Alumina Supported Copper-manganese Catalysts for Combustion of Exhaust Gases: Catalysts Characterization

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Copper-manganese Catalysts for Combustion of Exhaust Gases: Catalysts Characterization</title> <meta name="description" content="Alumina Supported Copper-manganese Catalysts for Combustion of Exhaust Gases: Catalysts Characterization"> <meta name="keywords" content="supported copper-manganese catalysts, CO, VOCs oxidation, combustion of exhaust gases"> <meta name="viewport" content="width=device-width, initial-scale=1, minimum-scale=1, maximum-scale=1, user-scalable=no"> <meta charset="utf-8"> <link href="https://cdn.waset.org/favicon.ico" type="image/x-icon" rel="shortcut icon"> <link href="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/css/bootstrap.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/plugins/fontawesome/css/all.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/css/site.css?v=150220211555" rel="stylesheet"> </head> <body> <header> <div class="container"> <nav class="navbar navbar-expand-lg navbar-light"> <a class="navbar-brand" 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</div> <div class="card publication-listing mt-3 mb-3"> <h5 class="card-header" style="font-size:.9rem">Alumina Supported Copper-manganese Catalysts for Combustion of Exhaust Gases: Catalysts Characterization</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Krasimir%20I.%20Ivanov">Krasimir I. Ivanov</a>, <a href="https://publications.waset.org/abstracts/search?q=Elitsa%20N.%20Kolentsova"> Elitsa N. Kolentsova</a>, <a href="https://publications.waset.org/abstracts/search?q=Dimitar%20Y.%20Dimitrov"> Dimitar Y. Dimitrov</a>, <a href="https://publications.waset.org/abstracts/search?q=Georgi%20V.%20Avdeev"> Georgi V. Avdeev</a>, <a href="https://publications.waset.org/abstracts/search?q=Tatyana%20T.%20Tabakova"> Tatyana T. Tabakova</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In recent research copper and manganese systems were found to be the most active in CO and organic compounds oxidation among the base catalysts. The mixed copper manganese oxide has been widely studied in oxidation reactions because of their higher activity at low temperatures in comparison with single oxide catalysts. The results showed that the formation of spinel CuxMn3鈭抶O4 in the oxidized catalyst is responsible for the activity even at room temperature. That is why most of the investigations are focused on the hopcalite catalyst (CuMn2O4) as the best copper-manganese catalyst. Now it鈥檚 known that this is true only for CO oxidation, but not for mixture of CO and VOCs. The purpose of this study is to investigate the alumina supported copper-manganese catalysts with different Cu/Mn molar ratio in terms of oxidation of CO, methanol and dimethyl ether. The catalysts were prepared by impregnation of 纬-Al2O3 with copper and manganese nitrates and the catalytic activity measurements were carried out in continuous flow equipment with a four-channel isothermal stainless steel reactor. Gas mixtures on the input and output of the reactor were analyzed with a gas chromatograph, equipped with FID and TCD detectors. The texture characteristics were determined by low-temperature (- 196 o小) nitrogen adsorption in a Quantachrome Instruments NOVA 1200e (USA) specific surface area&pore analyzer. Thermal, XRD and TPR analyses were performed. It was established that the active component of the mixed Cu-Mn/纬鈥揳lumina catalysts strongly depends on the Cu/Mn molar ratio. Highly active alumina supported Cu-Mn catalysts for CO, methanol and DME oxidation were synthesized. While the hopcalite is the best catalyst for CO oxidation, the best compromise for simultaneous oxidation of all components is the catalyst with Cu/Mn molar ratio 1:5. <iframe src="https://publications.waset.org/abstracts/23639.pdf" style="width:100%; height:400px;" frameborder="0"></iframe> <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=supported%20copper-manganese%20catalysts" title="supported copper-manganese catalysts">supported copper-manganese catalysts</a>, <a href="https://publications.waset.org/abstracts/search?q=CO" title=" CO"> CO</a>, <a href="https://publications.waset.org/abstracts/search?q=VOCs%20oxidation" title=" VOCs oxidation"> VOCs oxidation</a>, <a href="https://publications.waset.org/abstracts/search?q=combustion%20of%20exhaust%20gases" title=" combustion of exhaust gases"> combustion of exhaust gases</a> </p> <a 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Alumina Supported Copper-manganese Catalysts for Combustion of Exhaust Gases: Catalysts Characterization