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organic frameworks (LOFs)</title> <meta name="description" content="Search results for: lanthanoids organic frameworks (LOFs)"> <meta name="keywords" content="lanthanoids organic frameworks (LOFs)"> <meta name="viewport" content="width=device-width, initial-scale=1, minimum-scale=1, maximum-scale=1, user-scalable=no"> <meta charset="utf-8"> <link href="https://cdn.waset.org/favicon.ico" type="image/x-icon" rel="shortcut icon"> <link href="https://cdn.waset.org/static/plugins/bootstrap-4.2.1/css/bootstrap.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/plugins/fontawesome/css/all.min.css" rel="stylesheet"> <link href="https://cdn.waset.org/static/css/site.css?v=150220211555" rel="stylesheet"> </head> <body> <header> <div class="container"> <nav class="navbar navbar-expand-lg navbar-light"> <a class="navbar-brand" href="https://waset.org"> <img src="https://cdn.waset.org/static/images/wasetc.png" alt="Open Science Research Excellence" title="Open Science Research 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method="get" action="https://publications.waset.org/abstracts/search"> <div id="custom-search-input"> <div class="input-group"> <i class="fas fa-search"></i> <input type="text" class="search-query" name="q" placeholder="Author, Title, Abstract, Keywords" value="lanthanoids organic frameworks (LOFs)"> <input type="submit" class="btn_search" value="Search"> </div> </div> </form> </div> </div> <div class="row mt-3"> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Commenced</strong> in January 2007</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Frequency:</strong> Monthly</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Edition:</strong> International</div> </div> </div> <div class="col-sm-3"> <div class="card"> <div class="card-body"><strong>Paper Count:</strong> 3177</div> </div> </div> </div> <h1 class="mt-3 mb-3 text-center" style="font-size:1.6rem;">Search results for: lanthanoids organic frameworks (LOFs)</h1> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3177</span> Study of Lanthanoide Organic Frameworks Properties and Synthesis: Multicomponent Ligands</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ayla%20Roberta%20Galaco">Ayla Roberta Galaco</a>, <a href="https://publications.waset.org/abstracts/search?q=Juliana%20Fonseca%20De%20Lima"> Juliana Fonseca De Lima</a>, <a href="https://publications.waset.org/abstracts/search?q=Osvaldo%20Antonio%20Serra"> Osvaldo Antonio Serra</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Coordination polymers, also known as metal-organic frameworks (MOFs) or lanthanoide organic frameworks (LOFs) have been reported due of their promising applications in gas storage, separation, catalysis, luminescence, magnetism, drug delivery, and so on. As a type of organic–inorganic hybrid materials, the properties of coordination polymers could be chosen by deliberately selecting the organic and inorganic components. LOFs have received considerable attention because of their properties such as porosity, luminescence, and magnetism. Methods such as solvothermal synthesis are important as a strategy to control the structural and morphological properties as well as the composition of the target compounds. In this work the first solvothermal synthesis was employed to obtain the compound [Y0.4,Yb0.4,Er0.2(dmf)(for)(H2O)(tft)], by using terephthalic acid (tft) and oxalic acid, decomposed in formate (for), as ligands; Yttrium, Ytterbium and, Erbium as metal centers, in DMF and water for 4 days under 160 °C. The semi-rigid terephthalic acid (dicarboxylic) coordinates with Ln3+ ions and also is possible to form a polyfunctional bridge. On the other hand, oxalate anion has no high-energy vibrational groups, which benefits the excitation of Yb3+ in upconversion process. It was observed that the compounds with water molecules in the coordination sphere of the lanthanoide ions cause lower crystalline properties and change the structure of the LOF (1D, 2D, 3D). In the FTIR, the bands at 1589 and 1500 cm-1 correspond to the asymmetric stretching vibration of –COO. The band at 1383 cm-1 is assigned to the symmetric stretching vibration of –COO. Single crystal X-ray diffraction study reveals an infinite 3D coordination framework that crystalizes in space group P21/c. The other three products, [TR(chel)(ofd)0,5(H2O)2], where TR= Eu3+, Y3, and Yb3+/Er3+ were obtained by using 1, 2-phenylenedioxydiacetic acid (ofd) and chelidonic acid (chel) as organic ligands. Thermal analysis shows that the lanthanoide organic frameworks do not collapse at temperatures below 250 °C. By the polycrystalline X-ray diffraction patterns (PXRD) it was observed that the compounds with Eu3+, Y3+, and Yb3+/Er3+ ions are isostructural. From PXRD patterns, high crystallinity can be noticed for the complexes. The final products were characterized by single X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), energy dispersive spectroscopy (EDS) and thermogravimetric analysis (TGA). The X-ray diffraction (XRD) is an effective method to investigate crystalline properties of synthesized materials. The solid crystal obtained in the synthesis show peaks at 2θ < 10°, indicating the MOF formation. The chemical composition of LOFs was also confirmed by EDS. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=isostructural" title="isostructural">isostructural</a>, <a href="https://publications.waset.org/abstracts/search?q=lanthanoids" title=" lanthanoids"> lanthanoids</a>, <a href="https://publications.waset.org/abstracts/search?q=lanthanoids%20organic%20frameworks%20%28LOFs%29" title=" lanthanoids organic frameworks (LOFs)"> lanthanoids organic frameworks (LOFs)</a>, <a href="https://publications.waset.org/abstracts/search?q=metal%20organic%20frameworks%20%20%28MOFs%29" title=" metal organic frameworks (MOFs)"> metal organic frameworks (MOFs)</a>, <a href="https://publications.waset.org/abstracts/search?q=thermogravimetry" title=" thermogravimetry"> thermogravimetry</a>, <a href="https://publications.waset.org/abstracts/search?q=X-Ray%20diffraction" title=" X-Ray diffraction"> X-Ray diffraction</a> </p> <a href="https://publications.waset.org/abstracts/65646/study-of-lanthanoide-organic-frameworks-properties-and-synthesis-multicomponent-ligands" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/65646.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">260</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3176</span> Temperature Effects on CO₂ Intake of MIL-101 and ZIF-301</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=M.%20Ba-Shammakh">M. Ba-Shammakh</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Metal-organic frameworks (MOFs) are promising materials for CO₂ capture and they have high adsorption capacity towards CO₂. In this study, two different metal organic frameworks (i.e. MIL-101 and ZIF-301) were tested for different flue gases that have different CO₂ fractions. In addition, the effect of temperature was investigated for MIL-101 and ZIF-301. The results show that MIL-101 performs well for pure CO₂ stream while its intake decreases dramatically for other flue gases that have variable CO₂ fraction ranging from 5 to 15 %. The second material (ZIF-301) showed a better result in all flue gases and higher CO₂ intake compared to MIL-101 even at high temperature. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=CO%E2%82%82%20capture" title="CO₂ capture">CO₂ capture</a>, <a href="https://publications.waset.org/abstracts/search?q=Metal%20Organic%20Frameworks%20%28MOFs%29" title=" Metal Organic Frameworks (MOFs)"> Metal Organic Frameworks (MOFs)</a>, <a href="https://publications.waset.org/abstracts/search?q=MIL-101" title=" MIL-101"> MIL-101</a>, <a href="https://publications.waset.org/abstracts/search?q=ZIF-301" title=" ZIF-301"> ZIF-301</a> </p> <a href="https://publications.waset.org/abstracts/73035/temperature-effects-on-co2-intake-of-mil-101-and-zif-301" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/73035.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">198</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3175</span> Catalytic Applications of Metal-Organic Frameworks for Organic Pollutant Removal in Wastewater Treatment: A Review</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Matthew%20Ndubuisi%20Abonyi">Matthew Ndubuisi Abonyi</a>, <a href="https://publications.waset.org/abstracts/search?q=Christopher%20Chiedozie%20Obi"> Christopher Chiedozie Obi</a>, <a href="https://publications.waset.org/abstracts/search?q=Joseph%20Tagbo%20Nwabanne"> Joseph Tagbo Nwabanne</a> </p> <p class="card-text"><strong>Abstract:</strong></p> This review focuses on the application of Metal-Organic Frameworks (MOF)-based catalysts in the degradation of organic pollutants in wastewater. The degradation of organic pollutants in wastewater remains a critical environmental challenge, necessitating innovative solutions for effective treatment. MOFs have garnered significant attention as promising catalysts for this purpose, owing to their exceptional surface area, tunable porosity, and diverse chemical functionalities. It explores various catalytic mechanisms, including photocatalysis, Fenton-like reactions, and other advanced oxidation processes facilitated by MOFs. The review also explores the design strategies that enhance the catalytic performance of MOFs, such as structural modifications, composite formation, and post-synthetic modifications. Furthermore, real-world case studies are presented, highlighting the practical applications and environmental impact of MOF-based catalysts in wastewater treatment. Challenges associated with the scalability and stability of these materials are discussed, along with future directions for research and development. This review highlights the significant potential of MOF-based catalysts in addressing the pressing issue of water pollution and advocates for continued innovation to optimize their application in wastewater treatment. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=metal-organic%20frameworks%20%28MOFs%29" title="metal-organic frameworks (MOFs)">metal-organic frameworks (MOFs)</a>, <a href="https://publications.waset.org/abstracts/search?q=catalysis" title=" catalysis"> catalysis</a>, <a href="https://publications.waset.org/abstracts/search?q=wastewater%20treatment" title=" wastewater treatment"> wastewater treatment</a>, <a href="https://publications.waset.org/abstracts/search?q=organic%20pollutant%20degradation" title=" organic pollutant degradation"> organic pollutant degradation</a>, <a href="https://publications.waset.org/abstracts/search?q=photocatalysis" title=" photocatalysis"> photocatalysis</a> </p> <a href="https://publications.waset.org/abstracts/190018/catalytic-applications-of-metal-organic-frameworks-for-organic-pollutant-removal-in-wastewater-treatment-a-review" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/190018.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">23</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3174</span> The shaping of Metal-Organic Frameworks for Water Vapor Adsorption</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Tsung-Lin%20Hsieh">Tsung-Lin Hsieh</a>, <a href="https://publications.waset.org/abstracts/search?q=Jiun-Jen%20Chen"> Jiun-Jen Chen</a>, <a href="https://publications.waset.org/abstracts/search?q=Yuhao%20Kang"> Yuhao Kang</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Metal-organic frameworks (MOFs) have drawn scientists’ attention for decades due to its high specific surface area, tunable pore size, and relatively low temperature for regeneration. Bearing with those mentioned properties, MOFs has been widely used in various applications, such as adsorption/separation and catalysis. However, the current challenge for practical use of MOFs is to effectively shape these crystalline powder material into controllable forms such as pellets, granules, and monoliths with sufficient mechanical and chemical stability, while maintaining the excellent properties of MOFs powders. Herein, we have successfully synthesized an Al-based MOF powder which exhibits a high water capacity at relatively low humidity conditions and relatively low temperature for regeneration. Then the synthesized Al-MOF was shaped into granules with particle size of 2-4 mm by (1) tumbling granulation, (2) High shear mixing granulation, and (3) Extrusion techniques. Finally, the water vapor adsorption rate and crush strength of Al-MOF granules by different shaping techniques were measured and compared. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=granulation" title="granulation">granulation</a>, <a href="https://publications.waset.org/abstracts/search?q=granules" title=" granules"> granules</a>, <a href="https://publications.waset.org/abstracts/search?q=metal-organic%20frameworks" title=" metal-organic frameworks"> metal-organic frameworks</a>, <a href="https://publications.waset.org/abstracts/search?q=water%20vapor%20adsorption" title=" water vapor adsorption"> water vapor adsorption</a> </p> <a href="https://publications.waset.org/abstracts/127112/the-shaping-of-metal-organic-frameworks-for-water-vapor-adsorption" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/127112.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">158</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3173</span> Nanoscale Metal-Organic Framework Coated Carbon Nitride Nanosheet for Combination Cancer Therapy</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Rui%20Chen">Rui Chen</a>, <a href="https://publications.waset.org/abstracts/search?q=Jinfeng%20Zhang"> Jinfeng Zhang</a>, <a href="https://publications.waset.org/abstracts/search?q=Chun-Sing%20Lee"> Chun-Sing Lee</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In the past couple of decades, nanoscale metal-organic frameworks (NMOFs) have been highlighted as promising delivery platforms for biomedical applications, which combine many potent features such as high loading capacity, progressive biodegradability and low cytotoxicity. While NMOF has been extensively used as carriers for drugs of different modalities, so far there is no report on exploiting the advantages of NMOF for combination therapy. Herein, we prepared core-shell nanoparticles, where each nanoparticle contains a single graphitic-phase carbon nitride (g-C3N4) nanosheet encapsulated by a zeolitic-imidazolate frameworks-8 (ZIF-8) shell. The g-C3N4 nanosheets are effective visible-light photosensitizer for photodynamic therapy (PDT). When hosting DOX (doxorubicin), the as-synthesized core-shell nanoparticles could realize combinational photo-chemo therapy and provide dual-color fluorescence imaging. Therefore, we expect NMOFs-based core-shell nanoparticles could provide a new way to achieve much-enhanced cancer therapy. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=carbon%20nitride" title="carbon nitride">carbon nitride</a>, <a href="https://publications.waset.org/abstracts/search?q=combination%20therapy" title=" combination therapy"> combination therapy</a>, <a href="https://publications.waset.org/abstracts/search?q=drug%20delivery" title=" drug delivery"> drug delivery</a>, <a href="https://publications.waset.org/abstracts/search?q=nanoscale%20metal-organic%20frameworks" title=" nanoscale metal-organic frameworks"> nanoscale metal-organic frameworks</a> </p> <a href="https://publications.waset.org/abstracts/26681/nanoscale-metal-organic-framework-coated-carbon-nitride-nanosheet-for-combination-cancer-therapy" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/26681.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">425</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3172</span> Microporous 3D Aluminium Metal-Organic Frameworks in Chitosan Based Mixed Matrix Membrane for Ethanol/Water Separation</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Madhan%20Vinu">Madhan Vinu</a>, <a href="https://publications.waset.org/abstracts/search?q=Yue-Chun%20Jiang"> Yue-Chun Jiang</a>, <a href="https://publications.waset.org/abstracts/search?q=Yi-Feng%20Lin"> Yi-Feng Lin</a>, <a href="https://publications.waset.org/abstracts/search?q=Chia-Her%20Lin"> Chia-Her Lin</a> </p> <p class="card-text"><strong>Abstract:</strong></p> An effective approach to enhance the ethanol/water pervaporation of mixed matrix membranes prepared from three microporous aluminium based metal-organic frameworks (MOFs), [Al(OH)(BPDC)] (DUT-5), [Al(OH)(NDC)] (DUT-4) and [Al(OH)(BzPDC)] (CAU-8) have been synthesized by employing solvothermal reactions. Interestingly, all Al-MOFs showed attractive surface area with microporous 12.3, 10.2 and 8.0 Å for DUT-5, DUT-4 and CAU-8 MOFs which are confirmed through N₂ gas sorption measurements. All the microporous compounds are highly stable as confirmed by thermogravimetric analysis and temperature-dependent powder X-ray diffraction measurements. Furthermore, the synthesized microporous MOF particles of DUT-5, DUT-4, and CAU-8 were successfully incorporated into biological chitosan (CS) membranes to form DUT-5@CS, DUT-4@CS, and CAU-8@CS membranes. The different MOF loadings such as 0.1, 0.15, and 0.2 wt% in CS networks have been prepared, and the same were used to separate mixtures of water and ethanol at 25ºC in the pervaporation process. In particular, when 0.15 wt% of DUT-5 was loaded, MOF@CS membrane displayed excellent permeability and selectivity in ethanol/water separation than that of the previous literature. These CS based membranes separation through functionalized microporous MOFs reveals the key governing factors that are essential for designing novel MOF membranes for bioethanol purification. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=metal-organic%20framework" title="metal-organic framework">metal-organic framework</a>, <a href="https://publications.waset.org/abstracts/search?q=microporous%20materials" title=" microporous materials"> microporous materials</a>, <a href="https://publications.waset.org/abstracts/search?q=separation" title=" separation"> separation</a>, <a href="https://publications.waset.org/abstracts/search?q=chitosan%20membranes" title=" chitosan membranes"> chitosan membranes</a> </p> <a href="https://publications.waset.org/abstracts/85380/microporous-3d-aluminium-metal-organic-frameworks-in-chitosan-based-mixed-matrix-membrane-for-ethanolwater-separation" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/85380.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">221</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3171</span> Synthesis, Structural Characterization and Biological Activity of Bis{(E)-1-[(2,4,6-Tribromophenyl) Diazenyl] Naphthalen-2-Olato} Copper (II) Dimethyl Sulfoxide Monosolvate</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Hassiba%20Bougueria">Hassiba Bougueria</a>, <a href="https://publications.waset.org/abstracts/search?q=Nesrine%20Benarous"> Nesrine Benarous</a>, <a href="https://publications.waset.org/abstracts/search?q=Souheyla%20Chetioui"> Souheyla Chetioui</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Azo dyes are one of the most widely used compounds in organic chemistry, primarily due to their relatively simple preparation methods. They have therefore been widely used, in particular as colorants for textiles, printing inks, cosmetics, and food additives. In addition to their use as dyes, azo compounds have attracted much attention from chemists as their potential applications are important in coordination chemistry, metal-organic frameworks (MOF) structures, COF (covalent-organic frameworks), and catalysis. Moreover, they have found many applications in different fields, such as nonlinear optics, optical storage, photoluminescence, and magnetism. The compound bis{(E)-1-[(2,4,6-tribromophenyl)diazenyl]naphthalen-2-olato}copper(II) dimethyl sulfoxide monosolvate, the CuII atom is tetracoordinate with a square-planar geometry, surrounded by two bidentate (E)-1-[(2,4,6-tribromophenyl)diazenyl]naphthalene-2-olate ligands via two N atoms and two O atoms. The O-Cu-O angles and N-Cu-N are of the order of 177.90(16)° and 177.8(2)°, respectively. The distances Cu-O and Cu- N are 1.892(4) Å and 1.976(4) Å, respectively. The cohesion of the crystal is ensured by hydrogen bonds of the C—H…O type and by π=π staking interactions [centroid–centroid distance = 3.679(4)Å]. The DMSO solvent molecule is disordered at two positions with occupancy rates of 0.70 and 0.30. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=azo%20dyes" title="azo dyes">azo dyes</a>, <a href="https://publications.waset.org/abstracts/search?q=DRX" title=" DRX"> DRX</a>, <a href="https://publications.waset.org/abstracts/search?q=structural%20characterization" title=" structural characterization"> structural characterization</a>, <a href="https://publications.waset.org/abstracts/search?q=biological%20activity" title=" biological activity"> biological activity</a> </p> <a href="https://publications.waset.org/abstracts/158136/synthesis-structural-characterization-and-biological-activity-of-bise-1-246-tribromophenyl-diazenyl-naphthalen-2-olato-copper-ii-dimethyl-sulfoxide-monosolvate" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/158136.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">87</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3170</span> Unlocking the Potential of Phosphatic Wastes: Sustainable Valorization Pathways for Synthesizing Functional Metal-Organic Frameworks and Zeolites</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ali%20Mohammed%20Yimer">Ali Mohammed Yimer</a>, <a href="https://publications.waset.org/abstracts/search?q=Ayalew%20H.%20Assen"> Ayalew H. Assen</a>, <a href="https://publications.waset.org/abstracts/search?q=Youssef%20Belmabkhout"> Youssef Belmabkhout</a> </p> <p class="card-text"><strong>Abstract:</strong></p> This study delves into sustainable approaches for valorizing phosphatic wastes, specifically phosphate mining wastes and phosphogypsum, which are byproducts of phosphate industries and pose significant environmental challenges due to their accumulation. We propose a unified strategic synthesis method aimed at converting these wastes into hetero-functional porous materials. Our approach involves isolating the primary components of phosphatic wastes, such as CaO, SiO2 and Al2O3 to fabricate functional porous materials falling into two distinct classes. Firstly, alumina and silica components are extracted or isolated to produce zeolites (including CAN, GIS, SOD, FAU, and LTA), characterized by a Si/Al ratio of less than 5. Secondly, residual calcium is utilized to synthesize calcium-based metal–organic frameworks (Ca-MOFs) employing various organic linkers like Ca-BDC, Ca-BTC and Ca-TCPB (SBMOF-2), thereby providing flexibility in material design. Characterization techniques including XRD, SEM-EDX, FTIR, and TGA-MS affirm successful material assembly, while sorption analyses using N2, CO2, and H2O demonstrate the porosity of the materials. Particularly noteworthy is the water/alcohol separation potential exhibited by the Ca-BTC MOF, owing to its optimal pore aperture size (∼3.4 Å). To enhance replicability and scalability, detailed protocols for each synthesis step and specific conditions for each process are provided, ensuring that the methodology can be easily reproduced and scaled up for industrial applications. This synthetic transformation approach represents a valorization route for converting phosphatic wastes into extended porous structures, promising significant environmental and economic benefits. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=calcium-based%20metal-organic%20frameworks" title="calcium-based metal-organic frameworks">calcium-based metal-organic frameworks</a>, <a href="https://publications.waset.org/abstracts/search?q=low-silica%20zeolites" title=" low-silica zeolites"> low-silica zeolites</a>, <a href="https://publications.waset.org/abstracts/search?q=porous%20materials" title=" porous materials"> porous materials</a>, <a href="https://publications.waset.org/abstracts/search?q=sustainable%20synthesis" title=" sustainable synthesis"> sustainable synthesis</a>, <a href="https://publications.waset.org/abstracts/search?q=valorization" title=" valorization"> valorization</a> </p> <a href="https://publications.waset.org/abstracts/188791/unlocking-the-potential-of-phosphatic-wastes-sustainable-valorization-pathways-for-synthesizing-functional-metal-organic-frameworks-and-zeolites" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/188791.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">38</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3169</span> Adsorption of Dyes and Iodine: Reaching Outstanding Kinetics with CuII-Based Metal–Organic Nanoballs</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Eder%20Amayuelas">Eder Amayuelas</a>, <a href="https://publications.waset.org/abstracts/search?q=Bego%C3%B1a%20Baz%C3%A1n"> Begoña Bazán</a>, <a href="https://publications.waset.org/abstracts/search?q=M.%20Karmele%20Urtiaga"> M. Karmele Urtiaga</a>, <a href="https://publications.waset.org/abstracts/search?q=Gotzone%20Barandika"> Gotzone Barandika</a>, <a href="https://publications.waset.org/abstracts/search?q=Mar%C3%ADa%20I.%20Arriortua"> María I. Arriortua</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Metal Organic Frameworks (MOFs) have attracted great interest in recent years, taking a lead role in the field of catalysis, drug delivery, sensors and absorption. In the past decade, promising results have been reported specifically in the field of adsorption, based on the topology and chemical features of this type of porous material. Thus, its application in industry and environment for the adsorption of pollutants is presented as a response to an increasingly important need. In this area, organic dyes are nowadays widely used in many industries including medicine, textile, leather, printing and plastics. The consequence of this fact is that dyes are present as emerging pollutants in soils and water where they remain for long periods of time due to their high stability, with a potential risk of toxicity in wildlife and in humans. On the other hand, the presence of iodine in soils, water and gas as a nuclear activity pollutant product or its extended use as a germicide is still a problem in many countries, which indicates the imperative need for its removal. In this context, this work presents the characterization as an adsorbent of the activated compound αMOP@Ei2-1 obtained from the already reported [Cu₂₄(m-BDC)₂₄(DMF)₂₀(H₂O)₄]•24DMF•40H₂O (MOP@Ei2-1), where m-BDC is the 1,3-benzenedicarboxylic ligand and DMF is N,N′-dimethylformamide. The structure of MOP@Ei2-1 consists of Cu24 clusters arranged in such a way that 12 paddle-wheels are connected through m-BDC ligands. The clusters exhibit an internal cavity where crystallization molecules of DMF and water are located. Adsorption of dyes and iodine as pollutant examples has been carried out, focusing attention on the kinetics of the rapid process. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=adsorption" title="adsorption">adsorption</a>, <a href="https://publications.waset.org/abstracts/search?q=organic%20dyes" title=" organic dyes"> organic dyes</a>, <a href="https://publications.waset.org/abstracts/search?q=iodine" title=" iodine"> iodine</a>, <a href="https://publications.waset.org/abstracts/search?q=metal%20organic%20frameworks" title=" metal organic frameworks"> metal organic frameworks</a> </p> <a href="https://publications.waset.org/abstracts/48201/adsorption-of-dyes-and-iodine-reaching-outstanding-kinetics-with-cuii-based-metal-organic-nanoballs" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/48201.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">276</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3168</span> Moisture Resistant K-loaded ZIF-8 Catalyst for Glycerol Carbonate Production</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Anshu%20Tyagi">Anshu Tyagi</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Zeolitic imidazolate frameworks (ZIFs), a subclass of metal-organic frameworks (MOFs) with structures resembling aluminosilicate zeolites, are gaining significant attention due to their unique properties. ZIF-8, in particular, has shown high surface area and enhanced hydrophobicity, making it a promising candidate for catalytic applications. In this study, ZIF-8 was synthesized in an aqueous medium by mixing 2-methylimidazole (mIm) with zinc nitrate hexahydrate (Zn) in deionized water. To improve the basicity and catalytic performance of ZIF-8, a series of K-loaded ZIF-8 catalysts (K/ZIF-8) were prepared by varying the KOH content from 5 to 10 wt%. Characterization of the synthesized catalysts was conducted using powder X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), high-resolution transmission electron microscopy (HRTEM), and temperature-programmed desorption (TPD) techniques. The ZIF-8 and K/ZIF-8 catalysts were applied in the transesterification of glycerol (GL) and dimethyl carbonate (DMC) to form glycerol carbonate (GLC). Various reaction parameters, including DMC/GL molar ratio, KOH loading, catalyst amount, and reaction temperature, were systematically studied to optimize the GLC yield. Under optimized conditions, the 10 wt% KOH-loaded ZIF-8 catalyst (10-K/ZIF-8) demonstrated excellent catalytic activity, achieving up to 95% GLC yield at a DMC/GL molar ratio of 3:1 within 0.5 hours. Remarkably, despite the hygroscopic nature of potassium, the catalyst exhibited significant water resistance, maintaining performance with up to 5 wt% water in relation to GL. Furthermore, the catalyst retained its activity after three recycling cycles without any notable loss in catalytic efficiency. This study highlights the potential of K/ZIF-8 as an efficient, water-tolerant catalyst for the transesterification of GL with DMC, offering high GLC yields and recyclability. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=metal-organic%20frameworks%20%28MOFs%29" title="metal-organic frameworks (MOFs)">metal-organic frameworks (MOFs)</a>, <a href="https://publications.waset.org/abstracts/search?q=zeolitic%20imidazolate%20frameworks%20%28ZIFs%29" title=" zeolitic imidazolate frameworks (ZIFs)"> zeolitic imidazolate frameworks (ZIFs)</a>, <a href="https://publications.waset.org/abstracts/search?q=transesterification" title=" transesterification"> transesterification</a>, <a href="https://publications.waset.org/abstracts/search?q=sustainable%20catalytic" title=" sustainable catalytic"> sustainable catalytic</a> </p> <a href="https://publications.waset.org/abstracts/195202/moisture-resistant-k-loaded-zif-8-catalyst-for-glycerol-carbonate-production" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/195202.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">2</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3167</span> Mixed Matrix Membranes Based on [M₂(DOBDC)] (M = Mg, Co, Ni) and Polydimethylsiloxane for CO₂/N₂ Separation</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Hyunuk%20Kim">Hyunuk Kim</a>, <a href="https://publications.waset.org/abstracts/search?q=Yang%20No%20Yun"> Yang No Yun</a>, <a href="https://publications.waset.org/abstracts/search?q=Muhammad%20Sohail"> Muhammad Sohail</a>, <a href="https://publications.waset.org/abstracts/search?q=Jong-Ho%20Moon"> Jong-Ho Moon</a>, <a href="https://publications.waset.org/abstracts/search?q=Young%20Cheol%20Park"> Young Cheol Park</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Metal-organic frameworks (MOFs), which are emerging absorbents assembled from metal ions and organic ligands, have attracted attention for their permanent porosity and design of tunable pore size. These microporous materials showed interesting properties for CO₂ storage and separation. In particular, MOFs with high surface area and open metal sites showed the remarkable adsorption capacity and selectivity for CO₂. [Mg₂ (DOBDC)] (DOBDC = 2,5-dioxidobenzene-1,4-dicarboxylate) (MOF-74 or CPO-27) is a well-known absorbent showing an exceptionally high CO₂ sorption capacity at low partial pressure and room temperature. In this work, we synthesized [M₂(DOBDC)(DMF)₂] (M = Mg, Co, Ni) and determined their single-crystal structures by X-ray crystallography. The removal of coordinated guest molecules generates Lewis acidic sites and showed high CO₂ adsorption affinity. Both CO₂ adsorption capacity and surface area are much higher than reported values in literature. To fabricate MMMs, microcrystalline [M₂ (DOBDC)(DMF)₂] was synthesized by microwave reaction and dispersed in PDMS solution. The MMMs with a various amount of [M₂ (DOBDC)(DMF) ₂] in PDMS were fabricated by a solution casting method. [M₂ (DOBDC)(DMF)₂]@PDMS membrane showed higher CO2 permeability and CO₂/N₂ selectivity than those of PDMS. Therefore, we believe that MMMs combining polymer and MOFs provide new materials for CO₂ separation technology. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=metal-organic%20frameworks" title="metal-organic frameworks">metal-organic frameworks</a>, <a href="https://publications.waset.org/abstracts/search?q=mixed%20matrix%20membrane" title=" mixed matrix membrane"> mixed matrix membrane</a>, <a href="https://publications.waset.org/abstracts/search?q=CO2%2FN2%20separation" title=" CO2/N2 separation"> CO2/N2 separation</a>, <a href="https://publications.waset.org/abstracts/search?q=polydimethylsiloxane%20%28PDMS%29" title=" polydimethylsiloxane (PDMS)"> polydimethylsiloxane (PDMS)</a> </p> <a href="https://publications.waset.org/abstracts/72483/mixed-matrix-membranes-based-on-m2dobdc-m-mg-co-ni-and-polydimethylsiloxane-for-co2n2-separation" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/72483.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">206</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3166</span> Separation of Lanthanides Ions from Mineral Waste with Functionalized Pillar[5]Arenes: Synthesis, Physicochemical Characterization and Molecular Dynamics Studies</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Ariesny%20Vera">Ariesny Vera</a>, <a href="https://publications.waset.org/abstracts/search?q=Rodrigo%20Montecinos"> Rodrigo Montecinos</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The rare-earth elements (REEs) or rare-earth metals (REMs), correspond to seventeen chemical elements composed by the fifteen lanthanoids, as well as scandium and yttrium. Lanthanoids corresponds to lanthanum and the f-block elements, from cerium to lutetium. Scandium and yttrium are considered rare-earth elements because they have ionic radii similar to the lighter f-block elements. These elements were called rare earths because they are simply more difficult to extract and separate individually than the most metals and, generally, they do not accumulate in minerals, they are rarely found in easily mined ores and are often unfavorably distributed in common ores/minerals. REEs show unique chemical and physical properties, in comparison to the other metals in the periodic table. Nowadays, these physicochemical properties are utilized in a wide range of synthetic, catalytic, electronic, medicinal, and military applications. Because of their applications, the global demand for rare earth metals is becoming progressively more important in the transition to a self-sustaining society and greener economy. However, due to the difficult separation between lanthanoid ions, the high cost and pollution of these processes, the scientists search the development of a method that combines selectivity and quantitative separation of lanthanoids from the leaching liquor, while being more economical and environmentally friendly processes. This motivation has favored the design and development of more efficient and environmentally friendly cation extractors with the incorporation of compounds as ionic liquids, membrane inclusion polymers (PIM) and supramolecular systems. Supramolecular chemistry focuses on the development of host-guest systems, in which a host molecule can recognize and bind a certain guest molecule or ion. Normally, the formation of a host-guest complex involves non-covalent interactions Additionally, host-guest interactions can be influenced among others effects by the structural nature of host and guests. The different macrocyclic hosts for lanthanoid species that have been studied are crown ethers, cyclodextrins, cucurbituryls, calixarenes and pillararenes.Among all the factors that can influence and affect lanthanoid (III) coordination, perhaps the most basic of them is the systematic control using macrocyclic substituents that promote a selective coordination. In this sense, macrocycles pillar[n]arenes (P[n]As) present a relatively easy functionalization and they have more π-rich cavity than other host molecules. This gives to P[n]As a negative electrostatic potential in the cavity which would be responsible for the selectivity of these compounds towards cations. Furthermore, the cavity size, the linker, and the functional groups of the polar headgroups could be modified in order to control the association of lanthanoid cations. In this sense, different P[n]As systems, specifically derivatives of the pentamer P[5]A functionalized with amide, amine, phosphate and sulfate derivatives, have been designed in terms of experimental synthesis and molecular dynamics, and the interaction between these P[5]As and some lanthanoid ions such as La³+, Eu³+ and Lu³+ has been studied by physicochemical characterization by 1H-NMR, ITC and fluorescence in the case of Eu³+ systems. The molecular dynamics study of these systems was developed in hexane as solvent, also taking into account the lanthanoid ions mentioned above, and the respective comparison studies between the different ions. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=lanthanoids" title="lanthanoids">lanthanoids</a>, <a href="https://publications.waset.org/abstracts/search?q=macrocycles" title=" macrocycles"> macrocycles</a>, <a href="https://publications.waset.org/abstracts/search?q=pillar%5Bn%5Darenes" title=" pillar[n]arenes"> pillar[n]arenes</a>, <a href="https://publications.waset.org/abstracts/search?q=rare-earth%20metal%20extraction" title=" rare-earth metal extraction"> rare-earth metal extraction</a>, <a href="https://publications.waset.org/abstracts/search?q=supramolecular%20chemistry" title=" supramolecular chemistry"> supramolecular chemistry</a>, <a href="https://publications.waset.org/abstracts/search?q=supramolecular%20complexes." title=" supramolecular complexes."> supramolecular complexes.</a> </p> <a href="https://publications.waset.org/abstracts/164684/separation-of-lanthanides-ions-from-mineral-waste-with-functionalized-pillar5arenes-synthesis-physicochemical-characterization-and-molecular-dynamics-studies" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/164684.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">77</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3165</span> Selective Guest Accommodation in Zn(II) Bimetallic: Organic Coordination Frameworks</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Bukunola%20K.%20Oguntade">Bukunola K. Oguntade</a>, <a href="https://publications.waset.org/abstracts/search?q=Gareth%20M.%20Watkins"> Gareth M. Watkins</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The synthesis and characterization of metal-organic frameworks (MOFs) is an area of coordination chemistry which has grown rapidly in recent years. Worldwide there has been growing concerns about future energy supplies, and its environmental impacts. A good number of MOFs have been tested for the adsorption of small molecules in the vapour phase. An important issue for potential applications of MOFs for gas adsorption and storage materials is the stability of their structure upon sorption. Therefore, study on the thermal stability of MOFs upon adsorption is important. The incorporation of two or more transition metals in a coordination polymer is a current challenge for designed synthesis. This work focused on the synthesis, characterization and small molecule adsorption properties of three microporous (one zinc monometal and two bimetallics) complexes involving Cu(II), Zn(II) and 1,2,4,5-benzenetetracarboxylic acid using the ambient precipitation and solvothermal method. The complexes were characterized by elemental analysis, Infrared spectroscopy, Scanning Electron microscopy, Thermogravimetry analysis and X-ray Powder diffraction. The N2-adsorption Isotherm showed the complexes to be of TYPE III in reference to IUPAC classification, with very small pores only capable for small molecule sorption. All the synthesized compounds were observed to contain water as guest. Investigations of their inclusion properties for small molecules in the vapour phase showed water and methanol as the only possible inclusion candidates with 10.25H2O in the monometal complex [Zn4(H2B4C)2.5(OH)3(H2O)]·10H2O but not reusable after a complete structural collapse. The ambient precipitation bimetallic; [(CuZnB4C(H2O)2]·5H2O, was found to be reusable and recoverable from structure collapse after adsorption of 5.75H2O. In addition, Solvo-[CuZnB4C(H2O)2.5]·2H2O obtained from solvothermal method show two cycles of rehydration with 1.75H2O and 0.75MeOH inclusion while structure remains unaltered upon dehydration and adsorption. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=adsorption" title="adsorption">adsorption</a>, <a href="https://publications.waset.org/abstracts/search?q=characterization" title=" characterization"> characterization</a>, <a href="https://publications.waset.org/abstracts/search?q=copper" title=" copper"> copper</a>, <a href="https://publications.waset.org/abstracts/search?q=metal%20-organic%20frameworks" title=" metal -organic frameworks"> metal -organic frameworks</a>, <a href="https://publications.waset.org/abstracts/search?q=zinc" title=" zinc"> zinc</a> </p> <a href="https://publications.waset.org/abstracts/96381/selective-guest-accommodation-in-znii-bimetallic-organic-coordination-frameworks" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/96381.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">134</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3164</span> Synthesis and Characterization of pH-Sensitive Graphene Quantum Dot-Loaded Metal-Organic Frameworks for Targeted Drug Delivery and Fluorescent Imaging</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Sayed%20Maeen%20Badshah">Sayed Maeen Badshah</a>, <a href="https://publications.waset.org/abstracts/search?q=Kuen-Song%20Lin"> Kuen-Song Lin</a>, <a href="https://publications.waset.org/abstracts/search?q=Abrar%20Hussain"> Abrar Hussain</a>, <a href="https://publications.waset.org/abstracts/search?q=Jamshid%20Hussain"> Jamshid Hussain</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Liver cancer is a significant global health issue, ranking fifth in incidence and second in mortality. Effective therapeutic strategies are urgently needed to combat this disease, particularly in regions with high prevalence. This study focuses on developing and characterizing fluorescent organometallic frameworks as distinct drug delivery carriers with potential applications in both the treatment and biological imaging of liver cancer. This work introduces two distinct organometallic frameworks: the cake-shaped GQD@NH₂-MIL-125 and the cross-shaped M8U6/FM8U6. The GQD@NH₂-MIL-125 framework is particularly noteworthy for its high fluorescence, making it an effective tool for biological imaging. X-ray diffraction (XRD) analysis revealed specific diffraction peaks at 6.81ᵒ (011), 9.76ᵒ (002), and 11.69ᵒ (121), with an additional significant peak at 26ᵒ (2θ), corresponding to the carbon material. Morphological analysis using Field Emission Scanning Electron Microscopy (FE-SEM), and Transmission Electron Microscopy (TEM) demonstrated that the framework has a front particle size of 680 nm and a side particle size of 55±5 nm. High-resolution TEM (HR-TEM) images confirmed the successful attachment of graphene quantum dots (GQDs) onto the NH2-MIL-125 framework. Fourier-Transform Infrared (FT-IR) spectroscopy identified crucial functional groups within the GQD@NH₂-MIL-125 structure, including O-Ti-O metal bonds within the 500 to 700 cm⁻¹ range, and N-H and C-N bonds at 1,646 cm⁻¹ and 1,164 cm⁻¹, respectively. BET isotherm analysis further revealed a specific surface area of 338.1 m²/g and an average pore size of 46.86 nm. This framework also demonstrated UV-active properties, as identified by UV-visible light spectra, and its photoluminescence (PL) spectra showed an emission peak around 430 nm when excited at 350 nm, indicating its potential as a fluorescent drug delivery carrier. In parallel, the cross-shaped M8U6/FM8U6 frameworks were synthesized and characterized using X-ray diffraction, which identified distinct peaks at 2θ = 7.4 (111), 8.5 (200), 9.2 (002), 10.8 (002), 12.1 (220), 16.7 (103), and 17.1 (400). FE-SEM, HR-TEM, and TEM analyses revealed particle sizes of 350±50 nm for M8U6 and 200±50 nm for FM8U6. These frameworks, synthesized from terephthalic acid (H₂BDC), displayed notable vibrational bonds, such as C=O at 1,650 cm⁻¹, Fe-O in MIL-88 at 520 cm⁻¹, and Zr-O in UIO-66 at 482 cm⁻¹. BET analysis showed specific surface areas of 740.1 m²/g with a pore size of 22.92 nm for M8U6 and 493.9 m²/g with a pore size of 35.44 nm for FM8U6. Extended X-ray Absorption Fine Structure (EXAFS) spectra confirmed the stability of Ti-O bonds in the frameworks, with bond lengths of 2.026 Å for MIL-125, 1.962 Å for NH₂-MIL-125, and 1.817 Å for GQD@NH₂-MIL-125. These findings highlight the potential of these organometallic frameworks for enhanced liver cancer therapy through precise drug delivery and imaging, representing a significant advancement in nanomaterial applications in biomedical science. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=liver%20cancer%20cells" title="liver cancer cells">liver cancer cells</a>, <a href="https://publications.waset.org/abstracts/search?q=metal%20organic%20frameworks" title=" metal organic frameworks"> metal organic frameworks</a>, <a href="https://publications.waset.org/abstracts/search?q=Doxorubicin%20%28DOX%29" title=" Doxorubicin (DOX)"> Doxorubicin (DOX)</a>, <a href="https://publications.waset.org/abstracts/search?q=drug%20release." title=" drug release."> drug release.</a> </p> <a href="https://publications.waset.org/abstracts/194174/synthesis-and-characterization-of-ph-sensitive-graphene-quantum-dot-loaded-metal-organic-frameworks-for-targeted-drug-delivery-and-fluorescent-imaging" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/194174.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">9</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3163</span> Theoretical and Experimental Investigation of Fe and Ni-TCNQ on Graphene</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=A.%20Shahsavar">A. Shahsavar</a>, <a href="https://publications.waset.org/abstracts/search?q=Z.%20Jakub"> Z. Jakub</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Due to the outstanding properties of the 2D metal-organic frameworks (MOF), intensive computational and experimental studies have been done. However, the lack of fundamental studies of MOFs on the graphene backbone is observed. This work studies Fe and Ni as metal and tetracyanoquinodimethane (TCNQ) with a high electron affinity as an organic linker functionalized on graphene. Here we present DFT calculations results to unveil the electronic and magnetic properties of iron and nickel-TCNQ physisorbed on graphene. Adsorption and Fermi energies, structural, and magnetic properties will be reported. Our experimental observations prove Fe- and NiTCNQ@Gr/Ir(111) are thermally highly stable up to 500 and 250°C, respectively, making them promising materials for single-atom catalysts or high-density storage media. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=DFT" title="DFT">DFT</a>, <a href="https://publications.waset.org/abstracts/search?q=graphene" title=" graphene"> graphene</a>, <a href="https://publications.waset.org/abstracts/search?q=MTCNQ" title=" MTCNQ"> MTCNQ</a>, <a href="https://publications.waset.org/abstracts/search?q=self-assembly" title=" self-assembly"> self-assembly</a> </p> <a href="https://publications.waset.org/abstracts/151583/theoretical-and-experimental-investigation-of-fe-and-ni-tcnq-on-graphene" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/151583.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">132</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3162</span> Factors Influencing the Resistance of the Purchase of Organic Food and Market Education Process in Indonesia</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Fety%20Nurlia%20Muzayanah">Fety Nurlia Muzayanah</a>, <a href="https://publications.waset.org/abstracts/search?q=Arif%20Imam%20Suroso"> Arif Imam Suroso</a>, <a href="https://publications.waset.org/abstracts/search?q=Mukhamad%20Najib"> Mukhamad Najib</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The market share of organic food in Indonesia just reaches 0.5-2 percents from the entire of agricultural products. The aim of this research is to analyze the relation of gender, work, age and final education toward the buying interest of organic food, to identify the factors influencing the resistance of the purchase of organic food, and to identify the market education process. The analysis result of Structural Equation Modeling (SEM) shows the factors causing the resistance of the purchase of organic food are the negative attitude toward organic food, the lack of affordable in range for organic food product and the lack of awareness toward organic food, while the subjective norms have no significant effect toward the buying interest. The market education process which can be done is the education about the use of the health of organic food, the organic certification and the economic value. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=market%20education" title="market education">market education</a>, <a href="https://publications.waset.org/abstracts/search?q=organic%20food" title=" organic food"> organic food</a>, <a href="https://publications.waset.org/abstracts/search?q=consumer%20behavior" title=" consumer behavior"> consumer behavior</a>, <a href="https://publications.waset.org/abstracts/search?q=structural%20equation%20modeling" title=" structural equation modeling"> structural equation modeling</a> </p> <a href="https://publications.waset.org/abstracts/21708/factors-influencing-the-resistance-of-the-purchase-of-organic-food-and-market-education-process-in-indonesia" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/21708.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">613</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3161</span> Consumer Attitude and Purchase Intention towards Organic Food: Insights from Pakistan</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Muneshia%20Maheshwar">Muneshia Maheshwar</a>, <a href="https://publications.waset.org/abstracts/search?q=Kanwal%20Gul"> Kanwal Gul</a>, <a href="https://publications.waset.org/abstracts/search?q=Shakira%20%20Fareed"> Shakira Fareed</a>, <a href="https://publications.waset.org/abstracts/search?q=Ume-Amama%20Areeb%20Gul"> Ume-Amama Areeb Gul</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Organic food is commonly known for its healthier content without the use of pesticides, herbicides, inorganic fertilizers, antibiotics and growth hormones. The aim of this research is to examine the effect of health consciousness, environmental concern and organic food knowledge on both the intention to buy organic foods and the attitude towards organic foods and the effect of attitude towards organic foods on the intention to buy organic foods in Pakistan. Primary data was used which was collected through adopted questionnaire from previous research. Non- probability convenience sampling was used to select sample size of 200 consumers based on Karachi. The data was analyzed through Descriptive statistics and Multi regression method. The findings of the study showed that the attitude and the intention to buy organic food were affected by health consciousness, environmental concern, and organic food knowledge. The results also revealed that attitude also affects the intention to buy organic food. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=health%20consciousness" title="health consciousness">health consciousness</a>, <a href="https://publications.waset.org/abstracts/search?q=attitude" title=" attitude"> attitude</a>, <a href="https://publications.waset.org/abstracts/search?q=intention%20to%20purchase" title=" intention to purchase"> intention to purchase</a>, <a href="https://publications.waset.org/abstracts/search?q=environmental%20concern" title=" environmental concern"> environmental concern</a>, <a href="https://publications.waset.org/abstracts/search?q=organic%20food%20knowledge" title=" organic food knowledge"> organic food knowledge</a> </p> <a href="https://publications.waset.org/abstracts/78597/consumer-attitude-and-purchase-intention-towards-organic-food-insights-from-pakistan" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/78597.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">248</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3160</span> High Temperature and High Pressure Purification of Hydrogen from Syngas Using Metal Organic Framework Adsorbent</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Samira%20Rostom">Samira Rostom</a>, <a href="https://publications.waset.org/abstracts/search?q=Robert%20Symonds"> Robert Symonds</a>, <a href="https://publications.waset.org/abstracts/search?q=Robin%20W.%20Hughes"> Robin W. Hughes</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Hydrogen is considered as one of the most important clean and renewable energy carriers for a sustainable energy future. However, its efficient and cost-effective purification remains challenging. This paper presents the potential of using metal–organic frameworks (MOFs) in combination with pressure swing adsorption (PSA) technology for syngas based H2 purification. PSA process analysis is done considering high pressure and elevated temperature process conditions, it reduces the demand for off-gas recycle to the fuel reactor and simultaneously permits higher desorption pressure, thereby reducing the parasitic load on the hydrogen compressor. The elevated pressure and temperature adsorption we present here is beneficial to minimizing overall process heating and cooling demand compared to existing processes. Here, we report the comparative performance of zeolite-5A, Cu-BTC, and the mix of zeolite-5A/Cu-BTC for H2 purification from syngas typical of those exiting water-gas-shift reactors. The MOFs were synthesized hydrothermally and then mixed systematically at different weight ratios to find the optimum composition based on the adsorption performance. The formation of different compounds were characterized by XRD, N2 adsorption and desorption, SEM, FT-IR, TG, and water vapor adsorption technologies. Single-component adsorption isotherms of CO2, CO, CH4, N2, and H2 over single materials and composites were measured at elevated pressures and different temperatures to determine their equilibrium adsorption capacity. The examination of the stability and regeneration performance of metal–organic frameworks was carried out using a gravimetric system at temperature ranges of 25-150℃ for a pressure range of 0-30 bar. The studies of adsorption/desorption on the MOFs showed selective adsorption of CO2, CH4, CO, and N2 over H2. Overall, the findings of this study suggest that the Ni-MOF-74/Cu-BTC composites are promising candidates for industrial H2 purification processes. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=MOF" title="MOF">MOF</a>, <a href="https://publications.waset.org/abstracts/search?q=H2%20purification" title=" H2 purification"> H2 purification</a>, <a href="https://publications.waset.org/abstracts/search?q=high%20T" title=" high T"> high T</a>, <a href="https://publications.waset.org/abstracts/search?q=PSA" title=" PSA"> PSA</a> </p> <a href="https://publications.waset.org/abstracts/160618/high-temperature-and-high-pressure-purification-of-hydrogen-from-syngas-using-metal-organic-framework-adsorbent" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/160618.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">101</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3159</span> Layer by Layer Coating of Zinc Oxide/Metal Organic Framework Nanocomposite on Ceramic Support for Solvent/Solvent Separation Using Pervaporation Method</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=S.%20A.%20A.%20Nabeela%20Nasreen">S. A. A. Nabeela Nasreen</a>, <a href="https://publications.waset.org/abstracts/search?q=S.%20Sundarrajan"> S. Sundarrajan</a>, <a href="https://publications.waset.org/abstracts/search?q=S.%20A.%20Syed%20Nizar"> S. A. Syed Nizar</a>, <a href="https://publications.waset.org/abstracts/search?q=Seeram%20Ramakrishna"> Seeram Ramakrishna</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Metal-organic frameworks (MOFs) have attracted considerable interest due to its diverse pore size tunability, fascinating topologies and extensive uses in fields such as catalysis, membrane separation, chemical sensing, etc. Zeolitic imidazolate frameworks (ZIFs) are a class of MOF with porous crystals containing extended three-dimensional structures of tetrahedral metal ions (e.g., Zn) bridged by Imidazolate (Im). Selected ZIFs are used to separate solvent/solvent mixtures. A layer by layer formation of the nanocomposite of Zinc oxide (ZnO) and ZIF on a ceramic support using a solvothermal method was engaged and tested for target solvent/solvent separation. Metal oxide layer was characterized by XRD, SEM, and TEM to confirm the smooth and continuous coating for the separation process. The chemical composition of ZIF films was studied by using X-Ray absorption near-edge structure (XANES) spectroscopy. The obtained ceramic tube with metal oxide and ZIF layer coating were tested for its packing density, thickness, distribution of seed layers and variation of permeation rate of solvent mixture (isopropyl alcohol (IPA)/methyl isobutyl ketone (MIBK). Pervaporation technique was used for the separation to achieve a high permeation rate with separation ratio of > 99.5% of the solvent mixture. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=metal%20oxide" title="metal oxide">metal oxide</a>, <a href="https://publications.waset.org/abstracts/search?q=membrane" title=" membrane"> membrane</a>, <a href="https://publications.waset.org/abstracts/search?q=pervaporation" title=" pervaporation"> pervaporation</a>, <a href="https://publications.waset.org/abstracts/search?q=solvothermal" title=" solvothermal"> solvothermal</a>, <a href="https://publications.waset.org/abstracts/search?q=ZIF" title=" ZIF"> ZIF</a> </p> <a href="https://publications.waset.org/abstracts/97314/layer-by-layer-coating-of-zinc-oxidemetal-organic-framework-nanocomposite-on-ceramic-support-for-solventsolvent-separation-using-pervaporation-method" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/97314.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">197</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3158</span> DFT Insights into CO₂ Capture Mechanisms and Kinetics in Diamine-Appended Grafted Mg₂ (dobpdc) Metal- Organic Frameworks</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Mao-Sheng%20Su">Mao-Sheng Su</a>, <a href="https://publications.waset.org/abstracts/search?q=Santhanamoorthi%20Nachimuthu"> Santhanamoorthi Nachimuthu</a>, <a href="https://publications.waset.org/abstracts/search?q=Jyh-Chiang%20Jiang"> Jyh-Chiang Jiang</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Climate change is widely recognized as a global crisis, with anthropogenic CO₂ emissions from fossil fuel combustion and industrial processes being major contributors. To address this challenge, carbon capture and sequestration (CCS) technology has emerged as a key strategy for selectively capturing CO₂ from flue gas streams. Among the various solid adsorbents, metal–organic frameworks (MOFs) are notable for their extensive surface area and controllable pore chemistry. The porous MOF structure is comprised of metal ions or clusters coordinated to organic linker compounds. In particular, the pore parameters of MOFs are readily tunable, making them promising materials for CO₂ capture applications. Among these, amine-functionalized MOFs have demonstrated exceptional CO₂ capture abilities because their high uptake capacity and selectivity. In this study, we have investigated the CO₂ capture abilities and adsorption mechanisms of the diamine-appended framework N-Ethylethylenediamine-Mg₂(4,4’-dioxidobiphenyl-3,3’-dicarboxylate) (e-2-Mg₂(dobpdc)) using density functional theory (DFT) calculations. Previous studies have suggested that CO₂ can be captured via both outer- and inner-amine binding sites. Our findings reveal that CO₂ adsorption at the outer amine site is kinetically more favorable compared to the inner amine site, with a lower energy barrier of 1.34 eV for CO₂ physisorption to chemisorption compared to the inner amine, which has an activation barrier of 1.60 eV. Furthermore, we find that CO₂ adsorption is significantly enhanced in an alkaline environment, as deprotonation of the diamine molecule reduces the energy barrier to 0.24 eV. This theoretical study provides detailed insights into CO₂ adsorption in diamine-appended e-2-Mg₂(dobpdc) MOF, offering a deeper understanding of CO₂ capture mechanisms and valuable information for the advancement of effective CO₂ sequestration technologies. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=DFT" title="DFT">DFT</a>, <a href="https://publications.waset.org/abstracts/search?q=MOFs" title=" MOFs"> MOFs</a>, <a href="https://publications.waset.org/abstracts/search?q=CO%E2%82%82%20capture" title=" CO₂ capture"> CO₂ capture</a>, <a href="https://publications.waset.org/abstracts/search?q=catalyst" title=" catalyst"> catalyst</a> </p> <a href="https://publications.waset.org/abstracts/192123/dft-insights-into-co2-capture-mechanisms-and-kinetics-in-diamine-appended-grafted-mg2-dobpdc-metal-organic-frameworks" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/192123.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">28</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3157</span> Ionic Liquids as Substrates for Metal-Organic Framework Synthesis</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Julian%20Mehler">Julian Mehler</a>, <a href="https://publications.waset.org/abstracts/search?q=Marcus%20Fischer"> Marcus Fischer</a>, <a href="https://publications.waset.org/abstracts/search?q=Martin%20Hartmann"> Martin Hartmann</a>, <a href="https://publications.waset.org/abstracts/search?q=Peter%20S.%20Schulz"> Peter S. Schulz</a> </p> <p class="card-text"><strong>Abstract:</strong></p> During the last two decades, the synthesis of metal-organic frameworks (MOFs) has gained ever increasing attention. Based on their pore size and shape as well as host-guest interactions, they are of interest for numerous fields related to porous materials, like catalysis and gas separation. Usually, MOF-synthesis takes place in an organic solvent between room temperature and approximately 220 °C, with mixtures of polyfunctional organic linker molecules and metal precursors as substrates. Reaction temperatures above the boiling point of the solvent, i.e. solvothermal reactions, are run in autoclaves or sealed glass vessels under autogenous pressures. A relatively new approach for the synthesis of MOFs is the so-called ionothermal synthesis route. It applies an ionic liquid as a solvent, which can serve as a structure-directing template and/or a charge-compensating agent in the final coordination polymer structure. Furthermore, this method often allows for less harsh reaction conditions than the solvothermal route. Here a variation of the ionothermal approach is reported, where the ionic liquid also serves as an organic linker source. By using 1-ethyl-3-methylimidazolium terephthalates ([EMIM][Hbdc] and [EMIM]₂[bdc]), the one-step synthesis of MIL-53(Al)/Boehemite composites with interesting features is possible. The resulting material is already formed at moderate temperatures (90-130 °C) and is stabilized in the usually unfavored ht-phase. Additionally, in contrast to already published procedures for MIL-53(Al) synthesis, no further activation at high temperatures is mandatory. A full characterization of this novel composite material is provided, including XRD, SS-NMR, El-Al., SEM as well as sorption measurements and its interesting features are compared to MIL-53(Al) samples produced by the classical solvothermal route. Furthermore, the syntheses of the applied ionic liquids and salts is discussed. The influence of the degree of ionicity of the linker source [EMIM]x[H(2-x)bdc] on the crystal structure and the achievable synthesis temperature are investigated and give insight into the role of the IL during synthesis. Aside from the synthesis of MIL-53 from EMIM terephthalates, the use of the phosphonium cation in this approach is discussed as well. Additionally, the employment of ILs in the preparation of other MOFs is presented briefly. This includes the ZIF-4 framework from the respective imidazolate ILs and chiral camphorate based frameworks from their imidazolium precursors. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=ionic%20liquids" title="ionic liquids">ionic liquids</a>, <a href="https://publications.waset.org/abstracts/search?q=ionothermal%20synthesis" title=" ionothermal synthesis"> ionothermal synthesis</a>, <a href="https://publications.waset.org/abstracts/search?q=material%20synthesis" title=" material synthesis"> material synthesis</a>, <a href="https://publications.waset.org/abstracts/search?q=MIL-53" title=" MIL-53"> MIL-53</a>, <a href="https://publications.waset.org/abstracts/search?q=MOFs" title=" MOFs"> MOFs</a> </p> <a href="https://publications.waset.org/abstracts/76567/ionic-liquids-as-substrates-for-metal-organic-framework-synthesis" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/76567.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">208</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3156</span> Consumer Behavior and Knowledge on Organic Products in Thailand</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Warunpun%20Kongsom">Warunpun Kongsom</a>, <a href="https://publications.waset.org/abstracts/search?q=Chaiwat%20Kongsom"> Chaiwat Kongsom</a> </p> <p class="card-text"><strong>Abstract:</strong></p> The objective of this study was to investigate the awareness, knowledge and consumer behavior towards organic products in Thailand. For this study, a purposive sampling technique was used to identify a sample group of 2,575 consumers over the age of 20 years who intended or made purchases from 1) green shops; 2) supermarkets with branches; and, 3) green markets. A questionnaire was used for data collection across the country. Descriptive statistics were used for data analysis. The results showed that more than 92% of consumers were aware of organic agriculture, but had less knowledge about it. More than 60% of consumers knew that organic agriculture production and processing did not allow the use of chemicals. And about 40% of consumers were confused between the food safety logo and the certified organic logo, and whether GMO was allowed in organic agriculture practice or not. In addition, most consumers perceived that organic agricultural products, good agricultural practice (GAP) products, agricultural chemicals free products, and hydroponic vegetable products had the same standard. In the view of organic consumers, the organic Thailand label was the most seen and reliable among various organic labels. Less than 3% of consumers thought that the International Federation of Organic Agriculture Movements (IFOAM) Global Organic Mark (GOM) was the most seen and reliable. For the behaviors of organic consumers, they purchased organic products mainly at the supermarket and green shop (55.4%), one to two times per month, and with a total expenditure of about 200 to 400 baht each time. The main reason for buying organic products was safety and free from agricultural chemicals. The considered factors in organic product selection were price (29.5%), convenience (22.4%), and a reliable certification system (21.3%). The demands for organic products were mainly rice, vegetables and fruits. Processed organic products were relatively small in quantity. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=consumer%20behavior" title="consumer behavior">consumer behavior</a>, <a href="https://publications.waset.org/abstracts/search?q=consumer%20knowledge" title=" consumer knowledge"> consumer knowledge</a>, <a href="https://publications.waset.org/abstracts/search?q=organic%20products" title=" organic products"> organic products</a>, <a href="https://publications.waset.org/abstracts/search?q=Thailand" title=" Thailand"> Thailand</a> </p> <a href="https://publications.waset.org/abstracts/47388/consumer-behavior-and-knowledge-on-organic-products-in-thailand" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/47388.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">296</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3155</span> Sustainability of Offshore Petroleum Resources Extraction and Management of Bangladesh: International and Regional Frameworks</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Muhammad%20Farhad%20Hosen">Muhammad Farhad Hosen</a> </p> <p class="card-text"><strong>Abstract:</strong></p> This article examines the sustainability of offshore petroleum resource extraction and management in Bangladesh, focusing on international and regional frameworks. The analysis includes international conventions such as UNCLOS, IMO regulations, and SDGs, as well as regional cooperation through organizations like BIMSTEC and SAARC. The objective is to highlight the impact of these frameworks on sustainable extraction practices, address challenges, and offer recommendations for enhancing Bangladesh's legal and regulatory approaches to offshore resource management. The article underscores the need for harmonizing national laws with international standards, enhancing enforcement mechanisms, and promoting regional cooperation to ensure sustainable development. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=Bangladesh" title="Bangladesh">Bangladesh</a>, <a href="https://publications.waset.org/abstracts/search?q=international%20frameworks" title=" international frameworks"> international frameworks</a>, <a href="https://publications.waset.org/abstracts/search?q=offshore%20petroleum" title=" offshore petroleum"> offshore petroleum</a>, <a href="https://publications.waset.org/abstracts/search?q=regional%20framework" title=" regional framework"> regional framework</a>, <a href="https://publications.waset.org/abstracts/search?q=sustainability" title=" sustainability"> sustainability</a> </p> <a href="https://publications.waset.org/abstracts/191015/sustainability-of-offshore-petroleum-resources-extraction-and-management-of-bangladesh-international-and-regional-frameworks" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/191015.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">28</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3154</span> Designing Metal Organic Frameworks for Sustainable CO₂ Utilization</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Matthew%20E.%20Potter">Matthew E. Potter</a>, <a href="https://publications.waset.org/abstracts/search?q=Daniel%20J.%20Stewart"> Daniel J. Stewart</a>, <a href="https://publications.waset.org/abstracts/search?q=Lindsay%20M.%20Armstrong"> Lindsay M. Armstrong</a>, <a href="https://publications.waset.org/abstracts/search?q=Pier%20J.%20A.%20Sazio"> Pier J. A. Sazio</a>, <a href="https://publications.waset.org/abstracts/search?q=Robert%20R.%20Raja"> Robert R. Raja</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Rising CO₂ levels in the atmosphere means that CO₂ is a highly desirable feedstock. This requires specific catalysts to be designed to activate this inert molecule, combining a catalytic site tailored for CO₂ transformations with a support that can readily adsorb CO₂. Metal organic frameworks (MOFs) are regularly used as CO₂ sorbents. The organic nature of the linker molecules, connecting the metal nodes, offers many post-synthesis modifications to introduce catalytic active sites into the frameworks. However, the metal nodes may be coordinatively unsaturated, allowing them to bind to organic moieties. Imidazoles have shown promise catalyzing the formation of cyclic carbonates from epoxides with CO₂. Typically, this synthesis route employs toxic reagents such as phosgene, liberating HCl. Therefore an alternative route with CO₂ is highly appealing. In this work we design active sites for CO₂ activation, by tethering substituted-imidazole organocatalytic species to the available Cr3+ metal nodes of a Cr-MIL-101 MOF, for the first time, to create a tailored species for carbon capture utilization applications. Our tailored design strategy combining a CO₂ sorbent, Cr-MIL-101, with an anchored imidazole results in a highly active and selective multifunctional catalyst, achieving turnover frequencies of over 750 hr-1. These findings demonstrate the synergy between the MOF framework and imidazoles for CO₂ utilization applications. Further, the effect of substrate variation has been explored yielding mechanistic insights into this process. Through characterization, we show that the structural and compositional integrity of the Cr-MIL-101 has been preserved on functionalizing the imidazoles. Further, we show the binding of the imidazoles to the Cr3+ metal nodes. This can be seen through our EPR study, where the distortion of the Cr3+ on binding to the imidazole shows the CO₂ binding site is close to the active imidazole. This has a synergistic effect, improving catalytic performance. We believe the combination of MOF support and organocatalyst allows many possibilities to generate new multifunctional catalysts for CO₂ utilisation. In conclusion, we have validated our design procedure, combining a known CO₂ sorbent, with an active imidazole species to create a unique tailored multifunctional catalyst for CO₂ utilization. This species achieves high activity and selectivity for the formation of cyclic carbonates and offers a sustainable alternative to traditional synthesis methods. This work represents a unique design strategy for CO₂ utilization while offering exciting possibilities for further work in characterization, computational modelling, and post-synthesis modification. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=carbonate" title="carbonate">carbonate</a>, <a href="https://publications.waset.org/abstracts/search?q=catalysis" title=" catalysis"> catalysis</a>, <a href="https://publications.waset.org/abstracts/search?q=MOF" title=" MOF"> MOF</a>, <a href="https://publications.waset.org/abstracts/search?q=utilisation" title=" utilisation"> utilisation</a> </p> <a href="https://publications.waset.org/abstracts/75794/designing-metal-organic-frameworks-for-sustainable-co2-utilization" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/75794.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">180</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3153</span> Quantum Sieving for Hydrogen Isotope Separation</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Hyunchul%20Oh">Hyunchul Oh</a> </p> <p class="card-text"><strong>Abstract:</strong></p> One of the challenges in modern separation science and technology is the separation of hydrogen isotopes mixtures since D2 and H2 consist of almost identical size, shape and thermodynamic properties. Recently, quantum sieving of isotopes by confinement in narrow space has been proposed as an alternative technique. Despite many theoretical suggestions, however, it has been difficult to discover a feasible microporous material up to now. Among various porous materials, the novel class of microporous framework materials (COFs, ZIFs and MOFs) is considered as a promising material class for isotope sieving due to ultra-high porosity and uniform pore size which can be tailored. Hence, we investigate experimentally the fundamental correlation between D2/H2 molar ratio and pore size at optimized operating conditions by using different ultramicroporous frameworks. The D2/H2 molar ratio is strongly depending on pore size, pressure and temperature. An experimentally determined optimum pore diameter for quantum sieving lies between 3.0 and 3.4 Å which can be an important guideline for designing and developing feasible microporous frameworks for isotope separation. Afterwards, we report a novel strategy for efficient hydrogen isotope separation at technologically relevant operating pressure through the development of quantum sieving exploited by the pore aperture engineering. The strategy involves installation of flexible components in the pores of the framework to tune the pore surface. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=gas%20adsorption" title="gas adsorption">gas adsorption</a>, <a href="https://publications.waset.org/abstracts/search?q=hydrogen%20isotope" title=" hydrogen isotope"> hydrogen isotope</a>, <a href="https://publications.waset.org/abstracts/search?q=metal%20organic%20frameworks%28MOFs%29" title=" metal organic frameworks(MOFs)"> metal organic frameworks(MOFs)</a>, <a href="https://publications.waset.org/abstracts/search?q=quantum%20sieving" title=" quantum sieving"> quantum sieving</a> </p> <a href="https://publications.waset.org/abstracts/41208/quantum-sieving-for-hydrogen-isotope-separation" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/41208.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">265</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3152</span> An Organic Dye-Based Staining for Plant DNA</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Beg%C3%BCm%20Terzi">Begüm Terzi</a>, <a href="https://publications.waset.org/abstracts/search?q=%C3%96zlem%20Ate%C5%9F%20S%C3%B6nmezo%C4%9Flu"> Özlem Ateş Sönmezoğlu</a>, <a href="https://publications.waset.org/abstracts/search?q=Kerime%20%C3%96zkay"> Kerime Özkay</a>, <a href="https://publications.waset.org/abstracts/search?q=Ahmet%20Y%C4%B1ld%C4%B1r%C4%B1m"> Ahmet Yıldırım</a> </p> <p class="card-text"><strong>Abstract:</strong></p> In plant biotechnology, electrophoresis is used to detect nucleic acids. Ethidium bromide (EtBr) is used as an intercalator dye to stain DNA in agarose gel electrophoresis, but this dye is mutagenic and carcinogenic. In this study, a visible, reliable and organic Ruthenium-based dye (N-719) for staining plant DNA in comparison to EtBr. When prestaining and post-staining for gel electrophoresis, N-719 stained both DNA and PCR product bands with the same clarity as EtBr. The organic dye N-719 stained DNA bands as sensitively and as clearly as EtBr. The organic dye was found to have staining activity suitable for the identification of DNA.Consequently, N-719 organic dye can be used to stain and visualize DNA during gel electrophoresis as alternatives to EtBr in plant biotechnology studies. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=agarose%20gel" title="agarose gel">agarose gel</a>, <a href="https://publications.waset.org/abstracts/search?q=DNA%20staining" title=" DNA staining"> DNA staining</a>, <a href="https://publications.waset.org/abstracts/search?q=organic%20dye" title=" organic dye"> organic dye</a>, <a href="https://publications.waset.org/abstracts/search?q=N-719" title=" N-719"> N-719</a> </p> <a href="https://publications.waset.org/abstracts/68758/an-organic-dye-based-staining-for-plant-dna" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/68758.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">267</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3151</span> Programming Systems in Implementation of Process Safety at Chemical Process Industry</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Maryam%20Shayan">Maryam Shayan</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Programming frameworks have been utilized as a part of chemical industry process safety operation and configuration to enhance its effectiveness. This paper gives a brief survey and investigation of the best in class and effects of programming frameworks in process security. A study was completed by talking staff accountable for procedure wellbeing practices in the Iranian chemical process industry and diving into writing of innovation for procedure security. This article investigates the useful and operational attributes of programming frameworks for security and endeavors to sort the product as indicated by its level of effect in the administration chain of importance. The study adds to better comprehension of the parts of Information Communication Technology in procedure security, the future patterns and conceivable gaps for innovative work. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=programming%20frameworks" title="programming frameworks">programming frameworks</a>, <a href="https://publications.waset.org/abstracts/search?q=chemical%20industry%20process" title=" chemical industry process"> chemical industry process</a>, <a href="https://publications.waset.org/abstracts/search?q=process%20security" title=" process security"> process security</a>, <a href="https://publications.waset.org/abstracts/search?q=administration%20chain" title=" administration chain"> administration chain</a>, <a href="https://publications.waset.org/abstracts/search?q=information%20communication%20technology" title=" information communication technology"> information communication technology</a> </p> <a href="https://publications.waset.org/abstracts/32709/programming-systems-in-implementation-of-process-safety-at-chemical-process-industry" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/32709.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">373</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3150</span> Metal-Organic Frameworks for Innovative Functional Textiles</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Hossam%20E.%20Emam">Hossam E. Emam</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Metal–organic frameworks (MOFs) are new hybrid materials investigated from 15 years ago; they synthesized from metals as inorganic center joined with multidentate organic linkers to form a 1D, 2D or 3D network structure. MOFs have unique properties such as pore crystalline structure, large surface area, chemical tenability and luminescent characters. These significant properties enable MOFs to be applied in many fields such like gas storage, adsorption/separation, drug delivery/biomedicine, catalysis, polymerization, magnetism and luminescence applications. Recently, many of published reports interested in superiority of MOFs for functionalization of textiles to exploit the unique properties of MOFs. Incorporation of MOFs is found to acquire the textiles some additional formidable functions to be used in considerable fields such like water treatment and fuel purification. Modification of textiles with MOFs could be easily performed by two main techniques; Ex-situ (preparation of MOFs then applied onto textiles) and in-situ (ingrowth of MOFs within textiles networks). Uniqueness of MOFs could be assimilated in acquirement of decorative color, antimicrobial character, anti-mosquitos character, ultraviolet radiation protective, self-clean, photo-luminescent and sensor character. Additionally, textiles treatment with MOFs make it applicable as filter in the adsorption of toxic gases, hazardous materials (such as pesticides, dyes and aromatics molecules) and fuel purification (such as removal of oxygenated, nitrogenated and sulfur compounds). Also, the porous structure of MOFs make it mostly utilized in control release of insecticides from the surface of the textile. Moreover, MOF@textiles as recyclable materials lead it applicable as photo-catalyst composites for photo-degradation of different dyes in the day light. Therefore, MOFs is extensively considered for imparting textiles with formidable properties as ingeniousness way for textile functionalization. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=MOF" title="MOF">MOF</a>, <a href="https://publications.waset.org/abstracts/search?q=functional%20textiles" title=" functional textiles"> functional textiles</a>, <a href="https://publications.waset.org/abstracts/search?q=water%20treatment" title=" water treatment"> water treatment</a>, <a href="https://publications.waset.org/abstracts/search?q=fuel%20purification" title=" fuel purification"> fuel purification</a>, <a href="https://publications.waset.org/abstracts/search?q=environmental%20applications" title=" environmental applications"> environmental applications</a> </p> <a href="https://publications.waset.org/abstracts/123054/metal-organic-frameworks-for-innovative-functional-textiles" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/123054.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">145</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3149</span> Governing Urban Water Infrasystems: A Case Study of Los Angeles in the Context of Global Frameworks</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Joachim%20Monkelbaan">Joachim Monkelbaan</a>, <a href="https://publications.waset.org/abstracts/search?q=Marcia%20Hale"> Marcia Hale</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Now that global frameworks for sustainability governance (e.g. the Sustainable Development Goals, Paris Climate Agreement and Sendai Framework for Disaster Risk Reduction) are in place, the question is how these aspirations that represent major transitions can be put into practice. Water ‘infrasystems’ can play an especially significant role in strengthening regional sustainability. Infrasystems include both hard and soft infrastructure, such as pipes and technology for delivering water, as well as the institutions and governance models that direct its delivery. As such, an integrated infrasystems view is crucial for Integrative Water Management (IWM). Due to frequently contested ownership of and responsibility for water resources, these infrasystems can also play an important role in facilitating conflict and catalysing community empowerment, especially through participatory approaches to governance. In this paper, we analyze the water infrasystem of the Los Angeles region through the lens of global frameworks for sustainability governance. By complementing a solid overview of governance theories with empirical data from interviews with water actors in the LA metropolitan region (including NGOs, water managers, scientists and elected officials), this paper elucidates ways for this infrasystem to be better aligned with global sustainability frameworks. In addition, it opens up the opportunity to scrutinize the appropriateness of global frameworks when it comes to fostering sustainability action at the local level. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=governance" title="governance">governance</a>, <a href="https://publications.waset.org/abstracts/search?q=transitions" title=" transitions"> transitions</a>, <a href="https://publications.waset.org/abstracts/search?q=global%20frameworks" title=" global frameworks"> global frameworks</a>, <a href="https://publications.waset.org/abstracts/search?q=infrasystems" title=" infrasystems"> infrasystems</a> </p> <a href="https://publications.waset.org/abstracts/48236/governing-urban-water-infrasystems-a-case-study-of-los-angeles-in-the-context-of-global-frameworks" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/48236.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">245</span> </span> </div> </div> <div class="card paper-listing mb-3 mt-3"> <h5 class="card-header" style="font-size:.9rem"><span class="badge badge-info">3148</span> Development of Metal-Organic Frameworks-Type Hybrid Functionalized Materials for Selective Uranium Extraction</h5> <div class="card-body"> <p class="card-text"><strong>Authors:</strong> <a href="https://publications.waset.org/abstracts/search?q=Damien%20Rinsant">Damien Rinsant</a>, <a href="https://publications.waset.org/abstracts/search?q=Eugen%20Andreiadis"> Eugen Andreiadis</a>, <a href="https://publications.waset.org/abstracts/search?q=Michael%20Carboni"> Michael Carboni</a>, <a href="https://publications.waset.org/abstracts/search?q=Daniel%20Meyer"> Daniel Meyer</a> </p> <p class="card-text"><strong>Abstract:</strong></p> Different types of materials have been developed for the solid/liquid uranium extraction processes, such as functionalized organic polymers, hybrid silica or inorganic adsorbents. In general, these materials exhibit a moderate affinity for uranyl ions and poor selectivity against impurities like iron, vanadium or molybdenum. Moreover, the structural organization deficiency of these materials generates ion diffusion issues inside the material. Therefore, the aim of our study is to developed efficient and organized materials, stable in the acid media encountered in uranium extraction processes. Metal organic frameworks (MOFs) are hybrid crystalline materials consisting of an inorganic part (cluster or metal ions) and tailored organic linkers connected via coordination bonds. These hierarchical materials have exceptional surface area, thermal stability and a large variety of tunable structures. However, due to the reversibility of constitutive coordination bonds, MOFs have moderate stability in strongly complexing or acidic media. Only few of them are known to be stable in aqueous media and only one example is described in strong acidic media. However, these conditions are very often encountered in the environmental pollution remediation of mine wastewaters. To tackle the challenge of developing MOFs adapted for uranium extraction from acid mine waters, we have investigated the stability of several materials. To ensure a good stability we have synthetized and characterized different materials based on highly coordinated metal clusters, such as LnOFs and Zirconium based materials. Among the latter, the UiO family shows a great stability in sulfuric acid media even in the presence of 1.4 M sodium sulfate at pH 2. However, the stability in phosphoric media is reduced due to the high affinity between zirconium and phosphate ligand. Based on these results, we have developed a tertiary amine functionalized MOF denoted UiO-68-NMe2 particularly adapted for the extraction of anionic uranyl (VI) sulfate complexes mainly present in the acid mine solutions. The adsorption capacity of the material has been determined upon varying total sulfate concentration, contact time and uranium concentration. The extraction tests put in evidence different phenomena due to the complexity of the extraction media and the interaction between the MOF and sulfate anion. Finally, the extraction mechanisms and the interaction between uranyl and the MOF structure have been investigated. The functionalized material UiO-68-NMe2 has been characterized in the presence and absence of uranium by FT-IR, UV and Raman techniques. Moreover, the stability of the protonated amino functionalized MOF has been evaluated. The synthesis, characterization and evaluation of this type of hybrid material, particularly adapted for uranium extraction in sulfuric acid media by an anionic exchange mechanism, paved the way for the development of metal organic frameworks functionalized by different other chelating motifs, such as bifunctional ligands showing an enhanced affinity and selectivity for uranium in acid and complexing media. Work in this direction is currently in progress. <p class="card-text"><strong>Keywords:</strong> <a href="https://publications.waset.org/abstracts/search?q=extraction" title="extraction">extraction</a>, <a href="https://publications.waset.org/abstracts/search?q=MOF" title=" MOF"> MOF</a>, <a href="https://publications.waset.org/abstracts/search?q=ligand" title=" ligand"> ligand</a>, <a href="https://publications.waset.org/abstracts/search?q=uranium" title=" uranium"> uranium</a> </p> <a href="https://publications.waset.org/abstracts/97172/development-of-metal-organic-frameworks-type-hybrid-functionalized-materials-for-selective-uranium-extraction" class="btn btn-primary btn-sm">Procedia</a> <a href="https://publications.waset.org/abstracts/97172.pdf" target="_blank" class="btn btn-primary btn-sm">PDF</a> <span class="bg-info text-light px-1 py-1 float-right rounded"> Downloads <span class="badge badge-light">160</span> </span> </div> </div> <ul class="pagination"> <li class="page-item 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