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(PDF) KD 4.2 KIMIA | Nurul Auliyah - Academia.edu

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Reaksi Reversible dan Irreversible Berdasarkan arahnya, reaksi kimia dapat dibagi atas dua yaitu sebagai berikut. 1. Reaksi berkesudahan disebut reaksi irreversible (satu arah). Hasil reaksi tidak dapat diubah lagi menjadi zat pereaksi yang artinya zat yang direaksikan habis dan terbentuk zat baru Ciri-ciri reaksi satu arah sebagai berikut : • Reaksi ditulis dengan satu anak panah (→) • Reaksi berlansung satu arah dari kiri ke kanan. • Zat hasil reaksi tidak dapat dikembalikan seperti zat mula-mula. • Reaksi baru berhenti apabila salah satu atau semua reaktan habis. Contoh: 1. NaOH (aq) + HCl (aq) → NaCl (aq) + H 2 O (l) Pada reaksi tersebut NaOH habis bereaksi denagn HCl membentuk NaCl dan air. NaCl dan air tidak dapat bereaksi kembali menjadi NaOH dan HCl. 2. Mg (s) + 2 HCl (aq) → MgCl 2(aq) + H 2(g) Mg habis bereaksi denagn HCl membentuk MgCl2 dan gas H2. MgCl2 dan H 2 tidak dapat bereaksi kembali membentuk Mg dan HCl. 2. Reaksi kesetimbangan disebut reaksi reversible (reaksi dua arah). Reaksi yang dapat berlangsung dalam dua arah disebut reaksi dapat balik. Yang dimaksud dengan reaksi reversible adalah zat-zat hasil reaksi dapat bereaksi kembali membentuk zat pereaksi. Ciri-ciri reaksi bolak-balik sebagai berikut :</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;KESETIMBANGAN KIMIA&quot;,&quot;attachmentId&quot;:47726338,&quot;attachmentType&quot;:&quot;docx&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/27468590/KESETIMBANGAN_KIMIA&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/27468590/KESETIMBANGAN_KIMIA"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="8" data-entity-id="29910103" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/29910103/KIMIA_ORGANIK_II">KIMIA ORGANIK II</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="17601438" href="https://unmul.academia.edu/NauvalFadillah">Nauval Fadillah</a></div><p class="ds-related-work--abstract ds2-5-body-sm">semoga laporan ini dapat membantu kawan-kawan semua. khusus untuk kawan-kawan dari KIMIA FMIPA UNMUL. silahkan laporan ini dibaca sebagai refrensi bahan belajar. saya melarang keras KALIAN MENJIPLAK 100%.</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;KIMIA ORGANIK II&quot;,&quot;attachmentId&quot;:50371863,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/29910103/KIMIA_ORGANIK_II&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/29910103/KIMIA_ORGANIK_II"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div><div class="ds-related-work--container js-wsj-grid-card" data-collection-position="9" data-entity-id="38565946" data-sort-order="default"><a class="ds-related-work--title js-wsj-grid-card-title ds2-5-body-md ds2-5-body-link" href="https://www.academia.edu/38565946/KIM_2_1_KESETIMBANGAN_KIMIA">KIM 2 1 KESETIMBANGAN KIMIA</a><div class="ds-related-work--metadata"><a class="js-wsj-grid-card-author ds2-5-body-sm ds2-5-body-link" data-author-id="105294030" href="https://independent.academia.edu/ew186">e w</a></div><p class="ds-related-work--metadata ds2-5-body-xs">Materi Kesetimbangan Kimia , 2019</p><p class="ds-related-work--abstract ds2-5-body-sm">Reaksi satu arah (irreversible) atau reaksi tidak dapat balik adalah reaksi yang terjadi pada satu arah, dan produknya tidak dapat kembali menjadi reaktan. Reaksi bolak-balik (reversible) atau reaksi dapat balik adalah reaksi yang terjadi pada dua arah yang berlawanan dalam waktu bersamaan. Dalam reaksi bolak-balik, produk dapat berubah menjadi reaktan, dan reaktan dapat berubah menjadi produk (menjadi reaksi yang berlawanan). Pada kesetimbangan kimia, hanya ada penyebutan zat di sebelah kiri dan di sebelah kanan. Reaksi bolak-balik dinyatakan dengan dua panah yang berlawanan arah, menyatakan reaksi maju (ke kanan) dan reaksi balik (ke kiri). Contoh: Diketahui perubahan air menjadi uap air dapat balik, sehingga reaksi dapat ditulis H2O(l) → H2O(g) H2O(l) qe H2O(g) H2O(g) → H2O(l) Reaksi bolak-balik sempurna terjadi dalam sistem tertutup, karena tidak terjadi penambahan atau pengeluaran zat, keluarnya panas/kalor dari sistem, hilangnya gas yang terbentuk, dan sebagainya. Reaksi dikatakan setimbang atau mencapai kesetimbangan apabila: 1) Reaksi bolak-balik yang mengandung zat berwujud gas terjadi dalam sistem tertutup. 2) Ketika konsentrasi seluruh zat nilainya tetap. 3) Ketika laju reaksi maju (v1) sama dengan laju reaksi balik (v2). Contoh: Pada reaksi kesetimbangan berikut, N2(g) + 3H2(g) qe 2NH3(g) keadaan setimbang terjadi ketika: Pada kesetimbangan kimia, ikatan akan terputus atau terbentuk seiring dengan maju-mundurnya atom di antara molekul reaktan dan produk. Kesetimbangan kimia bersifat dinamis karena walaupun keadaan sudah setimbang, reaksi tetap berlangsung pada tingkat mikroskopis (molekul). Reaksi mikroskopis tidak tampak karena v1 sama dengan v2, sehingga seakan-akan reaksi sudah berhenti. Kesetimbangan kimia dibagi menjadi dua: 1) Kesetimbangan homogen (satu wujud/fase) Contoh: Gas N2(g) + 3H2(g) qe 2NH3(g) 2SO2(g) + O2(g) qe 2SO3(g) Larutan H2O(l) qe H + (aq) + OH-(aq) NH4OH(aq) qe NH4 + (aq) + OH-(aq) CH3COOH(aq) qe CH3COO-(aq)+ H + (aq) 2) Kesetimbangan heterogen (lebih dari satu fase) Contoh: Dua fase CaCO3(s)qe CaO(s) + CO2(g) Ag2CrO4(s)qe 2Ag + (aq)+CrO4 2-(aq) BaSO4(s)qe Ba 2+ (aq) + SO4 2-(aq) Tiga fase Ca(HCO3)2(aq)qe CaCO3(s)+ H2O(l) + CO2(g) B. REAKSI KESETIMBANGAN Kesetimbangan disosiasi adalah reaksi kesetimbangan yang menguraikan suatu zat menjadi zat lain, dan reaksi baliknya adalah kesetimbangan asosiasi/pembentukan. Derajat disosiasi adalah perbandingan jumlah mol terdisosiasi (bereaksi) dengan jumlah mol zat sebelum terdisosiasi (mula-mula). konsentrasi waktu H2 NH3 N2 setimbang laju reaksi waktu V1 V2 setimbang V1 = V2 α = jumlah zat terdisosiasi jumlah zat awal</p><div class="ds-related-work--ctas"><button class="ds2-5-text-link ds2-5-text-link--inline js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;wsj-grid-card-download-pdf-modal&quot;,&quot;work_title&quot;:&quot;KIM 2 1 KESETIMBANGAN KIMIA&quot;,&quot;attachmentId&quot;:58638780,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;work_url&quot;:&quot;https://www.academia.edu/38565946/KIM_2_1_KESETIMBANGAN_KIMIA&quot;,&quot;alternativeTracking&quot;:true}"><span class="material-symbols-outlined" style="font-size: 18px" translate="no">download</span><span class="ds2-5-text-link__content">Download free PDF</span></button><a class="ds2-5-text-link ds2-5-text-link--inline js-wsj-grid-card-view-pdf" href="https://www.academia.edu/38565946/KIM_2_1_KESETIMBANGAN_KIMIA"><span class="ds2-5-text-link__content">View PDF</span><span class="material-symbols-outlined" style="font-size: 18px" translate="no">chevron_right</span></a></div></div></div></div><div class="ds-sticky-ctas--wrapper js-loswp-sticky-ctas hidden"><div class="ds-sticky-ctas--grid-container"><div class="ds-sticky-ctas--container"><button class="ds2-5-button js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;continue-reading-button--sticky-ctas&quot;,&quot;attachmentId&quot;:90136041,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;workUrl&quot;:null}">See full PDF</button><button class="ds2-5-button ds2-5-button--secondary js-swp-download-button" data-signup-modal="{&quot;location&quot;:&quot;download-pdf-button--sticky-ctas&quot;,&quot;attachmentId&quot;:90136041,&quot;attachmentType&quot;:&quot;pdf&quot;,&quot;workUrl&quot;:null}"><span class="material-symbols-outlined" style="font-size: 20px" translate="no">download</span>Download PDF</button></div></div></div><div class="ds-below-fold--grid-container"><div class="ds-work--container js-loswp-embedded-document"><div class="attachment_preview" data-attachment="Attachment_90136041" style="display: none"><div class="js-scribd-document-container"><div class="scribd--document-loading js-scribd-document-loader" style="display: block;"><img alt="Loading..." src="//a.academia-assets.com/images/loaders/paper-load.gif" /><p>Loading Preview</p></div></div><div style="text-align: center;"><div class="scribd--no-preview-alert js-preview-unavailable"><p>Sorry, preview is currently unavailable. 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