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overflow: hidden; text-overflow: ellipsis; -webkit-line-clamp: 3; -webkit-box-orient: vertical; }</style><div class="col-xs-12 clearfix"><div class="u-floatLeft"><h1 class="PageHeader-title u-m0x u-fs30">Ionic Liquids</h1><div class="u-tcGrayDark">12,528 Followers</div><div class="u-tcGrayDark u-mt2x">Recent papers in <b>Ionic Liquids</b></div></div></div></div></div></div><div class="TabbedNavigation"><div class="container"><div class="row"><div class="col-xs-12 clearfix"><ul class="nav u-m0x u-p0x list-inline u-displayFlex"><li class="active"><a href="https://www.academia.edu/Documents/in/Ionic_Liquids">Top Papers</a></li><li><a href="https://www.academia.edu/Documents/in/Ionic_Liquids/MostCited">Most Cited Papers</a></li><li><a href="https://www.academia.edu/Documents/in/Ionic_Liquids/MostDownloaded">Most Downloaded Papers</a></li><li><a href="https://www.academia.edu/Documents/in/Ionic_Liquids/MostRecent">Newest Papers</a></li><li><a class="" href="https://www.academia.edu/People/Ionic_Liquids">People</a></li></ul></div><style type="text/css">ul.nav{flex-direction:row}@media(max-width: 567px){ul.nav{flex-direction:column}.TabbedNavigation li{max-width:100%}.TabbedNavigation li.active{background-color:var(--background-grey, #dddde2)}.TabbedNavigation li.active:before,.TabbedNavigation li.active:after{display:none}}</style></div></div></div><div class="container"><div class="row"><div class="col-xs-12"><div class="u-displayFlex"><div class="u-flexGrow1"><div class="works"><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_40120822" data-work_id="40120822" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/40120822/Ionic_liquids_Promising_Green_Solvents_for_Lignocellulosic_Biomass_Utilization">Ionic liquids: Promising Green Solvents for Lignocellulosic Biomass Utilization</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Ionic liquids are effective solvents/media for the utilization of lignocellulosic biomass. The unique properties of ionic liquids enable them to effectively dissolve and/or convert the biomass into various types of products. This review... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_40120822" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Ionic liquids are effective solvents/media for the utilization of lignocellulosic biomass. The unique properties of ionic liquids enable them to effectively dissolve and/or convert the biomass into various types of products. This review aims to cover the latest progress achieved in applications of ionic liquids on biomass conversion and analysis.<br />Specifically, several recently developed approaches on how to overcome current challenges on the use of ionic liquids in the biomass conversion were highlighted. Recent studies addressing the potential applications of ionic liquids for the production of novel biomass-derived chemicals and materials were also discussed.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/40120822" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="fc5d334172f858f65aada032818be512" rel="nofollow" data-download="{"attachment_id":60334242,"asset_id":40120822,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/60334242/download_file?st=MTczMzA4NDk3OSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="41042877" href="https://utk.academia.edu/ArtRagauskas">Art Ragauskas</a><script data-card-contents-for-user="41042877" type="text/json">{"id":41042877,"first_name":"Art","last_name":"Ragauskas","domain_name":"utk","page_name":"ArtRagauskas","display_name":"Art Ragauskas","profile_url":"https://utk.academia.edu/ArtRagauskas?f_ri=33003","photo":"https://0.academia-photos.com/41042877/13634410/14781351/s65_art.ragauskas.jpg"}</script></span></span></li><li class="js-paper-rank-work_40120822 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="40120822"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 40120822, container: ".js-paper-rank-work_40120822", }); 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$(".js-view-count[data-work-id=40120822]").text(description); $(".js-view-count-work_40120822").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_40120822").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="40120822"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">4</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="33003" href="https://www.academia.edu/Documents/in/Ionic_Liquids">Ionic Liquids</a>, <script data-card-contents-for-ri="33003" type="text/json">{"id":33003,"name":"Ionic Liquids","url":"https://www.academia.edu/Documents/in/Ionic_Liquids?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="54182" href="https://www.academia.edu/Documents/in/Biofuels">Biofuels</a>, <script data-card-contents-for-ri="54182" type="text/json">{"id":54182,"name":"Biofuels","url":"https://www.academia.edu/Documents/in/Biofuels?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="555745" href="https://www.academia.edu/Documents/in/Recalcitrance">Recalcitrance</a>, <script data-card-contents-for-ri="555745" type="text/json">{"id":555745,"name":"Recalcitrance","url":"https://www.academia.edu/Documents/in/Recalcitrance?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="998970" href="https://www.academia.edu/Documents/in/Pretreatment">Pretreatment</a><script data-card-contents-for-ri="998970" type="text/json">{"id":998970,"name":"Pretreatment","url":"https://www.academia.edu/Documents/in/Pretreatment?f_ri=33003","nofollow":false}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=40120822]'), work: {"id":40120822,"title":"Ionic liquids: Promising Green Solvents for Lignocellulosic Biomass Utilization","created_at":"2019-08-19T09:17:51.467-07:00","url":"https://www.academia.edu/40120822/Ionic_liquids_Promising_Green_Solvents_for_Lignocellulosic_Biomass_Utilization?f_ri=33003","dom_id":"work_40120822","summary":"Ionic liquids are effective solvents/media for the utilization of lignocellulosic biomass. The unique properties of ionic liquids enable them to effectively dissolve and/or convert the biomass into various types of products. This review aims to cover the latest progress achieved in applications of ionic liquids on biomass conversion and analysis.\nSpecifically, several recently developed approaches on how to overcome current challenges on the use of ionic liquids in the biomass conversion were highlighted. Recent studies addressing the potential applications of ionic liquids for the production of novel biomass-derived chemicals and materials were also discussed.","downloadable_attachments":[{"id":60334242,"asset_id":40120822,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":41042877,"first_name":"Art","last_name":"Ragauskas","domain_name":"utk","page_name":"ArtRagauskas","display_name":"Art Ragauskas","profile_url":"https://utk.academia.edu/ArtRagauskas?f_ri=33003","photo":"https://0.academia-photos.com/41042877/13634410/14781351/s65_art.ragauskas.jpg"}],"research_interests":[{"id":33003,"name":"Ionic Liquids","url":"https://www.academia.edu/Documents/in/Ionic_Liquids?f_ri=33003","nofollow":false},{"id":54182,"name":"Biofuels","url":"https://www.academia.edu/Documents/in/Biofuels?f_ri=33003","nofollow":false},{"id":555745,"name":"Recalcitrance","url":"https://www.academia.edu/Documents/in/Recalcitrance?f_ri=33003","nofollow":false},{"id":998970,"name":"Pretreatment","url":"https://www.academia.edu/Documents/in/Pretreatment?f_ri=33003","nofollow":false}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_40051514" data-work_id="40051514" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/40051514/CO_2_absorption_and_ion_mobility_in_aqueous_choline_based_ionic_liquids">CO 2 absorption and ion mobility in aqueous choline-based ionic liquids</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">CO 2 absorption and ion mobility are investigated in a series of 50/50 wt% aqueous solutions of choline-based ionic liquids with different cations and anions: [N 1,1,4,2OH ][Threo], [N 1,1,5,2OH ][Threo], [N 1,1,6,2OH ][Threo], [N... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_40051514" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">CO 2 absorption and ion mobility are investigated in a series of 50/50 wt% aqueous solutions of choline-based ionic liquids with different cations and anions: [N 1,1,4,2OH ][Threo], [N 1,1,5,2OH ][Threo], [N 1,1,6,2OH ][Threo], [N 1,1,5,2OH ][β-ala] and [N 1,1,5,2OH ][Tau]. The process of CO 2 absorption was completed in an hour reaching maximum of absorption capacity 0.07-0.10 wt% to ionic liquid (by 0.4-0.6 molar ratios). A rapid CO 2 absorption is observed by the formation of solid product as a result of reaction between CO 2 molecule and the ionic liquid. Diffusion coefficients of the cation and anion in the mixture are comparable while the diffusivity of water molecules is found to be quite different from the ions. In the process of CO 2 absorption, an increase in the diffusivity of ions is observed due to the precipitation of solid products and depletion of ions contents in the liquid phase of the system. 13 C NMR measurements of diffusivity of CO 2 enriched with 13 C isotope showed that a part of the absorbed CO 2 remained in the liquid phase being physically and chemically bound to ions. The ionic liquid is recycled by evaporating water and releasing CO 2 molecules using vacuum and temperature.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/40051514" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="152749dbc33d78a7d6ab5ff9a7a5ccda" rel="nofollow" data-download="{"attachment_id":60251205,"asset_id":40051514,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/60251205/download_file?st=MTczMzA4NDk3OSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="658981" href="https://ri-se.academia.edu/ShubhankarBhattacharyya">Shubhankar Bhattacharyya</a><script data-card-contents-for-user="658981" type="text/json">{"id":658981,"first_name":"Shubhankar","last_name":"Bhattacharyya","domain_name":"ri-se","page_name":"ShubhankarBhattacharyya","display_name":"Shubhankar Bhattacharyya","profile_url":"https://ri-se.academia.edu/ShubhankarBhattacharyya?f_ri=33003","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_40051514 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="40051514"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 40051514, container: ".js-paper-rank-work_40051514", }); 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$(".js-view-count[data-work-id=40051514]").text(description); $(".js-view-count-work_40051514").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_40051514").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="40051514"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">5</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="33003" href="https://www.academia.edu/Documents/in/Ionic_Liquids">Ionic Liquids</a>, <script data-card-contents-for-ri="33003" type="text/json">{"id":33003,"name":"Ionic Liquids","url":"https://www.academia.edu/Documents/in/Ionic_Liquids?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="43832" href="https://www.academia.edu/Documents/in/CO2_capture_and_storage">CO2 capture and storage</a>, <script data-card-contents-for-ri="43832" type="text/json">{"id":43832,"name":"CO2 capture and storage","url":"https://www.academia.edu/Documents/in/CO2_capture_and_storage?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="244590" href="https://www.academia.edu/Documents/in/NMR_Diffusion">NMR Diffusion</a>, <script data-card-contents-for-ri="244590" type="text/json">{"id":244590,"name":"NMR Diffusion","url":"https://www.academia.edu/Documents/in/NMR_Diffusion?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="295928" href="https://www.academia.edu/Documents/in/Amino_Acids">Amino Acids</a><script data-card-contents-for-ri="295928" type="text/json">{"id":295928,"name":"Amino Acids","url":"https://www.academia.edu/Documents/in/Amino_Acids?f_ri=33003","nofollow":false}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=40051514]'), work: {"id":40051514,"title":"CO 2 absorption and ion mobility in aqueous choline-based ionic liquids","created_at":"2019-08-09T23:34:37.388-07:00","url":"https://www.academia.edu/40051514/CO_2_absorption_and_ion_mobility_in_aqueous_choline_based_ionic_liquids?f_ri=33003","dom_id":"work_40051514","summary":"CO 2 absorption and ion mobility are investigated in a series of 50/50 wt% aqueous solutions of choline-based ionic liquids with different cations and anions: [N 1,1,4,2OH ][Threo], [N 1,1,5,2OH ][Threo], [N 1,1,6,2OH ][Threo], [N 1,1,5,2OH ][β-ala] and [N 1,1,5,2OH ][Tau]. The process of CO 2 absorption was completed in an hour reaching maximum of absorption capacity 0.07-0.10 wt% to ionic liquid (by 0.4-0.6 molar ratios). A rapid CO 2 absorption is observed by the formation of solid product as a result of reaction between CO 2 molecule and the ionic liquid. Diffusion coefficients of the cation and anion in the mixture are comparable while the diffusivity of water molecules is found to be quite different from the ions. In the process of CO 2 absorption, an increase in the diffusivity of ions is observed due to the precipitation of solid products and depletion of ions contents in the liquid phase of the system. 13 C NMR measurements of diffusivity of CO 2 enriched with 13 C isotope showed that a part of the absorbed CO 2 remained in the liquid phase being physically and chemically bound to ions. The ionic liquid is recycled by evaporating water and releasing CO 2 molecules using vacuum and temperature.","downloadable_attachments":[{"id":60251205,"asset_id":40051514,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":658981,"first_name":"Shubhankar","last_name":"Bhattacharyya","domain_name":"ri-se","page_name":"ShubhankarBhattacharyya","display_name":"Shubhankar Bhattacharyya","profile_url":"https://ri-se.academia.edu/ShubhankarBhattacharyya?f_ri=33003","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":33003,"name":"Ionic Liquids","url":"https://www.academia.edu/Documents/in/Ionic_Liquids?f_ri=33003","nofollow":false},{"id":43832,"name":"CO2 capture and storage","url":"https://www.academia.edu/Documents/in/CO2_capture_and_storage?f_ri=33003","nofollow":false},{"id":244590,"name":"NMR Diffusion","url":"https://www.academia.edu/Documents/in/NMR_Diffusion?f_ri=33003","nofollow":false},{"id":295928,"name":"Amino Acids","url":"https://www.academia.edu/Documents/in/Amino_Acids?f_ri=33003","nofollow":false},{"id":990296,"name":"Choline","url":"https://www.academia.edu/Documents/in/Choline?f_ri=33003"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_39368508" data-work_id="39368508" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/39368508/Reactivity_of_1_2_cyclic_sulfite_xylosides_towards_nucleophiles">Reactivity of 1,2-cyclic sulfite xylosides towards nucleophiles</a></div></div><div class="u-pb4x u-mt3x"></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/39368508" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="b9029c3333f49fb4f387c9596fd5d09c" rel="nofollow" data-download="{"attachment_id":59511450,"asset_id":39368508,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/59511450/download_file?st=MTczMzA4NDk3OSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="18246939" href="https://southalabama.academia.edu/mariemigaud">marie migaud</a><script data-card-contents-for-user="18246939" type="text/json">{"id":18246939,"first_name":"marie","last_name":"migaud","domain_name":"southalabama","page_name":"mariemigaud","display_name":"marie migaud","profile_url":"https://southalabama.academia.edu/mariemigaud?f_ri=33003","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_39368508 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="39368508"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 39368508, container: ".js-paper-rank-work_39368508", }); 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Unusual partitioning and diffusion effects of Fe(CN)64−/3− in droplet and thin layer deposits of 1-methyl-3-(2,6-(S)-dimethylocten-2-yl)-imidazolium tetrafluoroborate</a></div></div><div class="u-pb4x u-mt3x"></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/38992632" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="21d06285f9c7ee326bbd6dc0a50e083c" rel="nofollow" data-download="{"attachment_id":59099578,"asset_id":38992632,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/59099578/download_file?st=MTczMzA4NDk3OSw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="5430397" href="https://independent.academia.edu/JairtonDupont">Jairton Dupont</a><script data-card-contents-for-user="5430397" type="text/json">{"id":5430397,"first_name":"Jairton","last_name":"Dupont","domain_name":"independent","page_name":"JairtonDupont","display_name":"Jairton Dupont","profile_url":"https://independent.academia.edu/JairtonDupont?f_ri=33003","photo":"https://0.academia-photos.com/5430397/2385808/2778147/s65_jairton.dupont.jpg"}</script></span></span></li><li class="js-paper-rank-work_38992632 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="38992632"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 38992632, container: ".js-paper-rank-work_38992632", }); 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href="https://www.academia.edu/33339629/Reaction_Rates_as_a_Function_of_Scale_within_Ionic_Liquids_Microscale_in_Droplet_Microreactors_versus_Macroscale_Reactions_in_the_Case_of_the_Grieco_Three_Component_Condensation_Reaction">Reaction Rates as a Function of Scale within Ionic Liquids: Microscale in Droplet Microreactors versus Macroscale Reactions in the Case of the Grieco Three-Component Condensation Reaction</a></div></div><div class="u-pb4x u-mt3x"></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/33339629" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="4d0d39d14ad6da4911fc2178a290d48b" 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type="text/json">{"id":4987,"name":"Kinetics","url":"https://www.academia.edu/Documents/in/Kinetics?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="16215" href="https://www.academia.edu/Documents/in/Ionic_Liquid">Ionic Liquid</a>, <script data-card-contents-for-ri="16215" type="text/json">{"id":16215,"name":"Ionic Liquid","url":"https://www.academia.edu/Documents/in/Ionic_Liquid?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="33003" href="https://www.academia.edu/Documents/in/Ionic_Liquids">Ionic Liquids</a><script data-card-contents-for-ri="33003" type="text/json">{"id":33003,"name":"Ionic Liquids","url":"https://www.academia.edu/Documents/in/Ionic_Liquids?f_ri=33003","nofollow":false}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=33339629]'), work: {"id":33339629,"title":"Reaction Rates as a Function of Scale within 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Model","url":"https://www.academia.edu/Documents/in/Diffusion_Model?f_ri=33003"},{"id":1228946,"name":"Physical Properties","url":"https://www.academia.edu/Documents/in/Physical_Properties?f_ri=33003"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_31908473" data-work_id="31908473" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/31908473/Synthesis_and_anti_microbial_potencies_of_1_2_hydroxyethyl_3_alkylimidazolium_chloride_ionic_liquids_Microbial_viabilities_at_different_ionic_liquids_concentrations">Synthesis and anti-microbial potencies of 1-(2-hydroxyethyl)-3-alkylimidazolium chloride ionic liquids: Microbial viabilities at different ionic liquids concentrations</a></div></div><div class="u-pb4x u-mt3x"></div><ul 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type="text/json">{"id":1131,"name":"Biomedical Engineering","url":"https://www.academia.edu/Documents/in/Biomedical_Engineering?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="4748" href="https://www.academia.edu/Documents/in/Electrochemistry">Electrochemistry</a>, <script data-card-contents-for-ri="4748" type="text/json">{"id":4748,"name":"Electrochemistry","url":"https://www.academia.edu/Documents/in/Electrochemistry?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="12842" href="https://www.academia.edu/Documents/in/Carbon_Nanotube">Carbon Nanotube</a><script data-card-contents-for-ri="12842" type="text/json">{"id":12842,"name":"Carbon Nanotube","url":"https://www.academia.edu/Documents/in/Carbon_Nanotube?f_ri=33003","nofollow":false}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=1802509]'), work: 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type="text/json">{"id":523,"name":"Chemistry","url":"https://www.academia.edu/Documents/in/Chemistry?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="3408" href="https://www.academia.edu/Documents/in/Green_Chemistry">Green Chemistry</a>, <script data-card-contents-for-ri="3408" type="text/json">{"id":3408,"name":"Green Chemistry","url":"https://www.academia.edu/Documents/in/Green_Chemistry?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="7766" href="https://www.academia.edu/Documents/in/Solar_Cell">Solar Cell</a>, <script data-card-contents-for-ri="7766" type="text/json">{"id":7766,"name":"Solar Cell","url":"https://www.academia.edu/Documents/in/Solar_Cell?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="8384" href="https://www.academia.edu/Documents/in/Dye_Sensitized_Solar_Cells">Dye Sensitized Solar Cells</a><script data-card-contents-for-ri="8384" 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href="https://www.academia.edu/1966987/Fast_enzymatic_saccharification_of_switchgrass_after_pretreatment_with_ionic_liquids">Fast enzymatic saccharification of switchgrass after pretreatment with ionic liquids</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The pretreatment of cellulose using ionic liquids (ILs) has been shown to be an effective method for improving the enzymatic hydrolysis of cellulose; this technique affords a fast and complete saccharification of cellulose into reducing... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_1966987" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The pretreatment of cellulose using ionic liquids (ILs) has been shown to be an effective method for improving the enzymatic hydrolysis of cellulose; this technique affords a fast and complete saccharification of cellulose into reducing sugars (Dadi et al., Biotechnol Bioeng. 2006; 95:904–910; Liu and Chen, Chinese Sci Bull. 2006; 51:2432–2436; Zhao et al., J Biotechnol. 2009; 139:47–54). Motivated by these advances, this study examines the effect of IL-pretreatment on the enzymatic hydrolysis of purified xylan (as a model system of hemicellulose) and switchgrass (as a real lignocellulose). The IL-pretreatment resulted in no improvement in the hydrolysis of xylan. The likely reason is that pure xylan has a low degree of polymerization (DP), and is readily biodegraded even without any pretreatment. However, in real cellulosic materials (such as switchgrass), xylan is entrapped within the cellulosic matrix, and cannot be conveniently accessed by enzymes. Our data demonstrate that the IL-pretreatment of switchgrass significantly improved the enzymatic saccharification of both cellulose (96% D-glucose yield in 24 h) and xylan (63% D-xylose yield in 24 h). The compositional analysis of switchgrass suggests a lower lignin content after IL-pretreatment. In addition, the infrared spectrum of regenerated switchgrass indicates a lower substrate crystallinity, whereas the enzyme adsorption isotherm further implies that the regenerated substrate is more accessible to enzymes. This study has further confirmed that IL-pretreatment is an effective tool in enhancing the enzymatic hydrolysis of cellulosic biomass, and allowing a more complete saccharification. © 2009 American Institute of Chemical Engineers Biotechnol. Prog., 2010</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/1966987" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="7beb4cf66a3d8dce55b5c4fd2267163b" rel="nofollow" data-download="{"attachment_id":50805234,"asset_id":1966987,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/50805234/download_file?st=MTczMzA4NDk4MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="212638" href="https://spanalumni.academia.edu/HuaZhao">Hua Zhao</a><script data-card-contents-for-user="212638" type="text/json">{"id":212638,"first_name":"Hua","last_name":"Zhao","domain_name":"spanalumni","page_name":"HuaZhao","display_name":"Hua Zhao","profile_url":"https://spanalumni.academia.edu/HuaZhao?f_ri=33003","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_1966987 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="1966987"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 1966987, container: ".js-paper-rank-work_1966987", }); 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this technique affords a fast and complete saccharification of cellulose into reducing sugars (Dadi et al., Biotechnol Bioeng. 2006; 95:904–910; Liu and Chen, Chinese Sci Bull. 2006; 51:2432–2436; Zhao et al., J Biotechnol. 2009; 139:47–54). Motivated by these advances, this study examines the effect of IL-pretreatment on the enzymatic hydrolysis of purified xylan (as a model system of hemicellulose) and switchgrass (as a real lignocellulose). The IL-pretreatment resulted in no improvement in the hydrolysis of xylan. The likely reason is that pure xylan has a low degree of polymerization (DP), and is readily biodegraded even without any pretreatment. However, in real cellulosic materials (such as switchgrass), xylan is entrapped within the cellulosic matrix, and cannot be conveniently accessed by enzymes. Our data demonstrate that the IL-pretreatment of switchgrass significantly improved the enzymatic saccharification of both cellulose (96% D-glucose yield in 24 h) and xylan (63% D-xylose yield in 24 h). The compositional analysis of switchgrass suggests a lower lignin content after IL-pretreatment. In addition, the infrared spectrum of regenerated switchgrass indicates a lower substrate crystallinity, whereas the enzyme adsorption isotherm further implies that the regenerated substrate is more accessible to enzymes. This study has further confirmed that IL-pretreatment is an effective tool in enhancing the enzymatic hydrolysis of cellulosic biomass, and allowing a more complete saccharification. © 2009 American Institute of Chemical Engineers Biotechnol. 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itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/3169544/A_novel_method_for_the_synthesis_of_2_imidazolones">A novel method for the synthesis of 2-imidazolones</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The superoxide ion electrochemically generated by reduction of oxygen, or chemically generated by dissolving potassium superoxide in ionic liquids, reacts with alkyl imidazolium cations of imidazolium-based ionic liquids at room... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_3169544" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The superoxide ion electrochemically generated by reduction of oxygen, or chemically generated by dissolving potassium superoxide in ionic liquids, reacts with alkyl imidazolium cations of imidazolium-based ionic liquids at room temperature and atmospheric pressure to give the corresponding 2-imidazolones in excellent yields.The superoxide ion electrochemically generated by reduction of oxygen, or chemically generated by dissolving potassium superoxide in ionic liquids, reacts with alkyl imidazolium cations of imidazolium-based ionic liquids at room temperature and atmospheric pressure to give the corresponding 2-imidazolones in excellent yields.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/3169544" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li 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href="https://king-saud.academia.edu/InasMAlNashef">Inas M. AlNashef</a><script data-card-contents-for-user="2668362" type="text/json">{"id":2668362,"first_name":"Inas M.","last_name":"AlNashef","domain_name":"king-saud","page_name":"InasMAlNashef","display_name":"Inas M. 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AlNashef","profile_url":"https://king-saud.academia.edu/InasMAlNashef?f_ri=33003","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":531,"name":"Organic Chemistry","url":"https://www.academia.edu/Documents/in/Organic_Chemistry?f_ri=33003","nofollow":false},{"id":8620,"name":"Poverty Reduction Strategies","url":"https://www.academia.edu/Documents/in/Poverty_Reduction_Strategies?f_ri=33003","nofollow":false},{"id":16215,"name":"Ionic Liquid","url":"https://www.academia.edu/Documents/in/Ionic_Liquid?f_ri=33003","nofollow":false},{"id":33003,"name":"Ionic Liquids","url":"https://www.academia.edu/Documents/in/Ionic_Liquids?f_ri=33003","nofollow":false},{"id":53556,"name":"Preparation of Allylic and Propargylic Imidazole Derivatives and Their Enyne Metathesis Reactions","url":"https://www.academia.edu/Documents/in/Preparation_of_Allylic_and_Propargylic_Imidazole_Derivatives_and_Their_Enyne_Metathesis_Reactions?f_ri=33003"},{"id":55388,"name":"Organic Synthesis","url":"https://www.academia.edu/Documents/in/Organic_Synthesis?f_ri=33003"},{"id":148176,"name":"Atmospheric Pressure","url":"https://www.academia.edu/Documents/in/Atmospheric_Pressure?f_ri=33003"},{"id":160656,"name":"Potassium","url":"https://www.academia.edu/Documents/in/Potassium?f_ri=33003"},{"id":168891,"name":"Chemical Analysis","url":"https://www.academia.edu/Documents/in/Chemical_Analysis?f_ri=33003"},{"id":169415,"name":"Article","url":"https://www.academia.edu/Documents/in/Article?f_ri=33003"},{"id":213343,"name":"Superoxide Dismutase","url":"https://www.academia.edu/Documents/in/Superoxide_Dismutase?f_ri=33003"},{"id":391252,"name":"Room Temperature","url":"https://www.academia.edu/Documents/in/Room_Temperature?f_ri=33003"},{"id":484952,"name":"Students perception of using Molecular models in teaching Chemical structure and bonding","url":"https://www.academia.edu/Documents/in/Students_perception_of_using_Molecular_models_in_teaching_Chemical_structure_and_bonding?f_ri=33003"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_3352352" data-work_id="3352352" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/3352352/Development_of_a_voltammetric_electronic_tongue_for_discrimination_of_edible_oils">Development of a voltammetric electronic tongue for discrimination of edible oils</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">In this paper, we propose a novel strategy to perform cyclic voltammetric measurements with a platinum microelectrode directly in edible oil samples. The microelectrode was employed as an electronic tongue that, along with the application... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_3352352" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">In this paper, we propose a novel strategy to perform cyclic voltammetric measurements with a platinum microelectrode directly in edible oil samples. The microelectrode was employed as an electronic tongue that, along with the application of chemometrics to the current–potential responses, proved useful for discriminating oils on the basis of their quality and geographical origin. The method proposed here is based on the use of suitable room temperature ionic liquids, added to oils as supporting electrolytes to provide conductivity to the low-polarity samples. The entire voltammograms, recorded directly on the oil/RTIL mixtures, were processed via principal component analysis and a classification technique (K nearest neighbors), to extract information on samples characteristics. Data processing showed that oils having different nature (i.e. maize and olive) or geographical origin (i.e. olive oils coming from different regions) can be distinguished. Figure A novel strategy to perform voltammetric measurements with a platinum microelectrode directly in edible oil samples is presented. The microelectrode is employed as an electronic tongue that, along with the application of chemometrics to the voltammetric responses, allows oil discrimination according to their quality and geographical origin.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/3352352" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="ffce59aedad703b66092830496d9dc67" rel="nofollow" data-download="{"attachment_id":50319961,"asset_id":3352352,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/50319961/download_file?st=MTczMzA4NDk4MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="188023" href="https://unige-it.academia.edu/PaoloOliveri">Paolo Oliveri</a><script data-card-contents-for-user="188023" type="text/json">{"id":188023,"first_name":"Paolo","last_name":"Oliveri","domain_name":"unige-it","page_name":"PaoloOliveri","display_name":"Paolo Oliveri","profile_url":"https://unige-it.academia.edu/PaoloOliveri?f_ri=33003","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_3352352 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="3352352"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 3352352, container: ".js-paper-rank-work_3352352", }); 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The microelectrode was employed as an electronic tongue that, along with the application of chemometrics to the current–potential responses, proved useful for discriminating oils on the basis of their quality and geographical origin. The method proposed here is based on the use of suitable room temperature ionic liquids, added to oils as supporting electrolytes to provide conductivity to the low-polarity samples. The entire voltammograms, recorded directly on the oil/RTIL mixtures, were processed via principal component analysis and a classification technique (K nearest neighbors), to extract information on samples characteristics. Data processing showed that oils having different nature (i.e. maize and olive) or geographical origin (i.e. olive oils coming from different regions) can be distinguished. Figure A novel strategy to perform voltammetric measurements with a platinum microelectrode directly in edible oil samples is presented. The microelectrode is employed as an electronic tongue that, along with the application of chemometrics to the voltammetric responses, allows oil discrimination according to their quality and geographical origin.","downloadable_attachments":[{"id":50319961,"asset_id":3352352,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":188023,"first_name":"Paolo","last_name":"Oliveri","domain_name":"unige-it","page_name":"PaoloOliveri","display_name":"Paolo 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Structures","url":"https://www.academia.edu/Documents/in/Crystal_Structures?f_ri=33003"},{"id":610960,"name":"Australian","url":"https://www.academia.edu/Documents/in/Australian?f_ri=33003"},{"id":627110,"name":"BioSensors","url":"https://www.academia.edu/Documents/in/BioSensors-1?f_ri=33003"},{"id":780543,"name":"G protein","url":"https://www.academia.edu/Documents/in/G_protein?f_ri=33003"},{"id":1199463,"name":"Combinatorial","url":"https://www.academia.edu/Documents/in/Combinatorial?f_ri=33003"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_3713254" data-work_id="3713254" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/3713254/Ionic_liquid_as_catalyst_in_the_synthesis_of_N_alkyl_trifluoromethyl_pyrazoles">Ionic liquid as catalyst in the synthesis of N-alkyl trifluoromethyl pyrazoles</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The efficacy of ionic liquids was evaluated in the N-alkylation reaction of 3,5-dimethyl- and 5-trifluoromethyl-3-methyl-1H-pyrazoles, from the reaction of N–H pyrazoles with alkyl halides (R1–X, where R1 = Bu, octyl, allyl, benzyl,... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_3713254" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The efficacy of ionic liquids was evaluated in the N-alkylation reaction of 3,5-dimethyl- and 5-trifluoromethyl-3-methyl-1H-pyrazoles, from the reaction of N–H pyrazoles with alkyl halides (R1–X, where R1 = Bu, octyl, allyl, benzyl, –CH2CH2CONEt2, –CH2C(O)Ph, CH2CH2C(O)Ph and X = Cl, Br, I). Novel trifluoromethylated pyrazoles are among the compounds obtained. The reaction was chemoselective for trifluoromethylpyrazoles and 1-alkyl-3-trifluoromethyl-5-methyl-1H-pyrazoles were preferentially formed. The reaction time and yields were investigated and this method showed shorter reaction times and better yields in comparison with the reaction performed in molecular solvents.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/3713254" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="f088093ef3fd534c1051d0518c1ac07e" rel="nofollow" data-download="{"attachment_id":50166457,"asset_id":3713254,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/50166457/download_file?st=MTczMzA4NDk4MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="4543279" href="https://independent.academia.edu/DayseMoreira">Dayse Moreira</a><script data-card-contents-for-user="4543279" type="text/json">{"id":4543279,"first_name":"Dayse","last_name":"Moreira","domain_name":"independent","page_name":"DayseMoreira","display_name":"Dayse Moreira","profile_url":"https://independent.academia.edu/DayseMoreira?f_ri=33003","photo":"https://0.academia-photos.com/4543279/1880287/2231634/s65_dayse.moreira.jpg"}</script></span></span></li><li class="js-paper-rank-work_3713254 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="3713254"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 3713254, container: ".js-paper-rank-work_3713254", }); 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$(".js-view-count[data-work-id=3713254]").text(description); $(".js-view-count-work_3713254").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_3713254").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="3713254"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">5</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="72" href="https://www.academia.edu/Documents/in/Chemical_Engineering">Chemical Engineering</a>, <script data-card-contents-for-ri="72" type="text/json">{"id":72,"name":"Chemical Engineering","url":"https://www.academia.edu/Documents/in/Chemical_Engineering?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="4749" href="https://www.academia.edu/Documents/in/Catalysis">Catalysis</a>, <script data-card-contents-for-ri="4749" type="text/json">{"id":4749,"name":"Catalysis","url":"https://www.academia.edu/Documents/in/Catalysis?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="16215" href="https://www.academia.edu/Documents/in/Ionic_Liquid">Ionic Liquid</a>, <script data-card-contents-for-ri="16215" type="text/json">{"id":16215,"name":"Ionic Liquid","url":"https://www.academia.edu/Documents/in/Ionic_Liquid?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="33003" href="https://www.academia.edu/Documents/in/Ionic_Liquids">Ionic Liquids</a><script data-card-contents-for-ri="33003" type="text/json">{"id":33003,"name":"Ionic Liquids","url":"https://www.academia.edu/Documents/in/Ionic_Liquids?f_ri=33003","nofollow":false}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=3713254]'), work: {"id":3713254,"title":"Ionic liquid as catalyst in the synthesis of N-alkyl trifluoromethyl pyrazoles","created_at":"2013-06-14T13:45:57.794-07:00","url":"https://www.academia.edu/3713254/Ionic_liquid_as_catalyst_in_the_synthesis_of_N_alkyl_trifluoromethyl_pyrazoles?f_ri=33003","dom_id":"work_3713254","summary":"The efficacy of ionic liquids was evaluated in the N-alkylation reaction of 3,5-dimethyl- and 5-trifluoromethyl-3-methyl-1H-pyrazoles, from the reaction of N–H pyrazoles with alkyl halides (R1–X, where R1 = Bu, octyl, allyl, benzyl, –CH2CH2CONEt2, –CH2C(O)Ph, CH2CH2C(O)Ph and X = Cl, Br, I). Novel trifluoromethylated pyrazoles are among the compounds obtained. The reaction was chemoselective for trifluoromethylpyrazoles and 1-alkyl-3-trifluoromethyl-5-methyl-1H-pyrazoles were preferentially formed. The reaction time and yields were investigated and this method showed shorter reaction times and better yields in comparison with the reaction performed in molecular solvents.","downloadable_attachments":[{"id":50166457,"asset_id":3713254,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":4543279,"first_name":"Dayse","last_name":"Moreira","domain_name":"independent","page_name":"DayseMoreira","display_name":"Dayse Moreira","profile_url":"https://independent.academia.edu/DayseMoreira?f_ri=33003","photo":"https://0.academia-photos.com/4543279/1880287/2231634/s65_dayse.moreira.jpg"}],"research_interests":[{"id":72,"name":"Chemical Engineering","url":"https://www.academia.edu/Documents/in/Chemical_Engineering?f_ri=33003","nofollow":false},{"id":4749,"name":"Catalysis","url":"https://www.academia.edu/Documents/in/Catalysis?f_ri=33003","nofollow":false},{"id":16215,"name":"Ionic Liquid","url":"https://www.academia.edu/Documents/in/Ionic_Liquid?f_ri=33003","nofollow":false},{"id":33003,"name":"Ionic Liquids","url":"https://www.academia.edu/Documents/in/Ionic_Liquids?f_ri=33003","nofollow":false},{"id":119665,"name":"Reaction Time","url":"https://www.academia.edu/Documents/in/Reaction_Time?f_ri=33003"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_4070621" data-work_id="4070621" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/4070621/Preparation_of_gold_nanoparticles_functionalized_multiwalled_carbon_nanotube_nanocomposites_and_its_glucose_biosensing_application">Preparation of gold nanoparticles/functionalized multiwalled carbon nanotube nanocomposites and its glucose biosensing application</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">Gold nanoparticles stabilized by amino-terminated ionic liquid (Au-IL) have been in situ noncovalently deposited on poly(sodium 4-styrene-sulfonate) (PSS)-functionalized multiwalled carbon nanotubes (MWCNTs) to form a MWCNTs/PSS/Au-IL... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_4070621" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">Gold nanoparticles stabilized by amino-terminated ionic liquid (Au-IL) have been in situ noncovalently deposited on poly(sodium 4-styrene-sulfonate) (PSS)-functionalized multiwalled carbon nanotubes (MWCNTs) to form a MWCNTs/PSS/Au-IL nanocomposite. PSS can interact with MWCNTs through hydrophobic interaction. Amino-terminated ionic liquid was applied to reduce aqueous HAuCl4, and the resulting gold nanoparticles were attached to the PSS-functionalized MWCNTs simultaneously. Most gold nanoparticles dispersed well on the functionalized MWCNTs. Transmission electron microscopy, Raman and X-ray photoelectron spectroscopy were used to confirm the composition and structure of the nanocomposites. The resulting MWCNTs/PSS/Au-IL composite exhibits good electrocatalysis toward oxygen and hydrogen peroxide reduction. And good biocompatibility with glucose oxidase was also demonstrated due to its good biocatalysis toward glucose substrate, which offered a friendly environment for the immobilization of biomolecules. Such bionanocomposite provides us potential applications in fabrication of biosensors. The resulting biosensor exhibits good response to glucose with a low detection limit 25 μM. It also has excellent reproducibility, satisfied operational stability and good storage stability.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/4070621" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="7e5bb78d64a837b4f6f54211a0a7175d" rel="nofollow" data-download="{"attachment_id":50047202,"asset_id":4070621,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/50047202/download_file?st=MTczMzA4NDk4MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="4904397" href="https://udel.academia.edu/ChangshengShan">Changsheng Shan</a><script data-card-contents-for-user="4904397" type="text/json">{"id":4904397,"first_name":"Changsheng","last_name":"Shan","domain_name":"udel","page_name":"ChangshengShan","display_name":"Changsheng Shan","profile_url":"https://udel.academia.edu/ChangshengShan?f_ri=33003","photo":"https://0.academia-photos.com/4904397/2111851/2481437/s65_changsheng.shan.jpg"}</script></span></span></li><li class="js-paper-rank-work_4070621 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="4070621"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 4070621, container: ".js-paper-rank-work_4070621", }); 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$(".js-view-count[data-work-id=4070621]").text(description); $(".js-view-count-work_4070621").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_4070621").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="4070621"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">32</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="524" href="https://www.academia.edu/Documents/in/Analytical_Chemistry">Analytical Chemistry</a>, <script data-card-contents-for-ri="524" type="text/json">{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="1131" href="https://www.academia.edu/Documents/in/Biomedical_Engineering">Biomedical Engineering</a>, <script data-card-contents-for-ri="1131" type="text/json">{"id":1131,"name":"Biomedical Engineering","url":"https://www.academia.edu/Documents/in/Biomedical_Engineering?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="4331" href="https://www.academia.edu/Documents/in/Biosensors">Biosensors</a>, <script data-card-contents-for-ri="4331" type="text/json">{"id":4331,"name":"Biosensors","url":"https://www.academia.edu/Documents/in/Biosensors?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="4748" href="https://www.academia.edu/Documents/in/Electrochemistry">Electrochemistry</a><script data-card-contents-for-ri="4748" type="text/json">{"id":4748,"name":"Electrochemistry","url":"https://www.academia.edu/Documents/in/Electrochemistry?f_ri=33003","nofollow":false}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=4070621]'), work: {"id":4070621,"title":"Preparation of gold nanoparticles/functionalized multiwalled carbon nanotube nanocomposites and its glucose biosensing application","created_at":"2013-07-20T10:35:02.692-07:00","url":"https://www.academia.edu/4070621/Preparation_of_gold_nanoparticles_functionalized_multiwalled_carbon_nanotube_nanocomposites_and_its_glucose_biosensing_application?f_ri=33003","dom_id":"work_4070621","summary":"Gold nanoparticles stabilized by amino-terminated ionic liquid (Au-IL) have been in situ noncovalently deposited on poly(sodium 4-styrene-sulfonate) (PSS)-functionalized multiwalled carbon nanotubes (MWCNTs) to form a MWCNTs/PSS/Au-IL nanocomposite. PSS can interact with MWCNTs through hydrophobic interaction. Amino-terminated ionic liquid was applied to reduce aqueous HAuCl4, and the resulting gold nanoparticles were attached to the PSS-functionalized MWCNTs simultaneously. Most gold nanoparticles dispersed well on the functionalized MWCNTs. Transmission electron microscopy, Raman and X-ray photoelectron spectroscopy were used to confirm the composition and structure of the nanocomposites. The resulting MWCNTs/PSS/Au-IL composite exhibits good electrocatalysis toward oxygen and hydrogen peroxide reduction. And good biocompatibility with glucose oxidase was also demonstrated due to its good biocatalysis toward glucose substrate, which offered a friendly environment for the immobilization of biomolecules. Such bionanocomposite provides us potential applications in fabrication of biosensors. The resulting biosensor exhibits good response to glucose with a low detection limit 25 μM. It also has excellent reproducibility, satisfied operational stability and good storage stability.","downloadable_attachments":[{"id":50047202,"asset_id":4070621,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":4904397,"first_name":"Changsheng","last_name":"Shan","domain_name":"udel","page_name":"ChangshengShan","display_name":"Changsheng Shan","profile_url":"https://udel.academia.edu/ChangshengShan?f_ri=33003","photo":"https://0.academia-photos.com/4904397/2111851/2481437/s65_changsheng.shan.jpg"}],"research_interests":[{"id":524,"name":"Analytical Chemistry","url":"https://www.academia.edu/Documents/in/Analytical_Chemistry?f_ri=33003","nofollow":false},{"id":1131,"name":"Biomedical Engineering","url":"https://www.academia.edu/Documents/in/Biomedical_Engineering?f_ri=33003","nofollow":false},{"id":4331,"name":"Biosensors","url":"https://www.academia.edu/Documents/in/Biosensors?f_ri=33003","nofollow":false},{"id":4748,"name":"Electrochemistry","url":"https://www.academia.edu/Documents/in/Electrochemistry?f_ri=33003","nofollow":false},{"id":5303,"name":"Carbon","url":"https://www.academia.edu/Documents/in/Carbon?f_ri=33003"},{"id":8950,"name":"Nanoparticle","url":"https://www.academia.edu/Documents/in/Nanoparticle?f_ri=33003"},{"id":12842,"name":"Carbon Nanotube","url":"https://www.academia.edu/Documents/in/Carbon_Nanotube?f_ri=33003"},{"id":14076,"name":"Transmission Electron Microscopy","url":"https://www.academia.edu/Documents/in/Transmission_Electron_Microscopy?f_ri=33003"},{"id":16215,"name":"Ionic Liquid","url":"https://www.academia.edu/Documents/in/Ionic_Liquid?f_ri=33003"},{"id":17733,"name":"Nanotechnology","url":"https://www.academia.edu/Documents/in/Nanotechnology?f_ri=33003"},{"id":23695,"name":"Electrocatalysis","url":"https://www.academia.edu/Documents/in/Electrocatalysis?f_ri=33003"},{"id":33003,"name":"Ionic Liquids","url":"https://www.academia.edu/Documents/in/Ionic_Liquids?f_ri=33003"},{"id":65698,"name":"Gold nanoparticle","url":"https://www.academia.edu/Documents/in/Gold_nanoparticle?f_ri=33003"},{"id":71289,"name":"Glucose","url":"https://www.academia.edu/Documents/in/Glucose?f_ri=33003"},{"id":76736,"name":"Gold","url":"https://www.academia.edu/Documents/in/Gold?f_ri=33003"},{"id":88640,"name":"Gold Nanoparticles","url":"https://www.academia.edu/Documents/in/Gold_Nanoparticles?f_ri=33003"},{"id":99017,"name":"Nanocomposite","url":"https://www.academia.edu/Documents/in/Nanocomposite?f_ri=33003"},{"id":109419,"name":"Biosensor","url":"https://www.academia.edu/Documents/in/Biosensor?f_ri=33003"},{"id":129704,"name":"OR","url":"https://www.academia.edu/Documents/in/OR?f_ri=33003"},{"id":184907,"name":"Microelectrodes","url":"https://www.academia.edu/Documents/in/Microelectrodes?f_ri=33003"},{"id":263097,"name":"Application","url":"https://www.academia.edu/Documents/in/Application?f_ri=33003"},{"id":274826,"name":"Hydrogen Peroxide","url":"https://www.academia.edu/Documents/in/Hydrogen_Peroxide?f_ri=33003"},{"id":549280,"name":"Reproducibility of Results","url":"https://www.academia.edu/Documents/in/Reproducibility_of_Results?f_ri=33003"},{"id":627110,"name":"BioSensors","url":"https://www.academia.edu/Documents/in/BioSensors-1?f_ri=33003"},{"id":679783,"name":"Boolean Satisfiability","url":"https://www.academia.edu/Documents/in/Boolean_Satisfiability?f_ri=33003"},{"id":901876,"name":"Sensitivity and Specificity","url":"https://www.academia.edu/Documents/in/Sensitivity_and_Specificity?f_ri=33003"},{"id":902639,"name":"X Ray Photoelectron Spectroscopy","url":"https://www.academia.edu/Documents/in/X_Ray_Photoelectron_Spectroscopy?f_ri=33003"},{"id":1145520,"name":"Equipment Design","url":"https://www.academia.edu/Documents/in/Equipment_Design?f_ri=33003"},{"id":1157424,"name":"Equipment Failure Analysis","url":"https://www.academia.edu/Documents/in/Equipment_Failure_Analysis?f_ri=33003"},{"id":1412233,"name":"Biosensing Techniques","url":"https://www.academia.edu/Documents/in/Biosensing_Techniques?f_ri=33003"},{"id":1529889,"name":"Nanotubes Carbon","url":"https://www.academia.edu/Documents/in/Nanotubes_Carbon?f_ri=33003"},{"id":2047413,"name":"Glucose Oxidase","url":"https://www.academia.edu/Documents/in/Glucose_Oxidase?f_ri=33003"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_4268502" data-work_id="4268502" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/4268502/Synthesis_and_PhysicoChemical_Properties_of_New_Tetraethylammonium_Based_Amino_Acid_Chiral_Ionic_Liquids">Synthesis and PhysicoChemical Properties of New Tetraethylammonium-Based Amino Acid Chiral Ionic Liquids</a></div></div><div class="u-pb4x u-mt3x"></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/4268502" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa 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itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="5177641" href="https://independent.academia.edu/KamaliahSirat">Kamaliah Sirat</a><script data-card-contents-for-user="5177641" type="text/json">{"id":5177641,"first_name":"Kamaliah","last_name":"Sirat","domain_name":"independent","page_name":"KamaliahSirat","display_name":"Kamaliah Sirat","profile_url":"https://independent.academia.edu/KamaliahSirat?f_ri=33003","photo":"https://0.academia-photos.com/5177641/2279569/2663032/s65_kamaliah.sirat.jpg"}</script></span></span></li><li class="js-paper-rank-work_4268502 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="4268502"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 4268502, container: ".js-paper-rank-work_4268502", }); });</script></li><li class="js-percentile-work_4268502 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window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=4268502]").text(description); $(".js-view-count-work_4268502").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_4268502").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="4268502"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">28</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="48" href="https://www.academia.edu/Documents/in/Engineering">Engineering</a>, <script data-card-contents-for-ri="48" type="text/json">{"id":48,"name":"Engineering","url":"https://www.academia.edu/Documents/in/Engineering?f_ri=33003","nofollow":false}</script><a 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{"id":29495353,"title":"Speciation of Uranyl Nitrato Complexes in Acetonitrile and in the Ionic Liquid 1-Butyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide","created_at":"2016-10-28T03:58:12.415-07:00","url":"https://www.academia.edu/29495353/Speciation_of_Uranyl_Nitrato_Complexes_in_Acetonitrile_and_in_the_Ionic_Liquid_1_Butyl_3_methylimidazolium_Bis_trifluoromethylsulfonyl_imide?f_ri=33003","dom_id":"work_29495353","summary":null,"downloadable_attachments":[{"id":49935177,"asset_id":29495353,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":55751071,"first_name":"Isabelle","last_name":"Billard","domain_name":"independent","page_name":"IsabelleBillard","display_name":"Isabelle Billard","profile_url":"https://independent.academia.edu/IsabelleBillard?f_ri=33003","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":530,"name":"Inorganic 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class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/4422431/Selective_Hydrogenation_of_1_3Butadiene_to_1Butene_by_Pd_0_Nanoparticles_Embedded_in_Imidazolium_Ionic_Liquids">Selective Hydrogenation of 1,3Butadiene to 1Butene by Pd(0) Nanoparticles Embedded in Imidazolium Ionic Liquids</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The reduction of Pd(acac)2 (acac=acetylacetonate), dissolved in 1-n-butyl-3-methylimidazolium hexafluorophosphate (BMI⋅PF6) or tetrafluoroborate (BMI⋅BF4) ionic liquids, by molecular hydrogen (4 atm) at 75 °C affords stable, nanoscale... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_4422431" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The reduction of Pd(acac)2 (acac=acetylacetonate), dissolved in 1-n-butyl-3-methylimidazolium hexafluorophosphate (BMI⋅PF6) or tetrafluoroborate (BMI⋅BF4) ionic liquids, by molecular hydrogen (4 atm) at 75 °C affords stable, nanoscale Pd(0) particles with sizes of 4.9±0.8 nm. Inasmuch as 1,3-butadiene is at least four times more soluble in the BMI⋅BF4 than butenes, the selective partial hydrogenation could be performed by Pd(0) nanoparticles embedded in the ionic liquid. Thus, the isolated nanoparticles promote the hydrogenation of 1,3-butadiene to butenes under solventless or multiphase conditions. Selectivities up to 97% in butenes were observed in the hydrogenation of 1,3-butadiene by Pd(0) nanoparticles embedded in BMI⋅BF4 under mild reaction conditions (40 °C and 4 atm of hydrogen at constant pressure). Selectivities up to 72% in 1-butene were achieved at 99% 1,3-butadiene conversion, 40 °C and 4 atm of constant pressure of hydrogen. The amounts of butane (fully hydrogenated 1,3-butadiene) and cis-2-butene products are marginal and the butenes do not undergo isomerisation process, indicating that the soluble Pd(0) nanoparticles possess a pronounced surface-like rather than homogeneous-like catalytic properties.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/4422431" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="7b676ad33248060052b977f9276cdfe7" rel="nofollow" data-download="{"attachment_id":49869495,"asset_id":4422431,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/49869495/download_file?st=MTczMzA4NDk4MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="5430397" href="https://independent.academia.edu/JairtonDupont">Jairton Dupont</a><script data-card-contents-for-user="5430397" type="text/json">{"id":5430397,"first_name":"Jairton","last_name":"Dupont","domain_name":"independent","page_name":"JairtonDupont","display_name":"Jairton Dupont","profile_url":"https://independent.academia.edu/JairtonDupont?f_ri=33003","photo":"https://0.academia-photos.com/5430397/2385808/2778147/s65_jairton.dupont.jpg"}</script></span></span></li><li class="js-paper-rank-work_4422431 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="4422431"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 4422431, container: ".js-paper-rank-work_4422431", }); 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$(".js-view-count[data-work-id=4422431]").text(description); $(".js-view-count-work_4422431").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_4422431").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="4422431"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">7</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="72" href="https://www.academia.edu/Documents/in/Chemical_Engineering">Chemical Engineering</a>, <script data-card-contents-for-ri="72" type="text/json">{"id":72,"name":"Chemical Engineering","url":"https://www.academia.edu/Documents/in/Chemical_Engineering?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="530" href="https://www.academia.edu/Documents/in/Inorganic_Chemistry">Inorganic Chemistry</a>, <script data-card-contents-for-ri="530" type="text/json">{"id":530,"name":"Inorganic Chemistry","url":"https://www.academia.edu/Documents/in/Inorganic_Chemistry?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="531" href="https://www.academia.edu/Documents/in/Organic_Chemistry">Organic Chemistry</a>, <script data-card-contents-for-ri="531" type="text/json">{"id":531,"name":"Organic Chemistry","url":"https://www.academia.edu/Documents/in/Organic_Chemistry?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="13621" href="https://www.academia.edu/Documents/in/Nanoparticles">Nanoparticles</a><script data-card-contents-for-ri="13621" type="text/json">{"id":13621,"name":"Nanoparticles","url":"https://www.academia.edu/Documents/in/Nanoparticles?f_ri=33003","nofollow":false}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=4422431]'), work: {"id":4422431,"title":"Selective Hydrogenation of 1,3Butadiene to 1Butene by Pd(0) Nanoparticles Embedded in Imidazolium Ionic Liquids","created_at":"2013-09-06T02:50:39.392-07:00","url":"https://www.academia.edu/4422431/Selective_Hydrogenation_of_1_3Butadiene_to_1Butene_by_Pd_0_Nanoparticles_Embedded_in_Imidazolium_Ionic_Liquids?f_ri=33003","dom_id":"work_4422431","summary":"The reduction of Pd(acac)2 (acac=acetylacetonate), dissolved in 1-n-butyl-3-methylimidazolium hexafluorophosphate (BMI⋅PF6) or tetrafluoroborate (BMI⋅BF4) ionic liquids, by molecular hydrogen (4 atm) at 75 °C affords stable, nanoscale Pd(0) particles with sizes of 4.9±0.8 nm. Inasmuch as 1,3-butadiene is at least four times more soluble in the BMI⋅BF4 than butenes, the selective partial hydrogenation could be performed by Pd(0) nanoparticles embedded in the ionic liquid. Thus, the isolated nanoparticles promote the hydrogenation of 1,3-butadiene to butenes under solventless or multiphase conditions. Selectivities up to 97% in butenes were observed in the hydrogenation of 1,3-butadiene by Pd(0) nanoparticles embedded in BMI⋅BF4 under mild reaction conditions (40 °C and 4 atm of hydrogen at constant pressure). Selectivities up to 72% in 1-butene were achieved at 99% 1,3-butadiene conversion, 40 °C and 4 atm of constant pressure of hydrogen. The amounts of butane (fully hydrogenated 1,3-butadiene) and cis-2-butene products are marginal and the butenes do not undergo isomerisation process, indicating that the soluble Pd(0) nanoparticles possess a pronounced surface-like rather than homogeneous-like catalytic properties.","downloadable_attachments":[{"id":49869495,"asset_id":4422431,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":5430397,"first_name":"Jairton","last_name":"Dupont","domain_name":"independent","page_name":"JairtonDupont","display_name":"Jairton Dupont","profile_url":"https://independent.academia.edu/JairtonDupont?f_ri=33003","photo":"https://0.academia-photos.com/5430397/2385808/2778147/s65_jairton.dupont.jpg"}],"research_interests":[{"id":72,"name":"Chemical Engineering","url":"https://www.academia.edu/Documents/in/Chemical_Engineering?f_ri=33003","nofollow":false},{"id":530,"name":"Inorganic Chemistry","url":"https://www.academia.edu/Documents/in/Inorganic_Chemistry?f_ri=33003","nofollow":false},{"id":531,"name":"Organic Chemistry","url":"https://www.academia.edu/Documents/in/Organic_Chemistry?f_ri=33003","nofollow":false},{"id":13621,"name":"Nanoparticles","url":"https://www.academia.edu/Documents/in/Nanoparticles?f_ri=33003","nofollow":false},{"id":16215,"name":"Ionic Liquid","url":"https://www.academia.edu/Documents/in/Ionic_Liquid?f_ri=33003"},{"id":33003,"name":"Ionic Liquids","url":"https://www.academia.edu/Documents/in/Ionic_Liquids?f_ri=33003"},{"id":201716,"name":"Palladium","url":"https://www.academia.edu/Documents/in/Palladium?f_ri=33003"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_29323386" data-work_id="29323386" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/29323386/An_investigation_of_the_reaction_between_1_butyl_3_methylimidazolium_trifluoromethanesulfonate_and_superoxide_ion">An investigation of the reaction between 1-butyl-3-methylimidazolium trifluoromethanesulfonate and superoxide ion</a></div></div><div class="u-pb4x u-mt3x"></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/29323386" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="969c7809bc9b4f8138dd05e11c897fe1" rel="nofollow" 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type="text/json">{"id":55384659,"first_name":"Inas","last_name":"AlNashef","domain_name":"masdar","page_name":"InasAlNashef","display_name":"Inas AlNashef","profile_url":"https://masdar.academia.edu/InasAlNashef?f_ri=33003","photo":"https://0.academia-photos.com/55384659/31547597/28909913/s65_inas.alnashef.jpg"}</script></span></span></li><li class="js-paper-rank-work_29323386 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="29323386"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 29323386, container: ".js-paper-rank-work_29323386", }); });</script></li><li class="js-percentile-work_29323386 InlineList-item InlineList-item--bordered hidden u-tcGrayDark"><span class="percentile-widget hidden"><span class="u-mr2x percentile-widget" style="display: none">•</span><span class="u-mr2x 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}); });</script></span><script>$(function() { $(".js-view-count-work_29323386").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="29323386"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">15</a>  </div><span class="InlineList-item-text u-textTruncate u-pl10x"><a class="InlineList-item-text" data-has-card-for-ri="9114" href="https://www.academia.edu/Documents/in/Chemotherapy">Chemotherapy</a>, <script data-card-contents-for-ri="9114" type="text/json">{"id":9114,"name":"Chemotherapy","url":"https://www.academia.edu/Documents/in/Chemotherapy?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="16215" href="https://www.academia.edu/Documents/in/Ionic_Liquid">Ionic Liquid</a>, <script data-card-contents-for-ri="16215" type="text/json">{"id":16215,"name":"Ionic Liquid","url":"https://www.academia.edu/Documents/in/Ionic_Liquid?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="20902" href="https://www.academia.edu/Documents/in/Cyclic_Voltammetry">Cyclic Voltammetry</a>, <script data-card-contents-for-ri="20902" type="text/json">{"id":20902,"name":"Cyclic Voltammetry","url":"https://www.academia.edu/Documents/in/Cyclic_Voltammetry?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="33003" href="https://www.academia.edu/Documents/in/Ionic_Liquids">Ionic Liquids</a><script data-card-contents-for-ri="33003" type="text/json">{"id":33003,"name":"Ionic Liquids","url":"https://www.academia.edu/Documents/in/Ionic_Liquids?f_ri=33003","nofollow":false}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=29323386]'), work: {"id":29323386,"title":"An investigation of the reaction between 1-butyl-3-methylimidazolium trifluoromethanesulfonate and superoxide ion","created_at":"2016-10-21T06:38:21.415-07:00","url":"https://www.academia.edu/29323386/An_investigation_of_the_reaction_between_1_butyl_3_methylimidazolium_trifluoromethanesulfonate_and_superoxide_ion?f_ri=33003","dom_id":"work_29323386","summary":null,"downloadable_attachments":[{"id":49764103,"asset_id":29323386,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":55384659,"first_name":"Inas","last_name":"AlNashef","domain_name":"masdar","page_name":"InasAlNashef","display_name":"Inas AlNashef","profile_url":"https://masdar.academia.edu/InasAlNashef?f_ri=33003","photo":"https://0.academia-photos.com/55384659/31547597/28909913/s65_inas.alnashef.jpg"}],"research_interests":[{"id":9114,"name":"Chemotherapy","url":"https://www.academia.edu/Documents/in/Chemotherapy?f_ri=33003","nofollow":false},{"id":16215,"name":"Ionic Liquid","url":"https://www.academia.edu/Documents/in/Ionic_Liquid?f_ri=33003","nofollow":false},{"id":20902,"name":"Cyclic Voltammetry","url":"https://www.academia.edu/Documents/in/Cyclic_Voltammetry?f_ri=33003","nofollow":false},{"id":33003,"name":"Ionic Liquids","url":"https://www.academia.edu/Documents/in/Ionic_Liquids?f_ri=33003","nofollow":false},{"id":82978,"name":"Reactive Oxygen Species","url":"https://www.academia.edu/Documents/in/Reactive_Oxygen_Species?f_ri=33003"},{"id":142159,"name":"Luminescence of lanthanide ions","url":"https://www.academia.edu/Documents/in/Luminescence_of_lanthanide_ions?f_ri=33003"},{"id":266690,"name":"Ionic liquids and solvents","url":"https://www.academia.edu/Documents/in/Ionic_liquids_and_solvents?f_ri=33003"},{"id":1451890,"name":"Superoxide Ion","url":"https://www.academia.edu/Documents/in/Superoxide_Ion?f_ri=33003"},{"id":1451893,"name":"Chronoamperometry","url":"https://www.academia.edu/Documents/in/Chronoamperometry?f_ri=33003"},{"id":1451895,"name":"Imidazolium Cation","url":"https://www.academia.edu/Documents/in/Imidazolium_Cation?f_ri=33003"},{"id":1455811,"name":"Superoxides","url":"https://www.academia.edu/Documents/in/Superoxides?f_ri=33003"},{"id":1457337,"name":"Potassium Superoxide","url":"https://www.academia.edu/Documents/in/Potassium_Superoxide?f_ri=33003"},{"id":1457338,"name":"Trifluoromethanesulfonate Anion","url":"https://www.academia.edu/Documents/in/Trifluoromethanesulfonate_Anion?f_ri=33003"},{"id":1457339,"name":"Trifluoromethanesulfonate","url":"https://www.academia.edu/Documents/in/Trifluoromethanesulfonate?f_ri=33003"},{"id":2114155,"name":"Molecular liquids","url":"https://www.academia.edu/Documents/in/Molecular_liquids?f_ri=33003"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_29299583" data-work_id="29299583" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/29299583/Insights_into_the_effect_of_CO_2_absorption_on_the_ionic_mobility_of_ionic_liquids">Insights into the effect of CO 2 absorption on the ionic mobility of ionic liquids</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">We investigate a comparative effect of CO 2 absorption on the ionic mobility of two choline based ionic liquids comprising two different anions such as threonine and imidazole. The synthesized ionic liquids were characterized using 1 H... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_29299583" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">We investigate a comparative effect of CO 2 absorption on the ionic mobility of two choline based ionic liquids comprising two different anions such as threonine and imidazole. The synthesized ionic liquids were characterized using 1 H and 13 C NMR and other spectroscopic techniques. By keeping a common cation and changing the anion from threonine to imidazole both the viscosity and density reduced drastically. We found that [N 1,1,6,2OH ][Imi] exhibits the highest CO 2 capture capacity at 20 1C of 5.27 mol of CO 2 per kg of ionic liquid (1.27 mol of CO 2 per mol of ionic liquid, 23.26 wt% of CO 2) whereas [N 1,1,6,2OH ][Threo] exhibits 3.6 mol of CO 2 per kg of ionic liquid (1.05 mol of CO 2 per mol of ionic liquid, 15.87 wt% of CO 2). The activation energy for diffusion is calculated using the Vogel-Fulcher-Tamman (VFT) equation in the form of diffusivity. It was found that the activation energy for the diffusion of [N 1,1,6,2OH ][Threo] is B10 times higher than that of [N 1,1,6,2OH ][Imi]. 1 H diffusion NMR data revealed that the diffusivity of [N 1,1,6,2OH ][Imi] is increased after CO 2 absorption whereas a decrease in diffusivity was observed in the case of [N 1,1,6,2OH ][Threo]. This anomalous behavior of [N 1,1,6,2OH ][Imi] was further explained by using DFT calculations.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/29299583" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="622aad5b9c1de10b62442afadf28c507" rel="nofollow" data-download="{"attachment_id":49740999,"asset_id":29299583,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/49740999/download_file?st=MTczMzA4NDk4MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="658981" href="https://ri-se.academia.edu/ShubhankarBhattacharyya">Shubhankar Bhattacharyya</a><script data-card-contents-for-user="658981" type="text/json">{"id":658981,"first_name":"Shubhankar","last_name":"Bhattacharyya","domain_name":"ri-se","page_name":"ShubhankarBhattacharyya","display_name":"Shubhankar Bhattacharyya","profile_url":"https://ri-se.academia.edu/ShubhankarBhattacharyya?f_ri=33003","photo":"/images/s65_no_pic.png"}</script></span></span></li><li class="js-paper-rank-work_29299583 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="29299583"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 29299583, container: ".js-paper-rank-work_29299583", }); });</script></li><li class="js-percentile-work_29299583 InlineList-item InlineList-item--bordered hidden u-tcGrayDark"><span class="percentile-widget hidden"><span class="u-mr2x percentile-widget" style="display: none">•</span><span class="u-mr2x work-percentile"></span></span><script>$(function () { var workId = 29299583; window.Academia.workPercentilesFetcher.queue(workId, function (percentileText) { var container = $(".js-percentile-work_29299583"); container.find('.work-percentile').text(percentileText.charAt(0).toUpperCase() + percentileText.slice(1)); container.find('.percentile-widget').show(); container.find('.percentile-widget').removeClass('hidden'); }); });</script></li><li class="js-view-count-work_29299583 InlineList-item InlineList-item--bordered hidden"><div><span><span class="js-view-count view-count u-mr2x" data-work-id="29299583"><i class="fa fa-spinner fa-spin"></i></span><script>$(function () { var workId = 29299583; window.Academia.workViewCountsFetcher.queue(workId, function (count) { var description = window.$h.commaizeInt(count) + " " + window.$h.pluralize(count, 'View'); $(".js-view-count[data-work-id=29299583]").text(description); $(".js-view-count-work_29299583").attr('title', description).tooltip(); }); });</script></span><script>$(function() { $(".js-view-count-work_29299583").removeClass('hidden') })</script></div></li><li class="InlineList-item u-positionRelative" style="max-width: 250px"><div class="u-positionAbsolute" data-has-card-for-ri-list="29299583"><i class="fa fa-tag InlineList-item-icon u-positionRelative"></i>  <a class="InlineList-item-text u-positionRelative">3</a>  </div><span class="InlineList-item-text u-textTruncate u-pl9x"><a class="InlineList-item-text" data-has-card-for-ri="33003" href="https://www.academia.edu/Documents/in/Ionic_Liquids">Ionic Liquids</a>, <script data-card-contents-for-ri="33003" type="text/json">{"id":33003,"name":"Ionic Liquids","url":"https://www.academia.edu/Documents/in/Ionic_Liquids?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="43832" href="https://www.academia.edu/Documents/in/CO2_capture_and_storage">CO2 capture and storage</a>, <script data-card-contents-for-ri="43832" type="text/json">{"id":43832,"name":"CO2 capture and storage","url":"https://www.academia.edu/Documents/in/CO2_capture_and_storage?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="115319" href="https://www.academia.edu/Documents/in/Carbon_Capture_and_Storage">Carbon Capture and Storage</a><script data-card-contents-for-ri="115319" type="text/json">{"id":115319,"name":"Carbon Capture and Storage","url":"https://www.academia.edu/Documents/in/Carbon_Capture_and_Storage?f_ri=33003","nofollow":false}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=29299583]'), work: {"id":29299583,"title":"Insights into the effect of CO 2 absorption on the ionic mobility of ionic liquids","created_at":"2016-10-20T07:08:18.231-07:00","url":"https://www.academia.edu/29299583/Insights_into_the_effect_of_CO_2_absorption_on_the_ionic_mobility_of_ionic_liquids?f_ri=33003","dom_id":"work_29299583","summary":"We investigate a comparative effect of CO 2 absorption on the ionic mobility of two choline based ionic liquids comprising two different anions such as threonine and imidazole. The synthesized ionic liquids were characterized using 1 H and 13 C NMR and other spectroscopic techniques. By keeping a common cation and changing the anion from threonine to imidazole both the viscosity and density reduced drastically. We found that [N 1,1,6,2OH ][Imi] exhibits the highest CO 2 capture capacity at 20 1C of 5.27 mol of CO 2 per kg of ionic liquid (1.27 mol of CO 2 per mol of ionic liquid, 23.26 wt% of CO 2) whereas [N 1,1,6,2OH ][Threo] exhibits 3.6 mol of CO 2 per kg of ionic liquid (1.05 mol of CO 2 per mol of ionic liquid, 15.87 wt% of CO 2). The activation energy for diffusion is calculated using the Vogel-Fulcher-Tamman (VFT) equation in the form of diffusivity. It was found that the activation energy for the diffusion of [N 1,1,6,2OH ][Threo] is B10 times higher than that of [N 1,1,6,2OH ][Imi]. 1 H diffusion NMR data revealed that the diffusivity of [N 1,1,6,2OH ][Imi] is increased after CO 2 absorption whereas a decrease in diffusivity was observed in the case of [N 1,1,6,2OH ][Threo]. This anomalous behavior of [N 1,1,6,2OH ][Imi] was further explained by using DFT calculations.","downloadable_attachments":[{"id":49740999,"asset_id":29299583,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":658981,"first_name":"Shubhankar","last_name":"Bhattacharyya","domain_name":"ri-se","page_name":"ShubhankarBhattacharyya","display_name":"Shubhankar Bhattacharyya","profile_url":"https://ri-se.academia.edu/ShubhankarBhattacharyya?f_ri=33003","photo":"/images/s65_no_pic.png"}],"research_interests":[{"id":33003,"name":"Ionic Liquids","url":"https://www.academia.edu/Documents/in/Ionic_Liquids?f_ri=33003","nofollow":false},{"id":43832,"name":"CO2 capture and storage","url":"https://www.academia.edu/Documents/in/CO2_capture_and_storage?f_ri=33003","nofollow":false},{"id":115319,"name":"Carbon Capture and Storage","url":"https://www.academia.edu/Documents/in/Carbon_Capture_and_Storage?f_ri=33003","nofollow":false}]}, }) } 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href="https://www.academia.edu/Documents/in/Chemical_Engineering">Chemical Engineering</a>, <script data-card-contents-for-ri="72" type="text/json">{"id":72,"name":"Chemical Engineering","url":"https://www.academia.edu/Documents/in/Chemical_Engineering?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="529" href="https://www.academia.edu/Documents/in/Quantum_Chemistry">Quantum Chemistry</a>, <script data-card-contents-for-ri="529" type="text/json">{"id":529,"name":"Quantum Chemistry","url":"https://www.academia.edu/Documents/in/Quantum_Chemistry?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="2215" href="https://www.academia.edu/Documents/in/Water">Water</a>, <script data-card-contents-for-ri="2215" type="text/json">{"id":2215,"name":"Water","url":"https://www.academia.edu/Documents/in/Water?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="3586" href="https://www.academia.edu/Documents/in/VLE">VLE</a><script data-card-contents-for-ri="3586" type="text/json">{"id":3586,"name":"VLE","url":"https://www.academia.edu/Documents/in/VLE?f_ri=33003","nofollow":false}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=6384076]'), work: {"id":6384076,"title":"Evaluation of COSMO-RS for the prediction of LLE and VLE of alcohols + ionic liquids","created_at":"2014-03-12T02:02:47.365-07:00","url":"https://www.academia.edu/6384076/Evaluation_of_COSMO_RS_for_the_prediction_of_LLE_and_VLE_of_alcohols_ionic_liquids?f_ri=33003","dom_id":"work_6384076","summary":null,"downloadable_attachments":[{"id":33197355,"asset_id":6384076,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":10006796,"first_name":"Mara","last_name":"Freire","domain_name":"independent","page_name":"MaraFreire","display_name":"Mara 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sciences","url":"https://www.academia.edu/Documents/in/Physical_sciences?f_ri=33003"},{"id":161176,"name":"The","url":"https://www.academia.edu/Documents/in/The?f_ri=33003"},{"id":260118,"name":"CHEMICAL SCIENCES","url":"https://www.academia.edu/Documents/in/CHEMICAL_SCIENCES?f_ri=33003"},{"id":263252,"name":"Anions","url":"https://www.academia.edu/Documents/in/Anions?f_ri=33003"},{"id":958106,"name":"Salts","url":"https://www.academia.edu/Documents/in/Salts?f_ri=33003"},{"id":1242504,"name":"Molecular Dynamic Simulation","url":"https://www.academia.edu/Documents/in/Molecular_Dynamic_Simulation?f_ri=33003"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_6523155" data-work_id="6523155" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/6523155/Ionic_liquids_as_alternative_co_solvents_for_laccase_Study_of_enzyme_activity_and_stability">Ionic liquids as alternative co-solvents for laccase: Study of enzyme activity and stability</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The activity and stability of commercial laccase (DeniLite base) in three different water soluble ionic liquids (ILs) (1-ethyl-3-methylimidazolium 2-(2-methoxyethoxy) ethylsulfate, [emim][MDEGSO4], 1-ethyl-3-methylimidazolium... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_6523155" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The activity and stability of commercial laccase (DeniLite base) in three different water soluble ionic liquids (ILs) (1-ethyl-3-methylimidazolium 2-(2-methoxyethoxy) ethylsulfate, [emim][MDEGSO4], 1-ethyl-3-methylimidazolium ethylsulfate, [emim][EtSO4], and 1-ethyl-3-methylimidazolium methanesulfonate, [emim][MeSO3]) have been studied and compared to that in two organic solvents (acetonitrile and dimethyl sulfoxide). Initial enzyme activities were similar among the ILs if the same conditions were used. A high reduction on initial enzyme activity was found with acidic pH (5.0). The effect of pH and solvent concentration on enzyme stability were investigated in more detail for 1 week. The enzyme maintained a high stability at pH 9.0 for all ILs tested. [emim][MDEGSO4] was the most promising IL for laccase with an activity loss of about 10% after 7 days of incubation. The kinetic studies in the presence of ABTS as substrate allowed to calculate the Michaelis– Menten parameters. Good agreement was found between experimental data and calculated values using the Michaelis–Menten mechanism, with a total average relative deviation of 2.1%. Biotechnol. Biotechnol. Bioeng. 2008;101: 201–207. © 2008 Wiley Periodicals, Inc.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/6523155" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="6e4ad85f705bbcf4865a82eb8d35bfdc" rel="nofollow" data-download="{"attachment_id":48826350,"asset_id":6523155,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/48826350/download_file?st=MTczMzA4NDk4MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="10430466" href="https://independent.academia.edu/AnaTavares7">Ana Tavares</a><script data-card-contents-for-user="10430466" type="text/json">{"id":10430466,"first_name":"Ana","last_name":"Tavares","domain_name":"independent","page_name":"AnaTavares7","display_name":"Ana Tavares","profile_url":"https://independent.academia.edu/AnaTavares7?f_ri=33003","photo":"https://0.academia-photos.com/10430466/9525738/10611932/s65_ana.tavares.jpg_oh_87b5cd12dadc10c639ea213007577bf9_oe_55eb31c3___gda___1442262696_9a4d596526ff5f342384fff112a4a2b8"}</script></span></span></li><li class="js-paper-rank-work_6523155 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="6523155"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 6523155, container: ".js-paper-rank-work_6523155", }); 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Initial enzyme activities were similar among the ILs if the same conditions were used. A high reduction on initial enzyme activity was found with acidic pH (5.0). The effect of pH and solvent concentration on enzyme stability were investigated in more detail for 1 week. The enzyme maintained a high stability at pH 9.0 for all ILs tested. [emim][MDEGSO4] was the most promising IL for laccase with an activity loss of about 10% after 7 days of incubation. The kinetic studies in the presence of ABTS as substrate allowed to calculate the Michaelis– Menten parameters. Good agreement was found between experimental data and calculated values using the Michaelis–Menten mechanism, with a total average relative deviation of 2.1%. Biotechnol. Biotechnol. Bioeng. 2008;101: 201–207. © 2008 Wiley Periodicals, Inc.","downloadable_attachments":[{"id":48826350,"asset_id":6523155,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":10430466,"first_name":"Ana","last_name":"Tavares","domain_name":"independent","page_name":"AnaTavares7","display_name":"Ana Tavares","profile_url":"https://independent.academia.edu/AnaTavares7?f_ri=33003","photo":"https://0.academia-photos.com/10430466/9525738/10611932/s65_ana.tavares.jpg_oh_87b5cd12dadc10c639ea213007577bf9_oe_55eb31c3___gda___1442262696_9a4d596526ff5f342384fff112a4a2b8"}],"research_interests":[{"id":4987,"name":"Kinetics","url":"https://www.academia.edu/Documents/in/Kinetics?f_ri=33003","nofollow":false},{"id":5398,"name":"Biotechnology","url":"https://www.academia.edu/Documents/in/Biotechnology?f_ri=33003","nofollow":false},{"id":16215,"name":"Ionic Liquid","url":"https://www.academia.edu/Documents/in/Ionic_Liquid?f_ri=33003","nofollow":false},{"id":25600,"name":"Stability","url":"https://www.academia.edu/Documents/in/Stability?f_ri=33003","nofollow":false},{"id":28235,"name":"Multidisciplinary","url":"https://www.academia.edu/Documents/in/Multidisciplinary?f_ri=33003"},{"id":33003,"name":"Ionic Liquids","url":"https://www.academia.edu/Documents/in/Ionic_Liquids?f_ri=33003"},{"id":69542,"name":"Computer Simulation","url":"https://www.academia.edu/Documents/in/Computer_Simulation?f_ri=33003"},{"id":203963,"name":"Laccase","url":"https://www.academia.edu/Documents/in/Laccase?f_ri=33003"},{"id":583568,"name":"Enzyme activity","url":"https://www.academia.edu/Documents/in/Enzyme_activity?f_ri=33003"},{"id":1745595,"name":"Solvents","url":"https://www.academia.edu/Documents/in/Solvents?f_ri=33003"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_28296423" data-work_id="28296423" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/28296423/Adsorption_of_phenols_from_contaminated_water_through_titania_silica_mixed_imidazolium_based_ionic_liquid_Equilibrium_kinetic_and_thermodynamic_modeling_studies">Adsorption of phenols from contaminated water through titania-silica mixed imidazolium based ionic liquid: Equilibrium, kinetic and thermodynamic modeling studies</a></div></div><div class="u-pb4x u-mt3x"><div class="summary u-fs14 u-fw300 u-lineHeight1_5 u-tcGrayDarkest"><div class="summarized">The present study describes the synthesis and characterization of titania-silica mixed imidazolium based ionic liquid (Ti-Si-IL) as well as evaluation of its adsorption behavior towards the 2,4-dinitrophenol (2,4-DNP) and... <a class="more_link u-tcGrayDark u-linkUnstyled" data-container=".work_28296423" data-show=".complete" data-hide=".summarized" data-more-link-behavior="true" href="#">more</a></div><div class="complete hidden">The present study describes the synthesis and characterization of titania-silica mixed imidazolium based ionic liquid (Ti-Si-IL) as well as evaluation of its adsorption behavior towards the 2,4-dinitrophenol (2,4-DNP) and 2,4,6-trichlorophenol (2,4,6-TCP). Synthesized Ti-Si-IL adsorbent was characterized by Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FESEM), BET surface area Brunauer-Emmett-Teller (BET), thermogravimetric analysis (TGA) and elemental analysis (CHN). The adsorption of 2,4-DNP and 2,4,6-TCP on Ti-Si-IL was investigated systematically by evaluating the effects of adsorbent dosage, initial pH, contact time and temperature. Satisfactory adsorption 95% and 65% for 2,4-DNP and 2,4,6-TCP was observed at pH 4 and 6, respectively. The kinetic results for 2,4-DNP and 2,4,6-TCP on Ti-Si-IL indicated that the kinetic data follows pseudo-second-order model (R2 = 0.9985 and 0.9750, respectively). Adsorption isotherms were fitted well by the Langmuir model for 2,4-DNP (qm = 44.64 mg g−1 at 318 K) and Freundlich model for 2,4,6-TCP (KF = 0.63 mg g−1 at 318 K). The +ΔH° and -ΔG° values demonstrated that the adsorption of 2,4-DNP was endothermic and spontaneous in nature. While the -ΔH° and +ΔG° values for 2,4,6-TCP adsorption demonstrated exothermic and comparatively nonspontaneous. During the removal process, the role of different functional groups, cyclic structure was monitored and found that the ionic property as well as π-π interactions of host molecules played important role in the extent of adsorption.</div></div></div><ul class="InlineList u-ph0x u-fs13"><li class="InlineList-item logged_in_only"><div class="share_on_academia_work_button"><a class="academia_share Button Button--inverseBlue Button--sm js-bookmark-button" data-academia-share="Work/28296423" data-share-source="work_strip" data-spinner="small_white_hide_contents"><i class="fa fa-plus"></i><span class="work-strip-link-text u-ml1x" data-content="button_text">Bookmark</span></a></div></li><li class="InlineList-item"><div class="download"><a id="ccf03a3eb9ac347d1b88f17a9fe4a309" rel="nofollow" data-download="{"attachment_id":48629349,"asset_id":28296423,"asset_type":"Work","always_allow_download":false,"track":null,"button_location":"work_strip","source":null,"hide_modal":null}" class="Button Button--sm Button--inverseGreen js-download-button prompt_button doc_download" href="https://www.academia.edu/attachments/48629349/download_file?st=MTczMzA4NDk4MCw4LjIyMi4yMDguMTQ2&s=work_strip"><i class="fa fa-arrow-circle-o-down fa-lg"></i><span class="u-textUppercase u-ml1x" data-content="button_text">Download</span></a></div></li><li class="InlineList-item"><ul class="InlineList InlineList--bordered u-ph0x"><li class="InlineList-item InlineList-item--bordered"><span class="InlineList-item-text">by <span itemscope="itemscope" itemprop="author" itemtype="https://schema.org/Person"><a class="u-tcGrayDark u-fw700" data-has-card-for-user="1145972" href="https://malaya.academia.edu/SBAKHSHAEI">SHABNAM BAKHSHAEI</a><script data-card-contents-for-user="1145972" type="text/json">{"id":1145972,"first_name":"SHABNAM","last_name":"BAKHSHAEI","domain_name":"malaya","page_name":"SBAKHSHAEI","display_name":"SHABNAM BAKHSHAEI","profile_url":"https://malaya.academia.edu/SBAKHSHAEI?f_ri=33003","photo":"https://0.academia-photos.com/1145972/1955915/12445296/s65_shabnam.bakhshaei.jpg"}</script></span></span></li><li class="js-paper-rank-work_28296423 InlineList-item InlineList-item--bordered hidden"><span class="js-paper-rank-view hidden u-tcGrayDark" data-paper-rank-work-id="28296423"><i class="u-m1x fa fa-bar-chart"></i><strong class="js-paper-rank"></strong></span><script>$(function() { new Works.PaperRankView({ workId: 28296423, container: ".js-paper-rank-work_28296423", }); 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Synthesized Ti-Si-IL adsorbent was characterized by Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FESEM), BET surface area Brunauer-Emmett-Teller (BET), thermogravimetric analysis (TGA) and elemental analysis (CHN). The adsorption of 2,4-DNP and 2,4,6-TCP on Ti-Si-IL was investigated systematically by evaluating the effects of adsorbent dosage, initial pH, contact time and temperature. Satisfactory adsorption 95% and 65% for 2,4-DNP and 2,4,6-TCP was observed at pH 4 and 6, respectively. The kinetic results for 2,4-DNP and 2,4,6-TCP on Ti-Si-IL indicated that the kinetic data follows pseudo-second-order model (R2 = 0.9985 and 0.9750, respectively). Adsorption isotherms were fitted well by the Langmuir model for 2,4-DNP (qm = 44.64 mg g−1 at 318 K) and Freundlich model for 2,4,6-TCP (KF = 0.63 mg g−1 at 318 K). The +ΔH° and -ΔG° values demonstrated that the adsorption of 2,4-DNP was endothermic and spontaneous in nature. While the -ΔH° and +ΔG° values for 2,4,6-TCP adsorption demonstrated exothermic and comparatively nonspontaneous. During the removal process, the role of different functional groups, cyclic structure was monitored and found that the ionic property as well as π-π interactions of host molecules played important role in the extent of adsorption.","downloadable_attachments":[{"id":48629349,"asset_id":28296423,"asset_type":"Work","always_allow_download":false}],"ordered_authors":[{"id":1145972,"first_name":"SHABNAM","last_name":"BAKHSHAEI","domain_name":"malaya","page_name":"SBAKHSHAEI","display_name":"SHABNAM BAKHSHAEI","profile_url":"https://malaya.academia.edu/SBAKHSHAEI?f_ri=33003","photo":"https://0.academia-photos.com/1145972/1955915/12445296/s65_shabnam.bakhshaei.jpg"}],"research_interests":[{"id":522,"name":"Thermodynamics","url":"https://www.academia.edu/Documents/in/Thermodynamics?f_ri=33003","nofollow":false},{"id":4987,"name":"Kinetics","url":"https://www.academia.edu/Documents/in/Kinetics?f_ri=33003","nofollow":false},{"id":33003,"name":"Ionic Liquids","url":"https://www.academia.edu/Documents/in/Ionic_Liquids?f_ri=33003","nofollow":false},{"id":39752,"name":"Adsorption","url":"https://www.academia.edu/Documents/in/Adsorption?f_ri=33003","nofollow":false},{"id":48601,"name":"General Equilibrium","url":"https://www.academia.edu/Documents/in/General_Equilibrium?f_ri=33003"}]}, }) } })();</script></ul></li></ul></div></div><div class="u-borderBottom1 u-borderColorGrayLighter"><div class="clearfix u-pv7x u-mb0x js-work-card work_28150227" data-work_id="28150227" itemscope="itemscope" itemtype="https://schema.org/ScholarlyArticle"><div class="header"><div class="title u-fontSerif u-fs22 u-lineHeight1_3"><a class="u-tcGrayDarkest js-work-link" href="https://www.academia.edu/28150227/Synthesis_and_crystal_structure_of_N_phenyl_N_pyridin_2_ylmethyl_S_methyl_thiouronium_iodide">Synthesis and crystal structure of N-phenyl-N′-(pyridin-2-ylmethyl)-S-methyl-thiouronium iodide</a></div></div><div class="u-pb4x u-mt3x"></div><ul 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data-has-card-for-ri="16215" href="https://www.academia.edu/Documents/in/Ionic_Liquid">Ionic Liquid</a>, <script data-card-contents-for-ri="16215" type="text/json">{"id":16215,"name":"Ionic Liquid","url":"https://www.academia.edu/Documents/in/Ionic_Liquid?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="33003" href="https://www.academia.edu/Documents/in/Ionic_Liquids">Ionic Liquids</a>, <script data-card-contents-for-ri="33003" type="text/json">{"id":33003,"name":"Ionic Liquids","url":"https://www.academia.edu/Documents/in/Ionic_Liquids?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="50630" href="https://www.academia.edu/Documents/in/Crystal_structure">Crystal structure</a>, <script data-card-contents-for-ri="50630" type="text/json">{"id":50630,"name":"Crystal structure","url":"https://www.academia.edu/Documents/in/Crystal_structure?f_ri=33003","nofollow":false}</script><a class="InlineList-item-text" data-has-card-for-ri="151091" href="https://www.academia.edu/Documents/in/Nitrogen">Nitrogen</a><script data-card-contents-for-ri="151091" type="text/json">{"id":151091,"name":"Nitrogen","url":"https://www.academia.edu/Documents/in/Nitrogen?f_ri=33003","nofollow":false}</script></span></li><script>(function(){ if (true) { new Aedu.ResearchInterestListCard({ el: $('*[data-has-card-for-ri-list=28150227]'), work: {"id":28150227,"title":"Synthesis and crystal structure of N-phenyl-N′-(pyridin-2-ylmethyl)-S-methyl-thiouronium 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