+engineering&value_lang=en_US">Engineering::Civil engineering</a></td></tr> <td class="metadataFieldLabel">Issue Date: </td><td class="metadataFieldValue">2021</td></tr> <td class="metadataFieldLabel">Source: </td><td class="metadataFieldValue">Wang,  D., Zhao,  H., Fei,  X., Synder,  S. A., Fang,  M. & Liu,  M. (2021). A comprehensive review on the analytical method, occurrence, transformation and toxicity of a reactive pollutant: BADGE. Environment International, 155, 106701-. https://dx.doi.org/10.1016/j.envint.2021.106701</td></tr> <td class="metadataFieldLabel">Project: </td><td class="metadataFieldValue"><a href="/browse?type=fypgrantid&authority=pj00480&authority_lang=en_US" class="authority fypgrantid">04SBS000714N025</a> <a href="/cris/project/pj00480" class="authority"><span class="fa fa-info"></span> </a></td></tr> <td class="metadataFieldLabel">Journal: </td><td class="metadataFieldValue">Environment International <a href="/cris/journals/journals00453" class="authority"><span class="fa fa-info"></span></a></td></tr> <td class="metadataFieldLabel">Abstract: </td><td class="metadataFieldValue">Bisphenol A diglycidyl ether (BADGE)-based epoxy resin is one of the most widely used epoxy resins with an annual production amount of several million tons. Compared with all other legacy or emerging organic compounds, BADGE is special due to its toxicity and high reactivity in the environment. More and more studies are available on its analytical methods, occurrence, transformation and toxicity. Here, we provided a comprehensive review of the current BADGE-related studies, with focus on its production, application, available analytical methods, occurrences in the environment and human specimen, abiotic and biotic transformation, as well as the in vitro and in vivo toxicities. The available data show that BADGE and its derivatives are ubiquitous environmental chemicals and often well detected in human specimens. For their analysis, a water-free sample pretreatment should be considered to avoid hydrolysis. Additionally, their complex reactions with endogenous metabolites are areas of great interest. To date, the monitoring and further understanding of their transport and fate in the environment are still quite lacking, comparing with its analogues bisphenol A (BPA) and bisphenol S (BPS). In terms of toxicity, the summary of its current studies and Environmental Protection Agency (EPA) ToxCast toxicity database suggests BADGE might be an endocrine disruptor, though more detailed evidence is still needed to confirm this hypothesis in in vivo animal models. Future study of BADGE should focus on its metabolic transformation, reaction with protein and validation of its role as an endocrine disruptor. We believe that the elucidation of BADGEs can greatly enhance our understandings of those reactive compounds in the environment and human.</td></tr> <td class="metadataFieldLabel">URI: </td><td class="metadataFieldValue"><a href="https://hdl.handle.net/10356/161451">https://hdl.handle.net/10356/161451</a></td></tr> <td class="metadataFieldLabel">ISSN: </td><td class="metadataFieldValue">0160-4120</td></tr> <td class="metadataFieldLabel">DOI: </td><td class="metadataFieldValue"><a href="https://doi.org/10.1016%2Fj.envint.2021.106701">10.1016/j.envint.2021.106701</a></td></tr> <td class="metadataFieldLabel">Schools: </td><td class="metadataFieldValue"><a href="/browse?type=dspaceitemschool&authority=ou00011&authority_lang=en_US" class="authority dspaceitemschool">School of Civil and Environmental Engineering</a> <a href="/cris/ou/ou00011" class="authority"><span class="fa fa-university"></span></a></td></tr> <td class="metadataFieldLabel">Research Centres: </td><td class="metadataFieldValue"><a href="/browse?type=dspaceitemresearch&authority=ou00019&authority_lang=en_US" class="authority dspaceitemresearch">Nanyang Environment and Water Research Institute</a> <a href="/cris/ou/ou00019" class="authority"><span class="fa fa-university"></span></a></td></tr> <td class="metadataFieldLabel">Rights: </td><td class="metadataFieldValue">© 2021 The Authors. 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